@article{60568, author = {{Bocchini, Adriana and Kollmann, S. and Gerstmann, Uwe and Schmidt, Wolf Gero and Grundmeier, Guido}}, issn = {{0039-6028}}, journal = {{Surface Science}}, publisher = {{Elsevier BV}}, title = {{{Phosphonic acid adsorption on α-Bi2O3 surfaces}}}, doi = {{10.1016/j.susc.2025.122776}}, volume = {{760}}, year = {{2025}}, } @article{61353, abstract = {{Abstract Muonic hydrogen is an exotic atom where a muon instead of an electron is bound to a proton. The comparably high mass of the muon (≈ 207 · me ) has two important effects, (i) the reduced mass of the system becomes more important, and (ii) the muon is localized much closer to the nucleus. Thus, muonic hydrogen is not only excellently suitable for evaluating highly precise quantum electrodynamic (QED) calculations, but may also be used for assessing new approaches including finite nuclear size (FNS) effects to evaluate the proton structure and improve calculation schemes for the hyperfine splittings of many-particle systems, as e.g. to be implemented in density functional theory (DFT) software packages. Here, starting from Dirac’s equation we calculate the relativistic hyperfine splitting of the ground state and several excited states of muonic hydrogen analytically for different charge and magnetization models. The FNS related hyperfine shifts are compared with the differences between QED calculations and experimental measurements. This comparison also allows to unravel the role of the reduced mass, which is on one hand crucial in case of muonic atoms, but on the other hand is by no means well defined in relativistic quantum mechanics.}}, author = {{Franzke, Katharina L. and Schmidt, Wolf Gero and Gerstmann, Uwe}}, issn = {{1742-6588}}, journal = {{Journal of Physics: Conference Series}}, number = {{1}}, publisher = {{IOP Publishing}}, title = {{{Finite-size and relativistic effects onto hyperfine interaction of muonic hydrogen}}}, doi = {{10.1088/1742-6596/3027/1/012001}}, volume = {{3027}}, year = {{2025}}, } @inproceedings{61352, author = {{Devaraj, Vasanthan and Ruiz Alvarado, Isaac Azahel and Lee, Jongmin and Oh, Jin-Woo and Gerstmann, Uwe and Schmidt, Wolf Gero and Zentgraf, Thomas}}, booktitle = {{2025 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC)}}, publisher = {{IEEE}}, title = {{{Dynamic and Reversible Plasmonic Nanogaps From Isolated Dimer Nanoparticles via Self-Assembly}}}, doi = {{10.1109/cleo/europe-eqec65582.2025.11109762}}, year = {{2025}}, } @article{62866, abstract = {{Abstract The development of efficient and broadly applicable n‐doping strategies for organic semiconductors (OSCs) is crucial for advancing the performance of various organic electronic devices. Here, a novel nucleophilic‐attack n‐doping mechanism is unveiled that achieves exceptionally high conductivity in doped OSC films and demonstrates broad applicability across OSCs. The remarkable efficacy of n‐Butyl lithium (n‐BuLi) is highlighted in n‐doping C 60 and PC 61 BM, achieving a conductivity of 1.27 S cm −1 and 2.57 S cm −1 , respectively, which are among the highest reported values for these materials. The investigation reveals that the n‐BuLi anion interacts with electron‐deficient units in OSCs, generating a carbanion that facilitates efficient electron transfer for n‐doping. This mechanism is further validated across diverse fullerenes, polymeric, and small molecule OSCs, and is extendable to other high‐performance dopants such as tert‐Butyllithium (tert‐BuLi) and sodium ethoxide (NaOEt). Device studies show that n‐BuLi‐doped C 60 enables substantially improved diode rectification, attributed to greater junction built‐in potential. These findings establish a unified chemical‐bonding‐based n‐doping paradigm, complementing existing electrophilic‐attack p‐doping concepts, and pave the way for achieving efficient doping of OSCs for advanced organic electronic applications. }}, author = {{Wei, Huan and Wu, Tong and Dong, Chuanding and Chen, Chen and Gong, Zhenqi and Xia, Jiangnan and Peng, Chengyuan and Ding, Jiaqi and Zhang, Yu and Shi, Wenpei and Schumacher, Stefan and Zhang, Xue