@article{22535,
  author       = {{Knust, Steffen and Ruhm, Lukas and Kuhlmann, Andreas and Meinderink, Dennis and Bürger, Julius and Lindner, Jörg K. N. and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido}},
  issn         = {{0377-0486}},
  journal      = {{Journal of Raman Spectroscopy}},
  pages        = {{1237--1245}},
  title        = {{{In situ backside Raman spectroscopy of zinc oxide nanorods in an atmospheric‐pressure dielectric barrier discharge plasma}}},
  doi          = {{10.1002/jrs.6123}},
  year         = {{2021}},
}

@article{35326,
  abstract     = {{<jats:p>Thermostable compartmentalized sodium-water sites through intercalated γ-aminopropyl-dimethyl-ethoxy silane in synthetic hectorite.</jats:p>}},
  author       = {{Keil, Waldemar and Zhao, Kai and Oswald, Arthur and Bremser, Wolfgang and Schmidt, Claudia and Hintze-Bruening, Horst}},
  issn         = {{1463-9076}},
  journal      = {{Physical Chemistry Chemical Physics}},
  keywords     = {{Physical and Theoretical Chemistry, General Physics and Astronomy}},
  number       = {{1}},
  pages        = {{477--487}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Thermostable water reservoirs in the interlayer space of a sodium hectorite clay through the intercalation of γ-aminopropyl(dimethyl)ethoxysilane in toluene}}},
  doi          = {{10.1039/d1cp03321b}},
  volume       = {{24}},
  year         = {{2021}},
}

@article{25897,
  abstract     = {{A comparison of infrared spectroscopic analytical approaches was made in order to assess their applicability for internal structure characterization of SiO2 thin films. Markers for porosity and/or disorder based on the analysis of the asymmetric stretching absorption band of SiO2 between 900−1350 cm−1 were discussed. The shape of this band, which shows a well-defined LO–TO splitting, depends not only on the inherent characteristics of the film under analysis but also on the particular geometry of the IR experiment and the specific surface selection rules of the substrate. Three types of SiO2 thin films with clearly defined porosity ranging from dense films to mesoporous films were investigated by transmission (at different incidence angles), direct specular reflection (at different angles), and diffuse reflection. Two different types of substrate, metallic and semiconducting, were used. The combined effect of substrate and specific technique in the final shape of the band, was discussed, and the efficacy for their applicability to the determination of porosity in thin SiO2 films was critically evaluated.}},
  author       = {{de los Arcos, Teresa and Müller, Hendrik and Wang, Fuzeng and Damerla, Varun Raj and Hoppe, Christian and Weinberger, Christian and Tiemann, Michael and Grundmeier, Guido}},
  issn         = {{0924-2031}},
  journal      = {{Vibrational Spectroscopy}},
  title        = {{{Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films}}},
  doi          = {{10.1016/j.vibspec.2021.103256}},
  year         = {{2021}},
}

@article{22635,
  abstract     = {{Photodynamic therapy (PDT) using TiO2 nanoparticles has become an important alternative treatment for different types of cancer due to their high photocatalytic activity and high absorption of UV-A light. To potentiate this treatment, we have coated commercial glass plates with TiO2 nanoparticles prepared by the sol–gel method (TiO2-m), which exhibit a remarkable selectivity for the irreversible trapping of cancer cells. The physicochemical properties of the deposited TiO2-m nanoparticle coatings have been characterized by a number of complementary surface-analytical techniques and their interaction with leukemia and healthy blood cells were investigated. Scanning electron and atomic force microscopy verify the formation of a compact layer of TiO2-m nanoparticles. The particles are predominantly in the anatase phase and have hydroxyl-terminated surfaces as revealed by Raman, X-ray photoelectron, and infrared spectroscopy, as well as X-ray diffraction. We find that lymphoblastic leukemia cells adhere to the TiO2-m coating and undergo amoeboid-like migration, whereas lymphocytic cells show distinctly weaker interactions with the coating. This evidences the potential of this nanomaterial coating to selectively trap cancer cells and renders it a promising candidate for the development of future prototypes of PDT devices for the treatment of leukemia and other types of cancers with non-adherent cells.}},
  author       = {{Garcia Diosa, Jaime Andres and Gonzalez Orive, Alejandro and Weinberger, Christian and Schwiderek, Sabrina and Knust, Steffen and Tiemann, Michael and Grundmeier, Guido and Keller, Adrian and Camargo Amado, Ruben Jesus}},
  issn         = {{1552-4973}},
  journal      = {{Journal of Biomedical Materials Research Part B: Applied Biomaterials}},
  pages        = {{2142–2153}},
  title        = {{{TiO2 nanoparticle coatings on glass surfaces for the selective trapping of leukemia cells from peripheral blood}}},
  doi          = {{10.1002/jbm.b.34862}},
  volume       = {{109}},
  year         = {{2021}},
}

