[{"keyword":["Catalysis"],"language":[{"iso":"eng"}],"publication":"Catalysts","abstract":[{"lang":"eng","text":"This work presents a new and facile route for the preparation of iron oxide-based catalysts supported on alumina, which enables the targeted synthesis of catalysts with an increased amount of isolated tetrahedrally coordinated iron centers compared to a conventional impregnation procedure, and therefore leads to an increase in activity for CO oxidation reaction. By a multi-step impregnation–calcination protocol, the catalysts were synthesized with iron loadings of between 1 and 10 wt%, and their catalytic activity was then compared with a 10 wt% loaded catalyst prepared by conventional single impregnation. With a loading of 8 wt%, the presented catalysts showed an improved catalytic activity regarding light-off and full conversion temperatures compared to this reference. Through the application of several analytical methods (PXRD, PDF, DRUVS, SEM, XAFS), the improved catalytic activity can be correlated with an increased amount of isolated iron centers and a significantly reduced fraction of agglomerates or particles."}],"publisher":"MDPI AG","date_created":"2024-07-02T07:10:14Z","title":"New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation","issue":"7","year":"2024","_id":"54969","department":[{"_id":"306"}],"user_id":"48467","article_number":"416","article_type":"original","type":"journal_article","status":"public","date_updated":"2025-08-15T12:50:52Z","volume":14,"author":[{"first_name":"Steffen","full_name":"Schlicher, Steffen","last_name":"Schlicher"},{"orcid":"0000-0003-2061-7289","last_name":"Schoch","full_name":"Schoch, Roland","id":"48467","first_name":"Roland"},{"last_name":"Prinz","full_name":"Prinz, Nils","first_name":"Nils"},{"first_name":"Mirijam","last_name":"Zobel","full_name":"Zobel, Mirijam"},{"id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","first_name":"Matthias"}],"doi":"10.3390/catal14070416","publication_identifier":{"issn":["2073-4344"]},"publication_status":"published","intvolume":" 14","citation":{"apa":"Schlicher, S., Schoch, R., Prinz, N., Zobel, M., & Bauer, M. (2024). New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation. Catalysts, 14(7), Article 416. https://doi.org/10.3390/catal14070416","ama":"Schlicher S, Schoch R, Prinz N, Zobel M, Bauer M. New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation. Catalysts. 2024;14(7). doi:10.3390/catal14070416","mla":"Schlicher, Steffen, et al. “New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation.” Catalysts, vol. 14, no. 7, 416, MDPI AG, 2024, doi:10.3390/catal14070416.","short":"S. Schlicher, R. Schoch, N. Prinz, M. Zobel, M. Bauer, Catalysts 14 (2024).","bibtex":"@article{Schlicher_Schoch_Prinz_Zobel_Bauer_2024, title={New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation}, volume={14}, DOI={10.3390/catal14070416}, number={7416}, journal={Catalysts}, publisher={MDPI AG}, author={Schlicher, Steffen and Schoch, Roland and Prinz, Nils and Zobel, Mirijam and Bauer, Matthias}, year={2024} }","ieee":"S. Schlicher, R. Schoch, N. Prinz, M. Zobel, and M. Bauer, “New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation,” Catalysts, vol. 14, no. 7, Art. no. 416, 2024, doi: 10.3390/catal14070416.","chicago":"Schlicher, Steffen, Roland Schoch, Nils Prinz, Mirijam Zobel, and Matthias Bauer. “New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation.” Catalysts 14, no. 7 (2024). https://doi.org/10.3390/catal14070416."}},{"keyword":["Catalysis","General Chemistry","pc2-ressources","Computing Resources Provided by the Paderborn Center for Parallel Computing"],"language":[{"iso":"eng"}],"_id":"46547","user_id":"44418","status":"public","publication":"ACS Catalysis","type":"journal_article","title":"Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions","doi":"10.1021/acscatal.3c02092","publisher":"American Chemical Society (ACS)","date_updated":"2024-03-07T09:34:41Z","volume":13,"date_created":"2023-08-16T14:44:11Z","author":[{"first_name":"Andrea","last_name":"Rogolino","full_name":"Rogolino, Andrea"},{"last_name":"Filho","full_name":"Filho, José B. G.","first_name":"José B. G."},{"first_name":"Lorena","id":"44418","full_name":"Fritsch, Lorena","last_name":"Fritsch"},{"full_name":"Ardisson, José D.","last_name":"Ardisson","first_name":"José D."},{"full_name":"da Silva, Marcos A. R.","last_name":"da Silva","first_name":"Marcos A. R."},{"last_name":"Atta Diab","full_name":"Atta Diab, Gabriel Ali","first_name":"Gabriel Ali"},{"full_name":"Silva, Ingrid Fernandes","last_name":"Silva","first_name":"Ingrid Fernandes"},{"first_name":"Carlos André Ferreira","full_name":"Moraes, Carlos André Ferreira","last_name":"Moraes"},{"first_name":"Moacir Rossi","full_name":"Forim, Moacir Rossi","last_name":"Forim"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"last_name":"Kühne","full_name":"Kühne, Thomas D.","first_name":"Thomas D."},{"full_name":"Antonietti, Markus","last_name":"Antonietti","first_name":"Markus"},{"last_name":"Teixeira","full_name":"Teixeira, Ivo F.","first_name":"Ivo F."}],"year":"2023","page":"8662-8669","intvolume":" 13","citation":{"mla":"Rogolino, Andrea, et al. “Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions.” ACS Catalysis, vol. 13, no. 13, American Chemical Society (ACS), 2023, pp. 8662–69, doi:10.1021/acscatal.3c02092.","short":"A. Rogolino, J.B.G. Filho, L. Fritsch, J.D. Ardisson, M.A.R. da Silva, G.A. Atta Diab, I.F. Silva, C.A.F. Moraes, M.R. Forim, M. Bauer, T.D. Kühne, M. Antonietti, I.F. Teixeira, ACS Catalysis 13 (2023) 8662–8669.","bibtex":"@article{Rogolino_Filho_Fritsch_Ardisson_da Silva_Atta Diab_Silva_Moraes_Forim_Bauer_et al._2023, title={Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions}, volume={13}, DOI={10.1021/acscatal.3c02092}, number={13}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Rogolino, Andrea and Filho, José B. G. and Fritsch, Lorena and Ardisson, José D. and da Silva, Marcos A. R. and Atta Diab, Gabriel Ali and Silva, Ingrid Fernandes and Moraes, Carlos André Ferreira and Forim, Moacir Rossi and Bauer, Matthias and et al.}, year={2023}, pages={8662–8669} }","apa":"Rogolino, A., Filho, J. B. G., Fritsch, L., Ardisson, J. D., da Silva, M. A. R., Atta Diab, G. A., Silva, I. F., Moraes, C. A. F., Forim, M. R., Bauer, M., Kühne, T. D., Antonietti, M., & Teixeira, I. F. (2023). Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions. ACS Catalysis, 13(13), 8662–8669. https://doi.org/10.1021/acscatal.3c02092","ama":"Rogolino A, Filho JBG, Fritsch L, et al. Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions. ACS Catalysis. 2023;13(13):8662-8669. doi:10.1021/acscatal.3c02092","ieee":"A. Rogolino et al., “Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions,” ACS Catalysis, vol. 13, no. 13, pp. 8662–8669, 2023, doi: 10.1021/acscatal.3c02092.","chicago":"Rogolino, Andrea, José B. G. Filho, Lorena Fritsch, José D. Ardisson, Marcos A. R. da Silva, Gabriel Ali Atta Diab, Ingrid Fernandes Silva, et al. “Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions.” ACS Catalysis 13, no. 13 (2023): 8662–69. https://doi.org/10.1021/acscatal.3c02092."},"publication_identifier":{"issn":["2155-5435","2155-5435"]},"publication_status":"published","issue":"13"},{"status":"public","abstract":[{"lang":"eng","text":"Macrocyclization reactions are still challenging due to competing oligomerization, which requires the use of small substrate concentrations. Here, the cationic tungsten imido and tungsten oxo alkylidene N-heterocyclic carbene complexes [[W(N-2,6-Cl2-C6H3)(CHCMe2Ph(OC6F5)(pivalonitrile)(IMes)+ B(ArF)4−] (W1) and [W(O)(CHCMe2Ph(OCMe(CF3)2)(IMes)(CH3CN)+ B(ArF)4−] (W2) (IMes=1,3-dimesitylimidazol-2-ylidene; B(ArF)4−=tetrakis(3,5-bis(trifluoromethyl)phenyl borate) have been immobilized inside the pores of ordered mesoporous silica (OMS) with pore diameters of 3.3 and 6.8 nm, respectively, using a pore-selective immobilization protocol. X-ray absorption spectroscopy of W1@OMS showed that even though the catalyst structure is contracted due to confinement by the mesopores, both the oxidation state and structure of the catalyst stayed intact upon immobilization. Catalytic testing with four differently sized α,ω-dienes revealed a dramatically increased macrocyclization (MC) and Z-selectivity of the supported catalysts compared to the homogenous progenitors, allowing high substrate concentrations of 25 mM. With the supported complexes, a maximum increase in MC-selectivity from 27 to 81 % and in Z-selectivity from 17 to 34 % was achieved. In general, smaller mesopores exhibited a stronger confinement effect. A comparison of the two supported tungsten-based catalysts showed that W1@OMS possesses a higher MC-selectivity, while W2@OMS exhibits a higher Z-selectivity which can be rationalized by the structures of the catalysts."