and Bai, Yugang and Jiang, Lang and Liao, Lei and Nguyen, Thuc‐Quyen and Hu, Yuanyuan}}, issn = {{2198-3844}}, journal = {{Advanced Science}}, publisher = {{Wiley}}, title = {{{Efficient n‐Doping of Organic Semiconductors via a Broadly Applicable Nucleophilic‐Attack Mechanism}}}, doi = {{10.1002/advs.202520487}}, year = {{2025}}, } @article{60992, abstract = {{Non-Hermitian systems hosting exceptional points (EPs) exhibit enhanced sensitivity and unconventional mode dynamics. Going beyond isolated EPs, here we report on the existence of exceptional rings (ERs) in planar optical resonators with specific form of circular dichroism and TE-TM splitting. Such exceptional rings possess intriguing topologies as discussed earlier for condensed matter systems, but they remain virtually unexplored in presence of nonlinearity, for which our photonic platform is ideal. We find that when Kerr-type nonlinearity (or saturable gain) is introduced, the linear ER splits into two concentric ERs, with the larger-radius ring being a ring of third-order EPs. Transitioning from linear to nonlinear regime, we present a rigorous analysis of spectral topology and report enhanced and adjustable perturbation response in the nonlinear regime. Whereas certain features are specific to our system, the results on non-Hermitian spectral topology and nonlinearity-enhanced perturbation response are generic and equally relevant to a broad class of other nonlinear non-Hermitian systems, providing a universal framework for engineering ERs and EPs in nonlinear non-Hermitian systems.}}, author = {{Wingenbach, Jan and Ares Santos, Laura and Ma, Xuekai and Sperling, Jan and Schumacher, Stefan}}, journal = {{Arxiv}}, publisher = {{Arxiv}}, title = {{{Sensitivity and Topology of Exceptional Rings in Nonlinear Non-Hermitian Planar Optical Microcavities}}}, doi = {{10.48550/ARXIV.2507.07099}}, year = {{2025}}, } @article{62926, abstract = {{Abstract Negatively charged boron vacancies () in hexagonal boron nitride (hBN) are emerging as promising solid‐state spin qubits due to their optical accessibility, structural simplicity, and compatibility with photonic platforms. However, quantifying the density of such defects in thin hBN flakes has remained elusive, limiting progress in device integration and reproducibility. Here, an all‐optical method is presented to quantify defect density in hBN by correlating Raman and photoluminescence (PL) signatures with irradiation fluence. Two defect‐induced Raman modes, D1 and D2, are identified and assigned them to vibrational modes of using polarization‐resolved Raman measurements and density functional theory (DFT) calculations. By adapting a numerical model originally developed for graphene, an empirical relationship linking Raman (D1, E 2g ) and PL intensities is established to absolute defect densities. This method is universally applicable across various irradiation types and uniquely suited for thin flakes, where conventional techniques fail. The approach enables accurate, direct, and non‐destructive quantification of spin defect densities down to 10 15  defects/cm 3 , offering a powerful tool for optimizing and benchmarking hBN for quantum optical applications. }}, author = {{Patra, Atanu and Konrad, Paul and Sperlich, Andreas and Biktagirov, Timur and Schmidt, Wolf Gero and Spencer, Lesley and Aharonovich, Igor and Höfling, Sven and Dyakonov, Vladimir}}, issn = {{1616-301X}}, journal = {{Advanced Functional Materials}}, publisher = {{Wiley}}, title = {{{Quantifying Spin Defect Density in hBN via Raman and Photoluminescence Analysis}}}, doi = {{10.1002/adfm.202517851}}, year = {{2025}}, } @article{62980, abstract = {{We introduce a new classification of multimode states with a fixed number of photons. This classification is based on the factorizability of homogeneous multivariate polynomials and is invariant under unitary transformations. The classes physically correspond to field excitations in terms of single and multiple photons, each of which is in an arbitrary irreducible superposition of quantized modes. We further show how the transitions between classes are rendered possible by photon addition, photon subtraction, and photon-projection nonlinearities. We explicitly put forward a design for a multilayer interferometer in which the states for different classes can be generated with state-of-the-art experimental techniques. Limitations of the proposed designs are analyzed using the introduced classification, providing a benchmark for the robustness of certain states and classes.