--- _id: '41003' abstract: - lang: eng text: Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(II) complexes increases the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2 ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(II) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap article_type: original author: - first_name: Thomas full_name: Reuter, Thomas last_name: Reuter - first_name: Ayla full_name: Kruse, Ayla last_name: Kruse - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Stefan full_name: Lochbrunner, Stefan last_name: Lochbrunner - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Katja full_name: Heinze, Katja last_name: Heinze citation: ama: Reuter T, Kruse A, Schoch R, Lochbrunner S, Bauer M, Heinze K. Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion. Chemical Communications. 2021;57(61):7541-7544. doi:10.1039/d1cc02173g apa: Reuter, T., Kruse, A., Schoch, R., Lochbrunner, S., Bauer, M., & Heinze, K. (2021). Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion. Chemical Communications, 57(61), 7541–7544. https://doi.org/10.1039/d1cc02173g bibtex: '@article{Reuter_Kruse_Schoch_Lochbrunner_Bauer_Heinze_2021, title={Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion}, volume={57}, DOI={10.1039/d1cc02173g}, number={61}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Reuter, Thomas and Kruse, Ayla and Schoch, Roland and Lochbrunner, Stefan and Bauer, Matthias and Heinze, Katja}, year={2021}, pages={7541–7544} }' chicago: 'Reuter, Thomas, Ayla Kruse, Roland Schoch, Stefan Lochbrunner, Matthias Bauer, and Katja Heinze. “Higher MLCT Lifetime of Carbene Iron(<scp>ii</Scp>) Complexes by Chelate Ring Expansion.” Chemical Communications 57, no. 61 (2021): 7541–44. https://doi.org/10.1039/d1cc02173g.' ieee: 'T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, and K. Heinze, “Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion,” Chemical Communications, vol. 57, no. 61, pp. 7541–7544, 2021, doi: 10.1039/d1cc02173g.' mla: Reuter, Thomas, et al. “Higher MLCT Lifetime of Carbene Iron(<scp>ii</Scp>) Complexes by Chelate Ring Expansion.” Chemical Communications, vol. 57, no. 61, Royal Society of Chemistry (RSC), 2021, pp. 7541–44, doi:10.1039/d1cc02173g. short: T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, K. Heinze, Chemical Communications 57 (2021) 7541–7544. date_created: 2023-01-30T16:49:33Z date_updated: 2023-01-31T08:06:16Z department: - _id: '35' - _id: '306' doi: 10.1039/d1cc02173g intvolume: ' 57' issue: '61' keyword: - Materials Chemistry - Metals and Alloys - Surfaces - Coatings and Films - General Chemistry - Ceramics and Composites - Electronic - Optical and Magnetic Materials - Catalysis language: - iso: eng page: 7541-7544 publication: Chemical Communications publication_identifier: issn: - 1359-7345 - 1364-548X publication_status: published publisher: Royal Society of Chemistry (RSC) status: public title: Higher MLCT lifetime of carbene iron(ii) complexes by chelate ring expansion type: journal_article user_id: '48467' volume: 57 year: '2021' ... --- _id: '40997' abstract: - lang: eng text: 'On transition metals such as iron rests lots of hope to replace precious metal catalysts in the field of photochemistry for a more sustainable future. Indeed, significant progress has been made in recent years in terms of lifetime extension and emerging applications in catalysis. For this reason, recent synthetic strategies of new photoactive iron compounds, which have proved to show particularly promising properties, are reviewed here. The lifetime of the excited state serves as a key parameter for comparison with the standard ruthenium complex, [Ru(bpy)3]2+, to discuss the potential and performance of the iron complexes. This approach is complemented by a more holistic examination of the sustainability of such a substitution strategy in order to answer the question: when or at which point can we assume that iron represents a more sustainable alternative for noble metals in photochemical applications?' article_type: review author: - first_name: Philipp full_name: Dierks, Philipp last_name: Dierks - first_name: Yannik full_name: Vukadinovic, Yannik last_name: Vukadinovic - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 citation: ama: 'Dierks P, Vukadinovic Y, Bauer M. Photoactive iron complexes: more sustainable, but still a challenge. Inorganic Chemistry Frontiers. 2021;9(2):206-220. doi:10.1039/d1qi01112j' apa: 'Dierks, P., Vukadinovic, Y., & Bauer, M. (2021). Photoactive iron complexes: more sustainable, but still a challenge. Inorganic Chemistry Frontiers, 9(2), 206–220. https://doi.org/10.1039/d1qi01112j' bibtex: '@article{Dierks_Vukadinovic_Bauer_2021, title={Photoactive iron complexes: more sustainable, but still a challenge}, volume={9}, DOI={10.1039/d1qi01112j}, number={2}, journal={Inorganic Chemistry Frontiers}, publisher={Royal Society of Chemistry (RSC)}, author={Dierks, Philipp and Vukadinovic, Yannik and Bauer, Matthias}, year={2021}, pages={206–220} }' chicago: 'Dierks, Philipp, Yannik Vukadinovic, and Matthias Bauer. “Photoactive Iron Complexes: More Sustainable, but Still a Challenge.” Inorganic Chemistry Frontiers 9, no. 2 (2021): 206–20. https://doi.org/10.1039/d1qi01112j.' ieee: 'P. Dierks, Y. Vukadinovic, and M. Bauer, “Photoactive iron complexes: more sustainable, but still a challenge,” Inorganic Chemistry Frontiers, vol. 9, no. 2, pp. 206–220, 2021, doi: 10.1039/d1qi01112j.' mla: 'Dierks, Philipp, et al. “Photoactive Iron Complexes: More Sustainable, but Still a Challenge.” Inorganic Chemistry Frontiers, vol. 9, no. 2, Royal Society of Chemistry (RSC), 2021, pp. 206–20, doi:10.1039/d1qi01112j.' short: P. Dierks, Y. Vukadinovic, M. Bauer, Inorganic Chemistry Frontiers 9 (2021) 206–220. date_created: 2023-01-30T16:47:45Z date_updated: 2023-01-31T08:04:56Z department: - _id: '35' - _id: '306' doi: 10.1039/d1qi01112j intvolume: ' 9' issue: '2' keyword: - Inorganic Chemistry language: - iso: eng page: 206-220 publication: Inorganic Chemistry Frontiers publication_identifier: issn: - 2052-1553 publication_status: published publisher: Royal Society of Chemistry (RSC) status: public title: 'Photoactive iron complexes: more sustainable, but still a challenge' type: journal_article user_id: '48467' volume: 9 year: '2021' ... --- _id: '41000' abstract: - lang: eng text: Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies for the construction of functional molecules as they obviate the need for pre-functionalized substrates and minimize waste generation. Great challenges reside in the control of selectivities, the utilization of unbiased hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms. An especially mild borylation of benzylic CH bonds was developed with the ligand-free pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic, and preparative mechanistic studies are indicative of a tandem catalysis mechanism of CH-borylation and dehydrocoupling via molecular CoI catalysts. article_type: original author: - first_name: Pradip full_name: Ghosh, Pradip last_name: Ghosh - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Axel full_name: Jacobi von Wangelin, Axel last_name: Jacobi von Wangelin citation: ama: Ghosh P, Schoch R, Bauer M, Jacobi von Wangelin A. Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International Edition. 2021;61(1). doi:10.1002/anie.202110821 apa: Ghosh, P., Schoch, R., Bauer, M., & Jacobi von Wangelin, A. (2021). Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International Edition, 61(1). https://doi.org/10.1002/anie.202110821 bibtex: '@article{Ghosh_Schoch_Bauer_Jacobi von Wangelin_2021, title={Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis}, volume={61}, DOI={10.1002/anie.202110821}, number={1}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021} }' chicago: Ghosh, Pradip, Roland Schoch, Matthias Bauer, and Axel Jacobi von Wangelin. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte Chemie International Edition 61, no. 1 (2021). https://doi.org/10.1002/anie.202110821. ieee: 'P. Ghosh, R. Schoch, M. Bauer, and A. Jacobi von Wangelin, “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis,” Angewandte Chemie International Edition, vol. 61, no. 1, 2021, doi: 10.1002/anie.202110821.' mla: Ghosh, Pradip, et al. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte Chemie International Edition, vol. 61, no. 1, Wiley, 2021, doi:10.1002/anie.202110821. short: P. Ghosh, R. Schoch, M. Bauer, A. Jacobi von Wangelin, Angewandte Chemie International Edition 61 (2021). date_created: 2023-01-30T16:48:53Z date_updated: 2023-01-31T08:05:26Z department: - _id: '35' - _id: '306' doi: 10.1002/anie.202110821 intvolume: ' 61' issue: '1' keyword: - General Chemistry - Catalysis language: - iso: eng publication: Angewandte Chemie International Edition publication_identifier: issn: - 1433-7851 - 1521-3773 publication_status: published publisher: Wiley status: public title: Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis type: journal_article user_id: '48467' volume: 61 year: '2021' ... --- _id: '41013' abstract: - lang: eng text: Within this article, it is shown that an electrochemical defluorination and additional fluorination of Ruddlesden–Popper-type La2NiO3F2 is possible within all-solid-state fluoride-ion batteries. Structural changes within the reduced and oxidized phases have been examined by X-ray diffraction studies at different states of charging and discharging. The synthesis of the oxidized phase La2NiO3F2+x proved to be successful by structural analysis using both X-ray powder diffraction and automated electron diffraction tomography techniques. The structural reversibility on re-fluorinating and re-defluorinating is also demonstrated. Moreover, the influence of different sequences of consecutive reduction and oxidation steps on the formed phases has been investigated. The observed structural changes have been compared to changes in phases obtained via other topochemical modification approaches such as hydride-based reduction and oxidative fluorination using F2 gas, highlighting the potential of such electrochemical reactions as alternative synthesis routes. Furthermore, the electrochemical routes represent safe and controllable synthesis approaches for novel phases, which cannot be synthesized via other topochemical methods. Additionally, side reactions, occurring alongside the desired electrochemical reactions, have been addressed and the cycling performance has been studied. article_type: original author: - first_name: Kerstin full_name: Wissel, Kerstin last_name: Wissel - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Tobias full_name: Vogel, Tobias last_name: Vogel - first_name: Manuel full_name: Donzelli, Manuel last_name: Donzelli - first_name: Galina full_name: Matveeva, Galina last_name: Matveeva - first_name: Ute full_name: Kolb, Ute last_name: Kolb - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Peter R. full_name: Slater, Peter R. last_name: Slater - first_name: Oliver full_name: Clemens, Oliver last_name: Clemens citation: ama: Wissel K, Schoch R, Vogel T, et al. Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries. Chemistry of Materials. 2021;33(2):499-512. doi:10.1021/acs.chemmater.0c01762 apa: Wissel, K., Schoch, R., Vogel, T., Donzelli, M., Matveeva, G., Kolb, U., Bauer, M., Slater, P. R., & Clemens, O. (2021). Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries. Chemistry of Materials, 33(2), 499–512. https://doi.org/10.1021/acs.chemmater.0c01762 bibtex: '@article{Wissel_Schoch_Vogel_Donzelli_Matveeva_Kolb_Bauer_Slater_Clemens_2021, title={Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries}, volume={33}, DOI={10.1021/acs.chemmater.0c01762}, number={2}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Wissel, Kerstin and Schoch, Roland and Vogel, Tobias and Donzelli, Manuel and Matveeva, Galina and Kolb, Ute and Bauer, Matthias and Slater, Peter R. and Clemens, Oliver}, year={2021}, pages={499–512} }' chicago: 'Wissel, Kerstin, Roland Schoch, Tobias Vogel, Manuel Donzelli, Galina Matveeva, Ute Kolb, Matthias Bauer, Peter R. Slater, and Oliver Clemens. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries.” Chemistry of Materials 33, no. 2 (2021): 499–512. https://doi.org/10.1021/acs.chemmater.0c01762.' ieee: 'K. Wissel et al., “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries,” Chemistry of Materials, vol. 33, no. 2, pp. 499–512, 2021, doi: 10.1021/acs.chemmater.0c01762.' mla: Wissel, Kerstin, et al. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries.” Chemistry of Materials, vol. 33, no. 2, American Chemical Society (ACS), 2021, pp. 499–512, doi:10.1021/acs.chemmater.0c01762. short: K. Wissel, R. Schoch, T. Vogel, M. Donzelli, G. Matveeva, U. Kolb, M. Bauer, P.R. Slater, O. Clemens, Chemistry of Materials 33 (2021) 499–512. date_created: 2023-01-30T17:01:00Z date_updated: 2023-01-31T08:07:28Z department: - _id: '35' - _id: '306' doi: 10.1021/acs.chemmater.0c01762 intvolume: ' 33' issue: '2' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 499-512 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries type: journal_article user_id: '48467' volume: 33 year: '2021' ... --- _id: '41010' abstract: - lang: eng text: We present the η3-coordination of the 2-phosphaethynthiolate anion in the complex (PN)2La(SCP) (2) [PN=N-(2-(diisopropylphosphanyl)-4-methylphenyl)-2,4,6-trimethylanilide)]. Structural comparison with dinuclear thiocyanate-bridged (PN)2La(μ-1,3-SCN)2La(PN)2 (3) and azide-bridged (PN)2La(μ-1,3-N3)2La(PN)2 (4) complexes indicates that the [SCP]− coordination mode is mainly governed by electronic, rather than steric factors. Quantum mechanical investigations reveal large contributions of the antibonding π*-orbital of the [SCP]− ligand to the LUMO of complex 2, rendering it the ideal precursor for the first functionalization of the [SCP]− anion. Complex 2 was therefore reacted with CAACs which induced a selective rearrangement of the [SCP]− ligand to form the first CAAC stabilized group 15–group 16 fulminate-type complexes (PN)2La{SPC(RCAAC)} (5 a,b, R=Ad, Me). A detailed reaction mechanism for the SCP-to-SPC isomerization is proposed based on DFT calculations. article_type: original author: - first_name: Fabian A. full_name: Watt, Fabian A. last_name: Watt - first_name: Lukas full_name: Burkhardt, Lukas last_name: Burkhardt - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Stefan full_name: Mitzinger, Stefan last_name: Mitzinger - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Florian full_name: Weigend, Florian last_name: Weigend - first_name: Jose M. full_name: Goicoechea, Jose M. last_name: Goicoechea - first_name: Frank full_name: Tambornino, Frank last_name: Tambornino - first_name: Stephan full_name: Hohloch, Stephan last_name: Hohloch citation: ama: Watt FA, Burkhardt L, Schoch R, et al. η            3            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**. Angewandte Chemie International Edition. 2021;60(17):9534-9539. doi:10.1002/anie.202100559 apa: Watt, F. A., Burkhardt, L., Schoch, R., Mitzinger, S., Bauer, M., Weigend, F., Goicoechea, J. M., Tambornino, F., & Hohloch, S. (2021). η            3            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**. Angewandte Chemie International Edition, 60(17), 9534–9539. https://doi.org/10.1002/anie.202100559 bibtex: '@article{Watt_Burkhardt_Schoch_Mitzinger_Bauer_Weigend_Goicoechea_Tambornino_Hohloch_2021, title={η            3            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**}, volume={60}, DOI={10.1002/anie.202100559}, number={17}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Watt, Fabian A. and Burkhardt, Lukas and Schoch, Roland and Mitzinger, Stefan and Bauer, Matthias and Weigend, Florian and Goicoechea, Jose M. and Tambornino, Frank and Hohloch, Stephan}, year={2021}, pages={9534–9539} }' chicago: 'Watt, Fabian A., Lukas Burkhardt, Roland Schoch, Stefan Mitzinger, Matthias Bauer, Florian Weigend, Jose M. Goicoechea, Frank Tambornino, and Stephan Hohloch. “η            3            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” Angewandte Chemie International Edition 60, no. 17 (2021): 9534–39. https://doi.org/10.1002/anie.202100559.' ieee: 'F. A. Watt et al., “η            3            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**,” Angewandte Chemie International Edition, vol. 60, no. 17, pp. 9534–9539, 2021, doi: 10.1002/anie.202100559.' mla: Watt, Fabian A., et al. “η            3            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” Angewandte Chemie International Edition, vol. 60, no. 17, Wiley, 2021, pp. 9534–39, doi:10.1002/anie.202100559. short: F.A. Watt, L. Burkhardt, R. Schoch, S. Mitzinger, M. Bauer, F. Weigend, J.M. Goicoechea, F. Tambornino, S. Hohloch, Angewandte Chemie International Edition 60 (2021) 9534–9539. date_created: 2023-01-30T17:00:21Z date_updated: 2023-01-31T08:06:50Z department: - _id: '35' - _id: '306' doi: 10.1002/anie.202100559 intvolume: ' 60' issue: '17' keyword: - General Chemistry - Catalysis language: - iso: eng page: 9534-9539 publication: Angewandte Chemie International Edition publication_identifier: issn: - 1433-7851 - 1521-3773 publication_status: published publisher: Wiley status: public title: η 3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)** type: journal_article user_id: '48467' volume: 60 year: '2021' ... --- _id: '41012' abstract: - lang: eng text: Here we explore the electronic structure of the diiron complex [(dppf)Fe(CO)3]0/+ [10/+; dppf = 1,1′-bis(diphenylphosphino)ferrocene] in two oxidation states by an advanced multitechnique experimental approach. A combination of magnetic circular dichroism, X-ray absorption and emission, high-frequency electron paramagnetic resonance (EPR), and Mössbauer spectroscopies is used to establish that oxidation of 10 occurs on the carbonyl iron ion, resulting in a low-spin iron(I) ion. It is shown that an unequivocal result is obtained by combining several methods. Compound 1+ displays slow spin dynamics, which is used here to study its geometric structure by means of pulsed EPR methods. Surprisingly, these data show an association of the tetrakis[3,5-bis(trifluoromethylphenyl)]borate counterion with 1+. article_type: original author: - first_name: Mario full_name: Winkler, Mario last_name: Winkler - first_name: Marc full_name: Schnierle, Marc last_name: Schnierle - first_name: Felix full_name: Ehrlich, Felix last_name: Ehrlich - first_name: Kim-Isabelle full_name: Mehnert, Kim-Isabelle last_name: Mehnert - first_name: David full_name: Hunger, David last_name: Hunger - first_name: Alena M. full_name: Sheveleva, Alena M. last_name: Sheveleva - first_name: Lukas full_name: Burkhardt, Lukas last_name: Burkhardt - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Floriana full_name: Tuna, Floriana last_name: Tuna - first_name: Mark R. full_name: Ringenberg, Mark R. last_name: Ringenberg - first_name: Joris full_name: van Slageren, Joris last_name: van Slageren citation: ama: 'Winkler M, Schnierle M, Ehrlich F, et al. Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) 3]+/0. Inorganic Chemistry. 2021;60(5):2856-2865. doi:10.1021/acs.inorgchem.0c03259' apa: 'Winkler, M., Schnierle, M., Ehrlich, F., Mehnert, K.-I., Hunger, D., Sheveleva, A. M., Burkhardt, L., Bauer, M., Tuna, F., Ringenberg, M. R., & van Slageren, J. (2021). Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) 3]+/0. Inorganic Chemistry, 60(5), 2856–2865. https://doi.org/10.1021/acs.inorgchem.0c03259' bibtex: '@article{Winkler_Schnierle_Ehrlich_Mehnert_Hunger_Sheveleva_Burkhardt_Bauer_Tuna_Ringenberg_et al._2021, title={Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) 3]+/0}, volume={60}, DOI={10.1021/acs.inorgchem.0c03259}, number={5}, journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Winkler, Mario and Schnierle, Marc and Ehrlich, Felix and Mehnert, Kim-Isabelle and Hunger, David and Sheveleva, Alena M. and Burkhardt, Lukas and Bauer, Matthias and Tuna, Floriana and Ringenberg, Mark R. and et al.}, year={2021}, pages={2856–2865} }' chicago: 'Winkler, Mario, Marc Schnierle, Felix Ehrlich, Kim-Isabelle Mehnert, David Hunger, Alena M. Sheveleva, Lukas Burkhardt, et al. “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(Dppf)Fe(CO) 3]+/0.” Inorganic Chemistry 60, no. 5 (2021): 2856–65. https://doi.org/10.1021/acs.inorgchem.0c03259.' ieee: 'M. Winkler et al., “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) 3]+/0,” Inorganic Chemistry, vol. 60, no. 5, pp. 2856–2865, 2021, doi: 10.1021/acs.inorgchem.0c03259.' mla: 'Winkler, Mario, et al. “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(Dppf)Fe(CO) 3]+/0.” Inorganic Chemistry, vol. 60, no. 5, American Chemical Society (ACS), 2021, pp. 2856–65, doi:10.1021/acs.inorgchem.0c03259.' short: M. Winkler, M. Schnierle, F. Ehrlich, K.-I. Mehnert, D. Hunger, A.M. Sheveleva, L. Burkhardt, M. Bauer, F. Tuna, M.R. Ringenberg, J. van Slageren, Inorganic Chemistry 60 (2021) 2856–2865. date_created: 2023-01-30T17:00:49Z date_updated: 2023-01-31T08:07:16Z department: - _id: '35' - _id: '306' doi: 10.1021/acs.inorgchem.0c03259 intvolume: ' 60' issue: '5' keyword: - Inorganic Chemistry - Physical and Theoretical Chemistry language: - iso: eng page: 2856-2865 publication: Inorganic Chemistry publication_identifier: issn: - 0020-1669 - 1520-510X publication_status: published publisher: American Chemical Society (ACS) status: public title: 'Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) 3]+/0' type: journal_article user_id: '48467' volume: 60 year: '2021' ... --- _id: '41011' abstract: - lang: eng text: The controlled assembly of well-defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D-structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe4, Fe6, and Fe7 nanoplatelets and calculated intermediates enable an unprecedented insight into the underlying building principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles. article_type: original author: - first_name: Uttam full_name: Chakraborty, Uttam last_name: Chakraborty - first_name: Patrick full_name: Bügel, Patrick last_name: Bügel - first_name: Lorena full_name: Fritsch, Lorena id: '44418' last_name: Fritsch - first_name: Florian full_name: Weigend, Florian last_name: Weigend - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Axel full_name: Jacobi von Wangelin, Axel last_name: Jacobi von Wangelin citation: ama: 'Chakraborty U, Bügel P, Fritsch L, Weigend F, Bauer M, Jacobi von Wangelin A. Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles. ChemistryOpen. 2021;10(2):265-271. doi:10.1002/open.202000307' apa: 'Chakraborty, U., Bügel, P., Fritsch, L., Weigend, F., Bauer, M., & Jacobi von Wangelin, A. (2021). Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles. ChemistryOpen, 10(2), 265–271. https://doi.org/10.1002/open.202000307' bibtex: '@article{Chakraborty_Bügel_Fritsch_Weigend_Bauer_Jacobi von Wangelin_2021, title={Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles}, volume={10}, DOI={10.1002/open.202000307}, number={2}, journal={ChemistryOpen}, publisher={Wiley}, author={Chakraborty, Uttam and Bügel, Patrick and Fritsch, Lorena and Weigend, Florian and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021}, pages={265–271} }' chicago: 'Chakraborty, Uttam, Patrick Bügel, Lorena Fritsch, Florian Weigend, Matthias Bauer, and Axel Jacobi von Wangelin. “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles.” ChemistryOpen 10, no. 2 (2021): 265–71. https://doi.org/10.1002/open.202000307.' ieee: 'U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, and A. Jacobi von Wangelin, “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles,” ChemistryOpen, vol. 10, no. 2, pp. 265–271, 2021, doi: 10.1002/open.202000307.' mla: 'Chakraborty, Uttam, et al. “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles.” ChemistryOpen, vol. 10, no. 2, Wiley, 2021, pp. 265–71, doi:10.1002/open.202000307.' short: U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, A. Jacobi von Wangelin, ChemistryOpen 10 (2021) 265–271. date_created: 2023-01-30T17:00:36Z date_updated: 2023-01-31T08:07:01Z department: - _id: '35' - _id: '306' doi: 10.1002/open.202000307 intvolume: ' 10' issue: '2' keyword: - General Chemistry language: - iso: eng page: 265-271 publication: ChemistryOpen publication_identifier: issn: - 2191-1363 - 2191-1363 publication_status: published publisher: Wiley status: public title: 'Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles' type: journal_article user_id: '48467' volume: 10 year: '2021' ... --- _id: '25894' abstract: - lang: eng text: Powder X-ray diffraction (XRD) patterns of ordered mesoporous CMK-8 and CMK-9 carbon materials are simulated by geometric modeling. The materials are amorphous at the atomic length scale but exhibit highly symmetric gyroidal structures at the nanometer scale, corresponding to regular, continuous nanopore systems with cubic symmetry. Their structures lead to characteristic low-angle XRD signatures. We introduce a model based on geometrical considerations to simulate CMK-8 and CMK-9 structures with variable volume fraction of carbon (vs. pore volume, i.e., variable 'pore wall thickness'). In addition, we also simulate carbon materials with variable amounts of guest species (e.g., sulfur) residing in their pores. The corresponding XRD patterns are calculated. The carbon volume fraction turns out to have a significant impact on the relative diffraction peak intensities, especially in case of CMK-9 carbon that features a bimodal porosity. Likewise, the presence of guest species in the pores may also strongly affect the relative peak intensities. Our study suggests that careful evaluation of experimental low-angle XRD patterns of (real) CMK-8 or CMK-9 materials offers an opportunity to obtain detailed information about the nanostructural properties in addition to the mere identification of the pore systems geometry. article_number: '110330' article_type: original author: - first_name: Bertram full_name: Schwind, Bertram last_name: Schwind - first_name: Jan-Henrik full_name: Smått, Jan-Henrik last_name: Smått - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: Christian full_name: Weinberger, Christian id: '11848' last_name: Weinberger citation: ama: Schwind B, Smått J-H, Tiemann M, Weinberger C. Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns. Microporous and Mesoporous Materials. Published online 2021. doi:10.1016/j.micromeso.2020.110330 apa: Schwind, B., Smått, J.-H., Tiemann, M., & Weinberger, C. (2021). Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns. Microporous and Mesoporous Materials, Article 110330. https://doi.org/10.1016/j.micromeso.2020.110330 bibtex: '@article{Schwind_Smått_Tiemann_Weinberger_2021, title={Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns}, DOI={10.1016/j.micromeso.2020.110330}, number={110330}, journal={Microporous and Mesoporous Materials}, author={Schwind, Bertram and Smått, Jan-Henrik and Tiemann, Michael and Weinberger, Christian}, year={2021} }' chicago: Schwind, Bertram, Jan-Henrik Smått, Michael Tiemann, and Christian Weinberger. “Modeling of Gyroidal Mesoporous CMK-8 and CMK-9 Carbon Nanostructures and Their X-Ray Diffraction Patterns.” Microporous and Mesoporous Materials, 2021. https://doi.org/10.1016/j.micromeso.2020.110330. ieee: 'B. Schwind, J.