[{"type":"journal_article","publication":"Nature Chemistry","status":"public","_id":"47589","user_id":"53339","department":[{"_id":"2"},{"_id":"389"}],"keyword":["General Chemical Engineering","General Chemistry"],"language":[{"iso":"eng"}],"publication_status":"published","publication_identifier":{"issn":["1755-4330","1755-4349"]},"year":"2023","citation":{"bibtex":"@article{Krämer_Paradies_Fernández_Breher_2023, title={A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media}, DOI={<a href=\"https://doi.org/10.1038/s41557-023-01340-9\">10.1038/s41557-023-01340-9</a>}, journal={Nature Chemistry}, publisher={Springer Science and Business Media LLC}, author={Krämer, Felix and Paradies, Jan and Fernández, Israel and Breher, Frank}, year={2023} }","short":"F. Krämer, J. Paradies, I. Fernández, F. Breher, Nature Chemistry (2023).","mla":"Krämer, Felix, et al. “A Crystalline Aluminium–Carbon-Based Ambiphile Capable of Activation and Catalytic Transfer of Ammonia in Non-Aqueous Media.” <i>Nature Chemistry</i>, Springer Science and Business Media LLC, 2023, doi:<a href=\"https://doi.org/10.1038/s41557-023-01340-9\">10.1038/s41557-023-01340-9</a>.","apa":"Krämer, F., Paradies, J., Fernández, I., &#38; Breher, F. (2023). A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media. <i>Nature Chemistry</i>. <a href=\"https://doi.org/10.1038/s41557-023-01340-9\">https://doi.org/10.1038/s41557-023-01340-9</a>","ama":"Krämer F, Paradies J, Fernández I, Breher F. A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media. <i>Nature Chemistry</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1038/s41557-023-01340-9\">10.1038/s41557-023-01340-9</a>","ieee":"F. Krämer, J. Paradies, I. Fernández, and F. Breher, “A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media,” <i>Nature Chemistry</i>, 2023, doi: <a href=\"https://doi.org/10.1038/s41557-023-01340-9\">10.1038/s41557-023-01340-9</a>.","chicago":"Krämer, Felix, Jan Paradies, Israel Fernández, and Frank Breher. “A Crystalline Aluminium–Carbon-Based Ambiphile Capable of Activation and Catalytic Transfer of Ammonia in Non-Aqueous Media.” <i>Nature Chemistry</i>, 2023. <a href=\"https://doi.org/10.1038/s41557-023-01340-9\">https://doi.org/10.1038/s41557-023-01340-9</a>."},"publisher":"Springer Science and Business Media LLC","date_updated":"2023-10-04T14:41:12Z","date_created":"2023-10-04T14:40:07Z","author":[{"full_name":"Krämer, Felix","last_name":"Krämer","first_name":"Felix"},{"last_name":"Paradies","orcid":"0000-0002-3698-668X","id":"53339","full_name":"Paradies, Jan","first_name":"Jan"},{"first_name":"Israel","full_name":"Fernández, Israel","last_name":"Fernández"},{"first_name":"Frank","last_name":"Breher","full_name":"Breher, Frank"}],"title":"A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media","doi":"10.1038/s41557-023-01340-9"},{"status":"public","type":"journal_article","publication":"ACS Applied Nano Materials","keyword":["General Materials Science"],"language":[{"iso":"eng"}],"_id":"48013","user_id":"48864","department":[{"_id":"302"}],"year":"2023","citation":{"bibtex":"@article{Liu_Schumann_Abele_Ren_Hanke_Xin_Hartmann_Schlierf_Keller_Lin_et al._2023, title={Thermophoretic Analysis of Biomolecules across the Nanoscales in Self-Assembled Polymeric Matrices}, DOI={<a href=\"https://doi.org/10.1021/acsanm.3c03623\">10.1021/acsanm.3c03623</a>}, journal={ACS Applied Nano Materials}, publisher={American Chemical Society (ACS)}, author={Liu, Ping and Schumann, Nils and Abele, Fabian and Ren, Fazheng and Hanke, Marcel and Xin, Yang and Hartmann, Andreas and Schlierf, Michael and Keller, Adrian and Lin, Weilin and et al.