}],"publication":"ChemCatChem","type":"journal_article","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"article_type":"original","department":[{"_id":"306"}],"user_id":"48467","_id":"52344","intvolume":" 15","citation":{"apa":"Ziegler, F., Bruckner, J. R., Nowakowski, M., Bauer, M., Probst, P., Atwi, B., & Buchmeiser, M. R. (2023). Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes. ChemCatChem, 15(21). https://doi.org/10.1002/cctc.202300871","bibtex":"@article{Ziegler_Bruckner_Nowakowski_Bauer_Probst_Atwi_Buchmeiser_2023, title={Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes}, volume={15}, DOI={10.1002/cctc.202300871}, number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Ziegler, Felix and Bruckner, Johanna R. and Nowakowski, Michał and Bauer, Matthias and Probst, Patrick and Atwi, Boshra and Buchmeiser, Michael R.}, year={2023} }","short":"F. Ziegler, J.R. Bruckner, M. Nowakowski, M. Bauer, P. Probst, B. Atwi, M.R. Buchmeiser, ChemCatChem 15 (2023).","mla":"Ziegler, Felix, et al. “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes.” ChemCatChem, vol. 15, no. 21, Wiley, 2023, doi:10.1002/cctc.202300871.","ieee":"F. Ziegler et al., “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes,” ChemCatChem, vol. 15, no. 21, 2023, doi: 10.1002/cctc.202300871.","chicago":"Ziegler, Felix, Johanna R. Bruckner, Michał Nowakowski, Matthias Bauer, Patrick Probst, Boshra Atwi, and Michael R. Buchmeiser. “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes.” ChemCatChem 15, no. 21 (2023). https://doi.org/10.1002/cctc.202300871.","ama":"Ziegler F, Bruckner JR, Nowakowski M, et al. Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes. ChemCatChem. 2023;15(21). doi:10.1002/cctc.202300871"},"year":"2023","issue":"21","publication_identifier":{"issn":["1867-3880","1867-3899"]},"publication_status":"published","doi":"10.1002/cctc.202300871","title":"Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes","volume":15,"date_created":"2024-03-07T09:44:33Z","author":[{"first_name":"Felix","last_name":"Ziegler","full_name":"Ziegler, Felix"},{"full_name":"Bruckner, Johanna R.","last_name":"Bruckner","first_name":"Johanna R."},{"first_name":"Michał","id":"78878","full_name":"Nowakowski, Michał","orcid":"0000-0002-3734-7011","last_name":"Nowakowski"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"first_name":"Patrick","last_name":"Probst","full_name":"Probst, Patrick"},{"last_name":"Atwi","full_name":"Atwi, Boshra","first_name":"Boshra"},{"last_name":"Buchmeiser","full_name":"Buchmeiser, Michael R.","first_name":"Michael R."}],"date_updated":"2024-05-07T11:41:51Z","publisher":"Wiley"},{"issue":"12","year":"2023","publisher":"Royal Society of Chemistry (RSC)","date_created":"2024-03-07T09:12:06Z","title":"Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis","publication":"Catalysis Science Technology","abstract":[{"lang":"eng","text":"Improved enantioselectivity in the 1,2-addition was observed for chiral Rh norbornadiene catalysts immobilized on ordered mesoporous silica with small pores. Confinement effects were rationalized by experimental and computational studies."}],"keyword":["Catalysis"],"language":[{"iso":"eng"}],"publication_status":"published","publication_identifier":{"issn":["2044-4753","2044-4761"]},"citation":{"ama":"Kirchhof M, Gugeler K, Beurer A-K, et al. Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. Catalysis Science Technology. 2023;13(12):3709-3724. doi:10.1039/d3cy00381g","ieee":"M. Kirchhof et al., “Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis,” Catalysis Science Technology, vol. 13, no. 12, pp. 3709–3724, 2023, doi: 10.1039/d3cy00381g.","chicago":"Kirchhof, Manuel, Katrin Gugeler, Ann-Katrin Beurer, Felix Richard Fischer, Derman Batman, Soeren M. Bauch, Sofia Kolin, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects on Asymmetric Catalysis.” Catalysis Science Technology 13, no. 12 (2023): 3709–24. https://doi.org/10.1039/d3cy00381g.","apa":"Kirchhof, M., Gugeler, K., Beurer, A.-K., Fischer, F. R., Batman, D., Bauch, S. M., Kolin, S., Nicholas, E., Schoch, R., Vogler, C., Kousik, S. R., Zens, A., Plietker, B., Atanasova, P., Naumann, S., Bauer, M., Bruckner, J. R., Traa, Y., Kästner, J., & Laschat, S. (2023). Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. Catalysis Science Technology, 13(12), 3709–3724. https://doi.org/10.1039/d3cy00381g","short":"M. Kirchhof, K. Gugeler, A.-K. Beurer, F.R. Fischer, D. Batman, S.M. Bauch, S. Kolin, E. Nicholas, R. Schoch, C. Vogler, S.R. Kousik, A. Zens, B. Plietker, P. Atanasova, S. Naumann, M. Bauer, J.R. Bruckner, Y. Traa, J. Kästner, S. Laschat, Catalysis Science Technology 13 (2023) 3709–3724.","mla":"Kirchhof, Manuel, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects on Asymmetric Catalysis.” Catalysis Science Technology, vol. 13, no. 12, Royal Society of Chemistry (RSC), 2023, pp. 3709–24, doi:10.1039/d3cy00381g.","bibtex":"@article{Kirchhof_Gugeler_Beurer_Fischer_Batman_Bauch_Kolin_Nicholas_Schoch_Vogler_et al._2023, title={Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis}, volume={13}, DOI={10.1039/d3cy00381g}, number={12}, journal={Catalysis Science Technology}, publisher={Royal Society of Chemistry (RSC)}, author={Kirchhof, Manuel and Gugeler, Katrin and Beurer, Ann-Katrin and Fischer, Felix Richard and Batman, Derman and Bauch, Soeren M. and Kolin, Sofia and Nicholas, Elliot and Schoch, Roland and Vogler, Charlotte and et al.}, year={2023}, pages={3709–3724} }"},"intvolume":" 13","page":"3709-3724","date_updated":"2025-06-16T09:00:17Z","author":[{"first_name":"Manuel","full_name":"Kirchhof, Manuel","last_name":"Kirchhof"},{"full_name":"Gugeler, Katrin","last_name":"Gugeler","first_name":"Katrin"},{"full_name":"Beurer, Ann-Katrin","last_name":"Beurer","first_name":"Ann-Katrin"},{"last_name":"Fischer","full_name":"Fischer, Felix Richard","first_name":"Felix Richard"},{"full_name":"Batman, Derman","last_name":"Batman","first_name":"Derman"},{"full_name":"Bauch, Soeren M.","last_name":"Bauch","first_name":"Soeren M."},{"first_name":"Sofia","last_name":"Kolin","full_name":"Kolin, Sofia"},{"last_name":"Nicholas","full_name":"Nicholas, Elliot","first_name":"Elliot"},{"last_name":"Schoch","orcid":"0000-0003-2061-7289","full_name":"Schoch, Roland","id":"48467","first_name":"Roland"},{"last_name":"Vogler","full_name":"Vogler, Charlotte","first_name":"Charlotte"},{"last_name":"Kousik","full_name":"Kousik, Shravan R.","first_name":"Shravan R."},{"first_name":"Anna","full_name":"Zens, Anna","last_name":"Zens"},{"full_name":"Plietker, Bernd","last_name":"Plietker","first_name":"Bernd"},{"first_name":"Petia","full_name":"Atanasova, Petia","last_name":"Atanasova"},{"first_name":"Stefan","full_name":"Naumann, Stefan","last_name":"Naumann"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"first_name":"Johanna R.","last_name":"Bruckner","full_name":"Bruckner, Johanna R."},{"last_name":"Traa","full_name":"Traa, Yvonne","first_name":"Yvonne"},{"first_name":"Johannes","full_name":"Kästner, Johannes","last_name":"Kästner"},{"last_name":"Laschat","full_name":"Laschat, Sabine","first_name":"Sabine"}],"volume":13,"doi":"10.1039/d3cy00381g","type":"journal_article","status":"public","_id":"52343","user_id":"48467","department":[{"_id":"306"}],"article_type":"original"},{"citation":{"chicago":"Strübbe, Sven, Michał Nowakowski, Roland Schoch, and Matthias Bauer. “High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts.” ChemPhysChem, 2023. https://doi.org/10.1002/cphc.202300113.","ieee":"S. Strübbe, M. Nowakowski, R. Schoch, and M. Bauer, “High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts,” ChemPhysChem, 2023, doi: 10.1002/cphc.202300113.","ama":"Strübbe S, Nowakowski M, Schoch R, Bauer M. High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts. ChemPhysChem. Published online 2023. doi:10.1002/cphc.202300113","bibtex":"@article{Strübbe_Nowakowski_Schoch_Bauer_2023, title={High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts}, DOI={10.1002/cphc.202300113}, journal={ChemPhysChem}, publisher={Wiley}, author={Strübbe, Sven and Nowakowski, Michał and Schoch, Roland and Bauer, Matthias}, year={2023} }","mla":"Strübbe, Sven, et al. “High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts.” ChemPhysChem, Wiley, 2023, doi:10.1002/cphc.202300113.","short":"S. Strübbe, M. Nowakowski, R. Schoch, M. Bauer, ChemPhysChem (2023).","apa":"Strübbe, S., Nowakowski, M., Schoch, R., & Bauer, M. (2023). High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts. ChemPhysChem. https://doi.org/10.1002/cphc.202300113"},"year":"2023","publication_status":"published","publication_identifier":{"issn":["1439-4235","1439-7641"]},"doi":"10.1002/cphc.202300113","title":"High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts","date_created":"2023-10-17T08:14:08Z","author":[{"id":"76968","full_name":"Strübbe, Sven","last_name":"Strübbe","first_name":"Sven"},{"first_name":"Michał","full_name":"Nowakowski, Michał","id":"78878","orcid":"0000-0002-3734-7011","last_name":"Nowakowski"},{"first_name":"Roland","full_name":"Schoch, Roland","id":"48467","orcid":"0000-0003-2061-7289","last_name":"Schoch"},{"full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076","first_name":"Matthias"}],"date_updated":"2025-08-15T12:53:23Z","publisher":"Wiley","status":"public","abstract":[{"text":"AbstractA