[{"year":"2018","page":"4243–4247","intvolume":"        10","citation":{"ama":"Rothermel N, Bouzouita D, Rother T, et al. Surprising Differences of Alkane C-H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface-Substrate Recognition? <i>ChemCatChem</i>. 2018;10(19):4243–4247. doi:<a href=\"https://doi.org/10.1002/cctc.201801022\">10.1002/cctc.201801022</a>","chicago":"Rothermel, N., D. Bouzouita, T. Rother, I. Rosal, S. Tricard, R. Poteau, Torsten Gutmann, B. Chaudret, H. H. Limbach, and G. Buntkowsky. “Surprising Differences of Alkane C-H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface-Substrate Recognition?” <i>ChemCatChem</i> 10, no. 19 (2018): 4243–4247. <a href=\"https://doi.org/10.1002/cctc.201801022\">https://doi.org/10.1002/cctc.201801022</a>.","ieee":"N. Rothermel <i>et al.</i>, “Surprising Differences of Alkane C-H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface-Substrate Recognition?,” <i>ChemCatChem</i>, vol. 10, no. 19, pp. 4243–4247, 2018, doi: <a href=\"https://doi.org/10.1002/cctc.201801022\">10.1002/cctc.201801022</a>.","apa":"Rothermel, N., Bouzouita, D., Rother, T., Rosal, I., Tricard, S., Poteau, R., Gutmann, T., Chaudret, B., Limbach, H. H., &#38; Buntkowsky, G. (2018). Surprising Differences of Alkane C-H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface-Substrate Recognition? <i>ChemCatChem</i>, <i>10</i>(19), 4243–4247. <a href=\"https://doi.org/10.1002/cctc.201801022\">https://doi.org/10.1002/cctc.201801022</a>","mla":"Rothermel, N., et al. “Surprising Differences of Alkane C-H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface-Substrate Recognition?” <i>ChemCatChem</i>, vol. 10, no. 19, 2018, pp. 4243–4247, doi:<a href=\"https://doi.org/10.1002/cctc.201801022\">10.1002/cctc.201801022</a>.","short":"N. Rothermel, D. Bouzouita, T. Rother, I. Rosal, S. Tricard, R. Poteau, T. Gutmann, B. Chaudret, H.H. Limbach, G. Buntkowsky, ChemCatChem 10 (2018) 4243–4247.","bibtex":"@article{Rothermel_Bouzouita_Rother_Rosal_Tricard_Poteau_Gutmann_Chaudret_Limbach_Buntkowsky_2018, title={Surprising Differences of Alkane C-H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface-Substrate Recognition?}, volume={10}, DOI={<a href=\"https://doi.org/10.1002/cctc.201801022\">10.1002/cctc.201801022</a>}, number={19}, journal={ChemCatChem}, author={Rothermel, N. and Bouzouita, D. and Rother, T. and Rosal, I. and Tricard, S. and Poteau, R. and Gutmann, Torsten and Chaudret, B. and Limbach, H. H. and Buntkowsky, G.}, year={2018}, pages={4243–4247} }"},"issue":"19","title":"Surprising Differences of Alkane C-H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface-Substrate Recognition?","doi":"10.1002/cctc.201801022","date_updated":"2026-02-17T16:13:52Z","volume":10,"author":[{"last_name":"Rothermel","full_name":"Rothermel, N.","first_name":"N."},{"full_name":"Bouzouita, D.","last_name":"Bouzouita","first_name":"D."},{"first_name":"T.","full_name":"Rother, T.","last_name":"Rother"},{"first_name":"I.","last_name":"Rosal","full_name":"Rosal, I."},{"first_name":"S.","full_name":"Tricard, S.","last_name":"Tricard"},{"first_name":"R.","full_name":"Poteau, R.","last_name":"Poteau"},{"last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165","first_name":"Torsten"},{"first_name":"B.","last_name":"Chaudret","full_name":"Chaudret, B."},{"first_name":"H. H.","last_name":"Limbach","full_name":"Limbach, H. H."},{"first_name":"G.","last_name":"Buntkowsky","full_name":"Buntkowsky, G."}],"date_created":"2026-02-07T16:06:27Z","abstract":[{"text":"The activation of C-H bonds of alkanes remains a major challenge for chemistry. In a series of deuteration experiments with D-2 in contact with bis-(diphenylphosphino) butane (dppb) stabilized ruthenium nanoparticles (liquid substrates, 60 degrees C, 6 bar D-2) we have observed a surprisingly large reactivity of cyclopentane as compared to cyclohexane and other alkanes. DFT calculations using a ligand-free Ru13H17 model cluster as catalyst indicate oxidative C-H cleavage of the bound substrates as rate limiting reaction step. They also indicate similar binding and activation enthalpies of reactions of cyclopentane and cyclohexane.","lang":"eng"}],"status":"public","publication":"ChemCatChem","type":"journal_article","extern":"1","language":[{"iso":"eng"}],"_id":"64031","user_id":"100715"},{"extern":"1","language":[{"iso":"eng"}],"user_id":"100715","_id":"64007","status":"public","abstract":[{"lang":"eng","text":"The equilibration of H2, HD and D2 between the gas phase and surface hydrides of solid organic-ligand-stabilized Ru metal nanoparticles has been studied by gas phase 1H NMR spectroscopy using closed NMR tubes as batch reactors at room temperature and 800 mbar. When two different nanoparticle systems, Ru/PVP (PVP [identical with] polyvinylpyrrolidone) and Ru/HDA (HDA [identical with] hexadecylamine) were exposed to D2 gas, only the release of HD from the hydride containing surface could be detected in the initial stages of the reaction, but no H2. In the case of Ru/HDA also the reverse experiment was performed where surface deuterated nanoparticles were exposed to H2. In that case, the conversion of H2 into gaseous HD was detected. In order to analyze the experimental kinetic and spectroscopic data, we explored two different mechanisms taking into account potential kinetic and equilibrium H/D isotope effects. Firstly, we explored the dissociative exchange mechanism consisting of dissociative adsorption of dihydrogen, fast hydride surface diffusion and associative desorption of dihydrogen. It is shown that if D2 is the reaction partner, only H2 will be released in the beginning of the reaction, and HD only in later reaction stages. The second mechanism, dubbed here associative exchange consists of the binding of dihydrogen to Ru surface atoms, followed by a H-transfer to or by H-exchange with an adjacent hydride site, and finally of the associative desorption of dihydrogen. In that case, in the exchange with D2, only HD will be released in the beginning of the reaction. Our experimental results are not compatible with the dissociative exchange but can be explained in terms of the associative exchange. Whereas the former will dominate at low temperatures and pressures, the latter will prevail around room temperature and normal pressures where transition metal nanoparticles are generally used as reaction catalysts."}],"type":"journal_article","publication":"Physical Chemistry Chemical Physics","doi":"10.1039/C7CP07770J","title":"Gas phase 1H NMR studies and kinetic modeling of dihydrogen isotope equilibration catalyzed by Ru-nanoparticles under normal conditions: dissociative vs. associative exchange","author":[{"last_name":"Limbach","full_name":"Limbach, Hans-Heinrich","first_name":"Hans-Heinrich"},{"first_name":"Tal","last_name":"Pery","full_name":"Pery, Tal"},{"last_name":"Rothermel","full_name":"Rothermel, Niels","first_name":"Niels"},{"full_name":"Chaudret, Bruno","last_name":"Chaudret","first_name":"Bruno"},{"id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann","first_name":"Torsten"},{"full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky","first_name":"Gerd"}],"date_created":"2026-02-07T15:56:08Z","volume":20,"date_updated":"2026-02-17T16:15:31Z","publisher":"The Royal Society of Chemistry","citation":{"apa":"Limbach, H.-H., Pery, T., Rothermel, N., Chaudret, B., Gutmann, T., &#38; Buntkowsky, G. (2018). Gas phase 1H NMR studies and kinetic modeling of dihydrogen isotope equilibration catalyzed by Ru-nanoparticles under normal conditions: dissociative vs. associative exchange. <i>Physical Chemistry Chemical Physics</i>, <i>20</i>(16), 10697–10712. <a href=\"https://doi.org/10.1039/C7CP07770J\">https://doi.org/10.1039/C7CP07770J</a>","bibtex":"@article{Limbach_Pery_Rothermel_Chaudret_Gutmann_Buntkowsky_2018, title={Gas phase 1H NMR studies and kinetic modeling of dihydrogen isotope equilibration catalyzed by Ru-nanoparticles under normal conditions: dissociative vs. associative exchange}, volume={20}, DOI={<a href=\"https://doi.org/10.1039/C7CP07770J\">10.1039/C7CP07770J</a>}, number={16}, journal={Physical Chemistry Chemical Physics}, publisher={The Royal Society of Chemistry}, author={Limbach, Hans-Heinrich and Pery, Tal and Rothermel, Niels and Chaudret, Bruno and Gutmann, Torsten and Buntkowsky, Gerd}, year={2018}, pages={10697–10712} }","short":"H.-H. Limbach, T. Pery, N. Rothermel, B. Chaudret, T. Gutmann, G. Buntkowsky, Physical Chemistry Chemical Physics 20 (2018) 10697–10712.","mla":"Limbach, Hans-Heinrich, et al. “Gas Phase 1H NMR Studies and Kinetic Modeling of Dihydrogen Isotope Equilibration Catalyzed by Ru-Nanoparticles under Normal Conditions: Dissociative vs. Associative Exchange.” <i>Physical Chemistry Chemical Physics</i>, vol. 20, no. 16, The Royal Society of Chemistry, 2018, pp. 10697–10712, doi:<a href=\"https://doi.org/10.1039/C7CP07770J\">10.1039/C7CP07770J</a>.","ieee":"H.-H. Limbach, T. Pery, N. Rothermel, B. Chaudret, T. Gutmann, and G. Buntkowsky, “Gas phase 1H NMR studies and kinetic modeling of dihydrogen isotope equilibration catalyzed by Ru-nanoparticles under normal conditions: dissociative vs. associative exchange,” <i>Physical Chemistry Chemical Physics</i>, vol. 20, no. 16, pp. 10697–10712, 2018, doi: <a href=\"https://doi.org/10.1039/C7CP07770J\">10.1039/C7CP07770J</a>.","chicago":"Limbach, Hans-Heinrich, Tal Pery, Niels Rothermel, Bruno Chaudret, Torsten Gutmann, and Gerd Buntkowsky. “Gas Phase 1H NMR Studies and Kinetic Modeling of Dihydrogen Isotope Equilibration Catalyzed by Ru-Nanoparticles under Normal Conditions: Dissociative vs. Associative Exchange.” <i>Physical Chemistry Chemical Physics</i> 20, no. 16 (2018): 10697–10712. <a href=\"https://doi.org/10.1039/C7CP07770J\">https://doi.org/10.1039/C7CP07770J</a>.","ama":"Limbach H-H, Pery T, Rothermel N, Chaudret B, Gutmann T, Buntkowsky G. Gas phase 1H NMR studies and kinetic modeling of dihydrogen isotope equilibration catalyzed by Ru-nanoparticles under normal conditions: dissociative vs. associative exchange. <i>Physical Chemistry Chemical Physics</i>. 