}, year={2023} }","short":"P. Liu, N. Schumann, F. Abele, F. Ren, M. Hanke, Y. Xin, A. Hartmann, M. Schlierf, A. Keller, W. Lin, Y. Zhang, ACS Applied Nano Materials (2023).","mla":"Liu, Ping, et al. “Thermophoretic Analysis of Biomolecules across the Nanoscales in Self-Assembled Polymeric Matrices.” <i>ACS Applied Nano Materials</i>, American Chemical Society (ACS), 2023, doi:<a href=\"https://doi.org/10.1021/acsanm.3c03623\">10.1021/acsanm.3c03623</a>.","apa":"Liu, P., Schumann, N., Abele, F., Ren, F., Hanke, M., Xin, Y., Hartmann, A., Schlierf, M., Keller, A., Lin, W., &#38; Zhang, Y. (2023). Thermophoretic Analysis of Biomolecules across the Nanoscales in Self-Assembled Polymeric Matrices. <i>ACS Applied Nano Materials</i>. <a href=\"https://doi.org/10.1021/acsanm.3c03623\">https://doi.org/10.1021/acsanm.3c03623</a>","chicago":"Liu, Ping, Nils Schumann, Fabian Abele, Fazheng Ren, Marcel Hanke, Yang Xin, Andreas Hartmann, et al. “Thermophoretic Analysis of Biomolecules across the Nanoscales in Self-Assembled Polymeric Matrices.” <i>ACS Applied Nano Materials</i>, 2023. <a href=\"https://doi.org/10.1021/acsanm.3c03623\">https://doi.org/10.1021/acsanm.3c03623</a>.","ieee":"P. Liu <i>et al.</i>, “Thermophoretic Analysis of Biomolecules across the Nanoscales in Self-Assembled Polymeric Matrices,” <i>ACS Applied Nano Materials</i>, 2023, doi: <a href=\"https://doi.org/10.1021/acsanm.3c03623\">10.1021/acsanm.3c03623</a>.","ama":"Liu P, Schumann N, Abele F, et al. Thermophoretic Analysis of Biomolecules across the Nanoscales in Self-Assembled Polymeric Matrices. <i>ACS Applied Nano Materials</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1021/acsanm.3c03623\">10.1021/acsanm.3c03623</a>"},"publication_status":"published","publication_identifier":{"issn":["2574-0970","2574-0970"]},"title":"Thermophoretic Analysis of Biomolecules across the Nanoscales in Self-Assembled Polymeric Matrices","doi":"10.1021/acsanm.3c03623","date_updated":"2023-10-11T17:04:21Z","publisher":"American Chemical Society (ACS)","author":[{"full_name":"Liu, Ping","last_name":"Liu","first_name":"Ping"},{"first_name":"Nils","last_name":"Schumann","full_name":"Schumann, Nils"},{"last_name":"Abele","full_name":"Abele, Fabian","first_name":"Fabian"},{"full_name":"Ren, Fazheng","last_name":"Ren","first_name":"Fazheng"},{"first_name":"Marcel","full_name":"Hanke, Marcel","last_name":"Hanke"},{"first_name":"Yang","full_name":"Xin, Yang","last_name":"Xin"},{"full_name":"Hartmann, Andreas","last_name":"Hartmann","first_name":"Andreas"},{"first_name":"Michael","full_name":"Schlierf, Michael","last_name":"Schlierf"},{"last_name":"Keller","orcid":"0000-0001-7139-3110","id":"48864","full_name":"Keller, Adrian","first_name":"Adrian"},{"last_name":"Lin","full_name":"Lin, Weilin","first_name":"Weilin"},{"first_name":"Yixin","full_name":"Zhang, Yixin","last_name":"Zhang"}],"date_created":"2023-10-11T17:03:32Z"},{"publication":"Chemistry – A European Journal","type":"journal_article","status":"public","abstract":[{"lang":"eng","text":"<jats:p>Bacterial