-H. Smått, M. Tiemann, and C. Weinberger, “Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns,” Microporous and Mesoporous Materials, Art. no. 110330, 2021, doi: 10.1016/j.micromeso.2020.110330.' mla: Schwind, Bertram, et al. “Modeling of Gyroidal Mesoporous CMK-8 and CMK-9 Carbon Nanostructures and Their X-Ray Diffraction Patterns.” Microporous and Mesoporous Materials, 110330, 2021, doi:10.1016/j.micromeso.2020.110330. short: B. Schwind, J.-H. Smått, M. Tiemann, C. Weinberger, Microporous and Mesoporous Materials (2021). date_created: 2021-10-08T10:02:31Z date_updated: 2023-03-07T10:44:44Z department: - _id: '35' - _id: '2' - _id: '307' doi: 10.1016/j.micromeso.2020.110330 language: - iso: eng publication: Microporous and Mesoporous Materials publication_identifier: issn: - 1387-1811 publication_status: published quality_controlled: '1' status: public title: Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns type: journal_article user_id: '23547' year: '2021' ... --- _id: '25897' abstract: - lang: eng text: A comparison of infrared spectroscopic analytical approaches was made in order to assess their applicability for internal structure characterization of SiO2 thin films. Markers for porosity and/or disorder based on the analysis of the asymmetric stretching absorption band of SiO2 between 900−1350 cm−1 were discussed. The shape of this band, which shows a well-defined LO–TO splitting, depends not only on the inherent characteristics of the film under analysis but also on the particular geometry of the IR experiment and the specific surface selection rules of the substrate. Three types of SiO2 thin films with clearly defined porosity ranging from dense films to mesoporous films were investigated by transmission (at different incidence angles), direct specular reflection (at different angles), and diffuse reflection. Two different types of substrate, metallic and semiconducting, were used. The combined effect of substrate and specific technique in the final shape of the band, was discussed, and the efficacy for their applicability to the determination of porosity in thin SiO2 films was critically evaluated. article_number: '103256' article_type: original author: - first_name: Teresa full_name: de los Arcos, Teresa last_name: de los Arcos - first_name: Hendrik full_name: Müller, Hendrik last_name: Müller - first_name: Fuzeng full_name: Wang, Fuzeng last_name: Wang - first_name: Varun Raj full_name: Damerla, Varun Raj last_name: Damerla - first_name: Christian full_name: Hoppe, Christian last_name: Hoppe - first_name: Christian full_name: Weinberger, Christian id: '11848' last_name: Weinberger - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: Guido full_name: Grundmeier, Guido id: '194' last_name: Grundmeier citation: ama: de los Arcos T, Müller H, Wang F, et al. Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films. Vibrational Spectroscopy. Published online 2021. doi:10.1016/j.vibspec.2021.103256 apa: de los Arcos, T., Müller, H., Wang, F., Damerla, V. R., Hoppe, C., Weinberger, C., Tiemann, M., & Grundmeier, G. (2021). Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films. Vibrational Spectroscopy, Article 103256. https://doi.org/10.1016/j.vibspec.2021.103256 bibtex: '@article{de los Arcos_Müller_Wang_Damerla_Hoppe_Weinberger_Tiemann_Grundmeier_2021, title={Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films}, DOI={10.1016/j.vibspec.2021.103256}, number={103256}, journal={Vibrational Spectroscopy}, author={de los Arcos, Teresa and Müller, Hendrik and Wang, Fuzeng and Damerla, Varun Raj and Hoppe, Christian and Weinberger, Christian and Tiemann, Michael and Grundmeier, Guido}, year={2021} }' chicago: Arcos, Teresa de los, Hendrik Müller, Fuzeng Wang, Varun Raj Damerla, Christian Hoppe, Christian Weinberger, Michael Tiemann, and Guido Grundmeier. “Review of Infrared Spectroscopy Techniques for the Determination of Internal Structure in Thin SiO2 Films.” Vibrational Spectroscopy, 2021. https://doi.org/10.1016/j.vibspec.2021.103256. ieee: 'T. de los Arcos et al., “Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films,” Vibrational Spectroscopy, Art. no. 103256, 2021, doi: 10.1016/j.vibspec.2021.103256.' mla: de los Arcos, Teresa, et al. “Review of Infrared Spectroscopy Techniques for the Determination of Internal Structure in Thin SiO2 Films.” Vibrational Spectroscopy, 103256, 2021, doi:10.1016/j.vibspec.2021.103256. short: T. de los Arcos, H. Müller, F. Wang, V.R. Damerla, C. Hoppe, C. Weinberger, M. Tiemann, G. Grundmeier, Vibrational Spectroscopy (2021). date_created: 2021-10-08T10:09:45Z date_updated: 2023-03-07T10:44:06Z department: - _id: '35' - _id: '2' - _id: '307' - _id: '302' doi: 10.1016/j.vibspec.2021.103256 language: - iso: eng publication: Vibrational Spectroscopy publication_identifier: issn: - 0924-2031 publication_status: published quality_controlled: '1' status: public title: Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films type: journal_article user_id: '23547' year: '2021' ... --- _id: '25893' abstract: - lang: eng text: Tailor-made ordered mesoporous materials bear great potential in numerous fields of application where large interfaces are required. However, the inherent surfacechemical properties of conventional materials, such as silica, carbon or organosilica, poses some limitations with respect to their application. Surface manipulation by functionalization with chemically more reactive groups is one way to improve materials for their desired purpose. Another approach is the design of high surface-area composite materials. The surface manipulation, either by functionalization or by introducing guest species, can be performed selectively. This means that when several distinct, i.e. , hierarchical, types of surfaces or pore systems exist in a material, each of them may be chosen for manipulation. Several strategies can be identified to achieve this goal. Molecules or molecule assemblies can be utilized to temporarily protect pores or surfaces (soft protection), while manipulation occurs at the accessible sites. This approach is a recurring motive in this review and can also be applied to rigid template matrices (hard protection). Furthermore, the size of functionalization agents (size protection) and their reactivity/diffusion (kinetic protection) into the pores can also be utilized to achieve selectivity. In addition, challenges in the synthesis and characterization of selectively manipulated ordered mesoporous materials are discussed. article_number: '2001153' article_type: review author: - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: Christian full_name: Weinberger, Christian id: '11848' last_name: Weinberger citation: ama: Tiemann M, Weinberger C. Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials. Advanced Materials Interfaces. Published online 2021. doi:10.1002/admi.202001153 apa: Tiemann, M., & Weinberger, C. (2021). Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials. Advanced Materials Interfaces, Article 2001153. https://doi.org/10.1002/admi.202001153 bibtex: '@article{Tiemann_Weinberger_2021, title={Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials}, DOI={10.1002/admi.202001153}, number={2001153}, journal={Advanced Materials Interfaces}, author={Tiemann, Michael and Weinberger, Christian}, year={2021} }' chicago: Tiemann, Michael, and Christian Weinberger. “Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials.” Advanced Materials Interfaces, 2021. https://doi.org/10.1002/admi.202001153. ieee: 'M. Tiemann and C. Weinberger, “Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials,” Advanced Materials Interfaces, Art. no. 2001153, 2021, doi: 10.1002/admi.202001153.' mla: Tiemann, Michael, and Christian Weinberger. “Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials.” Advanced Materials Interfaces, 2001153, 2021, doi:10.1002/admi.202001153. short: M. Tiemann, C. Weinberger, Advanced Materials Interfaces (2021). date_created: 2021-10-08T10:01:21Z date_updated: 2023-03-07T10:45:40Z department: - _id: '35' - _id: '2' - _id: '307' doi: 10.1002/admi.202001153 language: - iso: eng main_file_link: - open_access: '1' url: https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202001153 oa: '1' publication: Advanced Materials Interfaces publication_identifier: issn: - 2196-7350 - 2196-7350 publication_status: published quality_controlled: '1' status: public title: Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials type: journal_article user_id: '23547' year: '2021' ... --- _id: '25896' abstract: - lang: eng text: In this report, a flame spray pyrolysis setup has been examined with various in situ extraction methods of particle samples along the flame axis. First, two precursor formulations leading to the formation of iron oxide nanoparticles were used in a standardized SpraySyn burner