2018;20(16):10697–10712. doi:<a href=\"https://doi.org/10.1039/C7CP07770J\">10.1039/C7CP07770J</a>"},"intvolume":"        20","page":"10697–10712","year":"2018","issue":"16"},{"abstract":[{"text":"Seven novel dirhodium coordination polymers (Rh-2-Ln) (n = 1-7) are prepared by employing bitopic ligands to connect dirhodium nodes. The formation of the framework is confirmed by attenuated total reflectance Fourier transform infrared (ATR-FTIR) and H-1 C-13 cross polarization magic angle spinning nuclear magnetic resonance (CP MAS NMR) spectroscopy. Defect sites resulting from incomplete ligand substitution are revealed by F-19 MAS NMR. The random stacking behavior of the frameworks in the obtained solid is analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The Rh-2/O interaction in neighboring layers is investigated by diffuse reflectance ultra-violet visible light (DR-UV-vis) spectroscopy and X-ray photoelectron spectroscopy (XPS). This interaction is relevant to understand the catalytic behavior of various Rh-2-Ln catalysts in the cyclopropanation of styrene with ethyl diazoacetate (EDA). In this context, the structure-reactivity relationship is discussed by taking into consideration both interlayer Rh-2/O interactions and steric effects of side chains.","lang":"eng"}],"status":"public","type":"journal_article","publication":"Catalysis Science & Technology","keyword":["Chemistry","asymmetric cyclopropanation","c-h insertion","carbene transformations","carboxylates","catalysts","functionalization","immobilization","metal-organic frameworks","nmr","solid support"],"language":[{"iso":"eng"}],"extern":"1","_id":"64010","user_id":"100715","year":"2018","citation":{"chicago":"Liu, J. Q., Y. P. Xu, P. B. Groszewicz, M. Brodrecht, C. Fasel, K. Hofmann, X. J. Tan, Torsten Gutmann, and G. Buntkowsky. “Novel Dirhodium Coordination Polymers: The Impact of Side Chains on Cyclopropanation.” <i>Catalysis Science &#38; Technology</i> 8, no. 20 (2018): 5190–5200. <a href=\"https://doi.org/10.1039/c8cy01493k\">https://doi.org/10.1039/c8cy01493k</a>.","ieee":"J. Q. Liu <i>et al.</i>, “Novel dirhodium coordination polymers: the impact of side chains on cyclopropanation,” <i>Catalysis Science &#38; Technology</i>, vol. 8, no. 20, pp. 5190–5200, 2018, doi: <a href=\"https://doi.org/10.1039/c8cy01493k\">10.1039/c8cy01493k</a>.","ama":"Liu JQ, Xu YP, Groszewicz PB, et al. Novel dirhodium coordination polymers: the impact of side chains on cyclopropanation. <i>Catalysis Science &#38; Technology</i>. 2018;8(20):5190–5200. doi:<a href=\"https://doi.org/10.1039/c8cy01493k\">10.1039/c8cy01493k</a>","mla":"Liu, J. Q., et al. “Novel Dirhodium Coordination Polymers: The Impact of Side Chains on Cyclopropanation.” <i>Catalysis Science &#38; Technology</i>, vol. 8, no. 20, 2018, pp. 5190–5200, doi:<a href=\"https://doi.org/10.1039/c8cy01493k\">10.1039/c8cy01493k</a>.","bibtex":"@article{Liu_Xu_Groszewicz_Brodrecht_Fasel_Hofmann_Tan_Gutmann_Buntkowsky_2018, title={Novel dirhodium coordination polymers: the impact of side chains on cyclopropanation}, volume={8}, DOI={<a href=\"https://doi.org/10.1039/c8cy01493k\">10.1039/c8cy01493k</a>}, number={20}, journal={Catalysis Science &#38; Technology}, author={Liu, J. Q. and Xu, Y. P. and Groszewicz, P. B. and Brodrecht, M. and Fasel, C. and Hofmann, K. and Tan, X. J. and Gutmann, Torsten and Buntkowsky, G.}, year={2018}, pages={5190–5200} }","short":"J.Q. Liu, Y.P. Xu, P.B. Groszewicz, M. Brodrecht, C. Fasel, K. Hofmann, X.J. Tan, T. Gutmann, G. Buntkowsky, Catalysis Science &#38; Technology 8 (2018) 5190–5200.","apa":"Liu, J. Q., Xu, Y. P., Groszewicz, P. B., Brodrecht, M., Fasel, C., Hofmann, K., Tan, X. J., Gutmann, T., &#38; Buntkowsky, G. (2018). Novel dirhodium coordination polymers: the impact of side chains on cyclopropanation. <i>Catalysis Science &#38; Technology</i>, <i>8</i>(20), 5190–5200. <a href=\"https://doi.org/10.1039/c8cy01493k\">https://doi.org/10.1039/c8cy01493k</a>"},"intvolume":"         8","page":"5190–5200","publication_identifier":{"issn":["2044-4753"]},"issue":"20","title":"Novel dirhodium coordination polymers: the impact of side chains on cyclopropanation","doi":"10.1039/c8cy01493k","date_updated":"2026-02-17T16:15:22Z","date_created":"2026-02-07T15:57:34Z","author":[{"first_name":"J. Q.","full_name":"Liu, J. Q.","last_name":"Liu"},{"last_name":"Xu","full_name":"Xu, Y. P.","first_name":"Y. P."},{"full_name":"Groszewicz, P. B.","last_name":"Groszewicz","first_name":"P. B."},{"full_name":"Brodrecht, M.","last_name":"Brodrecht","first_name":"M."},{"first_name":"C.","last_name":"Fasel","full_name":"Fasel, C."},{"first_name":"K.","full_name":"Hofmann, K.","last_name":"Hofmann"},{"full_name":"Tan, X. J.","last_name":"Tan","first_name":"X. J."},{"first_name":"Torsten","last_name":"Gutmann","id":"118165","full_name":"Gutmann, Torsten"},{"last_name":"Buntkowsky","full_name":"Buntkowsky, G.","first_name":"G."}],"volume":8},{"author":[{"first_name":"P. W.","last_name":"Liu","full_name":"Liu, P. W."},{"first_name":"B.","full_name":"Pang, B.","last_name":"Pang"},{"first_name":"L.","full_name":"Tian, L.","last_name":"Tian"},{"last_name":"Schafer","full_name":"Schafer, T.","first_name":"T."},{"first_name":"Torsten","full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann"},{"first_name":"H.","last_name":"Liu","full_name":"Liu, H."},{"last_name":"Volkert","full_name":"Volkert, C. A.","first_name":"C. A."},{"first_name":"G.","full_name":"Buntkowsky, G.","last_name":"Buntkowsky"},{"last_name":"Zhang","full_name":"Zhang, K.","first_name":"K."}],"date_created":"2026-02-07T16:00:36Z","volume":11,"date_updated":"2026-02-17T16:15:14Z","doi":"10.1002/cssc.201801678","title":"Efficient, Self-Terminating Isolation of Cellulose Nanocrystals through Periodate Oxidation in Pickering Emulsions","issue":"20","citation":{"ama":"Liu PW, Pang B, Tian L, et al. Efficient, Self-Terminating Isolation of Cellulose Nanocrystals through Periodate Oxidation in Pickering Emulsions. <i>ChemSusChem</i>. 2018;11(20):3581–3585. doi:<a href=\"https://doi.org/10.1002/cssc.201801678\">10.1002/cssc.201801678</a>","chicago":"Liu, P. W., B. Pang, L. Tian, T. Schafer, Torsten Gutmann, H. Liu, C. A. Volkert, G. Buntkowsky, and K. Zhang. “Efficient, Self-Terminating Isolation of Cellulose Nanocrystals through Periodate Oxidation in Pickering Emulsions.” <i>ChemSusChem</i> 11, no. 20 (2018): 3581–3585. <a href=\"https://doi.org/10.1002/cssc.201801678\">https://doi.org/10.1002/cssc.201801678</a>.","ieee":"P. W. Liu <i>et al.</i>, “Efficient, Self-Terminating Isolation of Cellulose Nanocrystals through Periodate Oxidation in Pickering Emulsions,” <i>ChemSusChem</i>, vol. 11, no. 20, pp. 3581–3585, 2018, doi: <a href=\"https://doi.org/10.1002/cssc.201801678\">10.1002/cssc.201801678</a>.","short":"P.W. Liu, B. Pang, L. Tian, T. Schafer, T. Gutmann, H. Liu, C.A. Volkert, G. Buntkowsky, K. Zhang, ChemSusChem 11 (2018) 3581–3585.","bibtex":"@article{Liu_Pang_Tian_Schafer_Gutmann_Liu_Volkert_Buntkowsky_Zhang_2018, title={Efficient, Self-Terminating Isolation of Cellulose Nanocrystals through Periodate Oxidation in Pickering Emulsions}, volume={11}, DOI={<a href=\"https://doi.org/10.1002/cssc.201801678\">10.1002/cssc.201801678</a>}, number={20}, journal={ChemSusChem}, author={Liu, P. W. and Pang, B. and Tian, L. and Schafer, T. and Gutmann, Torsten and Liu, H. and Volkert, C. A. and Buntkowsky, G. and Zhang, K.}, year={2018}, pages={3581–3585} }","mla":"Liu, P. W., et al. “Efficient, Self-Terminating Isolation of Cellulose Nanocrystals through Periodate Oxidation in Pickering Emulsions.” <i>ChemSusChem</i>, vol. 11, no. 20, 2018, pp. 3581–3585, doi:<a href=\"https://doi.org/10.1002/cssc.201801678\">10.1002/cssc.201801678</a>.","apa":"Liu, P. W., Pang, B., Tian, L., Schafer, T., Gutmann, T., Liu, H., Volkert, C. A., Buntkowsky, G., &#38; Zhang, K. (2018). Efficient, Self-Terminating Isolation of Cellulose Nanocrystals through Periodate Oxidation in Pickering Emulsions. <i>ChemSusChem</i>, <i>11</i>(20), 3581–3585. <a href=\"https://doi.org/10.1002/cssc.201801678\">https://doi.org/10.1002/cssc.201801678</a>"},"intvolume":"        11","page":"3581–3585","year":"2018","user_id":"100715","_id":"64014","extern":"1","language":[{"iso":"eng"}],"type":"journal_article","publication":"ChemSusChem","status":"public","abstract":[{"lang":"eng","text":"Many efforts have been made to isolate native nanocrystals from raw materials in the last two decades, such as cellulose nanocrystals (CNCs), but existing methods still suffer from low yields, complicated synthesis processes, and nonuniform sizes of obtained CNCs. This study concerns a facile, self-terminating, and efficient method for the formation of uniform CNCs in high yields during the periodate oxidation process within Pickering emulsions. A biphasic system containing hexane with dissolved hexylamine and an aqueous solution of sodium periodate (NaIO4) was used as the reaction medium. Regulated by hexylamine, owing to its limited solubility in water, the pH value of the aqueous phase was enhanced to around 9.8, leading to the precipitation of sodium orthoperiodate (Na2H3IO6) nanoplates and thus the formation of the initial Pickering emulsions. During the gradual formation of cellulose nanofibers and then CNCs, CNCs were attracted to stabilize the interface of the Pickering emulsions, which prevented further decomposition of CNCs by the oxidizing agent in aqueous suspensions. Thus, this isolation strategy secured the efficient separation of CNCs based on their own particular amphiphilic properties and achieved a high yield of up to 56 wt%."}]},{"date_updated":"2026-02-17T16:15:45Z","date_created":"2026-02-07T15:52:47Z","author":[{"full_name":"Kumari, B.","last_name":"Kumari","first_name":"B."},{"last_name":"John","full_name":"John, D.","first_name":"D."},{"last_name":"Hoffmann","full_name":"Hoffmann, P.","first_name":"P."},{"first_name":"A.","last_name":"Spende","full_name":"Spende, A."},{"first_name":"M. E.","full_name":"Toimil-Molares, M. E.","last_name":"Toimil-Molares"},{"first_name":"C.","last_name":"Trautmann","full_name":"Trautmann, C."},{"last_name":"Hess","full_name":"Hess, C.","first_name":"C."},{"full_name":"Ruff, P.","last_name":"Ruff","first_name":"P."},{"first_name":"M.","full_name":"Schulze, M.","last_name":"Schulze"},{"first_name":"R.","last_name":"Stark","full_name":"Stark, R."},{"first_name":"G.","full_name":"Buntkowsky, G.","last_name":"Buntkowsky"},{"first_name":"A.","last_name":"Andrieu-Brunsen","full_name":"Andrieu-Brunsen, A."