[{"_id":"42017","user_id":"237","department":[{"_id":"314"}],"keyword":["Materials Chemistry","Inorganic Chemistry","Polymers and Plastics","Organic Chemistry"],"language":[{"iso":"eng"}],"type":"journal_article","publication":"Macromolecules","status":"public","date_updated":"2023-02-10T15:23:52Z","publisher":"American Chemical Society (ACS)","author":[{"last_name":"Kramer","full_name":"Kramer, Thomas","first_name":"Thomas"},{"full_name":"Schweins, Ralf","last_name":"Schweins","first_name":"Ralf"},{"last_name":"Huber","full_name":"Huber, Klaus","id":"237","first_name":"Klaus"}],"date_created":"2023-02-10T15:23:24Z","volume":38,"title":"Silsesquioxane Molecules and Polystyrene Chains as a Model System for Colloid−Polymer Mixtures in the Protein Limit","doi":"10.1021/ma048766x","publication_status":"published","publication_identifier":{"issn":["0024-9297","1520-5835"]},"issue":"1","year":"2005","citation":{"ama":"Kramer T, Schweins R, Huber K. Silsesquioxane Molecules and Polystyrene Chains as a Model System for Colloid−Polymer Mixtures in the Protein Limit. <i>Macromolecules</i>. 2005;38(1):151-159. doi:<a href=\"https://doi.org/10.1021/ma048766x\">10.1021/ma048766x</a>","ieee":"T. Kramer, R. Schweins, and K. Huber, “Silsesquioxane Molecules and Polystyrene Chains as a Model System for Colloid−Polymer Mixtures in the Protein Limit,” <i>Macromolecules</i>, vol. 38, no. 1, pp. 151–159, 2005, doi: <a href=\"https://doi.org/10.1021/ma048766x\">10.1021/ma048766x</a>.","chicago":"Kramer, Thomas, Ralf Schweins, and Klaus Huber. “Silsesquioxane Molecules and Polystyrene Chains as a Model System for Colloid−Polymer Mixtures in the Protein Limit.” <i>Macromolecules</i> 38, no. 1 (2005): 151–59. <a href=\"https://doi.org/10.1021/ma048766x\">https://doi.org/10.1021/ma048766x</a>.","apa":"Kramer, T., Schweins, R., &#38; Huber, K. (2005). Silsesquioxane Molecules and Polystyrene Chains as a Model System for Colloid−Polymer Mixtures in the Protein Limit. <i>Macromolecules</i>, <i>38</i>(1), 151–159. <a href=\"https://doi.org/10.1021/ma048766x\">https://doi.org/10.1021/ma048766x</a>","short":"T. Kramer, R. Schweins, K. Huber, Macromolecules 38 (2005) 151–159.","mla":"Kramer, Thomas, et al. “Silsesquioxane Molecules and Polystyrene Chains as a Model System for Colloid−Polymer Mixtures in the Protein Limit.” <i>Macromolecules</i>, vol. 38, no. 1, American Chemical Society (ACS), 2005, pp. 151–59, doi:<a href=\"https://doi.org/10.1021/ma048766x\">10.1021/ma048766x</a>.","bibtex":"@article{Kramer_Schweins_Huber_2005, title={Silsesquioxane Molecules and Polystyrene Chains as a Model System for Colloid−Polymer Mixtures in the Protein Limit}, volume={38}, DOI={<a href=\"https://doi.org/10.1021/ma048766x\">10.1021/ma048766x</a>}, number={1}, journal={Macromolecules}, publisher={American Chemical Society (ACS)}, author={Kramer, Thomas and Schweins, Ralf and Huber, Klaus}, year={2005}, pages={151–159} }"},"intvolume":"        38","page":"151-159"},{"language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Inorganic Chemistry","Polymers and Plastics","Organic Chemistry"],"department":[{"_id":"314"}],"user_id":"237","_id":"42014","status":"public","publication":"Macromolecules","type":"journal_article","doi":"10.1021/ma051308j","title":"Coil Dimensions of Polystyrene Chains in Colloid−Polymer Mixtures at the Protein Limit:  A SANS Study","volume":38,"author":[{"first_name":"Thomas","last_name":"Kramer","full_name":"Kramer, Thomas"},{"first_name":"Ralf","full_name":"Schweins, Ralf","last_name":"Schweins"},{"last_name":"Huber","id":"237","full_name":"Huber, Klaus","first_name":"Klaus"}],"date_created":"2023-02-10T15:20:44Z","publisher":"American Chemical Society (ACS)","date_updated":"2023-02-10T15:21:03Z","intvolume":"        38","page":"9783-9793","citation":{"ama":"Kramer T, Schweins R, Huber K. Coil Dimensions of Polystyrene Chains in Colloid−Polymer Mixtures at the Protein Limit:  A SANS Study. <i>Macromolecules</i>. 