colonization and biofilm formation on abiotic surfaces are initiated by the adhesion of peptides and proteins. Understanding the adhesion of such peptides and proteins at a molecular level thus represents an important step toward controlling and suppressing biofilm formation on technological and medical materials. This study investigates the molecular adhesion of a pilus‐derived peptide that facilitates biofilm formation of Pseudomonas aeruginosa, a multidrug‐resistant opportunistic pathogen frequently encountered in healthcare settings. Single‐molecule force spectroscopy (SMFS) was performed on chemically etched ZnO surfaces to gather insights about peptide adsorption force and its kinetics. Metal‐free click chemistry for the fabrication of peptide‐terminated SMFS cantilevers was performed on amine‐terminated gold cantilevers and verified by X‐ray photoelectron spectroscopy (XPS) and polarization‐modulated infrared reflection absorption spectroscopy (PM‐IRRAS). Atomic force microscopy (AFM) and XPS analyses reveal stable topographies and surface chemistries of the substrates that are not affected by SMFS. Rupture events described by the worm‐like chain model (WLC) up to 600 pN were detected for the non‐polar ZnO(11‐20) surfaces. The dissociation barrier energy at zero force ΔG(0), the transition state distance xb and bound‐unbound dissociation rate at zero force koff(0) for the single crystalline substrate indicate that coordination and hydrogen bonds dominate the peptide/surface interaction.</jats:p>"}],"department":[{"_id":"302"},{"_id":"633"}],"user_id":"48864","_id":"48588","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","citation":{"bibtex":"@article{Prüßner_Meinderink_Zhu_Orive_Kielar_Huck_Steinrück_Keller_Grundmeier_2023, title={Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces}, DOI={<a href=\"https://doi.org/10.1002/chem.202302464\">10.1002/chem.202302464</a>}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Prüßner, Tim and Meinderink, Dennis and Zhu, Siqi and Orive, Alejandro G. and Kielar, Charlotte and Huck, Marten and Steinrück, Hans-Georg and Keller, Adrian and Grundmeier, Guido}, year={2023} }","short":"T. Prüßner, D. Meinderink, S. Zhu, A.G. Orive, C. Kielar, M. Huck, H.-G. Steinrück, A. Keller, G. Grundmeier, Chemistry – A European Journal (2023).","mla":"Prüßner, Tim, et al. “Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas Aeruginosa Biofilm Formation on Non‐polar ZnO Surfaces.” <i>Chemistry – A European Journal</i>, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/chem.202302464\">10.1002/chem.202302464</a>.","apa":"Prüßner, T., Meinderink, D., Zhu, S., Orive, A. G., Kielar, C., Huck, M., Steinrück, H.-G., Keller, A., &#38; Grundmeier, G. (2023). Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces. <i>Chemistry – A European Journal</i>. <a href=\"https://doi.org/10.1002/chem.202302464\">https://doi.org/10.1002/chem.202302464</a>","ama":"Prüßner T, Meinderink D, Zhu S, et al. Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces. <i>Chemistry – A European Journal</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1002/chem.202302464\">10.1002/chem.202302464</a>","ieee":"T. Prüßner <i>et al.