},{"first_name":"Torsten","id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann"}],"volume":232,"title":"Surface Enhanced DNP Assisted Solid-State NMR of Functionatized SiO2 Coated Potycarbonate Membranes","doi":"10.1515/zpch-2017-1032","publication_identifier":{"issn":["0942-9352"]},"issue":"7-8","year":"2018","citation":{"ama":"Kumari B, John D, Hoffmann P, et al. Surface Enhanced DNP Assisted Solid-State NMR of Functionatized SiO2 Coated Potycarbonate Membranes. <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>. 2018;232(7-8):1173–1186. doi:<a href=\"https://doi.org/10.1515/zpch-2017-1032\">10.1515/zpch-2017-1032</a>","chicago":"Kumari, B., D. John, P. Hoffmann, A. Spende, M. E. Toimil-Molares, C. Trautmann, C. Hess, et al. “Surface Enhanced DNP Assisted Solid-State NMR of Functionatized SiO2 Coated Potycarbonate Membranes.” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i> 232, no. 7–8 (2018): 1173–1186. <a href=\"https://doi.org/10.1515/zpch-2017-1032\">https://doi.org/10.1515/zpch-2017-1032</a>.","ieee":"B. Kumari <i>et al.</i>, “Surface Enhanced DNP Assisted Solid-State NMR of Functionatized SiO2 Coated Potycarbonate Membranes,” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, vol. 232, no. 7–8, pp. 1173–1186, 2018, doi: <a href=\"https://doi.org/10.1515/zpch-2017-1032\">10.1515/zpch-2017-1032</a>.","apa":"Kumari, B., John, D., Hoffmann, P., Spende, A., Toimil-Molares, M. E., Trautmann, C., Hess, C., Ruff, P., Schulze, M., Stark, R., Buntkowsky, G., Andrieu-Brunsen, A., &#38; Gutmann, T. (2018). Surface Enhanced DNP Assisted Solid-State NMR of Functionatized SiO2 Coated Potycarbonate Membranes. <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, <i>232</i>(7–8), 1173–1186. <a href=\"https://doi.org/10.1515/zpch-2017-1032\">https://doi.org/10.1515/zpch-2017-1032</a>","bibtex":"@article{Kumari_John_Hoffmann_Spende_Toimil-Molares_Trautmann_Hess_Ruff_Schulze_Stark_et al._2018, title={Surface Enhanced DNP Assisted Solid-State NMR of Functionatized SiO2 Coated Potycarbonate Membranes}, volume={232}, DOI={<a href=\"https://doi.org/10.1515/zpch-2017-1032\">10.1515/zpch-2017-1032</a>}, number={7–8}, journal={Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics}, author={Kumari, B. and John, D. and Hoffmann, P. and Spende, A. and Toimil-Molares, M. E. and Trautmann, C. and Hess, C. and Ruff, P. and Schulze, M. and Stark, R. and et al.}, year={2018}, pages={1173–1186} }","short":"B. Kumari, D. John, P. Hoffmann, A. Spende, M.E. Toimil-Molares, C. Trautmann, C. Hess, P. Ruff, M. Schulze, R. Stark, G. Buntkowsky, A. Andrieu-Brunsen, T. Gutmann, Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics 232 (2018) 1173–1186.","mla":"Kumari, B., et al. “Surface Enhanced DNP Assisted Solid-State NMR of Functionatized SiO2 Coated Potycarbonate Membranes.” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, vol. 232, no. 7–8, 2018, pp. 1173–1186, doi:<a href=\"https://doi.org/10.1515/zpch-2017-1032\">10.1515/zpch-2017-1032</a>."},"intvolume":"       232","page":"1173–1186","_id":"64000","user_id":"100715","language":[{"iso":"eng"}],"extern":"1","type":"journal_article","publication":"Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry & Chemical Physics","abstract":[{"lang":"eng","text":"Surface enhanced solid-state NMR by dynamic nuclear polarization (DNP SENS) enables the characterization of the inner-pore surface functionalization of porous etched ion-track membranes exhibiting low specific surface areas compared to typical SBA- or MCM-type mesoporous silica materials. The membranes were conformally coated with a 5 nm thin SiO2 layer by atomic layer deposition. This layer was subsequently modified by aminopropyl silane linkers that allow further functionalization via the terminal amine group. The results evidence that in principle DNP SENS is a capable tool to analyze more complex porous systems, e.g. bioinspired functional etched ion-track membranes down to the molecular level. These results are relevant also for single nanopore systems, for which a direct analysis of the channel surface functionalization is not feasible by classical characterization methods. The applicability of DNP SENS to complex porous systems requires the optimization of the sample preparation and measurement parameters."}],"status":"public"},{"issue":"34","publication_identifier":{"issn":["1932-7447"]},"page":"19540–19550","intvolume":"       122","citation":{"short":"B. Kumari, M. Brodrecht, H. Breitzke, M. Werner, B. Grunberg, H.H. Limbach, S. Forg, E.P. Sanjon, B. Drossel, T. Gutmann, G. Buntkowsky, Journal of Physical Chemistry C 122 (2018) 19540–19550.","mla":"Kumari, B., et al. “Mixtures of Alcohols and Water Confined in Mesoporous Silica: A Combined Solid-State NMR and Molecular Dynamics Simulation Study.” <i>Journal of Physical Chemistry C</i>, vol. 122, no. 34, 2018, pp. 19540–19550, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.8b04745\">10.1021/acs.jpcc.8b04745</a>.","bibtex":"@article{Kumari_Brodrecht_Breitzke_Werner_Grunberg_Limbach_Forg_Sanjon_Drossel_Gutmann_et al._2018, title={Mixtures of Alcohols and Water confined in Mesoporous Silica: A Combined Solid-State NMR and Molecular Dynamics Simulation Study}, volume={122}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.8b04745\">10.1021/acs.jpcc.8b04745</a>}, number={34}, journal={Journal of Physical Chemistry C}, author={Kumari, B. and Brodrecht, M. and Breitzke, H. and Werner, M. and Grunberg, B. and Limbach, H. H. and Forg, S. and Sanjon, E. P. and Drossel, B. and Gutmann, Torsten and et al.}, year={2018}, pages={19540–19550} }","apa":"Kumari, B., Brodrecht, M., Breitzke, H., Werner, M., Grunberg, B., Limbach, H. H., Forg, S., Sanjon, E. P., Drossel, B., Gutmann, T., &#38; Buntkowsky, G. (2018). Mixtures of Alcohols and Water confined in Mesoporous Silica: A Combined Solid-State NMR and Molecular Dynamics Simulation Study. <i>Journal of Physical Chemistry C</i>, <i>122</i>(34), 19540–19550. <a href=\"https://doi.org/10.1021/acs.jpcc.8b04745\">https://doi.org/10.1021/acs.jpcc.8b04745</a>","ama":"Kumari B, Brodrecht M, Breitzke H, et al. Mixtures of Alcohols and Water confined in Mesoporous Silica: A Combined Solid-State NMR and Molecular Dynamics Simulation Study. <i>Journal of Physical Chemistry C</i>. 2018;122(34):19540–19550. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.8b04745\">10.1021/acs.jpcc.8b04745</a>","chicago":"Kumari, B., M. Brodrecht, H. Breitzke, M. Werner, B. Grunberg, H. H. Limbach, S. Forg, et al. “Mixtures of Alcohols and Water Confined in Mesoporous Silica: A Combined Solid-State NMR and Molecular Dynamics Simulation Study.” <i>Journal of Physical Chemistry C</i> 122, no. 34 (2018): 19540–19550. <a href=\"https://doi.org/10.1021/acs.jpcc.8b04745\">https://doi.org/10.1021/acs.jpcc.8b04745</a>.","ieee":"B. Kumari <i>et al.</i>, “Mixtures of Alcohols and Water confined in Mesoporous Silica: A Combined Solid-State NMR and Molecular Dynamics Simulation Study,” <i>Journal of Physical Chemistry C</i>, vol. 122, no. 34, pp. 19540–19550, 2018, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.8b04745\">10.1021/acs.jpcc.8b04745</a>."},"year":"2018","volume":122,"author":[{"full_name":"Kumari, B.","last_name":"Kumari","first_name":"B."},{"last_name":"Brodrecht","full_name":"Brodrecht, M.","first_name":"M."},{"full_name":"Breitzke, H.","last_name":"Breitzke","first_name":"H."},{"full_name":"Werner, M.","last_name":"Werner","first_name":"M."},{"last_name":"Grunberg","full_name":"Grunberg, B.","first_name":"B."},{"full_name":"Limbach, H. H.","last_name":"Limbach","first_name":"H. H."},{"full_name":"Forg, S.","last_name":"Forg","first_name":"S."},{"last_name":"Sanjon","full_name":"Sanjon, E. P.","first_name":"E. P."},{"full_name":"Drossel, B.","last_name":"Drossel","first_name":"B."},{"first_name":"Torsten","last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165"},{"first_name":"G.","last_name":"Buntkowsky","full_name":"Buntkowsky, G."}],"date_created":"2026-02-07T15:51:48Z","date_updated":"2026-02-17T16:15:56Z","doi":"10.1021/acs.jpcc.8b04745","title":"Mixtures of Alcohols and Water confined in Mesoporous Silica: A Combined Solid-State NMR and Molecular Dynamics Simulation Study","publication":"Journal of Physical Chemistry C","type":"journal_article","status":"public","abstract":[{"text":"The behavior of mixtures of 1-octanol with water with different molar ratios confined inside the mesoporous silica SBA-15 was investigated by a combination of solid-state NMR spectroscopy and molecular dynamics (MD) simulations. Two-dimensional H-1-Si-29 FSLG-HET-COR NMR spectra revealed the orientation of 1-octanol relative to the pore walls. These arrangements are in good agreement with the preferred structures found by MD. In addition, MD simulations also shed light on molecular orientations and interactions in the pore center region, which are not resolvable by solid-state NMR.","lang":"eng"}],"user_id":"100715","_id":"63999","language":[{"iso":"eng"}],"extern":"1"},{"abstract":[{"lang":"eng","text":"The colligative property freezing point depression is evaluated as a means for estimating the extent of aggregation for solutions of poly(ethylene oxide) alcohol (C10E6) nonionic surfactant in cyclohexane. Combined with additional measurements of self-diffusion coefficients, it is shown that both unaggregated C10E6 as well as reverse micelles are significantly present for the entire range of measured C10E6 concentration (0.048−2.35 mol kg−1). A change in speciation near 0.2 mol kg−1 is indicated by the results from both freezing point depression and selfdiffusion coefficient measurements. It is shown that average reverse micelle radii and aggregation numbers obtained from the ratio of solvent and C10E6 self-diffusion coefficients are consistent with prior reported results. However, unreasonably small radii for the reverse micelles as well as for the cyclohexane were obtained from analysis of the results by the Stokes−Einstein equation using additional measured solution viscosities. The concentration of reverse micelles and unaggregated C10E6 was calculated from the freezing point depression results using the aggregation numbers obtained from ratio of self-diffusion coefficients. These concentrations indicate that the reverse micelles become smaller in average size and increase in number with increasing temperature without an increase in unaggregated C10E6."