[{"publication":"Advanced Engineering Materials","abstract":[{"lang":"eng","text":"The tribological behavior of thermo‐responsive poly(N‐isopropylacrylamide) (PNIPAAm)‐based microgels is investigated for use as water‐dispersible lubricant additives. Two types of microgels are synthesized using a surfactant‐free emulsion polymerization method: MG0, consisting of pure PNIPAAm with a volume phase transition temperature (VPTT) of ≈33 °C, and MG16, consisting of PNIPAAm copolymerized with hydrophobic tert‐butyl acrylamide, exhibiting a lower VPTT of around 23 °C. Swelling and lubrication performance are evaluated at 20 and 40 °C. Both microgels significantly reduce friction and wear compared to water alone. At 20 °C, MG0 remains fully swollen and provides effective wear protection through hydrated microgel lubrication. MG16, being near its VPTT, exhibits partial collapse and slightly higher wear. At 40 °C, MG16 demonstrates improved wear resistance, attributed to enhanced film compaction in the collapsed state. Raman spectroscopy and scanning electron microscopy–energy‐dispersive X‐ray spectroscopy confirm that carbon‐rich tribofilms are formed via tribochemical reactions. MG0 produces more graphitic films, while MG16 generates amorphous carbon structures. These findings highlight the tunability of microgel composition for designing adaptive, water‐based lubricants for temperature‐sensitive applications."}],"language":[{"iso":"eng"}],"issue":"1","year":"2025","publisher":"Wiley","date_created":"2026-03-11T08:53:17Z","title":"Microgel Additives for Aqueous Lubrication: Tailoring Friction and Wear via Composition and Thermal Responsiveness","type":"journal_article","status":"public","_id":"64885","department":[{"_id":"163"}],"user_id":"94","article_number":"e202501673","article_type":"original","publication_identifier":{"issn":["1438-1656","1527-2648"]},"publication_status":"published","intvolume":"        28","citation":{"ieee":"J. Syed, F. Dyck, A. Herberg, D. Kuckling, and N. N. Gosvami, “Microgel Additives for Aqueous Lubrication: Tailoring Friction and Wear via Composition and Thermal Responsiveness,” <i>Advanced Engineering Materials</i>, vol. 28, no. 1, Art. no. e202501673, 2025, doi: <a href=\"https://doi.org/10.1002/adem.202501673\">10.1002/adem.202501673</a>.","chicago":"Syed, Junaid, Florian Dyck, Artjom Herberg, Dirk Kuckling, and Nitya Nand Gosvami. “Microgel Additives for Aqueous Lubrication: Tailoring Friction and Wear via Composition and Thermal Responsiveness.” <i>Advanced Engineering Materials</i> 28, no. 1 (2025). <a href=\"https://doi.org/10.1002/adem.202501673\">https://doi.org/10.1002/adem.202501673</a>.","ama":"Syed J, Dyck F, Herberg A, Kuckling D, Gosvami NN. Microgel Additives for Aqueous Lubrication: Tailoring Friction and Wear via Composition and Thermal Responsiveness. <i>Advanced Engineering Materials</i>. 2025;28(1). doi:<a href=\"https://doi.org/10.1002/adem.202501673\">10.1002/adem.202501673</a>","mla":"Syed, Junaid, et al. “Microgel Additives for Aqueous Lubrication: Tailoring Friction and Wear via Composition and Thermal Responsiveness.” <i>Advanced Engineering Materials</i>, vol. 28, no. 1, e202501673, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/adem.202501673\">10.1002/adem.202501673</a>.","bibtex":"@article{Syed_Dyck_Herberg_Kuckling_Gosvami_2025, title={Microgel Additives for Aqueous Lubrication: Tailoring Friction and Wear via Composition and Thermal Responsiveness}, volume={28}, DOI={<a href=\"https://doi.org/10.1002/adem.202501673\">10.1002/adem.202501673</a>}, number={1e202501673}, journal={Advanced