@article{62090,
  abstract     = {{<jats:p>The selective <jats:italic>N</jats:italic>-formylation and <jats:italic>N</jats:italic>-methylation of amines with carbon dioxide (CO<jats:sub>2</jats:sub>) catalyzed by methyltriphenylphosphonium methylcarbonate and tuned by polymethylhydrosiloxane or trimethoxysilane as reducing agents is reported.</jats:p>}},
  author       = {{Ren, Changyue and Terazzi, Constanza and Werner, Thomas}},
  issn         = {{1463-9262}},
  journal      = {{Green Chemistry}},
  keywords     = {{T1, T2, CSSD}},
  number       = {{1}},
  pages        = {{439--447}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Tuneable reduction of CO<sub>2</sub> – organocatalyzed selective formylation and methylation of amines}}},
  doi          = {{10.1039/d3gc03993e}},
  volume       = {{26}},
  year         = {{2024}},
}

@article{62091,
  author       = {{Ren, Changyue and Spannenberg, Anke and Werner, Thomas}},
  issn         = {{2168-0485}},
  journal      = {{ACS Sustainable Chemistry &amp; Engineering}},
  keywords     = {{T1, T2, CSSD}},
  number       = {{29}},
  pages        = {{10969--10977}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>}}},
  doi          = {{10.1021/acssuschemeng.4c03464}},
  volume       = {{12}},
  year         = {{2024}},
}

@article{62096,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>The biocatalytic kinetic resolution of cyclic carbonates derived from glycerol is reported. A selection of 26 esterases and lipases was tested for the asymmetric hydrolysis of the model substrate (epichlorohydrin carbonate) in aqueous medium. Among them, Pig Liver Esterase and Novozym® 435 showed the best selectivity with <jats:italic>E</jats:italic>=38 and 49, respectively. Both enzymes were employed for the conversion of 12 glycerol derivatives under optimized conditions. The resolution of halogenated carbonates afforded the unconverted enantiomer in up to &gt;99 : 1 <jats:italic>er</jats:italic>. Furthermore, Novozym® 435 was successfully recycled 10 times without significant loss of activity. Upscaling and isolation of the chiral carbonate was also demonstrated. Subsequent conversion of this chiral building block allowed the direct one‐pot synthesis of (<jats:italic>S</jats:italic>)‐Guaifenesin, (<jats:italic>S</jats:italic>)‐Mephenesin and (<jats:italic>S</jats:italic>)‐Chlorphenesin in up to 89 % yield and 94 : 6 <jats:italic>er</jats:italic>.</jats:p>}},
  author       = {{Terazzi, Constanza and Spannenberg, Anke and von Langermann, Jan and Werner, Thomas}},
  issn         = {{1867-3880}},
  journal      = {{ChemCatChem}},
  keywords     = {{T1, T4, CSSD}},
  number       = {{19}},
  publisher    = {{Wiley}},
  title        = {{{Chemoenzymatic Synthesis of Chiral Building Blocks Based on the Kinetic Resolution of Glycerol‐Derived Cyclic Carbonates}}},
  doi          = {{10.1002/cctc.202300917}},
  volume       = {{15}},
  year         = {{2023}},
}

@article{37938,
  author       = {{Terazzi, Constanza and Laatz, Karoline and von Langermann, Jan and Werner, Thomas}},
  issn         = {{2168-0485}},
  journal      = {{ACS Sustainable Chemistry and Engineering}},
  keywords     = {{T1, T3, CSSD}},
  number       = {{40}},
  pages        = {{13335--13342}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Synthesis of Cyclic Carbonates Catalyzed by CaI<sub>2</sub>–Et<sub>3</sub>N and Studies on Their Biocatalytic Kinetic Resolution}}},
  doi          = {{10.1021/acssuschemeng.2c03210}},
  volume       = {{10}},
  year         = {{2022}},
}

@article{37940,
  author       = {{Ren, Changyue and Spannenberg, Anke and Werner, Thomas}},
  issn         = {{2193-5807}},
  journal      = {{Asian Journal of Organic Chemistry}},
  keywords     = {{T1, T2, CSSD}},
  number       = {{9}},
  publisher    = {{Wiley}},
  title        = {{{Synthesis of Bifunctional Phosphonium Salts Bearing Perfluorinated Side Chains and Their Application in the Synthesis of Cyclic Carbonates from Epoxides and CO            <sub>2</sub>}}},
  doi          = {{10.1002/ajoc.202200156}},
  volume       = {{11}},
  year         = {{2022}},
}

