@article{42878,
  author       = {{Köring, Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  publisher    = {{Wiley}},
  title        = {{{Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation}}},
  doi          = {{10.1002/anie.202301632}},
  year         = {{2023}},
}

@article{42879,
  author       = {{Köring, Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  keywords     = {{General Medicine}},
  publisher    = {{Wiley}},
  title        = {{{Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation}}},
  doi          = {{10.1002/ange.202301632}},
  year         = {{2023}},
}

@article{43457,
  abstract     = {{The production of hydrogen and the utilization of biomass for sustainable concepts of energy conversion and storage require gas sensors that discriminate between hydrogen (H2) and carbon monoxide (CO). Mesoporous copper–ceria (Cu–CeO2) materials with large specific surface areas and uniform porosity are prepared by nanocasting, and their textural properties are characterized by N2 physisorption, powder XRD, scanning electron microscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy. The oxidation states of copper (Cu+, Cu2+) and cerium (Ce3+, Ce4+) are investigated by XPS. The materials are used as resistive gas sensors for H2 and CO. The sensors show a stronger response to CO than to H2 and low cross-sensitivity to humidity. Copper turns out to be a necessary component; copper-free ceria materials prepared by the same method show only poor sensing performance. By measuring both gases (CO and H2) simultaneously, it is shown that this behavior can be utilized for selective sensing of CO in the presence of H2.}},
  author       = {{Baier, Dominik and Priamushko, Tatiana and Weinberger, Christian and Kleitz, Freddy and Tiemann, Michael}},
  issn         = {{2379-3694}},
  journal      = {{ACS Sensors}},
  keywords     = {{Fluid Flow and Transfer Processes, Process Chemistry and Technology, Instrumentation, Bioengineering}},
  number       = {{4}},
  pages        = {{1616 -- 1623}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Selective Discrimination between CO and H2 with Copper–Ceria-Resistive Gas Sensors}}},
  doi          = {{10.1021/acssensors.2c02739}},
  volume       = {{8}},
  year         = {{2023}},
}

@article{40981,
  abstract     = {{Room temperature sodium-sulfur (RT Na-S) batteries are considered potential candidates for stationary power storage applications due to their low cost, broad active material availability and low toxicity. Challenges, such as high volume expansion of the S-cathode upon discharge, low electronic conductivity of S as active material and herewith limited rate capability as well as the shuttling of polysulfides (PSs) as intermediates often impede the cycle stability and practical application of Na-S batteries. Sulfurized poly(acrylonitrile) (SPAN) inherently inhibits the shuttling of PSs and shows compatibility with carbonate-based electrolytes, however, its exact redox mechanism remained unclear to date. Herein, we implement a commercially available and simple electrolyte into the Na-SPAN cell chemistry and demonstrate its high rate and cycle stability. Through the application of in situ techniques utilizing electronic impedance spectroscopy (EIS) and X-ray absorption spectroscopy (XAS) at different depths of charge and discharge, an insight into SPAN’s redox chemistry is obtained.}},
  author       = {{Kappler, Julian and Tonbul, Güldeniz and Schoch, Roland and Murugan, Saravanakumar and Nowakowski, Michał and Lange, Pia Lena and Klostermann, Sina Vanessa and Bauer, Matthias and Schleid, Thomas and Kästner, Johannes and Buchmeiser, Michael Rudolf}},
  issn         = {{0013-4651}},
  journal      = {{Journal of The Electrochemical Society}},
  keywords     = {{Materials Chemistry, Electrochemistry, Surfaces, Coatings and Films, Condensed Matter Physics, Renewable Energy, Sustainability and the Environment, Electronic, Optical and Magnetic Materials}},
  number       = {{1}},
  publisher    = {{The Electrochemical Society}},
  title        = {{{Understanding the Redox Mechanism of Sulfurized Poly(acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries}}},
  doi          = {{10.1149/1945-7111/acb2fa}},
  volume       = {{170}},
  year         = {{2023}},
}

@inproceedings{44380,
  author       = {{Tonbul, Güldeniz and Kappler, Julian  and Murugan, Saravanakumar  and Schoch, Roland  and Nowakowski, Michal  and Lange, Pia and Bauer, Matthias  and Buchmeiser, Michael R.}},
  location     = {{Aachen}},
  title        = {{{Characterization of Na-S Battery System Using X-ray Absorption Spectroscopy}}},
  year         = {{2023}},
}