}],"status":"public","publication":"Journal of Physical Chemistry B","type":"journal_article","language":[{"iso":"eng"}],"extern":"1","_id":"63978","user_id":"100715","year":"2018","page":"4913–4921","intvolume":"       122","citation":{"short":"M.M. Hoffmann, S. Bothe, T. Gutmann, G. Buntkowsky, Journal of Physical Chemistry B 122 (2018) 4913–4921.","mla":"Hoffmann, Markus M., et al. “Combining Freezing Point Depression and Self-Diffusion Data for Characterizing Aggregation.” <i>Journal of Physical Chemistry B</i>, vol. 122, no. 18, American Chemical Society, 2018, pp. 4913–4921, doi:<a href=\"https://doi.org/10.1021/acs.jpcb.8b03456\">10.1021/acs.jpcb.8b03456</a>.","bibtex":"@article{Hoffmann_Bothe_Gutmann_Buntkowsky_2018, title={Combining Freezing Point Depression and Self-Diffusion Data for Characterizing Aggregation}, volume={122}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcb.8b03456\">10.1021/acs.jpcb.8b03456</a>}, number={18}, journal={Journal of Physical Chemistry B}, publisher={American Chemical Society}, author={Hoffmann, Markus M. and Bothe, Sarah and Gutmann, Torsten and Buntkowsky, Gerd}, year={2018}, pages={4913–4921} }","apa":"Hoffmann, M. M., Bothe, S., Gutmann, T., &#38; Buntkowsky, G. (2018). Combining Freezing Point Depression and Self-Diffusion Data for Characterizing Aggregation. <i>Journal of Physical Chemistry B</i>, <i>122</i>(18), 4913–4921. <a href=\"https://doi.org/10.1021/acs.jpcb.8b03456\">https://doi.org/10.1021/acs.jpcb.8b03456</a>","ama":"Hoffmann MM, Bothe S, Gutmann T, Buntkowsky G. Combining Freezing Point Depression and Self-Diffusion Data for Characterizing Aggregation. <i>Journal of Physical Chemistry B</i>. 2018;122(18):4913–4921. doi:<a href=\"https://doi.org/10.1021/acs.jpcb.8b03456\">10.1021/acs.jpcb.8b03456</a>","chicago":"Hoffmann, Markus M., Sarah Bothe, Torsten Gutmann, and Gerd Buntkowsky. “Combining Freezing Point Depression and Self-Diffusion Data for Characterizing Aggregation.” <i>Journal of Physical Chemistry B</i> 122, no. 18 (2018): 4913–4921. <a href=\"https://doi.org/10.1021/acs.jpcb.8b03456\">https://doi.org/10.1021/acs.jpcb.8b03456</a>.","ieee":"M. M. Hoffmann, S. Bothe, T. Gutmann, and G. Buntkowsky, “Combining Freezing Point Depression and Self-Diffusion Data for Characterizing Aggregation,” <i>Journal of Physical Chemistry B</i>, vol. 122, no. 18, pp. 4913–4921, 2018, doi: <a href=\"https://doi.org/10.1021/acs.jpcb.8b03456\">10.1021/acs.jpcb.8b03456</a>."},"issue":"18","title":"Combining Freezing Point Depression and Self-Diffusion Data for Characterizing Aggregation","doi":"10.1021/acs.jpcb.8b03456","publisher":"American Chemical Society","date_updated":"2026-02-17T16:17:10Z","volume":122,"date_created":"2026-02-07T15:43:11Z","author":[{"first_name":"Markus M.","full_name":"Hoffmann, Markus M.","last_name":"Hoffmann"},{"first_name":"Sarah","full_name":"Bothe, Sarah","last_name":"Bothe"},{"first_name":"Torsten","full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann"},{"full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky","first_name":"Gerd"}]},{"extern":"1","language":[{"iso":"eng"}],"_id":"63938","user_id":"100715","status":"public","publication":"Journal of Physical Chemistry C","type":"journal_article","title":"Getting Insights into the Influence of Crystal Plane Effect of Shaped Ceria on Its Catalytic Performances","doi":"10.1021/acs.jpcc.8b06138","date_updated":"2026-02-17T16:18:45Z","publisher":"American Chemical Society","volume":122,"author":[{"first_name":"Yuan","full_name":"Cao, Yuan","last_name":"Cao"},{"full_name":"Zhao, Li","last_name":"Zhao","first_name":"Li"},{"last_name":"Gutmann","id":"118165","full_name":"Gutmann, Torsten","first_name":"Torsten"},{"first_name":"Yeping","full_name":"Xu, Yeping","last_name":"Xu"},{"last_name":"Dong","full_name":"Dong, Lin","first_name":"Lin"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"},{"first_name":"Fei","last_name":"Gao","full_name":"Gao, Fei"}],"date_created":"2026-02-07T09:08:25Z","year":"2018","intvolume":"       122","page":"20402–20409","citation":{"short":"Y. Cao, L. Zhao, T. Gutmann, Y. Xu, L. Dong, G. Buntkowsky, F. Gao, Journal of Physical Chemistry C 122 (2018) 20402–20409.","mla":"Cao, Yuan, et al. “Getting Insights into the Influence of Crystal Plane Effect of Shaped Ceria on Its Catalytic Performances.” <i>Journal of Physical Chemistry C</i>, vol. 122, no. 35, American Chemical Society, 2018, pp. 20402–20409, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.8b06138\">10.1021/acs.jpcc.8b06138</a>.","bibtex":"@article{Cao_Zhao_Gutmann_Xu_Dong_Buntkowsky_Gao_2018, title={Getting Insights into the Influence of Crystal Plane Effect of Shaped Ceria on Its Catalytic Performances}, volume={122}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.8b06138\">10.1021/acs.jpcc.8b06138</a>}, number={35}, journal={Journal of Physical Chemistry C}, publisher={American Chemical Society}, author={Cao, Yuan and Zhao, Li and Gutmann, Torsten and Xu, Yeping and Dong, Lin and Buntkowsky, Gerd and Gao, Fei}, year={2018}, pages={20402–20409} }","apa":"Cao, Y., Zhao, L., Gutmann, T., Xu, Y., Dong, L., Buntkowsky, G., &#38; Gao, F. (2018). Getting Insights into the Influence of Crystal Plane Effect of Shaped Ceria on Its Catalytic Performances. <i>Journal of Physical Chemistry C</i>, <i>122</i>(35), 20402–20409. <a href=\"https://doi.org/10.1021/acs.jpcc.8b06138\">https://doi.org/10.1021/acs.jpcc.8b06138</a>","ieee":"Y. Cao <i>et al.</i>, “Getting Insights into the Influence of Crystal Plane Effect of Shaped Ceria on Its Catalytic Performances,” <i>Journal of Physical Chemistry C</i>, vol. 122, no. 35, pp. 20402–20409, 2018, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.8b06138\">10.1021/acs.jpcc.8b06138</a>.","chicago":"Cao, Yuan, Li Zhao, Torsten Gutmann, Yeping Xu, Lin Dong, Gerd Buntkowsky, and Fei Gao. “Getting Insights into the Influence of Crystal Plane Effect of Shaped Ceria on Its Catalytic Performances.” <i>Journal of Physical Chemistry C</i> 122, no. 35 (2018): 20402–20409. <a href=\"https://doi.org/10.1021/acs.jpcc.8b06138\">https://doi.org/10.1021/acs.jpcc.8b06138</a>.","ama":"Cao Y, Zhao L, Gutmann T, et al. Getting Insights into the Influence of Crystal Plane Effect of Shaped Ceria on Its Catalytic Performances. <i>Journal of Physical Chemistry C</i>. 2018;122(35):20402–20409. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.8b06138\">10.1021/acs.jpcc.8b06138</a>"},"publication_identifier":{"issn":["1932-7447"]},"issue":"35"},{"publication":"Journal of Physical Chemistry A","type":"journal_article","status":"public","user_id":"100715","_id":"63940","extern":"1","language":[{"iso":"eng"}],"issue":"45","intvolume":"       122","page":"8938–8947","citation":{"mla":"Dagys, Laurynas, et al. “Quasi-Equilibria and Polarization Transfer Between Adjacent and Remote Spins: 1H–13C CP MAS Kinetics in Glycine.” <i>Journal of Physical Chemistry A</i>, vol. 122, no. 45, American Chemical Society, 2018, pp. 8938–8947, doi:<a href=\"https://doi.org/10.1021/acs.jpca.8b09036\">10.1021/acs.jpca.8b09036</a>.","bibtex":"@article{Dagys_Klimavicius_Gutmann_Buntkowsky_Balevicius_2018, title={Quasi-Equilibria and Polarization Transfer Between Adjacent and Remote Spins: 1H–13C CP MAS Kinetics in Glycine}, volume={122}, DOI={<a href=\"https://doi.org/10.1021/acs.jpca.8b09036\">10.1021/acs.jpca.8b09036</a>}, number={45}, journal={Journal of Physical Chemistry A}, publisher={American Chemical Society}, author={Dagys, Laurynas and Klimavicius, Vytautas and Gutmann, Torsten and Buntkowsky, Gerd and Balevicius, Vytautas}, year={2018}, pages={8938–8947} }","short":"L. Dagys, V. Klimavicius, T. Gutmann, G. Buntkowsky, V. Balevicius, Journal of Physical Chemistry A 122 (2018) 8938–8947.","apa":"Dagys, L., Klimavicius, V., Gutmann, T., Buntkowsky, G., &#38; Balevicius, V. (2018). Quasi-Equilibria and Polarization Transfer Between Adjacent and Remote Spins: 1H–13C CP MAS Kinetics in Glycine. <i>Journal of Physical Chemistry A</i>, <i>122</i>(45), 8938–8947. <a href=\"https://doi.org/10.1021/acs.jpca.8b09036\">https://doi.org/10.1021/acs.jpca.8b09036</a>","ieee":"L. Dagys, V. Klimavicius, T. Gutmann, G. Buntkowsky, and V. Balevicius, “Quasi-Equilibria and Polarization Transfer Between Adjacent and Remote Spins: 1H–13C CP MAS Kinetics in Glycine,” <i>Journal of Physical Chemistry A</i>, vol. 122, no. 45, pp. 8938–8947, 2018, doi: <a href=\"https://doi.org/10.1021/acs.jpca.8b09036\">10.1021/acs.jpca.8b09036</a>.","chicago":"Dagys, Laurynas, Vytautas Klimavicius, Torsten Gutmann, Gerd Buntkowsky, and Vytautas Balevicius. “Quasi-Equilibria and Polarization Transfer Between Adjacent and Remote Spins: 1H–13C CP MAS Kinetics in Glycine.” <i>Journal of Physical Chemistry A</i> 122, no. 45 (2018): 8938–8947. <a href=\"https://doi.org/10.1021/acs.jpca.8b09036\">https://doi.org/10.1021/acs.jpca.8b09036</a>.","ama":"Dagys L, Klimavicius V, Gutmann T, Buntkowsky G, Balevicius V. Quasi-Equilibria and Polarization Transfer Between Adjacent and Remote Spins: 1H–13C CP MAS Kinetics in Glycine. <i>Journal of Physical Chemistry A</i>. 2018;122(45):8938–8947. doi:<a href=\"https://doi.org/10.1021/acs.jpca.8b09036\">10.1021/acs.jpca.8b09036</a>"},"year":"2018","volume":122,"author":[{"first_name":"Laurynas","full_name":"Dagys, Laurynas","last_name":"Dagys"},{"last_name":"Klimavicius","full_name":"Klimavicius, Vytautas","first_name":"Vytautas"},{"first_name":"Torsten","last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"},{"first_name":"Vytautas","last_name":"Balevicius","full_name":"Balevicius, Vytautas"}],"date_created":"2026-02-07T09:09:32Z","publisher":"American Chemical Society","date_updated":"2026-02-17T16:18:41Z","doi":"10.1021/acs.jpca.8b09036","title":"Quasi-Equilibria and Polarization Transfer Between Adjacent and Remote Spins: 1H–13C CP MAS Kinetics in Glycine"},{"status":"public","abstract":[{"text":"Synthesis of novel trityl-nitroxyl biradicals and their performance as polarization agents in DNP-enhanced solid-state MAS NMR spectroscopy is presented. Signal enhancements in H-1, H-1 -{\\textgreater} C-13 CP MAS, and C-13 MAS experiments obtained with these radicals dissolved in 1,1,2,2-tetrachloroethane (TCE) solution are compared with the enhancements obtained from TCE solutions of binitroxyl radicals. The signal enhancements are correlated with the distance between the radical centers of the biradicals, as determined by theoretical structure calculations. Some of the biradical TCE solutions display direct-channel resonances in C-13 MAS experiments as well as indirect channel resonances induced via the proton spin reservoir. Differential scanning calorimetry reveals that only these solutions do not form any solid crystalline phases upon rapid cooling, suggesting that molecular motions needed for polarization transfer from radicals to C-13 via the proton spin reservoir remain active at the experimental low temperatures of nominal 120 K. DNP magnetic field sweep enhancement profiles for selected new biradicals are presented as well. These indicate that the DNP transfer is dominated by the cross-effect mechanism.","lang":"eng"}],"type":"journal_article","publication":"Journal of Physical Chemistry C","extern":"1","language":[{"iso":"eng"}],"user_id":"100715","_id":"63926","citation":{"ieee":"S. Bothe <i>et al.