@inproceedings{62969,
  author       = {{Pollmeier, Pascal and Vogelsang, Christoph and Fechner, Sabine}},
  booktitle    = {{15th Conference of the European Science Education Research Association (ESERA)}},
  keywords     = {{Epistemologie, Evidenzen, Daten, Umgang mit Daten, Kompetenzen, Studierende, pre-service teachers}},
  location     = {{Cappadocia}},
  title        = {{{Evidence based practice of pre-service teachers}}},
  year         = {{2023}},
}

@article{58608,
  abstract     = {{Interfacial reactions at the polycarbonate (PC)/FeCr-alloy interface during melt contact were studied as function of the Fe:Cr ratio within the alloy. Thin Fe/Cr films with lateral composition gradients were deposited by magnetron sputtering; the analysis of the films was done with microscopy and X-ray photoelectron spectroscopy (XPS). The local interfacial polymeric film formation could be therefore directly correlated with the Fe:Cr ratio. The local thickness and structure of the formed polycarbonate residue was analyzed by means of imaging ellipsometry, atomic force microscopy as well as Fourier-transform infrared spectroscopy under grazing incidence and XPS. Moreover, confocal fluorescence microscopy of the PC melt/alloy interface could reveal the formation of minor degradation products in the interphase region. The results show that already an Fe:Cr ratio of 2 : 1 leads to a strong inhibition of the thermal degradation in comparison to the unalloyed iron, and that in general, the enrichment of chromium in the passive film leads to an effective suppression of interfacial PC degradation. The data contributes to improving the mechanistic understanding of the role of iron during this process. Additionally, a critical concentration of chromium in the alloys used for PC processing can be deduced.}},
  author       = {{Theile-Rasche, Chantal and Meng, T. and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido}},
  issn         = {{2523-3971}},
  journal      = {{SN Applied Sciences}},
  number       = {{10}},
  pages        = {{1–12}},
  title        = {{{Analysis of polycarbonate degradation at melt/FeCr-alloy interfaces as a function of the alloy composition by means of combinatorial thin film chemistry}}},
  doi          = {{10.1007/s42452-023-05441-5}},
  volume       = {{5}},
  year         = {{2023}},
}

@article{58609,
  abstract     = {{Plasma Processes and Polymers is a plasma journal focusing on the interdisciplinary field of low temperature plasma science.}},
  author       = {{de los Arcos de Pedro, Maria Teresa and Awakowicz, Peter and Böke, Marc and Boysen, Nils and Brinkmann, Ralf Peter and Dahlmann, Rainer and Devi, Anjana and Eremin, Denis and Franke, Jonas and Gergs, Tobias and Jenderny, Jonathan and Kemaneci, Efe and Kühne, Thomas D. and Kusmierz, Simon and Mussenbrock, Thomas and Rubner, Jens and Trieschmann, Jan and Wessling, Matthias and Xie, Xiaofan and Zanders, David and Zysk, Frederik and Grundmeier, Guido}},
  issn         = {{1612-8850}},
  journal      = {{PLASMA PROCESSES AND POLYMERS}},
  pages        = {{e2300186}},
  title        = {{{PECVD and PEALD on polymer substrates (part II): Understanding and tuning of barrier and membrane properties of thin films}}},
  doi          = {{10.1002/ppap.202300186}},
  year         = {{2023}},
}

@article{58610,
  author       = {{de los Arcos de Pedro, Maria Teresa and Awakowicz, Peter and Benedikt, Jan and Biskup, Beatrix and Böke, Marc and Boysen, Nils and Buschhaus, Rahel and Dahlmann, Rainer and Devi, Anjana and Gergs, Tobias and Jenderny, Jonathan and von Keudell, Achim and Kühne, Thomas D. and Kusmierz, Simon and Müller, Hendrik and Mussenbrock, Thomas and Trieschmann, Jan and Zanders, David and Zysk, Frederik and Grundmeier, Guido}},
  issn         = {{1612-8850}},
  journal      = {{PLASMA PROCESSES AND POLYMERS}},
  pages        = {{e2300150}},
  title        = {{{PECVD and PEALD on polymer substrates (part I): Fundamentals and analysis of plasma activation and thin film growth}}},
  doi          = {{10.1002/ppap.202300150}},
  year         = {{2023}},
}