@article{42517,
  author       = {{Tapio, Kosti and Kielar, Charlotte and Parikka, Johannes M. and Keller, Adrian and Järvinen, Heini and Fahmy, Karim and Toppari, J. Jussi}},
  issn         = {{0897-4756}},
  journal      = {{Chemistry of Materials}},
  keywords     = {{Materials Chemistry, General Chemical Engineering, General Chemistry}},
  pages        = {{1961–1971}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Large-Scale Formation of DNA Origami Lattices on Silicon}}},
  doi          = {{10.1021/acs.chemmater.2c03190}},
  volume       = {{35}},
  year         = {{2023}},
}

@article{42518,
  author       = {{Pothineni, Bhanu Kiran and Keller, Adrian}},
  issn         = {{2699-9307}},
  journal      = {{Advanced NanoBiomed Research}},
  keywords     = {{General Medicine}},
  publisher    = {{Wiley}},
  title        = {{{Nanoparticle‐Based Formulations of Glycopeptide Antibiotics: A Means for Overcoming Vancomycin Resistance in Bacterial Pathogens?}}},
  doi          = {{10.1002/anbr.202200134}},
  volume       = {{3}},
  year         = {{2023}},
}

@article{44503,
  author       = {{Hanke, Marcel and Tomm, Emilia and Grundmeier, Guido and Keller, Adrian}},
  issn         = {{1439-4227}},
  journal      = {{ChemBioChem}},
  keywords     = {{Organic Chemistry, Molecular Biology, Molecular Medicine, Biochemistry}},
  publisher    = {{Wiley}},
  title        = {{{Effect of Ionic Strength on the Thermal Stability of DNA Origami Nanostructures}}},
  doi          = {{10.1002/cbic.202300338}},
  year         = {{2023}},
}

@article{44504,
  author       = {{Linko, Veikko and Keller, Adrian}},
  issn         = {{1613-6810}},
  journal      = {{Small}},
  keywords     = {{Biomaterials, Biotechnology, General Materials Science, General Chemistry}},
  publisher    = {{Wiley}},
  title        = {{{Stability of DNA Origami Nanostructures in Physiological Media: The Role of Molecular Interactions}}},
  doi          = {{10.1002/smll.202301935}},
  year         = {{2023}},
}

@article{44523,
  author       = {{Paradies, Jan}},
  issn         = {{0001-4842}},
  journal      = {{Accounts of Chemical Research}},
  keywords     = {{General Medicine, General Chemistry}},
  number       = {{7}},
  pages        = {{821--834}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed Hydrogenations, Dehydrogenations, and Cycloisomerizations}}},
  doi          = {{10.1021/acs.accounts.2c00832}},
  volume       = {{56}},
  year         = {{2023}},
}

@article{44837,
  abstract     = {{Hydrothermal carbonization (HTC) is an efficient thermochemical method for the conversion of organic feedstock to carbonaceous solids. HTC of different saccharides is known to produce microspheres (MS) with mostly Gaussian size distribution, which are utilized as functional materials in various applications, both as pristine MS and as a precursor for hard carbon MS. Although the average size of the MS can be influenced by adjusting the process parameters, there is no reliable mechanism to affect their size distribution. Our results demonstrate that HTC of trehalose, in contrast to other saccharides, results in a distinctly bimodal sphere diameter distribution consisting of small spheres with diameters of (2.1 ± 0.2) μm and of large spheres with diameters of (10.4 ± 2.6) μm. Remarkably, after pyrolytic post-carbonization at 1000 °C the MS develop a multimodal pore size distribution with abundant macropores > 100 nm, mesopores > 10 nm and micropores < 2 nm, which were examined by small-angle X-ray scattering and visualized by charge-compensated helium ion microscopy. The bimodal size distribution and hierarchical porosity provide an extraordinary set of properties and potential variables for the tailored synthesis of hierarchical porous carbons, making trehalose-derived hard carbon MS a highly promising material for applications in catalysis, filtration, and energy storage devices.}},
  author       = {{Wortmann, Martin and Keil, Waldemar and Diestelhorst, Elise and Westphal, Michael and Haverkamp, René and Brockhagen, Bennet and Biedinger, Jan and Bondzio, Laila and Weinberger, Christian and Baier, Dominik and Tiemann, Michael and Hütten, Andreas and Hellweg, Thomas and Reiss, Günter and Schmidt, Claudia and Sattler, Klaus and Frese, Natalie}},
  issn         = {{2046-2069}},
  journal      = {{RSC Advances}},
  keywords     = {{General Chemical Engineering, General Chemistry}},
  number       = {{21}},
  pages        = {{14181--14189}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Hard carbon microspheres with bimodal size distribution and hierarchical porosity <i>via</i> hydrothermal carbonization of trehalose}}},
  doi          = {{10.1039/d3ra01301d}},
  volume       = {{13}},
  year         = {{2023}},
}

