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Liquid-Phase Epitaxy of Multicomponent Layer-Based Porous Coordination Polymer Thin Films of [M(L)(P)0.5] Type: Importance of Deposition Sequence on the Oriented Growth. <i>Chemistry - A European Journal</i>. Published online 2011:1448-1455. doi:<a href=\"https://doi.org/10.1002/chem.201002381\">10.1002/chem.201002381</a>","ieee":"D. Zacher <i>et al.</i>, “Liquid-Phase Epitaxy of Multicomponent Layer-Based Porous Coordination Polymer Thin Films of [M(L)(P)0.5] Type: Importance of Deposition Sequence on the Oriented Growth,” <i>Chemistry - A European Journal</i>, pp. 1448–1455, 2011, doi: <a href=\"https://doi.org/10.1002/chem.201002381\">10.1002/chem.201002381</a>.","apa":"Zacher, D., Yusenko, K., Bétard, A., Henke, S., Molon, M., Ladnorg, T., Shekhah, O., Schüpbach, B., de los Arcos de Pedro, M. T., Krasnopolski, M., Meilikhov, M., Winter, J., Terfort, A., Wöll, C., &#38; Fischer, R. A. (2011). 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Thissen, and Guido Grundmeier. “Dissociative and Molecular Adsorption of Water Onα-Al2O3(0001).” <i>Physica Status Solidi (c)</i> 7, no. 2 (2010): 137–40. <a href=\"https://doi.org/10.1002/pssc.200982423\">https://doi.org/10.1002/pssc.200982423</a>.","short":"S. Wippermann, W.G. Schmidt, P. Thissen, G. Grundmeier, Physica Status Solidi (c) 7 (2010) 137–140."},"project":[{"_id":"52","name":"Computing Resources Provided by the Paderborn Center for Parallel Computing"}],"page":"137-140","_id":"13843","funded_apc":"1","user_id":"16199","volume":7,"status":"public"},{"page":"2641-2649","_id":"58593","publisher":"Wiley","user_id":"495","volume":636,"status":"public","citation":{"mla":"Neuba, Adam, et al. “Systematische Studie Zu Den Koordinationseigenschaften Des Guanidin‐Liganden Bis(Tetramethylguanidino)Propan Mit Den Metallen Mangan, Cobalt, Nickel, Zink, Cadmium, Quecksilber Und Silber.” <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i>, vol. 636, no. 15, Wiley, 2010, pp. 2641–49, doi:<a href=\"https://doi.org/10.1002/zaac.201000133\">10.1002/zaac.201000133</a>.","bibtex":"@article{Neuba_Herres‐Pawlis_Seewald_Börner_Heuwing_Flörke_Henkel_2010, title={Systematische Studie zu den Koordinationseigenschaften des Guanidin‐Liganden Bis(tetramethylguanidino)propan mit den Metallen Mangan, Cobalt, Nickel, Zink, Cadmium, Quecksilber und Silber}, volume={636}, DOI={<a href=\"https://doi.org/10.1002/zaac.201000133\">10.1002/zaac.201000133</a>}, number={15}, journal={Zeitschrift für anorganische und allgemeine Chemie}, publisher={Wiley}, author={Neuba, Adam and Herres‐Pawlis, Sonja and Seewald, Oliver and Börner, Janna and Heuwing, Andreas J. and Flörke, Ulrich and Henkel, Gerald}, year={2010}, pages={2641–2649} }","ama":"Neuba A, Herres‐Pawlis S, Seewald O, et al. Systematische Studie zu den Koordinationseigenschaften des Guanidin‐Liganden Bis(tetramethylguanidino)propan mit den Metallen Mangan, Cobalt, Nickel, Zink, Cadmium, Quecksilber und Silber. <i>Zeitschrift für anorganische und allgemeine Chemie</i>. 2010;636(15):2641-2649. doi:<a href=\"https://doi.org/10.1002/zaac.201000133\">10.1002/zaac.201000133</a>","ieee":"A. Neuba <i>et al.</i>, “Systematische Studie zu den Koordinationseigenschaften des Guanidin‐Liganden Bis(tetramethylguanidino)propan mit den Metallen Mangan, Cobalt, Nickel, Zink, Cadmium, Quecksilber und Silber,” <i>Zeitschrift für anorganische und allgemeine Chemie</i>, vol. 636, no. 15, pp. 2641–2649, 2010, doi: <a href=\"https://doi.org/10.1002/zaac.201000133\">10.1002/zaac.201000133</a>.","apa":"Neuba, A., Herres‐Pawlis, S., Seewald, O., Börner, J., Heuwing, A. J., Flörke, U., &#38; Henkel, G. (2010). Systematische Studie zu den Koordinationseigenschaften des Guanidin‐Liganden Bis(tetramethylguanidino)propan mit den Metallen Mangan, Cobalt, Nickel, Zink, Cadmium, Quecksilber und Silber. <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i>, <i>636</i>(15), 2641–2649. <a href=\"https://doi.org/10.1002/zaac.201000133\">https://doi.org/10.1002/zaac.201000133</a>","short":"A. Neuba, S. Herres‐Pawlis, O. Seewald, J. Börner, A.J. Heuwing, U. Flörke, G. Henkel, Zeitschrift Für Anorganische Und Allgemeine Chemie 636 (2010) 2641–2649.","chicago":"Neuba, Adam, Sonja Herres‐Pawlis, Oliver Seewald, Janna Börner, Andreas J. Heuwing, Ulrich Flörke, and Gerald Henkel. “Systematische Studie Zu Den Koordinationseigenschaften Des Guanidin‐Liganden Bis(Tetramethylguanidino)Propan Mit Den Metallen Mangan, Cobalt, Nickel, Zink, Cadmium, Quecksilber Und Silber.” <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i> 636, no. 15 (2010): 2641–49. <a href=\"https://doi.org/10.1002/zaac.201000133\">https://doi.org/10.1002/zaac.201000133</a>."},"language":[{"iso":"eng"}],"doi":"10.1002/zaac.201000133","year":"2010","title":"Systematische Studie zu den Koordinationseigenschaften des Guanidin‐Liganden Bis(tetramethylguanidino)propan mit den Metallen Mangan, Cobalt, Nickel, Zink, Cadmium, Quecksilber und Silber","publication_identifier":{"issn":["0044-2313","1521-3749"]},"author":[{"first_name":"Adam","last_name":"Neuba","full_name":"Neuba, Adam"},{"full_name":"Herres‐Pawlis, Sonja","last_name":"Herres‐Pawlis","first_name":"Sonja"},{"full_name":"Seewald, Oliver","first_name":"Oliver","last_name":"Seewald","id":"495"},{"last_name":"Börner","first_name":"Janna","full_name":"Börner, Janna"},{"full_name":"Heuwing, Andreas J.","first_name":"Andreas J.","last_name":"Heuwing"},{"first_name":"Ulrich","last_name":"Flörke","full_name":"Flörke, Ulrich"},{"full_name":"Henkel, Gerald","first_name":"Gerald","last_name":"Henkel"}],"date_updated":"2025-02-12T09:31:09Z","publication_status":"published","intvolume":"       636","date_created":"2025-02-12T09:23:52Z","type":"journal_article","department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"publication":"Zeitschrift für anorganische und allgemeine Chemie","issue":"15","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>The transition metal complexes with the ligand 1,3‐bis(<jats:italic>N</jats:italic>,<jats:italic>N</jats:italic>,<jats:italic>N′</jats:italic>,<jats:italic>N′</jats:italic>‐tetramethylguanidino)propane (btmgp), [Mn(btmgp)Br<jats:sub>2</jats:sub>] (<jats:bold>1</jats:bold>), [Co(btmgp)Cl<jats:sub>2</jats:sub>] (<jats:bold>2</jats:bold>), [Ni(btmgp)I<jats:sub>2</jats:sub>] (<jats:bold>3</jats:bold>), [Zn(btmgp)Cl<jats:sub>2</jats:sub>] (<jats:bold>4</jats:bold>), [Zn(btmgp)(O<jats:sub>2</jats:sub>CCH<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>] (<jats:bold>5</jats:bold>), [Cd(btmgp)Cl<jats:sub>2</jats:sub>] (<jats:bold>6</jats:bold>), [Hg(btmgp)Cl<jats:sub>2</jats:sub>] (<jats:bold>7</jats:bold>) and [Ag<jats:sub>2</jats:sub>(btmgp)<jats:sub>2</jats:sub>][ClO<jats:sub>4</jats:sub>]<jats:sub>2</jats:sub>·2MeCN (<jats:bold>8</jats:bold>), were prepared and characterised for the first time. The stoichiometric reaction of the corresponding water‐free metal salts with the ligand btmgp in dry MeCN or THF resulted in the straightforward formation of the mononuclear complexes <jats:bold>1</jats:bold>–<jats:bold>7</jats:bold> and the binuclear complex <jats:bold>8</jats:bold>. In complexes with <jats:italic>M</jats:italic><jats:sup>II</jats:sup> the metal ion shows a distorted tetrahedral coordination whereas in <jats:bold>8</jats:bold>, the coordination of the <jats:italic>M</jats:italic><jats:sup>I</jats:sup> ion is almost linear. The coordination behavior of btmgp and resulting structural parameters of the corresponding complexes were discussed in an comparative approach together with already described complexes of btmgp and the bisguanidine ligand N<jats:sup>1</jats:sup>,N<jats:sup>2</jats:sup>‐bis(1,3‐dimethylimidazolidin‐2‐ylidene)‐ethane‐1,2‐diamine (DMEG<jats:sub>2</jats:sub>e), respectively.</jats:p>","lang":"eng"}]},{"year":"2009","title":"The importance of catalyst oxidation for the growth of carbon nanotubes on Si substrates","status":"public","author":[{"id":"54556","full_name":"de los Arcos de Pedro, Maria Teresa","last_name":"de los Arcos de Pedro","first_name":"Maria Teresa"},{"last_name":"Oelhafen","first_name":"Peter","full_name":"Oelhafen, Peter"},{"full_name":"Mathys, Daniel","first_name":"Daniel","last_name":"Mathys"}],"publication_identifier":{"issn":["0008-6223"]},"publication_status":"published","date_updated":"2023-01-24T08:28:02Z","page":"1977-1982","language":[{"iso":"eng"}],"_id":"22610","user_id":"54556","doi":"10.1016/j.carbon.2009.03.049","publication":"Carbon","citation":{"chicago":"Arcos de Pedro, Maria Teresa de los, Peter Oelhafen, and Daniel Mathys. “The Importance of Catalyst Oxidation for the Growth of Carbon Nanotubes on Si Substrates.” <i>Carbon</i>, 2009, 1977–82. <a href=\"https://doi.org/10.1016/j.carbon.2009.03.049\">https://doi.org/10.1016/j.carbon.2009.03.049</a>.","short":"M.T. de los Arcos de Pedro, P. Oelhafen, D. Mathys, Carbon (2009) 1977–1982.","apa":"de los Arcos de Pedro, M. T., Oelhafen, P., &#38; Mathys, D. (2009). The importance of catalyst oxidation for the growth of carbon nanotubes on Si substrates. <i>Carbon</i>, 1977–1982. <a href=\"https://doi.org/10.1016/j.carbon.2009.03.049\">https://doi.org/10.1016/j.carbon.2009.03.049</a>","ieee":"M. T. de los Arcos de Pedro, P. Oelhafen, and D. Mathys, “The importance of catalyst oxidation for the growth of carbon nanotubes on Si substrates,” <i>Carbon</i>, pp. 1977–1982, 2009, doi: <a href=\"https://doi.org/10.1016/j.carbon.2009.03.049\">10.1016/j.carbon.2009.03.049</a>.","ama":"de los Arcos de Pedro MT, Oelhafen P, Mathys D. The importance of catalyst oxidation for the growth of carbon nanotubes on Si substrates. <i>Carbon</i>. Published online 2009:1977-1982. doi:<a href=\"https://doi.org/10.1016/j.carbon.2009.03.049\">10.1016/j.carbon.2009.03.049</a>","bibtex":"@article{de los Arcos de Pedro_Oelhafen_Mathys_2009, title={The importance of catalyst oxidation for the growth of carbon nanotubes on Si substrates}, DOI={<a href=\"https://doi.org/10.1016/j.carbon.2009.03.049\">10.1016/j.carbon.2009.03.049</a>}, journal={Carbon}, author={de los Arcos de Pedro, Maria Teresa and Oelhafen, Peter and Mathys, Daniel}, year={2009}, pages={1977–1982} }","mla":"de los Arcos de Pedro, Maria Teresa, et al. “The Importance of Catalyst Oxidation for the Growth of Carbon Nanotubes on Si Substrates.” <i>Carbon</i>, 2009, pp. 1977–82, doi:<a href=\"https://doi.org/10.1016/j.carbon.2009.03.049\">10.1016/j.carbon.2009.03.049</a>."},"extern":"1","date_created":"2021-07-07T11:32:05Z","type":"journal_article","department":[{"_id":"302"}]},{"publication_status":"published","date_updated":"2025-12-05T10:51:06Z","intvolume":"         7","title":"Dissociative and molecular adsorption of water onα-Al2O3(0001)","year":"2009","author":[{"full_name":"Wippermann, S.","first_name":"S.","last_name":"Wippermann"},{"first_name":"Wolf Gero","last_name":"Schmidt","orcid":"0000-0002-2717-5076","full_name":"Schmidt, Wolf Gero","id":"468"},{"full_name":"Thissen, P.","last_name":"Thissen","first_name":"P."},{"id":"194","first_name":"Guido","last_name":"Grundmeier","full_name":"Grundmeier, Guido"}],"publication_identifier":{"issn":["1862-6351","1610-1642"]},"doi":"10.1002/pssc.200982423","language":[{"iso":"eng"}],"publication":"physica status solidi (c)","issue":"2","type":"journal_article","department":[{"_id":"15"},{"_id":"170"},{"_id":"295"},{"_id":"2"},{"_id":"302"},{"_id":"35"},{"_id":"27"},{"_id":"230"}],"date_created":"2019-10-01T14:32:47Z","status":"public","user_id":"16199","volume":7,"page":"137-140","_id":"13580","project":[{"_id":"52","name":"Computing Resources Provided by the Paderborn Center for Parallel Computing"}],"citation":{"short":"S. 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Schmidt, Surface Science 603 (2009) 60–64.","mla":"Lange, B., et al. “Water Adsorption on Hydrogenated Si(111) Surfaces.” <i>Surface Science</i>, vol. 603, 2009, pp. 60–64, doi:<a href=\"https://doi.org/10.1016/j.susc.2008.10.030\">10.1016/j.susc.2008.10.030</a>.","ama":"Lange B, Posner R, Pohl K, et al. Water adsorption on hydrogenated Si(111) surfaces. <i>Surface Science</i>. 