</i>, “Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces,” <i>Chemistry – A European Journal</i>, 2023, doi: <a href=\"https://doi.org/10.1002/chem.202302464\">10.1002/chem.202302464</a>.","chicago":"Prüßner, Tim, Dennis Meinderink, Siqi Zhu, Alejandro G. Orive, Charlotte Kielar, Marten Huck, Hans-Georg Steinrück, Adrian Keller, and Guido Grundmeier. “Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas Aeruginosa Biofilm Formation on Non‐polar ZnO Surfaces.” <i>Chemistry – A European Journal</i>, 2023. <a href=\"https://doi.org/10.1002/chem.202302464\">https://doi.org/10.1002/chem.202302464</a>."},"year":"2023","author":[{"first_name":"Tim","full_name":"Prüßner, Tim","last_name":"Prüßner"},{"first_name":"Dennis","last_name":"Meinderink","orcid":"0000-0002-2755-6514","id":"32378","full_name":"Meinderink, Dennis"},{"first_name":"Siqi","full_name":"Zhu, Siqi","last_name":"Zhu"},{"full_name":"Orive, Alejandro G.","last_name":"Orive","first_name":"Alejandro G."},{"last_name":"Kielar","full_name":"Kielar, Charlotte","first_name":"Charlotte"},{"last_name":"Huck","full_name":"Huck, Marten","first_name":"Marten"},{"id":"84268","full_name":"Steinrück, Hans-Georg","orcid":"0000-0001-6373-0877","last_name":"Steinrück","first_name":"Hans-Georg"},{"full_name":"Keller, Adrian","id":"48864","orcid":"0000-0001-7139-3110","last_name":"Keller","first_name":"Adrian"},{"first_name":"Guido","id":"194","full_name":"Grundmeier, Guido","last_name":"Grundmeier"}],"date_created":"2023-11-02T09:23:41Z","date_updated":"2023-11-02T09:26:00Z","publisher":"Wiley","doi":"10.1002/chem.202302464","title":"Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces"},{"issue":"1","year":"2023","publisher":"Uniwersytet Gdanski","date_created":"2023-11-03T10:50:49Z","title":"Evidence-based practices in teaching","publication":"Problemy Wczesnej Edukacji","abstract":[{"lang":"eng","text":"This article presents the results of the implementation of the Erasmus Plus project (KA203 financed by the European Union, contract number 2019-1-NL01-KA203-060339) Research in Teacher Education (RiTE). The aim of the project was to promote and facilitate pre-service teachers to create and undertake evidence-based practices in teaching science, technology, engineering, and mathematics (STEM). In the RiTE project, pre-service teachers were encouraged to use evidence from educational and scientific research and to experiment and introduce didactic innovations in teaching and learning processes. Although it has its justification in the tradition of thinking about science, evidence-based practice is not yet consciously applied in school practice. In the article, we present both the theoretical framework for such practices, and the results of qualitative research – an analysis of interviews conducted with students, future teachers, and novice teachers involved in the project. The presented results show changes in the context of an understanding of evidence and what evidence-based practices are in the teaching process and the vision of such teaching presented by the respondents."}],"language":[{"iso":"eng"}],"publication_status":"published","publication_identifier":{"issn":["2451-2230","1734-1582"]},"citation":{"ama":"Rybska E, Dudziak R, Pollmeier P. Evidence-based practices in teaching. <i>Problemy Wczesnej Edukacji</i>. 