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Longwitz, J. Steinbauer, A. Spannenberg, T. Werner, ACS Catalysis 8 (2017) 665–672.","chicago":"Longwitz, Lars, Johannes Steinbauer, Anke Spannenberg, and Thomas Werner. “Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild Conditions.” <i>ACS Catalysis</i> 8, no. 1 (2017): 665–72. <a href=\"https://doi.org/10.1021/acscatal.7b03367\">https://doi.org/10.1021/acscatal.7b03367</a>.","apa":"Longwitz, L., Steinbauer, J., Spannenberg, A., &#38; Werner, T. (2017). Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild Conditions. <i>ACS Catalysis</i>, <i>8</i>(1), 665–672. <a href=\"https://doi.org/10.1021/acscatal.7b03367\">https://doi.org/10.1021/acscatal.7b03367</a>","ieee":"L. Longwitz, J. Steinbauer, A. Spannenberg, and T. 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Werner, “Organocatalyzed Reduction of Tertiary Phosphine Oxides,” <i>Advanced Synthesis and Catalysis</i>, vol. 358, no. 1, pp. 26–29, 2016, doi: <a href=\"https://doi.org/10.1002/adsc.201500762\">10.1002/adsc.201500762</a>."},"status":"public","publisher":"Wiley","_id":"37989","page":"26-29","volume":358,"user_id":"89271","issue":"1","publication":"Advanced Synthesis and Catalysis","extern":"1","date_created":"2023-01-22T21:05:14Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["T2","CSSD"],"type":"journal_article","author":[{"full_name":"Schirmer, Marie-Luis","first_name":"Marie-Luis","last_name":"Schirmer"},{"last_name":"Jopp","first_name":"Stefan","full_name":"Jopp, Stefan"},{"last_name":"Holz","first_name":"Jens","full_name":"Holz, Jens"},{"last_name":"Spannenberg","first_name":"Anke","full_name":"Spannenberg, Anke"},{"id":"89271","first_name":"Thomas","orcid":"0000-0001-9025-3244","last_name":"Werner","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["1615-4150"]},"year":"2016","title":"Organocatalyzed Reduction of Tertiary Phosphine Oxides","intvolume":"       358","publication_status":"published","date_updated":"2025-11-10T09:22:07Z","language":[{"iso":"eng"}],"doi":"10.1002/adsc.201500762"},{"status":"public","page":"504-508","publisher":"International Union of Crystallography (IUCr)","_id":"37984","user_id":"89271","volume":72,"citation":{"apa":"Schirmer, M.-L., Spannenberg, A., &#38; Werner, T. (2016). Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione. <i>Acta Crystallographica Section C Structural Chemistry</i>, <i>72</i>(6), 504–508. <a href=\"https://doi.org/10.1107/s2053229616008159\">https://doi.org/10.1107/s2053229616008159</a>","ieee":"M.-L. Schirmer, A. Spannenberg, and T. Werner, “Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione,” <i>Acta Crystallographica Section C Structural Chemistry</i>, vol. 72, no. 6, pp. 504–508, 2016, doi: <a href=\"https://doi.org/10.1107/s2053229616008159\">10.1107/s2053229616008159</a>.","chicago":"Schirmer, Marie-Luis, Anke Spannenberg, and Thomas Werner. “Highly Functionalized Alkenes Produced from Base-Free Organocatalytic Wittig Reactions: (<i>E</i>)-3-Benzylidenepyrrolidine-2,5-Dione, (<i>E</i>)-3-Benzylidene-1-Methylpyrrolidine-2,5-Dione and (<i>E</i>)-3-Benzylidene-1-<i>Tert</i>-Butylpyrrolidine-2,5-Dione.” <i>Acta Crystallographica Section C Structural Chemistry</i> 72, no. 6 (2016): 504–8. <a href=\"https://doi.org/10.1107/s2053229616008159\">https://doi.org/10.1107/s2053229616008159</a>.","short":"M.