@article{57620, author = {{Zhang, Bingru and Martens, Kevin and Kneer, Luisa and Nguyen, Linh and Kempter, Susanne and Huber, Klaus and Kitzerow, Heinz-Siegfried}}, issn = {{1542-1406}}, journal = {{Molecular Crystals and Liquid Crystals}}, pages = {{1--9}}, publisher = {{Informa UK Limited}}, title = {{{Investigation of nano-rods fabricated by the DNA origami method using static and dynamic light scattering}}}, doi = {{10.1080/15421406.2024.2418067}}, year = {{2024}}, } @article{57625, author = {{Giesselmann, Frank and Kitzerow, Heinz-Siegfried and Zentel, Rudolf}}, issn = {{1358-314X}}, journal = {{Liquid Crystals Today}}, number = {{1}}, pages = {{2--9}}, publisher = {{Informa UK Limited}}, title = {{{Fifty years of liquid crystal research in the mirror of the German Liquid Crystal Conference}}}, doi = {{10.1080/1358314x.2024.2415787}}, volume = {{33}}, year = {{2024}}, } @article{56947, abstract = {{Pore engineering is commonly used to alter the properties of metal–organic frameworks. This is achieved by incorporating different linker molecules (L) into the structure, generating isoreticular frameworks. CPO-27, also named MOF-74, is a prototypical material for this approach, offering the potential to modify the size of its one-dimensional pore channels and the hydrophobicity of pore walls using various linker ligands during synthesis. Thermal activation of these materials yields accessible open metal sites (i.e., under-coordinated metal centers) at the pore walls, thus acting as strong primary binding sites for guest molecules, including water. We study the effect of the pore size and linker hydrophobicity within a series of Ni2+-based isoreticular frameworks (i.e., Ni2L, L = dhtp, dhip, dondc, bpp, bpm, tpp), analyzing their water sorption behavior and the water interactions in the confined pore space. For this purpose, we apply water vapor sorption analysis and Fourier transform infrared spectroscopy. In addition, defect degrees of all compounds are determined by thermogravimetric analysis and solution 1H nuclear magnetic resonance spectroscopy. We find that larger defect degrees affect the preferential sorption sites in Ni2dhtp, while no such indication is found for the other materials in our study. Instead, strong evidence is found for the formation of water bridges/chains between coordinating water molecules, as previously observed for hydrophobic porous carbons and mesoporous silica. This suggests similar sorption energies for additional water molecules in materials with larger pore sizes after saturation of the primary binding sites, resulting in more bulk-like water arrangements. Consequently, the sorption mechanism is driven by classical pore condensation through H-bonding anchor sites instead of sorption at discrete sites.}}, author = {{Kloß, Marvin and Schäfers, Lara and Zhao, Zhenyu and Weinberger, Christian and Egold, Hans and Tiemann, Michael}}, issn = {{2079-4991}}, journal = {{Nanomaterials}}, number = {{22}}, pages = {{1791}}, publisher = {{MDPI AG}}, title = {{{Water Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites to Water-Bridge-Mediated Pore Condensation}}}, doi = {{10.3390/nano14221791}}, volume = {{14}}, year = {{2024}}, } @article{56080, abstract = {{CPO‐27 is a metal‐organic framework (MOF) with coordinatively unsaturated metal centers (open metal sites). It is therefore an ideal host material for small guest molecules, including water. This opens up numerous possible applications, such as proton conduction, humidity sensing, water harvesting, or adsorption‐driven heat pumps. For all of these applications, profound knowledge of the adsorption and desorption of water in the micropores is mandatory. The hydration and water structure in CPO‐27‐M (M = Zn or Cu) is investigated using water vapor sorption, Fourier transform infrared (FTIR) spectroscopy, density functional theory (DFT) calculations, and molecular dynamics simulation. In the pores of CPO‐27‐Zn, water binds as a ligand to the Zn center. Additional water molecules are stepwise incorporated at defined positions, forming a network of H‐bonds with the framework and with each other. In CPO‐27‐Cu, hydration proceeds by an entirely different mechanism. Here, water does not coordinate to the metal center, but only forms H‐bonds with the framework; pore filling occurs mostly in a single step, with the open metal site remaining unoccupied. Water in the pores forms clusters with extensive intra‐cluster H‐bonding.