new approach for the characterization of CO2 methanation catalysts prepared by thermal decomposition of a nickel MOF by hard X‐ray photon‐in/photon‐out spectroscopy in form of high energy resolution fluorescence detected X‐ray absorption near edge structure spectroscopy (HERFD‐XANES) and valence‐to‐core X‐ray emission (VtC‐XES) is presented. In contrast to conventional X‐ray absorption spectroscopy, the increased resolution of both methods allows a more precise phase determination of the final catalyst, which is influenced by the conditions during MOF decomposition.","lang":"eng"}],"type":"journal_article","publication":"ChemPhysChem","language":[{"iso":"eng"}],"keyword":["Catalysis"],"user_id":"48467","_id":"48167"},{"keyword":["Catalysis"],"language":[{"iso":"eng"}],"_id":"45480","user_id":"48467","abstract":[{"text":"For improved and rational design of catalysts, in-depth knowledge of their formation and structural evolution during synthesis is a key parameter. Thus, preparation of a Ni methanation catalyst derived from...","lang":"eng"}],"status":"public","publication":"New Journal of Chemistry","type":"journal_article","title":"Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering","doi":"10.1039/d3nj00493g","publisher":"Royal Society of Chemistry (RSC)","date_updated":"2025-08-15T12:56:35Z","author":[{"first_name":"Nils","last_name":"Prinz","full_name":"Prinz, Nils"},{"last_name":"Strübbe","full_name":"Strübbe, Sven","id":"76968","first_name":"Sven"},{"full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076","first_name":"Matthias"},{"first_name":"Mirijam","last_name":"Zobel","full_name":"Zobel, Mirijam"}],"date_created":"2023-06-06T07:33:35Z","year":"2023","citation":{"ama":"Prinz N, Strübbe S, Bauer M, Zobel M. Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering. New Journal of Chemistry. Published online 2023. doi:10.1039/d3nj00493g","ieee":"N. Prinz, S. Strübbe, M. Bauer, and M. Zobel, “Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering,” New Journal of Chemistry, 2023, doi: 10.1039/d3nj00493g.","chicago":"Prinz, Nils, Sven Strübbe, Matthias Bauer, and Mirijam Zobel. “Structural Transitions during Ni Nanoparticle Formation by Decomposition of a Ni-Containing Metal-Organic Framework Using in-Situ Total Scattering.” New Journal of Chemistry, 2023. https://doi.org/10.1039/d3nj00493g.","bibtex":"@article{Prinz_Strübbe_Bauer_Zobel_2023, title={Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering}, DOI={10.1039/d3nj00493g}, journal={New Journal of Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Prinz, Nils and Strübbe, Sven and Bauer, Matthias and Zobel, Mirijam}, year={2023} }","short":"N. Prinz, S. Strübbe, M. Bauer, M. Zobel, New Journal of Chemistry (2023).","mla":"Prinz, Nils, et al. “Structural Transitions during Ni Nanoparticle Formation by Decomposition of a Ni-Containing Metal-Organic Framework Using in-Situ Total Scattering.” New Journal of Chemistry, Royal Society of Chemistry (RSC), 2023, doi:10.1039/d3nj00493g.","apa":"Prinz, N., Strübbe, S., Bauer, M., & Zobel, M. (2023). Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering. New Journal of Chemistry. https://doi.org/10.1039/d3nj00493g"},"publication_identifier":{"issn":["1144-0546","1369-9261"]},"publication_status":"published"},{"user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"40988","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"type":"journal_article","publication":"ChemCatChem","status":"public","abstract":[{"text":"Increasing the metal-to-ligand charge transfer (MLCT) excited state lifetime of polypyridine iron(II) complexes can be achieved by lowering the ligand's π* orbital energy and by increasing the ligand field splitting. In the homo- and heteroleptic complexes [Fe(cpmp)2]2+ (12+) and [Fe(cpmp)(ddpd)]2+ (22+) with the tridentate ligands 6,2’’-carboxypyridyl-2,2’-methylamine-pyridyl-pyridine (cpmp) and N,N’-dimethyl-N,N’-di-pyridin-2-ylpyridine-2,6-diamine (ddpd) two or one dipyridyl ketone moieties provide low energy π* acceptor orbitals. A good metal-ligand orbital overlap to increase the ligand field splitting is achieved by optimizing the octahedricity through CO and NMe units between the coordinating pyridines which enable the formation of six-membered chelate rings. The push-pull ligand cpmp provides intra-ligand and ligand-to-ligand charge transfer (ILCT, LL'CT) excited states in addition to MLCT excited states. Ground and excited state properties of 12+ and 22+ were accessed by X-ray diffraction analyses, resonance Raman spectroscopy, (spectro)electrochemistry, EPR spectroscopy, X-ray emission spectroscopy, static and time-resolved IR and UV/Vis/NIR absorption spectroscopy as well as quantum chemical calculations.","lang":"eng"}],"author":[{"full_name":"Weber, Sebastian","last_name":"Weber","first_name":"Sebastian"},{"first_name":"Ronny T.","last_name":"Zimmermann","full_name":"Zimmermann, Ronny T."},{"last_name":"Bremer","full_name":"Bremer, Jens","first_name":"Jens"},{"first_name":"Ken L.","full_name":"Abel, Ken L.","last_name":"Abel"},{"full_name":"Poppitz, David","last_name":"Poppitz","first_name":"David"},{"last_name":"Prinz","full_name":"Prinz, Nils","first_name":"Nils"},{"last_name":"Ilsemann","full_name":"Ilsemann, Jan","first_name":"Jan"},{"first_name":"Sven","full_name":"Wendholt, Sven","last_name":"Wendholt"},{"last_name":"Yang","full_name":"Yang, Qingxin","first_name":"Qingxin"},{"first_name":"Reihaneh","full_name":"Pashminehazar, Reihaneh","last_name":"Pashminehazar"},{"full_name":"Monaco, Federico","last_name":"Monaco","first_name":"Federico"},{"first_name":"Peter","full_name":"Cloetens, Peter","last_name":"Cloetens"},{"full_name":"Huang, Xiaohui","last_name":"Huang","first_name":"Xiaohui"},{"first_name":"Christian","full_name":"Kübel, Christian","last_name":"Kübel"},{"first_name":"Evgenii","full_name":"Kondratenko, Evgenii","last_name":"Kondratenko"},{"orcid":"0000-0002-9294-6076","last_name":"Bauer","id":"47241","full_name":"Bauer, Matthias","first_name":"Matthias"},{"full_name":"Bäumer, Marcus","last_name":"Bäumer","first_name":"Marcus"},{"last_name":"Zobel","full_name":"Zobel, Mirijam","first_name":"Mirijam"},{"last_name":"Gläser","full_name":"Gläser, Roger","first_name":"Roger"},{"first_name":"Kai","last_name":"Sundmacher","full_name":"Sundmacher, Kai"},{"first_name":"Thomas L.","last_name":"Sheppard","full_name":"Sheppard, Thomas L."}],"date_created":"2023-01-30T16:25:02Z","volume":14,"publisher":"Wiley","date_updated":"2024-05-08T13:03:51Z","doi":"10.1002/cctc.202101878","title":"Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation","issue":"8","publication_status":"published","publication_identifier":{"issn":["1867-3880","1867-3899"]},"citation":{"ieee":"S. Weber et al., “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation,” ChemCatChem, vol. 14, no. 8, 2022, doi: 10.1002/cctc.202101878.","chicago":"Weber, Sebastian, Ronny T. Zimmermann, Jens Bremer, Ken L. Abel, David Poppitz, Nils Prinz, Jan Ilsemann, et al. “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation.” ChemCatChem 14, no. 8 (2022). https://doi.org/10.1002/cctc.202101878.","ama":"Weber S, Zimmermann RT, Bremer J, et al. Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation. ChemCatChem. 2022;14(8). doi:10.1002/cctc.202101878","short":"S. Weber, R.T. Zimmermann, J. Bremer, K.L. Abel, D. Poppitz, N. Prinz, J. Ilsemann, S. Wendholt, Q. Yang, R. Pashminehazar, F. Monaco, P. Cloetens, X. Huang, C. Kübel, E. Kondratenko, M. Bauer, M. Bäumer, M. Zobel, R. Gläser, K. Sundmacher, T.L. Sheppard, ChemCatChem 14 (2022).","mla":"Weber, Sebastian, et al. “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation.” ChemCatChem, vol. 14, no. 8, Wiley, 2022, doi:10.1002/cctc.202101878.","bibtex":"@article{Weber_Zimmermann_Bremer_Abel_Poppitz_Prinz_Ilsemann_Wendholt_Yang_Pashminehazar_et al._2022, title={Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation}, volume={14}, DOI={10.1002/cctc.202101878}, number={8}, journal={ChemCatChem}, publisher={Wiley}, author={Weber, Sebastian and Zimmermann, Ronny T. and Bremer, Jens and Abel, Ken L. and Poppitz, David and Prinz, Nils and Ilsemann, Jan and Wendholt, Sven and Yang, Qingxin and Pashminehazar, Reihaneh and et al.}, year={2022} }","apa":"Weber, S., Zimmermann, R. T., Bremer, J., Abel, K. L., Poppitz, D., Prinz, N., Ilsemann, J., Wendholt, S., Yang, Q., Pashminehazar, R., Monaco, F., Cloetens, P., Huang, X., Kübel, C., Kondratenko, E., Bauer, M., Bäumer, M., Zobel, M., Gläser, R., … Sheppard, T. L. (2022). Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation. ChemCatChem, 14(8). https://doi.org/10.1002/cctc.202101878"},"intvolume":" 14","year":"2022"},{"doi":"10.1002/chem.202201858","title":"Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry","volume":28,"author":[{"first_name":"Johannes","last_name":"Moll","full_name":"Moll, Johannes"},{"first_name":"Robert","full_name":"Naumann, Robert","last_name":"Naumann"},{"first_name":"Lukas","full_name":"Sorge, Lukas","last_name":"Sorge"},{"first_name":"Christoph","full_name":"Förster, Christoph","last_name":"Förster"},{"first_name":"Niklas","last_name":"Gessner","full_name":"Gessner, Niklas"},{"id":"54038","full_name":"Burkhardt, Lukas","orcid":"0000-0003-0747-9811","last_name":"Burkhardt","first_name":"Lukas"},{"last_name":"Ugur","full_name":"Ugur, Naz","first_name":"Naz"},{"first_name":"Patrick","full_name":"Nuernberger, Patrick","last_name":"Nuernberger"},{"first_name":"Wolfram","full_name":"Seidel, Wolfram","last_name":"Seidel"},{"first_name":"Charusheela","last_name":"Ramanan","full_name":"Ramanan, Charusheela"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"first_name":"Katja","full_name":"Heinze, Katja","last_name":"Heinze"}],"date_created":"2023-01-30T16:23:37Z","publisher":"Wiley","date_updated":"2023-01-31T08:00:32Z","intvolume":" 28","citation":{"mla":"Moll, Johannes, et al. “Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry.” Chemistry – A European Journal, vol. 28, no. 57, Wiley, 2022, doi:10.1002/chem.202201858.","bibtex":"@article{Moll_Naumann_Sorge_Förster_Gessner_Burkhardt_Ugur_Nuernberger_Seidel_Ramanan_et al._2022, title={Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry}, volume={28}, DOI={10.1002/chem.202201858}, number={57}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Moll, Johannes and Naumann, Robert and Sorge, Lukas and Förster, Christoph and Gessner, Niklas and Burkhardt, Lukas and Ugur, Naz and Nuernberger, Patrick and Seidel, Wolfram and Ramanan, Charusheela and et al.}, year={2022} }","short":"J. Moll, R. Naumann, L. Sorge, C. Förster, N. Gessner, L. Burkhardt, N. Ugur, P. Nuernberger, W. Seidel, C. Ramanan, M. Bauer, K. Heinze, Chemistry – A European Journal 28 (2022).","apa":"Moll, J., Naumann, R., Sorge, L., Förster, C., Gessner, N., Burkhardt, L., Ugur, N., Nuernberger, P., Seidel, W., Ramanan, C., Bauer, M., & Heinze, K. (2022). Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry. Chemistry – A European Journal, 28(57). https://doi.org/10.1002/chem.202201858","chicago":"Moll, Johannes, Robert Naumann, Lukas Sorge, Christoph Förster, Niklas Gessner, Lukas Burkhardt, Naz Ugur, et al. “Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry.” Chemistry – A European Journal 28, no. 57 (2022). https://doi.org/10.1002/chem.202201858.","ieee":"J. Moll et al., “Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry,” Chemistry – A European Journal, vol. 28, no. 57, 2022, doi: 10.1002/chem.202201858.","ama":"Moll J, Naumann R, Sorge L, et al. Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry. Chemistry – A European Journal. 2022;28(57). doi:10.1002/chem.202201858"},"year":"2022","issue":"57","publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"40985","status":"public","publication":"Chemistry – A European Journal","type":"journal_article"},{"keyword":["Physical and Theoretical Chemistry","Catalysis","General Environmental Science","Key"],"language":[{"iso":"eng"}],"abstract":[{"lang":"eng","text":"Catalysts 12, no. 6 (2022). https://doi.org/10.3390/catal12060675.","ieee":"S. Schlicher et al., “Quality or Quantity? How Structural Parameters Affect Catalytic Activity of Iron Oxides for CO Oxidation,” Catalysts, vol. 12, no. 6, Art. no. 675, 2022, doi: 10.3390/catal12060675.","ama":"Schlicher S, Prinz N, Bürger J, et al. Quality or Quantity? How Structural Parameters Affect Catalytic Activity of Iron Oxides for CO Oxidation. Catalysts. 2022;12(6). doi:10.3390/catal12060675","short":"S. Schlicher, N. Prinz, J. Bürger, A. Omlor, C. Singer, M. Zobel, R. Schoch, J.K.N. Lindner, V. Schünemann, S. Kureti, M. Bauer, Catalysts 12 (2022).","bibtex":"@article{Schlicher_Prinz_Bürger_Omlor_Singer_Zobel_Schoch_Lindner_Schünemann_Kureti_et al._2022, title={Quality or Quantity? How Structural Parameters Affect Catalytic Activity of Iron Oxides for CO Oxidation}, volume={12}, DOI={10.3390/catal12060675}, number={6675}, journal={Catalysts}, publisher={MDPI AG}, author={Schlicher, Steffen and Prinz, Nils and Bürger, Julius and Omlor, Andreas and Singer, Christian and Zobel, Mirijam and Schoch, Roland and Lindner, Jörg K. N. and Schünemann, Volker and Kureti, Sven and et al.}, year={2022} }","mla":"Schlicher, Steffen, et al. “Quality or Quantity? How Structural Parameters Affect Catalytic Activity of Iron Oxides for CO Oxidation.” Catalysts, vol. 12, no. 6, 675, MDPI AG, 2022, doi:10.3390/catal12060675.","apa":"Schlicher, S., Prinz, N., Bürger, J., Omlor, A., Singer, C., Zobel, M., Schoch, R., Lindner, J. K. N., Schünemann, V., Kureti, S., & Bauer, M. (2022). Quality or Quantity? How Structural Parameters Affect Catalytic Activity of Iron Oxides for CO Oxidation. Catalysts, 12(6), Article 675. https://doi.org/10.3390/catal12060675"},"intvolume":" 12","publication_status":"published","publication_identifier":{"issn":["2073-4344"]}},{"keyword":["Catalysis","General Chemistry"],"language":[{"iso":"eng"}],"publication":"ACS Catalysis","abstract":[{"text":"For entropic reasons, the synthesis of macrocycles via olefin ring-closing metathesis (RCM) is impeded by competing acyclic diene metathesis (ADMET) oligomerization. With cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes confined in tailored ordered mesoporous silica, RCM can be run with macrocyclization selectivities up to 98% and high substrate concentrations up to 0.1 M. Molecular dynamics simulations show that the high conversions are a direct result of the proximity between the surface-bound catalyst, proven by extended X-ray absorption spectroscopy, and the surface-located substrates. Back-diffusion of the macrocycles decreases with decreasing pore diameter of the silica and is responsible for the high macrocyclization efficiency. Also, Z-selectivity increases with decreasing pore diameter and increasing Tolman electronic parameter of the NHC. Running reactions at different concentrations allows for identifying the optimum substrate concentration for each material and substrate combination.","lang":"eng"}],"publisher":"American Chemical Society (ACS)","date_created":"2023-01-30T16:49:07Z","title":"Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes","issue":"18","year":"2021","_id":"41001","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"article_type":"original","type":"journal_article","status":"public","date_updated":"2024-05-07T11:44:19Z","author":[{"first_name":"Felix","last_name":"Ziegler","full_name":"Ziegler, Felix"},{"first_name":"Hamzeh","last_name":"Kraus","full_name":"Kraus, Hamzeh"},{"full_name":"Benedikter, Mathis J.","last_name":"Benedikter","first_name":"Mathis J."},{"last_name":"Wang","full_name":"Wang, Dongren","first_name":"Dongren"},{"first_name":"Johanna R.","last_name":"Bruckner","full_name":"Bruckner, Johanna R."},{"first_name":"Michał","id":"78878","full_name":"Nowakowski, Michał","last_name":"Nowakowski","orcid":"0000-0002-3734-7011"},{"first_name":"Kilian","last_name":"Weißer","full_name":"Weißer, Kilian"},{"last_name":"Solodenko","full_name":"Solodenko, Helena","first_name":"Helena"},{"first_name":"Guido","full_name":"Schmitz, Guido","last_name":"Schmitz"},{"last_name":"Bauer","orcid":"0000-0002-9294-6076","id":"47241","full_name":"Bauer, Matthias","first_name":"Matthias"},{"full_name":"Hansen, Niels","last_name":"Hansen","first_name":"Niels"},{"first_name":"Michael R.","full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser"}],"volume":11,"doi":"10.1021/acscatal.1c03057","publication_status":"published","publication_identifier":{"issn":["2155-5435","2155-5435"]},"citation":{"ama":"Ziegler F, Kraus H, Benedikter MJ, et al. Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes. ACS Catalysis. 2021;11(18):11570-11578. doi:10.1021/acscatal.1c03057","ieee":"F. Ziegler et al., “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes,” ACS Catalysis, vol. 11, no. 18, pp. 11570–11578, 2021, doi: 10.1021/acscatal.1c03057.","chicago":"Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, Dongren Wang, Johanna R. Bruckner, Michał Nowakowski, Kilian Weißer, et al. “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis 11, no. 18 (2021): 11570–78. https://doi.org/10.1021/acscatal.1c03057.","mla":"Ziegler, Felix, et al. “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis, vol. 11, no. 18, American Chemical Society (ACS), 2021, pp. 11570–78, doi:10.1021/acscatal.1c03057.","bibtex":"@article{Ziegler_Kraus_Benedikter_Wang_Bruckner_Nowakowski_Weißer_Solodenko_Schmitz_Bauer_et al._2021, title={Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes}, volume={11}, DOI={10.1021/acscatal.1c03057}, number={18}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren and Bruckner, Johanna R. and Nowakowski, Michał and Weißer, Kilian and Solodenko, Helena and Schmitz, Guido and Bauer, Matthias and et al.