2023;56(1):89-108. doi:<a href=\"https://doi.org/10.26881/pwe.2023.56.06\">10.26881/pwe.2023.56.06</a>","ieee":"E. Rybska, R. Dudziak, and P. Pollmeier, “Evidence-based practices in teaching,” <i>Problemy Wczesnej Edukacji</i>, vol. 56, no. 1, pp. 89–108, 2023, doi: <a href=\"https://doi.org/10.26881/pwe.2023.56.06\">10.26881/pwe.2023.56.06</a>.","chicago":"Rybska, Eliza, Renata Dudziak, and Pascal Pollmeier. “Evidence-Based Practices in Teaching.” <i>Problemy Wczesnej Edukacji</i> 56, no. 1 (2023): 89–108. <a href=\"https://doi.org/10.26881/pwe.2023.56.06\">https://doi.org/10.26881/pwe.2023.56.06</a>.","mla":"Rybska, Eliza, et al. “Evidence-Based Practices in Teaching.” <i>Problemy Wczesnej Edukacji</i>, vol. 56, no. 1, Uniwersytet Gdanski, 2023, pp. 89–108, doi:<a href=\"https://doi.org/10.26881/pwe.2023.56.06\">10.26881/pwe.2023.56.06</a>.","short":"E. Rybska, R. Dudziak, P. Pollmeier, Problemy Wczesnej Edukacji 56 (2023) 89–108.","bibtex":"@article{Rybska_Dudziak_Pollmeier_2023, title={Evidence-based practices in teaching}, volume={56}, DOI={<a href=\"https://doi.org/10.26881/pwe.2023.56.06\">10.26881/pwe.2023.56.06</a>}, number={1}, journal={Problemy Wczesnej Edukacji}, publisher={Uniwersytet Gdanski}, author={Rybska, Eliza and Dudziak, Renata and Pollmeier, Pascal}, year={2023}, pages={89–108} }","apa":"Rybska, E., Dudziak, R., &#38; Pollmeier, P. (2023). Evidence-based practices in teaching. <i>Problemy Wczesnej Edukacji</i>, <i>56</i>(1), 89–108. <a href=\"https://doi.org/10.26881/pwe.2023.56.06\">https://doi.org/10.26881/pwe.2023.56.06</a>"},"page":"89-108","intvolume":"        56","date_updated":"2023-11-03T10:52:21Z","author":[{"first_name":"Eliza","full_name":"Rybska, Eliza","last_name":"Rybska"},{"last_name":"Dudziak","full_name":"Dudziak, Renata","first_name":"Renata"},{"full_name":"Pollmeier, Pascal","id":"44191","last_name":"Pollmeier","first_name":"Pascal"}],"volume":56,"doi":"10.26881/pwe.2023.56.06","type":"journal_article","status":"public","_id":"48602","user_id":"44191","department":[{"_id":"386"}]},{"publication_identifier":{"issn":["1932-7447","1932-7455"]},"publication_status":"published","issue":"47","year":"2023","page":"23099–23108","intvolume":"       127","citation":{"chicago":"Moffitt, Stephanie L., Chuntian Cao, Maikel F. A. M. Van Hest, Laura T. Schelhas, Hans-Georg Steinrück, and Michael F. Toney. “Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing.” <i>The Journal of Physical Chemistry C</i> 127, no. 47 (2023): 23099–23108. <a href=\"https://doi.org/10.1021/acs.jpcc.3c06410\">https://doi.org/10.1021/acs.jpcc.3c06410</a>.","ieee":"S. L. Moffitt, C. Cao, M. F. A. M. Van Hest, L. T. Schelhas, H.-G. Steinrück, and M. F. Toney, “Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing,” <i>The Journal of Physical Chemistry C</i>, vol. 127, no. 47, pp. 23099–23108, 2023, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.3c06410\">10.1021/acs.jpcc.3c06410</a>.","ama":"Moffitt SL, Cao C, Van Hest MFAM, Schelhas LT, Steinrück H-G, Toney MF. Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing. <i>The Journal of Physical Chemistry C</i>. 2023;127(47):23099–23108. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.3c06410\">10.1021/acs.jpcc.3c06410</a>","apa":"Moffitt, S. L., Cao, C., Van Hest, M. F. A. M., Schelhas, L. T., Steinrück, H.-G., &#38; Toney, M. F. (2023). Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing. <i>The Journal of Physical Chemistry C</i>, <i>127</i>(47), 23099–23108. <a href=\"https://doi.org/10.1021/acs.jpcc.3c06410\">https://doi.org/10.1021/acs.jpcc.3c06410</a>","bibtex":"@article{Moffitt_Cao_Van Hest_Schelhas_Steinrück_Toney_2023, title={Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing}, volume={127}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.3c06410\">10.1021/acs.jpcc.3c06410</a>}, number={47}, journal={The Journal of Physical Chemistry C}, publisher={American Chemical Society (ACS)}, author={Moffitt, Stephanie L. and Cao, Chuntian and Van Hest, Maikel F. A. M. and Schelhas, Laura T. and Steinrück, Hans-Georg and Toney, Michael F.}, year={2023}, pages={23099–23108} }","mla":"Moffitt, Stephanie L., et al. “Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing.” <i>The Journal of Physical Chemistry C</i>, vol. 127, no. 47, American Chemical Society (ACS), 2023, pp. 23099–23108, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.3c06410\">10.1021/acs.jpcc.3c06410</a>.","short":"S.L. Moffitt, C. Cao, M.F.A.M. Van Hest, L.T. Schelhas, H.-G. Steinrück, M.F. Toney, The Journal of Physical Chemistry C 127 (2023) 23099–23108."},"publisher":"American Chemical Society (ACS)","date_updated":"2023-11-30T10:09:26Z","volume":127,"author":[{"first_name":"Stephanie L.","full_name":"Moffitt, Stephanie L.","last_name":"Moffitt"},{"first_name":"Chuntian","full_name":"Cao, Chuntian","last_name":"Cao"},{"full_name":"Van Hest, Maikel F. A. M.","last_name":"Van Hest","first_name":"Maikel F. A. M."},{"first_name":"Laura T.","last_name":"Schelhas","full_name":"Schelhas, Laura T."},{"first_name":"Hans-Georg","full_name":"Steinrück, Hans-Georg","id":"84268","last_name":"Steinrück","orcid":"0000-0001-6373-0877"},{"first_name":"Michael F.","last_name":"Toney","full_name":"Toney, Michael F."}],"date_created":"2023-11-30T10:08:46Z","title":"Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing","doi":"10.1021/acs.jpcc.3c06410","publication":"The Journal of Physical Chemistry C","type":"journal_article","status":"public","_id":"49356","department":[{"_id":"633"}],"user_id":"84268","keyword":["Surfaces","Coatings and Films","Physical and Theoretical Chemistry","General Energy","Electronic","Optical and Magnetic Materials"],"language":[{"iso":"eng"}]},{"issue":"12","publication_identifier":{"issn":["2159-3930"]},"publication_status":"published","intvolume":"        13","citation":{"apa":"Zhang, B., Plidschun, M., Schmidt, M. A., &#38; Kitzerow, H.-S. (2023). Anchoring and electro-optic switching of liquid crystals on nano-structured surfaces fabricated by two-photon based nano-printing. <i>Optical Materials Express</i>, <i>13</i>(12), Article 3467. <a href=\"https://doi.org/10.1364/ome.503100\">https://doi.org/10.1364/ome.503100</a>","bibtex":"@article{Zhang_Plidschun_Schmidt_Kitzerow_2023, title={Anchoring and electro-optic switching of liquid crystals on nano-structured surfaces fabricated by two-photon based nano-printing}, volume={13}, DOI={<a href=\"https://doi.org/10.1364/ome.503100\">10.1364/ome.503100</a>}, number={123467}, journal={Optical Materials Express}, publisher={Optica Publishing Group}, author={Zhang, Bingru and Plidschun, Malte and Schmidt, Markus A. and Kitzerow, Heinz-Siegfried}, year={2023} }","mla":"Zhang, Bingru, et al. “Anchoring and Electro-Optic Switching of Liquid Crystals on Nano-Structured Surfaces Fabricated by Two-Photon Based Nano-Printing.” <i>Optical Materials Express</i>, vol. 13, no. 12, 3467, Optica Publishing Group, 2023, doi:<a href=\"https://doi.org/10.1364/ome.503100\">10.1364/ome.503100</a>.","short":"B. Zhang, M. Plidschun, M.A. Schmidt, H.