</i>, “Novel Biradicals for Direct Excitation Highfield Dynamic Nuclear Polarization,” <i>Journal of Physical Chemistry C</i>, vol. 122, no. 21, pp. 11422–11432, 2018, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.8b02570\">10.1021/acs.jpcc.8b02570</a>.","chicago":"Bothe, S., J. Nowag, V. Klimavicius, M. Hoffmann, T. I. Troitskaya, E. V. Amosov, V. M. Tormyshev, et al. “Novel Biradicals for Direct Excitation Highfield Dynamic Nuclear Polarization.” <i>Journal of Physical Chemistry C</i> 122, no. 21 (2018): 11422–11432. <a href=\"https://doi.org/10.1021/acs.jpcc.8b02570\">https://doi.org/10.1021/acs.jpcc.8b02570</a>.","ama":"Bothe S, Nowag J, Klimavicius V, et al. Novel Biradicals for Direct Excitation Highfield Dynamic Nuclear Polarization. <i>Journal of Physical Chemistry C</i>. 2018;122(21):11422–11432. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.8b02570\">10.1021/acs.jpcc.8b02570</a>","mla":"Bothe, S., et al. “Novel Biradicals for Direct Excitation Highfield Dynamic Nuclear Polarization.” <i>Journal of Physical Chemistry C</i>, vol. 122, no. 21, 2018, pp. 11422–11432, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.8b02570\">10.1021/acs.jpcc.8b02570</a>.","short":"S. Bothe, J. Nowag, V. Klimavicius, M. Hoffmann, T.I. Troitskaya, E.V. Amosov, V.M. Tormyshev, I. Kirilyuk, A. Taratayko, A. Kuzhelev, D. Parkhomenko, E. Bagryanskaya, T. Gutmann, G. Buntkowsky, Journal of Physical Chemistry C 122 (2018) 11422–11432.","bibtex":"@article{Bothe_Nowag_Klimavicius_Hoffmann_Troitskaya_Amosov_Tormyshev_Kirilyuk_Taratayko_Kuzhelev_et al._2018, title={Novel Biradicals for Direct Excitation Highfield Dynamic Nuclear Polarization}, volume={122}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.8b02570\">10.1021/acs.jpcc.8b02570</a>}, number={21}, journal={Journal of Physical Chemistry C}, author={Bothe, S. and Nowag, J. and Klimavicius, V. and Hoffmann, M. and Troitskaya, T. I. and Amosov, E. V. and Tormyshev, V. M. and Kirilyuk, I. and Taratayko, A. and Kuzhelev, A. and et al.}, year={2018}, pages={11422–11432} }","apa":"Bothe, S., Nowag, J., Klimavicius, V., Hoffmann, M., Troitskaya, T. I., Amosov, E. V., Tormyshev, V. M., Kirilyuk, I., Taratayko, A., Kuzhelev, A., Parkhomenko, D., Bagryanskaya, E., Gutmann, T., &#38; Buntkowsky, G. (2018). Novel Biradicals for Direct Excitation Highfield Dynamic Nuclear Polarization. <i>Journal of Physical Chemistry C</i>, <i>122</i>(21), 11422–11432. <a href=\"https://doi.org/10.1021/acs.jpcc.8b02570\">https://doi.org/10.1021/acs.jpcc.8b02570</a>"},"intvolume":"       122","page":"11422–11432","year":"2018","issue":"21","publication_identifier":{"issn":["1932-7447"]},"doi":"10.1021/acs.jpcc.8b02570","title":"Novel Biradicals for Direct Excitation Highfield Dynamic Nuclear Polarization","date_created":"2026-02-07T08:59:17Z","author":[{"first_name":"S.","full_name":"Bothe, S.","last_name":"Bothe"},{"full_name":"Nowag, J.","last_name":"Nowag","first_name":"J."},{"first_name":"V.","last_name":"Klimavicius","full_name":"Klimavicius, V."},{"full_name":"Hoffmann, M.","last_name":"Hoffmann","first_name":"M."},{"last_name":"Troitskaya","full_name":"Troitskaya, T. I.","first_name":"T. I."},{"full_name":"Amosov, E. V.","last_name":"Amosov","first_name":"E. V."},{"last_name":"Tormyshev","full_name":"Tormyshev, V. M.","first_name":"V. M."},{"last_name":"Kirilyuk","full_name":"Kirilyuk, I.","first_name":"I."},{"first_name":"A.","full_name":"Taratayko, A.","last_name":"Taratayko"},{"full_name":"Kuzhelev, A.","last_name":"Kuzhelev","first_name":"A."},{"first_name":"D.","full_name":"Parkhomenko, D.","last_name":"Parkhomenko"},{"last_name":"Bagryanskaya","full_name":"Bagryanskaya, E.","first_name":"E."},{"first_name":"Torsten","last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165"},{"first_name":"G.","full_name":"Buntkowsky, G.","last_name":"Buntkowsky"}],"volume":122,"date_updated":"2026-02-17T16:19:13Z"},{"user_id":"100715","_id":"63928","extern":"1","language":[{"iso":"eng"}],"type":"journal_article","publication":"Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry & Chemical Physics","status":"public","abstract":[{"text":"A series of novel functionalized mesoporous silica-based materials with well-defined pore diameters, surface functionalization and surface morphology is synthesized by co-condensation or grafting techniques and characterized by solid-state NMR spectroscopy, DNP enhanced solid state-NMR and thermodynamic techniques. These materials are employed as host-systems for small-guest molecules like water, small alcohols, carbonic acids, small aromatic molecules, binary mixtures and others. The phase-behavior of these confined guests is studied by combinations of one dimensional solid-state NMR techniques (H-1 MAS, H-2-line shape analysis, C-13 CPMAS) and two-dimensional correlation experiments like H-1-Si-29- solid-state HETCOR.","lang":"eng"}],"date_created":"2026-02-07T09:00:34Z","author":[{"first_name":"M.","last_name":"Brodrecht","full_name":"Brodrecht, M."},{"full_name":"Kumari, B.","last_name":"Kumari","first_name":"B."},{"first_name":"H.","last_name":"Breitzke","full_name":"Breitzke, H."},{"first_name":"Torsten","full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann"},{"first_name":"G.","full_name":"Buntkowsky, G.","last_name":"Buntkowsky"}],"volume":232,"date_updated":"2026-02-17T16:19:09Z","doi":"10.1515/zpch-2017-1059","title":"Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions","issue":"7-8","publication_identifier":{"issn":["0942-9352"]},"citation":{"ieee":"M. Brodrecht, B. Kumari, H. Breitzke, T. Gutmann, and G. Buntkowsky, “Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions,” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, vol. 232, no. 7–8, pp. 1127–1146, 2018, doi: <a href=\"https://doi.org/10.1515/zpch-2017-1059\">10.1515/zpch-2017-1059</a>.","chicago":"Brodrecht, M., B. Kumari, H. Breitzke, Torsten Gutmann, and G. Buntkowsky. “Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions.” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i> 232, no. 7–8 (2018): 1127–1146. <a href=\"https://doi.org/10.1515/zpch-2017-1059\">https://doi.org/10.1515/zpch-2017-1059</a>.","ama":"Brodrecht M, Kumari B, Breitzke H, Gutmann T, Buntkowsky G. Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions. <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>. 2018;232(7-8):1127–1146. doi:<a href=\"https://doi.org/10.1515/zpch-2017-1059\">10.1515/zpch-2017-1059</a>","apa":"Brodrecht, M., Kumari, B., Breitzke, H., Gutmann, T., &#38; Buntkowsky, G. (2018). Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions. <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, <i>232</i>(7–8), 1127–1146. <a href=\"https://doi.org/10.1515/zpch-2017-1059\">https://doi.org/10.1515/zpch-2017-1059</a>","mla":"Brodrecht, M., et al. “Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions.” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, vol. 232, no. 7–8, 2018, pp. 1127–1146, doi:<a href=\"https://doi.org/10.1515/zpch-2017-1059\">10.1515/zpch-2017-1059</a>.","short":"M. Brodrecht, B. Kumari, H. Breitzke, T. Gutmann, G. Buntkowsky, Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics 232 (2018) 1127–1146.","bibtex":"@article{Brodrecht_Kumari_Breitzke_Gutmann_Buntkowsky_2018, title={Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions}, volume={232}, DOI={<a href=\"https://doi.org/10.1515/zpch-2017-1059\">10.1515/zpch-2017-1059</a>}, number={7–8}, journal={Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics}, author={Brodrecht, M. and Kumari, B. and Breitzke, H. and Gutmann, Torsten and Buntkowsky, G.}, year={2018}, pages={1127–1146} }"},"intvolume":"       232","page":"1127–1146","year":"2018"},{"type":"journal_article","publication":"Chemistry A European Journal","status":"public","_id":"63929","user_id":"100715","extern":"1","language":[{"iso":"eng"}],"issue":"67","year":"2018","citation":{"short":"M. Brodrecht, H. Breitzke, T. Gutmann, G. Buntkowsky, Chemistry A European Journal 24 (2018) 17814–17822.","mla":"Brodrecht, Martin, et al. “Biofunctionalization of Nano Channels by Direct In-Pore Solid-Phase Peptide Synthesis.” <i>Chemistry A European Journal</i>, vol. 24, no. 67, 2018, pp. 17814–17822, doi:<a href=\"https://doi.org/10.1002/chem.201804065\">10.1002/chem.201804065</a>.","bibtex":"@article{Brodrecht_Breitzke_Gutmann_Buntkowsky_2018, title={Biofunctionalization of Nano Channels by Direct In-Pore Solid-Phase Peptide Synthesis}, volume={24}, DOI={<a href=\"https://doi.org/10.1002/chem.201804065\">10.1002/chem.201804065</a>}, number={67}, journal={Chemistry A European Journal}, author={Brodrecht, Martin and Breitzke, Hergen and Gutmann, Torsten and Buntkowsky, Gerd}, year={2018}, pages={17814–17822} }","apa":"Brodrecht, M., Breitzke, H., Gutmann, T., &#38; Buntkowsky, G. (2018). Biofunctionalization of Nano Channels by Direct In-Pore Solid-Phase Peptide Synthesis. <i>Chemistry A European Journal</i>, <i>24</i>(67), 17814–17822. <a href=\"https://doi.org/10.1002/chem.201804065\">https://doi.org/10.1002/chem.201804065</a>","ama":"Brodrecht M, Breitzke H, Gutmann T, Buntkowsky G. Biofunctionalization of Nano Channels by Direct In-Pore Solid-Phase Peptide Synthesis. <i>Chemistry A European Journal</i>. 2018;24(67):17814–17822. doi:<a href=\"https://doi.org/10.1002/chem.201804065\">10.1002/chem.201804065</a>","ieee":"M. Brodrecht, H. Breitzke, T. Gutmann, and G. Buntkowsky, “Biofunctionalization of Nano Channels by Direct In-Pore Solid-Phase Peptide Synthesis,” <i>Chemistry A European Journal</i>, vol. 24, no. 67, pp. 17814–17822, 2018, doi: <a href=\"https://doi.org/10.1002/chem.201804065\">10.1002/chem.201804065</a>.","chicago":"Brodrecht, Martin, Hergen Breitzke, Torsten Gutmann, and Gerd Buntkowsky. “Biofunctionalization of Nano Channels by Direct In-Pore Solid-Phase Peptide Synthesis.” <i>Chemistry A European Journal</i> 24, no. 67 (2018): 17814–17822. <a href=\"https://doi.org/10.1002/chem.201804065\">https://doi.org/10.1002/chem.201804065</a>."