system, and the final particle outcome was characterized by a broad range of established powder characterization techniques (TEM/HRTEM, SAXS, XRD, BET). The characterization of the powder products evidenced that mostly homogeneous gas-to-particle conversion takes place when applying an acidic precursor solution, whereas the absence of the acid leads to a dominant droplet-to-particle pathway. Our study indicates that a droplet-to-particle-pathway could be present even when processing the acidic formulation. However, even if a secondary pathway might take place in this case as well, it is not dominant and nearly negligible. Subsequently, the in situ particle structure evolution was investigated for the dominant gas-to-particle pathway, and particles were extracted along the flame axis for online SMPS and offline TEM/HRTEM analysis. Due to the highly reactive conditions within the flame (high temperatures, turbulent flow field, high particle number concentrations), the extraction of representative samples from spray flames is challenging. In order to handle the reactive conditions, two extraction techniques were tailored in this report. To extract an aerosol sample within the flame for SMPS measurement, a Hole in a Tube probe was adjusted. Thus, the mobility particle diameter as well as the corresponding distribution widths were obtained at different heights above the burner along the flame axis. For TEM/HRTEM image analysis, particle samples were collected thermophoretically by means of a tailored shutter system. Since all sampling grids were protected until reaching the flame axis and due to the low sampling time, momentary captures of local particle structures could be extracted precisely. The particle morphologies have clearly shown an evolution from spherical and paired particles in the flame center to fractal and compact agglomerates at later synthesis stages. article_number: '105722' article_type: original author: - first_name: R. full_name: Tischendorf, R. last_name: Tischendorf - first_name: M. full_name: Simmler, M. last_name: Simmler - first_name: Christian full_name: Weinberger, Christian id: '11848' last_name: Weinberger - first_name: M. full_name: Bieber, M. last_name: Bieber - first_name: M. full_name: Reddemann, M. last_name: Reddemann - first_name: F. full_name: Fröde, F. last_name: Fröde - first_name: J. full_name: Lindner, J. last_name: Lindner - first_name: H. full_name: Pitsch, H. last_name: Pitsch - first_name: R. full_name: Kneer, R. last_name: Kneer - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: H. full_name: Nirschl, H. last_name: Nirschl - first_name: H.-J. full_name: Schmid, H.-J. last_name: Schmid citation: ama: Tischendorf R, Simmler M, Weinberger C, et al. Examination of the evolution of iron oxide nanoparticles in flame spray pyrolysis by tailored in situ particle sampling techniques. Journal of Aerosol Science. Published online 2021. doi:10.1016/j.jaerosci.2020.105722 apa: Tischendorf, R., Simmler, M., Weinberger, C., Bieber, M., Reddemann, M., Fröde, F., Lindner, J., Pitsch, H., Kneer, R., Tiemann, M., Nirschl, H., & Schmid, H.-J. (2021). Examination of the evolution of iron oxide nanoparticles in flame spray pyrolysis by tailored in situ particle sampling techniques. Journal of Aerosol Science, Article 105722. https://doi.org/10.1016/j.jaerosci.2020.105722 bibtex: '@article{Tischendorf_Simmler_Weinberger_Bieber_Reddemann_Fröde_Lindner_Pitsch_Kneer_Tiemann_et al._2021, title={Examination of the evolution of iron oxide nanoparticles in flame spray pyrolysis by tailored in situ particle sampling techniques}, DOI={10.1016/j.jaerosci.2020.105722}, number={105722}, journal={Journal of Aerosol Science}, author={Tischendorf, R. and Simmler, M. and Weinberger, Christian and Bieber, M. and Reddemann, M. and Fröde, F. and Lindner, J. and Pitsch, H. and Kneer, R. and Tiemann, Michael and et al.}, year={2021} }' chicago: Tischendorf, R., M. Simmler, Christian Weinberger, M. Bieber, M. Reddemann, F. Fröde, J. Lindner, et al. “Examination of the Evolution of Iron Oxide Nanoparticles in Flame Spray Pyrolysis by Tailored in Situ Particle Sampling Techniques.” Journal of Aerosol Science, 2021. https://doi.org/10.1016/j.jaerosci.2020.105722. ieee: 'R. Tischendorf et al., “Examination of the evolution of iron oxide nanoparticles in flame spray pyrolysis by tailored in situ particle sampling techniques,” Journal of Aerosol Science, Art. no. 105722, 2021, doi: 10.1016/j.jaerosci.2020.105722.' mla: Tischendorf, R., et al. “Examination of the Evolution of Iron Oxide Nanoparticles in Flame Spray Pyrolysis by Tailored in Situ Particle Sampling Techniques.” Journal of Aerosol Science, 105722, 2021, doi:10.1016/j.jaerosci.2020.105722. short: R. Tischendorf, M. Simmler, C. Weinberger, M. Bieber, M. Reddemann, F. Fröde, J. Lindner, H. Pitsch, R. Kneer, M. Tiemann, H. Nirschl, H.-J. Schmid, Journal of Aerosol Science (2021). date_created: 2021-10-08T10:07:18Z date_updated: 2023-03-08T08:07:30Z department: - _id: '9' - _id: '35' - _id: '2' - _id: '307' doi: 10.1016/j.jaerosci.2020.105722 language: - iso: eng publication: Journal of Aerosol Science publication_identifier: issn: - 0021-8502 publication_status: published quality_controlled: '1' status: public title: Examination of the evolution of iron oxide nanoparticles in flame spray pyrolysis by tailored in situ particle sampling techniques type: journal_article user_id: '23547' year: '2021' ... --- _id: '22635' abstract: - lang: eng text: Photodynamic therapy (PDT) using TiO2 nanoparticles has become an important alternative treatment for different types of cancer due to their high photocatalytic activity and high absorption of UV-A light. To potentiate this treatment, we have coated commercial glass plates with TiO2 nanoparticles prepared by the sol–gel method (TiO2-m), which exhibit a remarkable selectivity for the irreversible trapping of cancer cells. The physicochemical properties of the deposited TiO2-m nanoparticle coatings have been characterized by a number of complementary surface-analytical techniques and their interaction with leukemia and healthy blood cells were investigated. Scanning electron and atomic force microscopy verify the formation of a compact layer of TiO2-m nanoparticles. The particles are predominantly in the anatase phase and have hydroxyl-terminated surfaces as revealed by Raman, X-ray photoelectron, and infrared spectroscopy, as well as X-ray diffraction. We find that lymphoblastic leukemia cells adhere to the TiO2-m coating and undergo amoeboid-like migration, whereas lymphocytic cells show distinctly weaker interactions with the coating. This evidences the potential of this nanomaterial coating to selectively trap cancer cells and renders it a promising candidate for the development of future prototypes of PDT devices for the treatment of leukemia and other types of cancers with non-adherent cells. article_type: original author: - first_name: Jaime Andres full_name: Garcia Diosa, Jaime Andres last_name: Garcia Diosa - first_name: Alejandro full_name: Gonzalez Orive, Alejandro last_name: Gonzalez Orive - first_name: Christian full_name: Weinberger, Christian id: '11848' last_name: Weinberger - first_name: Sabrina full_name: Schwiderek, Sabrina last_name: Schwiderek - first_name: Steffen full_name: Knust, Steffen last_name: Knust - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: Guido full_name: Grundmeier, Guido id: '194' last_name: Grundmeier - first_name: Adrian full_name: Keller, Adrian id: '48864' last_name: Keller orcid: 0000-0001-7139-3110 - first_name: Ruben Jesus full_name: Camargo Amado, Ruben Jesus last_name: Camargo Amado citation: ama: 'Garcia Diosa JA, Gonzalez Orive A, Weinberger C, et al. TiO2 nanoparticle coatings on glass surfaces for the selective trapping of leukemia cells from peripheral blood. Journal of Biomedical Materials Research Part B: Applied Biomaterials. 2021;109:2142–2153. doi:10.1002/jbm.b.34862' apa: 'Garcia Diosa, J. A., Gonzalez Orive, A., Weinberger, C., Schwiderek, S., Knust, S., Tiemann, M., Grundmeier, G., Keller, A., & Camargo Amado, R. J. (2021). TiO2 nanoparticle coatings on glass surfaces for the selective trapping of leukemia cells from peripheral blood. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 109, 2142–2153. https://doi.org/10.1002/jbm.b.34862' bibtex: '@article{Garcia Diosa_Gonzalez Orive_Weinberger_Schwiderek_Knust_Tiemann_Grundmeier_Keller_Camargo Amado_2021, title={TiO2 nanoparticle coatings on glass surfaces for the selective trapping of leukemia cells from peripheral blood}, volume={109}, DOI={10.1002/jbm.b.34862}, journal={Journal of Biomedical Materials Research Part B: Applied Biomaterials}, author={Garcia Diosa, Jaime Andres and Gonzalez Orive, Alejandro and Weinberger, Christian and Schwiderek, Sabrina and Knust, Steffen and Tiemann, Michael and Grundmeier, Guido and Keller, Adrian and Camargo Amado, Ruben Jesus}, year={2021}, pages={2142–2153} }' chicago: 'Garcia Diosa, Jaime Andres, Alejandro Gonzalez Orive, Christian Weinberger, Sabrina Schwiderek, Steffen Knust, Michael Tiemann, Guido Grundmeier, Adrian Keller, and Ruben Jesus Camargo Amado. “TiO2 Nanoparticle Coatings on Glass Surfaces for the Selective Trapping of Leukemia Cells from Peripheral Blood.” Journal of Biomedical Materials Research Part B: Applied Biomaterials 109 (2021): 2142–2153. https://doi.org/10.1002/jbm.b.34862.' ieee: 'J. A. Garcia Diosa et al., “TiO2 nanoparticle coatings on glass surfaces for the selective trapping of leukemia cells from peripheral blood,” Journal of Biomedical Materials Research Part B: Applied Biomaterials, vol. 109, pp. 2142–2153, 2021, doi: 10.1002/jbm.b.34862.' mla: 'Garcia Diosa, Jaime Andres, et al. “TiO2 Nanoparticle Coatings on Glass Surfaces for the Selective Trapping of Leukemia Cells from Peripheral Blood.” Journal of Biomedical Materials Research Part B: Applied Biomaterials, vol. 109, 2021, pp. 2142–2153, doi:10.1002/jbm.b.34862.' short: 'J.A. Garcia Diosa, A. Gonzalez Orive, C. Weinberger, S. Schwiderek, S. Knust, M. Tiemann, G. Grundmeier, A. Keller, R.J. Camargo Amado, Journal of Biomedical Materials Research Part B: Applied Biomaterials 109 (2021) 2142–2153.' date_created: 2021-07-08T11:34:21Z date_updated: 2023-03-08T08:10:25Z department: - _id: '302' - _id: '307' - _id: '35' - _id: '2' doi: 10.1002/jbm.b.34862 intvolume: ' 109' language: - iso: eng page: 2142–2153 publication: 'Journal of Biomedical Materials Research Part B: Applied Biomaterials' publication_identifier: issn: - 1552-4973 - 1552-4981 publication_status: published quality_controlled: '1' status: public title: TiO2 nanoparticle coatings on glass surfaces for the selective trapping of leukemia cells from peripheral blood type: journal_article user_id: '23547' volume: 109 year: '2021' ... --- _id: '25892' abstract: - lang: eng text: The tetratopic linker 1,1,2,2-tetrakis(4-phosphonophenyl)ethylene (H8TPPE) was used to synthesize the three new porous metal–organic frameworks of composition [M2(H2O)2(H2TPPE)]·xH2O (M = Al3+, Ga3+, Fe3+), denoted as M-CAU-53 under hydrothermal reaction conditions, using the corresponding metal nitrates as starting materials. The crystal structures of the compounds were determined ab initio from powder X-ray diffraction data, revealing small structural differences. Proton conductivity measurements were carried out, indicating different conductivity mechanisms. The differences in proton conductivity could be linked to the individual structures. In addition, a thorough characterization via thermogravimetry, elemental analysis, IR-spectroscopy as well as N2- and H2O-sorption is given. article_type: original author: - first_name: Felix full_name: Steinke, Felix last_name: Steinke - first_name: Ali full_name: Javed, Ali last_name: Javed - first_name: Stephan full_name: Wöhlbrandt, Stephan last_name: Wöhlbrandt - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: Norbert full_name: Stock, Norbert last_name: Stock citation: ama: Steinke F, Javed A, Wöhlbrandt S, Tiemann M, Stock N. New isoreticular phosphonate MOFs based on a tetratopic linker. Dalton Transactions. Published online 2021:13572-13579. doi:10.1039/d1dt02610k apa: Steinke, F., Javed, A., Wöhlbrandt, S., Tiemann, M., & Stock, N. (2021). New isoreticular phosphonate MOFs based on a tetratopic linker. Dalton Transactions, 13572–13579. https://doi.org/10.1039/d1dt02610k bibtex: '@article{Steinke_Javed_Wöhlbrandt_Tiemann_Stock_2021, title={New isoreticular phosphonate MOFs based on a tetratopic linker}, DOI={10.1039/d1dt02610k}, journal={Dalton Transactions}, author={Steinke, Felix and Javed, Ali and Wöhlbrandt, Stephan and Tiemann, Michael and Stock, Norbert}, year={2021}, pages={13572–13579} }' chicago: Steinke, Felix, Ali Javed, Stephan Wöhlbrandt, Michael Tiemann, and Norbert Stock. “New Isoreticular Phosphonate MOFs Based on a Tetratopic Linker.” Dalton Transactions, 2021, 13572–79. https://doi.org/10.1039/d1dt02610k. ieee: 'F. Steinke, A. Javed, S. Wöhlbrandt, M. Tiemann, and N. Stock, “New isoreticular phosphonate MOFs based on a tetratopic linker,” Dalton Transactions, pp. 13572–13579, 2021, doi: 10.1039/d1dt02610k.' mla: Steinke, Felix, et al. “New Isoreticular Phosphonate MOFs Based on a Tetratopic Linker.” Dalton Transactions, 2021, pp. 13572–79, doi:10.1039/d1dt02610k. short: F. Steinke, A. Javed, S. Wöhlbrandt, M. Tiemann, N. Stock, Dalton Transactions (2021) 13572–13579. date_created: 2021-10-08T09:57:34Z date_updated: 2023-03-08T08:08:22Z department: - _id: '2' - _id: '307' doi: 10.1039/d1dt02610k language: - iso: eng page: 13572-13579 publication: Dalton Transactions publication_identifier: issn: - 1477-9226 - 1477-9234 publication_status: published quality_controlled: '1' status: public title: New isoreticular phosphonate MOFs based on a tetratopic linker type: journal_article user_id: '23547' year: '2021' ... --- _id: '41007' abstract: - lang: eng text: Two closely related FeII complexes with 2,6-bis(1-ethyl-1H-1,2,3-triazol-4yl)pyridine and 2,6-bis(1,2,3-triazol-5-ylidene)pyridine ligands are presented to gain new insights into the photophysics of bis(tridentate) iron(II) complexes. The [Fe(N^N^N)2]2+ pseudoisomer sensitizes singlet oxygen through a MC state with nanosecond lifetime after MLCT excitation, while the bis(tridentate) [Fe(C^N^C)2]2+ pseudoisomer possesses a similar 3MLCT lifetime as the tris(bidentate) [Fe(C^C)2(N^N)]2+ complexes with four mesoionic carbenes. article_type: original author: - first_name: Philipp full_name: Dierks, Philipp last_name: Dierks - first_name: Ayla full_name: Kruse, Ayla last_name: Kruse - first_name: Olga S. full_name: Bokareva, Olga S. last_name: Bokareva - first_name: Mohammed J. full_name: Al-Marri, Mohammed J. last_name: Al-Marri - first_name: Jens full_name: Kalmbach, Jens last_name: Kalmbach - first_name: Marc full_name: Baltrun, Marc last_name: Baltrun - first_name: Adam full_name: Neuba, Adam last_name: Neuba - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Stephan full_name: Hohloch, Stephan last_name: Hohloch - first_name: Katja full_name: Heinze, Katja last_name: Heinze - first_name: Michael full_name: Seitz, Michael last_name: Seitz - first_name: Oliver full_name: Kühn, Oliver last_name: Kühn - first_name: Stefan full_name: Lochbrunner, Stefan last_name: Lochbrunner - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 citation: ama: Dierks P, Kruse A, Bokareva OS, et al. Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes. Chemical Communications. 2021;57(54):6640-6643. doi:10.1039/d1cc01716k apa: Dierks, P., Kruse, A., Bokareva, O. S., Al-Marri, M. J., Kalmbach, J., Baltrun, M., Neuba, A., Schoch, R., Hohloch, S., Heinze, K., Seitz, M., Kühn, O., Lochbrunner, S., & Bauer, M. (2021). Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes. Chemical Communications, 57(54), 6640–6643. https://doi.org/10.1039/d1cc01716k bibtex: '@article{Dierks_Kruse_Bokareva_Al-Marri_Kalmbach_Baltrun_Neuba_Schoch_Hohloch_Heinze_et al._2021, title={Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes}, volume={57}, DOI={10.1039/d1cc01716k}, number={54}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Dierks, Philipp and Kruse, Ayla and Bokareva, Olga S. and Al-Marri, Mohammed J. and Kalmbach, Jens and Baltrun, Marc and Neuba, Adam and Schoch, Roland and Hohloch, Stephan and Heinze, Katja and et al.}, year={2021}, pages={6640–6643} }' chicago: 'Dierks, Philipp, Ayla Kruse, Olga S. Bokareva, Mohammed J. Al-Marri, Jens Kalmbach, Marc Baltrun, Adam Neuba, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric Iron(Ii) Complexes.” Chemical Communications 57, no. 54 (2021): 6640–43. https://doi.org/10.1039/d1cc01716k.' ieee: 'P. Dierks et al., “Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes,” Chemical Communications, vol. 57, no. 54, pp. 6640–6643, 2021, doi: 10.1039/d1cc01716k.' mla: Dierks, Philipp, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric Iron(Ii) Complexes.” Chemical Communications, vol. 57, no. 54, Royal Society of Chemistry (RSC), 2021, pp. 6640–43, doi:10.1039/d1cc01716k. short: P. Dierks, A. Kruse, O.S. Bokareva, M.J. Al-Marri, J. Kalmbach, M. Baltrun, A. Neuba, R. Schoch, S. Hohloch, K. Heinze, M. Seitz, O. Kühn, S. Lochbrunner, M. Bauer, Chemical Communications 57 (2021) 6640–6643. date_created: 2023-01-30T16:59:55Z date_updated: 2024-10-11T08:42:44Z department: - _id: '35' - _id: '306' doi: 10.1039/d1cc01716k intvolume: ' 57' issue: '54' keyword: - Materials Chemistry - Metals and Alloys - Surfaces - Coatings and Films - General Chemistry - Ceramics and Composite - Metallkomplexe - Optical and Magnetic Materials - Catalysis language: - iso: eng page: 6640-6643 publication: Chemical Communications publication_identifier: issn: - 1359-7345 - 1364-548X publication_status: published publisher: Royal Society of Chemistry (RSC) status: public title: Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes type: journal_article user_id: '48467' volume: 57 year: '2021' ... --- _id: '18534' author: - first_name: Yannik full_name: Vukadinovic, Yannik last_name: Vukadinovic - first_name: Lukas full_name: Burkhardt, Lukas last_name: Burkhardt - first_name: Ayla full_name: Päpcke, Ayla last_name: Päpcke - first_name: Anabel full_name: Miletic, Anabel last_name: Miletic - first_name: Lorena full_name: Fritsch, Lorena last_name: Fritsch - first_name: Björn full_name: Altenburger, Björn last_name: Altenburger - first_name: Roland full_name: Schoch, Roland last_name: Schoch - first_name: Adam full_name: Neuba, Adam last_name: Neuba - first_name: Stefan full_name: Lochbrunner, Stefan last_name: Lochbrunner - first_name: Matthias full_name: Bauer, Matthias last_name: Bauer citation: ama: 'Vukadinovic Y, Burkhardt L, Päpcke A, et al. When Donors Turn into Acceptors: Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands. Inorganic Chemistry. 