}, year={2021}, pages={11570–11578} }","short":"F. Ziegler, H. Kraus, M.J. Benedikter, D. Wang, J.R. Bruckner, M. Nowakowski, K. Weißer, H. Solodenko, G. Schmitz, M. Bauer, N. Hansen, M.R. Buchmeiser, ACS Catalysis 11 (2021) 11570–11578.","apa":"Ziegler, F., Kraus, H., Benedikter, M. J., Wang, D., Bruckner, J. R., Nowakowski, M., Weißer, K., Solodenko, H., Schmitz, G., Bauer, M., Hansen, N., & Buchmeiser, M. R. (2021). Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes. ACS Catalysis, 11(18), 11570–11578. https://doi.org/10.1021/acscatal.1c03057"},"intvolume":" 11","page":"11570-11578"},{"issue":"68","year":"2021","publisher":"Wiley","date_created":"2023-01-30T16:48:41Z","title":"Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes","publication":"Chemistry – A European Journal","abstract":[{"lang":"eng","text":"Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl, NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous progenitors, the immobilized catalysts were used in the hydrosilylation of terminal alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and stereoselective catalysts, allowing for the formation of the thermodynamically less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15 immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement, showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes, too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with its homogenous counterpart. These are the first examples of high β(Z)-selectivity in the hydrosilylation of alkynes by confinement generated upon immobilization inside mesoporous silica."}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"language":[{"iso":"eng"}],"publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","page":"17220-17229","intvolume":" 27","citation":{"bibtex":"@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={10.1002/chem.202103099}, number={68}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michał and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229} }","short":"P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R. Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.","mla":"Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal, vol. 27, no. 68, Wiley, 2021, pp. 17220–29, doi:10.1002/chem.202103099.","apa":"Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal, 27(68), 17220–17229. https://doi.org/10.1002/chem.202103099","ieee":"P. K. R. Panyam et al., “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes,” Chemistry – A European Journal, vol. 27, no. 68, pp. 17220–17229, 2021, doi: 10.1002/chem.202103099.","chicago":"Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michał Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal 27, no. 68 (2021): 17220–29. https://doi.org/10.1002/chem.202103099.","ama":"Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal. 2021;27(68):17220-17229. doi:10.1002/chem.202103099"},"date_updated":"2024-05-07T11:43:40Z","volume":27,"author":[{"last_name":"Panyam","full_name":"Panyam, Pradeep K. R.","first_name":"Pradeep K. R."},{"first_name":"Boshra","last_name":"Atwi","full_name":"Atwi, Boshra"},{"first_name":"Felix","last_name":"Ziegler","full_name":"Ziegler, Felix"},{"first_name":"Wolfgang","last_name":"Frey","full_name":"Frey, Wolfgang"},{"orcid":"0000-0002-3734-7011","last_name":"Nowakowski","full_name":"Nowakowski, Michał","id":"78878","first_name":"Michał"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser","first_name":"Michael R."}],"doi":"10.1002/chem.202103099","type":"journal_article","status":"public","_id":"40999","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","article_type":"original"},{"publisher":"Wiley","date_created":"2022-03-09T08:20:58Z","title":"Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad","issue":"38","year":"2021","keyword":["Photocatalytic Hydrogen Production","Catalysis","Inorganic Chemistry"],"language":[{"iso":"eng"}],"publication":"Chemistry – A European Journal","date_updated":"2024-05-07T11:44:08Z","volume":27,"author":[{"last_name":"Huber-Gedert","full_name":"Huber-Gedert, Marina","id":"38352","first_name":"Marina"},{"first_name":"Michał","id":"78878","full_name":"Nowakowski, Michał","last_name":"Nowakowski","orcid":"0000-0002-3734-7011"},{"full_name":"Kertmen, Ahmet","last_name":"Kertmen","first_name":"Ahmet"},{"id":"54038","full_name":"Burkhardt, Lukas","last_name":"Burkhardt","orcid":"0000-0003-0747-9811","first_name":"Lukas"},{"full_name":"Lindner, Natalia","last_name":"Lindner","first_name":"Natalia"},{"first_name":"Roland","last_name":"Schoch","full_name":"Schoch, Roland"},{"last_name":"Herbst‐Irmer","full_name":"Herbst‐Irmer, Regine","first_name":"Regine"},{"full_name":"Neuba, Adam","last_name":"Neuba","first_name":"Adam"},{"first_name":"Lennart","last_name":"Schmitz","full_name":"Schmitz, Lennart"},{"first_name":"Tae‐Kyu","last_name":"Choi","full_name":"Choi, Tae‐Kyu"},{"first_name":"Jacek","full_name":"Kubicki, Jacek","last_name":"Kubicki"},{"last_name":"Gawelda","full_name":"Gawelda, Wojciech","first_name":"Wojciech"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076"}],"doi":"10.1002/chem.202100766","publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","page":"9905-9918","intvolume":" 27","citation":{"ama":"Huber-Gedert M, Nowakowski M, Kertmen A, et al. Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal. 2021;27(38):9905-9918. doi:10.1002/chem.202100766","ieee":"M. Huber-Gedert et al., “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad,” Chemistry – A European Journal, vol. 27, no. 38, pp. 9905–9918, 2021, doi: 10.1002/chem.202100766.","chicago":"Huber-Gedert, Marina, Michał Nowakowski, Ahmet Kertmen, Lukas Burkhardt, Natalia Lindner, Roland Schoch, Regine Herbst‐Irmer, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European Journal 27, no. 38 (2021): 9905–18. https://doi.org/10.1002/chem.202100766.","mla":"Huber-Gedert, Marina, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European Journal, vol. 27, no. 38, Wiley, 2021, pp. 9905–18, doi:10.1002/chem.202100766.","bibtex":"@article{Huber-Gedert_Nowakowski_Kertmen_Burkhardt_Lindner_Schoch_Herbst‐Irmer_Neuba_Schmitz_Choi_et al._2021, title={Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad}, volume={27}, DOI={10.1002/chem.202100766}, number={38}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Huber-Gedert, Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner, Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz, Lennart and Choi, Tae‐Kyu and et al.}, year={2021}, pages={9905–9918} }","short":"M. Huber-Gedert, M. Nowakowski, A. Kertmen, L. Burkhardt, N. Lindner, R. Schoch, R. Herbst‐Irmer, A. Neuba, L. Schmitz, T. Choi, J. Kubicki, W. Gawelda, M. Bauer, Chemistry – A European Journal 27 (2021) 9905–9918.","apa":"Huber-Gedert, M., Nowakowski, M., Kertmen, A., Burkhardt, L., Lindner, N., Schoch, R., Herbst‐Irmer, R., Neuba, A., Schmitz, L., Choi, T., Kubicki, J., Gawelda, W., & Bauer, M. (2021). Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal, 27(38), 9905–9918. https://doi.org/10.1002/chem.202100766"},"_id":"30216","department":[{"_id":"306"}],"user_id":"48467","type":"journal_article","status":"public"},{"title":"Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity","doi":"10.1002/chem.202104108","date_updated":"2023-01-31T08:05:07Z","publisher":"Wiley","volume":28,"date_created":"2023-01-30T16:48:22Z","author":[{"last_name":"Emmerling","full_name":"Emmerling, Sebastian T.","first_name":"Sebastian T."},{"full_name":"Ziegler, Felix","last_name":"Ziegler","first_name":"Felix"},{"last_name":"Fischer","full_name":"Fischer, Felix R.","first_name":"Felix R."},{"first_name":"Roland","id":"48467","full_name":"Schoch, Roland","last_name":"Schoch","orcid":"0000-0003-2061-7289"},{"orcid":"0000-0002-9294-6076","last_name":"Bauer","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"},{"full_name":"Plietker, Bernd","last_name":"Plietker","first_name":"Bernd"},{"full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser","first_name":"Michael R."},{"first_name":"Bettina V.","full_name":"Lotsch, Bettina V.","last_name":"Lotsch"}],"year":"2021","intvolume":" 28","citation":{"short":"S.T. Emmerling, F. Ziegler, F.R. Fischer, R. Schoch, M. Bauer, B. Plietker, M.R. Buchmeiser, B.V. Lotsch, Chemistry – A European Journal 28 (2021).","bibtex":"@article{Emmerling_Ziegler_Fischer_Schoch_Bauer_Plietker_Buchmeiser_Lotsch_2021, title={Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity}, volume={28}, DOI={10.1002/chem.202104108}, number={8}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Emmerling, Sebastian T. and Ziegler, Felix and Fischer, Felix R. and Schoch, Roland and Bauer, Matthias and Plietker, Bernd and Buchmeiser, Michael R. and Lotsch, Bettina V.}, year={2021} }","mla":"Emmerling, Sebastian T., et al. