@article{59616,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub> is reported and applied in reactions with arenes, allylic, vinylic and acetylenic silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>}},
  author       = {{Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan}},
  issn         = {{1615-4150}},
  journal      = {{Advanced Synthesis &amp; Catalysis}},
  keywords     = {{fluoride, bond activation, borane, Lewis acid, C-C bond formation}},
  number       = {{13}},
  pages        = {{2933--2938}},
  publisher    = {{Wiley}},
  title        = {{{Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds}}},
  doi          = {{10.1002/adsc.202400511}},
  volume       = {{366}},
  year         = {{2024}},
}

@article{59617,
  abstract     = {{<jats:p>There is an increasing interest in sensing applications for a variety of analytes in aqueous environments, as conventional methods do not work reliably under humid conditions or they require complex equipment with experienced operators. Hydrogel sensors are easy to fabricate, are incredibly sensitive, and have broad dynamic ranges. Experiments on their robustness, reliability, and reusability have indicated the possible long-term applications of these systems in a variety of fields, including disease diagnosis, detection of pharmaceuticals, and in environmental testing. It is possible to produce hydrogels, which, upon sensing a specific analyte, can adsorb it onto their 3D-structure and can therefore be used to remove them from a given environment. High specificity can be obtained by using molecularly imprinted polymers. Typical detection principles involve optical methods including fluorescence and chemiluminescence, and volume changes in colloidal photonic crystals, as well as electrochemical methods. Here, we explore the current research utilizing hydrogel-based sensors in three main areas: (1) biomedical applications, (2) for detecting and quantifying pharmaceuticals of interest, and (3) detecting and quantifying environmental contaminants in aqueous environments.</jats:p>}},
  author       = {{Völlmecke, Katharina and Afroz, Rowshon and Bierbach, Sascha and Brenker, Lee Josephine and Frücht, Sebastian and Glass, Alexandra and Giebelhaus, Ryland and Hoppe, Axel and Kanemaru, Karen and Lazarek, Michal and Rabbe, Lukas and Song, Longfei and Velasco Suarez, Andrea and Wu, Shuang and Serpe, Michael and Kuckling, Dirk}},
  issn         = {{2310-2861}},
  journal      = {{Gels}},
  number       = {{12}},
  publisher    = {{MDPI AG}},
  title        = {{{Hydrogel-Based Biosensors}}},
  doi          = {{10.3390/gels8120768}},
  volume       = {{8}},
  year         = {{2022}},
}

@article{59619,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>A frustrated Lewis pair‐catalyzed hydroboration of aromatic and aliphatic nitriles was developed. The catalyst provides the primary amines in high yields of 77–99% with catalyst loading as low as 2 mol%. The reaction displays high functional group tolerance towards esters, amides, nitro groups and aliphatic halides. The addition of the diborylated amines to ethyl 3‐phenylpropiolate proceeds with Z‐selectivity with d.r. of &gt;99:1 in 77–90% yield over two steps. The reaction mechanism was investigated by control and computational experiments.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/png" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/adsc202200525-toc-0001-m.png"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text>
</jats:p>}},
  author       = {{Sieland, Benedikt and Hoppe, Axel and Stepen, Arne J. and Paradies, Jan}},
  issn         = {{1615-4150}},
  journal      = {{Advanced Synthesis &amp; Catalysis}},
  keywords     = {{hydroboration, nitrile, amine, frustrated Lewis pair, density functional theory}},
  number       = {{18}},
  pages        = {{3143--3148}},
  publisher    = {{Wiley}},
  title        = {{{Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis}}},
  doi          = {{10.1002/adsc.202200525}},
  volume       = {{364}},
  year         = {{2022}},
}

@article{59620,
  author       = {{Rust, Tarik and Jung, Dimitri and Hoppe, Axel and Schoppa, Timo and Langer, Klaus and Kuckling, Dirk}},
  issn         = {{2637-6105}},
  journal      = {{ACS Applied Polymer Materials}},
  keywords     = {{backbone-degradable, light-responsive, redox-responsive, drug delivery, nanoparticles}},
  number       = {{8}},
  pages        = {{3831--3842}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Backbone-Degradable (Co-)Polymers for Light-Triggered Drug Delivery}}},
  doi          = {{10.1021/acsapm.1c00411}},
  volume       = {{3}},
  year         = {{2021}},
}