}}, author = {{Kopylov, Denis A. and Offen, Christian and Ares, Laura and Wembe Moafo, Boris Edgar and Ober-Blöbaum, Sina and Meier, Torsten and Sharapova, Polina R. and Sperling, Jan}}, issn = {{2643-1564}}, journal = {{Physical Review Research}}, number = {{3}}, publisher = {{American Physical Society (APS)}}, title = {{{Multiphoton, multimode state classification for nonlinear optical circuits}}}, doi = {{10.1103/sv6z-v1gk}}, volume = {{7}}, year = {{2025}}, } @unpublished{62979, abstract = {{We introduce a new classification of multimode states with a fixed number of photons. This classification is based on the factorizability of homogeneous multivariate polynomials and is invariant under unitary transformations. The classes physically correspond to field excitations in terms of single and multiple photons, each of which being in an arbitrary irreducible superposition of quantized modes. We further show how the transitions between classes are rendered possible by photon addition, photon subtraction, and photon-projection nonlinearities. We explicitly put forward a design for a multilayer interferometer in which the states for different classes can be generated with state-of-the-art experimental techniques. Limitations of the proposed designs are analyzed using the introduced classification, providing a benchmark for the robustness of certain states and classes.}}, author = {{Meier, Torsten and Sharapova, Polina R. and Sperling, Jan and Ober-Blöbaum, Sina and Wembe Moafo, Boris Edgar and Offen, Christian}}, title = {{{Multiphoton, multimode state classification for nonlinear optical circuits}}}, year = {{2025}}, } @article{63021, abstract = {{Bell measurements, entailing the projection onto one of the Bell states, play a key role in quantum information and communication, where the outcome of a variety of protocols crucially depends on the success probability of such measurements. Although in the case of qubit systems, Bell measurements can be implemented using only linear optical components, the same result is no longer true for qudits, where at least the use of ancillary photons is required. In order to circumvent this limitation, one possibility is to introduce nonlinear effects. In this work, we adopt the latter approach and propose a scalable Bell measurement scheme for high-dimensional states, exploiting multiple squeezer devices applied to a linear optical circuit for discriminating the different Bell states. Our approach does not require ancillary photons, is not limited by the dimension of the quantum states, and is experimentally scalable, thus paving the way toward the realization of an effective high-dimensional Bell measurement.}}, author = {{Bianchi, Luca and Marconi, Carlo and Sperling, Jan and Bacco, Davide}}, issn = {{2643-1564}}, journal = {{Physical Review Research}}, number = {{2}}, publisher = {{American Physical Society (APS)}}, title = {{{Predetection squeezing as a resource for high-dimensional Bell-state measurements}}}, doi = {{10.1103/physrevresearch.7.023038}}, volume = {{7}}, year = {{2025}}, } @article{63160, author = {{Rose, Hendrik and Schumacher, Stefan and Meier, Torsten}}, issn = {{2469-9950}}, journal = {{Physical Review B}}, number = {{24}}, publisher = {{American Physical Society (APS)}}, title = {{{Microscopic approach to the quantized light-matter interaction in semiconductor nanostructures: Complex coupled dynamics of excitons, biexcitons, and photons}}}, doi = {{10.1103/528f-7smh}}, volume = {{112}}, year = {{2025}}, } @article{63534, abstract = {{Boson sampling is a key candidate for demonstrating quantum advantage and has already yielded significant advances in quantum