2009;603:60-64. doi:<a href=\"https://doi.org/10.1016/j.susc.2008.10.030\">10.1016/j.susc.2008.10.030</a>","bibtex":"@article{Lange_Posner_Pohl_Thierfelder_Grundmeier_Blankenburg_Schmidt_2009, title={Water adsorption on hydrogenated Si(111) surfaces}, volume={603}, DOI={<a href=\"https://doi.org/10.1016/j.susc.2008.10.030\">10.1016/j.susc.2008.10.030</a>}, journal={Surface Science}, author={Lange, B. and Posner, R. and Pohl, K. and Thierfelder, C. and Grundmeier, Guido and Blankenburg, S. and Schmidt, Wolf Gero}, year={2009}, pages={60–64} }"},"status":"public","user_id":"16199","volume":603,"page":"60-64","_id":"13664","funded_apc":"1"},{"department":[{"_id":"15"},{"_id":"170"},{"_id":"295"},{"_id":"2"},{"_id":"302"},{"_id":"35"},{"_id":"230"},{"_id":"27"}],"type":"journal_article","date_created":"2019-10-09T08:53:23Z","project":[{"name":"Computing Resources Provided by the Paderborn Center for Parallel Computing","_id":"52"}],"citation":{"chicago":"Thissen, P., Guido Grundmeier, S. Wippermann, and Wolf Gero Schmidt. “Water Adsorption on the α-Al2O3(0001) Surface.” <i>Physical Review B</i> 80, no. 24 (2009). <a href=\"https://doi.org/10.1103/physrevb.80.245403\">https://doi.org/10.1103/physrevb.80.245403</a>.","short":"P. Thissen, G. Grundmeier, S. Wippermann, W.G. Schmidt, Physical Review B 80 (2009).","ieee":"P. Thissen, G. Grundmeier, S. Wippermann, and W. G. Schmidt, “Water adsorption on the α-Al2O3(0001) surface,” <i>Physical Review B</i>, vol. 80, no. 24, 2009, doi: <a href=\"https://doi.org/10.1103/physrevb.80.245403\">10.1103/physrevb.80.245403</a>.","apa":"Thissen, P., Grundmeier, G., Wippermann, S., &#38; Schmidt, W. G. (2009). Water adsorption on the α-Al2O3(0001) surface. <i>Physical Review B</i>, <i>80</i>(24). <a href=\"https://doi.org/10.1103/physrevb.80.245403\">https://doi.org/10.1103/physrevb.80.245403</a>","bibtex":"@article{Thissen_Grundmeier_Wippermann_Schmidt_2009, title={Water adsorption on the α-Al2O3(0001) surface}, volume={80}, DOI={<a href=\"https://doi.org/10.1103/physrevb.80.245403\">10.1103/physrevb.80.245403</a>}, number={24}, journal={Physical Review B}, author={Thissen, P. and Grundmeier, Guido and Wippermann, S. and Schmidt, Wolf Gero}, year={2009} }","ama":"Thissen P, Grundmeier G, Wippermann S, Schmidt WG. Water adsorption on the α-Al2O3(0001) surface. <i>Physical Review B</i>. 2009;80(24). doi:<a href=\"https://doi.org/10.1103/physrevb.80.245403\">10.1103/physrevb.80.245403</a>","mla":"Thissen, P., et al. “Water Adsorption on the α-Al2O3(0001) Surface.” <i>Physical Review B</i>, vol. 80, no. 24, 2009, doi:<a href=\"https://doi.org/10.1103/physrevb.80.245403\">10.1103/physrevb.80.245403</a>."},"issue":"24","publication":"Physical Review B","volume":80,"user_id":"16199","doi":"10.1103/physrevb.80.245403","language":[{"iso":"eng"}],"_id":"13655","intvolume":"        80","publication_status":"published","date_updated":"2025-12-05T13:14:27Z","publication_identifier":{"issn":["1098-0121","1550-235X"]},"author":[{"full_name":"Thissen, P.","first_name":"P.","last_name":"Thissen"},{"last_name":"Grundmeier","first_name":"Guido","full_name":"Grundmeier, Guido","id":"194"},{"first_name":"S.","last_name":"Wippermann","full_name":"Wippermann, S."},{"id":"468","orcid":"0000-0002-2717-5076","last_name":"Schmidt","first_name":"Wolf Gero","full_name":"Schmidt, Wolf Gero"}],"title":"Water adsorption on the α-Al2O3(0001) surface","status":"public","year":"2009"},{"publication_identifier":{"issn":["0370-1972"]},"author":[{"full_name":"Rümmeli, M. H.","first_name":"M. H.","last_name":"Rümmeli"},{"full_name":"Schäffel, F.","last_name":"Schäffel","first_name":"F."},{"last_name":"de los Arcos de Pedro","first_name":"Maria Teresa","full_name":"de los Arcos de Pedro, Maria Teresa","id":"54556"},{"first_name":"D.","last_name":"Haberer","full_name":"Haberer, D."},{"full_name":"Bachmatiuk, A.","first_name":"A.","last_name":"Bachmatiuk"},{"full_name":"Kramberger, C.","first_name":"C.","last_name":"Kramberger"},{"first_name":"P.","last_name":"Ayala","full_name":"Ayala, P."},{"full_name":"Borowiak-Palen, E.","first_name":"E.","last_name":"Borowiak-Palen"},{"first_name":"D.","last_name":"Adebimpe","full_name":"Adebimpe, D."},{"full_name":"Gemming, T.","first_name":"T.","last_name":"Gemming"},{"last_name":"Leonhardt","first_name":"A.","full_name":"Leonhardt, A."},{"full_name":"Rellinghaus, B.","last_name":"Rellinghaus","first_name":"B."},{"first_name":"L.","last_name":"Schultz","full_name":"Schultz, L."},{"full_name":"Pichler, T.","last_name":"Pichler","first_name":"T."},{"first_name":"B.","last_name":"Büchner","full_name":"Büchner, B."}],"status":"public","year":"2008","title":"On the graphitisation role of oxide supports in carbon nanotube CVD synthesis","publication_status":"published","date_updated":"2023-01-24T08:28:18Z","language":[{"iso":"eng"}],"_id":"22611","page":"1939-1942","user_id":"54556","doi":"10.1002/pssb.200879597","citation":{"bibtex":"@article{Rümmeli_Schäffel_de los Arcos de Pedro_Haberer_Bachmatiuk_Kramberger_Ayala_Borowiak-Palen_Adebimpe_Gemming_et al._2008, title={On the graphitisation role of oxide supports in carbon nanotube CVD synthesis}, DOI={<a href=\"https://doi.org/10.1002/pssb.200879597\">10.1002/pssb.200879597</a>}, journal={physica status solidi (b)}, author={Rümmeli, M. H. and Schäffel, F. and de los Arcos de Pedro, Maria Teresa and Haberer, D. and Bachmatiuk, A. and Kramberger, C. and Ayala, P. and Borowiak-Palen, E. and Adebimpe, D. and Gemming, T. and et al.}, year={2008}, pages={1939–1942} }","ama":"Rümmeli MH, Schäffel F, de los Arcos de Pedro MT, et al. On the graphitisation role of oxide supports in carbon nanotube CVD synthesis. <i>physica status solidi (b)</i>. Published online 2008:1939-1942. doi:<a href=\"https://doi.org/10.1002/pssb.200879597\">10.1002/pssb.200879597</a>","mla":"Rümmeli, M. H., et al. “On the Graphitisation Role of Oxide Supports in Carbon Nanotube CVD Synthesis.” <i>Physica Status Solidi (b)</i>, 2008, pp. 1939–42, doi:<a href=\"https://doi.org/10.1002/pssb.200879597\">10.1002/pssb.200879597</a>.","short":"M.H. Rümmeli, F. Schäffel, M.T. de los Arcos de Pedro, D. Haberer, A. Bachmatiuk, C. Kramberger, P. Ayala, E. Borowiak-Palen, D. Adebimpe, T. Gemming, A. Leonhardt, B. Rellinghaus, L. Schultz, T. Pichler, B. Büchner, Physica Status Solidi (b) (2008) 1939–1942.","chicago":"Rümmeli, M. H., F. Schäffel, Maria Teresa de los Arcos de Pedro, D. Haberer, A. Bachmatiuk, C. Kramberger, P. Ayala, et al. “On the Graphitisation Role of Oxide Supports in Carbon Nanotube CVD Synthesis.” <i>Physica Status Solidi (b)</i>, 2008, 1939–42. <a href=\"https://doi.org/10.1002/pssb.200879597\">https://doi.org/10.1002/pssb.200879597</a>.","ieee":"M. H. Rümmeli <i>et al.