[{"user_id":"89271","volume":23,"page":"4852-4857","_id":"37945","publisher":"Royal Society of Chemistry (RSC)","status":"public","citation":{"ieee":"J. Tönjes, L. Longwitz, and T. Werner, “Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction,” <i>Green Chemistry</i>, vol. 23, no. 13, pp. 4852–4857, 2021, doi: <a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>.","apa":"Tönjes, J., Longwitz, L., &#38; Werner, T. (2021). Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction. <i>Green Chemistry</i>, <i>23</i>(13), 4852–4857. <a href=\"https://doi.org/10.1039/d1gc00953b\">https://doi.org/10.1039/d1gc00953b</a>","mla":"Tönjes, Jan, et al. “Poly(Methylhydrosiloxane) as a Reductant in the Catalytic Base-Free Wittig Reaction.” <i>Green Chemistry</i>, vol. 23, no. 13, Royal Society of Chemistry (RSC), 2021, pp. 4852–57, doi:<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>.","bibtex":"@article{Tönjes_Longwitz_Werner_2021, title={Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction}, volume={23}, DOI={<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>}, number={13}, journal={Green Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Tönjes, Jan and Longwitz, Lars and Werner, Thomas}, year={2021}, pages={4852–4857} }","chicago":"Tönjes, Jan, Lars Longwitz, and Thomas Werner. “Poly(Methylhydrosiloxane) as a Reductant in the Catalytic Base-Free Wittig Reaction.” <i>Green Chemistry</i> 23, no. 13 (2021): 4852–57. <a href=\"https://doi.org/10.1039/d1gc00953b\">https://doi.org/10.1039/d1gc00953b</a>.","ama":"Tönjes J, Longwitz L, Werner T. Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction. <i>Green Chemistry</i>. 2021;23(13):4852-4857. doi:<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>","short":"J. Tönjes, L. Longwitz, T. Werner, Green Chemistry 23 (2021) 4852–4857."},"doi":"10.1039/d1gc00953b","language":[{"iso":"eng"}],"date_updated":"2025-11-10T08:48:01Z","publication_status":"published","intvolume":"        23","year":"2021","title":"Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction","publication_identifier":{"issn":["1463-9262","1463-9270"]},"author":[{"last_name":"Tönjes","first_name":"Jan","full_name":"Tönjes, Jan"},{"full_name":"Longwitz, Lars","last_name":"Longwitz","first_name":"Lars"},{"full_name":"Werner, Thomas","orcid":"0000-0001-9025-3244","last_name":"Werner","first_name":"Thomas","id":"89271"}],"keyword":["T2","CSSD"],"type":"journal_article","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"date_created":"2023-01-22T20:25:13Z","abstract":[{"lang":"eng","text":"<p>PMHS proved to be a suitable terminal reductant for P(<sc>iii</sc>)/P(<sc>v</sc>) redox cycling with a methyl-substituted phosphetane as catalyst and BuOAc as solvent. The formation of water by silanol condensation was identified as main pathway of siloxane formation.</p>"}],"publication":"Green Chemistry","issue":"13"},{"publication":"Organic Process Research &amp; Development","issue":"1","type":"journal_article","keyword":["T4","CSSD"],"department":[{"_id":"35"},{"_id":"2"}],"date_created":"2025-11-05T15:26:05Z","publication_status":"published","date_updated":"2025-11-10T08:48:33Z","intvolume":"        25","title":"Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant","year":"2021","publication_identifier":{"issn":["1083-6160","1520-586X"]},"author":[{"full_name":"Stefanow, Vivian","first_name":"Vivian","last_name":"Stefanow"},{"full_name":"Grandane, Aiga","last_name":"Grandane","first_name":"Aiga"},{"last_name":"Eh","first_name":"Marcus","full_name":"Eh, Marcus"},{"full_name":"Panten, Johannes","first_name":"Johannes","last_name":"Panten"},{"first_name":"Anke","last_name":"Spannenberg","full_name":"Spannenberg, Anke"},{"id":"89271","last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244","full_name":"Werner, Thomas"}],"doi":"10.1021/acs.oprd.0c00423","language":[{"iso":"eng"}],"citation":{"short":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, T. Werner, Organic Process Research &#38;amp; Development 25 (2021) 89–97.","chicago":"Stefanow, Vivian, Aiga Grandane, Marcus Eh, Johannes Panten, Anke Spannenberg, and Thomas Werner. “Stereoselective Synthesis of a<i>Cis</i>-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” <i>Organic Process Research &#38;amp; Development</i> 25, no. 1 (2021): 89–97. <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">https://doi.org/10.1021/acs.oprd.0c00423</a>.","ieee":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, and T. Werner, “Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant,” <i>Organic Process Research &#38;amp; Development</i>, vol. 25, no. 1, pp. 89–97, 2021, doi: <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>.","apa":"Stefanow, V., Grandane, A., Eh, M., Panten, J., Spannenberg, A., &#38; Werner, T. (2021). Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. <i>Organic Process Research &#38;amp; Development</i>, <i>25</i>(1), 89–97. <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">https://doi.org/10.1021/acs.oprd.0c00423</a>","bibtex":"@article{Stefanow_Grandane_Eh_Panten_Spannenberg_Werner_2021, title={Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant}, volume={25}, DOI={<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>}, number={1}, journal={Organic Process Research &#38;amp; Development}, publisher={American Chemical Society (ACS)}, author={Stefanow, Vivian and Grandane, Aiga and Eh, Marcus and Panten, Johannes and Spannenberg, Anke and Werner, Thomas}, year={2021}, pages={89–97} }","ama":"Stefanow V, Grandane A, Eh M, Panten J, Spannenberg A, Werner T. Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. <i>Organic Process Research &#38;amp; Development</i>. 2021;25(1):89-97. doi:<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>","mla":"Stefanow, Vivian, et al. “Stereoselective Synthesis of a<i>Cis</i>-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” <i>Organic Process Research &#38;amp; Development</i>, vol. 25, no. 1, American Chemical Society (ACS), 2021, pp. 89–97, doi:<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>."},"status":"public","user_id":"89271","volume":25,"page":"89-97","_id":"62098","publisher":"American Chemical Society (ACS)"},{"status":"public","user_id":"89271","volume":25,"page":"89-97","_id":"62099","publisher":"American Chemical Society (ACS)","citation":{"ieee":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, and T. Werner, “Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant,” <i>Organic Process Research &#38;amp; Development</i>, vol. 25, no. 1, pp. 89–97, 2021, doi: <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>.","apa":"Stefanow, V., Grandane, A., Eh, M., Panten, J., Spannenberg, A., &#38; Werner, T. (2021). Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. <i>Organic Process Research &#38;amp; Development</i>, <i>25</i>(1), 89–97. <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">https://doi.org/10.1021/acs.oprd.0c00423</a>","short":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, T. Werner, Organic Process Research &#38;amp; Development 25 (2021) 89–97.","chicago":"Stefanow, Vivian, Aiga Grandane, Marcus Eh, Johannes Panten, Anke Spannenberg, and Thomas Werner. “Stereoselective Synthesis of a<i>Cis</i>-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” <i>Organic Process Research &#38;amp; Development</i> 25, no. 1 (2021): 89–97. <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">https://doi.org/10.1021/acs.oprd.0c00423</a>.","mla":"Stefanow, Vivian, et al. “Stereoselective Synthesis of a<i>Cis</i>-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” <i>Organic Process Research &#38;amp; Development</i>, vol. 25, no. 1, American Chemical Society (ACS), 2021, pp. 89–97, doi:<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>.","bibtex":"@article{Stefanow_Grandane_Eh_Panten_Spannenberg_Werner_2021, title={Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant}, volume={25}, DOI={<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>}, number={1}, journal={Organic Process Research &#38;amp; Development}, publisher={American Chemical Society (ACS)}, author={Stefanow, Vivian and Grandane, Aiga and Eh, Marcus and Panten, Johannes and Spannenberg, Anke and Werner, Thomas}, year={2021}, pages={89–97} }","ama":"Stefanow V, Grandane A, Eh M, Panten J, Spannenberg A, Werner T. Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. <i>Organic Process Research &#38;amp; Development</i>. 