---
_id: '26009'
abstract:
- lang: eng
  text: Lamellar mesostructured aluminophosphates were synthesized from aluminum triisopropoxide
    and phosphoric acid; monododecyl phosphate surfactant was used as structure-directing
    template. Depending on the relative Al/P ratio in the samples, variable relative
    amounts of tetrahedrally and octahedrally coordinated Al are found, indicating
    that both aluminophosphate and aluminum oxide species (as thermodynamically favored)
    are being formed in the syntheses. This is investigated quantitatively by Al K-edge
    XANES spectroscopy. The same syntheses were carried out without phosphoric acid,
    resulting in similar lamellar structures. The inorganic lamellae of these products
    consist to a significant extent of aluminophosphate rather than exclusively of
    aluminum oxide, which means that the phosphate headgroups of the surfactant molecules
    become incorporated into the inorganic network. Thus, for the first time, the
    surfactant serves as both template and reactant.
article_type: original
author:
- first_name: Michael
  full_name: Fröba, Michael
  last_name: Fröba
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: Fröba M, Tiemann M. A New Role of the Surfactant in the Synthesis of Mesostructured
    Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates. <i>Chemistry
    of Materials</i>. Published online 1998:3475-3483. doi:<a href="https://doi.org/10.1021/cm980712c">10.1021/cm980712c</a>
  apa: Fröba, M., &#38; Tiemann, M. (1998). A New Role of the Surfactant in the Synthesis
    of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates.
    <i>Chemistry of Materials</i>, 3475–3483. <a href="https://doi.org/10.1021/cm980712c">https://doi.org/10.1021/cm980712c</a>
  bibtex: '@article{Fröba_Tiemann_1998, title={A New Role of the Surfactant in the
    Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant
    for Aluminophosphates}, DOI={<a href="https://doi.org/10.1021/cm980712c">10.1021/cm980712c</a>},
    journal={Chemistry of Materials}, author={Fröba, Michael and Tiemann, Michael},
    year={1998}, pages={3475–3483} }'
  chicago: Fröba, Michael, and Michael Tiemann. “A New Role of the Surfactant in the
    Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant
    for Aluminophosphates.” <i>Chemistry of Materials</i>, 1998, 3475–83. <a href="https://doi.org/10.1021/cm980712c">https://doi.org/10.1021/cm980712c</a>.
  ieee: 'M. Fröba and M. Tiemann, “A New Role of the Surfactant in the Synthesis of
    Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates,”
    <i>Chemistry of Materials</i>, pp. 3475–3483, 1998, doi: <a href="https://doi.org/10.1021/cm980712c">10.1021/cm980712c</a>.'
  mla: Fröba, Michael, and Michael Tiemann. “A New Role of the Surfactant in the Synthesis
    of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates.”
    <i>Chemistry of Materials</i>, 1998, pp. 3475–83, doi:<a href="https://doi.org/10.1021/cm980712c">10.1021/cm980712c</a>.
  short: M. Fröba, M. Tiemann, Chemistry of Materials (1998) 3475–3483.
date_created: 2021-10-09T10:14:44Z
date_updated: 2023-03-09T09:07:28Z
department:
- _id: '35'
- _id: '163'
- _id: '307'
doi: 10.1021/cm980712c
extern: '1'
language:
- iso: eng
page: 3475-3483
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
quality_controlled: '1'
status: public
title: A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl
  Phosphate as Template and Reactant for Aluminophosphates
type: journal_article
user_id: '23547'
year: '1998'
...