@article{45013,
  author       = {{Codescu, M.-A. and Kunze, T. and Weiß, M. and Brehm, Martin and Kornilov, O. and Sebastiani, D. and Nibbering, E. T. J.}},
  journal      = {{J. Phys. Chem. Lett.}},
  pages        = {{4775--4785}},
  title        = {{{Ultrafast Proton Transfer Pathways Mediated by Amphoteric Imidazole}}},
  doi          = {{10.1021/acs.jpclett.3c00595}},
  volume       = {{14}},
  year         = {{2023}},
}

@article{45012,
  author       = {{Roos, E. and Sebastiani, D. and Brehm, Martin}},
  journal      = {{Phys. Chem. Chem. Phys.}},
  pages        = {{8755--8766}},
  title        = {{{A Force Field for Bio-Polymers in Ionic Liquids (BILFF) – Part 2: Cellulose in [EMIm][OAc] / Water Mixtures}}},
  doi          = {{10.1039/D2CP05636D}},
  volume       = {{25 (12)}},
  year         = {{2023}},
}

@article{45011,
  author       = {{Radicke, J. and Roos, E. and Sebastiani, D. and Brehm, Martin and Kressler, J.}},
  journal      = {{J. Polym. Sci.}},
  pages        = {{372--384}},
  title        = {{{Lactate-Based Ionic Liquids as Chiral Solvents for Cellulose}}},
  doi          = {{10.1002/pol.20220687}},
  volume       = {{61 (5)}},
  year         = {{2023}},
}

@article{43092,
  abstract     = {{<jats:p>By using coordinating anions such as acetate, a water-in-salt-like coordination environment of Zn ions is achieved in relatively dilute conditions, leading to prolonged and efficient cycling of zinc metal anodes.</jats:p>}},
  author       = {{Gomez Vazquez, Dario and Pollard, Travis P. and Mars, Julian and Yoo, Ji Mun and Steinrück, Hans-Georg and Bone, Sharon E. and Safonova, Olga V. and Toney, Michael F. and Borodin, Oleg and Lukatskaya, Maria R.}},
  issn         = {{1754-5692}},
  journal      = {{Energy & Environmental Science}},
  keywords     = {{Pollution, Nuclear Energy and Engineering, Renewable Energy, Sustainability and the Environment, Environmental Chemistry}},
  pages        = {{1982--1991 (2023).}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Creating water-in-salt-like environment using coordinating anions in non-concentrated aqueous electrolytes for efficient Zn batteries}}},
  doi          = {{10.1039/d3ee00205e}},
  volume       = {{16}},
  year         = {{2023}},
}

@article{44271,
  author       = {{Weadock, Nicholas J. and Sterling, Tyler C. and Vigil, Julian A. and Gold-Parker, Aryeh and Smith, Ian C. and Ahammed, Ballal and Krogstad, Matthew J. and Ye, Feng and Voneshen, David and Gehring, Peter M. and Rappe, Andrew M. and Steinrück, Hans-Georg and Ertekin, Elif and Karunadasa, Hemamala I. and Reznik, Dmitry and Toney, Michael F.}},
  issn         = {{2542-4351}},
  journal      = {{Joule}},
  keywords     = {{General Energy}},
  pages        = {{1051--1066}},
  publisher    = {{Elsevier BV}},
  title        = {{{The nature of dynamic local order in CH3NH3PbI3 and CH3NH3PbBr3}}},
  doi          = {{10.1016/j.joule.2023.03.017}},
  volume       = {{7}},
  year         = {{2023}},
}

