@article{41041, abstract = {{

Sr2TiO3F2−x, a potential anode material for fluoride ion batteries, is prepared in the charged state via selective low-temperature defluorination.

}}, author = {{Wissel, Kerstin and Dasgupta, Supratik and Benes, Alexander and Schoch, Roland and Bauer, Matthias and Witte, Ralf and Fortes, Andrew Dominic and Erdem, Emre and Rohrer, Jochen and Clemens, Oliver}}, issn = {{2050-7488}}, journal = {{Journal of Materials Chemistry A}}, keywords = {{General Materials Science, Renewable Energy, Sustainability and the Environment, General Chemistry}}, number = {{44}}, pages = {{22013--22026}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Developing intercalation based anode materials for fluoride-ion batteries: topochemical reduction of Sr2TiO3F2via a hydride based defluorination process}}}, doi = {{10.1039/c8ta01012a}}, volume = {{6}}, year = {{2018}}, } @article{41042, author = {{Garai, Antara and Sobottka, Sebastian and Schepper, Rahel and Sinha, Woormileela and Bauer, Matthias and Sarkar, Biprajit and Kar, Sanjib}}, issn = {{0947-6539}}, journal = {{Chemistry - A European Journal}}, keywords = {{General Chemistry, Catalysis, Organic Chemistry}}, number = {{48}}, pages = {{12613--12622}}, publisher = {{Wiley}}, title = {{{Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence}}}, doi = {{10.1002/chem.201801452}}, volume = {{24}}, year = {{2018}}, } @phdthesis{41004, author = {{Söyler, Hatice}}, title = {{{Syntheses of ruthenium complexes for studies on water oxidation and their immobilization approaches}}}, doi = {{10.17619/UNIPB/1-459}}, year = {{2018}}, } @phdthesis{40996, author = {{Tünnermann, Maike}}, title = {{{Photocatalytic water reduction systems based on iridium and non-noble metal complexes}}}, doi = {{10.17619/UNIPB/1-420}}, year = {{2018}}, } @article{41037, author = {{Fischer, Steffen and Rösel, Arend and Kammer, Anja and Barsch, Enrico and Schoch, Roland and Junge, Henrik and Bauer, Matthias and Beller, Matthias and Ludwig, Ralf}}, issn = {{0947-6539}}, journal = {{Chemistry - A European Journal}}, keywords = {{General Chemistry, Catalysis, Organic Chemistry}}, number = {{60}}, pages = {{16052--16065}}, publisher = {{Wiley}}, title = {{{Diferrate [Fe2(CO)6(μ-CO){μ-P(aryl)2}]− as Self-Assembling Iron/Phosphor-Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction-Spectroscopic Insights}}}, doi = {{10.1002/chem.201802694}}, volume = {{24}}, year = {{2018}}, } @article{41044, author = {{Otto, Sven and Dorn, Matthias and Förster, Christoph and Bauer, Matthias and Seitz, Michael and Heinze, Katja}}, issn = {{0010-8545}}, journal = {{Coordination Chemistry Reviews}}, keywords = {{Materials Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry}}, pages = {{102--111}}, publisher = {{Elsevier BV}}, title = {{{Understanding and exploiting long-lived near-infrared emission of a molecular ruby}}}, doi = {{10.1016/j.ccr.2018.01.004}}, volume = {{359}}, year = {{2018}}, } @article{41040, abstract = {{

Intermediate species formed during CO2 methanation over Rh/Al2O3 and Rh/SiO2 catalysts.