2005;38(23):9783-9793. doi:<a href=\"https://doi.org/10.1021/ma051308j\">10.1021/ma051308j</a>","ieee":"T. Kramer, R. Schweins, and K. Huber, “Coil Dimensions of Polystyrene Chains in Colloid−Polymer Mixtures at the Protein Limit:  A SANS Study,” <i>Macromolecules</i>, vol. 38, no. 23, pp. 9783–9793, 2005, doi: <a href=\"https://doi.org/10.1021/ma051308j\">10.1021/ma051308j</a>.","chicago":"Kramer, Thomas, Ralf Schweins, and Klaus Huber. “Coil Dimensions of Polystyrene Chains in Colloid−Polymer Mixtures at the Protein Limit:  A SANS Study.” <i>Macromolecules</i> 38, no. 23 (2005): 9783–93. <a href=\"https://doi.org/10.1021/ma051308j\">https://doi.org/10.1021/ma051308j</a>.","apa":"Kramer, T., Schweins, R., &#38; Huber, K. (2005). Coil Dimensions of Polystyrene Chains in Colloid−Polymer Mixtures at the Protein Limit:  A SANS Study. <i>Macromolecules</i>, <i>38</i>(23), 9783–9793. <a href=\"https://doi.org/10.1021/ma051308j\">https://doi.org/10.1021/ma051308j</a>","mla":"Kramer, Thomas, et al. “Coil Dimensions of Polystyrene Chains in Colloid−Polymer Mixtures at the Protein Limit:  A SANS Study.” <i>Macromolecules</i>, vol. 38, no. 23, American Chemical Society (ACS), 2005, pp. 9783–93, doi:<a href=\"https://doi.org/10.1021/ma051308j\">10.1021/ma051308j</a>.","short":"T. Kramer, R. Schweins, K. Huber, Macromolecules 38 (2005) 9783–9793.","bibtex":"@article{Kramer_Schweins_Huber_2005, title={Coil Dimensions of Polystyrene Chains in Colloid−Polymer Mixtures at the Protein Limit:  A SANS Study}, volume={38}, DOI={<a href=\"https://doi.org/10.1021/ma051308j\">10.1021/ma051308j</a>}, number={23}, journal={Macromolecules}, publisher={American Chemical Society (ACS)}, author={Kramer, Thomas and Schweins, Ralf and Huber, Klaus}, year={2005}, pages={9783–9793} }"},"year":"2005","issue":"23","publication_identifier":{"issn":["0024-9297","1520-5835"]},"publication_status":"published"},{"citation":{"short":"M. Tiemann, Ö. Weiß, J. Hartikainen, F. Marlow, M. Lindén, ChemPhysChem (2005) 2113–2119.","bibtex":"@article{Tiemann_Weiß_Hartikainen_Marlow_Lindén_2005, title={Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy}, DOI={<a href=\"https://doi.org/10.1002/cphc.200500163\">10.1002/cphc.200500163</a>}, journal={ChemPhysChem}, author={Tiemann, Michael and Weiß, Özlem and Hartikainen, Juha and Marlow, Frank and Lindén, Mika}, year={2005}, pages={2113–2119} }","mla":"Tiemann, Michael, et al. “Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy.” <i>ChemPhysChem</i>, 2005, pp. 2113–19, doi:<a href=\"https://doi.org/10.1002/cphc.200500163\">10.1002/cphc.200500163</a>.","apa":"Tiemann, M., Weiß, Ö., Hartikainen, J., Marlow, F., &#38; Lindén, M. (2005). Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy. <i>ChemPhysChem</i>, 2113–2119. <a href=\"https://doi.org/10.1002/cphc.200500163\">https://doi.org/10.1002/cphc.200500163</a>","ieee":"M. Tiemann, Ö. Weiß, J. Hartikainen, F. Marlow, and M. Lindén, “Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy,” <i>ChemPhysChem</i>, pp. 2113–2119, 2005, doi: <a href=\"https://doi.org/10.1002/cphc.200500163\">10.1002/cphc.200500163</a>.","chicago":"Tiemann, Michael, Özlem Weiß, Juha Hartikainen, Frank Marlow, and Mika Lindén. “Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy.” <i>ChemPhysChem</i>, 2005, 2113–19. <a href=\"https://doi.org/10.1002/cphc.200500163\">https://doi.org/10.1002/cphc.200500163</a>.","ama":"Tiemann M, Weiß Ö, Hartikainen J, Marlow F, Lindén M. Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy. <i>ChemPhysChem</i>. Published online 2005:2113-2119. doi:<a href=\"https://doi.org/10.1002/cphc.200500163\">10.1002/cphc.200500163</a>"},"page":"2113-2119","year":"2005","publication_status":"published","quality_controlled":"1","publication_identifier":{"issn":["1439-4235","1439-7641"]},"doi":"10.1002/cphc.200500163","title":"Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy","date_created":"2021-10-09T09:48:34Z","author":[{"full_name":"Tiemann, Michael","id":"23547","orcid":"0000-0003-1711-2722","last_name":"Tiemann","first_name":"Michael"},{"first_name":"Özlem","full_name":"Weiß, Özlem","last_name":"Weiß"},{"first_name":"Juha","last_name":"Hartikainen","full_name":"Hartikainen, Juha"},{"last_name":"Marlow","full_name":"Marlow, Frank","first_name":"Frank"},{"last_name":"Lindén","full_name":"Lindén, Mika","first_name":"Mika"}],"date_updated":"2023-03-09T08:58:26Z","status":"public","abstract":[{"lang":"eng","text":"The early stages of ZnS nanoparticle growth from supersaturated solution are investigated in situ by stopped-flow UV absorption spectroscopy with a time resolution of 1.28 ms. A model for data analysis is suggested which makes it possible to study both the average particle radius and the concentration. The average radii lie in the sub-nanometer range. During the first 40 ms, growth is predominantly governed by ripening."