Engineering Materials}, publisher={Wiley}, author={Syed, Junaid and Dyck, Florian and Herberg, Artjom and Kuckling, Dirk and Gosvami, Nitya Nand}, year={2025} }","short":"J. Syed, F. Dyck, A. Herberg, D. Kuckling, N.N. Gosvami, Advanced Engineering Materials 28 (2025).","apa":"Syed, J., Dyck, F., Herberg, A., Kuckling, D., &#38; Gosvami, N. N. (2025). Microgel Additives for Aqueous Lubrication: Tailoring Friction and Wear via Composition and Thermal Responsiveness. <i>Advanced Engineering Materials</i>, <i>28</i>(1), Article e202501673. <a href=\"https://doi.org/10.1002/adem.202501673\">https://doi.org/10.1002/adem.202501673</a>"},"date_updated":"2026-03-11T08:56:26Z","volume":28,"author":[{"first_name":"Junaid","last_name":"Syed","full_name":"Syed, Junaid"},{"last_name":"Dyck","full_name":"Dyck, Florian","first_name":"Florian"},{"last_name":"Herberg","full_name":"Herberg, Artjom","id":"94","first_name":"Artjom"},{"first_name":"Dirk","last_name":"Kuckling","full_name":"Kuckling, Dirk","id":"287"},{"last_name":"Gosvami","full_name":"Gosvami, Nitya Nand","first_name":"Nitya Nand"}],"doi":"10.1002/adem.202501673","main_file_link":[{"url":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/adem.202501673"}]},{"language":[{"iso":"eng"}],"keyword":["Ultra-high-performance liquid chromatography","ion mobility separation","mass spectrometry","LC-MS hyphenation","sequence-defined oligomers"],"article_type":"original","department":[{"_id":"163"}],"user_id":"94","_id":"32416","status":"public","abstract":[{"lang":"eng","text":"In recent years, sequence-defined oligomers (SDOs) gained increasing interest due to their perfectly controlled molecular structure, thus providing defined properties. In order to tune the properties, different functionalities need to be incorporated into the oligomers and the chain tacticity needs to be controlled. Beside the synthesis of SDOs, suitable methods need to be found to analyze the molecular structure. In this work, oligomers exhibiting an alternating or block-wise sequence of side chain functionalities were analyzed using a hyphenation of ultra-high-performance liquid chromatography and electrospray ionization mass spectrometry enhanced by ion mobility separation (IMS). Moieties in the side chains were varied according to polarity and bulkiness. Moreover, chain tacticity was varied. Drift times in the IMS cell and the corresponding collision cross section (CCS) values were shown to be individual parameters allowing the identification of SDOs, even in the case that SDO structures only differ in sequence or tacticity of side chain functionalities. Thus, a library of CCS values was obtained as reference used for the analysis of complex mixtures of SDOs."}],"publication":"International Journal of Polymer Analysis and Characterization","type":"journal_article","doi":"10.1080/1023666x.2022.2100968","title":"Hyphenation of ultra-high-performance liquid chromatography and ion mobility mass spectrometry for the analysis of sequence-defined oligomers with different functionalities and tacticity","author":[{"first_name":"Marie-Theres","last_name":"Berg","full_name":"Berg, Marie-Theres"},{"full_name":"Herberg, Artjom","id":"94","last_name":"Herberg","first_name":"Artjom"},{"first_name":"Dirk","id":"287","full_name":"Kuckling, Dirk","last_name":"Kuckling"}],"date_created":"2022-07-26T06:38:52Z","date_updated":"2023-01-10T08:14:52Z","publisher":"Informa UK Limited","page":"1-12","citation":{"short":"M.