2021;25(1):89-97. doi:<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>"},"publication_status":"published","date_updated":"2025-11-10T08:49:27Z","intvolume":"        25","year":"2021","title":"Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant","publication_identifier":{"issn":["1083-6160","1520-586X"]},"author":[{"first_name":"Vivian","last_name":"Stefanow","full_name":"Stefanow, Vivian"},{"last_name":"Grandane","first_name":"Aiga","full_name":"Grandane, Aiga"},{"last_name":"Eh","first_name":"Marcus","full_name":"Eh, Marcus"},{"last_name":"Panten","first_name":"Johannes","full_name":"Panten, Johannes"},{"full_name":"Spannenberg, Anke","last_name":"Spannenberg","first_name":"Anke"},{"last_name":"Werner","orcid":"0000-0001-9025-3244","first_name":"Thomas","full_name":"Werner, Thomas","id":"89271"}],"doi":"10.1021/acs.oprd.0c00423","language":[{"iso":"eng"}],"issue":"1","publication":"Organic Process Research &amp; Development","type":"journal_article","keyword":["T4","CSSD"],"department":[{"_id":"35"},{"_id":"2"}],"date_created":"2025-11-05T15:28:23Z"},{"citation":{"ama":"Wirth MA, Longwitz L, Kanwischer M, Gros P, Leinweber P, Werner T. AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate. <i>Ecotoxicology and Environmental Safety</i>. 2021;225. doi:<a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">10.1016/j.ecoenv.2021.112768</a>","bibtex":"@article{Wirth_Longwitz_Kanwischer_Gros_Leinweber_Werner_2021, title={AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate}, volume={225}, DOI={<a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">10.1016/j.ecoenv.2021.112768</a>}, number={112768}, journal={Ecotoxicology and Environmental Safety}, publisher={Elsevier BV}, author={Wirth, Marisa A. and Longwitz, Lars and Kanwischer, Marion and Gros, Peter and Leinweber, Peter and Werner, Thomas}, year={2021} }","mla":"Wirth, Marisa A., et al. “AMPA-15N – Synthesis and Application as Standard Compound in Traceable Degradation Studies of Glyphosate.” <i>Ecotoxicology and Environmental Safety</i>, vol. 225, 112768, Elsevier BV, 2021, doi:<a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">10.1016/j.ecoenv.2021.112768</a>.","short":"M.A. Wirth, L. Longwitz, M. Kanwischer, P. Gros, P. Leinweber, T. Werner, Ecotoxicology and Environmental Safety 225 (2021).","chicago":"Wirth, Marisa A., Lars Longwitz, Marion Kanwischer, Peter Gros, Peter Leinweber, and Thomas Werner. “AMPA-15N – Synthesis and Application as Standard Compound in Traceable Degradation Studies of Glyphosate.” <i>Ecotoxicology and Environmental Safety</i> 225 (2021). <a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">https://doi.org/10.1016/j.ecoenv.2021.112768</a>.","apa":"Wirth, M. A., Longwitz, L., Kanwischer, M., Gros, P., Leinweber, P., &#38; Werner, T. (2021). AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate. <i>Ecotoxicology and Environmental Safety</i>, <i>225</i>, Article 112768. <a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">https://doi.org/10.1016/j.ecoenv.2021.112768</a>","ieee":"M. A. Wirth, L. Longwitz, M. Kanwischer, P. Gros, P. Leinweber, and T. Werner, “AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate,” <i>Ecotoxicology and Environmental Safety</i>, vol. 225, Art. no. 112768, 2021, doi: <a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">10.1016/j.ecoenv.2021.112768</a>."},"status":"public","volume":225,"user_id":"89271","publisher":"Elsevier BV","_id":"37943","publication":"Ecotoxicology and Environmental Safety","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["T4","CSSD"],"type":"journal_article","date_created":"2023-01-22T20:23:06Z","intvolume":"       225","date_updated":"2025-11-10T08:48:20Z","publication_status":"published","publication_identifier":{"issn":["0147-6513"]},"author":[{"full_name":"Wirth, Marisa A.","first_name":"Marisa