}],"type":"journal_article","publication":"ChemPhysChem","language":[{"iso":"eng"}],"extern":"1","article_type":"original","user_id":"23547","department":[{"_id":"35"},{"_id":"2"},{"_id":"307"}],"_id":"25995"},{"date_updated":"2023-03-09T08:58:46Z","date_created":"2021-10-09T09:47:51Z","author":[{"first_name":"Jan","last_name":"Roggenbuck","full_name":"Roggenbuck, Jan"},{"first_name":"Michael","last_name":"Tiemann","orcid":"0000-0003-1711-2722","id":"23547","full_name":"Tiemann, Michael"}],"title":"Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon","doi":"10.1021/ja043605u","publication_identifier":{"issn":["0002-7863","1520-5126"]},"quality_controlled":"1","publication_status":"published","year":"2005","page":"1096-1097","citation":{"short":"J. Roggenbuck, M. Tiemann, Journal of the American Chemical Society (2005) 1096–1097.","bibtex":"@article{Roggenbuck_Tiemann_2005, title={Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon}, DOI={<a href=\"https://doi.org/10.1021/ja043605u\">10.1021/ja043605u</a>}, journal={Journal of the American Chemical Society}, author={Roggenbuck, Jan and Tiemann, Michael}, year={2005}, pages={1096–1097} }","mla":"Roggenbuck, Jan, and Michael Tiemann. “Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon.” <i>Journal of the American Chemical Society</i>, 2005, pp. 1096–97, doi:<a href=\"https://doi.org/10.1021/ja043605u\">10.1021/ja043605u</a>.","apa":"Roggenbuck, J., &#38; Tiemann, M. (2005). Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon. <i>Journal of the American Chemical Society</i>, 1096–1097. <a href=\"https://doi.org/10.1021/ja043605u\">https://doi.org/10.1021/ja043605u</a>","ama":"Roggenbuck J, Tiemann M. Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon. <i>Journal of the American Chemical Society</i>. Published online 2005:1096-1097. doi:<a href=\"https://doi.org/10.1021/ja043605u\">10.1021/ja043605u</a>","chicago":"Roggenbuck, Jan, and Michael Tiemann. “Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon.” <i>Journal of the American Chemical Society</i>, 2005, 1096–97. <a href=\"https://doi.org/10.1021/ja043605u\">https://doi.org/10.1021/ja043605u</a>.","ieee":"J. Roggenbuck and M. Tiemann, “Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon,” <i>Journal of the American Chemical Society</i>, pp. 1096–1097, 2005, doi: <a href=\"https://doi.org/10.1021/ja043605u\">10.1021/ja043605u</a>."},"_id":"25994","department":[{"_id":"35"},{"_id":"2"},{"_id":"307"}],"user_id":"23547","article_type":"original","extern":"1","language":[{"iso":"eng"}],"publication":"Journal of the American Chemical Society","type":"journal_article","abstract":[{"text":"Periodically ordered mesoporous magnesium oxides were synthesized by utilization of mesoporous CMK-3 carbon as exotemplate. The products exhibit high thermal stability and basic properties, which makes them promising for application in heterogeneous basic catalysis.","lang":"eng"}],"status":"public"},{"language":[{"iso":"eng"}],"_id":"58598","user_id":"495","department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>A series of bis‐guanidine ligands designed for use in biomimetic coordination chemistry has been extended to a library matrix combining unprecedented substitutional flexibility within the guanidyl residues with a wide range of aliphatic and aromatic spacers connecting these functionalities. The underlying protocol can be used with predefined ureas as well as secondary amines to build up these units by reaction with phosgene if the ureas are otherwise unavailable. In the latter case, the resulting urea intermediates do not have to be isolated as the reaction proceeds further with additional phosgene to yield a chloroformamidinium chloride which is transformed into the bis‐guanidine functionality by subsequent reaction with a suitable primary diamine in the presence of triethylamine as an auxiliary base. This concept has been used to synthesise and characterise more then two dozen different bis‐guanidines based on 12 discrete monoguanidine units and seven different spacers. These spacers have been chosen such that the most important phenotypes have been dealt with and which range from rigid to more flexible scaffolds. In addition to spacers with no metal‐binding capabilities, other species containing further donor functions such as <jats:italic>N</jats:italic>‐methyldiphenyleneamine or pyridine‐2,6‐diyl have also been used. The substitution patterns of the guanidine residues can be classified into acyclic and cyclic types. Among the cyclic types, one subset