simulation, machine learning, and graph theory. In this work, a unification and extension of distinct forms of boson sampling is developed. The devised protocol merges discrete-variable scattershot boson sampling with continuous-variable Gaussian boson sampling. Therefore, it is rendered possible to harness the complexity of more interesting states, such as squeezed photons, in advanced sampling protocols. A generating function formalism is developed for the joint description of multiphoton and multimode light undergoing Gaussian transformations. The resulting analytical tools enable one to explore interfaces of different photonic quantum-information-processing platforms. A numerical simulation of unified sampling is carried out, benchmarking its performance, complexity, and scalability. Entanglement is characterized to exemplify the generation of quantum correlations from the nonlinear interactions of a unified sampler.}}, author = {{Bianchi, Luca and Marconi, Carlo and Ares, Laura and Bacco, Davide and Sperling, Jan}}, issn = {{2643-1564}}, journal = {{Physical Review Research}}, number = {{4}}, publisher = {{American Physical Society (APS)}}, title = {{{Unified boson sampling}}}, doi = {{10.1103/8hy1-m5gg}}, volume = {{7}}, year = {{2025}}, } @article{63562, abstract = {{Entangled two-mode Gaussian states constitute an important building block for continuous variable quantum computing and communication protocols. In this work, we theoretically study two-mode bipartite states, which are extracted from multimode light generated via type-II parametric downconversion (PDC) in lossy waveguides. For these states, we demonstrate that the squeezing quantifies entanglement and we construct a measurement basis, which results in the maximal bipartite entanglement. We illustrate our findings by numerically solving the spatial master equation for PDC in a Markovian environment. The optimal measurement modes are compared with two widely used broadband bases: the Mercer–Wolf basis (the first-order coherence basis) and the Williamson–Euler basis.}}, author = {{Kopylov, Denis and Meier, Torsten and Sharapova, Polina R.}}, issn = {{2835-0103}}, journal = {{APL Quantum}}, number = {{4}}, publisher = {{AIP Publishing}}, title = {{{Bipartite entanglement extracted from multimode squeezed light generated in lossy waveguides}}}, doi = {{10.1063/5.0293116}}, volume = {{2}}, year = {{2025}}, } @article{60566, author = {{Bocchini, Adriana and Rüsing, Michael and Bollmers, Laura and Lengeling, Sebastian and Mues, Philipp and Padberg, Laura and Gerstmann, Uwe and Silberhorn, Christine and Eigner, Christof and Schmidt, Wolf Gero}}, issn = {{2475-9953}}, journal = {{Physical Review Materials}}, number = {{7}}, publisher = {{American Physical Society (APS)}}, title = {{{Mg dopants in lithium niobate: Defect models and impact on domain inversion}}}, doi = {{10.1103/5wz1-bjyr}}, volume = {{9}}, year = {{2025}}, } @article{50829, author = {{Heinisch, Nils and Köcher, Nikolas and Bauch, David and Schumacher, Stefan}}, issn = {{2643-1564}}, journal = {{Physical Review Research}}, number = {{1}}, publisher = {{American Physical Society (APS)}}, title = {{{Swing-up dynamics in quantum emitter cavity systems: Near ideal single photons and entangled photon pairs}}}, doi = {{10.1103/PhysRevResearch.6.L012017}}, volume = {{6}}, year = {{2024}}, } @article{52723, abstract = {{Miller's rule is an empirical relation between the nonlinear and linear optical coefficients that applies to a large class of materials but has only been rigorously derived for the classical Lorentz model with a weak anharmonic perturbation. In this work, we extend the proof and present a detailed derivation of Miller's rule for an equivalent quantum-mechanical anharmonic oscillator. For this purpose, the classical concept of velocity-dependent damping inherent to the Lorentz model is replaced by an adiabatic switch-on of the external electric field, which allows a unified treatment of the classical and quantum-mechanical systems using identical potentials and fields. Although the dynamics of the resulting charge oscillations, and