2020:8762-8774. doi:10.1021/acs.inorgchem.0c00393' apa: 'Vukadinovic, Y., Burkhardt, L., Päpcke, A., Miletic, A., Fritsch, L., Altenburger, B., … Bauer, M. (2020). When Donors Turn into Acceptors: Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands. Inorganic Chemistry, 8762–8774. https://doi.org/10.1021/acs.inorgchem.0c00393' bibtex: '@article{Vukadinovic_Burkhardt_Päpcke_Miletic_Fritsch_Altenburger_Schoch_Neuba_Lochbrunner_Bauer_2020, title={When Donors Turn into Acceptors: Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands}, DOI={10.1021/acs.inorgchem.0c00393}, journal={Inorganic Chemistry}, author={Vukadinovic, Yannik and Burkhardt, Lukas and Päpcke, Ayla and Miletic, Anabel and Fritsch, Lorena and Altenburger, Björn and Schoch, Roland and Neuba, Adam and Lochbrunner, Stefan and Bauer, Matthias}, year={2020}, pages={8762–8774} }' chicago: 'Vukadinovic, Yannik, Lukas Burkhardt, Ayla Päpcke, Anabel Miletic, Lorena Fritsch, Björn Altenburger, Roland Schoch, Adam Neuba, Stefan Lochbrunner, and Matthias Bauer. “When Donors Turn into Acceptors: Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-Imidazole-2-Ylidene Pyridine Ligands.” Inorganic Chemistry, 2020, 8762–74. https://doi.org/10.1021/acs.inorgchem.0c00393.' ieee: 'Y. Vukadinovic et al., “When Donors Turn into Acceptors: Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands,” Inorganic Chemistry, pp. 8762–8774, 2020.' mla: 'Vukadinovic, Yannik, et al. “When Donors Turn into Acceptors: Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-Imidazole-2-Ylidene Pyridine Ligands.” Inorganic Chemistry, 2020, pp. 8762–74, doi:10.1021/acs.inorgchem.0c00393.' short: Y. Vukadinovic, L. Burkhardt, A. Päpcke, A. Miletic, L. Fritsch, B. Altenburger, R. Schoch, A. Neuba, S. Lochbrunner, M. Bauer, Inorganic Chemistry (2020) 8762–8774. date_created: 2020-08-28T09:08:09Z date_updated: 2022-01-06T06:53:36Z department: - _id: '35' - _id: '306' doi: 10.1021/acs.inorgchem.0c00393 language: - iso: eng page: 8762-8774 publication: Inorganic Chemistry publication_identifier: issn: - 0020-1669 - 1520-510X publication_status: published status: public title: 'When Donors Turn into Acceptors: Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands' type: journal_article user_id: '54038' year: '2020' ... --- _id: '41022' author: - first_name: Manuel full_name: Kirchhof, Manuel last_name: Kirchhof - first_name: Katrin full_name: Gugeler, Katrin last_name: Gugeler - first_name: Felix Richard full_name: Fischer, Felix Richard last_name: Fischer - first_name: Michał full_name: Nowakowski, Michał id: '78878' last_name: Nowakowski orcid: 0000-0002-3734-7011 - first_name: Alina full_name: Bauer, Alina last_name: Bauer - first_name: Sonia full_name: Alvarez-Barcia, Sonia last_name: Alvarez-Barcia - first_name: Karina full_name: Abitaev, Karina last_name: Abitaev - first_name: Marc full_name: Schnierle, Marc last_name: Schnierle - first_name: Yaseen full_name: Qawasmi, Yaseen last_name: Qawasmi - first_name: Wolfgang full_name: Frey, Wolfgang last_name: Frey - first_name: Angelika full_name: Baro, Angelika last_name: Baro - first_name: Deven P. full_name: Estes, Deven P. last_name: Estes - first_name: Thomas full_name: Sottmann, Thomas last_name: Sottmann - first_name: Mark R. full_name: Ringenberg, Mark R. last_name: Ringenberg - first_name: Bernd full_name: Plietker, Bernd last_name: Plietker - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Johannes full_name: Kästner, Johannes last_name: Kästner - first_name: Sabine full_name: Laschat, Sabine last_name: Laschat citation: ama: Kirchhof M, Gugeler K, Fischer FR, et al. Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions. Organometallics. 2020;39(17):3131-3145. doi:10.1021/acs.organomet.0c00310 apa: Kirchhof, M., Gugeler, K., Fischer, F. R., Nowakowski, M., Bauer, A., Alvarez-Barcia, S., Abitaev, K., Schnierle, M., Qawasmi, Y., Frey, W., Baro, A., Estes, D. P., Sottmann, T., Ringenberg, M. R., Plietker, B., Bauer, M., Kästner, J., & Laschat, S. (2020). Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions. Organometallics, 39(17), 3131–3145. https://doi.org/10.1021/acs.organomet.0c00310 bibtex: '@article{Kirchhof_Gugeler_Fischer_Nowakowski_Bauer_Alvarez-Barcia_Abitaev_Schnierle_Qawasmi_Frey_et al._2020, title={Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions}, volume={39}, DOI={10.1021/acs.organomet.0c00310}, number={17}, journal={Organometallics}, publisher={American Chemical Society (ACS)}, author={Kirchhof, Manuel and Gugeler, Katrin and Fischer, Felix Richard and Nowakowski, Michał and Bauer, Alina and Alvarez-Barcia, Sonia and Abitaev, Karina and Schnierle, Marc and Qawasmi, Yaseen and Frey, Wolfgang and et al.}, year={2020}, pages={3131–3145} }' chicago: 'Kirchhof, Manuel, Katrin Gugeler, Felix Richard Fischer, Michał Nowakowski, Alina Bauer, Sonia Alvarez-Barcia, Karina Abitaev, et al. “Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions.” Organometallics 39, no. 17 (2020): 3131–45. https://doi.org/10.1021/acs.organomet.0c00310.' ieee: 'M. Kirchhof et al., “Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions,” Organometallics, vol. 39, no. 17, pp. 3131–3145, 2020, doi: 10.1021/acs.organomet.0c00310.' mla: Kirchhof, Manuel, et al. “Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions.” Organometallics, vol. 39, no. 17, American Chemical Society (ACS), 2020, pp. 3131–45, doi:10.1021/acs.organomet.0c00310. short: M. Kirchhof, K. Gugeler, F.R. Fischer, M. Nowakowski, A. Bauer, S. Alvarez-Barcia, K. Abitaev, M. Schnierle, Y. Qawasmi, W. Frey, A. Baro, D.P. Estes, T. Sottmann, M.R. Ringenberg, B. Plietker, M. Bauer, J. Kästner, S. Laschat, Organometallics 39 (2020) 3131–3145. date_created: 2023-01-30T17:37:18Z date_updated: 2024-05-07T11:41:01Z department: - _id: '35' - _id: '306' doi: 10.1021/acs.organomet.0c00310 intvolume: ' 39' issue: '17' keyword: - Inorganic Chemistry - Organic Chemistry - Physical and Theoretical Chemistry language: - iso: eng page: 3131-3145 publication: Organometallics publication_identifier: issn: - 0276-7333 - 1520-6041 publication_status: published publisher: American Chemical Society (ACS) status: public title: Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions type: journal_article user_id: '48467' volume: 39 year: '2020' ... --- _id: '41015' author: - first_name: Mathis full_name: Benedikter, Mathis last_name: Benedikter - first_name: Janis full_name: Musso, Janis last_name: Musso - first_name: Manoj K. full_name: Kesharwani, Manoj K. last_name: Kesharwani - first_name: K. Leonard full_name: Sterz, K. Leonard last_name: Sterz - first_name: Iris full_name: Elser, Iris last_name: Elser - first_name: Felix full_name: Ziegler, Felix last_name: Ziegler - first_name: Felix full_name: Fischer, Felix last_name: Fischer - first_name: Bernd full_name: Plietker, Bernd last_name: Plietker - first_name: Wolfgang full_name: Frey, Wolfgang last_name: Frey - first_name: Johannes full_name: Kästner, Johannes last_name: Kästner - first_name: Mario full_name: Winkler, Mario last_name: Winkler - first_name: Joris full_name: van Slageren, Joris last_name: van Slageren - first_name: Michał full_name: Nowakowski, Michał id: '78878' last_name: Nowakowski orcid: 0000-0002-3734-7011 - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Michael R. full_name: Buchmeiser, Michael R. last_name: Buchmeiser citation: ama: 'Benedikter M, Musso J, Kesharwani MK, et al. Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis. 2020;10(24):14810-14823. doi:10.1021/acscatal.0c03978' apa: 'Benedikter, M., Musso, J., Kesharwani, M. K., Sterz, K. L., Elser, I., Ziegler, F., Fischer, F., Plietker, B., Frey, W., Kästner, J., Winkler, M., van Slageren, J., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2020). Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis, 10(24), 14810–14823. https://doi.org/10.1021/acscatal.0c03978' bibtex: '@article{Benedikter_Musso_Kesharwani_Sterz_Elser_Ziegler_Fischer_Plietker_Frey_Kästner_et al._2020, title={Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach}, volume={10}, DOI={10.1021/acscatal.0c03978}, number={24}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz, K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker, Bernd and Frey, Wolfgang and Kästner, Johannes and et al.