is characterised by five‐ or six‐membered heterocycles containing both the amino nitrogen atoms and another one by individual N‐heterocyclic systems for each amino nitrogen. Structurally characterised examples are 2‐{2‐[2‐(tetramethylguanidi­no)ethoxy]ethoxy}‐1‐(tetramethylguanidino)ethane (TMG<jats:sub>2</jats:sub>doo) in its diprotonated form and 2,2′‐bis[2<jats:italic>N</jats:italic>‐(1,1′,3,3′‐tetramethylguanidine)]diphenyleneamine (TMG<jats:sub>2</jats:sub>PA) as wellas <jats:italic>N</jats:italic><jats:sup>1</jats:sup>,<jats:italic>N</jats:italic><jats:sup>3</jats:sup>‐bis(dimorpholinomethylene)propane‐1,3‐diamine (DMorphG<jats:sub>2</jats:sub>p) as free bases. For the permethylated bis‐guanidine derivatives, the barrier to rotation around the (C=N)<jats:sub>guanidine</jats:sub> bond has been determined by means of temperature‐dependent EXSY <jats:sup>1</jats:sup>H NMR spectroscopy to range between 54 and 79 kJ mol<jats:sup>–1</jats:sup> depending on the type of spacer. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2005)</jats:p>"}],"status":"public","type":"journal_article","publication":"European Journal of Organic Chemistry","title":"A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry","doi":"10.1002/ejoc.200500340","date_updated":"2025-02-12T09:30:43Z","publisher":"Wiley","author":[{"first_name":"Sonja","full_name":"Herres‐Pawlis, Sonja","last_name":"Herres‐Pawlis"},{"first_name":"Adam","full_name":"Neuba, Adam","last_name":"Neuba"},{"last_name":"Seewald","full_name":"Seewald, Oliver","id":"495","first_name":"Oliver"},{"full_name":"Seshadri, Tarimala","last_name":"Seshadri","first_name":"Tarimala"},{"first_name":"Hans","last_name":"Egold","full_name":"Egold, Hans"},{"first_name":"Ulrich","full_name":"Flörke, Ulrich","last_name":"Flörke"},{"first_name":"Gerald","full_name":"Henkel, Gerald","last_name":"Henkel"}],"date_created":"2025-02-12T09:27:00Z","volume":2005,"year":"2005","citation":{"apa":"Herres‐Pawlis, S., Neuba, A., Seewald, O., Seshadri, T., Egold, H., Flörke, U., &#38; Henkel, G. (2005). A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry. <i>European Journal of Organic Chemistry</i>, <i>2005</i>(22), 4879–4890. <a href=\"https://doi.org/10.1002/ejoc.200500340\">https://doi.org/10.1002/ejoc.200500340</a>","short":"S. Herres‐Pawlis, A. Neuba, O. Seewald, T. Seshadri, H. Egold, U. Flörke, G. Henkel, European Journal of Organic Chemistry 2005 (2005) 4879–4890.","mla":"Herres‐Pawlis, Sonja, et al. “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry.” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 22, Wiley, 2005, pp. 4879–90, doi:<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>.","bibtex":"@article{Herres‐Pawlis_Neuba_Seewald_Seshadri_Egold_Flörke_Henkel_2005, title={A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry}, volume={2005}, DOI={<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>}, number={22}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Herres‐Pawlis, Sonja and Neuba, Adam and Seewald, Oliver and Seshadri, Tarimala and Egold, Hans and Flörke, Ulrich and Henkel, Gerald}, year={2005}, pages={4879–4890} }","chicago":"Herres‐Pawlis, Sonja, Adam Neuba, Oliver Seewald, Tarimala Seshadri, Hans Egold, Ulrich Flörke, and Gerald Henkel. “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry.” <i>European Journal of Organic Chemistry</i> 2005, no. 22 (2005): 4879–90. <a href=\"https://doi.org/10.1002/ejoc.200500340\">https://doi.org/10.1002/ejoc.200500340</a>.","ieee":"S. Herres‐Pawlis <i>et al.</i>, “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry,” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 22, pp. 4879–4890, 2005, doi: <a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>.","ama":"Herres‐Pawlis S, Neuba A, Seewald O, et al. A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry. <i>European Journal of Organic Chemistry</i>. 