-S. Kitzerow, Optical Materials Express 13 (2023).","chicago":"Zhang, Bingru, Malte Plidschun, Markus A. Schmidt, and Heinz-Siegfried Kitzerow. “Anchoring and Electro-Optic Switching of Liquid Crystals on Nano-Structured Surfaces Fabricated by Two-Photon Based Nano-Printing.” <i>Optical Materials Express</i> 13, no. 12 (2023). <a href=\"https://doi.org/10.1364/ome.503100\">https://doi.org/10.1364/ome.503100</a>.","ieee":"B. Zhang, M. Plidschun, M. A. Schmidt, and H.-S. Kitzerow, “Anchoring and electro-optic switching of liquid crystals on nano-structured surfaces fabricated by two-photon based nano-printing,” <i>Optical Materials Express</i>, vol. 13, no. 12, Art. no. 3467, 2023, doi: <a href=\"https://doi.org/10.1364/ome.503100\">10.1364/ome.503100</a>.","ama":"Zhang B, Plidschun M, Schmidt MA, Kitzerow H-S. Anchoring and electro-optic switching of liquid crystals on nano-structured surfaces fabricated by two-photon based nano-printing. <i>Optical Materials Express</i>. 2023;13(12). doi:<a href=\"https://doi.org/10.1364/ome.503100\">10.1364/ome.503100</a>"},"year":"2023","volume":13,"author":[{"last_name":"Zhang","full_name":"Zhang, Bingru","first_name":"Bingru"},{"full_name":"Plidschun, Malte","last_name":"Plidschun","first_name":"Malte"},{"full_name":"Schmidt, Markus A.","last_name":"Schmidt","first_name":"Markus A."},{"first_name":"Heinz-Siegfried","full_name":"Kitzerow, Heinz-Siegfried","id":"254","last_name":"Kitzerow"}],"date_created":"2023-12-13T15:59:37Z","date_updated":"2023-12-13T16:06:29Z","publisher":"Optica Publishing Group","doi":"10.1364/ome.503100","title":"Anchoring and electro-optic switching of liquid crystals on nano-structured surfaces fabricated by two-photon based nano-printing","publication":"Optical Materials Express","type":"journal_article","status":"public","abstract":[{"text":"<jats:p>The alignment of liquid crystals on surfaces plays a central role in optimizing their performances. In this work, a cutting-edge nano-lithography-based method to control the local orientation of a thermotropic liquid crystal is applied to easily available commercial standard materials and evaluated. Parallel nanogrooves on a substrate, created through 3D nanoprinting in a negative-tone photoresin optimized for two-photon polymerization are used for this purpose. Azimuthal anchoring energies of the order from 10<jats:sup>−6</jats:sup> J/m<jats:sup>2</jats:sup> to 10<jats:sup>−5</jats:sup> J/m<jats:sup>2</jats:sup> are found, depending on the spacing, width and depth of the grooves. In part, these values are larger than those reported previously for another photopolymer. Both uniform alignment and spatial patterns of different alignment directions can be realized. Electro-optic studies confirm the suitability of the method for electrically addressable photonic applications and indicate strong polar anchoring.