-T. Berg, A. Herberg, D. Kuckling, International Journal of Polymer Analysis and Characterization (2022) 1–12.","bibtex":"@article{Berg_Herberg_Kuckling_2022, title={Hyphenation of ultra-high-performance liquid chromatography and ion mobility mass spectrometry for the analysis of sequence-defined oligomers with different functionalities and tacticity}, DOI={<a href=\"https://doi.org/10.1080/1023666x.2022.2100968\">10.1080/1023666x.2022.2100968</a>}, journal={International Journal of Polymer Analysis and Characterization}, publisher={Informa UK Limited}, author={Berg, Marie-Theres and Herberg, Artjom and Kuckling, Dirk}, year={2022}, pages={1–12} }","mla":"Berg, Marie-Theres, et al. “Hyphenation of Ultra-High-Performance Liquid Chromatography and Ion Mobility Mass Spectrometry for the Analysis of Sequence-Defined Oligomers with Different Functionalities and Tacticity.” <i>International Journal of Polymer Analysis and Characterization</i>, Informa UK Limited, 2022, pp. 1–12, doi:<a href=\"https://doi.org/10.1080/1023666x.2022.2100968\">10.1080/1023666x.2022.2100968</a>.","apa":"Berg, M.-T., Herberg, A., &#38; Kuckling, D. (2022). Hyphenation of ultra-high-performance liquid chromatography and ion mobility mass spectrometry for the analysis of sequence-defined oligomers with different functionalities and tacticity. <i>International Journal of Polymer Analysis and Characterization</i>, 1–12. <a href=\"https://doi.org/10.1080/1023666x.2022.2100968\">https://doi.org/10.1080/1023666x.2022.2100968</a>","chicago":"Berg, Marie-Theres, Artjom Herberg, and Dirk Kuckling. “Hyphenation of Ultra-High-Performance Liquid Chromatography and Ion Mobility Mass Spectrometry for the Analysis of Sequence-Defined Oligomers with Different Functionalities and Tacticity.” <i>International Journal of Polymer Analysis and Characterization</i>, 2022, 1–12. <a href=\"https://doi.org/10.1080/1023666x.2022.2100968\">https://doi.org/10.1080/1023666x.2022.2100968</a>.","ieee":"M.-T. Berg, A. Herberg, and D. Kuckling, “Hyphenation of ultra-high-performance liquid chromatography and ion mobility mass spectrometry for the analysis of sequence-defined oligomers with different functionalities and tacticity,” <i>International Journal of Polymer Analysis and Characterization</i>, pp. 1–12, 2022, doi: <a href=\"https://doi.org/10.1080/1023666x.2022.2100968\">10.1080/1023666x.2022.2100968</a>.","ama":"Berg M-T, Herberg A, Kuckling D. Hyphenation of ultra-high-performance liquid chromatography and ion mobility mass spectrometry for the analysis of sequence-defined oligomers with different functionalities and tacticity. <i>International Journal of Polymer Analysis and Characterization</i>. Published online 2022:1-12. doi:<a href=\"https://doi.org/10.1080/1023666x.2022.2100968\">10.1080/1023666x.2022.2100968</a>"},"year":"2022","publication_identifier":{"issn":["1023-666X","1563-5341"]},"publication_status":"published"},{"status":"public","abstract":[{"lang":"eng","text":"For the first time, poly(N-isopropylacrylamide) (PNIPAAm) star polymers with a β-cyclodextrin core are characterized in detail by size-exclusion chromatography (SEC) with triple detection to experimentally verify the number of arms. A combination of a refractive index detector, multi-angle laser light scattering detector, and an online-viscosimeter was used for branching analysis. At first, the SEC system was calibrated and the detector setup was validated using linear polystyrene reference polymers. The applicability of the established triple detection SEC for branching analysis was shown by the analysis of two commercially available polystyrene star polymers. Due to the high molar masses of the star polymers, both the contraction ratio g and g′ could be determined independently, thus allowing the calculation of the viscosity shielding ratio ε. Finally, the branching analysis of the PNIPAAm star polymers could experimentally confirm the assumed arm number of up to 21 arms. Moreover, an increasingly compact molecular structure and the influence of the arm number on the viscosity shielding ratio could be shown."