2005;2005(22):4879-4890. doi:<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>"},"intvolume":"      2005","page":"4879-4890","publication_status":"published","publication_identifier":{"issn":["1434-193X","1099-0690"]},"issue":"22"},{"language":[{"iso":"eng"}],"abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p><jats:bold>Syntheses and Structure of Chiral Metallatetrahedron Complexes of the Type [Re<jats:sub>2</jats:sub>(M<jats:sup>1</jats:sup>PPh<jats:sub>3</jats:sub>)(M<jats:sup>2</jats:sup>PPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (M<jats:sup>1</jats:sup> = Ag, Au; M<jats:sup>2</jats:sup> = Cu, Ag, Au)</jats:bold></jats:p><jats:p>From the reaction of Li[Re<jats:sub>2</jats:sub>(μ‐H)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>(C(Ph)O)] (<jats:bold>1</jats:bold>) with Ph<jats:sub>3</jats:sub>AuC≡CPh both benzaldehyde and the trinuclear complex Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>2a</jats:bold>) were obtained in high yield. The complex anion was isolated as its PPh<jats:sub>4</jats:sub>‐salt <jats:bold>2b</jats:bold>. The latter reacts with coinage metal complexes PPh<jats:sub>3</jats:sub>M<jats:sup>2</jats:sup>Cl [M<jats:sup>2</jats:sup> = Cu, Ag, Au] to give chiral heterometallatetrahedranes of the general formula [Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(M<jats:sup>2</jats:sup>PPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (M<jats:sup>2</jats:sup> = Cu <jats:bold>3a</jats:bold>, Ag <jats:bold>3b</jats:bold>, Au <jats:bold>3c</jats:bold>). The corresponding complex [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>3d</jats:bold>) is obtained from the reaction of [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>4</jats:bold>) with LiC≡CPh. <jats:bold>3d</jats:bold> undergoes a metathesis reaction in the presence of PPh<jats:sub>3</jats:sub>CuCl giving [Re<jats:sub>2</jats:sub>(AgPPh<jats:sub>3</jats:sub>)(CuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>C≡CPh] (<jats:bold>3e</jats:bold>) and PPh<jats:sub>3</jats:sub>AgCl. Analogous metathesis reactions are observed when <jats:bold>3c</jats:bold> is reacted with PPh<jats:sub>3</jats:sub>AgCl or PPh<jats:sub>3</jats:sub>CuCl giving <jats:bold>3a</jats:bold> or <jats:bold>3b</jats:bold>, respectively. The reaction of <jats:bold>1</jats:bold> with PPh<jats:sub>3</jats:sub>AuCl gives benzaldehyde and Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>5a</jats:bold>) which upon reaction with PhLi forms the trinuclear complex Li[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Ph] (<jats:bold>6a</jats:bold>). Again this complex was isolated as its PPh<jats:sub>4</jats:sub>‐salt <jats:bold>6b</jats:bold>. In contrast to <jats:bold>2b</jats:bold>, <jats:bold>6b</jats:bold> reacts with one equivalent of Ph<jats:sub>3</jats:sub>PAuCl by transmetalation to give Ph<jats:sub>3</jats:sub>PAuPh and PPh<jats:sub>4</jats:sub>[Re<jats:sub>2</jats:sub>(AuPPh<jats:sub>3</jats:sub>)(μ‐PCy<jats:sub>2</jats:sub>)(CO)<jats:sub>7</jats:sub>Cl] (<jats:bold>5b</jats:bold>). The X‐ray structures of the compounds <jats:bold>3a</jats:bold>, <jats:bold>3b</jats:bold>, <jats:bold>3e</jats:bold> and <jats:bold>4</jats:bold> are reported.</jats:p>"}],"publication":"Zeitschrift für anorganische und allgemeine Chemie","title":"Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au)","publisher":"Wiley","date_created":"2025-02-12T09:26:12Z","year":"2005","issue":"2","_id":"58597","user_id":"495","department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"status":"public","type":"journal_article","doi":"10.1002/zaac.200500340","date_updated":"2025-02-12T09:30:52Z","author":[{"first_name":"Oliver","last_name":"Seewald","id":"495","full_name":"Seewald, Oliver"},{"first_name":"Ulrich","full_name":"Flörke, Ulrich","last_name":"Flörke"},{"first_name":"Hans","full_name":"Egold, Hans","last_name":"Egold"},{"last_name":"Haupt","full_name":"Haupt, Hans‐Jürgen","first_name":"Hans‐Jürgen"},{"first_name":"Meinhard","last_name":"Schwefer","full_name":"Schwefer, Meinhard"}],"volume":632,"citation":{"bibtex":"@article{Seewald_Flörke_Egold_Haupt_Schwefer_2005, title={Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au)}, volume={632}, DOI={<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>}, number={2}, journal={Zeitschrift für anorganische und allgemeine Chemie}, publisher={Wiley}, author={Seewald, Oliver and Flörke, Ulrich and Egold, Hans and Haupt, Hans‐Jürgen and Schwefer, Meinhard}, year={2005}, pages={204–210} }","mla":"Seewald, Oliver, et al. “Synthese Und Struktur Chiraler Heterometallatetrahedrane Des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(Μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au).” <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i>, vol. 632, no. 2, Wiley, 2005, pp. 204–10, doi:<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>.","short":"O. Seewald, U. Flörke, H. Egold, H. Haupt, M. Schwefer, Zeitschrift Für Anorganische Und Allgemeine Chemie 632 (2005) 204–210.","apa":"Seewald, O., Flörke, U., Egold, H., Haupt, H., &#38; Schwefer, M. (2005). Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au). <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i>, <i>632</i>(2), 204–210. <a href=\"https://doi.org/10.1002/zaac.200500340\">https://doi.org/10.1002/zaac.200500340</a>","ama":"Seewald O, Flörke U, Egold H, Haupt H, Schwefer M. Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au). <i>Zeitschrift für anorganische und allgemeine Chemie</i>. 2005;632(2):204-210. doi:<a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>","chicago":"Seewald, Oliver, Ulrich Flörke, Hans Egold, Hans‐Jürgen Haupt, and Meinhard Schwefer. “Synthese Und Struktur Chiraler Heterometallatetrahedrane Des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(Μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au).” <i>Zeitschrift Für Anorganische Und Allgemeine Chemie</i> 632, no. 2 (2005): 204–10. <a href=\"https://doi.org/10.1002/zaac.200500340\">https://doi.org/10.1002/zaac.200500340</a>.","ieee":"O. Seewald, U. Flörke, H. Egold, H. Haupt, and M. Schwefer, “Synthese und Struktur chiraler Heterometallatetrahedrane des Typs [Re<sub>2</sub>(M<sup>1</sup>PPh<sub>3</sub>)(M<sup>2</sup>PPh<sub>3</sub>)(μ‐PCy<sub>2</sub>)(CO)<sub>7</sub>C≡CPh] (M<sup>1</sup> = Ag, Au; M<sup>2</sup> = Cu, Ag, Au),” <i>Zeitschrift für anorganische und allgemeine Chemie</i>, vol. 632, no. 2, pp. 204–210, 2005, doi: <a href=\"https://doi.org/10.1002/zaac.200500340\">10.1002/zaac.200500340</a>."},"page":"204-210","intvolume":"       632","publication_status":"published","publication_identifier":{"issn":["0044-2313","1521-3749"]}},{"issue":"4","quality_controlled":"1","publication_identifier":{"issn":["0148-6055","1520-8516"]},"publication_status":"published","page":"881-894","intvolume":"        48","citation":{"ama":"Cormier RJ, Schmidt C, Callaghan PT. Director reorientation of a side-chain liquid crystalline polymer under extensional flow. <i>Journal of Rheology</i>. 2004;48(4):881-894. doi:<a href=\"https://doi.org/10.1122/1.1753278\">10.1122/1.1753278</a>","ieee":"R. J. Cormier, C. Schmidt, and P. T. Callaghan, “Director reorientation of a side-chain liquid crystalline polymer under extensional flow,” <i>Journal of Rheology</i>, vol. 48, no. 4, pp. 881–894, 2004, doi: <a href=\"https://doi.org/10.1122/1.1753278\">10.1122/1.1753278</a>.","chicago":"Cormier, Ryan J., Claudia Schmidt, and Paul T. Callaghan. “Director Reorientation of a Side-Chain Liquid Crystalline Polymer under Extensional Flow.” <i>Journal of Rheology</i> 48, no. 4 (2004): 881–94. <a href=\"https://doi.org/10.1122/1.1753278\">https://doi.org/10.1122/1.1753278</a>.","bibtex":"@article{Cormier_Schmidt_Callaghan_2004, title={Director reorientation of a side-chain liquid crystalline polymer under extensional flow}, volume={48}, DOI={<a href=\"https://doi.org/10.1122/1.1753278\">10.1122/1.1753278</a>}, number={4}, journal={Journal of Rheology}, publisher={Society of Rheology}, author={Cormier, Ryan J. and Schmidt, Claudia and Callaghan, Paul T.}, year={2004}, pages={881–894} }","short":"R.J. Cormier, C. Schmidt, P.T. Callaghan, Journal of Rheology 48 (2004) 881–894.","mla":"Cormier, Ryan J., et al. “Director Reorientation of a Side-Chain Liquid Crystalline Polymer under Extensional Flow.” <i>Journal of Rheology</i>, vol. 48, no. 4, Society of Rheology, 2004, pp. 881–94, doi:<a href=\"https://doi.org/10.1122/1.1753278\">10.1122/1.1753278</a>.","apa":"Cormier, R. J., Schmidt, C., &#38; Callaghan, P. T. (2004). Director reorientation of a side-chain liquid crystalline polymer under extensional flow. <i>Journal of Rheology</i>, <i>48</i>(4), 881–894. <a href=\"https://doi.org/10.1122/1.1753278\">https://doi.org/10.1122/1.1753278</a>"},"year":"2004","volume":48,"author":[{"last_name":"Cormier","full_name":"Cormier, Ryan J.","first_name":"Ryan J."},{"first_name":"Claudia","orcid":"0000-0003-3179-9997","last_name":"Schmidt","full_name":"Schmidt, Claudia","id":"466"},{"first_name":"Paul T.","last_name":"Callaghan","full_name":"Callaghan, Paul T."}],"date_created":"2023-01-06T13:15:08Z","publisher":"Society of Rheology","date_updated":"2023-01-07T11:23:31Z","doi":"10.1122/1.1753278","title":"Director reorientation of a side-chain liquid crystalline polymer under extensional flow","publication":"Journal of Rheology","type":"journal_article","status":"public","department":[{"_id":"2"},{"_id":"315"}],"user_id":"466","_id":"35359","language":[{"iso":"eng"}],"keyword":["Mechanical Engineering","Mechanics of Materials","Condensed Matter Physics","General Materials Science"],"article_type":"original"},{"doi":"10.1080/02678290310001628555","author":[{"first_name":"C.","last_name":"Stubenrauch","full_name":"Stubenrauch, C."