A.","last_name":"Wirth"},{"first_name":"Lars","last_name":"Longwitz","full_name":"Longwitz, Lars"},{"last_name":"Kanwischer","first_name":"Marion","full_name":"Kanwischer, Marion"},{"full_name":"Gros, Peter","first_name":"Peter","last_name":"Gros"},{"last_name":"Leinweber","first_name":"Peter","full_name":"Leinweber, Peter"},{"first_name":"Thomas","last_name":"Werner","orcid":"https://orcid.org/0000-0001-9025-3244","full_name":"Werner, Thomas","id":"89271"}],"title":"AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate","year":"2021","doi":"10.1016/j.ecoenv.2021.112768","language":[{"iso":"eng"}],"article_number":"112768"},{"status":"public","page":"1096-1104","_id":"37948","publisher":"Wiley","user_id":"89271","volume":363,"citation":{"bibtex":"@article{Liu_Werner_2021, title={Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides}, volume={363}, DOI={<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>}, number={4}, journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Liu, Xin and Werner, Thomas}, year={2021}, pages={1096–1104} }","ama":"Liu X, Werner T. Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides. <i>Advanced Synthesis and Catalysis</i>. 2021;363(4):1096-1104. doi:<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>","mla":"Liu, Xin, and Thomas Werner. “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides.” <i>Advanced Synthesis and Catalysis</i>, vol. 363, no. 4, Wiley, 2021, pp. 1096–104, doi:<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>.","chicago":"Liu, Xin, and Thomas Werner. “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides.” <i>Advanced Synthesis and Catalysis</i> 363, no. 4 (2021): 1096–1104. <a href=\"https://doi.org/10.1002/adsc.202001209\">https://doi.org/10.1002/adsc.202001209</a>.","short":"X. Liu, T. Werner, Advanced Synthesis and Catalysis 363 (2021) 1096–1104.","ieee":"X. Liu and T. Werner, “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides,” <i>Advanced Synthesis and Catalysis</i>, vol. 363, no. 4, pp. 1096–1104, 2021, doi: <a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>.","apa":"Liu, X., &#38; Werner, T. (2021). Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides. <i>Advanced Synthesis and Catalysis</i>, <i>363</i>(4), 1096–1104. <a href=\"https://doi.org/10.1002/adsc.202001209\">https://doi.org/10.1002/adsc.202001209</a>"},"title":"Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides","year":"2021","author":[{"full_name":"Liu, Xin","first_name":"Xin","last_name":"Liu"},{"id":"89271","first_name":"Thomas","last_name":"Werner","orcid":"https://orcid.org/0000-0001-9025-3244","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"date_updated":"2025-11-10T08:48:47Z","publication_status":"published","intvolume":"       363","language":[{"iso":"eng"}],"doi":"10.1002/adsc.202001209","issue":"4","publication":"Advanced Synthesis and Catalysis","extern":"1","date_created":"2023-01-22T20:30:29Z","keyword":["T1","T3","CSSD"],"type":"journal_article","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}]},{"status":"public","user_id":"89271","volume":132,"page":"2782-2785","_id":"62101","publisher":"Wiley","citation":{"mla":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie</i>, vol. 132, no. 7, Wiley, 2020, pp. 2782–85, doi:<a href=\"https://doi.org/10.1002/ange.201912991\">10.1002/ange.201912991</a>.","bibtex":"@article{Longwitz_Werner_2020, title={Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis}, volume={132}, DOI={<a href=\"https://doi.org/10.1002/ange.201912991\">10.1002/ange.201912991</a>}, number={7}, journal={Angewandte Chemie}, publisher={Wiley}, author={Longwitz, Lars and Werner, Thomas}, year={2020}, pages={2782–2785} }","ama":"Longwitz L, Werner T. Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis. <i>Angewandte Chemie</i>. 2020;132(7):2782-2785. doi:<a href=\"https://doi.org/10.1002/ange.201912991\">10.1002/ange.201912991</a>","ieee":"L. Longwitz and T. Werner, “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis,” <i>Angewandte Chemie</i>, vol. 132, no. 7, pp. 2782–2785, 2020, doi: <a href=\"https://doi.org/10.1002/ange.201912991\">10.1002/ange.201912991</a>.","apa":"Longwitz, L., &#38; Werner, T. (2020). Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis. <i>Angewandte Chemie</i>, <i>132</i>(7), 2782–2785. <a href=\"https://doi.org/10.1002/ange.201912991\">https://doi.org/10.1002/ange.201912991</a>","short":"L. Longwitz, T. Werner, Angewandte Chemie 132 (2020) 2782–2785.","chicago":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie</i> 132, no. 7 (2020): 2782–85. <a href=\"https://doi.org/10.1002/ange.201912991\">https://doi.org/10.1002/ange.201912991</a>."