}],"publication":"International Journal of Polymer Analysis and Characterization","type":"journal_article","language":[{"iso":"eng"}],"keyword":["Size-exclusion chromatography","triple detection","branching analysis","star polymers","poly(N-isopropylacrylamide)","β-cyclodextrin"],"department":[{"_id":"163"}],"user_id":"94","_id":"32865","page":"1-19","citation":{"ama":"Herberg A, Kuckling D. Branching analysis of β-cyclodextrin-based poly(<i>N</i>-isopropylacrylamide) star polymers using triple detection SEC. <i>International Journal of Polymer Analysis and Characterization</i>. Published online 2022:1-19. doi:<a href=\"https://doi.org/10.1080/1023666x.2022.2110133\">10.1080/1023666x.2022.2110133</a>","chicago":"Herberg, Artjom, and Dirk Kuckling. “Branching Analysis of β-Cyclodextrin-Based Poly(<i>N</i>-Isopropylacrylamide) Star Polymers Using Triple Detection SEC.” <i>International Journal of Polymer Analysis and Characterization</i>, 2022, 1–19. <a href=\"https://doi.org/10.1080/1023666x.2022.2110133\">https://doi.org/10.1080/1023666x.2022.2110133</a>.","ieee":"A. Herberg and D. Kuckling, “Branching analysis of β-cyclodextrin-based poly(<i>N</i>-isopropylacrylamide) star polymers using triple detection SEC,” <i>International Journal of Polymer Analysis and Characterization</i>, pp. 1–19, 2022, doi: <a href=\"https://doi.org/10.1080/1023666x.2022.2110133\">10.1080/1023666x.2022.2110133</a>.","bibtex":"@article{Herberg_Kuckling_2022, title={Branching analysis of β-cyclodextrin-based poly(<i>N</i>-isopropylacrylamide) star polymers using triple detection SEC}, DOI={<a href=\"https://doi.org/10.1080/1023666x.2022.2110133\">10.1080/1023666x.2022.2110133</a>}, journal={International Journal of Polymer Analysis and Characterization}, publisher={Informa UK Limited}, author={Herberg, Artjom and Kuckling, Dirk}, year={2022}, pages={1–19} }","mla":"Herberg, Artjom, and Dirk Kuckling. “Branching Analysis of β-Cyclodextrin-Based Poly(<i>N</i>-Isopropylacrylamide) Star Polymers Using Triple Detection SEC.” <i>International Journal of Polymer Analysis and Characterization</i>, Informa UK Limited, 2022, pp. 1–19, doi:<a href=\"https://doi.org/10.1080/1023666x.2022.2110133\">10.1080/1023666x.2022.2110133</a>.","short":"A. Herberg, D. Kuckling, International Journal of Polymer Analysis and Characterization (2022) 1–19.","apa":"Herberg, A., &#38; Kuckling, D. (2022). Branching analysis of β-cyclodextrin-based poly(<i>N</i>-isopropylacrylamide) star polymers using triple detection SEC. <i>International Journal of Polymer Analysis and Characterization</i>, 1–19. <a href=\"https://doi.org/10.1080/1023666x.2022.2110133\">https://doi.org/10.1080/1023666x.2022.2110133</a>"},"year":"2022","publication_identifier":{"issn":["1023-666X","1563-5341"]},"publication_status":"published","doi":"10.1080/1023666x.2022.2110133","title":"Branching analysis of β-cyclodextrin-based poly(<i>N</i>-isopropylacrylamide) star polymers using triple detection