</i>, “On the graphitisation role of oxide supports in carbon nanotube CVD synthesis,” <i>physica status solidi (b)</i>, pp. 1939–1942, 2008, doi: <a href=\"https://doi.org/10.1002/pssb.200879597\">10.1002/pssb.200879597</a>.","apa":"Rümmeli, M. H., Schäffel, F., de los Arcos de Pedro, M. T., Haberer, D., Bachmatiuk, A., Kramberger, C., Ayala, P., Borowiak-Palen, E., Adebimpe, D., Gemming, T., Leonhardt, A., Rellinghaus, B., Schultz, L., Pichler, T., &#38; Büchner, B. (2008). On the graphitisation role of oxide supports in carbon nanotube CVD synthesis. <i>Physica Status Solidi (b)</i>, 1939–1942. <a href=\"https://doi.org/10.1002/pssb.200879597\">https://doi.org/10.1002/pssb.200879597</a>"},"publication":"physica status solidi (b)","extern":"1","date_created":"2021-07-07T11:39:16Z","department":[{"_id":"302"}],"type":"journal_article"},{"department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"type":"journal_article","date_created":"2025-02-12T09:24:36Z","issue":"7","publication":"Inorganica Chimica Acta","doi":"10.1016/j.ica.2007.09.047","language":[{"iso":"eng"}],"intvolume":"       361","date_updated":"2025-02-12T09:31:29Z","publication_status":"published","publication_identifier":{"issn":["0020-1693"]},"author":[{"last_name":"Ameerunisha Begum","first_name":"M.S.","full_name":"Ameerunisha Begum, M.S."},{"last_name":"Seewald","first_name":"Oliver","full_name":"Seewald, Oliver","id":"495"},{"full_name":"Flörke, Ulrich","first_name":"Ulrich","last_name":"Flörke"},{"first_name":"Gerald","last_name":"Henkel","full_name":"Henkel, Gerald"}],"year":"2008","title":"From the {Cu(μ2-S)N}4 butterfly architecture to the {Cu(μ3-S)N}12 double wheel","citation":{"bibtex":"@article{Ameerunisha Begum_Seewald_Flörke_Henkel_2008, title={From the {Cu(μ2-S)N}4 butterfly architecture to the {Cu(μ3-S)N}12 double wheel}, volume={361}, DOI={<a href=\"https://doi.org/10.1016/j.ica.2007.09.047\">10.1016/j.ica.2007.09.047</a>}, number={7}, journal={Inorganica Chimica Acta}, publisher={Elsevier BV}, author={Ameerunisha Begum, M.S. and Seewald, Oliver and Flörke, Ulrich and Henkel, Gerald}, year={2008}, pages={1868–1874} }","ama":"Ameerunisha Begum MS, Seewald O, Flörke U, Henkel G. From the {Cu(μ2-S)N}4 butterfly architecture to the {Cu(μ3-S)N}12 double wheel. <i>Inorganica Chimica Acta</i>. 2008;361(7):1868-1874. doi:<a href=\"https://doi.org/10.1016/j.ica.2007.09.047\">10.1016/j.ica.2007.09.047</a>","mla":"Ameerunisha Begum, M. S., et al. “From the {Cu(Μ2-S)N}4 Butterfly Architecture to the {Cu(Μ3-S)N}12 Double Wheel.” <i>Inorganica Chimica Acta</i>, vol. 361, no. 7, Elsevier BV, 2008, pp. 1868–74, doi:<a href=\"https://doi.org/10.1016/j.ica.2007.09.047\">10.1016/j.ica.2007.09.047</a>.","chicago":"Ameerunisha Begum, M.S., Oliver Seewald, Ulrich Flörke, and Gerald Henkel. “From the {Cu(Μ2-S)N}4 Butterfly Architecture to the {Cu(Μ3-S)N}12 Double Wheel.” <i>Inorganica Chimica Acta</i> 361, no. 7 (2008): 1868–74. <a href=\"https://doi.org/10.1016/j.ica.2007.09.047\">https://doi.org/10.1016/j.ica.2007.09.047</a>.","short":"M.S. Ameerunisha Begum, O. Seewald, U. Flörke, G. Henkel, Inorganica Chimica Acta 361 (2008) 1868–1874.","ieee":"M. S. Ameerunisha Begum, O. Seewald, U. Flörke, and G. Henkel, “From the {Cu(μ2-S)N}4 butterfly architecture to the {Cu(μ3-S)N}12 double wheel,” <i>Inorganica Chimica Acta</i>, vol. 361, no. 7, pp. 1868–1874, 2008, doi: <a href=\"https://doi.org/10.1016/j.ica.2007.09.047\">10.1016/j.ica.2007.09.047</a>.","apa":"Ameerunisha Begum, M. S., Seewald, O., Flörke, U., &#38; Henkel, G. (2008). From the {Cu(μ2-S)N}4 butterfly architecture to the {Cu(μ3-S)N}12 double wheel. <i>Inorganica Chimica Acta</i>, <i>361</i>(7), 1868–1874. <a href=\"https://doi.org/10.1016/j.ica.2007.09.047\">https://doi.org/10.1016/j.ica.2007.09.047</a>"},"volume":361,"user_id":"495","_id":"58594","publisher":"Elsevier BV","page":"1868-1874","status":"public"},{"department":[{"_id":"302"}],"type":"journal_article","date_created":"2021-07-07T11:39:42Z","extern":"1","citation":{"mla":"de los Arcos de Pedro, Maria Teresa, et al. “The Influence of Catalyst’s Oxidation Degree on Carbon Nanotube Growth as a Substrate-Independent Parameter.” <i>The Journal of Physical Chemistry C</i>, 2007, pp. 16392–96, doi:<a href=\"https://doi.org/10.1021/jp074928q\">10.1021/jp074928q</a>.","bibtex":"@article{de los Arcos de Pedro_Oelhafen_Thommen_Mathys_2007, title={The Influence of Catalyst’s Oxidation Degree on Carbon Nanotube Growth as a Substrate-Independent Parameter}, DOI={<a href=\"https://doi.org/10.1021/jp074928q\">10.1021/jp074928q</a>}, journal={The Journal of Physical Chemistry C}, author={de los Arcos de Pedro, Maria Teresa and Oelhafen, Peter and Thommen, Verena and Mathys, Daniel}, year={2007}, pages={16392–16396} }","ama":"de los Arcos de Pedro MT, Oelhafen P, Thommen V, Mathys D. The Influence of Catalyst’s Oxidation Degree on Carbon Nanotube Growth as a Substrate-Independent Parameter. <i>The Journal of Physical Chemistry C</i>. Published online 2007:16392-16396. doi:<a href=\"https://doi.org/10.1021/jp074928q\">10.1021/jp074928q</a>","ieee":"M. T. de los Arcos de Pedro, P. Oelhafen, V. Thommen, and D. Mathys, “The Influence of Catalyst’s Oxidation Degree on Carbon Nanotube Growth as a Substrate-Independent Parameter,” <i>The Journal of Physical Chemistry C</i>, pp. 16392–16396, 2007, doi: <a href=\"https://doi.org/10.1021/jp074928q\">10.1021/jp074928q</a>.","apa":"de los Arcos de Pedro, M. T., Oelhafen, P., Thommen, V., &#38; Mathys, D. (2007). The Influence of Catalyst’s Oxidation Degree on Carbon Nanotube Growth as a Substrate-Independent Parameter. <i>The Journal of Physical Chemistry C</i>, 16392–16396. <a href=\"https://doi.org/10.1021/jp074928q\">https://doi.org/10.1021/jp074928q</a>","short":"M.T. de los Arcos de Pedro, P. Oelhafen, V. Thommen, D. Mathys, The Journal of Physical Chemistry C (2007) 16392–16396.","chicago":"Arcos de Pedro, Maria Teresa de los, Peter Oelhafen, Verena Thommen, and Daniel Mathys. “The Influence of Catalyst’s Oxidation Degree on Carbon Nanotube Growth as a Substrate-Independent Parameter.” <i>The Journal of Physical Chemistry C</i>, 2007, 16392–96. <a href=\"https://doi.org/10.1021/jp074928q\">https://doi.org/10.1021/jp074928q</a>."