@article{58607,
  author       = {{Xie, Xiaofan and Zanders, David and Preischel, Florian and de los Arcos de Pedro, Maria Teresa and Devi, Anjana and Grundmeier, Guido}},
  issn         = {{0142-2421}},
  journal      = {{Surface and Interface Analysis}},
  title        = {{{Complementary spectroscopic and electrochemical analysis of the sealing of micropores in hexamethyldisilazane plasma polymer films by Al 2 O 3 atomic layer deposition}}},
  doi          = {{10.1002/sia.7256}},
  year         = {{2023}},
}

@article{52343,
  abstract     = {{Improved enantioselectivity in the 1,2-addition was observed for chiral Rh norbornadiene catalysts immobilized on ordered mesoporous silica with small pores. Confinement effects were rationalized by experimental and computational studies.}},
  author       = {{Kirchhof, Manuel and Gugeler, Katrin and Beurer, Ann-Katrin and Fischer, Felix Richard and Batman, Derman and Bauch, Soeren M. and Kolin, Sofia and Nicholas, Elliot and Schoch, Roland and Vogler, Charlotte and Kousik, Shravan R. and Zens, Anna and Plietker, Bernd and Atanasova, Petia and Naumann, Stefan and Bauer, Matthias and Bruckner, Johanna R. and Traa, Yvonne and Kästner, Johannes and Laschat, Sabine}},
  issn         = {{2044-4753}},
  journal      = {{Catalysis Science Technology}},
  keywords     = {{Catalysis}},
  number       = {{12}},
  pages        = {{3709--3724}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis}}},
  doi          = {{10.1039/d3cy00381g}},
  volume       = {{13}},
  year         = {{2023}},
}

@article{49608,
  abstract     = {{<jats:p>The effects of backbone amine functionalization in three new homoleptic C^N^C type ruthenium(II) complexes bearing a tridentate bis‐imidazole‐2‐ylidene pyridine ligand framework are characterized and studied by single crystal diffraction, electrochemistry, optical spectroscopy and transient absorption spectroscopy in combination with ab initio DFT calculations. Functionalization by dimethylamine groups in 4‐position of the pyridine backbone significantly influences the properties of the complexes as revealed by comparison with the unfunctionalized references. As a result of the amine functionalization, a higher molar absorption coefficient of the MLCT bands, a decreased photoluminescence quantum yield at room temperature together with a shortened excited state lifetime but an improved photostability is observed. Introduction of electron donating and withdrawing groups at the NHC unit modifies the electronic and optical properties, such as the oxidation potential, absorption and emission properties, and the lifetimes of the excited states.</jats:p>}},
  author       = {{Fritsch, Lorena and Vukadinovic, Yannik and Lang, Moritz and Naumann, Robert and Bertrams, Maria-Sophie and Kruse, Ayla and Schoch, Roland and Müller, Patrick and Neuba, Adam and Dierks, Philipp and Lochbrunner, Stefan and Kerzig, Christoph and Heinze, Katja and Bauer, Matthias}},
  issn         = {{2367-0932}},
  journal      = {{ChemPhotoChem}},
  keywords     = {{Photo}},
  publisher    = {{Wiley}},
  title        = {{{Chemical and photophysical properties of amine functionalized bis‐NHC‐pyridine‐Ru(II) complexes}}},
  doi          = {{10.1002/cptc.202300281}},
  year         = {{2023}},
}