SEC","date_created":"2022-08-17T06:28:55Z","author":[{"last_name":"Herberg","full_name":"Herberg, Artjom","id":"94","first_name":"Artjom"},{"first_name":"Dirk","id":"287","full_name":"Kuckling, Dirk","last_name":"Kuckling"}],"date_updated":"2023-01-10T08:13:52Z","publisher":"Informa UK Limited"},{"date_updated":"2022-07-28T10:02:28Z","publisher":"RSC","volume":10,"author":[{"full_name":"Berg, Marie-Theres","last_name":"Berg","first_name":"Marie-Theres"},{"first_name":"Chiel","last_name":"Mertens","full_name":"Mertens, Chiel"},{"first_name":"Filip","full_name":"Du Prez, Filip","last_name":"Du Prez"},{"first_name":"Thomas D.","last_name":"Kühne","full_name":"Kühne, Thomas D."},{"id":"94","full_name":"Herberg, Artjom","last_name":"Herberg","first_name":"Artjom"},{"first_name":"Dirk","last_name":"Kuckling","full_name":"Kuckling, Dirk","id":"287"}],"date_created":"2021-09-07T10:11:56Z","title":"Analysis of sequence-defined oligomers through Advanced Polymer Chromatography™ – mass spectrometry hyphenation","doi":"10.1039/d0ra06419j","publication_identifier":{"issn":["2046-2069"]},"publication_status":"published","year":"2020","intvolume":"        10","page":"35245-35252","citation":{"ieee":"M.-T. Berg, C. Mertens, F. Du Prez, T. D. Kühne, A. Herberg, and D. Kuckling, “Analysis of sequence-defined oligomers through Advanced Polymer Chromatography<sup>TM</sup> – mass spectrometry hyphenation,” <i>RSC Advances</i>, vol. 10, pp. 35245–35252, 2020, doi: <a href=\"https://doi.org/10.1039/d0ra06419j\">10.1039/d0ra06419j</a>.","chicago":"Berg, Marie-Theres, Chiel Mertens, Filip Du Prez, Thomas D. Kühne, Artjom Herberg, and Dirk Kuckling. “Analysis of Sequence-Defined Oligomers through Advanced Polymer Chromatography<sup>TM</sup> – Mass Spectrometry Hyphenation.” <i>RSC Advances</i> 10 (2020): 35245–52. <a href=\"https://doi.org/10.1039/d0ra06419j\">https://doi.org/10.1039/d0ra06419j</a>.","ama":"Berg M-T, Mertens C, Du Prez F, Kühne TD, Herberg A, Kuckling D. Analysis of sequence-defined oligomers through Advanced Polymer Chromatography<sup>TM</sup> – mass spectrometry hyphenation. <i>RSC Advances</i>. 2020;10:35245-35252. doi:<a href=\"https://doi.org/10.1039/d0ra06419j\">10.1039/d0ra06419j</a>","mla":"Berg, Marie-Theres, et al. “Analysis of Sequence-Defined Oligomers through Advanced Polymer Chromatography<sup>TM</sup> – Mass Spectrometry Hyphenation.” <i>RSC Advances</i>, vol. 10, RSC, 2020, pp. 35245–52, doi:<a href=\"https://doi.org/10.1039/d0ra06419j\">10.1039/d0ra06419j</a>.","bibtex":"@article{Berg_Mertens_Du Prez_Kühne_Herberg_Kuckling_2020, title={Analysis of sequence-defined oligomers through Advanced Polymer Chromatography<sup>TM</sup> – mass spectrometry hyphenation}, volume={10}, DOI={<a href=\"https://doi.org/10.1039/d0ra06419j\">10.1039/d0ra06419j</a>}, journal={RSC Advances}, publisher={RSC}, author={Berg, Marie-Theres and Mertens, Chiel and Du Prez, Filip and Kühne, Thomas D. and Herberg, Artjom and Kuckling, Dirk}, year={2020}, pages={35245–35252} }","short":"M.-T. Berg, C. Mertens, F. Du Prez, T.D. Kühne, A. Herberg, D. Kuckling, RSC Advances 10 (2020) 35245–35252.","apa":"Berg, M.-T., Mertens, C., Du Prez, F., Kühne, T. D., Herberg, A., &#38; Kuckling, D. (2020). Analysis of sequence-defined oligomers through Advanced Polymer Chromatography<sup>TM</sup> – mass spectrometry hyphenation. <i>RSC Advances</i>, <i>10</i>, 35245–35252. <a href=\"https://doi.org/10.1039/d0ra06419j\">https://doi.org/10.1039/d0ra06419j</a>"},"_id":"23848","department":[{"_id":"311"}],"user_id":"94","language":[{"iso":"eng"}],"publication":"RSC