},"publication":"The Journal of Physical Chemistry C","user_id":"54556","doi":"10.1021/jp074928q","language":[{"iso":"eng"}],"_id":"22613","page":"16392-16396","publication_status":"published","date_updated":"2023-01-24T08:28:48Z","publication_identifier":{"issn":["1932-7447","1932-7455"]},"author":[{"full_name":"de los Arcos de Pedro, Maria Teresa","last_name":"de los Arcos de Pedro","first_name":"Maria Teresa","id":"54556"},{"first_name":"Peter","last_name":"Oelhafen","full_name":"Oelhafen, Peter"},{"first_name":"Verena","last_name":"Thommen","full_name":"Thommen, Verena"},{"last_name":"Mathys","first_name":"Daniel","full_name":"Mathys, Daniel"}],"status":"public","title":"The Influence of Catalyst's Oxidation Degree on Carbon Nanotube Growth as a Substrate-Independent Parameter","year":"2007"},{"status":"public","title":"Optical characterization of alignment and effective refractive index in carbon nanotube films","year":"2007","publication_identifier":{"issn":["0957-4484","1361-6528"]},"author":[{"full_name":"de los Arcos de Pedro, Maria Teresa","last_name":"de los Arcos de Pedro","first_name":"Maria Teresa","id":"54556"},{"full_name":"Oelhafen, P","last_name":"Oelhafen","first_name":"P"},{"full_name":"Mathys, D","first_name":"D","last_name":"Mathys"}],"publication_status":"published","date_updated":"2023-01-24T08:28:33Z","article_number":"265706","_id":"22612","language":[{"iso":"eng"}],"user_id":"54556","doi":"10.1088/0957-4484/18/26/265706","publication":"Nanotechnology","citation":{"chicago":"Arcos de Pedro, Maria Teresa de los, P Oelhafen, and D Mathys. “Optical Characterization of Alignment and Effective Refractive Index in Carbon Nanotube Films.” <i>Nanotechnology</i>, 2007. <a href=\"https://doi.org/10.1088/0957-4484/18/26/265706\">https://doi.org/10.1088/0957-4484/18/26/265706</a>.","short":"M.T. de los Arcos de Pedro, P. Oelhafen, D. Mathys, Nanotechnology (2007).","ieee":"M. T. de los Arcos de Pedro, P. Oelhafen, and D. Mathys, “Optical characterization of alignment and effective refractive index in carbon nanotube films,” <i>Nanotechnology</i>, Art. no. 265706, 2007, doi: <a href=\"https://doi.org/10.1088/0957-4484/18/26/265706\">10.1088/0957-4484/18/26/265706</a>.","apa":"de los Arcos de Pedro, M. T., Oelhafen, P., &#38; Mathys, D. (2007). Optical characterization of alignment and effective refractive index in carbon nanotube films. <i>Nanotechnology</i>, Article 265706. <a href=\"https://doi.org/10.1088/0957-4484/18/26/265706\">https://doi.org/10.1088/0957-4484/18/26/265706</a>","bibtex":"@article{de los Arcos de Pedro_Oelhafen_Mathys_2007, title={Optical characterization of alignment and effective refractive index in carbon nanotube films}, DOI={<a href=\"https://doi.org/10.1088/0957-4484/18/26/265706\">10.1088/0957-4484/18/26/265706</a>}, number={265706}, journal={Nanotechnology}, author={de los Arcos de Pedro, Maria Teresa and Oelhafen, P and Mathys, D}, year={2007} }","ama":"de los Arcos de Pedro MT, Oelhafen P, Mathys D. Optical characterization of alignment and effective refractive index in carbon nanotube films. <i>Nanotechnology</i>. Published online 2007. doi:<a href=\"https://doi.org/10.1088/0957-4484/18/26/265706\">10.1088/0957-4484/18/26/265706</a>","mla":"de los Arcos de Pedro, Maria Teresa, et al. “Optical Characterization of Alignment and Effective Refractive Index in Carbon Nanotube Films.” <i>Nanotechnology</i>, 265706, 2007, doi:<a href=\"https://doi.org/10.1088/0957-4484/18/26/265706\">10.1088/0957-4484/18/26/265706</a>."},"extern":"1","date_created":"2021-07-07T11:39:27Z","type":"journal_article","department":[{"_id":"302"}]},{"citation":{"ama":"Neuba A, Seewald O, Flörke U, Henkel G. Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)}. <i>Acta Crystallographica Section E Structure Reports Online</i>. 2007;63(8):m2099-m2100. doi:<a href=\"https://doi.org/10.1107/s1600536807032801\">10.1107/s1600536807032801</a>","bibtex":"@article{Neuba_Seewald_Flörke_Henkel_2007, title={Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)}}, volume={63}, DOI={<a href=\"https://doi.org/10.1107/s1600536807032801\">10.1107/s1600536807032801</a>}, number={8}, journal={Acta Crystallographica Section E Structure Reports Online}, publisher={International Union of Crystallography (IUCr)}, author={Neuba, Adam and Seewald, Oliver and Flörke, Ulrich and Henkel, Gerald}, year={2007}, pages={m2099–m2100} }","mla":"Neuba, Adam, et al. “Di-μ-Oxido-Bis{[1,3-Bis(Tetramethylguanidino)Propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]Bromidomanganese(III)}.” <i>Acta Crystallographica Section E Structure Reports Online</i>, vol. 63, no. 8, International Union of Crystallography (IUCr), 2007, pp. m2099–100, doi:<a href=\"https://doi.org/10.1107/s1600536807032801\">10.1107/s1600536807032801</a>.","short":"A. Neuba, O. Seewald, U. Flörke, G. Henkel, Acta Crystallographica Section E Structure Reports Online 63 (2007) m2099–m2100.","chicago":"Neuba, Adam, Oliver Seewald, Ulrich Flörke, and Gerald Henkel. “Di-μ-Oxido-Bis{[1,3-Bis(Tetramethylguanidino)Propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]Bromidomanganese(III)}.” <i>Acta Crystallographica Section E Structure Reports Online</i> 63, no. 8 (2007): m2099–2100. <a href=\"https://doi.org/10.1107/s1600536807032801\">https://doi.org/10.1107/s1600536807032801</a>.","apa":"Neuba, A., Seewald, O., Flörke, U., &#38; Henkel, G. (2007). Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)}. <i>Acta Crystallographica Section E Structure Reports Online</i>, <i>63</i>(8), m2099–m2100. <a href=\"https://doi.org/10.1107/s1600536807032801\">https://doi.org/10.1107/s1600536807032801</a>","ieee":"A. Neuba, O. Seewald, U. Flörke, and G. Henkel, “Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)},” <i>Acta Crystallographica Section E Structure Reports Online</i>, vol. 63, no. 8, pp. m2099–m2100, 2007, doi: <a href=\"https://doi.org/10.1107/s1600536807032801\">10.1107/s1600536807032801</a>."