@article{24566,
  author       = {{Engelkemeier, Katja and Sun, Aijia and Voswinkel, Dietrich and Grydin, Olexandr and Schaper, Mirko and Bremser, Wolfgang}},
  issn         = {{2196-0216}},
  journal      = {{ChemElectroChem}},
  pages        = {{2155--2168}},
  publisher    = {{Wiley}},
  title        = {{{Zinc Anodizing: Structural Diversity of Anodic Zinc Oxide Controlled by the Type of Electrolyte}}},
  doi          = {{10.1002/celc.202100216}},
  year         = {{2021}},
}

@article{22859,
  author       = {{Grothe, Richard and Striewe, Jan Andre and Meinderink, Dennis and Tröster, Thomas and Grundmeier, Guido}},
  journal      = {{The Journal of Adhesion}},
  publisher    = {{Taylor & Francis }},
  title        = {{{Enhanced corrosion resistance of adhesive/galvanised steel interfaces by nanocrystalline ZnO thin film deposition and molecular adhesion promoting films}}},
  doi          = {{10.1080/00218464.2021.1957676}},
  year         = {{2021}},
}

@article{62803,
  abstract     = {{The aim to produce highly active, selective, and long-lived electrocatalysts by design drives major research efforts toward gaining fundamental understanding of the relationship between material properties and their catalytic performance. Surface characterization tools enable to assess atomic scale information on the complexity of electrocatalyst materials. Advancing electrochemical methodologies to adequately characterize such systems was less of a research focus point. In this Review, we shed light on the ability to gain fundamental insights into electrocatalysis from a complementary perspective and establish corresponding design strategies. These may rely on adopting the perceptions and models of other subareas of electrochemistry, such as corrosion, battery research, or electrodeposition. Concepts on how to account for and improve mass transport, manage gas bubble release, or exploit magnetic fields are highlighted in this respect. Particular attention is paid to deriving design strategies for nanoelectrocatalysts, which is often impeded, as structural and physical material properties are buried in electrochemical data of whole electrodes or even devices. Thus, a second major approach focuses on overcoming this difference in the considered level of complexity by methods of single-entity electrochemistry. The gained understanding of intrinsic catalyst performance may allow to rationally advance design concepts with increased complexity, such as three-dimensional electrode architectures. Many materials undergo structural changes upon formation of the working catalyst. Accordingly, developing “precatalysts” with low hindrance of the electrochemical transformation to the active catalyst is suggested as a final design strategy.}},
  author       = {{Linnemann, Julia and Kanokkanchana, Kannasoot and Tschulik, Kristina}},
  issn         = {{2155-5435}},
  journal      = {{ACS Catalysis}},
  keywords     = {{electrocatalysis}},
  number       = {{9}},
  pages        = {{5318--5346}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Design Strategies for Electrocatalysts from an Electrochemist’s Perspective}}},
  doi          = {{10.1021/acscatal.0c04118}},
  volume       = {{11}},
  year         = {{2021}},
}

