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Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)}. <i>Acta Crystallographica Section E Structure Reports Online</i>. 2007;63(8):m2099-m2100. doi:<a href=\"https://doi.org/10.1107/s1600536807032801\">10.1107/s1600536807032801</a>","bibtex":"@article{Neuba_Seewald_Flörke_Henkel_2007, title={Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)}}, volume={63}, DOI={<a href=\"https://doi.org/10.1107/s1600536807032801\">10.1107/s1600536807032801</a>}, number={8}, journal={Acta Crystallographica Section E Structure Reports Online}, publisher={International Union of Crystallography (IUCr)}, author={Neuba, Adam and Seewald, Oliver and Flörke, Ulrich and Henkel, Gerald}, year={2007}, pages={m2099–m2100} }","mla":"Neuba, Adam, et al. “Di-μ-Oxido-Bis{[1,3-Bis(Tetramethylguanidino)Propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]Bromidomanganese(III)}.” <i>Acta Crystallographica Section E Structure Reports Online</i>, vol. 63, no. 8, International Union of Crystallography (IUCr), 2007, pp. m2099–100, doi:<a href=\"https://doi.org/10.1107/s1600536807032801\">10.1107/s1600536807032801</a>.","short":"A. Neuba, O. Seewald, U. Flörke, G. Henkel, Acta Crystallographica Section E Structure Reports Online 63 (2007) m2099–m2100.","apa":"Neuba, A., Seewald, O., Flörke, U., &#38; Henkel, G. (2007). Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)}. <i>Acta Crystallographica Section E Structure Reports Online</i>, <i>63</i>(8), m2099–m2100. <a href=\"https://doi.org/10.1107/s1600536807032801\">https://doi.org/10.1107/s1600536807032801</a>"},"intvolume":"        63","page":"m2099-m2100","year":"2007","author":[{"last_name":"Neuba","full_name":"Neuba, Adam","first_name":"Adam"},{"id":"495","full_name":"Seewald, Oliver","last_name":"Seewald","first_name":"Oliver"},{"first_name":"Ulrich","full_name":"Flörke, Ulrich","last_name":"Flörke"},{"full_name":"Henkel, Gerald","last_name":"Henkel","first_name":"Gerald"}],"date_created":"2025-02-12T09:19:48Z","volume":63,"publisher":"International Union of Crystallography (IUCr)","date_updated":"2025-02-12T09:20:07Z","doi":"10.1107/s1600536807032801","title":"Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)}"},{"type":"journal_article","publication":"European Journal of Organic Chemistry","status":"public","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>A series of bis‐guanidine ligands designed for use in biomimetic coordination chemistry has been extended to a library matrix combining unprecedented substitutional flexibility within the guanidyl residues with a wide range of aliphatic and aromatic spacers connecting these functionalities. The underlying protocol can be used with predefined ureas as well as secondary amines to build up these units by reaction with phosgene if the ureas are otherwise unavailable. In the latter case, the resulting urea intermediates do not have to be isolated as the reaction proceeds further with additional phosgene to yield a chloroformamidinium chloride which is transformed into the bis‐guanidine functionality by subsequent reaction with a suitable primary diamine in the presence of triethylamine as an auxiliary base. This concept has been used to synthesise and characterise more then two dozen different bis‐guanidines based on 12 discrete monoguanidine units and seven different spacers. These spacers have been chosen such that the most important phenotypes have been dealt with and which range from rigid to more flexible scaffolds. In addition to spacers with no metal‐binding capabilities, other species containing further donor functions such as <jats:italic>N</jats:italic>‐methyldiphenyleneamine or pyridine‐2,6‐diyl have also been used. The substitution patterns of the guanidine residues can be classified into acyclic and cyclic types. Among the cyclic types, one subset is characterised by five‐ or six‐membered heterocycles containing both the amino nitrogen atoms and another one by individual N‐heterocyclic systems for each amino nitrogen. Structurally characterised examples are 2‐{2‐[2‐(tetramethylguanidi­no)ethoxy]ethoxy}‐1‐(tetramethylguanidino)ethane (TMG<jats:sub>2</jats:sub>doo) in its diprotonated form and 2,2′‐bis[2<jats:italic>N</jats:italic>‐(1,1′,3,3′‐tetramethylguanidine)]diphenyleneamine (TMG<jats:sub>2</jats:sub>PA) as wellas <jats:italic>N</jats:italic><jats:sup>1</jats:sup>,<jats:italic>N</jats:italic><jats:sup>3</jats:sup>‐bis(dimorpholinomethylene)propane‐1,3‐diamine (DMorphG<jats:sub>2</jats:sub>p) as free bases. For the permethylated bis‐guanidine derivatives, the barrier to rotation around the (C=N)<jats:sub>guanidine</jats:sub> bond has been determined by means of temperature‐dependent EXSY <jats:sup>1</jats:sup>H NMR spectroscopy to range between 54 and 79 kJ mol<jats:sup>–1</jats:sup> depending on the type of spacer. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2005)</jats:p>"}],"user_id":"495","department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"_id":"58598","language":[{"iso":"eng"}],"issue":"22","publication_status":"published","publication_identifier":{"issn":["1434-193X","1099-0690"]},"citation":{"ama":"Herres‐Pawlis S, Neuba A, Seewald O, et al. A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry. <i>European Journal of Organic Chemistry</i>. 2005;2005(22):4879-4890. doi:<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>","chicago":"Herres‐Pawlis, Sonja, Adam Neuba, Oliver Seewald, Tarimala Seshadri, Hans Egold, Ulrich Flörke, and Gerald Henkel. “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry.” <i>European Journal of Organic Chemistry</i> 2005, no. 22 (2005): 4879–90. <a href=\"https://doi.org/10.1002/ejoc.200500340\">https://doi.org/10.1002/ejoc.200500340</a>.","ieee":"S. Herres‐Pawlis <i>et al.</i>, “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry,” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 22, pp. 4879–4890, 2005, doi: <a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>.","short":"S. Herres‐Pawlis, A. Neuba, O. Seewald, T. Seshadri, H. Egold, U. Flörke, G. Henkel, European Journal of Organic Chemistry 2005 (2005) 4879–4890.","bibtex":"@article{Herres‐Pawlis_Neuba_Seewald_Seshadri_Egold_Flörke_Henkel_2005, title={A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry}, volume={2005}, DOI={<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>}, number={22}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Herres‐Pawlis, Sonja and Neuba, Adam and Seewald, Oliver and Seshadri, Tarimala and Egold, Hans and Flörke, Ulrich and Henkel, Gerald}, year={2005}, pages={4879–4890} }","mla":"Herres‐Pawlis, Sonja, et al. “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry.” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 22, Wiley, 2005, pp. 4879–90, doi:<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>.","apa":"Herres‐Pawlis, S., Neuba, A., Seewald, O., Seshadri, T., Egold, H., Flörke, U., &#38; Henkel, G. (2005). A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry. <i>European Journal of Organic Chemistry</i>, <i>2005</i>(22), 4879–4890. <a href=\"https://doi.org/10.1002/ejoc.200500340\">https://doi.org/10.1002/ejoc.200500340</a>"},"intvolume":"      2005","page":"4879-4890","year":"2005","date_created":"2025-02-12T09:27:00Z","author":[{"first_name":"Sonja","last_name":"Herres‐Pawlis","full_name":"Herres‐Pawlis, Sonja"},{"full_name":"Neuba, Adam","last_name":"Neuba","first_name":"Adam"},{"last_name":"Seewald","id":"495","full_name":"Seewald, Oliver","first_name":"Oliver"},{"full_name":"Seshadri, Tarimala","last_name":"Seshadri","first_name":"Tarimala"},{"first_name":"Hans","full_name":"Egold, Hans","last_name":"Egold"},{"first_name":"Ulrich","full_name":"Flörke, Ulrich","last_name":"Flörke"},{"last_name":"Henkel","full_name":"Henkel, Gerald","first_name":"Gerald"}],"volume":2005,"publisher":"Wiley","date_updated":"2025-02-12T09:30:43Z","doi":"10.1002/ejoc.200500340","title":"A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry"},{"date_updated":"2025-02-12T09:30:52Z","volume":632,"author":[{"full_name":"Seewald, Oliver","id":"495","last_name":"Seewald","first_name":"Oliver"},{"first_name":"Ulrich","full_name":"Flörke, Ulrich","last_name":"Flörke"},{"first_name":"Hans","full_name":"Egold, Hans","last_name":"Egold"},{"first_name":"Hans‐Jürgen","full_name":"Haupt, Hans‐Jürgen","last_name":"Haupt"},{"full_name":"Schwefer, Meinhard","last_name":"Schwefer","first_name":"Meinhard"}],"doi":"10.1002/zaac.200500340","publication_identifier":{"issn":["0044-2313","1521-3749"]},"publication_status":"published","intvolume":"       632","page":"204-210","citation":{"ama":"Seewald O, Flörke U, Egold H, Haupt H, Schwefer M. Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au). <i>Zeitschrift für anorganische und allgemeine Chemie</i>. 