},"publication_status":"published","date_updated":"2025-11-10T08:11:23Z","intvolume":"       132","year":"2020","title":"Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis","author":[{"last_name":"Longwitz","first_name":"Lars","full_name":"Longwitz, Lars"},{"id":"89271","orcid":"0000-0001-9025-3244","last_name":"Werner","first_name":"Thomas","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["0044-8249","1521-3757"]},"doi":"10.1002/ange.201912991","language":[{"iso":"eng"}],"abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>The carbon–carbon double bond of unsaturated carbonyl compounds was readily reduced by using a phosphetane oxide catalyst in the presence of a simple organosilane as the terminal reductant and water as the hydrogen source. Quantitative hydrogenation was observed when 1.0 mol % of a methyl‐substituted phosphetane oxide was employed as the catalyst. The procedure is highly selective towards activated double bonds, tolerating a variety of functional groups that are usually prone to reduction. In total, 25 alkenes and two alkynes were hydrogenated to the corresponding alkanes in excellent yields of up to 99 %. Notably, less active poly(methylhydrosiloxane) could also be utilized as the terminal reductant. Mechanistic investigations revealed the phosphane as the catalyst resting state and a protonation/deprotonation sequence as the crucial step in the catalytic cycle.</jats:p>"}],"issue":"7","publication":"Angewandte Chemie","type":"journal_article","keyword":["T2","T4"],"department":[{"_id":"35"},{"_id":"2"}],"date_created":"2025-11-05T15:39:06Z"},{"keyword":["T4"],"type":"patent","department":[{"_id":"35"},{"_id":"2"}],"date_created":"2025-11-10T08:09:42Z","ipc":"-","citation":{"ieee":"T. Werner, V. Stefanow, A. Grandane, J. Panten, and M. Eh, “Novel processes for preparing cis-cedrandiol.” 2020.","apa":"Werner, T., Stefanow, V., Grandane, A., Panten, J., &#38; Eh, M. (2020). <i>Novel processes for preparing cis-cedrandiol</i>.","chicago":"Werner, Thomas, V. Stefanow, A. Grandane, J. Panten, and M. Eh. “Novel Processes for Preparing Cis-Cedrandiol,” 2020.","short":"T. Werner, V. Stefanow, A. Grandane, J. Panten, M. Eh, (2020).","mla":"Werner, Thomas, et al. <i>Novel Processes for Preparing Cis-Cedrandiol</i>. 2020.","bibtex":"@article{Werner_Stefanow_Grandane_Panten_Eh_2020, title={Novel processes for preparing cis-cedrandiol}, author={Werner, Thomas and Stefanow, V. and Grandane, A. and Panten, J. and Eh, M.}, year={2020} }","ama":"Werner T, Stefanow V, Grandane A, Panten J, Eh M. Novel processes for preparing cis-cedrandiol. 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Quantitative hydrogenation was observed when 1.0 mol % of a methyl‐substituted phosphetane oxide was employed as the catalyst. The procedure is highly selective towards activated double bonds, tolerating a variety of functional groups that are usually prone to reduction. In total, 25 alkenes and two alkynes were hydrogenated to the corresponding alkanes in excellent yields of up to 99 %. Notably, less active poly(methylhydrosiloxane) could also be utilized as the terminal reductant. Mechanistic investigations revealed the phosphane as the catalyst resting state and a protonation/deprotonation sequence as the crucial step in the catalytic cycle.</jats:p>"}],"issue":"7","publication":"Angewandte Chemie International Edition","user_id":"89271","volume":59,"page":"2760-2763","publisher":"Wiley","_id":"62102","status":"public","citation":{"mla":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 7, Wiley, 2020, pp. 2760–63, doi:<a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>.","bibtex":"@article{Longwitz_Werner_2020, title={Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis}, volume={59}, DOI={<a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>}, number={7}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Longwitz, Lars and Werner, Thomas}, year={2020}, pages={2760–2763} }","ama":"Longwitz L, Werner T. 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