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” Chemistry – A European Journal, vol. 28, no. 8, Wiley, 2021, doi:10.1002/chem.202104108.","apa":"Emmerling, S. T., Ziegler, F., Fischer, F. R., Schoch, R., Bauer, M., Plietker, B., Buchmeiser, M. R., & Lotsch, B. V. (2021). Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. Chemistry – A European Journal, 28(8). https://doi.org/10.1002/chem.202104108","ama":"Emmerling ST, Ziegler F, Fischer FR, et al. Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. Chemistry – A European Journal. 2021;28(8). doi:10.1002/chem.202104108","ieee":"S. T. Emmerling et al., “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity,” Chemistry – A European Journal, vol. 28, no. 8, 2021, doi: 10.1002/chem.202104108.","chicago":"Emmerling, Sebastian T., Felix Ziegler, Felix R. Fischer, Roland Schoch, Matthias Bauer, Bernd Plietker, Michael R. Buchmeiser, and Bettina V. Lotsch. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” Chemistry – A European Journal 28, no. 8 (2021). https://doi.org/10.1002/chem.202104108."},"publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","issue":"8","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"article_type":"original","language":[{"iso":"eng"}],"_id":"40998","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","abstract":[{"text":"Covalent organic frameworks (COFs) offer vast structural and chemical diversity enabling a wide and growing range of applications. While COFs are well-established as heterogeneous catalysts, so far, their high and ordered porosity has scarcely been utilized to its full potential when it comes to spatially confined reactions in COF pores to alter the outcome of reactions. Here, we present a highly porous and crystalline, large-pore COF as catalytic support in α,ω-diene ring-closing metathesis reactions, leading to increased macrocyclization selectivity. COF pore-wall modification by immobilization of a Grubbs-Hoveyda-type catalyst via a mild silylation reaction provides a molecularly precise heterogeneous olefin metathesis catalyst. An increased macro(mono)cyclization (MMC) selectivity over oligomerization (O) for the heterogeneous COF-catalyst (MMC:O=1.35) of up to 51 % compared to the homogeneous catalyst (MMC:O=0.90) was observed along with a substrate-size dependency in selectivity, pointing to diffusion limitations induced by the pore confinement.","lang":"eng"}],"status":"public","publication":"Chemistry – A European Journal","type":"journal_article"},{"publication_identifier":{"issn":["1359-7345","1364-548X"]},"publication_status":"published","intvolume":" 57","page":"7541-7544","citation":{"bibtex":"@article{Reuter_Kruse_Schoch_Lochbrunner_Bauer_Heinze_2021, title={Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion}, volume={57}, DOI={10.1039/d1cc02173g}, number={61}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Reuter, Thomas and Kruse, Ayla and Schoch, Roland and Lochbrunner, Stefan and Bauer, Matthias and Heinze, Katja}, year={2021}, pages={7541–7544} }","short":"T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, K. Heinze, Chemical Communications 57 (2021) 7541–7544.","mla":"Reuter, Thomas, et al. “Higher MLCT Lifetime of Carbene Iron(<scp>ii</Scp>) Complexes by Chelate Ring Expansion.” Chemical Communications, vol. 57, no. 61, Royal Society of Chemistry (RSC), 2021, pp. 7541–44, doi:10.1039/d1cc02173g.","apa":"Reuter, T., Kruse, A., Schoch, R., Lochbrunner, S., Bauer, M., & Heinze, K. (2021). Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion. Chemical Communications, 57(61), 7541–7544. https://doi.org/10.1039/d1cc02173g","ama":"Reuter T, Kruse A, Schoch R, Lochbrunner S, Bauer M, Heinze K. Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion. Chemical Communications. 2021;57(61):7541-7544. doi:10.1039/d1cc02173g","chicago":"Reuter, Thomas, Ayla Kruse, Roland Schoch, Stefan Lochbrunner, Matthias Bauer, and Katja Heinze. “Higher MLCT Lifetime of Carbene Iron(<scp>ii</Scp>) Complexes by Chelate Ring Expansion.” Chemical Communications 57, no. 61 (2021): 7541–44. https://doi.org/10.1039/d1cc02173g.","ieee":"T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, and K. Heinze, “Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion,” Chemical Communications, vol. 57, no. 61, pp. 7541–7544, 2021, doi: 10.1039/d1cc02173g."},"volume":57,"author":[{"last_name":"Reuter","full_name":"Reuter, Thomas","first_name":"Thomas"},{"full_name":"Kruse, Ayla","last_name":"Kruse","first_name":"Ayla"},{"orcid":"0000-0003-2061-7289","last_name":"Schoch","full_name":"Schoch, Roland","id":"48467","first_name":"Roland"},{"full_name":"Lochbrunner, Stefan","last_name":"Lochbrunner","first_name":"Stefan"},{"orcid":"0000-0002-9294-6076","last_name":"Bauer","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"},{"last_name":"Heinze","full_name":"Heinze, Katja","first_name":"Katja"}],"date_updated":"2023-01-31T08:06:16Z","doi":"10.1039/d1cc02173g","type":"journal_article","status":"public","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41003","article_type":"original","issue":"61","year":"2021","date_created":"2023-01-30T16:49:33Z","publisher":"Royal Society of Chemistry (RSC)","title":"Higher MLCT lifetime of carbene iron(ii) complexes by chelate ring expansion","publication":"Chemical Communications","abstract":[{"text":"Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(II) complexes increases the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2 ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(II) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap","lang":"eng"}],"language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composites","Electronic","Optical and Magnetic Materials","Catalysis"]},{"article_type":"original","keyword":["General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"_id":"41000","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"abstract":[{"lang":"eng","text":"Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies for the construction of functional molecules as they obviate the need for pre-functionalized substrates and minimize waste generation. Great challenges reside in the control of selectivities, the utilization of unbiased hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms. An especially mild borylation of benzylic CH bonds was developed with the ligand-free pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic, and preparative mechanistic studies are indicative of a tandem catalysis mechanism of CH-borylation and dehydrocoupling via molecular CoI catalysts."}],"status":"public","type":"journal_article","publication":"Angewandte Chemie International Edition","title":"Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis","doi":"10.1002/anie.202110821","date_updated":"2023-01-31T08:05:26Z","publisher":"Wiley","date_created":"2023-01-30T16:48:53Z","author":[{"first_name":"Pradip","last_name":"Ghosh","full_name":"Ghosh, Pradip"},{"id":"48467","full_name":"Schoch, Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch","first_name":"Roland"},{"last_name":"Bauer","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"},{"first_name":"Axel","full_name":"Jacobi von Wangelin, Axel","last_name":"Jacobi von Wangelin"}],"volume":61,"year":"2021","citation":{"ieee":"P. Ghosh, R. Schoch, M. Bauer, and A. Jacobi von Wangelin, “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis,” Angewandte Chemie International Edition, vol. 61, no. 1, 2021, doi: 10.1002/anie.202110821.","chicago":"Ghosh, Pradip, Roland Schoch, Matthias Bauer, and Axel Jacobi von Wangelin. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte Chemie International Edition 61, no. 1 (2021). https://doi.org/10.1002/anie.202110821.","ama":"Ghosh P, Schoch R, Bauer M, Jacobi von Wangelin A. Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International Edition. 2021;61(1). doi:10.1002/anie.202110821","apa":"Ghosh, P., Schoch, R., Bauer, M., & Jacobi von Wangelin, A. (2021). Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International Edition, 61(1). https://doi.org/10.1002/anie.202110821","mla":"Ghosh, Pradip, et al. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte Chemie International Edition, vol. 61, no. 1, Wiley, 2021, doi:10.1002/anie.202110821.","bibtex":"@article{Ghosh_Schoch_Bauer_Jacobi von Wangelin_2021, title={Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis}, volume={61}, DOI={10.1002/anie.202110821}, number={1}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021} }","short":"P. Ghosh, R. Schoch, M. Bauer, A. Jacobi von Wangelin, Angewandte Chemie International Edition 61 (2021)."