},{"first_name":"S.","full_name":"Burauer, S.","last_name":"Burauer"},{"first_name":"R.","full_name":"Strey, R.","last_name":"Strey"},{"last_name":"Schmidt","orcid":"0000-0003-3179-9997","id":"466","full_name":"Schmidt, Claudia","first_name":"Claudia"}],"volume":31,"date_updated":"2023-01-07T11:23:00Z","citation":{"bibtex":"@article{Stubenrauch_Burauer_Strey_Schmidt_2004, title={A new approach to lamellar phases (L<sub>α</sub>) in water – non-ionic surfactant systems}, volume={31}, DOI={<a href=\"https://doi.org/10.1080/02678290310001628555\">10.1080/02678290310001628555</a>}, number={1}, journal={Liquid Crystals}, publisher={Informa UK Limited}, author={Stubenrauch, C. and Burauer, S. and Strey, R. and Schmidt, Claudia}, year={2004}, pages={39–53} }","short":"C. Stubenrauch, S. Burauer, R. Strey, C. Schmidt, Liquid Crystals 31 (2004) 39–53.","mla":"Stubenrauch, C., et al. “A New Approach to Lamellar Phases (L<sub>α</sub>) in Water – Non-Ionic Surfactant Systems.” <i>Liquid Crystals</i>, vol. 31, no. 1, Informa UK Limited, 2004, pp. 39–53, doi:<a href=\"https://doi.org/10.1080/02678290310001628555\">10.1080/02678290310001628555</a>.","apa":"Stubenrauch, C., Burauer, S., Strey, R., &#38; Schmidt, C. (2004). A new approach to lamellar phases (L<sub>α</sub>) in water – non-ionic surfactant systems. <i>Liquid Crystals</i>, <i>31</i>(1), 39–53. <a href=\"https://doi.org/10.1080/02678290310001628555\">https://doi.org/10.1080/02678290310001628555</a>","ama":"Stubenrauch C, Burauer S, Strey R, Schmidt C. A new approach to lamellar phases (L<sub>α</sub>) in water – non-ionic surfactant systems. <i>Liquid Crystals</i>. 2004;31(1):39-53. doi:<a href=\"https://doi.org/10.1080/02678290310001628555\">10.1080/02678290310001628555</a>","ieee":"C. Stubenrauch, S. Burauer, R. Strey, and C. Schmidt, “A new approach to lamellar phases (L<sub>α</sub>) in water – non-ionic surfactant systems,” <i>Liquid Crystals</i>, vol. 31, no. 1, pp. 39–53, 2004, doi: <a href=\"https://doi.org/10.1080/02678290310001628555\">10.1080/02678290310001628555</a>.","chicago":"Stubenrauch, C., S. Burauer, R. Strey, and Claudia Schmidt. “A New Approach to Lamellar Phases (L<sub>α</sub>) in Water – Non-Ionic Surfactant Systems.” <i>Liquid Crystals</i> 31, no. 1 (2004): 39–53. <a href=\"https://doi.org/10.1080/02678290310001628555\">https://doi.org/10.1080/02678290310001628555</a>."},"intvolume":"        31","page":"39-53","publication_status":"published","publication_identifier":{"issn":["0267-8292","1366-5855"]},"article_type":"original","user_id":"466","department":[{"_id":"2"},{"_id":"315"}],"_id":"35358","status":"public","type":"journal_article","title":"A new approach to lamellar phases (L<sub>α</sub>) in water – non-ionic surfactant systems","date_created":"2023-01-06T13:14:53Z","publisher":"Informa UK Limited","year":"2004","issue":"1","quality_controlled":"1","language":[{"iso":"eng"}],"keyword":["Condensed Matter Physics","General Materials Science","General Chemistry"],"publication":"Liquid Crystals"},{"author":[{"last_name":"Hinderling","full_name":"Hinderling, C.","first_name":"C."},{"first_name":"Y.","full_name":"Keles, Y.","last_name":"Keles"},{"first_name":"T.","last_name":"Stöckli","full_name":"Stöckli, T."},{"first_name":"H. F.","full_name":"Knapp, H. F.","last_name":"Knapp"},{"last_name":"de los Arcos de Pedro","id":"54556","full_name":"de los Arcos de Pedro, Maria Teresa","first_name":"Maria Teresa"},{"first_name":"P.","full_name":"Oelhafen, P.","last_name":"Oelhafen"},{"last_name":"Korczagin","full_name":"Korczagin, I.","first_name":"I."},{"first_name":"M. A.","full_name":"Hempenius, M. A.","last_name":"Hempenius"},{"first_name":"G. J.","last_name":"Vancso","full_name":"Vancso, G. J."},{"last_name":"Pugin","full_name":"Pugin, R.","first_name":"R."},{"last_name":"Heinzelmann","full_name":"Heinzelmann, H.","first_name":"H."}],"date_created":"2021-07-07T11:40:38Z","date_updated":"2023-01-24T08:29:17Z","doi":"10.1002/adma.200306447","title":"Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth","publication_identifier":{"issn":["0935-9648","1521-4095"]},"publication_status":"published","page":"876-879","citation":{"ieee":"C. Hinderling <i>et al.