@article{64893,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>The synthesis of three novel imidazolyl‐substituted sulfur‐containing heteroacenes is reported. These heteroacenes consisting of annelated benzo‐ and naphthothiophenes serve as precursors for the generation of open‐shell quinoid heteroacenes by oxidation with alkaline ferric cyanide. Spectroscopic and computational experiments support the formation of reactive open‐shell quinoids, which, however, quickly produce paramagnetic polymeric material.</jats:p>}},
  author       = {{Hou, Peng and Peschtrich, Sebastian and Feuerstein, Wolfram and Schoch, Roland and Hohloch, Stephan and Breher, Frank and Paradies, Jan}},
  issn         = {{2191-1363}},
  journal      = {{ChemistryOpen}},
  number       = {{11}},
  publisher    = {{Wiley}},
  title        = {{{Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids}}},
  doi          = {{10.1002/open.202300003}},
  volume       = {{12}},
  year         = {{2023}},
}

@article{30209,
  abstract     = {{<jats:p>DNA origami technology enables the folding of DNA strands into complex nanoscale shapes whose properties and interactions with molecular species often deviate significantly from that of genomic DNA. Here, we investigate the salting-out of different DNA origami shapes by the kosmotropic salt ammonium sulfate that is routinely employed in protein precipitation. We find that centrifugation in the presence of 3 M ammonium sulfate results in notable precipitation of DNA origami nanostructures but not of double-stranded genomic DNA. The precipitated DNA origami nanostructures can be resuspended in ammonium sulfate-free buffer without apparent formation of aggregates or loss of structural integrity. Even though quasi-1D six-helix bundle DNA origami are slightly less susceptible toward salting-out than more compact DNA origami triangles and 24-helix bundles, precipitation and recovery yields appear to be mostly independent of DNA origami shape and superstructure. Exploiting the specificity of ammonium sulfate salting-out for DNA origami nanostructures, we further apply this method to separate DNA origami triangles from genomic DNA fragments in a complex mixture. Our results thus demonstrate the possibility of concentrating and purifying DNA origami nanostructures by ammonium sulfate-induced salting-out.</jats:p>}},
  author       = {{Hanke, Marcel and Hansen, Niklas and Chen, Ruiping and Grundmeier, Guido and Fahmy, Karim and Keller, Adrian}},
  issn         = {{1422-0067}},
  journal      = {{International Journal of Molecular Sciences}},
  keywords     = {{Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Computer Science Applications, Spectroscopy, Molecular Biology, General Medicine, Catalysis}},
  number       = {{5}},
  pages        = {{2817}},
  publisher    = {{MDPI AG}},
  title        = {{{Salting-Out of DNA Origami Nanostructures by Ammonium Sulfate}}},
  doi          = {{10.3390/ijms23052817}},
  volume       = {{23}},
  year         = {{2022}},
}

@article{30910,
  author       = {{Ma, Lin and Pollard, Travis P. and Zhang, Yong and Schroeder, Marshall A. and Ren, Xiaoming and Han, Kee Sung and Ding, Michael S. and Cresce, Arthur V. and Atwater, Terrill B. and Mars, Julian and Cao, Longsheng and Steinrück, Hans-Georg and Mueller, Karl T. and Toney, Michael F. and Hourwitz, Matt and Fourkas, John T. and Maginn, Edward J. and Wang, Chunsheng and Borodin, Oleg and Xu, Kang}},
  issn         = {{2590-3322}},
  journal      = {{One Earth}},
  keywords     = {{Earth and Planetary Sciences (miscellaneous), General Environmental Science}},
  number       = {{4}},
  pages        = {{413--421}},
  publisher    = {{Elsevier BV}},
  title        = {{{Ammonium enables reversible aqueous Zn battery chemistries by tailoring the interphase}}},
  doi          = {{10.1016/j.oneear.2022.03.012}},
  volume       = {{5}},
  year         = {{2022}},
}