},"status":"public","volume":63,"user_id":"495","_id":"58591","publisher":"International Union of Crystallography (IUCr)","page":"m2099-m2100","issue":"8","publication":"Acta Crystallographica Section E Structure Reports Online","department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"type":"journal_article","date_created":"2025-02-12T09:19:48Z","intvolume":"        63","date_updated":"2025-02-12T09:20:07Z","publication_status":"published","author":[{"full_name":"Neuba, Adam","first_name":"Adam","last_name":"Neuba"},{"full_name":"Seewald, Oliver","last_name":"Seewald","first_name":"Oliver","id":"495"},{"full_name":"Flörke, Ulrich","first_name":"Ulrich","last_name":"Flörke"},{"full_name":"Henkel, Gerald","last_name":"Henkel","first_name":"Gerald"}],"publication_identifier":{"issn":["1600-5368"]},"year":"2007","title":"Di-μ-oxido-bis{[1,3-bis(tetramethylguanidino)propane-κ<sup>2</sup><i>N</i>,<i>N</i>′]bromidomanganese(III)}","doi":"10.1107/s1600536807032801","language":[{"iso":"eng"}]},{"citation":{"chicago":"Herres‐Pawlis, Sonja, Adam Neuba, Oliver Seewald, Tarimala Seshadri, Hans Egold, Ulrich Flörke, and Gerald Henkel. “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry.” <i>European Journal of Organic Chemistry</i> 2005, no. 22 (2005): 4879–90. <a href=\"https://doi.org/10.1002/ejoc.200500340\">https://doi.org/10.1002/ejoc.200500340</a>.","short":"S. Herres‐Pawlis, A. Neuba, O. Seewald, T. Seshadri, H. Egold, U. Flörke, G. Henkel, European Journal of Organic Chemistry 2005 (2005) 4879–4890.","apa":"Herres‐Pawlis, S., Neuba, A., Seewald, O., Seshadri, T., Egold, H., Flörke, U., &#38; Henkel, G. (2005). A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry. <i>European Journal of Organic Chemistry</i>, <i>2005</i>(22), 4879–4890. <a href=\"https://doi.org/10.1002/ejoc.200500340\">https://doi.org/10.1002/ejoc.200500340</a>","ieee":"S. Herres‐Pawlis <i>et al.</i>, “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry,” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 22, pp. 4879–4890, 2005, doi: <a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>.","ama":"Herres‐Pawlis S, Neuba A, Seewald O, et al. A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry. <i>European Journal of Organic Chemistry</i>. 2005;2005(22):4879-4890. doi:<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>","bibtex":"@article{Herres‐Pawlis_Neuba_Seewald_Seshadri_Egold_Flörke_Henkel_2005, title={A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry}, volume={2005}, DOI={<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>}, number={22}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Herres‐Pawlis, Sonja and Neuba, Adam and Seewald, Oliver and Seshadri, Tarimala and Egold, Hans and Flörke, Ulrich and Henkel, Gerald}, year={2005}, pages={4879–4890} }","mla":"Herres‐Pawlis, Sonja, et al. “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry.” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 22, Wiley, 2005, pp. 4879–90, doi:<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>."},"status":"public","_id":"58598","publisher":"Wiley","page":"4879-4890","volume":2005,"user_id":"495","issue":"22","publication":"European Journal of Organic Chemistry","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>A series of bis‐guanidine ligands designed for use in biomimetic coordination chemistry has been extended to a library matrix combining unprecedented substitutional flexibility within the guanidyl residues with a wide range of aliphatic and aromatic spacers connecting these functionalities. The underlying protocol can be used with predefined ureas as well as secondary amines to build up these units by reaction with phosgene if the ureas are otherwise unavailable. In the latter case, the resulting urea intermediates do not have to be isolated as the reaction proceeds further with additional phosgene to yield a chloroformamidinium chloride which is transformed into the bis‐guanidine functionality by subsequent reaction with a suitable primary diamine in the presence of triethylamine as an auxiliary base. This concept has been used to synthesise and characterise more then two dozen different bis‐guanidines based on 12 discrete monoguanidine units and seven different spacers. These spacers have been chosen such that the most important phenotypes have been dealt with and which range from rigid to more flexible scaffolds. In addition to spacers with no metal‐binding capabilities, other species containing further donor functions such as <jats:italic>N</jats:italic>‐methyldiphenyleneamine or pyridine‐2,6‐diyl have also been used. The substitution patterns of the guanidine residues can be classified into acyclic and cyclic types. Among the cyclic types, one subset is characterised by five‐ or six‐membered heterocycles containing both the amino nitrogen atoms and another one by individual N‐heterocyclic systems for each amino nitrogen. Structurally characterised examples are 2‐{2‐[2‐(tetramethylguanidi­no)ethoxy]ethoxy}‐1‐(tetramethylguanidino)ethane (TMG<jats:sub>2</jats:sub>doo) in its diprotonated form and 2,2′‐bis[2<jats:italic>N</jats:italic>‐(1,1′,3,3′‐tetramethylguanidine)]diphenyleneamine (TMG<jats:sub>2</jats:sub>PA) as wellas <jats:italic>N</jats:italic><jats:sup>1</jats:sup>,<jats:italic>N</jats:italic><jats:sup>3</jats:sup>‐bis(dimorpholinomethylene)propane‐1,3‐diamine (DMorphG<jats:sub>2</jats:sub>p) as free bases. For the permethylated bis‐guanidine derivatives, the barrier to rotation around the (C=N)<jats:sub>guanidine</jats:sub> bond has been determined by means of temperature‐dependent EXSY <jats:sup>1</jats:sup>H NMR spectroscopy to range between 54 and 79 kJ mol<jats:sup>–1</jats:sup> depending on the type of spacer. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2005)</jats:p>"}],"date_created":"2025-02-12T09:27:00Z","department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"type":"journal_article","author":[{"full_name":"Herres‐Pawlis, Sonja","last_name":"Herres‐Pawlis","first_name":"Sonja"},{"first_name":"Adam","last_name":"Neuba","full_name":"Neuba, Adam"},{"id":"495","first_name":"Oliver","last_name":"Seewald","full_name":"Seewald, Oliver"},{"full_name":"Seshadri, Tarimala","last_name":"Seshadri","first_name":"Tarimala"},{"full_name":"Egold, Hans","first_name":"Hans","last_name":"Egold"},{"first_name":"Ulrich","last_name":"Flörke","full_name":"Flörke, Ulrich"},{"full_name":"Henkel, Gerald","first_name":"Gerald","last_name":"Henkel"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"title":"A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry","year":"2005","intvolume":"      2005","publication_status":"published","date_updated":"2025-02-12T09:30:43Z","language":[{"iso":"eng"}],"doi":"10.1002/ejoc.200500340"},{"department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"type":"journal_article","date_created":"2025-02-12T09:26:12Z","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p><jats:bold>Syntheses