2005;632(2):204-210. doi:<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>","chicago":"Seewald, Oliver, Ulrich Flörke, Hans Egold, Hans‐Jürgen Haupt, and Meinhard Schwefer. “Synthese Und Struktur Chiraler Heterometallatetrahedrane Des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(Μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au).” <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i> 632, no. 2 (2005): 204–10. <a href=\"https://doi.org/10.1002/zaac.200500340\">https://doi.org/10.1002/zaac.200500340</a>.","ieee":"O. Seewald, U. Flörke, H. Egold, H. Haupt, and M. Schwefer, “Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au),” <i>Zeitschrift für anorganische und allgemeine Chemie</i>, vol. 632, no. 2, pp. 204–210, 2005, doi: <a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>.","mla":"Seewald, Oliver, et al. “Synthese Und Struktur Chiraler Heterometallatetrahedrane Des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(Μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au).” <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i>, vol. 632, no. 2, Wiley, 2005, pp. 204–10, doi:<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>.","bibtex":"@article{Seewald_Flörke_Egold_Haupt_Schwefer_2005, title={Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au)}, volume={632}, DOI={<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>}, number={2}, journal={Zeitschrift für anorganische und allgemeine Chemie}, publisher={Wiley}, author={Seewald, Oliver and Flörke, Ulrich and Egold, Hans and Haupt, Hans‐Jürgen and Schwefer, Meinhard}, year={2005}, pages={204–210} }","short":"O. Seewald, U. Flörke, H. Egold, H. Haupt, M. Schwefer, Zeitschrift Für Anorganische Und Allgemeine Chemie 632 (2005) 204–210.","apa":"Seewald, O., Flörke, U., Egold, H., Haupt, H., &#38; Schwefer, M. (2005). Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au). <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i>, <i>632</i>(2), 204–210. <a href=\"https://doi.org/10.1002/zaac.200500340\">https://doi.org/10.1002/zaac.200500340</a>"},"_id":"58597","department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"user_id":"495","type":"journal_article","status":"public","publisher":"Wiley","date_created":"2025-02-12T09:26:12Z","title":"Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au)","issue":"2","year":"2005","language":[{"iso":"eng"}],"publication":"Zeitschrift für anorganische und allgemeine Chemie","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p><jats:bold>Syntheses and Structure of Chiral Metallatetrahedron Complexes of the Type [Re<jats:sub>2</jats:sub>(M<jats:sup>1</jats:sup>PPh<jats:sub>3</jats:sub>)(M<jats:sup>2</jats:sup>PPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (M<jats:sup>1</jats:sup> = Ag, Au; M<jats:sup>2</jats:sup> = Cu, Ag, Au)</jats:bold></jats:p><jats:p>From the reaction of Li[Re<jats:sub>2</jats:sub>(μ‐H)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>(C(Ph)O)] (<jats:bold>1</jats:bold>) with Ph<jats:sub>3</jats:sub>AuC≡CPh both benzaldehyde and the trinuclear complex Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>2a</jats:bold>) were obtained in high yield. The complex anion was isolated as its PPh<jats:sub>4</jats:sub>‐salt <jats:bold>2b</jats:bold>. The latter reacts with coinage metal complexes PPh<jats:sub>3</jats:sub>M<jats:sup>2</jats:sup>Cl [M<jats:sup>2</jats:sup> = Cu, Ag, Au] to give chiral heterometallatetrahedranes of the general formula [Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(M<jats:sup>2</jats:sup>PPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (M<jats:sup>2</jats:sup> = Cu <jats:bold>3a</jats:bold>, Ag <jats:bold>3b</jats:bold>, Au <jats:bold>3c</jats:bold>). The corresponding complex [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>3d</jats:bold>) is obtained from the reaction of [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>4</jats:bold>) with LiC≡CPh. <jats:bold>3d</jats:bold> undergoes a metathesis reaction in the presence of PPh<jats:sub>3</jats:sub>CuCl giving [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)(CuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>3e</jats:bold>) and PPh<jats:sub>3</jats:sub>AgCl. Analogous metathesis reactions are observed when <jats:bold>3c</jats:bold> is reacted with PPh<jats:sub>3</jats:sub>AgCl or PPh<jats:sub>3</jats:sub>CuCl giving <jats:bold>3a</jats:bold> or <jats:bold>3b</jats:bold>, respectively. The reaction of <jats:bold>1</jats:bold> with PPh<jats:sub>3</jats:sub>AuCl gives benzaldehyde and Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>5a</jats:bold>) which upon reaction with PhLi forms the trinuclear complex Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Ph] (<jats:bold>6a</jats:bold>). Again this complex was isolated as its PPh<jats:sub>4</jats:sub>‐salt <jats:bold>6b</jats:bold>. In contrast to <jats:bold>2b</jats:bold>, <jats:bold>6b</jats:bold> reacts with one equivalent of Ph<jats:sub>3</jats:sub>PAuCl by transmetalation to give Ph<jats:sub>3</jats:sub>PAuPh and PPh<jats:sub>4</jats:sub>[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>5b</jats:bold>). The X‐ray structures of the compounds <jats:bold>3a</jats:bold>, <jats:bold>3b</jats:bold>, <jats:bold>3e</jats:bold> and <jats:bold>4</jats:bold> are reported.