}}, author = {{Martin, Natalia M. and Hemmingsson, Felix and Wang, Xueting and Merte, Lindsay R. and Hejral, Uta and Gustafson, Johan and Skoglundh, Magnus and Meira, Debora Motta and Dippel, Ann-Christin and Gutowski, Olof and Bauer, Matthias and Carlsson, Per-Anders}}, issn = {{2044-4753}}, journal = {{Catalysis Science & Technology}}, keywords = {{Catalysis}}, number = {{10}}, pages = {{2686--2696}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Structure–function relationship during CO2 methanation over Rh/Al2O3 and Rh/SiO2 catalysts under atmospheric pressure conditions}}}, doi = {{10.1039/c8cy00516h}}, volume = {{8}}, year = {{2018}}, } @article{41036, abstract = {{We report here a straightforward synthesis for a series of new structures with fused 1,10-phenanthroline-thiophene connection. They are synthesized with a modified Hinsberg thiophene procedure, followed by successive modification to yield several 5,7-disubstituted thieno[3,4-f][1,10]phenanthrolines, most notable thiophene-substituted compounds that could be potentially of use for organic electronics ­applications. For some selected examples, crystal structures were ­obtained, showing a nearly coplanar arrangement around the fused connection, also beneficial for an effective electron transfer in organic electronics or solar cells.}}, author = {{Bauer, Matthias and Tünnermann, Maike and Rehsies, Pia and Flörke, Ulrich}}, issn = {{0936-5214}}, journal = {{Synlett}}, keywords = {{Organic Chemistry}}, number = {{20}}, pages = {{2638--2642}}, publisher = {{Georg Thieme Verlag KG}}, title = {{{A Straightforward Synthesis to Novel 1,10-Phenanthrolines with Fused Thiophene Structure}}}, doi = {{10.1055/s-0037-1611022}}, volume = {{29}}, year = {{2018}}, } @article{41039, author = {{Burkhardt, Lukas and Mueller, Carsten and Groß, Oliver A. and Sun, Yu and Sitzmann, Helmut and Bauer, Matthias}}, issn = {{0020-1669}}, journal = {{Inorganic Chemistry}}, keywords = {{Inorganic Chemistry, Physical and Theoretical Chemistry}}, number = {{10}}, pages = {{6609--6618}}, publisher = {{American Chemical Society (ACS)}}, title = {{{The Bonding Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4] Revisited by Hard X-Ray Spectroscopy}}}, doi = {{10.1021/acs.inorgchem.8b03032}}, volume = {{58}}, year = {{2018}}, } @phdthesis{40992, author = {{Meinhardt, Regina}}, title = {{{Entwicklung und Synthese von Ein- und Mehrkomponentensystemen zur photokatalytischen Wasserreduktion}}}, doi = {{10.17619/UNIPB/1-325}}, year = {{2018}}, } @article{25912, abstract = {{It is possible to infiltrate a guest species selectively in one pore system of bimodal mesoporous CMK-5 carbon by an optimized nanocasting procedure. The selective filling has a drastic impact on the low-angle X-ray diffraction pattern of this novel class of materials. The structures of CMK-5, CMK-5 composite materials (sulfur and SnO2 as guest species), and CMK-3 carbon were simulated to investigate the influence of the pore filling with different guest species on the diffraction pattern and compared with experimental results. Additionally, the impact of structural defects is taken into account. The nature of the guest species strongly influences the relative intensity of the diffraction peaks. It turns out that the diffraction patterns of sulfur-carbon composite materials are nearly identical as those of CMK-3 carbon, which is attributed to a similar electron density of carbon and sulfur. Thus, sulfur is an ideal guest species to investigate the selective pore filling in CMK-5 carbon.}}, author = {{Weinberger, Christian and Hartmann, Marc and Ren, Sai and Sandberg, Thomas and Smått, Jan-Henrik and Tiemann, Michael}}, issn = {{1387-1811}}, journal = {{Microporous and Mesoporous Materials}}, pages = {{24--31}}, title = {{{Selective pore filling of mesoporous CMK-5 carbon studied by XRD: Comparison between theoretical simulations and experimental results}}}, doi = {{10.1016/j.micromeso.2018.02.035}}, year = {{2018}}, } @article{25910, abstract = {{We describe the synthesis of mesoporous Al2O3 and MgO layers on silicon wafer substrates by using poly(dimethylacrylamide) hydrogels as porogenic matrices. Hydrogel films are prepared by spreading the polymer through spin-coating, followed by photo-cross-linking and anchoring to the substrate surface. The metal oxides are obtained by swelling the hydrogels in the respective metal nitrate solutions and subsequent thermal conversion. Combustion of the hydrogel results in mesoporous metal oxide layers with thicknesses in the μm range and high specific surface areas up to 558 m2∙g−1. Materials are characterized by SEM, FIB ablation, EDX, and Kr physisorption porosimetry.}}, author = {{Chen, Zimei and Kuckling, Dirk and Tiemann, Michael}}, issn = {{2079-4991}}, journal = {{Nanomaterials}}, title = {{{Porous Aluminum Oxide and Magnesium Oxide Films Using Organic Hydrogels as Structure Matrices}}}, doi = {{10.3390/nano8040186}}, year = {{2018}}, } @article{25913, abstract = {{Ordered mesoporous CMK-5 carbon exhibits two distinct pore systems that can be modified individually. This work demonstrates how one of the pore systems can be selectively filled with elemental sulfur, while the other pore system remains empty. The resulting sulfur–carbon composite material with high residual porosity can be used as the cathode material in lithium–sulfur battery cells. We present a systematic investigation of the loading of CMK-5 carbon with variable relative amounts of sulfur and compare the results to the preparation of SnO2 (as well as TiO2, Mn2O3/Mn3O4, NiO) nanoparticle-loaded CMK-5 carbon.}}, author = {{Weinberger, Christian and Ren, Sai and Hartmann, Marc and Wagner, Thorsten and Karaman, Didem. Ş. and Rosenholm, Jessica M. and Tiemann, Michael}}, issn = {{2574-0970}}, journal = {{ACS Applied Nano Materials}}, pages = {{455--462}}, title = {{{Bimodal Mesoporous CMK-5 Carbon: Selective Pore Filling with Sulfur and SnO2 for Lithium Battery Electrodes}}}, doi = {{10.1021/acsanm.7b00307}}, year = {{2018}}, } @article{25909, abstract = {{Organic polymer-hydrogels are known to be capable of directing the nucleation and growth of inorganic materials, such as silica, metal oxides, apatite or metal chalcogenides. This approach can be exploited in the synthesis of materials that exhibit defined nanoporosity. When the organic polymer-based hydrogel is incorporated in the inorganic product, a composite is formed from which the organic component may be selectively removed, yielding nanopores in the inorganic product. Such porogenic impact resembles the concept of using soft or hard templates for porous materials. This micro-review provides a survey of select examples from the literature.}}, author = {{Weinberger, Christian and Kuckling, Dirk and Tiemann, Michael}}, issn = {{2310-2861}}, journal = {{Gels}}, title = {{{Hydrogels as Porogens for Nanoporous Inorganic Materials}}}, doi = {{10.3390/gels4040083}}, year = {{2018}}, } @article{13405, author = {{Müller, Patrick and Karhan, Kristof and Krack, Matthias and Gerstmann, Uwe and Schmidt, Wolf Gero and Bauer, Matthias and Kühne, Thomas D.}}, issn = {{0192-8651}}, journal = {{Journal of Computational Chemistry}}, pages = {{712--716}}, title = {{{Impact of finite-temperature and condensed-phase effects on theoretical X-ray absorption spectra of transition metal complexes}}}, doi = {{10.1002/jcc.25641}}, year = {{2018}}, } @article{25911, abstract = {{Different types of reduced graphene oxide and graphene oxide particles have been studied regarding their influence on the curing behaviour of epoxy-amine resins. Especially the specific surface area of reduced graphene oxide was selectively influenced by controlled drying of the material. The different types of reduced graphene oxide particles were used to produce epoxy-amine composites that significantly change their curing behaviour and mechanical properties. A variety of surface areas and compositions were prepared by combination of a fast heating rate and different drying methods. The combination of freeze drying with a fast heating rate leads to a large specific surface area of 680 m2/g. The morphologies of the particles were observed by scanning electron microscope and the BET surface area was measured with nitrogen-physisorption. The exfoliation quality was measured by XRD. The generated graphene oxide and thermally reduced graphene oxide particles were mixed with epoxy-amine resin. The curing behaviour was studied with rheological and differential scanning calorimetry (DSC) measurements. We observed that different surface functionalities lowers the Glass transition temperature and the gel time of an epoxy-amine curing system. In addition, we found that generated graphene oxide acts as flexibilizer. An increase of the deformation from 2.5 mm to 3.1 mm was measured by Erichsen Cupping Test.}}, author = {{Wolk, Andreas and Rosenthal, Marta and Weiß, Julia and Voigt, Markus and Wesendahl, Jan-Niklas and Hartmann, Marc and Grundmeier, Guido and Wilhelm, Rene and Meschut, Gerson and Tiemann, Michael and Bremser, Wolfgang}}, issn = {{0300-9440}}, journal = {{Progress in Organic Coatings}}, pages = {{280--289}}, title = {{{Graphene oxide as flexibilizer for epoxy amine resins}}}, doi = {{10.1016/j.porgcoat.2018.05.028}}, year = {{2018}}, } @article{13407, abstract = {{