@article{62806,
  abstract     = {{The electrical double‐layer plays a key role in important interfacial electrochemical processes from catalysis to energy storage and corrosion. Therefore, understanding its structure is crucial for the progress of sustainable technologies. We extract new physico‐chemical information on the capacitance and structure of the electrical double‐layer of platinum and gold nanoparticles at the molecular level, employing single nanoparticle electrochemistry. The charge storage ability of the solid/liquid interface is larger by one order‐of‐magnitude than predicted by the traditional mean‐field models of the double‐layer such as the Gouy–Chapman–Stern model. Performing molecular dynamics simulations, we investigate the possible relationship between the measured high capacitance and adsorption strength of the water adlayer formed at the metal surface. These insights may launch the active tuning of solid–solvent and solvent–solvent interactions as an innovative design strategy to transform energy technologies towards superior performance and sustainability.}},
  author       = {{Azimzadeh Sani, Mahnaz and Pavlopoulos, Nicholas G. and Pezzotti, Simone and Serva, Alessandra and Cignoni, Paolo and Linnemann, Julia and Salanne, Mathieu and Gaigeot, Marie‐Pierre and Tschulik, Kristina}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{single-entity electrochemistry, electrical double layer, supercapacitor, nanoparticles}},
  number       = {{5}},
  publisher    = {{Wiley}},
  title        = {{{Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer}}},
  doi          = {{10.1002/anie.202112679}},
  volume       = {{61}},
  year         = {{2021}},
}

@article{62805,
  abstract     = {{Single-entity electrochemistry allows for assessing electrocatalytic activities of individual material entities such as nanoparticles (NPs). Thus, it becomes possible to consider intrinsic electrochemical properties of nanocatalysts when researching how activity relates to physical and structural material properties. Conversely, conventional electrochemical techniques provide a normalized sum current referring to a huge ensemble of NPs constituting, along with additives (e.g., binders), a complete catalyst-coated electrode. Accordingly, recording electrocatalytic responses of single NPs avoids interferences of ensemble effects and reduces the complexity of electrocatalytic processes, thus enabling detailed description and modelling. Herein, we present insights into the oxygen evolution catalysis at individual cubic Co3O4 NPs impacting microelectrodes of different support materials. Simulating diffusion at supported nanocubes, measured step current signals can be analyzed, providing edge lengths, corresponding size distributions, and interference-free turnover frequencies. The provided nano-impact investigation of (electro-)catalyst-support effects contradicts assumptions on a low number of highly active sites.}},
  author       = {{Liu, Zhibin and Corva, Manuel and Amin, Hatem M. A. and Blanc, Niclas and Linnemann, Julia and Tschulik, Kristina}},
  issn         = {{1422-0067}},
  journal      = {{International Journal of Molecular Sciences}},
  keywords     = {{electrocatalysis, oxygen evolution reaction, cobalt spinel, single-entity electrochemistry}},
  number       = {{23}},
  publisher    = {{MDPI AG}},
  title        = {{{Single Co<sub>3</sub>O<sub>4</sub> Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects}}},
  doi          = {{10.3390/ijms222313137}},
  volume       = {{22}},
  year         = {{2021}},
}

@article{62851,
  abstract     = {{To reduce high-level radiotoxic waste generated by nuclear power plants, highly selective separation agents for minor actinides are mandatory. The mixed N,O-donor ligand N,N,N′,N′-tetrakis[(6-carboxypyridin-2-yl)methyl]ethylenediamine (H4TPAEN; 1) has shown good performance as a masking agent in Am3+/Eu3+ separation studies. Adjustments on the pyridyl backbone to raise the hydrophilicity led to a decrease in selectivity and a decrease in M3+–Nam interactions. An enhanced basicity of the pyridyl N-donors was given as a cause. In this work, we examine whether a decrease in O-donor basicity can promote the M3+–Nam interactions. Therefore, we replace the deprotonated “charged” carboxylic acid groups of TPAEN4– by neutral amide groups and introduce N,N,N′,N’-tetrakis[(6-N″,N′′-diethylcarbamoylpyridin-2-yl)methyl]ethylenediamine (TPAMEN; 2) as a new ligand. TPAMEN was crystallized with Eu(OTf)3 and Eu(NO3)3·6H2O to form positively charged 1:1 [Eu(TPAMEN)]3+ complexes in the solid state. Alterations in the M–O/N bond distances are compared to [Eu(TPAEN)]− and investigated by DFT calculations to expose the differences in charge/energy density distributions at europium(III) and the donor functionalities of the TPAEN4– and TPAMEN. On the basis of estimations of the bond orders, atomic charges spin populations, and density of states in the Eu and potential Am and Cm complexes, the specific contributions of the donor–metal interaction are analyzed. The prediction of complex formation energy differences for the [M(TPAEN)]− and [M(TPAMEN)]3+ (M3+ = Eu3+, Am3+) complexes provide an outlook on the potential performance of TPAMEN in Am3+/Eu3+ separation.}},
  author       = {{Schnaars, Kathleen and Kaneko, Masashi and Fujisawa, Kiyoshi}},
  issn         = {{0020-1669}},
  journal      = {{Inorganic Chemistry}},
  number       = {{4}},
  pages        = {{2477--2491}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu<sup>3+</sup> Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]<sup>3+</sup> Chelate Complex}}},
  doi          = {{10.1021/acs.inorgchem.0c03405}},
  volume       = {{60}},
  year         = {{2021}},
}