},"intvolume":" 61","publication_status":"published","publication_identifier":{"issn":["1433-7851","1521-3773"]},"issue":"1"},{"status":"public","type":"journal_article","article_type":"original","_id":"41010","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","intvolume":" 60","page":"9534-9539","citation":{"bibtex":"@article{Watt_Burkhardt_Schoch_Mitzinger_Bauer_Weigend_Goicoechea_Tambornino_Hohloch_2021, title={η 3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**}, volume={60}, DOI={10.1002/anie.202100559}, number={17}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Watt, Fabian A. and Burkhardt, Lukas and Schoch, Roland and Mitzinger, Stefan and Bauer, Matthias and Weigend, Florian and Goicoechea, Jose M. and Tambornino, Frank and Hohloch, Stephan}, year={2021}, pages={9534–9539} }","short":"F.A. Watt, L. Burkhardt, R. Schoch, S. Mitzinger, M. Bauer, F. Weigend, J.M. Goicoechea, F. Tambornino, S. Hohloch, Angewandte Chemie International Edition 60 (2021) 9534–9539.","mla":"Watt, Fabian A., et al. “η 3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” Angewandte Chemie International Edition, vol. 60, no. 17, Wiley, 2021, pp. 9534–39, doi:10.1002/anie.202100559.","apa":"Watt, F. A., Burkhardt, L., Schoch, R., Mitzinger, S., Bauer, M., Weigend, F., Goicoechea, J. M., Tambornino, F., & Hohloch, S. (2021). η 3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**. Angewandte Chemie International Edition, 60(17), 9534–9539. https://doi.org/10.1002/anie.202100559","chicago":"Watt, Fabian A., Lukas Burkhardt, Roland Schoch, Stefan Mitzinger, Matthias Bauer, Florian Weigend, Jose M. Goicoechea, Frank Tambornino, and Stephan Hohloch. “η 3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” Angewandte Chemie International Edition 60, no. 17 (2021): 9534–39. https://doi.org/10.1002/anie.202100559.","ieee":"F. A. Watt et al., “η 3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**,” Angewandte Chemie International Edition, vol. 60, no. 17, pp. 9534–9539, 2021, doi: 10.1002/anie.202100559.","ama":"Watt FA, Burkhardt L, Schoch R, et al. η 3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**. Angewandte Chemie International Edition. 2021;60(17):9534-9539. doi:10.1002/anie.202100559"},"publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published","doi":"10.1002/anie.202100559","date_updated":"2023-01-31T08:06:50Z","volume":60,"author":[{"first_name":"Fabian A.","full_name":"Watt, Fabian A.","last_name":"Watt"},{"full_name":"Burkhardt, Lukas","last_name":"Burkhardt","first_name":"Lukas"},{"full_name":"Schoch, Roland","id":"48467","orcid":"0000-0003-2061-7289","last_name":"Schoch","first_name":"Roland"},{"first_name":"Stefan","full_name":"Mitzinger, Stefan","last_name":"Mitzinger"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"first_name":"Florian","full_name":"Weigend, Florian","last_name":"Weigend"},{"last_name":"Goicoechea","full_name":"Goicoechea, Jose M.","first_name":"Jose M."},{"first_name":"Frank","last_name":"Tambornino","full_name":"Tambornino, Frank"},{"first_name":"Stephan","last_name":"Hohloch","full_name":"Hohloch, Stephan"}],"abstract":[{"text":"We present the η3-coordination of the 2-phosphaethynthiolate anion in the complex (PN)2La(SCP) (2) [PN=N-(2-(diisopropylphosphanyl)-4-methylphenyl)-2,4,6-trimethylanilide)]. Structural comparison with dinuclear thiocyanate-bridged (PN)2La(μ-1,3-SCN)2La(PN)2 (3) and azide-bridged (PN)2La(μ-1,3-N3)2La(PN)2 (4) complexes indicates that the [SCP]− coordination mode is mainly governed by electronic, rather than steric factors. Quantum mechanical investigations reveal large contributions of the antibonding π*-orbital of the [SCP]− ligand to the LUMO of complex 2, rendering it the ideal precursor for the first functionalization of the [SCP]− anion. Complex 2 was therefore reacted with CAACs which induced a selective rearrangement of the [SCP]− ligand to form the first CAAC stabilized group 15–group 16 fulminate-type complexes (PN)2La{SPC(RCAAC)} (5 a,b, R=Ad, Me). A detailed reaction mechanism for the SCP-to-SPC isomerization is proposed based on DFT calculations.","lang":"eng"}],"publication":"Angewandte Chemie International Edition","keyword":["General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"year":"2021","issue":"17","title":"η 3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**","publisher":"Wiley","date_created":"2023-01-30T17:00:21Z"},{"doi":"10.1039/d1cc01716k","title":"Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes","volume":57,"date_created":"2023-01-30T16:59:55Z","author":[{"first_name":"Philipp","full_name":"Dierks, Philipp","last_name":"Dierks"},{"full_name":"Kruse, Ayla","last_name":"Kruse","first_name":"Ayla"},{"first_name":"Olga S.","last_name":"Bokareva","full_name":"Bokareva, Olga S."},{"first_name":"Mohammed J.","last_name":"Al-Marri","full_name":"Al-Marri, Mohammed J."},{"first_name":"Jens","last_name":"Kalmbach","full_name":"Kalmbach, Jens"},{"last_name":"Baltrun","full_name":"Baltrun, Marc","first_name":"Marc"},{"full_name":"Neuba, Adam","last_name":"Neuba","first_name":"Adam"},{"orcid":"0000-0003-2061-7289","last_name":"Schoch","full_name":"Schoch, Roland","id":"48467","first_name":"Roland"},{"last_name":"Hohloch","full_name":"Hohloch, Stephan","first_name":"Stephan"},{"full_name":"Heinze, Katja","last_name":"Heinze","first_name":"Katja"},{"first_name":"Michael","full_name":"Seitz, Michael","last_name":"Seitz"},{"full_name":"Kühn, Oliver","last_name":"Kühn","first_name":"Oliver"},{"first_name":"Stefan","full_name":"Lochbrunner, Stefan","last_name":"Lochbrunner"},{"id":"47241","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer","first_name":"Matthias"}],"date_updated":"2024-10-11T08:42:44Z","publisher":"Royal Society of Chemistry (RSC)","page":"6640-6643","intvolume":" 57","citation":{"ama":"Dierks P, Kruse A, Bokareva OS, et al. Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes. Chemical Communications. 2021;57(54):6640-6643. doi:10.1039/d1cc01716k","chicago":"Dierks, Philipp, Ayla Kruse, Olga S. Bokareva, Mohammed J. Al-Marri, Jens Kalmbach, Marc Baltrun, Adam Neuba, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric Iron(Ii) Complexes.” Chemical Communications 57, no. 54 (2021): 6640–43. https://doi.org/10.1039/d1cc01716k.","ieee":"P. Dierks et al., “Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes,” Chemical Communications, vol. 57, no. 54, pp. 6640–6643, 2021, doi: 10.1039/d1cc01716k.","short":"P. Dierks, A. Kruse, O.S. Bokareva, M.J. Al-Marri, J. Kalmbach, M. Baltrun, A. Neuba, R. Schoch, S. Hohloch, K. Heinze, M. Seitz, O. Kühn, S. Lochbrunner, M. Bauer, Chemical Communications 57 (2021) 6640–6643.","bibtex":"@article{Dierks_Kruse_Bokareva_Al-Marri_Kalmbach_Baltrun_Neuba_Schoch_Hohloch_Heinze_et al._2021, title={Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes}, volume={57}, DOI={10.1039/d1cc01716k}, number={54}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Dierks, Philipp and Kruse, Ayla and Bokareva, Olga S. and Al-Marri, Mohammed J. and Kalmbach, Jens and Baltrun, Marc and Neuba, Adam and Schoch, Roland and Hohloch, Stephan and Heinze, Katja and et al.}, year={2021}, pages={6640–6643} }","mla":"Dierks, Philipp, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric Iron(Ii) Complexes.” Chemical Communications, vol. 57, no. 54, Royal Society of Chemistry (RSC), 2021, pp. 6640–43, doi:10.1039/d1cc01716k.","apa":"Dierks, P., Kruse, A., Bokareva, O. S., Al-Marri, M. J., Kalmbach, J., Baltrun, M., Neuba, A., Schoch, R., Hohloch, S., Heinze, K., Seitz, M., Kühn, O., Lochbrunner, S., & Bauer, M. (2021). Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes. Chemical Communications, 57(54), 6640–6643. https://doi.org/10.1039/d1cc01716k"},"year":"2021","issue":"54","publication_identifier":{"issn":["1359-7345","1364-548X"]},"publication_status":"published","language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composite","Metallkomplexe","Optical and Magnetic Materials","Catalysis"],"article_type":"original","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41007","status":"public","abstract":[{"text":"Two closely related FeII complexes with 2,6-bis(1-ethyl-1H-1,2,3-triazol-4yl)pyridine and 2,6-bis(1,2,3-triazol-5-ylidene)pyridine ligands are presented to gain new insights into the photophysics of bis(tridentate) iron(II) complexes. The [Fe(N^N^N)2]2+ pseudoisomer sensitizes singlet oxygen through a MC state with nanosecond lifetime after MLCT excitation, while the bis(tridentate) [Fe(C^N^C)2]2+ pseudoisomer possesses a similar 3MLCT lifetime as the tris(bidentate) [Fe(C^C)2(N^N)]2+ complexes with four mesoionic carbenes.","lang":"eng"}],"publication":"Chemical Communications","type":"journal_article"},{"issue":"24","publication_status":"published","publication_identifier":{"issn":["2155-5435","2155-5435"]},"citation":{"mla":"Benedikter, Mathis, et al. “Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis, vol. 10, no. 24, American Chemical Society (ACS), 2020, pp. 14810–23, doi:10.1021/acscatal.0c03978.","bibtex":"@article{Benedikter_Musso_Kesharwani_Sterz_Elser_Ziegler_Fischer_Plietker_Frey_Kästner_et al._2020, title={Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach}, volume={10}, DOI={10.1021/acscatal.0c03978}, number={24}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz, K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker, Bernd and Frey, Wolfgang and Kästner, Johannes and et al.