},"page":"17814–17822","intvolume":"        24","date_updated":"2026-02-17T16:19:07Z","date_created":"2026-02-07T09:00:57Z","author":[{"last_name":"Brodrecht","full_name":"Brodrecht, Martin","first_name":"Martin"},{"full_name":"Breitzke, Hergen","last_name":"Breitzke","first_name":"Hergen"},{"first_name":"Torsten","id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann"},{"last_name":"Buntkowsky","full_name":"Buntkowsky, Gerd","first_name":"Gerd"}],"volume":24,"title":"Biofunctionalization of Nano Channels by Direct In-Pore Solid-Phase Peptide Synthesis","doi":"10.1002/chem.201804065"},{"page":"204–213","intvolume":"       266","citation":{"ieee":"M. M. Azim <i>et al.</i>, “Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type,” <i>Microporous and Mesoporous Materials</i>, vol. 266, pp. 204–213, 2018, doi: <a href=\"https://doi.org/10.1016/j.micromeso.2018.02.053\">10.1016/j.micromeso.2018.02.053</a>.","chicago":"Azim, Muhammad Mohsin, Alfonso Pensado, Barbara Kirchner, Torsten Gutmann, Pedro B. Groszewicz, Gerd Buntkowsky, and Annegret Stark. “Ionothermal Synthesis of Crystalline Microporous Aluminophosphates: Systematic Study on the Conditions Affecting the Framework Type.” <i>Microporous and Mesoporous Materials</i> 266 (2018): 204–213. <a href=\"https://doi.org/10.1016/j.micromeso.2018.02.053\">https://doi.org/10.1016/j.micromeso.2018.02.053</a>.","ama":"Azim MM, Pensado A, Kirchner B, et al. Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type. <i>Microporous and Mesoporous Materials</i>. 2018;266:204–213. doi:<a href=\"https://doi.org/10.1016/j.micromeso.2018.02.053\">10.1016/j.micromeso.2018.02.053</a>","apa":"Azim, M. M., Pensado, A., Kirchner, B., Gutmann, T., Groszewicz, P. B., Buntkowsky, G., &#38; Stark, A. (2018). Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type. <i>Microporous and Mesoporous Materials</i>, <i>266</i>, 204–213. <a href=\"https://doi.org/10.1016/j.micromeso.2018.02.053\">https://doi.org/10.1016/j.micromeso.2018.02.053</a>","short":"M.M. Azim, A. Pensado, B. Kirchner, T. Gutmann, P.B. Groszewicz, G. Buntkowsky, A. Stark, Microporous and Mesoporous Materials 266 (2018) 204–213.","mla":"Azim, Muhammad Mohsin, et al. “Ionothermal Synthesis of Crystalline Microporous Aluminophosphates: Systematic Study on the Conditions Affecting the Framework Type.” <i>Microporous and Mesoporous Materials</i>, vol. 266, 2018, pp. 204–213, doi:<a href=\"https://doi.org/10.1016/j.micromeso.2018.02.053\">10.1016/j.micromeso.2018.02.053</a>.","bibtex":"@article{Azim_Pensado_Kirchner_Gutmann_Groszewicz_Buntkowsky_Stark_2018, title={Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type}, volume={266}, DOI={<a href=\"https://doi.org/10.1016/j.micromeso.2018.02.053\">10.1016/j.micromeso.2018.02.053</a>}, journal={Microporous and Mesoporous Materials}, author={Azim, Muhammad Mohsin and Pensado, Alfonso and Kirchner, Barbara and Gutmann, Torsten and Groszewicz, Pedro B. and Buntkowsky, Gerd and Stark, Annegret}, year={2018}, pages={204–213} }"},"year":"2018","doi":"10.1016/j.micromeso.2018.02.053","title":"Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type","volume":266,"author":[{"first_name":"Muhammad Mohsin","full_name":"Azim, Muhammad Mohsin","last_name":"Azim"},{"last_name":"Pensado","full_name":"Pensado, Alfonso","first_name":"Alfonso"},{"first_name":"Barbara","full_name":"Kirchner, Barbara","last_name":"Kirchner"},{"last_name":"Gutmann","id":"118165","full_name":"Gutmann, Torsten","first_name":"Torsten"},{"first_name":"Pedro B.","full_name":"Groszewicz, Pedro B.","last_name":"Groszewicz"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"},{"first_name":"Annegret","full_name":"Stark, Annegret","last_name":"Stark"}],"date_created":"2026-02-07T08:58:23Z","date_updated":"2026-02-17T16:19:17Z","status":"public","abstract":[{"lang":"eng","text":"In a systematic study on the synthesis of aluminophosphates (AlPOs) under ionothermal conditions, initially using 1-butyl-3-methylimidazolium bromide ([C4mim]Br) as ionic liquid solvent and structure-directing agent, the effect of the reaction conditions (i.e. molar P/Al, F/Al and ionic liquid/Al ratios, alternative fluoride sources, influence of the ionic liquid’s cation or anion, temperature, reaction time) on the framework type was studied in detail. In [C4mim]Br, the formation of the more thermodynamically stable AEL framework type proceeds via AFI. The framework type can be changed by choosing another anion or cation of the ionic liquid. Hence, the successful ionothermal synthesis of the AFI framework AlPO is reported by using either N-ethylpyridinium bromide ([C2py]Br) or 1-butyl-3-methylimidazolium chloride ([C4mim]Cl). The mineraliser [Me4N]F, rather than HF, has been used for the first time as an alternative fluoride source in ionothermal synthesis, which can also affect the framework type. Hence, a very efficient synthesis of the LTA framework type is reported in [C4mim]Br using [Me4N]F. Ab initio molecular dynamics (AIMD) studies showed that the anion bridges between the aluminium atoms of the framework and the cation. The interaction is more favoured in the presence of the bromide than the chloride, which may be a clue to the question why the AEL framework is not formed in the chloride-based ionic liquid. This study opens several routes to pursue in the future as numerous ionic liquids are available which can be used in ionothermal synthesis."}],"publication":"Microporous and Mesoporous Materials","type":"journal_article","language":[{"iso":"eng"}],"extern":"1","keyword":["Aluminophosphates","Ionic liquids","Ionothermal synthesis","Microporous materials","Zeolite analogous"],"user_id":"100715","_id":"63924"},{"citation":{"bibtex":"@book{Gutmann_Buntkowsky_Webb_2017, place={Cham}, title={Modern Magnetic Resonance}, publisher={Springer International Publishing}, author={Gutmann, Torsten and Buntkowsky, Gerd and Webb, Graham}, year={2017} }","short":"T. Gutmann, G. Buntkowsky, G. Webb, Modern Magnetic Resonance, Springer International Publishing, Cham, 2017.","mla":"Gutmann, Torsten, et al. <i>Modern Magnetic Resonance</i>. Springer International Publishing, 2017.","apa":"Gutmann, T., Buntkowsky, G., &#38; Webb, G. (2017). <i>Modern Magnetic Resonance</i>. Springer International Publishing.","ama":"Gutmann T, Buntkowsky G, Webb G. <i>Modern Magnetic Resonance</i>. Springer International Publishing; 2017.","chicago":"Gutmann, Torsten, Gerd Buntkowsky, and Graham Webb. <i>Modern Magnetic Resonance</i>. Cham: Springer International Publishing, 2017.","ieee":"T. Gutmann, G. Buntkowsky, and G. Webb, <i>Modern Magnetic Resonance</i>. Cham: Springer International Publishing, 2017."},"year":"2017","place":"Cham","publication_identifier":{"isbn":["978-3-319-28275-6"]},"title":"Modern Magnetic Resonance","date_created":"2026-02-15T18:38:48Z","author":[{"first_name":"Torsten","last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165"},{"first_name":"Gerd","last_name":"Buntkowsky","full_name":"Buntkowsky, Gerd"},{"last_name":"Webb","full_name":"Webb, Graham","first_name":"Graham"}],"date_updated":"2026-02-17T16:12:34Z","publisher":"Springer International Publishing","status":"public","type":"book","language":[{"iso":"eng"}],"user_id":"100715","_id":"64156"},{"title":"Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing","doi":"10.3390/nano7110390","date_updated":"2026-02-17T16:12:54Z","date_created":"2026-02-07T16:15:23Z","author":[{"first_name":"S.","last_name":"Vowinkel","full_name":"Vowinkel, S."},{"last_name":"Paul","full_name":"Paul, S.","first_name":"S."},{"first_name":"Torsten","id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann"},{"first_name":"M.","full_name":"Gallei, M.","last_name":"Gallei"}],"volume":7,"year":"2017","citation":{"short":"S. Vowinkel, S. Paul, T. Gutmann, M. Gallei, Nanomaterials 7 (2017) 390.","bibtex":"@article{Vowinkel_Paul_Gutmann_Gallei_2017, title={Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing}, volume={7}, DOI={<a href=\"https://doi.org/10.3390/nano7110390\">10.3390/nano7110390</a>}, number={11}, journal={Nanomaterials}, author={Vowinkel, S. and Paul, S. and Gutmann, Torsten and Gallei, M.}, year={2017}, pages={390} }","mla":"Vowinkel, S., et al. “Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing.” <i>Nanomaterials</i>, vol. 7, no. 11, 2017, p. 390, doi:<a href=\"https://doi.org/10.3390/nano7110390\">10.3390/nano7110390</a>.","apa":"Vowinkel, S., Paul, S., Gutmann, T., &#38; Gallei, M. (2017). Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing. <i>Nanomaterials</i>, <i>7</i>(11), 390. <a href=\"https://doi.org/10.3390/nano7110390\">https://doi.org/10.3390/nano7110390</a>","chicago":"Vowinkel, S., S. Paul, Torsten Gutmann, and M. Gallei. “Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing.” <i>Nanomaterials</i> 7, no. 11 (2017): 390. <a href=\"https://doi.org/10.3390/nano7110390\">https://doi.org/10.3390/nano7110390</a>.","ieee":"S. Vowinkel, S. Paul, T. Gutmann, and M. Gallei, “Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing,” <i>Nanomaterials</i>, vol. 7, no. 11, p. 390, 2017, doi: <a href=\"https://doi.org/10.3390/nano7110390\">10.3390/nano7110390</a>.","ama":"Vowinkel S, Paul S, Gutmann T, Gallei M. Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing. <i>Nanomaterials</i>. 