A study of structural evolution upon photoinduced charge transfer in a dicopper complex with biologically relevant sulfur coordination.

}}, author = {{Naumova, Maria and Khakhulin, Dmitry and Rebarz, Mateusz and Rohrmüller, Martin and Dicke, Benjamin and Biednov, Mykola and Britz, Alexander and Espinoza, Shirly and Grimm-Lebsanft, Benjamin and Kloz, Miroslav and Kretzschmar, Norman and Neuba, Adam and Ortmeyer, Jochen and Schoch, Roland and Andreasson, Jakob and Bauer, Matthias and Bressler, Christian and Schmidt, Wolf Gero and Henkel, Gerald and Rübhausen, Michael}}, issn = {{1463-9076}}, journal = {{Physical Chemistry Chemical Physics}}, pages = {{6274--6286}}, title = {{{Structural dynamics upon photoexcitation-induced charge transfer in a dicopper(i)–disulfide complex}}}, doi = {{10.1039/c7cp04880g}}, year = {{2018}}, } @article{16318, author = {{Burkhardt, Lukas and Holzwarth, Michael and Plietker, Bernd and Bauer, Matthias}}, issn = {{0020-1669}}, journal = {{Inorganic Chemistry}}, pages = {{13300--13310}}, title = {{{Detection and Characterization of Hydride Ligands in Iron Complexes by High-Resolution Hard X-ray Spectroscopy and Implications for Catalytic Processes}}}, doi = {{10.1021/acs.inorgchem.7b02063}}, year = {{2017}}, } @article{16322, author = {{Preiß, Sebastian and Förster, Christoph and Otto, Sven and Bauer, Matthias and Müller, Patrick and Hinderberger, Dariush and Hashemi Haeri, Haleh and Carella, Luca and Heinze, Katja}}, issn = {{1755-4330}}, journal = {{Nature Chemistry}}, pages = {{1249--1255}}, title = {{{Structure and reactivity of a mononuclear gold(II) complex}}}, doi = {{10.1038/nchem.2836}}, year = {{2017}}, } @phdthesis{16332, author = {{Stührenberg, Kai}}, title = {{{Phenanthroline-basierte Kupferkomplexe für Wasserspaltungsanwendungen}}}, doi = {{10.17619/UNIPB/1-253}}, year = {{2017}}, }