-L. Schirmer, A. Spannenberg, T. Werner, Acta Crystallographica Section C Structural Chemistry 72 (2016) 504–508.","mla":"Schirmer, Marie-Luis, et al. “Highly Functionalized Alkenes Produced from Base-Free Organocatalytic Wittig Reactions: (<i>E</i>)-3-Benzylidenepyrrolidine-2,5-Dione, (<i>E</i>)-3-Benzylidene-1-Methylpyrrolidine-2,5-Dione and (<i>E</i>)-3-Benzylidene-1-<i>Tert</i>-Butylpyrrolidine-2,5-Dione.” <i>Acta Crystallographica Section C Structural Chemistry</i>, vol. 72, no. 6, International Union of Crystallography (IUCr), 2016, pp. 504–08, doi:<a href=\"https://doi.org/10.1107/s2053229616008159\">10.1107/s2053229616008159</a>.","ama":"Schirmer M-L, Spannenberg A, Werner T. Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione. <i>Acta Crystallographica Section C Structural Chemistry</i>. 2016;72(6):504-508. doi:<a href=\"https://doi.org/10.1107/s2053229616008159\">10.1107/s2053229616008159</a>","bibtex":"@article{Schirmer_Spannenberg_Werner_2016, title={Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione}, volume={72}, DOI={<a href=\"https://doi.org/10.1107/s2053229616008159\">10.1107/s2053229616008159</a>}, number={6}, journal={Acta Crystallographica Section C Structural Chemistry}, publisher={International Union of Crystallography (IUCr)}, author={Schirmer, Marie-Luis and Spannenberg, Anke and Werner, Thomas}, year={2016}, pages={504–508} }"},"year":"2016","title":"Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione","publication_identifier":{"issn":["2053-2296"]},"author":[{"full_name":"Schirmer, Marie-Luis","first_name":"Marie-Luis","last_name":"Schirmer"},{"first_name":"Anke","last_name":"Spannenberg","full_name":"Spannenberg, Anke"},{"id":"89271","full_name":"Werner, Thomas","first_name":"Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244"}],"publication_status":"published","date_updated":"2025-11-10T09:23:46Z","intvolume":"        72","language":[{"iso":"eng"}],"doi":"10.1107/s2053229616008159","issue":"6","publication":"Acta Crystallographica Section C Structural Chemistry","extern":"1","abstract":[{"lang":"eng","text":"<jats:p>The Wittig reaction is a fundamental transformation for the preparation of alkenes from carbonyl compounds and phosphonium ylides. The ylides are prepared prior to the olefination step from the respective phosphonium salts by deprotonation utilizing strong bases. A first free-base catalytic Wittig reaction for the preparation of highly functionalized alkenes was based on tributylphosphane as the catalyst. Subsequently we developed a system employing a phospholene oxide as a pre-catalyst and trimethoxysilane as reducing agent which operates under milder conditions. The title compounds, (<jats:italic>E</jats:italic>)-3-benzylidenepyrrolidine-2,5-dione, C<jats:sub>11</jats:sub>H<jats:sub>9</jats:sub>NO<jats:sub>2</jats:sub>, (I), the methylpyrrolidine derivative, C<jats:sub>12</jats:sub>H<jats:sub>11</jats:sub>NO<jats:sub>2</jats:sub>, (II), and the<jats:italic>tert-</jats:italic>butylpyrrolidine derivative, C<jats:sub>15</jats:sub>H<jats:sub>17</jats:sub>NO<jats:sub>2</jats:sub>, (III), have been synthesized by base-free catalytic Wittig reactions. In the crystal of (I), molecules are linked into centrosymmetric dimers<jats:italic>via</jats:italic>pairs of N—H...O hydrogen bonds. Furthermore, in the crystal structure of (III), there are two molecules in the asymmetric unit, whereas in (I) and (II), only one molecule is present.