}}, author = {{Kloß, Marvin and Beerbaum, Michael and Baier, Dominik and Weinberger, Christian and Zysk, Frederik and Elgabarty, Hossam and Kühne, Thomas D. and Tiemann, Michael}}, issn = {{2196-7350}}, journal = {{Advanced Materials Interfaces}}, number = {{35}}, pages = {{2400476}}, publisher = {{Wiley}}, title = {{{Understanding Hydration in CPO‐27 Metal‐Organic Frameworks: Strong Impact of the Chemical Nature of the Metal (Cu, Zn)}}}, doi = {{10.1002/admi.202400476}}, volume = {{11}}, year = {{2024}}, } @article{58612, author = {{Luis-Sunga, Maximina and González-Orive, Alejandro and Calderón, Juan Carlos and Gamba, Ilaria and Ródenas, Airán and de los Arcos de Pedro, Maria Teresa and Hernández-Creus, Alberto and Grundmeier, Guido and Pastor, Elena and García, Gonzalo}}, issn = {{2574-0970}}, journal = {{ACS Applied Nano Materials}}, title = {{{Nickel-Induced Reduced Graphene Oxide Nanoribbon Formation on Highly Ordered Pyrolytic Graphite for Electronic and Magnetic Applications}}}, doi = {{10.1021/acsanm.3c05949}}, year = {{2024}}, } @article{58611, abstract = {{AFM-IR investigation of thin PECVD SiOx films on a polypropylene substrate in the surface-sensitive mode}}, author = {{Müller, Hendrik and Stadler, Hartmut and de los Arcos de Pedro, Maria Teresa and Keller, Adrian and Grundmeier, Guido}}, issn = {{2190-4286}}, journal = {{Beilstein Journal of Nanotechnology}}, number = {{1}}, pages = {{603–611}}, title = {{{AFM-IR investigation of thin PECVD SiO x films on a polypropylene substrate in the surface-sensitive mode}}}, doi = {{10.3762/bjnano.15.51}}, volume = {{15}}, year = {{2024}}, } @article{56075, abstract = {{An isostructural series of FeII, FeIII, and Fe(IV)complexes [Fe(ImP)2]0/+/2+ utilizing the ImP 1,1′-(1,3-phenylene)-bis(3-methyl-1-imidazol-2-ylidene) ligand, combining N-heterocy-clic carbenes and cyclometalating functions, is presented. The strong donor motif stabilizes the high-valent Fe(IV) oxidation state yet keeps the FeII oxidation state accessible from the parent Fe(III)compound. Chemical oxidation of [Fe(ImP)2]+ yields stable [FeIV(ImP)2]2+. In contrast, [FeII(ImP)2]0, obtained by reduction,is highly sensitive toward oxygen. Exhaustive ground state characterization by single-crystal X-ray diffraction, 1H NMR,Mössbauer spectroscopy, temperature-dependent magnetic measurements, a combination of X-ray absorption near edge structureand valence-to-core, as well as core-to-core X-ray emission spectroscopy, complemented by detailed density functional theory (DFT) analysis, reveals that the three complexes[Fe(ImP)2]0/+/2+ can be unequivocally attributed to low-spin d6, d5, and d4 complexes. The excited state landscape of the Fe(II) and Fe(IV) complexes is characterized by short-lived 3MLCT and 3LMCT states, with lifetimes of 5.1 and 1.4 ps, respectively. In the FeII-compound, an energetically low-lying MC state leads to fast deactivation of the MLCT state. The distorted square-pyramidal state, where one carbene is dissociated, can not only relax into the ground state, but also into a singlet dissociated state. Its formation was investigated with time-dependent optical spectroscopy, while insights into its structure were gained by NMR spectroscopy.