@article{30920,
  abstract     = {{<jats:title>Abstract</jats:title>
               <jats:p>Batteries capable of extreme fast-charging (XFC) are a necessity for the deployment of electric vehicles. Material properties of electrodes and electrolytes along with cell parameters such as stack pressure and temperature have coupled, synergistic, and sometimes deleterious effects on fast-charging performance. We develop a new experimental testbed that allows precise and conformal application of electrode stack pressure. We focus on cell capacity degradation using single-layer pouch cells with graphite anodes, LiNi0.5Mn0.3Co0.2O2 (NMC532) cathodes, and carbonate-based electrolyte. In the tested range (10 – 125 psi), cells cycled at higher pressure show higher capacity and less capacity fading. Additionally, Li plating decreases with increasing pressure as observed with scanning electron microscopy (SEM) and optical imaging. While the loss of Li inventory from Li plating is the largest contributor to capacity fade, electrochemical and SEM examination of the NMC cathodes after XFC experiments show increased secondary particle damage at lower pressure. We infer that the better performance at higher pressure is due to more homogenous reactions of active materials across the electrode and less polarization through the electrode thickness. Our study emphasizes the importance of electrode stack pressure in XFC batteries and highlights its subtle role in cell conditions.</jats:p>}},
  author       = {{Cao, Chuntian and Steinrück, Hans-Georg and Paul, Partha P and Dunlop, Alison R. and Trask, Stephen E. and Jansen, Andrew and Kasse, Robert M and Thampy, Vivek and Yusuf, Maha and Nelson Weker, Johanna and Shyam, Badri and Subbaraman, Ram and Davis, Kelly and Johnston, Christina M and Takacs, Christopher J and Toney, Michael}},
  issn         = {{0013-4651}},
  journal      = {{Journal of The Electrochemical Society}},
  keywords     = {{Materials Chemistry, Electrochemistry, Surfaces, Coatings and Films, Condensed Matter Physics, Renewable Energy, Sustainability and the Environment, Electronic, Optical and Magnetic Materials}},
  pages        = {{040540}},
  publisher    = {{The Electrochemical Society}},
  title        = {{{Conformal Pressure and Fast-Charging Li-Ion Batteries}}},
  doi          = {{10.1149/1945-7111/ac653f}},
  volume       = {{169}},
  year         = {{2022}},
}

@article{30922,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>Pure iron is very attractive as a biodegradable implant material due to its high biocompatibility. In combination with additive manufacturing, which facilitates great flexibility of the implant design, it is possible to selectively adjust the microstructure of the material in the process, thereby control the corrosion and fatigue behavior. In the present study, conventional hot-rolled (HR) pure iron is compared to pure iron manufactured by electron beam melting (EBM). The microstructure, the corrosion behavior and the fatigue properties were studied comprehensively. The investigated sample conditions showed significant differences in the microstructures that led to changes in corrosion and fatigue properties. The EBM iron showed significantly lower fatigue strength compared to the HR iron. These different fatigue responses were observed under purely mechanical loading as well as with superimposed corrosion influence and are summarized in a model that describes the underlying failure mechanisms.</jats:p>}},
  author       = {{Wackenrohr, Steffen and Torrent, Christof Johannes Jaime and Herbst, Sebastian and Nürnberger, Florian and Krooss, Philipp and Ebbert, Christoph and Voigt, Markus and Grundmeier, Guido and Niendorf, Thomas and Maier, Hans Jürgen}},
  issn         = {{2397-2106}},
  journal      = {{npj Materials Degradation}},
  keywords     = {{Materials Chemistry, Materials Science (miscellaneous), Chemistry (miscellaneous), Ceramics and Composites}},
  number       = {{1}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{Corrosion fatigue behavior of electron beam melted iron in simulated body fluid}}},
  doi          = {{10.1038/s41529-022-00226-4}},
  volume       = {{6}},
  year         = {{2022}},
}

