@article{35977,
  author       = {{Hoppe, Christian and Mitschker, Felix and Mai, Lukas and Liedke, Maciej Oskar and de los Arcos de Pedro, Maria Teresa and Awakowicz, Peter and Devi, Anjana and Attallah, Ahmed Gamal and Butterling, Maik and Wagner, Andreas and Grundmeier, Guido}},
  issn         = {{1612-8850}},
  journal      = {{Plasma Processes and Polymers}},
  keywords     = {{Polymers and Plastics, Condensed Matter Physics}},
  number       = {{4}},
  publisher    = {{Wiley}},
  title        = {{{Influence of surface activation on the microporosity of PE‐CVD and PE‐ALD SiO            <sub>              <i>x</i>            </sub>            thin films on PDMS}}},
  doi          = {{10.1002/ppap.202100174}},
  volume       = {{19}},
  year         = {{2022}},
}

@article{35976,
  author       = {{de los Arcos de Pedro, Maria Teresa and Weinberger, Christian and Zysk, Frederik and Raj Damerla, Varun and Kollmann, Sabrina and Vieth, Pascal and Tiemann, Michael and Kühne, Thomas D. and Grundmeier, Guido}},
  issn         = {{0169-4332}},
  journal      = {{Applied Surface Science}},
  keywords     = {{Surfaces, Coatings and Films, Condensed Matter Physics, Surfaces and Interfaces, General Physics and Astronomy, General Chemistry}},
  publisher    = {{Elsevier BV}},
  title        = {{{Challenges in the interpretation of gas core levels for the determination of gas-solid interactions within dielectric porous films by ambient pressure XPS}}},
  doi          = {{10.1016/j.apsusc.2022.154525}},
  volume       = {{604}},
  year         = {{2022}},
}

@article{35974,
  author       = {{Xie, Xiaofan and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido}},
  issn         = {{1612-8850}},
  journal      = {{Plasma Processes and Polymers}},
  keywords     = {{Polymers and Plastics, Condensed Matter Physics}},
  number       = {{11}},
  publisher    = {{Wiley}},
  title        = {{{Comparative analysis of hexamethyldisiloxane and hexamethyldisilazane plasma polymer thin films before and after plasma oxidation}}},
  doi          = {{10.1002/ppap.202200052}},
  volume       = {{19}},
  year         = {{2022}},
}

@article{36425,
  author       = {{Dogan, Deniz and Ruthmann, Simon and Seewald, Oliver and Bremser, Wolfgang}},
  issn         = {{0300-9440}},
  journal      = {{Progress in Organic Coatings}},
  keywords     = {{Materials Chemistry, Organic Chemistry, Surfaces, Coatings and Films, General Chemical Engineering}},
  publisher    = {{Elsevier BV}},
  title        = {{{Tuning of antifouling active PDMS domains tethered to epoxy/amine surface}}},
  doi          = {{10.1016/j.porgcoat.2022.106977}},
  volume       = {{170}},
  year         = {{2022}},
}

@article{41810,
  abstract     = {{<jats:p>Furfuryl amine-functionalized few-layered graphene was prepared <jats:italic>via</jats:italic> a mechanochemical process by a [4 + 2] cycloaddition under solvent-free conditions.</jats:p>}},
  author       = {{Torkaman, Najmeh Filvan and Kley, Marina and Bremser, Wolfgang and Wilhelm, René}},
  issn         = {{2046-2069}},
  journal      = {{RSC Advances}},
  keywords     = {{General Chemical Engineering, General Chemistry}},
  number       = {{27}},
  pages        = {{17249--17256}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Reversible functionalization and exfoliation of graphite by a Diels–Alder reaction with furfuryl amine}}},
  doi          = {{10.1039/d2ra02566c}},
  volume       = {{12}},
  year         = {{2022}},
}