}, year={2020}, pages={14810–14823} }' chicago: 'Benedikter, Mathis, Janis Musso, Manoj K. Kesharwani, K. Leonard Sterz, Iris Elser, Felix Ziegler, Felix Fischer, et al. “Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis 10, no. 24 (2020): 14810–23. https://doi.org/10.1021/acscatal.0c03978.' ieee: 'M. Benedikter et al., “Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach,” ACS Catalysis, vol. 10, no. 24, pp. 14810–14823, 2020, doi: 10.1021/acscatal.0c03978.' mla: 'Benedikter, Mathis, et al. “Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis, vol. 10, no. 24, American Chemical Society (ACS), 2020, pp. 14810–23, doi:10.1021/acscatal.0c03978.' short: M. Benedikter, J. Musso, M.K. Kesharwani, K.L. Sterz, I. Elser, F. Ziegler, F. Fischer, B. Plietker, W. Frey, J. Kästner, M. Winkler, J. van Slageren, M. Nowakowski, M. Bauer, M.R. Buchmeiser, ACS Catalysis 10 (2020) 14810–14823. date_created: 2023-01-30T17:12:11Z date_updated: 2024-05-07T11:42:56Z department: - _id: '35' - _id: '306' doi: 10.1021/acscatal.0c03978 intvolume: ' 10' issue: '24' keyword: - Catalysis - General Chemistry language: - iso: eng page: 14810-14823 publication: ACS Catalysis publication_identifier: issn: - 2155-5435 - 2155-5435 publication_status: published publisher: American Chemical Society (ACS) status: public title: 'Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach' type: journal_article user_id: '48467' volume: 10 year: '2020' ... --- _id: '41020' author: - first_name: Bernhard J. full_name: Gregori, Bernhard J. last_name: Gregori - first_name: Michał full_name: Nowakowski, Michał id: '78878' last_name: Nowakowski orcid: 0000-0002-3734-7011 - first_name: Anke full_name: Schoch, Anke id: '27611' last_name: Schoch orcid: 0000-0002-9457-400X - first_name: Simon full_name: Pöllath, Simon last_name: Pöllath - first_name: Josef full_name: Zweck, Josef last_name: Zweck - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Axel full_name: Jacobi von Wangelin, Axel last_name: Jacobi von Wangelin citation: ama: Gregori BJ, Nowakowski M, Schoch A, et al. Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes. ChemCatChem. 2020;12(21):5359-5363. doi:10.1002/cctc.202000994 apa: Gregori, B. J., Nowakowski, M., Schoch, A., Pöllath, S., Zweck, J., Bauer, M., & Jacobi von Wangelin, A. (2020). Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes. ChemCatChem, 12(21), 5359–5363. https://doi.org/10.1002/cctc.202000994 bibtex: '@article{Gregori_Nowakowski_Schoch_Pöllath_Zweck_Bauer_Jacobi von Wangelin_2020, title={Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}, volume={12}, DOI={10.1002/cctc.202000994}, number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Gregori, Bernhard J. and Nowakowski, Michał and Schoch, Anke and Pöllath, Simon and Zweck, Josef and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2020}, pages={5359–5363} }' chicago: 'Gregori, Bernhard J., Michał Nowakowski, Anke Schoch, Simon Pöllath, Josef Zweck, Matthias Bauer, and Axel Jacobi von Wangelin. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes.” ChemCatChem 12, no. 21 (2020): 5359–63. https://doi.org/10.1002/cctc.202000994.' ieee: 'B. J. Gregori et al., “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes,” ChemCatChem, vol. 12, no. 21, pp. 5359–5363, 2020, doi: 10.1002/cctc.202000994.' mla: Gregori, Bernhard J., et al. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes.” ChemCatChem, vol. 12, no. 21, Wiley, 2020, pp. 5359–63, doi:10.1002/cctc.202000994. short: B.J. Gregori, M. Nowakowski, A. Schoch, S. Pöllath, J. Zweck, M. Bauer, A. Jacobi von Wangelin, ChemCatChem 12 (2020) 5359–5363. date_created: 2023-01-30T17:35:14Z date_updated: 2024-05-07T11:40:10Z department: - _id: '35' - _id: '306' doi: 10.1002/cctc.202000994 intvolume: ' 12' issue: '21' keyword: - Inorganic Chemistry - Organic Chemistry - Physical and Theoretical Chemistry - Catalysis language: - iso: eng page: 5359-5363 publication: ChemCatChem publication_identifier: issn: - 1867-3880 - 1867-3899 publication_status: published publisher: Wiley status: public title: Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes type: journal_article user_id: '48467' volume: 12 year: '2020' ... --- _id: '16311' author: - first_name: Lukas full_name: Burkhardt, Lukas id: '54038' last_name: Burkhardt orcid: 0000-0003-0747-9811 - first_name: Yannik full_name: Vukadinovic, Yannik last_name: Vukadinovic - first_name: Michał full_name: Nowakowski, Michał id: '78878' last_name: Nowakowski orcid: 0000-0002-3734-7011 - first_name: Aleksandr full_name: Kalinko, Aleksandr last_name: Kalinko - first_name: Julian full_name: Rudolph, Julian last_name: Rudolph - first_name: Per-Anders full_name: Carlsson, Per-Anders last_name: Carlsson - first_name: Christoph R. full_name: Jacob, Christoph R. last_name: Jacob - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 citation: ama: Burkhardt L, Vukadinovic Y, Nowakowski M, et al. Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy. Inorganic Chemistry. Published online 2020:3551-3561. doi:10.1021/acs.inorgchem.9b02092 apa: Burkhardt, L., Vukadinovic, Y., Nowakowski, M., Kalinko, A., Rudolph, J., Carlsson, P.-A., Jacob, C. R., & Bauer, M. (2020). Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy. Inorganic Chemistry, 3551–3561. https://doi.org/10.1021/acs.inorgchem.9b02092 bibtex: '@article{Burkhardt_Vukadinovic_Nowakowski_Kalinko_Rudolph_Carlsson_Jacob_Bauer_2020, title={Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy}, DOI={10.1021/acs.inorgchem.9b02092}, journal={Inorganic Chemistry}, author={Burkhardt, Lukas and Vukadinovic, Yannik and Nowakowski, Michał and Kalinko, Aleksandr and Rudolph, Julian and Carlsson, Per-Anders and Jacob, Christoph R. and Bauer, Matthias}, year={2020}, pages={3551–3561} }' chicago: Burkhardt, Lukas, Yannik Vukadinovic, Michał Nowakowski, Aleksandr Kalinko, Julian Rudolph, Per-Anders Carlsson, Christoph R. Jacob, and Matthias Bauer. “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-Ray Emission and Absorption Spectroscopy.” Inorganic Chemistry, 2020, 3551–61. https://doi.org/10.1021/acs.inorgchem.9b02092. ieee: 'L. Burkhardt et al., “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy,” Inorganic Chemistry, pp. 3551–3561, 2020, doi: 10.1021/acs.inorgchem.9b02092.' mla: Burkhardt, Lukas, et al. “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-Ray Emission and Absorption Spectroscopy.” Inorganic Chemistry, 2020, pp. 3551–61, doi:10.1021/acs.inorgchem.9b02092. short: L. Burkhardt, Y. Vukadinovic, M. Nowakowski, A. Kalinko, J. Rudolph, P.-A. Carlsson, C.R. Jacob, M. Bauer, Inorganic Chemistry (2020) 3551–3561. date_created: 2020-03-23T10:38:47Z date_updated: 2024-05-07T11:44:33Z department: - _id: '43' - _id: '35' - _id: '306' doi: 10.1021/acs.inorgchem.9b02092 language: - iso: eng page: 3551-3561 project: - _id: '52' name: Computing Resources Provided by the Paderborn Center for Parallel Computing publication: Inorganic Chemistry publication_identifier: issn: - 0020-1669 - 1520-510X publication_status: published status: public title: Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy type: journal_article user_id: '48467' year: '2020' ... --- _id: '41005' author: - first_name: Yannik full_name: Vukadinovic, Yannik last_name: Vukadinovic citation: ama: Vukadinovic Y. N-Heterocyclic Carbene Based Iron and Ruthenium Photosensitizer with Amine Donors - A Systematic Study on Spectroscopic Differences.; 2020. doi:10.17619/UNIPB/1-1060 apa: Vukadinovic, Y. (2020). N-heterocyclic carbene based iron and ruthenium photosensitizer with amine donors - A systematic study on spectroscopic differences. https://doi.org/10.17619/UNIPB/1-1060 bibtex: '@book{Vukadinovic_2020, title={N-heterocyclic carbene based iron and ruthenium photosensitizer with amine donors - A systematic study on spectroscopic differences}, DOI={10.17619/UNIPB/1-1060}, author={Vukadinovic, Yannik}, year={2020} }' chicago: Vukadinovic, Yannik. N-Heterocyclic Carbene Based Iron and Ruthenium Photosensitizer with Amine Donors - A Systematic Study on Spectroscopic Differences, 2020. https://doi.org/10.17619/UNIPB/1-1060. ieee: Y. Vukadinovic, N-heterocyclic carbene based iron and ruthenium photosensitizer with amine donors - A systematic study on spectroscopic differences. 2020. mla: Vukadinovic, Yannik. N-Heterocyclic Carbene Based Iron and Ruthenium Photosensitizer with Amine Donors - A Systematic Study on Spectroscopic Differences. 2020, doi:10.17619/UNIPB/1-1060. short: Y. Vukadinovic, N-Heterocyclic Carbene Based Iron and Ruthenium Photosensitizer with Amine Donors - A Systematic Study on Spectroscopic Differences, 2020. date_created: 2023-01-30T16:58:21Z date_updated: 2023-01-31T08:18:58Z department: - _id: '35' - _id: '306' doi: 10.17619/UNIPB/1-1060 language: - iso: eng status: public supervisor: - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 title: N-heterocyclic carbene based iron and ruthenium photosensitizer with amine donors - A systematic study on spectroscopic differences type: dissertation user_id: '27611' year: '2020' ...