@article{65632,
  author       = {{Zhuravlev, Evgeny and Milkereit, Benjamin and Yang, Bin and Heiland, Steffen and Vieth, Pascal and Voigt, Markus and Schaper, Mirko and Grundmeier, Guido and Schick, Christoph and Kessler, Olaf}},
  issn         = {{0264-1275}},
  journal      = {{Materials &amp; Design}},
  publisher    = {{Elsevier BV}},
  title        = {{{Assessment of AlZnMgCu alloy powder modification for crack-free laser powder bed fusion by differential fast scanning calorimetry}}},
  doi          = {{10.1016/j.matdes.2021.109677}},
  volume       = {{204}},
  year         = {{2021}},
}

@article{25301,
  author       = {{Scherer, Beate and Kottenstedde, Ingo Leonard and Bremser, Wolfgang and Matysik, Frank-Michael}},
  issn         = {{0142-9418}},
  journal      = {{Polymer Testing}},
  title        = {{{Analytical characterization of polyamide 11 used in the context of selective laser sintering: Physico-chemical correlations}}},
  doi          = {{10.1016/j.polymertesting.2020.106786}},
  year         = {{2020}},
}

@article{23599,
  abstract     = {{<jats:p>Grazing-incidence wide-angle X-ray scattering (GIWAXS) has become an increasingly popular technique for quantitative structural characterization and comparison of thin films. For this purpose, accurate intensity normalization and peak position determination are crucial. At present, few tools exist to estimate the uncertainties of these measurements. Here, a simulation package is introduced called <jats:italic>GIWAXS-SIIRkit</jats:italic>, where SIIR stands for scattering intensity, indexing and refraction. The package contains several tools that are freely available for download and can be executed in MATLAB. The package includes three functionalities: estimation of the relative scattering intensity and the corresponding uncertainty based on experimental setup and sample dimensions; extraction and indexing of peak positions to approximate the crystal structure of organic materials starting from calibrated GIWAXS patterns; and analysis of the effects of refraction on peak positions. Each tool is based on a graphical user interface and designed to have a short learning curve. A user guide is provided with detailed usage instruction, tips for adding functionality and customization, and exemplary files.</jats:p>}},
  author       = {{Savikhin, Victoria and Steinrück, Hans-Georg and Liang, Ru-Ze and Collins, Brian A. and Oosterhout, Stefan D. and Beaujuge, Pierre M. and Toney, Michael F.}},
  issn         = {{1600-5767}},
  journal      = {{Journal of Applied Crystallography}},
  pages        = {{1108--1129}},
  title        = {{{GIWAXS-SIIRkit: scattering intensity, indexing and refraction calculation toolkit for grazing-incidence wide-angle X-ray scattering of organic materials}}},
  doi          = {{10.1107/s1600576720005476}},
  volume       = {{53}},
  year         = {{2020}},
}

@article{23600,
  author       = {{Gebers, Jan and Özen, Bilal and Hartmann, Lucia and Schaer, Michel and Suàrez, Stéphane and Bugnon, Philippe and Scopelliti, Rosario and Steinrück, Hans-Georg and Konovalov, Oleg and Magerl, Andreas and Brinkmann, Martin and Petraglia, Riccardo and Silva, Piotr and Corminboeuf, Clémence and Frauenrath, Holger}},
  issn         = {{0947-6539}},
  journal      = {{Chemistry – A European Journal}},
  pages        = {{10265--10275}},
  title        = {{{Crystallization and Organic Field‐Effect Transistor Performance of a Hydrogen‐Bonded Quaterthiophene}}},
  doi          = {{10.1002/chem.201904562}},
  volume       = {{26}},
  year         = {{2020}},
}