@article{33691,
  abstract     = {{Near ambient pressure XPS in nitrogen atmosphere was utilized to investigate gas-solid interactions within porous SiO2 films ranging from 30 to 75 nm thickness. The films were differentiated in terms of porosity and roughness. The XPS N1s core levels of the N2 gas in presence of the SiO2 samples showed variations in width, binding energy and line shape. The width correlated with the surface charge induced in the dielectric films upon X-ray irradiation. The observed different binding energies observed for the N1s peak can only partly be associated with intrinsic work function differences between the samples, opening the possibility that the effect of physisorption at room temperature could be detected by a shift in the measured binding energy. However, the signals also show an increasing asymmetry with rising surface charge. This might be associated with the formation of vertical electrical gradients within the dielectric porous thin films, which complicates the assignment of binding energy positions to specific surface-related effects. With the support of Monte Carlo and first principles density functional theory calculations, the observed shifts were discussed in terms of the possible formation of transitory dipoles upon N2 physisorption within the porous SiO2 films.}},
  author       = {{de los Arcos, Teresa and Weinberger, Christian and Zysk, Frederik and Raj Damerla, Varun and Kollmann, Sabrina and Vieth, Pascal and Tiemann, Michael and Kühne, Thomas and Grundmeier, Guido}},
  issn         = {{0169-4332}},
  journal      = {{Applied Surface Science}},
  keywords     = {{Surfaces, Coatings and Films, Condensed Matter Physics, Surfaces and Interfaces, General Physics and Astronomy, General Chemistry}},
  publisher    = {{Elsevier BV}},
  title        = {{{Challenges in the interpretation of gas core levels for the determination of gas-solid interactions within dielectric porous films by ambient pressure XPS}}},
  doi          = {{10.1016/j.apsusc.2022.154525}},
  volume       = {{604}},
  year         = {{2022}},
}

@article{33965,
  author       = {{Bocchini, Adriana and Gerstmann, Uwe and Bartley, Tim and Steinrück, Hans-Georg and Henkel, Gerald and Schmidt, Wolf Gero}},
  journal      = {{Phys. Rev. Materials}},
  pages        = {{105401}},
  publisher    = {{American Physical Society}},
  title        = {{{Electrochemical performance of KTiOAsO_4 (KTA) in potassium-ion batteries from density-functional theory}}},
  doi          = {{10.1103/PhysRevMaterials.6.105401}},
  volume       = {{6}},
  year         = {{2022}},
}

@article{40154,
  abstract     = {{<jats:p>The development of bioresorbable materials for temporary implantation enables progress in medical technology. Iron (Fe)-based degradable materials are biocompatible and exhibit good mechanical properties, but their degradation rate is low. Aside from alloying with Manganese (Mn), the creation of phases with high electrochemical potential such as silver (Ag) phases to cause the anodic dissolution of FeMn is promising. However, to enable residue-free dissolution, the Ag needs to be modified. This concern is addressed, as FeMn modified with a degradable Ag-Calcium-Lanthanum (AgCaLa) alloy is investigated. The electrochemical properties and the degradation behavior are determined via a static immersion test. The local differences in electrochemical potential increase the degradation rate (low pH values), and the formation of gaps around the Ag phases (neutral pH values) demonstrates the benefit of the strategy. Nevertheless, the formation of corrosion-inhibiting layers avoids an increased degradation rate under a neutral pH value. The complete bioresorption of the material is possible since the phases of the degradable AgCaLa alloy dissolve after the FeMn matrix. Cell viability tests reveal biocompatibility, and the antibacterial activity of the degradation supernatant is observed. Thus, FeMn modified with degradable AgCaLa phases is promising as a bioresorbable material if corrosion-inhibiting layers can be diminished.</jats:p>}},
  author       = {{Krüger, Jan Tobias and Hoyer, Kay-Peter and Huang, Jingyuan and Filor, Viviane and Mateus-Vargas, Rafael Hernan and Oltmanns, Hilke and Meißner, Jessica and Grundmeier, Guido and Schaper, Mirko}},
  issn         = {{2079-4983}},
  journal      = {{Journal of Functional Biomaterials}},
  keywords     = {{Biomedical Engineering, Biomaterials}},
  number       = {{4}},
  pages        = {{185}},
  publisher    = {{MDPI AG}},
  title        = {{{FeMn with Phases of a Degradable Ag Alloy for Residue-Free and Adapted Bioresorbability}}},
  doi          = {{10.3390/jfb13040185}},
  volume       = {{13}},
  year         = {{2022}},
}