</i>, “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth,” <i>Advanced Materials</i>, pp. 876–879, 2004, doi: <a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>.","chicago":"Hinderling, C., Y. Keles, T. Stöckli, H. F. Knapp, Maria Teresa de los Arcos de Pedro, P. Oelhafen, I. Korczagin, et al. “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth.” <i>Advanced Materials</i>, 2004, 876–79. <a href=\"https://doi.org/10.1002/adma.200306447\">https://doi.org/10.1002/adma.200306447</a>.","ama":"Hinderling C, Keles Y, Stöckli T, et al. Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth. <i>Advanced Materials</i>. Published online 2004:876-879. doi:<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>","apa":"Hinderling, C., Keles, Y., Stöckli, T., Knapp, H. F., de los Arcos de Pedro, M. T., Oelhafen, P., Korczagin, I., Hempenius, M. A., Vancso, G. J., Pugin, R., &#38; Heinzelmann, H. (2004). Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth. <i>Advanced Materials</i>, 876–879. <a href=\"https://doi.org/10.1002/adma.200306447\">https://doi.org/10.1002/adma.200306447</a>","mla":"Hinderling, C., et al. “Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth.” <i>Advanced Materials</i>, 2004, pp. 876–79, doi:<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>.","bibtex":"@article{Hinderling_Keles_Stöckli_Knapp_de los Arcos de Pedro_Oelhafen_Korczagin_Hempenius_Vancso_Pugin_et al._2004, title={Organometallic Block Copolymers as Catalyst Precursors for Templated Carbon Nanotube Growth}, DOI={<a href=\"https://doi.org/10.1002/adma.200306447\">10.1002/adma.200306447</a>}, journal={Advanced Materials}, author={Hinderling, C. and Keles, Y. and Stöckli, T. and Knapp, H. F. and de los Arcos de Pedro, Maria Teresa and Oelhafen, P. and Korczagin, I. and Hempenius, M. A. and Vancso, G. J. and Pugin, R. and et al.}, year={2004}, pages={876–879} }","short":"C. Hinderling, Y. Keles, T. Stöckli, H.F. Knapp, M.T. de los Arcos de Pedro, P. Oelhafen, I. Korczagin, M.A. Hempenius, G.J. Vancso, R. Pugin, H. Heinzelmann, Advanced Materials (2004) 876–879."},"year":"2004","department":[{"_id":"302"}],"user_id":"54556","_id":"22616","language":[{"iso":"eng"}],"extern":"1","publication":"Advanced Materials","type":"journal_article","status":"public"},{"status":"public","type":"journal_article","publication":"The Journal of Physical Chemistry B","extern":"1","language":[{"iso":"eng"}],"_id":"22615","user_id":"54556","department":[{"_id":"302"}],"year":"2004","citation":{"ama":"de los Arcos de Pedro MT, Garnier MG, Seo JW, Oelhafen P, Thommen V, Mathys D. The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth. <i>The Journal of Physical Chemistry B</i>. Published online 2004:7728-7734. doi:<a href=\"https://doi.org/10.1021/jp049495v\">10.1021/jp049495v</a>","chicago":"Arcos de Pedro, Maria Teresa de los, Michael Gunnar Garnier, Jin Won Seo, Peter Oelhafen, Verena Thommen, and Daniel Mathys. “The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth.” <i>The Journal of Physical Chemistry B</i>, 2004, 7728–34. <a href=\"https://doi.org/10.1021/jp049495v\">https://doi.org/10.1021/jp049495v</a>.","ieee":"M. T. de los Arcos de Pedro, M. G. Garnier, J. W. Seo, P. Oelhafen, V. Thommen, and D. Mathys, “The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth,” <i>The Journal of Physical Chemistry B</i>, pp. 7728–7734, 2004, doi: <a href=\"https://doi.org/10.1021/jp049495v\">10.1021/jp049495v</a>.","short":"M.T. de los Arcos de Pedro, M.G. Garnier, J.W. Seo, P. Oelhafen, V. Thommen, D. Mathys, The Journal of Physical Chemistry B (2004) 7728–7734.","mla":"de los Arcos de Pedro, Maria Teresa, et al. “The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth.” <i>The Journal of Physical Chemistry B</i>, 2004, pp. 7728–34, doi:<a href=\"https://doi.org/10.1021/jp049495v\">10.1021/jp049495v</a>.","bibtex":"@article{de los Arcos de Pedro_Garnier_Seo_Oelhafen_Thommen_Mathys_2004, title={The Influence of Catalyst Chemical State and Morphology on Carbon Nanotube Growth}, DOI={<a href=\"https://doi.org/10.1021/jp049495v\">10.1021/jp049495v</a>}, journal={The Journal of Physical Chemistry B}, author={de los Arcos de Pedro, Maria Teresa and Garnier, Michael Gunnar and Seo, Jin Won and Oelhafen, Peter and Thommen, Verena and Mathys, Daniel}, year={2004}, pages={7728–7734} }","apa":"de los Arcos de Pedro, M. T., Garnier, M. G., Seo, J. W., Oelhafen, P., Thommen, V., &#38; Mathys, D. (2004). 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