@article{37950,
  author       = {{Hu, Yuya and Wei, Zhihong and Frey, Anna and Kubis, Christoph and Ren, Chang‐Yue and Spannenberg, Anke and Jiao, Haijun and Werner, Thomas}},
  issn         = {{1864-5631}},
  journal      = {{ChemSusChem}},
  keywords     = {{T1}},
  number       = {{1}},
  pages        = {{363--372}},
  publisher    = {{Wiley}},
  title        = {{{Catalytic, Kinetic, and Mechanistic Insights into the Fixation of CO<sub>2</sub> with Epoxides Catalyzed by Phenol‐Functionalized Phosphonium Salts}}},
  doi          = {{10.1002/cssc.202002267}},
  volume       = {{14}},
  year         = {{2021}},
}

@article{37944,
  abstract     = {{<p>A Mn–PNP complex proved to be a suitable catalyst for the transfer hydrogenation of amides, carbamates, urea derivatives and even polyurethanes.</p>}},
  author       = {{Liu, Xin and Werner, Thomas}},
  issn         = {{2041-6520}},
  journal      = {{Chemical Science}},
  keywords     = {{T1, T3, CSSD}},
  number       = {{31}},
  pages        = {{10590--10597}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Indirect reduction of CO<sub>2</sub> and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes}}},
  doi          = {{10.1039/d1sc02663a}},
  volume       = {{12}},
  year         = {{2021}},
}

@article{37948,
  author       = {{Liu, Xin and Werner, Thomas}},
  issn         = {{1615-4150}},
  journal      = {{Advanced Synthesis and Catalysis}},
  keywords     = {{T1, T3, CSSD}},
  number       = {{4}},
  pages        = {{1096--1104}},
  publisher    = {{Wiley}},
  title        = {{{Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides}}},
  doi          = {{10.1002/adsc.202001209}},
  volume       = {{363}},
  year         = {{2021}},
}

@article{37955,
  author       = {{Wulf, Christoph and Reckers, Matthias and Perechodjuk, Anna and Werner, Thomas}},
  issn         = {{2168-0485}},
  journal      = {{ACS Sustainable Chemistry and Engineering}},
  keywords     = {{T1, T3, CSSD}},
  number       = {{3}},
  pages        = {{1651--1658}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Catalytic Systems for the Synthesis of Biscarbonates and Their Impact on the Sequential Preparation of Non-Isocyanate Polyurethanes}}},
  doi          = {{10.1021/acssuschemeng.9b06662}},
  volume       = {{8}},
  year         = {{2020}},
}

@article{37953,
  author       = {{Hu, Yuya and Peglow, Sandra and Longwitz, Lars and Frank, Marcus and Epping, Jan Dirk and Brüser, Volker and Werner, Thomas}},
  issn         = {{1864-5631}},
  journal      = {{ChemSusChem}},
  keywords     = {{T2, T1, CSSD}},
  number       = {{7}},
  pages        = {{1825--1833}},
  publisher    = {{Wiley}},
  title        = {{{Plasma‐Assisted Immobilization of a Phosphonium Salt and Its Use as a Catalyst in the Valorization of CO            <sub>2</sub>}}},
  doi          = {{10.1002/cssc.201903384}},
  volume       = {{13}},
  year         = {{2020}},
}

@article{37963,
  author       = {{Büttner, Hendrik and Kohrt, Christina and Wulf, Christoph and Schäffner, Benjamin and Groenke, Karsten and Hu, Yuya and Kruse, Daniela and Werner, Thomas}},
  issn         = {{1864-5631}},
  journal      = {{ChemSusChem}},
  keywords     = {{T1, T4, CSSD}},
  number       = {{12}},
  pages        = {{2701--2707}},
  publisher    = {{Wiley}},
  title        = {{{Life Cycle Assessment for the Organocatalytic Synthesis of Glycerol Carbonate Methacrylate}}},
  doi          = {{10.1002/cssc.201900678}},
  volume       = {{12}},
  year         = {{2019}},
}

@article{37957,
  author       = {{Hu, Yuya and Steinbauer, Johannes and Stefanow, Vivian and Spannenberg, Anke and Werner, Thomas}},
  issn         = {{2168-0485}},
  journal      = {{ACS Sustainable Chemistry and Engineering}},
  keywords     = {{T1, T3, CSSD}},
  number       = {{15}},
  pages        = {{13257--13269}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Polyethers as Complexing Agents in Calcium-Catalyzed Cyclic Carbonate Synthesis}}},
  doi          = {{10.1021/acssuschemeng.9b02502}},
  volume       = {{7}},
  year         = {{2019}},
}

@article{37967,
  author       = {{Steinbauer, Johannes and Kubis, Christoph and Ludwig, Ralf and Werner, Thomas}},
  issn         = {{2168-0485}},
  journal      = {{ACS Sustainable Chemistry and Engineering}},
  keywords     = {{T1, T2, CSSD}},
  number       = {{8}},
  pages        = {{10778--10788}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Mechanistic Study on the Addition of CO<sub>2</sub> to Epoxides Catalyzed by Ammonium and Phosphonium Salts: A Combined Spectroscopic and Kinetic Approach}}},
  doi          = {{10.1021/acssuschemeng.8b02093}},
  volume       = {{6}},
  year         = {{2018}},
}