hence the induced polarizations, deviate due to the finite zero-point motion in the quantum-mechanical framework, we find that Miller's rule is nevertheless identical in both cases up to terms of first order in the anharmonicity. With a view to practical applications, especially in the context of ab initio calculations for the optical response where adiabatically switched-on fields are widely assumed, we demonstrate that a correct treatment of finite broadening parameters is essential to avoid spurious errors that may falsely suggest a violation of Miller's rule, and we illustrate this point by means of a numerical example.}}, author = {{Meyer, Maximilian Tim and Schindlmayr, Arno}}, issn = {{1361-6455}}, journal = {{Journal of Physics B: Atomic, Molecular and Optical Physics}}, number = {{9}}, publisher = {{IOP Publishing}}, title = {{{Derivation of Miller's rule for the nonlinear optical susceptibility of a quantum anharmonic oscillator}}}, doi = {{10.1088/1361-6455/ad369c}}, volume = {{57}}, year = {{2024}}, } @article{54093, author = {{Pinske, Julien and Sperling, Jan}}, issn = {{2469-9926}}, journal = {{Physical Review A}}, number = {{5}}, publisher = {{American Physical Society (APS)}}, title = {{{Unbreakable and breakable quantum censorship}}}, doi = {{10.1103/physreva.109.052408}}, volume = {{109}}, year = {{2024}}, } @article{55140, author = {{Yasmin, Farha and Sperling, Jan}}, issn = {{2469-9926}}, journal = {{Physical Review A}}, number = {{1}}, publisher = {{American Physical Society (APS)}}, title = {{{Entanglement-assisted quantum speedup: Beating local quantum speed limits}}}, doi = {{10.1103/physreva.110.012424}}, volume = {{110}}, year = {{2024}}, } @article{55173, author = {{Di Fidio, Christian and Ares, Laura and Sperling, Jan}}, issn = {{2469-9926}}, journal = {{Physical Review A}}, number = {{1}}, publisher = {{American Physical Society (APS)}}, title = {{{Quantum walks and entanglement in cavity networks}}}, doi = {{10.1103/physreva.110.013705}}, volume = {{110}}, year = {{2024}}, } @article{55264, abstract = {{Tunneling ionization is a crucial process in the interaction between strong laser fields and matter which initiates numerous nonlinear phenomena including high-order harmonic generation, photoelectron holography, etc. Both adiabatic and nonadiabatic tunneling ionization are well understood in atomic systems. However, the tunneling dynamics in solids, especially nonadiabatic tunneling, has not yet been fully understood. Here, we study the sub-cycle resolved strong-field tunneling dynamics in solids via a complex saddle-point method. We compare the instantaneous momentum at the moment of tunneling and the tunneling distances over a range of Keldysh parameters. Our results demonstrate that for nonadiabatic tunneling, tunneling ionization away from Γ point is possible. When this happens the electron has a nonzero initial velocity when it emerges in the conduction band. Moreover, consistent with atomic tunneling, a reduced tunneling distance as compared to the quasi-static case is found. Our results provide remarkable insight into the basic physics governing the sub-cycle electron tunneling dynamics with significant implications for understanding subsequent strong-field nonlinear phenomena in solids.}}, author = {{Yang, Shidong and Liu, Xiwang and Zhang, Hongdan and Song, Xiaohong and Zuo, Ruixin and Meier, Torsten and Yang, Weifeng}}, issn = {{1094-4087}}, journal = {{Optics Express}}, number = {{9}}, publisher = {{Optica Publishing Group}}, title = {{{Sub-cycle strong-field tunneling dynamics in solids}}}, doi = {{10.1364/oe.521207}}, volume = {{32}}, year = {{2024}}, } @article{55267, author = {{Schäfer, F. and Trautmann, A. and Ngo, C. and Steiner, J. T. and Fuchs, C. and Volz, K. and Dobener, F. and Stein, M. and Meier, Torsten and Chatterjee, S.}}, issn = {{2469-9950}}, journal = {{Physical Review B}}, number = {{7}}, publisher = {{American Physical Society (APS)}}, title = {{{Optical Stark effect in type-II semiconductor heterostructures}}}, doi = {{10.1103/physrevb.109.075301}}, volume = {{109}}, year = {{2024}}, }