@article{23601,
  author       = {{Abdelsamie, Maged and Xu, Junwei and Bruening, Karsten and Tassone, Christopher J. and Steinrück, Hans-Georg and Toney, Michael F.}},
  issn         = {{1616-301X}},
  journal      = {{Advanced Functional Materials}},
  pages        = {{2001752}},
  title        = {{{Impact of Processing on Structural and Compositional Evolution in Mixed Metal Halide Perovskites during Film Formation}}},
  doi          = {{10.1002/adfm.202001752}},
  volume       = {{30}},
  year         = {{2020}},
}

@article{23602,
  author       = {{Tanim, Tanvir R. and Paul, Partha P. and Thampy, Vivek and Cao, Chuntian and Steinrück, Hans-Georg and Nelson Weker, Johanna and Toney, Michael F. and Dufek, Eric J. and Evans, Michael C. and Jansen, Andrew N. and Polzin, Bryant J. and Dunlop, Alison R. and Trask, Stephen E.}},
  issn         = {{2666-3864}},
  journal      = {{Cell Reports Physical Science}},
  pages        = {{100114}},
  title        = {{{Heterogeneous Behavior of Lithium Plating during Extreme Fast Charging}}},
  doi          = {{10.1016/j.xcrp.2020.100114}},
  volume       = {{1}},
  year         = {{2020}},
}

@article{23603,
  author       = {{Bone, Sharon E. and Steinrück, Hans-Georg and Toney, Michael F.}},
  issn         = {{2542-4351}},
  journal      = {{Joule}},
  pages        = {{1637--1659}},
  title        = {{{Advanced Characterization in Clean Water Technologies}}},
  doi          = {{10.1016/j.joule.2020.06.020}},
  volume       = {{4}},
  year         = {{2020}},
}

@article{23604,
  abstract     = {{<p>Investigation of the mechanisms underlying control of electrodeposited lithium metal morphology using electrolyte additives in lithium metal batteries.</p>}},
  author       = {{Kasse, Robert M. and Geise, Natalie R. and Ko, Jesse S. and Nelson Weker, Johanna and Steinrück, Hans-Georg and Toney, Michael F.}},
  issn         = {{2050-7488}},
  journal      = {{Journal of Materials Chemistry A}},
  pages        = {{16960--16972}},
  title        = {{{Understanding additive controlled lithium morphology in lithium metal batteries}}},
  doi          = {{10.1039/d0ta06020h}},
  volume       = {{8}},
  year         = {{2020}},
}

@article{23605,
  author       = {{Paulsen, Bryan D. and Wu, Ruiheng and Takacs, Christopher J. and Steinrück, Hans-Georg and Strzalka, Joseph and Zhang, Qingteng and Toney, Michael F. and Rivnay, Jonathan}},
  issn         = {{0935-9648}},
  journal      = {{Advanced Materials}},
  pages        = {{2003404}},
  title        = {{{Time‐Resolved Structural Kinetics of an Organic Mixed Ionic–Electronic Conductor}}},
  doi          = {{10.1002/adma.202003404}},
  volume       = {{32}},
  year         = {{2020}},
}

@article{23606,
  author       = {{Steinrück, Hans-Georg and Cao, Chuntian and Lukatskaya, Maria R. and Takacs, Christopher J. and Wan, Gang and Mackanic, David G. and Tsao, Yuchi and Zhao, Jingbo and Helms, Brett A. and Xu, Kang and Borodin, Oleg and Wishart, James F. and Toney, Michael F.}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  pages        = {{23180--23187}},
  title        = {{{Interfacial Speciation Determines Interfacial Chemistry: X‐ray‐Induced Lithium Fluoride Formation from Water‐in‐salt Electrolytes on Solid Surfaces}}},
  doi          = {{10.1002/anie.202007745}},
  volume       = {{59}},
  year         = {{2020}},
}