@article{37969,
  abstract     = {{<p>Simple zinc organyls (R<sub>2</sub>Zn) efficiently catalyze the copolymerization of CO<sub>2</sub> and cyclohexene oxide. The effect of various reaction parameters has been studied. The reaction proceeds under halogen-free conditions and no co-catalyst is required.</p>}},
  author       = {{Wulf, Christoph and Doering, Ulrike and Werner, Thomas}},
  issn         = {{2046-2069}},
  journal      = {{RSC Advances}},
  keywords     = {{T1, T3, CSSD}},
  number       = {{7}},
  pages        = {{3673--3679}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Copolymerization of CO<sub>2</sub> and epoxides mediated by zinc organyls}}},
  doi          = {{10.1039/c7ra12535f}},
  volume       = {{8}},
  year         = {{2018}},
}

@article{62105,
  author       = {{Longwitz, Lars and Steinbauer, Johannes and Spannenberg, Anke and Werner, Thomas}},
  issn         = {{2155-5435}},
  journal      = {{ACS Catalysis}},
  keywords     = {{T1, T3, T4, CSSD}},
  number       = {{1}},
  pages        = {{665--672}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild Conditions}}},
  doi          = {{10.1021/acscatal.7b03367}},
  volume       = {{8}},
  year         = {{2018}},
}

@article{37970,
  author       = {{Longwitz, Lars and Steinbauer, Johannes and Spannenberg, Anke and Werner, Thomas}},
  issn         = {{2155-5435}},
  journal      = {{ACS Catalysis}},
  keywords     = {{T1, T3, T4}},
  number       = {{1}},
  pages        = {{665--672}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild Conditions}}},
  doi          = {{10.1021/acscatal.7b03367}},
  volume       = {{8}},
  year         = {{2017}},
}

@article{37973,
  abstract     = {{<p>An immobilized bifunctional phosphonium salt catalyst efficiently catalyzed the synthesis of cyclic carbonates under mild conditions, and was reused up to 15 times.</p>}},
  author       = {{Steinbauer, J. and Longwitz, L. and Frank, M. and Epping, J. and Kragl, U. and Werner, Thomas}},
  issn         = {{1463-9262}},
  journal      = {{Green Chemistry}},
  keywords     = {{T1, T2, CSSD}},
  number       = {{18}},
  pages        = {{4435--4445}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Immobilized bifunctional phosphonium salts as recyclable organocatalysts in the cycloaddition of CO<sub>2</sub> and epoxides}}},
  doi          = {{10.1039/c7gc01782k}},
  volume       = {{19}},
  year         = {{2017}},
}

@article{37975,
  abstract     = {{<p>Calcium punched beyond its weight: An <italic>in situ</italic> formed Ca<sup>2+</sup>–crown ether complex showed unprecedented efficiency in cyclic carbonate synthesis.</p>}},
  author       = {{Steinbauer, J. and Spannenberg, A. and Werner, Thomas}},
  issn         = {{1463-9262}},
  journal      = {{Green Chemistry}},
  keywords     = {{T1, T3, CSSD}},
  number       = {{16}},
  pages        = {{3769--3779}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{An in situ formed Ca<sup>2+</sup>–crown ether complex and its use in CO<sub>2</sub>-fixation reactions with terminal and internal epoxides}}},
  doi          = {{10.1039/c7gc01114h}},
  volume       = {{19}},
  year         = {{2017}},
}

@article{37977,
  author       = {{Büttner, Hendrik and Longwitz, Lars and Steinbauer, Johannes and Wulf, Christoph and Werner, Thomas}},
  issn         = {{2365-0869}},
  journal      = {{Topics in Current Chemistry}},
  keywords     = {{T1, CSSD}},
  number       = {{3}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{Recent Developments in the Synthesis of Cyclic Carbonates from Epoxides and CO2}}},
  doi          = {{10.1007/s41061-017-0136-5}},
  volume       = {{375}},
  year         = {{2017}},
}

@article{37978,
  author       = {{Büttner, Hendrik and Steinbauer, Johannes and Wulf, Christoph and Dindaroglu, Mehmet and Schmalz, Hans-Günther and Werner, Thomas}},
  issn         = {{1864-5631}},
  journal      = {{ChemSusChem}},
  keywords     = {{T1, T2, CSSD}},
  number       = {{6}},
  pages        = {{1076--1079}},
  publisher    = {{Wiley}},
  title        = {{{Organocatalyzed Synthesis of Oleochemical Carbonates from CO<sub>2</sub>and Renewables}}},
  doi          = {{10.1002/cssc.201601163}},
  volume       = {{10}},
  year         = {{2017}},
}