@article{34652,
  author       = {{Vieth, P. and Garthe, M.-A. and Voswinkel, Dietrich and Schaper, Mirko and Grundmeier, Guido}},
  issn         = {{0257-8972}},
  journal      = {{Surface and Coatings Technology}},
  keywords     = {{Materials Chemistry, Surfaces, Coatings and Films, Surfaces and Interfaces, Condensed Matter Physics, General Chemistry}},
  publisher    = {{Elsevier BV}},
  title        = {{{Enhancement of the delamination resistance of adhesive film coated surface laser melted aluminum 7075-T6 alloy by aminophosphonic acid adsorption}}},
  doi          = {{10.1016/j.surfcoat.2022.128835}},
  volume       = {{447}},
  year         = {{2022}},
}

@article{30103,
  author       = {{Huang, Jingyuan and Orive, Alejandro Gonzalez and Krüger, Jan Tobias and Hoyer, Kay-Peter and Keller, Adrian and Grundmeier, Guido}},
  issn         = {{0010-938X}},
  journal      = {{Corrosion Science}},
  keywords     = {{General Materials Science, General Chemical Engineering, General Chemistry}},
  pages        = {{110186}},
  publisher    = {{Elsevier BV}},
  title        = {{{Influence of proteins on the corrosion of a conventional and selective laser beam melted FeMn alloy in physiological electrolytes}}},
  doi          = {{10.1016/j.corsci.2022.110186}},
  volume       = {{200}},
  year         = {{2022}},
}

@article{34654,
  author       = {{Kusoglu, Ihsan Murat and Vieth, Pascal and Heiland, Steffen and Huber, Florian and Lüddecke, Arne and Ziefuss, Anna Rosa and Kwade, Arno and Schmidt, Michael and Schaper, Mirko and Barcikowski, Stephan and Grundmeier, Guido}},
  issn         = {{2212-8271}},
  journal      = {{Procedia CIRP}},
  keywords     = {{General Medicine}},
  pages        = {{10--13}},
  publisher    = {{Elsevier BV}},
  title        = {{{Microstructure and corrosion properties of PBF-LB produced carbide nanoparticles additivated AlSi10Mg parts}}},
  doi          = {{10.1016/j.procir.2022.08.046}},
  volume       = {{111}},
  year         = {{2022}},
}

@article{33834,
  abstract     = {{<jats:p>Elucidating and quantifying the effects of doping on halide perovskites using lithium ion batteries.</jats:p>}},
  author       = {{Mathieson, Angus G. M. and Dose, Wesley M. and Steinrück, Hans-Georg and Takacs, Christopher J. and Feldmann, Sascha and Pandya, Raj and Merryweather, Alice J. and Mackanic, David and Rao, Akshay and Deschler, Felix and De Volder, Michael}},
  issn         = {{1754-5692}},
  journal      = {{Energy & Environmental Science}},
  keywords     = {{Pollution, Nuclear Energy and Engineering, Renewable Energy, Sustainability and the Environment, Environmental Chemistry}},
  number       = {{10}},
  pages        = {{4323--4337}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{A mechanistic study of the dopant-induced breakdown in halide perovskites using solid state energy storage devices}}},
  doi          = {{10.1039/d2ee01754g}},
  volume       = {{15}},
  year         = {{2022}},
}

@article{46479,
  author       = {{Bobzin, K. and Kalscheuer, C. and Grundmeier, Guido and Kollmann, S. and Carlet, M. and de los Arcos de Pedro, Maria Teresa}},
  issn         = {{0257-8972}},
  journal      = {{Surface and Coatings Technology}},
  keywords     = {{Materials Chemistry, Surfaces, Coatings and Films, Surfaces and Interfaces, Condensed Matter Physics, General Chemistry}},
  publisher    = {{Elsevier BV}},
  title        = {{{Oxidation stability of chromium aluminum oxynitride hard coatings}}},
  doi          = {{10.1016/j.surfcoat.2022.128927}},
  volume       = {{449}},
  year         = {{2022}},
}

@article{58571,
  author       = {{Dogan, Deniz and Ruthmann, Simon and Seewald, Oliver and Bremser, Wolfgang}},
  issn         = {{0300-9440}},
  journal      = {{Progress in Organic Coatings}},
  publisher    = {{Elsevier BV}},
  title        = {{{Tuning of antifouling active PDMS domains tethered to epoxy/amine surface}}},
  doi          = {{10.1016/j.porgcoat.2022.106977}},
  volume       = {{170}},
  year         = {{2022}},
}