}}, author = {{Steube, Jakob and Fritsch, Lorena and Kruse, Ayla and Bokareva, Olga S. and Demeshko, Serhiy and Elgabarty, Hossam and Schoch, Roland and Alaraby, Mohammad and Egold, Hans and Bracht, Bastian Johannes and Schmitz, Lennart and Hohloch, Stephan and Kühne, Thomas D. and Meyer, Franc and Kühn, Oliver and Lochbrunner, Stefan and Bauer, Matthias}}, issn = {{0020-1669}}, journal = {{Inorganic Chemistry}}, keywords = {{Photo}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Isostructural Series of a Cyclometalated Iron Complex in Three Oxidation States}}}, doi = {{10.1021/acs.inorgchem.4c02576}}, year = {{2024}}, } @article{56074, abstract = {{Effective photoinduced charge transfer makes molecular bimetallic assemblies attractive for applications as active light‐induced proton reduction systems. Developing competitive base metal dyads is mandatory for a more sustainable future. However, the electron transfer mechanisms from the photosensitizer to the proton reduction catalyst in base metal dyads remain so far unexplored. A Fe─Co dyad that exhibits photocatalytic H2 production activity is studied using femtosecond X‐ray emission spectroscopy, complemented by ultrafast optical spectroscopy and theoretical time‐dependent DFT calculations, to understand the electronic and structural dynamics after photoexcitation and during the subsequent charge transfer process from the Fe(II) photosensitizer to the cobaloxime catalyst. This novel approach enables the simultaneous measurement of the transient X‐ray emission at the iron and cobalt K‐edges in a two‐color experiment. With this methodology, the excited state dynamics are correlated to the electron transfer processes, and evidence of the Fe→Co electron transfer as an initial step of proton reduction activity is unraveled.}}, author = {{Nowakowski, Michał and Huber‐Gedert, Marina and Elgabarty, Hossam and Kalinko, Aleksandr and Kubicki, Jacek and Kertmen, Ahmet and Lindner, Natalia and Khakhulin, Dmitry and Lima, Frederico A. and Choi, Tae‐Kyu and Biednov, Mykola and Schmitz, Lennart and Piergies, Natalia and Zalden, Peter and Kubicek, Katerina and Rodriguez‐Fernandez, Angel and Salem, Mohammad Alaraby and Canton, Sophie E. and Bressler, Christian and Kühne, Thomas D. and Gawelda, Wojciech and Bauer, Matthias}}, issn = {{2198-3844}}, journal = {{Advanced Science}}, keywords = {{Photo, Xray}}, publisher = {{Wiley}}, title = {{{Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad}}}, doi = {{10.1002/advs.202404348}}, year = {{2024}}, } @article{52346, abstract = {{Promising cathode materials for fluoride-ion batteries (FIBs) are 3d transition metal containing oxides with Ruddlesden-Popper-type structure. So far, multi-elemental compositions were not investigated, but could alternate electrochemical performance similar to what has been found for cathode materials for lithium-ion batteries. Within this study, we investigate RP type La2Ni0.75Co0.25O4.08 as an intercalation-based active cathode material for all-solid-state FIBs. We determine the structural changes of La2Ni0.75Co0.25O4.08 during fluoride intercalation / de-intercalation by ex-situ X-ray diffraction, which showed that F- insertion leads to transformation of the parent phase to three different phases. Changes in Ni and Co oxidation states and coordination environment were examined by X-ray absorption spectroscopy and magnetic measurements in order to understand the complex reaction behaviour of the phases in detail, showing that the two transition metals behave differently in the charging and discharging process. Under optimized operating conditions, a cycle life of 120 cycles at a critical cut-off capacity of 40 mAh g-1 against Pb/PbF2 was obtained, which is one of the highest observed for intercalation electrode materials in FIBs so far. The average Coulombic efficiencies ranged from 85% to 90%. Thus, La2Ni0.75Co0.25O4.08 could be a promising candidate for cycling-stable high-energy cathode materials for all-solid-state FIBs}}, author = {{Vanita, Vanita and Waidha, Aamir Iqbal and Vasala, Sami and Puphal, Pascal and Schoch, Roland and Glatzel, Pieter and Bauer, Matthias and Clemens, Oliver}}, issn = {{2050-7488}}, journal = {{Journal of Materials Chemistry A}}, keywords = {{Xray}}, number = {{12}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries}}}, doi = {{10.1039/d4ta00704b}}, year = {{2024}}, } @article{60216, abstract = {{Hydride donors such as DIBAL or CuH react with ZnO and ZrO2 via hydrogen spillover. This suggests that hydrogen spillover in catalysts based on these metal oxides may take place via initial hydride transfer and not via proton–electron transfer.