@article{30923,
  abstract     = {{<jats:p>Additive manufacturing (AM) processes are not solely used where maximum design freedom meets low lot sizes. Direct microstructure design and topology optimization can be realized concomitantly during processing by adjusting the geometry, the material composition, and the solidification behavior of the material considered. However, when complex specific requirements have to be met, a targeted part design is highly challenging. In the field of biodegradable implant surgery, a cytocompatible material of an application-adapted shape has to be characterized by a specific degradation behavior and reliably predictable mechanical properties. For instance, small amounts of oxides can have a significant effect on microstructural development, thus likewise affecting the strength and corrosion behavior of the processed material. In the present study, biocompatible pure Fe was processed using electron powder bed fusion (E-PBF). Two different modifications of the Fe were processed by incorporating Fe oxide and Ce oxide in different proportions in order to assess their impact on the microstructural evolution, the mechanical response and the corrosion behavior. The quasistatic mechanical and chemical properties were analyzed and correlated with the final microstructural appearance.</jats:p>}},
  author       = {{Torrent, Christof J. J. and Krooß, Philipp and Huang, Jingyuan and Voigt, Markus and Ebbert, Christoph and Knust, Steffen and Grundmeier, Guido and Niendorf, Thomas}},
  issn         = {{2674-063X}},
  journal      = {{Alloys}},
  number       = {{1}},
  pages        = {{31--53}},
  publisher    = {{MDPI AG}},
  title        = {{{Oxide Modified Iron in Electron Beam Powder Bed Fusion—From Processability to Corrosion Properties}}},
  doi          = {{10.3390/alloys1010004}},
  volume       = {{1}},
  year         = {{2022}},
}

@article{30738,
  author       = {{Xin, Yang and Piskunen, Petteri and Suma, Antonio and Li, Changyong and Ijäs, Heini and Ojasalo, Sofia and Seitz, Iris and Kostiainen, Mauri A. and Grundmeier, Guido and Linko, Veikko and Keller, Adrian}},
  issn         = {{1613-6810}},
  journal      = {{Small}},
  keywords     = {{Biomaterials, Biotechnology, General Materials Science, General Chemistry}},
  pages        = {{2107393}},
  publisher    = {{Wiley}},
  title        = {{{Environment‐Dependent Stability and Mechanical Properties of DNA Origami Six‐Helix Bundles with Different Crossover Spacings}}},
  doi          = {{10.1002/smll.202107393}},
  volume       = {{18}},
  year         = {{2022}},
}

@article{29806,
  author       = {{Huang, Jingyuan and Voigt, Markus and Wackenrohr, Steffen and Ebbert, Christoph and Keller, Adrian and Maier, Hans Jürgen and Grundmeier, Guido}},
  issn         = {{0947-5117}},
  journal      = {{Materials and Corrosion}},
  keywords     = {{Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, Mechanical Engineering, Mechanics of Materials, Environmental Chemistry, Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, Mechanical Engineering, Mechanics of Materials, Environmental Chemistry, Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, Mechanical Engineering, Mechanics of Materials, Environmental Chemistry}},
  pages        = {{1034}},
  publisher    = {{Wiley}},
  title        = {{{Influence of hydrogel coatings on corrosion and fatigue of iron in simulated body fluid}}},
  doi          = {{10.1002/maco.202112841}},
  volume       = {{73}},
  year         = {{2022}},
}

@article{32432,
  author       = {{Yang, Yu and Huang, Jingyuan and Dornbusch, Daniel and Grundmeier, Guido and Fahmy, Karim and Keller, Adrian and Cheung, David L.}},
  issn         = {{0743-7463}},
  journal      = {{Langmuir}},
  keywords     = {{Electrochemistry, Spectroscopy, Surfaces and Interfaces, Condensed Matter Physics, General Materials Science}},
  pages        = {{9257–9265}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Effect of Surface Hydrophobicity on the Adsorption of a Pilus-Derived Adhesin-like Peptide}}},
  doi          = {{10.1021/acs.langmuir.2c01016}},
  volume       = {{38}},
  year         = {{2022}},
}