}, year={2020}, pages={14810–14823} }","short":"M. Benedikter, J. Musso, M.K. Kesharwani, K.L. Sterz, I. Elser, F. Ziegler, F. Fischer, B. Plietker, W. Frey, J. Kästner, M. Winkler, J. van Slageren, M. Nowakowski, M. Bauer, M.R. Buchmeiser, ACS Catalysis 10 (2020) 14810–14823.","apa":"Benedikter, M., Musso, J., Kesharwani, M. K., Sterz, K. L., Elser, I., Ziegler, F., Fischer, F., Plietker, B., Frey, W., Kästner, J., Winkler, M., van Slageren, J., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2020). Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis, 10(24), 14810–14823. https://doi.org/10.1021/acscatal.0c03978","chicago":"Benedikter, Mathis, Janis Musso, Manoj K. Kesharwani, K. Leonard Sterz, Iris Elser, Felix Ziegler, Felix Fischer, et al. “Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis 10, no. 24 (2020): 14810–23. https://doi.org/10.1021/acscatal.0c03978.","ieee":"M. Benedikter et al., “Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach,” ACS Catalysis, vol. 10, no. 24, pp. 14810–14823, 2020, doi: 10.1021/acscatal.0c03978.","ama":"Benedikter M, Musso J, Kesharwani MK, et al. Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis. 2020;10(24):14810-14823. doi:10.1021/acscatal.0c03978"},"intvolume":" 10","page":"14810-14823","year":"2020","date_created":"2023-01-30T17:12:11Z","author":[{"first_name":"Mathis","last_name":"Benedikter","full_name":"Benedikter, Mathis"},{"full_name":"Musso, Janis","last_name":"Musso","first_name":"Janis"},{"first_name":"Manoj K.","full_name":"Kesharwani, Manoj K.","last_name":"Kesharwani"},{"last_name":"Sterz","full_name":"Sterz, K. Leonard","first_name":"K. Leonard"},{"first_name":"Iris","full_name":"Elser, Iris","last_name":"Elser"},{"first_name":"Felix","full_name":"Ziegler, Felix","last_name":"Ziegler"},{"full_name":"Fischer, Felix","last_name":"Fischer","first_name":"Felix"},{"full_name":"Plietker, Bernd","last_name":"Plietker","first_name":"Bernd"},{"full_name":"Frey, Wolfgang","last_name":"Frey","first_name":"Wolfgang"},{"full_name":"Kästner, Johannes","last_name":"Kästner","first_name":"Johannes"},{"full_name":"Winkler, Mario","last_name":"Winkler","first_name":"Mario"},{"last_name":"van Slageren","full_name":"van Slageren, Joris","first_name":"Joris"},{"first_name":"Michał","orcid":"0000-0002-3734-7011","last_name":"Nowakowski","full_name":"Nowakowski, Michał","id":"78878"},{"first_name":"Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","id":"47241","full_name":"Bauer, Matthias"},{"first_name":"Michael R.","full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser"}],"volume":10,"date_updated":"2024-05-07T11:42:56Z","publisher":"American Chemical Society (ACS)","doi":"10.1021/acscatal.0c03978","title":"Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach","type":"journal_article","publication":"ACS Catalysis","status":"public","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"41015","language":[{"iso":"eng"}],"keyword":["Catalysis","General Chemistry"]},{"title":"Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes","date_created":"2023-01-30T17:35:14Z","publisher":"Wiley","year":"2020","issue":"21","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"publication":"ChemCatChem","doi":"10.1002/cctc.202000994","volume":12,"author":[{"full_name":"Gregori, Bernhard J.","last_name":"Gregori","first_name":"Bernhard J."},{"last_name":"Nowakowski","orcid":"0000-0002-3734-7011","full_name":"Nowakowski, Michał","id":"78878","first_name":"Michał"},{"first_name":"Anke","id":"27611","full_name":"Schoch, Anke","last_name":"Schoch","orcid":"0000-0002-9457-400X"},{"full_name":"Pöllath, Simon","last_name":"Pöllath","first_name":"Simon"},{"last_name":"Zweck","full_name":"Zweck, Josef","first_name":"Josef"},{"last_name":"Bauer","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"},{"first_name":"Axel","last_name":"Jacobi von Wangelin","full_name":"Jacobi von Wangelin, Axel"}],"date_updated":"2024-05-07T11:40:10Z","page":"5359-5363","intvolume":" 12","citation":{"chicago":"Gregori, Bernhard J., Michał Nowakowski, Anke Schoch, Simon Pöllath, Josef Zweck, Matthias Bauer, and Axel Jacobi von Wangelin. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes.” ChemCatChem 12, no. 21 (2020): 5359–63. https://doi.org/10.1002/cctc.202000994.","ieee":"B. J. Gregori et al., “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes,” ChemCatChem, vol. 12, no. 21, pp. 5359–5363, 2020, doi: 10.1002/cctc.202000994.","ama":"Gregori BJ, Nowakowski M, Schoch A, et al. Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes. ChemCatChem. 2020;12(21):5359-5363. doi:10.1002/cctc.202000994","short":"B.J. Gregori, M. Nowakowski, A. Schoch, S. Pöllath, J. Zweck, M. Bauer, A. Jacobi von Wangelin, ChemCatChem 12 (2020) 5359–5363.","mla":"Gregori, Bernhard J., et al. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes.” ChemCatChem, vol. 12, no. 21, Wiley, 2020, pp. 5359–63, doi:10.1002/cctc.202000994.","bibtex":"@article{Gregori_Nowakowski_Schoch_Pöllath_Zweck_Bauer_Jacobi von Wangelin_2020, title={Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}, volume={12}, DOI={10.1002/cctc.202000994}, number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Gregori, Bernhard J. and Nowakowski, Michał and Schoch, Anke and Pöllath, Simon and Zweck, Josef and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2020}, pages={5359–5363} }","apa":"Gregori, B. J., Nowakowski, M., Schoch, A., Pöllath, S., Zweck, J., Bauer, M., & Jacobi von Wangelin, A. (2020). Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes. ChemCatChem, 12(21), 5359–5363. https://doi.org/10.1002/cctc.202000994"},"publication_identifier":{"issn":["1867-3880","1867-3899"]},"publication_status":"published","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41020","status":"public","type":"journal_article"},{"page":"15800-15813","intvolume":" 12","citation":{"mla":"Prinz, Nils, et al. “Hard X-Ray-Based Techniques for Structural Investigations of CO2 Methanation Catalysts Prepared by MOF Decomposition.” Nanoscale, vol. 12, no. 29, Royal Society of Chemistry (RSC), 2020, pp. 15800–13, doi:10.1039/d0nr01750g.","bibtex":"@article{Prinz_Schwensow_Strübbe_Jentys_Bauer_Kleist_Zobel_2020, title={Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition}, volume={12}, DOI={10.1039/d0nr01750g}, number={29}, journal={Nanoscale}, publisher={Royal Society of Chemistry (RSC)}, author={Prinz, Nils and Schwensow, Leif and Strübbe, Sven and Jentys, Andreas and Bauer, Matthias and Kleist, Wolfgang and Zobel, Mirijam}, year={2020}, pages={15800–15813} }","short":"N. Prinz, L. Schwensow, S. Strübbe, A. Jentys, M. Bauer, W. Kleist, M. Zobel, Nanoscale 12 (2020) 15800–15813.","apa":"Prinz, N., Schwensow, L., Strübbe, S., Jentys, A., Bauer, M., Kleist, W., & Zobel, M. (2020). Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition. Nanoscale, 12(29), 15800–15813. https://doi.org/10.1039/d0nr01750g","ieee":"N. Prinz et al., “Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition,” Nanoscale, vol. 12, no. 29, pp. 15800–15813, 2020, doi: 10.1039/d0nr01750g.","chicago":"Prinz, Nils, Leif Schwensow, Sven Strübbe, Andreas Jentys, Matthias Bauer, Wolfgang Kleist, and Mirijam Zobel. “Hard X-Ray-Based Techniques for Structural Investigations of CO2 Methanation Catalysts Prepared by MOF Decomposition.” Nanoscale 12, no. 29 (2020): 15800–813. https://doi.org/10.1039/d0nr01750g.","ama":"Prinz N, Schwensow L, Strübbe S, et al. Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition. Nanoscale. 2020;12(29):15800-15813. doi:10.1039/d0nr01750g"},"year":"2020","issue":"29","publication_identifier":{"issn":["2040-3364","2040-3372"]},"publication_status":"published","doi":"10.1039/d0nr01750g","title":"Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition","volume":12,"author":[{"full_name":"Prinz, Nils","last_name":"Prinz","first_name":"Nils"},{"first_name":"Leif","last_name":"Schwensow","full_name":"Schwensow, Leif"},{"first_name":"Sven","last_name":"Strübbe","full_name":"Strübbe, Sven","id":"76968"},{"first_name":"Andreas","last_name":"Jentys","full_name":"Jentys, Andreas"},{"first_name":"Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241"},{"last_name":"Kleist","full_name":"Kleist, Wolfgang","first_name":"Wolfgang"},{"first_name":"Mirijam","full_name":"Zobel, Mirijam","last_name":"Zobel"}],"date_created":"2023-01-30T17:47:17Z","publisher":"Royal Society of Chemistry (RSC)","date_updated":"2025-08-15T12:43:52Z","status":"public","abstract":[{"lang":"eng","text":"We investigate the structure-activity correlations of methanation catalysts obtained by thermal decomposition of a Ni-based metal-organic framework, using pair distribution function, X-ray absorption spectroscopy and X-ray diffraction."}],"publication":"Nanoscale","type":"journal_article","language":[{"iso":"eng"}],"keyword":["Xray","Catalysis"],"department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41025"}]