}}, author = {{Benz, Michael and Bunjaku, Osman and Nowakowski, Michał and Allgaier, Alexander and Biswas, Indro and van Slageren, Joris and Bauer, Matthias and Estes, Deven P.}}, issn = {{2044-4753}}, journal = {{Catalysis Science & Technology}}, keywords = {{Xray}}, number = {{20}}, pages = {{5854--5863}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Hydrogen spillover through hydride transfer: the reaction of ZnO and ZrO2 with strong hydride donors}}}, doi = {{10.1039/d4cy00504j}}, volume = {{14}}, year = {{2024}}, } @article{54024, abstract = {{Transition metal complexes, particularly copper hydrides, play an important role in various catalytic processes and molecular inorganic chemistry. This study employs synchrotron hard X‐ray spectroscopy to gain insights into the geometric and electronic properties of copper hydrides as potential catalysts for CO2 hydrogenation. The potential of high energy resolution X‐ray absorption near‐edge structure (HERFD‐XANES) and valence‐to‐core X‐ray emission (VtC‐XES) is demonstrated with measurement on Stryker's reagent (Cu6H6) and [Cu3(μ3‐H)(dpmppe)2](PF6)2 (Cu3H), alongside a non‐hydride copper compound (Cu‐I). The XANES analysis reveals that coordination geometries strongly influence the spectra, providing only indirect details about hydride coordination. The VtC‐XES analysis exhibits a distinct signal around 8975 eV, offering a diagnostic tool to identify hydride ligands. Theoretical calculations support and extend these findings by comparing hydride‐containing complexes with their hydride‐free counterparts.}}, author = {{Fritsch, Lorena and Rehsies, Pia and Barakat, Wael and Estes, Deven P. and Bauer, Matthias}}, issn = {{0947-6539}}, journal = {{Chemistry – A European Journal}}, keywords = {{Xray}}, number = {{36}}, publisher = {{Wiley}}, title = {{{Detection and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy}}}, doi = {{10.1002/chem.202400357}}, volume = {{30}}, year = {{2024}}, } @article{54969, abstract = {{This work presents a new and facile route for the preparation of iron oxide-based catalysts supported on alumina, which enables the targeted synthesis of catalysts with an increased amount of isolated tetrahedrally coordinated iron centers compared to a conventional impregnation procedure, and therefore leads to an increase in activity for CO oxidation reaction. By a multi-step impregnation–calcination protocol, the catalysts were synthesized with iron loadings of between 1 and 10 wt%, and their catalytic activity was then compared with a 10 wt% loaded catalyst prepared by conventional single impregnation. With a loading of 8 wt%, the presented catalysts showed an improved catalytic activity regarding light-off and full conversion temperatures compared to this reference. Through the application of several analytical methods (PXRD, PDF, DRUVS, SEM, XAFS), the improved catalytic activity can be correlated with an increased amount of isolated iron centers and a significantly reduced fraction of agglomerates or particles.}}, author = {{Schlicher, Steffen and Schoch, Roland and Prinz, Nils and Zobel, Mirijam and Bauer, Matthias}}, issn = {{2073-4344}}, journal = {{Catalysts}}, keywords = {{Catalysis}}, number = {{7}}, publisher = {{MDPI AG}}, title = {{{New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation}}}, doi = {{10.3390/catal14070416}}, volume = {{14}}, year = {{2024}}, } @article{61848, abstract = {{AbstractUnderstanding how water interacts with nanopores of carbonaceous electrodes is crucial for energy storage and conversion applications. A high surface area of carbonaceous materials does not necessarily need to translate