2017;7(11):390. doi:<a href=\"https://doi.org/10.3390/nano7110390\">10.3390/nano7110390</a>"},"intvolume":"         7","page":"390","publication_identifier":{"issn":["2079-4991"]},"issue":"11","keyword":["Materials Science","Science & Technology - Other Topics","solid-state nmr","spectroscopy","catalysts","colloidal crystals","colloids","cross-linking","elastomeric opal films","emulsion polymerization","gamma-methacryloxypropyltrimethoxysilane","hybrid films","melt-shear organization","nanoparticles","particle","photons","polymers","processing","self-assembly","transition"],"language":[{"iso":"eng"}],"extern":"1","_id":"64053","user_id":"100715","abstract":[{"lang":"eng","text":"The utilization and preparation of functional hybrid films for optical sensing applications and membranes is of utmost importance. In this work, we report the convenient and scalable preparation of self-crosslinking particle-based films derived by directed self-assembly of alkoxysilane-based cross-linkers as part of a core-shell particle architecture. The synthesis of well-designed monodisperse core-shell particles by emulsion polymerization is the basic prerequisite for subsequent particle processing via the melt-shear organization technique. In more detail, the core particles consist of polystyrene (PS) or poly(methyl methacrylate) (PMMA), while the comparably soft particle shell consists of poly(ethyl acrylate) (PEA) and different alkoxysilane-based poly(methacrylate)s. For hybrid film formation and convenient self-cross-linking, different alkyl groups at the siloxane moieties were investigated in detail by solid-state Magic-Angle Spinning Nuclear Magnetic Resonance (MAS, NMR) spectroscopy revealing different crosslinking capabilities, which strongly influence the properties of the core or shell particle films with respect to transparency and iridescent reflection colors. Furthermore, solid-state NMR spectroscopy and investigation of the thermal properties by differential scanning calorimetry (DSC) measurements allow for insights into the cross-linking capabilities prior to and after synthesis, as well as after the thermally and pressure-induced processing steps. Subsequently, free-standing and self-crosslinked particle-based films featuring excellent particle order are obtained by application of the melt-shear organization technique, as shown by microscopy (TEM, SEM)."}],"status":"public","type":"journal_article","publication":"Nanomaterials"},{"title":"Thermoreversible Self-Assembly of Perfluorinated Core-Coronas Cellulose-Nanoparticles in Dry State","doi":"10.1002/adma.201702473","date_updated":"2026-02-17T16:12:48Z","date_created":"2026-02-07T16:16:37Z","author":[{"last_name":"Wang","full_name":"Wang, Yonggui","first_name":"Yonggui"},{"first_name":"Pedro B.","full_name":"Groszewicz, Pedro B.","last_name":"Groszewicz"},{"full_name":"Rosenfeldt, Sabine","last_name":"Rosenfeldt","first_name":"Sabine"},{"first_name":"Hendrik","full_name":"Schmidt, Hendrik","last_name":"Schmidt"},{"first_name":"Cynthia A.","full_name":"Volkert, Cynthia A.","last_name":"Volkert"},{"full_name":"Vana, Philipp","last_name":"Vana","first_name":"Philipp"},{"first_name":"Torsten","last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165"},{"last_name":"Buntkowsky","full_name":"Buntkowsky, Gerd","first_name":"Gerd"},{"first_name":"Kai","full_name":"Zhang, Kai","last_name":"Zhang"}],"year":"2017","page":"1702473","citation":{"chicago":"Wang, Yonggui, Pedro B. Groszewicz, Sabine Rosenfeldt, Hendrik Schmidt, Cynthia A. Volkert, Philipp Vana, Torsten Gutmann, Gerd Buntkowsky, and Kai Zhang. “Thermoreversible Self-Assembly of Perfluorinated Core-Coronas Cellulose-Nanoparticles in Dry State.” <i>Advanced Materials</i>, 2017, 1702473. <a href=\"https://doi.org/10.1002/adma.201702473\">https://doi.org/10.1002/adma.201702473</a>.","ieee":"Y. Wang <i>et al.</i>, “Thermoreversible Self-Assembly of Perfluorinated Core-Coronas Cellulose-Nanoparticles in Dry State,” <i>Advanced Materials</i>, p. 1702473, 2017, doi: <a href=\"https://doi.org/10.1002/adma.201702473\">10.1002/adma.201702473</a>.","ama":"Wang Y, Groszewicz PB, Rosenfeldt S, et al. Thermoreversible Self-Assembly of Perfluorinated Core-Coronas Cellulose-Nanoparticles in Dry State. <i>Advanced Materials</i>. Published online 2017:1702473. doi:<a href=\"https://doi.org/10.1002/adma.201702473\">10.1002/adma.201702473</a>","mla":"Wang, Yonggui, et al. “Thermoreversible Self-Assembly of Perfluorinated Core-Coronas Cellulose-Nanoparticles in Dry State.” <i>Advanced Materials</i>, 2017, p. 1702473, doi:<a href=\"https://doi.org/10.1002/adma.201702473\">10.1002/adma.201702473</a>.","bibtex":"@article{Wang_Groszewicz_Rosenfeldt_Schmidt_Volkert_Vana_Gutmann_Buntkowsky_Zhang_2017, title={Thermoreversible Self-Assembly of Perfluorinated Core-Coronas Cellulose-Nanoparticles in Dry State}, DOI={<a href=\"https://doi.org/10.1002/adma.201702473\">10.1002/adma.201702473</a>}, journal={Advanced Materials}, author={Wang, Yonggui and Groszewicz, Pedro B. and Rosenfeldt, Sabine and Schmidt, Hendrik and Volkert, Cynthia A. and Vana, Philipp and Gutmann, Torsten and Buntkowsky, Gerd and Zhang, Kai}, year={2017}, pages={1702473} }","short":"Y. Wang, P.B. Groszewicz, S. Rosenfeldt, H. Schmidt, C.A. Volkert, P. Vana, T. Gutmann, G. Buntkowsky, K. Zhang, Advanced Materials (2017) 1702473.","apa":"Wang, Y., Groszewicz, P. B., Rosenfeldt, S., Schmidt, H., Volkert, C. A., Vana, P., Gutmann, T., Buntkowsky, G., &#38; Zhang, K. (2017). Thermoreversible Self-Assembly of Perfluorinated Core-Coronas Cellulose-Nanoparticles in Dry State. <i>Advanced Materials</i>, 1702473. <a href=\"https://doi.org/10.1002/adma.201702473\">https://doi.org/10.1002/adma.201702473</a>"},"keyword":["nanoparticles","self-assembly","cellulose","core-coronas structure","thermoreversible"],"language":[{"iso":"eng"}],"extern":"1","_id":"64057","user_id":"100715","abstract":[{"lang":"eng","text":"Self-assembly of nanoparticles (NPs) forming unique structures has been investigated extensively over the past few years. However, many self-assembled structures by NPs are irreversible, because they are generally constructed using their suspensions. It is still challenging for NPs to reversibly self-assemble in dry state, let alone of polymeric NPs with general sizes of hundreds of nm. Herein, this study reports a new reversible self-assembly phenomenon of NPs in dry state, forming thermoreversible strip-like supermolecular structures. These novel NPs of around 150 nm are perfluorinated surface-undecenoated cellulose nanoparticles (FSU-CNPs) with a core-coronas structure. The thermoreversible self-assembled structure is formed after drying in the air at the interface between FSU-CNP films and Teflon substrates. Remarkably, the formation and dissociation of this assembled structure are accompanied by a reversible conversion of the surface hydrophobicity, film transparency, and anisotropic properties. These findings show novel feasibility of reversible self-assembly of NPs in dry state, and thereby expand our knowledge of self-assembly phenomenon."}],"status":"public","publication":"Advanced Materials","type":"journal_article"},{"status":"public","type":"journal_article","publication":"Journal of Physical Chemistry C","extern":"1","language":[{"iso":"eng"}],"user_id":"100715","_id":"64048","citation":{"ama":"Thankamony ASL, Knoche S, Bothe S, et al. Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR. <i>Journal of Physical Chemistry C</i>. 2017;121(38):20857–20864. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.7b06761\">10.1021/acs.jpcc.7b06761</a>","chicago":"Thankamony, Aany S. L., Stefan Knoche, Sarah Bothe, Alfons Drochner, Anil P. Jagtap, Snorri Th Sigurdsson, Herbert Vogel, Bastian J. M. Etzold, Torsten Gutmann, and Gerd Buntkowsky. “Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR.” <i>Journal of Physical Chemistry C</i> 121, no. 38 (2017): 20857–20864. <a href=\"https://doi.org/10.1021/acs.jpcc.7b06761\">https://doi.org/10.1021/acs.jpcc.7b06761</a>.","ieee":"A. S. L. Thankamony <i>et al.</i>, “Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR,” <i>Journal of Physical Chemistry C</i>, vol. 121, no. 38, pp. 20857–20864, 2017, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.7b06761\">10.1021/acs.jpcc.7b06761</a>.","apa":"Thankamony, A. S. L., Knoche, S., Bothe, S., Drochner, A., Jagtap, A. P., Sigurdsson, S. T., Vogel, H., Etzold, B. J. M., Gutmann, T., &#38; Buntkowsky, G. (2017). Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR. <i>Journal of Physical Chemistry C</i>, <i>121</i>(38), 20857–20864. <a href=\"https://doi.org/10.1021/acs.jpcc.7b06761\">https://doi.org/10.1021/acs.jpcc.7b06761</a>","short":"A.S.L. Thankamony, S. Knoche, S. Bothe, A. Drochner, A.P. Jagtap, S.T. Sigurdsson, H. Vogel, B.J.M. Etzold, T. Gutmann, G. Buntkowsky, Journal of Physical Chemistry C 121 (2017) 20857–20864.","mla":"Thankamony, Aany S. L., et al. “Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR.” <i>Journal of Physical Chemistry C</i>, vol. 121, no. 38, American Chemical Society, 2017, pp. 20857–20864, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.7b06761\">10.1021/acs.jpcc.7b06761</a>.","bibtex":"@article{Thankamony_Knoche_Bothe_Drochner_Jagtap_Sigurdsson_Vogel_Etzold_Gutmann_Buntkowsky_2017, title={Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR}, volume={121}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.7b06761\">10.1021/acs.jpcc.7b06761</a>}, number={38}, journal={Journal of Physical Chemistry C}, publisher={American Chemical Society}, author={Thankamony, Aany S. L. and Knoche, Stefan and Bothe, Sarah and Drochner, Alfons and Jagtap, Anil P. and Sigurdsson, Snorri Th and Vogel, Herbert and Etzold, Bastian J. M. and Gutmann, Torsten and Buntkowsky, Gerd}, year={2017}, pages={20857–20864} }"},"intvolume":"       121","page":"20857–20864","year":"2017","issue":"38","publication_identifier":{"issn":["1932-7447"]},"doi":"10.1021/acs.jpcc.7b06761","title":"Characterization of V–Mo–W Mixed Oxide Catalyst Surface Species by 51V Solid-State Dynamic Nuclear Polarization NMR","author":[{"full_name":"Thankamony, Aany S. L.","last_name":"Thankamony","first_name":"Aany S. L."},{"last_name":"Knoche","full_name":"Knoche, Stefan","first_name":"Stefan"},{"first_name":"Sarah","last_name":"Bothe","full_name":"Bothe, Sarah"},{"first_name":"Alfons","last_name":"Drochner","full_name":"Drochner, Alfons"},{"full_name":"Jagtap, Anil P.","last_name":"Jagtap","first_name":"Anil P."},{"full_name":"Sigurdsson, Snorri Th","last_name":"Sigurdsson","first_name":"Snorri Th"},{"last_name":"Vogel","full_name":"Vogel, Herbert","first_name":"Herbert"},{"full_name":"Etzold, Bastian J. M.","last_name":"Etzold","first_name":"Bastian J. M."},{"first_name":"Torsten","last_name":"Gutmann","id":"118165","full_name":"Gutmann, Torsten"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"}],"date_created":"2026-02-07T16:13:02Z","volume":121,"publisher":"American Chemical Society","date_updated":"2026-02-17T16:13:04Z"},{"_id":"64012","user_id":"100715","language":[{"iso":"eng"}],"extern":"1","publication":"Journal of Physical Chemistry C","type":"journal_article","status":"public","date_updated":"2026-02-17T16:15:18Z","publisher":"American Chemical Society","volume":121,"author":[{"first_name":"Jiquan","last_name":"Liu","full_name":"Liu, Jiquan"},{"last_name":"Groszewicz","full_name":"Groszewicz, Pedro B.","first_name":"Pedro B."