@article{62235,
  abstract     = {{<jats:p>Additive manufacturing (AM) processes are not solely used where maximum design freedom meets low lot sizes. Direct microstructure design and topology optimization can be realized concomitantly during processing by adjusting the geometry, the material composition, and the solidification behavior of the material considered. However, when complex specific requirements have to be met, a targeted part design is highly challenging. In the field of biodegradable implant surgery, a cytocompatible material of an application-adapted shape has to be characterized by a specific degradation behavior and reliably predictable mechanical properties. For instance, small amounts of oxides can have a significant effect on microstructural development, thus likewise affecting the strength and corrosion behavior of the processed material. In the present study, biocompatible pure Fe was processed using electron powder bed fusion (E-PBF). Two different modifications of the Fe were processed by incorporating Fe oxide and Ce oxide in different proportions in order to assess their impact on the microstructural evolution, the mechanical response and the corrosion behavior. The quasistatic mechanical and chemical properties were analyzed and correlated with the final microstructural appearance.</jats:p>}},
  author       = {{Torrent, Christof J. J. and Krooß, Philipp and Huang, Jingyuan and Voigt, Markus and Ebbert, Christoph and Knust, Steffen and Grundmeier, Guido and Niendorf, Thomas}},
  issn         = {{2674-063X}},
  journal      = {{Alloys}},
  number       = {{1}},
  pages        = {{31--53}},
  publisher    = {{MDPI AG}},
  title        = {{{Oxide Modified Iron in Electron Beam Powder Bed Fusion—From Processability to Corrosion Properties}}},
  doi          = {{10.3390/alloys1010004}},
  volume       = {{1}},
  year         = {{2022}},
}

@article{62801,
  abstract     = {{The three-dimensional (3D) distribution of individual atoms on the surface of catalyst nanoparticles plays a vital role in their activity and stability. Optimising the performance of electrocatalysts requires atomic-scale information, but it is difficult to obtain. Here, we use atom probe tomography to elucidate the 3D structure of 10 nm sized Co2FeO4 and CoFe2O4 nanoparticles during oxygen evolution reaction (OER). We reveal nanoscale spinodal decomposition in pristine Co2FeO4. The interfaces of Co-rich and Fe-rich nanodomains of Co2FeO4 become trapping sites for hydroxyl groups, contributing to a higher OER activity compared to that of CoFe2O4. However, the activity of Co2FeO4 drops considerably due to concurrent irreversible transformation towards CoIVO2 and pronounced Fe dissolution. In contrast, there is negligible elemental redistribution for CoFe2O4 after OER, except for surface structural transformation towards (FeIII, CoIII)2O3. Overall, our study provides a unique 3D compositional distribution of mixed Co-Fe spinel oxides, which gives atomic-scale insights into active sites and the deactivation of electrocatalysts during OER.}},
  author       = {{Xiang, Weikai and Yang, Nating and Li, Xiaopeng and Linnemann, Julia and Hagemann, Ulrich and Ruediger, Olaf and Heidelmann, Markus and Falk, Tobias and Aramini, Matteo and DeBeer, Serena and Muhler, Martin and Tschulik, Kristina and Li, Tong}},
  issn         = {{2041-1723}},
  journal      = {{Nature Communications}},
  keywords     = {{electrocatalysis, oxygen evolution reaction, cobalt spinel, electrochemical impedance spectroscopy}},
  number       = {{1}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{3D atomic-scale imaging of mixed Co-Fe spinel oxide nanoparticles during oxygen evolution reaction}}},
  doi          = {{10.1038/s41467-021-27788-2}},
  volume       = {{13}},
  year         = {{2022}},
}