to a high electrolyte‐solid interface area. Herein, we study the interaction of water with nanoporous C1N1 materials to explain their very low specific capacitance in aqueous electrolytes despite their high surface area. Water was used to probe chemical environments, provided by pores of different sizes, in 1H MAS NMR experiments. We observe that regardless of their high hydrophilicity, only a negligible portion of water can enter the nanopores of C1N1, in contrast to a reference pure carbon material with a similar pore structure. The common paradigm that water easily enters hydrophilic pores does not apply to C1N1 nanopores below a few nanometers. Calorimetric and sorption experiments demonstrated strong water adsorption on the C1N1 surface, which restricts water mobility across the interface and impedes its penetration into the nanopores.}}, author = {{Lamata‐Bermejo, Irene and Keil, Waldemar and Nolkemper, Karlo and Heske, Julian and Kossmann, Janina and Elgabarty, Hossam and Wortmann, Martin and Chorążewski, Mirosław and Schmidt, Claudia and Kühne, Thomas D. and López‐Salas, Nieves and Odziomek, Mateusz}}, issn = {{1433-7851}}, journal = {{Angewandte Chemie International Edition}}, number = {{50}}, publisher = {{Wiley}}, title = {{{Understanding the Wettability of C1N1 (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes}}}, doi = {{10.1002/anie.202411493}}, volume = {{63}}, year = {{2024}}, } @article{62093, abstract = {{AbstractUnter anderem das hat die Organik im letzten Jahr bewegt: milde Oxidation mit Elektrochemie, Oxidation zu enantiomerenreinen Sulfonylverbindungen, Flüssigkristallphasen erkennen mit maschinellem Lernen, CO2reagiert zu Succinat und Carbamaten, eine Alternative zu Bisphenol A, Subporphyrine, photoschaltbare Spinmaterialien, photochemische Thiophen‐Ringerweiterung, und Peptide werden mit Bor versehen und cyclisiert. Die Zusammenstellung des Trendberichts koordiniert hat Martin Breugst, Universität Chemnitz.}}, author = {{Breugst, Martin and Andexer, Jennifer and Barra, Lena and Beil, Sebastian B. and Breinbauer, Rolf and Burkhardt, Immo and Dumele, Oliver and Ernst, Martin and Gellrich, Urs and Germer, Philipp and Giese, Michael and Huy, Peter and Kath‐Schorr, Stephanie and Klepp, Julian and Körber, Karsten and Kordes, Markus and Kuttruff, Christian A. and Lindel, Thomas and Myllek, Sebastian and Pfrengle, Fabian and Pietruszka, Jörg and Schaschke, Norbert and Senge, Mathias O. and Storch, Golo and Teichert, Johannes F. and Tönjes, Jan and Waldvogel, Siegfried R. and Werner, Thomas and Winter, Christian}}, issn = {{1439-9598}}, journal = {{Nachrichten aus der Chemie}}, number = {{3}}, pages = {{44--67}}, publisher = {{Wiley}}, title = {{{Trendbericht Organische Chemie 2024}}}, doi = {{10.1002/nadc.20244139258}}, volume = {{72}}, year = {{2024}}, } @article{62092, author = {{Nyemeck, Suzanne L. and Eyong, Kenneth O. and Bidingha, Ronald and Kamdem, Michael HK. and Ndinteh, Derek T. and Odumosu, Patricia O. and Folefoc, Gabriel N. and Bilanda, Danielle C. and Egbe, Andrew E. and Werner, Thomas and Bekono, Boris D. and Ntie-Kang, Fidele}}, issn = {{1874-3900}}, journal = {{Phytochemistry Letters}}, keywords = {{T4}}, pages = {{59--67}}, publisher = {{Elsevier BV}}, title = {{{Design, isolation, synthesis, and mechanistic insight of flavonoids isolated from Beilschmiedia obscura, as potential α-glucosidase inhibitors}}}, doi = {{10.1016/j.phytol.2024.06.004}}, volume = {{62}}, year = {{2024}}, } @article{62090, abstract = {{The selective N-formylation and N-methylation of amines with carbon dioxide (CO2) catalyzed by methyltriphenylphosphonium methylcarbonate and tuned by polymethylhydrosiloxane or trimethoxysilane as reducing agents is reported.