and Structure of Chiral Metallatetrahedron Complexes of the Type [Re<jats:sub>2</jats:sub>(M<jats:sup>1</jats:sup>PPh<jats:sub>3</jats:sub>)(M<jats:sup>2</jats:sup>PPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (M<jats:sup>1</jats:sup> = Ag, Au; M<jats:sup>2</jats:sup> = Cu, Ag, Au)</jats:bold></jats:p><jats:p>From the reaction of Li[Re<jats:sub>2</jats:sub>(μ‐H)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>(C(Ph)O)] (<jats:bold>1</jats:bold>) with Ph<jats:sub>3</jats:sub>AuC≡CPh both benzaldehyde and the trinuclear complex Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>2a</jats:bold>) were obtained in high yield. The complex anion was isolated as its PPh<jats:sub>4</jats:sub>‐salt <jats:bold>2b</jats:bold>. The latter reacts with coinage metal complexes PPh<jats:sub>3</jats:sub>M<jats:sup>2</jats:sup>Cl [M<jats:sup>2</jats:sup> = Cu, Ag, Au] to give chiral heterometallatetrahedranes of the general formula [Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(M<jats:sup>2</jats:sup>PPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (M<jats:sup>2</jats:sup> = Cu <jats:bold>3a</jats:bold>, Ag <jats:bold>3b</jats:bold>, Au <jats:bold>3c</jats:bold>). The corresponding complex [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>3d</jats:bold>) is obtained from the reaction of [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>4</jats:bold>) with LiC≡CPh. <jats:bold>3d</jats:bold> undergoes a metathesis reaction in the presence of PPh<jats:sub>3</jats:sub>CuCl giving [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)(CuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>3e</jats:bold>) and PPh<jats:sub>3</jats:sub>AgCl. Analogous metathesis reactions are observed when <jats:bold>3c</jats:bold> is reacted with PPh<jats:sub>3</jats:sub>AgCl or PPh<jats:sub>3</jats:sub>CuCl giving <jats:bold>3a</jats:bold> or <jats:bold>3b</jats:bold>, respectively. The reaction of <jats:bold>1</jats:bold> with PPh<jats:sub>3</jats:sub>AuCl gives benzaldehyde and Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>5a</jats:bold>) which upon reaction with PhLi forms the trinuclear complex Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Ph] (<jats:bold>6a</jats:bold>). Again this complex was isolated as its PPh<jats:sub>4</jats:sub>‐salt <jats:bold>6b</jats:bold>. In contrast to <jats:bold>2b</jats:bold>, <jats:bold>6b</jats:bold> reacts with one equivalent of Ph<jats:sub>3</jats:sub>PAuCl by transmetalation to give Ph<jats:sub>3</jats:sub>PAuPh and PPh<jats:sub>4</jats:sub>[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>5b</jats:bold>). The X‐ray structures of the compounds <jats:bold>3a</jats:bold>, <jats:bold>3b</jats:bold>, <jats:bold>3e</jats:bold> and <jats:bold>4</jats:bold> are reported.</jats:p>","lang":"eng"}],"publication":"Zeitschrift für anorganische und allgemeine Chemie","issue":"2","doi":"10.1002/zaac.200500340","language":[{"iso":"eng"}],"intvolume":"       632","date_updated":"2025-02-12T09:30:52Z","publication_status":"published","publication_identifier":{"issn":["0044-2313","1521-3749"]},"author":[{"id":"495","full_name":"Seewald, Oliver","last_name":"Seewald","first_name":"Oliver"},{"last_name":"Flörke","first_name":"Ulrich","full_name":"Flörke, Ulrich"},{"full_name":"Egold, Hans","last_name":"Egold","first_name":"Hans"},{"full_name":"Haupt, Hans‐Jürgen","first_name":"Hans‐Jürgen","last_name":"Haupt"},{"last_name":"Schwefer","first_name":"Meinhard","full_name":"Schwefer, Meinhard"}],"title":"Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au)","year":"2005","citation":{"apa":"Seewald, O., Flörke, U., Egold, H., Haupt, H., &#38; Schwefer, M. (2005). Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au). <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i>, <i>632</i>(2), 204–210. <a href=\"https://doi.org/10.1002/zaac.200500340\">https://doi.org/10.1002/zaac.200500340</a>","ieee":"O. Seewald, U. Flörke, H. Egold, H. Haupt, and M. Schwefer, “Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au),” <i>Zeitschrift für anorganische und allgemeine Chemie</i>, vol. 632, no. 2, pp. 204–210, 2005, doi: <a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>.","short":"O. Seewald, U. Flörke, H. Egold, H. Haupt, M. Schwefer, Zeitschrift Für Anorganische Und Allgemeine Chemie 632 (2005) 204–210.","chicago":"Seewald, Oliver, Ulrich Flörke, Hans Egold, Hans‐Jürgen Haupt, and Meinhard Schwefer. “Synthese Und Struktur Chiraler Heterometallatetrahedrane Des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(Μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au).” <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i> 632, no. 2 (2005): 204–10. <a href=\"https://doi.org/10.1002/zaac.200500340\">https://doi.org/10.1002/zaac.200500340</a>.","mla":"Seewald, Oliver, et al. “Synthese Und Struktur Chiraler Heterometallatetrahedrane Des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(Μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au).” <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i>, vol. 632, no. 2, Wiley, 2005, pp. 204–10, doi:<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>.","ama":"Seewald O, Flörke U, Egold H, Haupt H, Schwefer M. Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au). <i>Zeitschrift für anorganische und allgemeine Chemie</i>. 2005;632(2):204-210. doi:<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>","bibtex":"@article{Seewald_Flörke_Egold_Haupt_Schwefer_2005, title={Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au)}, volume={632}, DOI={<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>}, number={2}, journal={Zeitschrift für anorganische und allgemeine Chemie}, publisher={Wiley}, author={Seewald, Oliver and Flörke, Ulrich and Egold, Hans and Haupt, Hans‐Jürgen and Schwefer, Meinhard}, year={2005}, pages={204–210} }"},"volume":632,"user_id":"495","_id":"58597","publisher":"Wiley","page":"204-210","status":"public"},{"date_created":"2021-07-07T11:40:38Z","type":"journal_article","department":[{"_id":"302"}],"publication":"Advanced Materials","citation":{"ama":"Hinderling C, Keles Y, Stöckli T, et al. Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth. <i>Advanced Materials</i>. Published online 2004:876-879. doi:<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>","bibtex":"@article{Hinderling_Keles_Stöckli_Knapp_de los Arcos de Pedro_Oelhafen_Korczagin_Hempenius_Vancso_Pugin_et al._2004, title={Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth}, DOI={<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>}, journal={Advanced Materials}, author={Hinderling, C. and Keles, Y. and Stöckli, T. and Knapp, H. F. and de los Arcos de Pedro, Maria Teresa and Oelhafen, P. and Korczagin, I. and Hempenius, M. A. and Vancso, G. J. and Pugin, R. and et al.}, year={2004}, pages={876–879} }","mla":"Hinderling, C., et al. “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth.” <i>Advanced Materials</i>, 2004, pp. 876–79, doi:<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>.","chicago":"Hinderling, C., Y. Keles, T. Stöckli, H. F. Knapp, Maria Teresa de los Arcos de Pedro, P. Oelhafen, I. Korczagin, et al. “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth.” <i>Advanced Materials</i>, 2004, 876–79. <a href=\"https://doi.org/10.1002/adma.200306447\">https://doi.org/10.1002/adma.200306447</a>.","short":"C. Hinderling, Y. Keles, T. Stöckli, H.F. Knapp, M.T. de los Arcos de Pedro, P. Oelhafen, I. Korczagin, M.A. Hempenius, G.J. Vancso, R. Pugin, H. Heinzelmann, Advanced Materials (2004) 876–879.","apa":"Hinderling, C., Keles, Y., Stöckli, T., Knapp, H. F., de los Arcos de Pedro, M. T., Oelhafen, P., Korczagin, I., Hempenius, M. A., Vancso, G. J., Pugin, R., &#38; Heinzelmann, H. (2004). Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth. <i>Advanced Materials</i>, 876–879. <a href=\"https://doi.org/10.1002/adma.200306447\">https://doi.org/10.1002/adma.200306447</a>","ieee":"C. Hinderling <i>et al.</i>, “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth,” <i>Advanced Materials</i>, pp. 876–879, 2004, doi: <a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>."},"extern":"1","page":"876-879","_id":"22616","language":[{"iso":"eng"}],"doi":"10.1002/adma.200306447","user_id":"54556","status":"public","year":"2004","title":"Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth","author":[{"full_name":"Hinderling, C.","last_name":"Hinderling","first_name":"C."},{"full_name":"Keles, Y.","first_name":"Y.","last_name":"Keles"},{"full_name":"Stöckli, T.","first_name":"T.","last_name":"Stöckli"},{"full_name":"Knapp, H. F.","last_name":"Knapp","first_name":"H. F."},{"id":"54556","first_name":"Maria Teresa","last_name":"de los Arcos de Pedro","full_name":"de los Arcos de Pedro, Maria Teresa"},{"full_name":"Oelhafen, P.","first_name":"P.","last_name":"Oelhafen"},{"first_name":"I.","last_name":"Korczagin","full_name":"Korczagin, I."},{"full_name":"Hempenius, M. A.","last_name":"Hempenius","first_name":"M. A."},{"full_name":"Vancso, G. J.","last_name":"Vancso","first_name":"G. J."},{"full_name":"Pugin, R.","last_name":"Pugin","first_name":"R."},{"full_name":"Heinzelmann, H.","first_name":"H.","last_name":"Heinzelmann"}],"publication_identifier":{"issn":["0935-9648","1521-4095"]},"date_updated":"2023-01-24T08:29:17Z","publication_status":"published"},{"user_id":"54556","doi":"10.1021/jp049495v","language":[{"iso":"eng"}],"_id":"22615","page":"7728-7734","publication_status":"published","date_updated":"2023-01-24T08:29:03Z","author":[{"first_name":"Maria Teresa","last_name":"de los Arcos de Pedro","full_name":"de los Arcos de Pedro, Maria Teresa","id":"54556"},{"first_name":"Michael Gunnar","last_name":"Garnier","full_name":"Garnier, Michael Gunnar"},{"full_name":"Seo, Jin Won","first_name":"Jin Won","last_name":"Seo"},{"full_name":"Oelhafen, Peter","last_name":"Oelhafen","first_name":"Peter"},{"last_name":"Thommen","first_name":"Verena","full_name":"Thommen, Verena"},{"first_name":"Daniel","last_name":"Mathys","full_name":"Mathys, Daniel"}],"publication_identifier":{"issn":["1520-6106","1520-5207"]},"year":"2004","status":"public","title":"The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth","department":[{"_id":"302"}],"type":"journal_article","date_created":"2021-07-07T11:40:10Z","extern":"1","citation":{"mla":"de los Arcos de Pedro, Maria Teresa, et al. “The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth.” <i>The Journal of Physical Chemistry B</i>, 2004, pp. 7728–34, doi:<a href=\"https://doi.org/10.1021/jp049495v\">10.1021/jp049495v</a>.","bibtex":"@article{de los Arcos de Pedro_Garnier_Seo_Oelhafen_Thommen_Mathys_2004, title={The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth}, DOI={<a href=\"https://doi.org/10.1021/jp049495v\">10.1021/jp049495v</a>}, journal={The Journal of Physical Chemistry B}, author={de los Arcos de Pedro, Maria Teresa and Garnier, Michael Gunnar and Seo, Jin Won and Oelhafen, Peter and Thommen, Verena and Mathys, Daniel}, year={2004}, pages={7728–7734} }","ama":"de los Arcos de Pedro MT, Garnier MG, Seo JW, Oelhafen P, Thommen V, Mathys D. The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth. <i>The Journal of Physical Chemistry B</i>. Published online 2004:7728-7734. doi:<a href=\"https://doi.org/10.1021/jp049495v\">10.1021/jp049495v</a>","ieee":"M. T. de los Arcos de Pedro, M. G. Garnier, J. W. Seo, P. Oelhafen, V. Thommen, and D. Mathys, “The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth,” <i>The Journal of Physical Chemistry B</i>, pp. 7728–7734, 2004, doi: <a href=\"https://doi.org/10.1021/jp049495v\">10.1021/jp049495v</a>.","apa":"de los Arcos de Pedro, M. T., Garnier, M. G., Seo, J. W., Oelhafen, P., Thommen, V., &#38; Mathys, D. (2004). The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth. <i>The Journal of Physical Chemistry B</i>, 7728–7734. <a href=\"https://doi.org/10.1021/jp049495v\">https://doi.org/10.1021/jp049495v</a>","short":"M.T. de los Arcos de Pedro, M.G. Garnier, J.W. Seo, P. Oelhafen, V. Thommen, D. Mathys, The Journal of Physical Chemistry B (2004) 7728–7734.","chicago":"Arcos de Pedro, Maria Teresa de los, Michael Gunnar Garnier, Jin Won Seo, Peter Oelhafen, Verena Thommen, and Daniel Mathys. “The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth.” <i>The Journal of Physical Chemistry B</i>, 2004, 7728–34. <a href=\"https://doi.org/10.1021/jp049495v\">https://doi.org/10.1021/jp049495v</a>."},"publication":"The Journal of Physical Chemistry B"}]