},{"first_name":"Qingbo","full_name":"Wen, Qingbo","last_name":"Wen"},{"first_name":"Aany Sofia Lilly","last_name":"Thankamony","full_name":"Thankamony, Aany Sofia Lilly"},{"first_name":"Bin","full_name":"Zhang, Bin","last_name":"Zhang"},{"first_name":"Ulrike","last_name":"Kunz","full_name":"Kunz, Ulrike"},{"first_name":"Grit","last_name":"Sauer","full_name":"Sauer, Grit"},{"full_name":"Xu, Yeping","last_name":"Xu","first_name":"Yeping"},{"id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann","first_name":"Torsten"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"}],"date_created":"2026-02-07T15:59:06Z","title":"Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid-State NMR Techniques","doi":"10.1021/acs.jpcc.7b06807","publication_identifier":{"issn":["1932-7447"]},"issue":"32","year":"2017","intvolume":"       121","page":"17409–17416","citation":{"apa":"Liu, J., Groszewicz, P. B., Wen, Q., Thankamony, A. S. L., Zhang, B., Kunz, U., Sauer, G., Xu, Y., Gutmann, T., &#38; Buntkowsky, G. (2017). Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid-State NMR Techniques. <i>Journal of Physical Chemistry C</i>, <i>121</i>(32), 17409–17416. <a href=\"https://doi.org/10.1021/acs.jpcc.7b06807\">https://doi.org/10.1021/acs.jpcc.7b06807</a>","short":"J. Liu, P.B. Groszewicz, Q. Wen, A.S.L. Thankamony, B. Zhang, U. Kunz, G. Sauer, Y. Xu, T. Gutmann, G. Buntkowsky, Journal of Physical Chemistry C 121 (2017) 17409–17416.","bibtex":"@article{Liu_Groszewicz_Wen_Thankamony_Zhang_Kunz_Sauer_Xu_Gutmann_Buntkowsky_2017, title={Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid-State NMR Techniques}, volume={121}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.7b06807\">10.1021/acs.jpcc.7b06807</a>}, number={32}, journal={Journal of Physical Chemistry C}, publisher={American Chemical Society}, author={Liu, Jiquan and Groszewicz, Pedro B. and Wen, Qingbo and Thankamony, Aany Sofia Lilly and Zhang, Bin and Kunz, Ulrike and Sauer, Grit and Xu, Yeping and Gutmann, Torsten and Buntkowsky, Gerd}, year={2017}, pages={17409–17416} }","mla":"Liu, Jiquan, et al. “Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid-State NMR Techniques.” <i>Journal of Physical Chemistry C</i>, vol. 121, no. 32, American Chemical Society, 2017, pp. 17409–17416, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.7b06807\">10.1021/acs.jpcc.7b06807</a>.","ieee":"J. Liu <i>et al.</i>, “Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid-State NMR Techniques,” <i>Journal of Physical Chemistry C</i>, vol. 121, no. 32, pp. 17409–17416, 2017, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.7b06807\">10.1021/acs.jpcc.7b06807</a>.","chicago":"Liu, Jiquan, Pedro B. Groszewicz, Qingbo Wen, Aany Sofia Lilly Thankamony, Bin Zhang, Ulrike Kunz, Grit Sauer, Yeping Xu, Torsten Gutmann, and Gerd Buntkowsky. “Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid-State NMR Techniques.” <i>Journal of Physical Chemistry C</i> 121, no. 32 (2017): 17409–17416. <a href=\"https://doi.org/10.1021/acs.jpcc.7b06807\">https://doi.org/10.1021/acs.jpcc.7b06807</a>.","ama":"Liu J, Groszewicz PB, Wen Q, et al. Revealing Structure Reactivity Relationships in Heterogenized Dirhodium Catalysts by Solid-State NMR Techniques. <i>Journal of Physical Chemistry C</i>. 2017;121(32):17409–17416. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.7b06807\">10.1021/acs.jpcc.7b06807</a>"}},{"citation":{"apa":"Hoffmann, M. M., Bothe, S., Gutmann, T., Hartmann, F.-F., Reggelin, M., &#38; Buntkowsky, G. (2017). Directly vs Indirectly Enhanced 13C in Dynamic Nuclear Polarization Magic Angle Spinning NMR Experiments of Nonionic Surfactant Systems. <i>Journal of Physical Chemistry C</i>, <i>121</i>(4), 2418–2427. <a href=\"https://doi.org/10.1021/acs.jpcc.6b13087\">https://doi.org/10.1021/acs.jpcc.6b13087</a>","bibtex":"@article{Hoffmann_Bothe_Gutmann_Hartmann_Reggelin_Buntkowsky_2017, title={Directly vs Indirectly Enhanced 13C in Dynamic Nuclear Polarization Magic Angle Spinning NMR Experiments of Nonionic Surfactant Systems}, volume={121}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.6b13087\">10.1021/acs.jpcc.6b13087</a>}, number={4}, journal={Journal of Physical Chemistry C}, publisher={American Chemical Society}, author={Hoffmann, Markus M. and Bothe, Sarah and Gutmann, Torsten and Hartmann, Frank-Frederik and Reggelin, Michael and Buntkowsky, Gerd}, year={2017}, pages={2418–2427} }","short":"M.M. Hoffmann, S. Bothe, T. Gutmann, F.-F. Hartmann, M. Reggelin, G. Buntkowsky, Journal of Physical Chemistry C 121 (2017) 2418–2427.","mla":"Hoffmann, Markus M., et al. “Directly vs Indirectly Enhanced 13C in Dynamic Nuclear Polarization Magic Angle Spinning NMR Experiments of Nonionic Surfactant Systems.” <i>Journal of Physical Chemistry C</i>, vol. 121, no. 4, American Chemical Society, 2017, pp. 2418–2427, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.6b13087\">10.1021/acs.jpcc.6b13087</a>.","ama":"Hoffmann MM, Bothe S, Gutmann T, Hartmann F-F, Reggelin M, Buntkowsky G. Directly vs Indirectly Enhanced 13C in Dynamic Nuclear Polarization Magic Angle Spinning NMR Experiments of Nonionic Surfactant Systems. <i>Journal of Physical Chemistry C</i>. 2017;121(4):2418–2427. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.6b13087\">10.1021/acs.jpcc.6b13087</a>","chicago":"Hoffmann, Markus M., Sarah Bothe, Torsten Gutmann, Frank-Frederik Hartmann, Michael Reggelin, and Gerd Buntkowsky. “Directly vs Indirectly Enhanced 13C in Dynamic Nuclear Polarization Magic Angle Spinning NMR Experiments of Nonionic Surfactant Systems.” <i>Journal of Physical Chemistry C</i> 121, no. 4 (2017): 2418–2427. <a href=\"https://doi.org/10.1021/acs.jpcc.6b13087\">https://doi.org/10.1021/acs.jpcc.6b13087</a>.","ieee":"M. M. Hoffmann, S. Bothe, T. Gutmann, F.-F. Hartmann, M. Reggelin, and G. Buntkowsky, “Directly vs Indirectly Enhanced 13C in Dynamic Nuclear Polarization Magic Angle Spinning NMR Experiments of Nonionic Surfactant Systems,” <i>Journal of Physical Chemistry C</i>, vol. 121, no. 4, pp. 2418–2427, 2017, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.6b13087\">10.1021/acs.jpcc.6b13087</a>."},"page":"2418–2427","intvolume":"       121","year":"2017","issue":"4","publication_identifier":{"issn":["1932-7447"]},"doi":"10.1021/acs.jpcc.6b13087","title":"Directly vs Indirectly Enhanced 13C in Dynamic Nuclear Polarization Magic Angle Spinning NMR Experiments of Nonionic Surfactant Systems","date_created":"2026-02-07T15:43:37Z","author":[{"first_name":"Markus M.","last_name":"Hoffmann","full_name":"Hoffmann, Markus M."},{"first_name":"Sarah","full_name":"Bothe, Sarah","last_name":"Bothe"},{"first_name":"Torsten","id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann"},{"first_name":"Frank-Frederik","full_name":"Hartmann, Frank-Frederik","last_name":"Hartmann"},{"full_name":"Reggelin, Michael","last_name":"Reggelin","first_name":"Michael"},{"first_name":"Gerd","last_name":"Buntkowsky","full_name":"Buntkowsky, Gerd"}],"volume":121,"date_updated":"2026-02-17T16:17:02Z","publisher":"American Chemical Society","status":"public","type":"journal_article","publication":"Journal of Physical Chemistry C","language":[{"iso":"eng"}],"extern":"1","user_id":"100715","_id":"63979"},{"publication_identifier":{"issn":["1932-7447"]},"issue":"41","year":"2017","page":"22948–22957","intvolume":"       121","citation":{"ama":"Hoffmann MM, Bothe S, Gutmann T, Buntkowsky G. Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy. <i>Journal of Physical Chemistry C</i>. 2017;121(41):22948–22957. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.7b07965\">10.1021/acs.jpcc.7b07965</a>","ieee":"M. M. Hoffmann, S. Bothe, T. Gutmann, and G. Buntkowsky, “Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy,” <i>Journal of Physical Chemistry C</i>, vol. 121, no. 41, pp. 22948–22957, 2017, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.7b07965\">10.1021/acs.jpcc.7b07965</a>.","chicago":"Hoffmann, Markus M., Sarah Bothe, Torsten Gutmann, and Gerd Buntkowsky. “Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy.” <i>Journal of Physical Chemistry C</i> 121, no. 41 (2017): 22948–22957. <a href=\"https://doi.org/10.1021/acs.jpcc.7b07965\">https://doi.org/10.1021/acs.jpcc.7b07965</a>.","apa":"Hoffmann, M. M., Bothe, S., Gutmann, T., &#38; Buntkowsky, G. (2017). Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy. <i>Journal of Physical Chemistry C</i>, <i>121</i>(41), 22948–22957. <a href=\"https://doi.org/10.1021/acs.jpcc.7b07965\">https://doi.org/10.1021/acs.jpcc.7b07965</a>","short":"M.M. Hoffmann, S. Bothe, T. Gutmann, G. Buntkowsky, Journal of Physical Chemistry C 121 (2017) 22948–22957.","bibtex":"@article{Hoffmann_Bothe_Gutmann_Buntkowsky_2017, title={Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy}, volume={121}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.7b07965\">10.1021/acs.jpcc.7b07965</a>}, number={41}, journal={Journal of Physical Chemistry C}, publisher={American Chemical Society}, author={Hoffmann, Markus M. and Bothe, Sarah and Gutmann, Torsten and Buntkowsky, Gerd}, year={2017}, pages={22948–22957} }","mla":"Hoffmann, Markus M., et al. “Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy.” <i>Journal of Physical Chemistry C</i>, vol. 121, no. 41, American Chemical Society, 2017, pp. 22948–22957, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.7b07965\">10.1021/acs.jpcc.7b07965</a>."},"date_updated":"2026-02-17T16:17:13Z","publisher":"American Chemical Society","volume":121,"date_created":"2026-02-07T15:42:53Z","author":[{"last_name":"Hoffmann","full_name":"Hoffmann, Markus M.","first_name":"Markus M."},{"first_name":"Sarah","full_name":"Bothe, Sarah","last_name":"Bothe"},{"full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann","first_name":"Torsten"},{"full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky","first_name":"Gerd"}],"title":"Unusual Local Molecular Motions in the Solid State Detected by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy","doi":"10.1021/acs.jpcc.7b07965","publication":"Journal of Physical Chemistry C","type":"journal_article","status":"public","_id":"63977","user_id":"100715","language":[{"iso":"eng"}],"extern":"1"}]