}}, author = {{Ren, Changyue and Terazzi, Constanza and Werner, Thomas}}, issn = {{1463-9262}}, journal = {{Green Chemistry}}, keywords = {{T1, T2, CSSD}}, number = {{1}}, pages = {{439--447}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Tuneable reduction of CO2 – organocatalyzed selective formylation and methylation of amines}}}, doi = {{10.1039/d3gc03993e}}, volume = {{26}}, year = {{2024}}, } @article{62091, author = {{Ren, Changyue and Spannenberg, Anke and Werner, Thomas}}, issn = {{2168-0485}}, journal = {{ACS Sustainable Chemistry & Engineering}}, keywords = {{T1, T2, CSSD}}, number = {{29}}, pages = {{10969--10977}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Phosphonium-Salt-Catalyzed N-Methylation and N-Formylation of Amines with CO2}}}, doi = {{10.1021/acssuschemeng.4c03464}}, volume = {{12}}, year = {{2024}}, } @article{62088, author = {{Tönjes, Jan and Medvarić, Viktorija and Werner, Thomas}}, issn = {{0022-3263}}, journal = {{The Journal of Organic Chemistry}}, keywords = {{T2, CSSD}}, number = {{15}}, pages = {{10729--10735}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis}}}, doi = {{10.1021/acs.joc.4c00985}}, volume = {{89}}, year = {{2024}}, } @article{62236, abstract = {{AbstractDue to its excellent biocompatibility, pure iron is a very promising implant material, but often features corrosion rates that are too low. Using additive manufacturing and modified powders the microstructure and, thus, the material properties, e.g., the corrosion properties, can be tailored for specific applications. Within the scope of this study, pure iron powder was modified with different amounts of CeO2 or Fe2O3 nanoparticles and subsequently processed by Electron Beam Powder Bed Fusion (PBF-EB/M). The corrosion-fatigue behavior of CeO2 and Fe2O3 modified iron was investigated using rotation bending tests under the influence of simulated body fluid (m-SBF). While the modification using Fe2O3 showed reduced fatigue and corrosion-fatigue strengths, it could be demonstrated that the modification with CeO2 is characterized by improved fatigue properties. The superior fatigue properties in air are attributed to the positive impact of dispersion strengthening. Additionally, an increased degradation rate compared to pure iron could be observed, eventually promoting an earlier failure of the specimens in the corrosion fatigue tests.}}, author = {{Wackenrohr, Steffen and Torrent, Christof Johannes Jaime and Herbst, Sebastian and Nürnberger, Florian and Krooss, Philipp and Frenck, Johanna-Maria and Ebbert, Christoph and Voigt, Markus and Grundmeier, Guido and Niendorf, Thomas and Maier, Hans Jürgen}}, issn = {{2397-2106}}, journal = {{npj Materials Degradation}}, number = {{1}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Corrosion fatigue behavior of nanoparticle modified iron processed by electron powder bed fusion}}}, doi = {{10.1038/s41529-024-00470-w}}, volume = {{8}}, year = {{2024}}, } @article{62255, abstract = {{AbstractCellular stress and ageing involve an increase in crowding and aggregation of amylogenic proteins. We here investigate if crowding is the intrinsic cause of aggregation and utilise a previously established non-protein aggregation sensor, namely pseudoisocyanine chloride (PIC). PIC shows fibrillization in cells into a highly fluorescent J-aggregated state and is sensitive to crowding. Surprisingly, cell stress conditions stabilise the monomeric rather than the aggregated state of PIC both in the cytoplasm and in stress granules. Regarding the different physiochemical changes of the cytoplasm occurring upon cell stress, involving volume reduction, phase separation and solidification, the intrinsic crowding effect is not the key factor to drive associated self-assembly processes.}}, author = {{Pollak, Roland and Koch, Leon and König, Benedikt and Ribeiro, Sara S. and Samanta, Nirnay and Huber, Klaus and Ebbinghaus, Simon}}, issn = {{2399-3669}}, journal = {{Communications Chemistry}}, number = {{1}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Cell stress and phase separation stabilize the monomeric state of pseudoisocyanine chloride employed as a self-assembly crowding sensor}}}, doi = {{10.1038/s42004-024-01315-y}}, volume = {{7}}, year = {{2024}}, }