A Comparative Kinetic and Computational Investigation of the CarbonSulfur Cross Coupling of Potassium Thioacetate and 2Bromo Thiophene Using Palladium/Bisphosphine Complexes
S. Peschtrich, R. Schoch, D. Kuckling, J. Paradies, European Journal of Organic Chemistry 27 (2024).
LibreCat: /record/52541
DOI: 10.1002/ejoc.202301207

Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements
L. Köring, B. Birenheide, F. Krämer, J.O. Wenzel, R. Schoch, M. Brehm, F. Breher, J. Paradies, European Journal of Inorganic Chemistry (2024).
LibreCat: /record/52572
DOI: 10.1002/ejic.202400057

BoronCentered Lewis Superacid through RedoxActive Ligands: Application in C–F and S–F Bond Activation
L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer, F. Breher, J. Paradies, Angewandte Chemie International Edition (2023).
LibreCat: /record/35694
DOI: 10.1002/anie.202216959

Frustrated Lewis Pair Catalysed Reactions
R. Zhou, Z. Tavandashti, J. Paradies, SynOpen (2023).
LibreCat: /record/35693
DOI: 10.1055/a-2005-5443

BoronCentered Lewis Superacid through RedoxActive Ligands: Application in CF and SF Bond Activation
L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer, F. Breher, J. Paradies, Angewandte Chemie International Edition (2023).
LibreCat: /record/42878
DOI: 10.1002/anie.202301632

BoronCentered Lewis Superacid through RedoxActive Ligands: Application in CF and SF Bond Activation
L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer, F. Breher, J. Paradies, Angewandte Chemie (2023).
LibreCat: /record/42879
DOI: 10.1002/ange.202301632

Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed Hydrogenations, Dehydrogenations, and Cycloisomerizations
J. Paradies, Accounts of Chemical Research 56 (2023) 821–834.
LibreCat: /record/44523
DOI: 10.1021/acs.accounts.2c00832

Dispersion EnergyStabilized Boron and Phosphorus Lewis Pairs
B. Sieland, M. Stahn, R. Schoch, C. Daniliuc, S. Spicher, S. Grimme, A. Hansen, J. Paradies, Angewandte Chemie International Edition (2023).
LibreCat: /record/46277
DOI: 10.1002/anie.202308752

A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media
F. Krämer, J. Paradies, I. Fernández, F. Breher, Nature Chemistry (2023).
LibreCat: /record/47589
DOI: 10.1038/s41557-023-01340-9

Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbonbased Ambiphiles
F. Krämer, J. Paradies, I. Fernández, F. Breher, Chemistry – A European Journal 30 (2023).
LibreCat: /record/52542
DOI: 10.1002/chem.202303380

Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022)
P. Hou, S. Peschtrich, N. Huber, W. Feuerstein, A. Bihlmeier, I. Krummenacher, R. Schoch, W. Klopper, F. Breher, J. Paradies, Chemistry – A European Journal 28 (2022).
LibreCat: /record/35703
DOI: 10.1002/chem.202200982

Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives
P. Hou, S. Peschtrich, N. Huber, W. Feuerstein, A. Bihlmeier, I. Krummenacher, R. Schoch, W. Klopper, F. Breher, J. Paradies, Chemistry – A European Journal 28 (2022).
LibreCat: /record/35688
DOI: 10.1002/chem.202200478

Sigmatropic [1,5] Carbon Shift of Transient  Ammonium Enolates
G. Wicker, R. Zhou, R. Schoch, J. Paradies, Angewandte Chemie International Edition 61 (2022).
LibreCat: /record/35689
DOI: 10.1002/anie.202204378

Cover Picture: Sigmatropic [1,5] Carbon Shift of Transient  Ammonium Enolates (Angew. Chem. Int. Ed. 31/2022)
G. Wicker, R. Zhou, R. Schoch, J. Paradies, Angewandte Chemie International Edition 61 (2022).
LibreCat: /record/35691
DOI: 10.1002/anie.202207944

Frustrated Lewis PairCatalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis
B. Sieland, A. Hoppe, A.J. Stepen, J. Paradies, Advanced Synthesis &;amp; Catalysis 364 (2022) 3143–3148.
LibreCat: /record/35692
DOI: 10.1002/adsc.202200525

Coupling of CO<sub>2</sub> and epoxides catalysed by novel <i>N</i>-fused mesoionic carbene complexes of nickel(<scp>ii</scp>)
F.A. Watt, B. Sieland, N. Dickmann, R. Schoch, R. Herbst-Irmer, H. Ott, J. Paradies, D. Kuckling, S. Hohloch, Dalton Transactions 50 (2021) 17361–17371.
LibreCat: /record/31019
DOI: 10.1039/d1dt03311e

MixedValence Compounds as Polarizing Agents for Overhauser Dynamic Nuclear Polarization in Solids
A. Gurinov, B. Sieland, A. Kuzhelev, H. Elgabarty, T. Kühne, T. Prisner, J. Paradies, M. Baldus, K.L. Ivanov, S. Pylaeva, Angewandte Chemie International Edition 60 (2021) 15371–15375.
LibreCat: /record/33653
DOI: 10.1002/anie.202103215

Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides
J. Paradies, L. Köring, N.A. Sitte, Synthesis 54 (2021) 1287–1300.
LibreCat: /record/35686
DOI: 10.1055/a-1681-3972

Borane Catalyzed Redox Isomerization of 2Amino Chalcones: Hydride Abstraction or Hydride Migration?
R. Zhou, J. Paradies, European Journal of Organic Chemistry 2021 (2021) 6334–6339.
LibreCat: /record/35687
DOI: 10.1002/ejoc.202100883

Diastereoselective Synthesis of Dihydro-quinolin-4-ones by a Borane-Catalyzed Redox-Neutral endo-1,7-Hydride Shift
G. Wicker, R. Schoch, J. Paradies, Organic Letters (2021) 3626–3630.
LibreCat: /record/22232
DOI: 10.1021/acs.orglett.1c01018