@article{44116,
  abstract     = {{Faradaic reactions including charge transfer are often accompanied with diffusion limitation inside the bulk. Conductive two-dimensional frameworks (2D MOFs) with a fast ion transport can combine both - charge transfer and fast diffusion inside their porous structure. To study remaining diffusion limitations caused by particle morphology, different synthesis routes of Cu-2,3,6,7,10,11-hexahydroxytriphenylene (Cu3(HHTP)2), a copper-based 2D MOF, are used to obtain flake- and rod-like MOF particles. Both morphologies are systematically characterized and evaluated for redox-active Li+ ion storage. The redox mechanism is investigated by means of X-ray absorption spectroscopy, FTIR spectroscopy and in situ XRD. Both types are compared regarding kinetic properties for Li+ ion storage via cyclic voltammetry and impedance spectroscopy. A significant influence of particle morphology for 2D MOFs on kinetic aspects of electrochemical Li+ ion storage can be observed. This study opens the path for optimization of redox active porous structures to overcome diffusion limitations of Faradaic processes.}},
  author       = {{Wrogemann, Jens Matthies and Lüther, Marco Joes and Bärmann, Peer and Lounasvuori, Mailis and Javed, Ali and Tiemann, Michael and Golnak, Ronny and Xiao, Jie and Petit, Tristan and Placke, Tobias and Winter, Martin}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{26}},
  pages        = {{e202303111}},
  publisher    = {{Wiley}},
  title        = {{{Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage}}},
  doi          = {{10.1002/anie.202303111}},
  volume       = {{62}},
  year         = {{2023}},
}

@article{45828,
  abstract     = {{<jats:p>This article presents the potential-dependent adsorption of two proteins, bovine serum albumin (BSA) and lysozyme (LYZ), on Ti6Al4V alloy at pH 7.4 and 37 °C. The adsorption process was studied on an electropolished alloy under cathodic and anodic overpotentials, compared to the open circuit potential (OCP). To analyze the adsorption process, various complementary interface analytical techniques were employed, including PM-IRRAS (polarization-modulation infrared reflection-absorption spectroscopy), AFM (atomic force microscopy), XPS (X-ray photoelectron spectroscopy), and E-QCM (electrochemical quartz crystal microbalance) measurements. The polarization experiments were conducted within a potential range where charging of the electric double layer dominates, and Faradaic currents can be disregarded. The findings highlight the significant influence of the interfacial charge distribution on the adsorption of BSA and LYZ onto the alloy surface. Furthermore, electrochemical analysis of the protein layers formed under applied overpotentials demonstrated improved corrosion protection properties. These studies provide valuable insights into protein adsorption on titanium alloys under physiological conditions, characterized by varying potentials of the passive alloy.</jats:p>}},
  author       = {{Duderija, Belma and González-Orive, Alejandro and Ebbert, Christoph and Neßlinger, Vanessa and Keller, Adrian and Grundmeier, Guido}},
  issn         = {{1420-3049}},
  journal      = {{Molecules}},
  keywords     = {{Chemistry (miscellaneous), Analytical Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Molecular Medicine, Drug Discovery, Pharmaceutical Science}},
  number       = {{13}},
  pages        = {{5109}},
  publisher    = {{MDPI AG}},
  title        = {{{Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy}}},
  doi          = {{10.3390/molecules28135109}},
  volume       = {{28}},
  year         = {{2023}},
}

@inbook{45829,
  author       = {{Keller, Adrian and Grundmeier, Guido}},
  booktitle    = {{Reference Module in Chemistry, Molecular Sciences and Chemical Engineering}},
  isbn         = {{9780124095472}},
  publisher    = {{Elsevier}},
  title        = {{{High-speed AFM studies of macromolecular dynamics at solid/liquid interfaces}}},
  doi          = {{10.1016/b978-0-323-85669-0.00123-9}},
  year         = {{2023}},
}

@article{46061,
  abstract     = {{<jats:p>DNA origami nanostructures have emerged as functional materials for applications in various areas of science and technology. In particular, the transfer of the DNA origami shape into inorganic materials using...</jats:p>}},
  author       = {{Pothineni, Bhanu Kiran and Grundmeier, Guido and Keller, Adrian}},
  issn         = {{2040-3364}},
  journal      = {{Nanoscale}},
  keywords     = {{General Materials Science}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Cation-dependent assembly of hexagonal DNA origami lattices on SiO2 surfaces}}},
  doi          = {{10.1039/d3nr02926c}},
  year         = {{2023}},
}