@article{32589,
  abstract     = {{<jats:p>Guanidinium (Gdm) undergoes interactions with both hydrophilic and hydrophobic groups and, thus, is a highly potent denaturant of biomolecular structure. However, our molecular understanding of the interaction of Gdm with proteins and DNA is still rather limited. Here, we investigated the denaturation of DNA origami nanostructures by three Gdm salts, i.e., guanidinium chloride (GdmCl), guanidinium sulfate (Gdm2SO4), and guanidinium thiocyanate (GdmSCN), at different temperatures and in dependence of incubation time. Using DNA origami nanostructures as sensors that translate small molecular transitions into nanostructural changes, the denaturing effects of the Gdm salts were directly visualized by atomic force microscopy. GdmSCN was the most potent DNA denaturant, which caused complete DNA origami denaturation at 50 °C already at a concentration of 2 M. Under such harsh conditions, denaturation occurred within the first 15 min of Gdm exposure, whereas much slower kinetics were observed for the more weakly denaturing salt Gdm2SO4 at 25 °C. Lastly, we observed a novel non-monotonous temperature dependence of DNA origami denaturation in Gdm2SO4 with the fraction of intact nanostructures having an intermediate minimum at about 40 °C. Our results, thus, provide further insights into the highly complex Gdm–DNA interaction and underscore the importance of the counteranion species.</jats:p>}},
  author       = {{Hanke, Marcel and Hansen, Niklas and Tomm, Emilia and Grundmeier, Guido and Keller, Adrian}},
  issn         = {{1422-0067}},
  journal      = {{International Journal of Molecular Sciences}},
  keywords     = {{Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Computer Science Applications, Spectroscopy, Molecular Biology, General Medicine, Catalysis}},
  number       = {{15}},
  pages        = {{8547}},
  publisher    = {{MDPI AG}},
  title        = {{{Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate}}},
  doi          = {{10.3390/ijms23158547}},
  volume       = {{23}},
  year         = {{2022}},
}

@article{34099,
  abstract     = {{<jats:p>Using a unique combination of advanced characterization techniques, we identify specific degradation mechanisms and quantify degradative species formed during fast charge cycling of lithium-ion battery pouch cells.</jats:p>}},
  author       = {{McShane, Eric J. and Paul, Partha P. and Tanim, Tanvir R. and Cao, Chuntian and Steinrück, Hans-Georg and Thampy, Vivek and Trask, Stephen E. and Dunlop, Alison R. and Jansen, Andrew N. and Dufek, Eric J. and Toney, Michael F. and Weker, Johanna Nelson and McCloskey, Bryan D.}},
  issn         = {{2050-7488}},
  journal      = {{Journal of Materials Chemistry A}},
  keywords     = {{General Materials Science, Renewable Energy, Sustainability and the Environment, General Chemistry}},
  number       = {{44}},
  pages        = {{23927--23939}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Multimodal quantification of degradation pathways during extreme fast charging of lithium-ion batteries}}},
  doi          = {{10.1039/d2ta05887a}},
  volume       = {{10}},
  year         = {{2022}},
}

@article{34098,
  author       = {{Yusuf, Maha and LaManna, Jacob M. and Paul, Partha P. and Agyeman-Budu, David N. and Cao, Chuntian and Dunlop, Alison R. and Jansen, Andrew N. and Polzin, Bryant J. and Trask, Stephen E. and Tanim, Tanvir R. and Dufek, Eric J. and Thampy, Vivek and Steinrück, Hans-Georg and Toney, Michael F. and Nelson Weker, Johanna}},
  issn         = {{2666-3864}},
  journal      = {{Cell Reports Physical Science}},
  keywords     = {{General Physics and Astronomy, General Energy, General Engineering, General Materials Science, General Chemistry}},
  number       = {{11}},
  pages        = {{101145}},
  publisher    = {{Elsevier BV}},
  title        = {{{Simultaneous neutron and X-ray tomography for visualization of graphite electrode degradation in fast-charged lithium-ion batteries}}},
  doi          = {{10.1016/j.xcrp.2022.101145}},
  volume       = {{3}},
  year         = {{2022}},
}

@article{33446,
  author       = {{Dreher, Yannik and Fichtler, Julius and Karfusehr, Christoph and Jahnke, Kevin and Xin, Yang and Keller, Adrian and Göpfrich, Kerstin}},
  issn         = {{0006-3495}},
  journal      = {{Biophysical Journal}},
  keywords     = {{Biophysics}},
  pages        = {{4840--4848}},
  publisher    = {{Elsevier BV}},
  title        = {{{Genotype-phenotype mapping with polyominos made from DNA origami tiles}}},
  doi          = {{10.1016/j.bpj.2022.09.006}},
  volume       = {{121}},
  year         = {{2022}},
}