@article{62813,
  abstract     = {{Nanostructured manganese oxides have a rich variety of morphologies and crystal phases which can undergo transformations during synthesis and application. Although these structural features are crucial for their performance, the mechanisms behind such transitions are not well understood. Herein, we describe the mechanism of transformation from layered 2D δ-MnO2 nanosheets to the scarcely reported γ-MnO2 nanocone morphology. Despite the common purpose of introducing Fe dopants to enhance the conductivity of layered manganese oxides, the Fe galvanic exchange reaction was found responsible for such coupled phase/morphology transition. Electrochemical characterization confirmed a distinct electrochemical behaviour of the nanocones, emphasizing the need to unravel the mechanism of 2D MnO2 transformation. Such mechanistic insights were gained by systematic and rigorous electron microscopy studies. The effect of the local chemical composition was determined by energy dispersive X-ray spectroscopy while electron energy loss spectroscopy unravelled the key influence of the oxidation state of Mn ions within nanosheets and nanocones. We propose and demonstrate a Mn2+-mediated oxidative mechanism of coupled morphology/phase transformation subjected to the equilibrium of Fe and Mn ions during galvanic exchange reaction. These findings contribute to the understanding of the growth and morphology/phase transformations of manganese oxide nanostructures, providing insights for the rational design of nanomaterials.}},
  author       = {{Aymerich-Armengol, Raquel and Cignoni, Paolo and Ebbinghaus, Petra and Linnemann, Julia and Rabe, Martin and Tschulik, Kristina and Scheu, Christina and Lim, Joohyun}},
  issn         = {{2050-7488}},
  journal      = {{Journal of Materials Chemistry A}},
  keywords     = {{manganese oxide, nanomaterials, TEM, supercapacitors}},
  number       = {{45}},
  pages        = {{24190--24198}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Mechanism of coupled phase/morphology transformation of 2D manganese oxides through Fe galvanic exchange reaction}}},
  doi          = {{10.1039/d2ta06552e}},
  volume       = {{10}},
  year         = {{2022}},
}

@article{63206,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>Pure iron is very attractive as a biodegradable implant material due to its high biocompatibility. In combination with additive manufacturing, which facilitates great flexibility of the implant design, it is possible to selectively adjust the microstructure of the material in the process, thereby control the corrosion and fatigue behavior. In the present study, conventional hot-rolled (HR) pure iron is compared to pure iron manufactured by electron beam melting (EBM). The microstructure, the corrosion behavior and the fatigue properties were studied comprehensively. The investigated sample conditions showed significant differences in the microstructures that led to changes in corrosion and fatigue properties. The EBM iron showed significantly lower fatigue strength compared to the HR iron. These different fatigue responses were observed under purely mechanical loading as well as with superimposed corrosion influence and are summarized in a model that describes the underlying failure mechanisms.</jats:p>}},
  author       = {{Wackenrohr, Steffen and Torrent, Christof Johannes Jaime and Herbst, Sebastian and Nürnberger, Florian and Krooss, Philipp and Ebbert, Christoph and Voigt, Markus and Grundmeier, Guido and Niendorf, Thomas and Maier, Hans Jürgen}},
  issn         = {{2397-2106}},
  journal      = {{npj Materials Degradation}},
  number       = {{1}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{Corrosion fatigue behavior of electron beam melted iron in simulated body fluid}}},
  doi          = {{10.1038/s41529-022-00226-4}},
  volume       = {{6}},
  year         = {{2022}},
}

@article{25182,
  author       = {{Zhang, Yong and Wan, Gang and Lewis, Nicholas H. C. and Mars, Julian and Bone, Sharon E. and Steinrück, Hans-Georg and Lukatskaya, Maria R. and Weadock, Nicholas J. and Bajdich, Michal and Borodin, Oleg and Tokmakoff, Andrei and Toney, Michael F. and Maginn, Edward J.}},
  issn         = {{2380-8195}},
  journal      = {{ACS Energy Letters}},
  pages        = {{3458--3463}},
  title        = {{{Water or Anion? Uncovering the Zn2+ Solvation Environment in Mixed Zn(TFSI)2 and LiTFSI Water-in-Salt Electrolytes}}},
  doi          = {{10.1021/acsenergylett.1c01624}},
  volume       = {{6}},
  year         = {{2021}},
}

@article{25183,
  author       = {{Geise, Natalie R. and Kasse, Robert M. and Nelson Weker, Johanna and Steinrück, Hans-Georg and Toney, Michael F.}},
  issn         = {{0897-4756}},
  journal      = {{Chemistry of Materials}},
  pages        = {{7537--7545}},
  title        = {{{Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando X-ray Diffraction}}},
  doi          = {{10.1021/acs.chemmater.1c02585}},
  volume       = {{33}},
  year         = {{2021}},
}