Advances","type":"journal_article","status":"public"},{"user_id":"94","department":[{"_id":"311"}],"_id":"23847","language":[{"iso":"eng"}],"article_number":"2265","type":"journal_article","publication":"Polymers","status":"public","author":[{"first_name":"Xiaoqian","last_name":"Yu","full_name":"Yu, Xiaoqian"},{"first_name":"Artjom","last_name":"Herberg","id":"94","full_name":"Herberg, Artjom"},{"last_name":"Kuckling","full_name":"Kuckling, Dirk","id":"287","first_name":"Dirk"}],"date_created":"2021-09-07T10:08:42Z","volume":12,"publisher":"MDPI","date_updated":"2022-07-28T10:02:05Z","doi":"10.3390/polym12102265","title":"Micellar Organocatalysis Using Smart Polymer Supports: Influence of Thermoresponsive Self-Assembly on Catalytic Activity","issue":"10","publication_status":"published","publication_identifier":{"issn":["2073-4360"]},"citation":{"apa":"Yu, X., Herberg, A., &#38; Kuckling, D. (2020). Micellar Organocatalysis Using Smart Polymer Supports: Influence of Thermoresponsive Self-Assembly on Catalytic Activity. <i>Polymers</i>, <i>12</i>(10), Article 2265. <a href=\"https://doi.org/10.3390/polym12102265\">https://doi.org/10.3390/polym12102265</a>","short":"X. Yu, A. Herberg, D. Kuckling, Polymers 12 (2020).","bibtex":"@article{Yu_Herberg_Kuckling_2020, title={Micellar Organocatalysis Using Smart Polymer Supports: Influence of Thermoresponsive Self-Assembly on Catalytic Activity}, volume={12}, DOI={<a href=\"https://doi.org/10.3390/polym12102265\">10.3390/polym12102265</a>}, number={102265}, journal={Polymers}, publisher={MDPI}, author={Yu, Xiaoqian and Herberg, Artjom and Kuckling, Dirk}, year={2020} }","mla":"Yu, Xiaoqian, et al. “Micellar Organocatalysis Using Smart Polymer Supports: Influence of Thermoresponsive Self-Assembly on Catalytic Activity.” <i>Polymers</i>, vol. 12, no. 10, 2265, MDPI, 2020, doi:<a href=\"https://doi.org/10.3390/polym12102265\">10.3390/polym12102265</a>.","ieee":"X. Yu, A. Herberg, and D. Kuckling, “Micellar Organocatalysis Using Smart Polymer Supports: Influence of Thermoresponsive Self-Assembly on Catalytic Activity,” <i>Polymers</i>, vol. 12, no. 10, Art. no. 2265, 2020, doi: <a href=\"https://doi.org/10.3390/polym12102265\">10.3390/polym12102265</a>.","chicago":"Yu, Xiaoqian, Artjom Herberg, and Dirk Kuckling. “Micellar Organocatalysis Using Smart Polymer Supports: Influence of Thermoresponsive Self-Assembly on Catalytic Activity.” <i>Polymers</i> 12, no. 10 (2020). <a href=\"https://doi.org/10.3390/polym12102265\">https://doi.org/10.3390/polym12102265</a>.","ama":"Yu X, Herberg A, Kuckling D. Micellar Organocatalysis Using Smart Polymer Supports: Influence of Thermoresponsive Self-Assembly on Catalytic Activity. <i>Polymers</i>. 2020;12(10). doi:<a href=\"https://doi.org/10.3390/polym12102265\">10.3390/polym12102265</a>"},"intvolume":"        12","year":"2020"},{"title":"End Group Stability of Atom Transfer Radical Polymerization (ATRP)-Synthesized Poly(N-isopropylacrylamide): Perspectives for Diblock Copolymer Synthesis","doi":"https://doi.org/10.3390/polym11040678","publisher":"MDPI","date_updated":"2022-04-21T09:09:00Z","volume":11,"author":[{"last_name":"Herberg","id":"94","full_name":"Herberg, Artjom","first_name":"Artjom"},{"first_name":"Xiaoqian","last_name":"Yu","full_name":"Yu, Xiaoqian"},{"full_name":"Kuckling, Dirk","id":"287","last_name":"Kuckling","first_name":"Dirk"}],"date_created":"2022-04-21T09:08:41Z","year":"2019","intvolume":"        11","citation":{"ama":"Herberg A, Yu X, Kuckling D. End Group Stability of Atom Transfer Radical Polymerization (ATRP)-Synthesized Poly(N-isopropylacrylamide): Perspectives for Diblock Copolymer Synthesis. <i>Polymers</i>. 