</jats:p>"}]},{"citation":{"chicago":"Hinderling, C., Y. Keles, T. Stöckli, H. F. Knapp, Maria Teresa de los Arcos de Pedro, P. Oelhafen, I. Korczagin, et al. “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth.” <i>Advanced Materials</i>, 2004, 876–79. <a href=\"https://doi.org/10.1002/adma.200306447\">https://doi.org/10.1002/adma.200306447</a>.","ieee":"C. Hinderling <i>et al.</i>, “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth,” <i>Advanced Materials</i>, pp. 876–879, 2004, doi: <a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>.","ama":"Hinderling C, Keles Y, Stöckli T, et al. Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth. <i>Advanced Materials</i>. Published online 2004:876-879. doi:<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>","bibtex":"@article{Hinderling_Keles_Stöckli_Knapp_de los Arcos de Pedro_Oelhafen_Korczagin_Hempenius_Vancso_Pugin_et al._2004, title={Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth}, DOI={<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>}, journal={Advanced Materials}, author={Hinderling, C. and Keles, Y. and Stöckli, T. and Knapp, H. F. and de los Arcos de Pedro, Maria Teresa and Oelhafen, P. and Korczagin, I. and Hempenius, M. A. and Vancso, G. J. and Pugin, R. and et al.}, year={2004}, pages={876–879} }","mla":"Hinderling, C., et al. “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth.” <i>Advanced Materials</i>, 2004, pp. 876–79, doi:<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>.","short":"C. Hinderling, Y. Keles, T. Stöckli, H.F. Knapp, M.T. de los Arcos de Pedro, P. Oelhafen, I. Korczagin, M.A. Hempenius, G.J. Vancso, R. Pugin, H. Heinzelmann, Advanced Materials (2004) 876–879.","apa":"Hinderling, C., Keles, Y., Stöckli, T., Knapp, H. F., de los Arcos de Pedro, M. T., Oelhafen, P., Korczagin, I., Hempenius, M. A., Vancso, G. J., Pugin, R., &#38; Heinzelmann, H. (2004). Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth. <i>Advanced Materials</i>, 876–879. <a href=\"https://doi.org/10.1002/adma.200306447\">https://doi.org/10.1002/adma.200306447</a>"},"page":"876-879","year":"2004","publication_status":"published","publication_identifier":{"issn":["0935-9648","1521-4095"]},"doi":"10.1002/adma.200306447","title":"Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth","date_created":"2021-07-07T11:40:38Z","author":[{"first_name":"C.","full_name":"Hinderling, C.","last_name":"Hinderling"},{"full_name":"Keles, Y.","last_name":"Keles","first_name":"Y."},{"first_name":"T.","full_name":"Stöckli, T.","last_name":"Stöckli"},{"first_name":"H. F.","last_name":"Knapp","full_name":"Knapp, H. F."},{"id":"54556","full_name":"de los Arcos de Pedro, Maria Teresa","last_name":"de los Arcos de Pedro","first_name":"Maria Teresa"},{"last_name":"Oelhafen","full_name":"Oelhafen, P.","first_name":"P."},{"first_name":"I.","full_name":"Korczagin, I.","last_name":"Korczagin"},{"first_name":"M. A.","last_name":"Hempenius","full_name":"Hempenius, M. A."},{"last_name":"Vancso","full_name":"Vancso, G. J.","first_name":"G. J."},{"first_name":"R.","last_name":"Pugin","full_name":"Pugin, R."},{"first_name":"H.","last_name":"Heinzelmann","full_name":"Heinzelmann, H."}],"date_updated":"2023-01-24T08:29:17Z","status":"public","type":"journal_article","publication":"Advanced Materials","language":[{"iso":"eng"}],"extern":"1","user_id":"54556","department":[{"_id":"302"}],"_id":"22616"},{"doi":"10.1021/jp049495v","title":"The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth","author":[{"last_name":"de los Arcos de Pedro","id":"54556","full_name":"de los Arcos de Pedro, Maria Teresa","first_name":"Maria Teresa"},{"last_name":"Garnier","full_name":"Garnier, Michael Gunnar","first_name":"Michael Gunnar"},{"first_name":"Jin Won","last_name":"Seo","full_name":"Seo, Jin Won"},{"last_name":"Oelhafen","full_name":"Oelhafen, Peter","first_name":"Peter"},{"first_name":"Verena","full_name":"Thommen, Verena","last_name":"Thommen"},{"last_name":"Mathys","full_name":"Mathys, Daniel","first_name":"Daniel"}],"date_created":"2021-07-07T11:40:10Z","date_updated":"2023-01-24T08:29:03Z","page":"7728-7734","citation":{"apa":"de los Arcos de Pedro, M. 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