</jats:p>"}],"date_created":"2023-01-22T21:03:23Z","keyword":["T2"],"type":"journal_article","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}]},{"status":"public","page":"7480-7489","_id":"37981","publisher":"Royal Society of Chemistry (RSC)","user_id":"89271","volume":14,"citation":{"mla":"Diebler, J., et al. “Atom Economical Synthesis of Di- and Trithiocarbonates by the Lithium Tert-Butoxide Catalyzed Addition of Carbon Disulfide to Epoxides and Thiiranes.” <i>Organic and Biomolecular Chemistry</i>, vol. 14, no. 31, Royal Society of Chemistry (RSC), 2016, pp. 7480–89, doi:<a href=\"https://doi.org/10.1039/c6ob01081d\">10.1039/c6ob01081d</a>.","ama":"Diebler J, Spannenberg A, Werner T. Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes. <i>Organic and Biomolecular Chemistry</i>. 2016;14(31):7480-7489. doi:<a href=\"https://doi.org/10.1039/c6ob01081d\">10.1039/c6ob01081d</a>","bibtex":"@article{Diebler_Spannenberg_Werner_2016, title={Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes}, volume={14}, DOI={<a href=\"https://doi.org/10.1039/c6ob01081d\">10.1039/c6ob01081d</a>}, number={31}, journal={Organic and Biomolecular Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Diebler, J. and Spannenberg, A. and Werner, Thomas}, year={2016}, pages={7480–7489} }","apa":"Diebler, J., Spannenberg, A., &#38; Werner, T. (2016). Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes. <i>Organic and Biomolecular Chemistry</i>, <i>14</i>(31), 7480–7489. <a href=\"https://doi.org/10.1039/c6ob01081d\">https://doi.org/10.1039/c6ob01081d</a>","ieee":"J. Diebler, A. Spannenberg, and T. Werner, “Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes,” <i>Organic and Biomolecular Chemistry</i>, vol. 14, no. 31, pp. 7480–7489, 2016, doi: <a href=\"https://doi.org/10.1039/c6ob01081d\">10.1039/c6ob01081d</a>.","short":"J. Diebler, A. Spannenberg, T. Werner, Organic and Biomolecular Chemistry 14 (2016) 7480–7489.","chicago":"Diebler, J., A. Spannenberg, and Thomas Werner. “Atom Economical Synthesis of Di- and Trithiocarbonates by the Lithium Tert-Butoxide Catalyzed Addition of Carbon Disulfide to Epoxides and Thiiranes.” <i>Organic and Biomolecular Chemistry</i> 14, no. 31 (2016): 7480–89. <a href=\"https://doi.org/10.1039/c6ob01081d\">https://doi.org/10.1039/c6ob01081d</a>."},"title":"Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes","year":"2016","publication_identifier":{"issn":["1477-0520","1477-0539"]},"author":[{"first_name":"J.","last_name":"Diebler","full_name":"Diebler, J."},{"first_name":"A.","last_name":"Spannenberg","full_name":"Spannenberg, A."},{"id":"89271","full_name":"Werner, Thomas","orcid":"0000-0001-9025-3244","first_name":"Thomas","last_name":"Werner"}],"publication_status":"published","date_updated":"2025-11-10T09:24:16Z","intvolume":"        14","language":[{"iso":"eng"}],"doi":"10.1039/c6ob01081d","publication":"Organic and Biomolecular Chemistry","issue":"31","extern":"1","abstract":[{"text":"<p>The lithium <italic>tert</italic>-butoxide catalyzed addition of CS<sub>2</sub> to epoxides and thiiranes under mild conditions is reported. A mechanism has been proposed taking into account the regio- and stereochemical outcome of the reaction.</p>","lang":"eng"}],"date_created":"2023-01-22T21:01:59Z","type":"journal_article","keyword":["CSSD"],"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}]}]