2019;11(4). doi:<a href=\"https://doi.org/10.3390/polym11040678\">https://doi.org/10.3390/polym11040678</a>","chicago":"Herberg, Artjom, Xiaoqian Yu, and Dirk Kuckling. “End Group Stability of Atom Transfer Radical Polymerization (ATRP)-Synthesized Poly(N-Isopropylacrylamide): Perspectives for Diblock Copolymer Synthesis.” <i>Polymers</i> 11, no. 4 (2019). <a href=\"https://doi.org/10.3390/polym11040678\">https://doi.org/10.3390/polym11040678</a>.","ieee":"A. Herberg, X. Yu, and D. Kuckling, “End Group Stability of Atom Transfer Radical Polymerization (ATRP)-Synthesized Poly(N-isopropylacrylamide): Perspectives for Diblock Copolymer Synthesis,” <i>Polymers</i>, vol. 11, no. 4, Art. no. 678, 2019, doi: <a href=\"https://doi.org/10.3390/polym11040678\">https://doi.org/10.3390/polym11040678</a>.","bibtex":"@article{Herberg_Yu_Kuckling_2019, title={End Group Stability of Atom Transfer Radical Polymerization (ATRP)-Synthesized Poly(N-isopropylacrylamide): Perspectives for Diblock Copolymer Synthesis}, volume={11}, DOI={<a href=\"https://doi.org/10.3390/polym11040678\">https://doi.org/10.3390/polym11040678</a>}, number={4678}, journal={Polymers}, publisher={MDPI}, author={Herberg, Artjom and Yu, Xiaoqian and Kuckling, Dirk}, year={2019} }","mla":"Herberg, Artjom, et al. “End Group Stability of Atom Transfer Radical Polymerization (ATRP)-Synthesized Poly(N-Isopropylacrylamide): Perspectives for Diblock Copolymer Synthesis.” <i>Polymers</i>, vol. 11, no. 4, 678, MDPI, 2019, doi:<a href=\"https://doi.org/10.3390/polym11040678\">https://doi.org/10.3390/polym11040678</a>.","short":"A. Herberg, X. Yu, D. Kuckling, Polymers 11 (2019).","apa":"Herberg, A., Yu, X., &#38; Kuckling, D. (2019). End Group Stability of Atom Transfer Radical Polymerization (ATRP)-Synthesized Poly(N-isopropylacrylamide): Perspectives for Diblock Copolymer Synthesis. <i>Polymers</i>, <i>11</i>(4), Article 678. <a href=\"https://doi.org/10.3390/polym11040678\">https://doi.org/10.3390/polym11040678</a>"},"publication_status":"published","issue":"4","keyword":["controlled radical polymerization","atom transfer radical polymerization","end group determination","N-isopropylacrylamide","block copolymerization","smart polymers","temperature sensitive polymers","lower critical solution temperature","ESI-TOF mass spectrometry","ion mobility separation","size exclusion chromatography"],"article_number":"678","language":[{"iso":"eng"}],"_id":"30932","department":[{"_id":"311"}],"user_id":"94","status":"public","publication":"Polymers","type":"journal_article"},{"intvolume":"       120","citation":{"ama":"Yu X, Herberg A, Kuckling D. Azlactone-functionalized smart block copolymers for organocatalyst immobilization. <i>European Polymer Journal</i>. 2019;120. doi:<a href=\"https://doi.org/10.1016/j.eurpolymj.2019.08.034\">10.1016/j.eurpolymj.2019.08.034</a>","chicago":"Yu, Xiaoqian, Artjom Herberg, and Dirk Kuckling. “Azlactone-Functionalized Smart Block Copolymers for Organocatalyst Immobilization.” <i>European Polymer Journal</i> 120 (2019). <a href=\"https://doi.org/10.1016/j.eurpolymj.2019.08.034\">https://doi.org/10.1016/j.eurpolymj.2019.08.034</a>.","ieee":"X. Yu, A. Herberg, and D. Kuckling, “Azlactone-functionalized smart block copolymers for organocatalyst immobilization,” <i>European Polymer Journal</i>, vol. 120, Art. no. 109207, 2019, doi: <a href=\"https://doi.org/10.1016/j.eurpolymj.2019.08.034\">10.1016/j.eurpolymj.2019.08.034</a>.","apa":"Yu, X., Herberg, A., &#38; Kuckling, D. (2019). 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