</jats:p>","lang":"eng"}],"department":[{"_id":"313"},{"_id":"230"},{"_id":"35"}],"user_id":"254","_id":"49609","language":[{"iso":"eng"}],"keyword":["Electronic","Optical and Magnetic Materials"],"article_number":"3467"},{"_id":"43440","department":[{"_id":"313"},{"_id":"230"}],"user_id":"254","type":"journal_article","status":"public","date_updated":"2023-12-13T15:54:31Z","volume":50,"author":[{"full_name":"Zhang, Bingru","last_name":"Zhang","first_name":"Bingru"},{"full_name":"Nguyen, Linh","last_name":"Nguyen","first_name":"Linh"},{"full_name":"Martens, Kevin","last_name":"Martens","first_name":"Kevin"},{"full_name":"Heuer-Jungemann, Amelie","last_name":"Heuer-Jungemann","first_name":"Amelie"},{"full_name":"Philipp, Julian","last_name":"Philipp","first_name":"Julian"},{"first_name":"Susanne","full_name":"Kempter, Susanne","last_name":"Kempter"},{"first_name":"Joachim O.","full_name":"Rädler, Joachim O.","last_name":"Rädler"},{"full_name":"Liedl, Tim","last_name":"Liedl","first_name":"Tim"},{"last_name":"Kitzerow","full_name":"Kitzerow, Heinz-Siegfried","id":"254","first_name":"Heinz-Siegfried"}],"doi":"10.1080/02678292.2023.2188494","publication_identifier":{"issn":["0267-8292","1366-5855"]},"publication_status":"published","intvolume":"        50","page":"1243-1251","citation":{"apa":"Zhang, B., Nguyen, L., Martens, K., Heuer-Jungemann, A., Philipp, J., Kempter, S., Rädler, J. O., Liedl, T., &#38; Kitzerow, H.-S. (2023). Luminescent DNA-origami nano-rods dispersed in a lyotropic chromonic liquid crystal. <i>Liquid Crystals</i>, <i>50</i>(7–10), 1243–1251. <a href=\"https://doi.org/10.1080/02678292.2023.2188494\">https://doi.org/10.1080/02678292.2023.2188494</a>","bibtex":"@article{Zhang_Nguyen_Martens_Heuer-Jungemann_Philipp_Kempter_Rädler_Liedl_Kitzerow_2023, title={Luminescent DNA-origami nano-rods dispersed in a lyotropic chromonic liquid crystal}, volume={50}, DOI={<a href=\"https://doi.org/10.1080/02678292.2023.2188494\">10.1080/02678292.2023.2188494</a>}, number={7–10}, journal={Liquid Crystals}, publisher={Informa UK Limited}, author={Zhang, Bingru and Nguyen, Linh and Martens, Kevin and Heuer-Jungemann, Amelie and Philipp, Julian and Kempter, Susanne and Rädler, Joachim O. and Liedl, Tim and Kitzerow, Heinz-Siegfried}, year={2023}, pages={1243–1251} }","mla":"Zhang, Bingru, et al. “Luminescent DNA-Origami Nano-Rods Dispersed in a Lyotropic Chromonic Liquid Crystal.” <i>Liquid Crystals</i>, vol. 50, no. 7–10, Informa UK Limited, 2023, pp. 1243–51, doi:<a href=\"https://doi.org/10.1080/02678292.2023.2188494\">10.1080/02678292.2023.2188494</a>.","short":"B. Zhang, L. Nguyen, K. Martens, A. Heuer-Jungemann, J. Philipp, S. Kempter, J.O. Rädler, T. Liedl, H.-S. Kitzerow, Liquid Crystals 50 (2023) 1243–1251.","ama":"Zhang B, Nguyen L, Martens K, et al. Luminescent DNA-origami nano-rods dispersed in a lyotropic chromonic liquid crystal. <i>Liquid Crystals</i>. 2023;50(7-10):1243-1251. doi:<a href=\"https://doi.org/10.1080/02678292.2023.2188494\">10.1080/02678292.2023.2188494</a>","chicago":"Zhang, Bingru, Linh Nguyen, Kevin Martens, Amelie Heuer-Jungemann, Julian Philipp, Susanne Kempter, Joachim O. Rädler, Tim Liedl, and Heinz-Siegfried Kitzerow. “Luminescent DNA-Origami Nano-Rods Dispersed in a Lyotropic Chromonic Liquid Crystal.” <i>Liquid Crystals</i> 50, no. 7–10 (2023): 1243–51. <a href=\"https://doi.org/10.1080/02678292.2023.2188494\">https://doi.org/10.1080/02678292.2023.2188494</a>.","ieee":"B. Zhang <i>et al.</i>, “Luminescent DNA-origami nano-rods dispersed in a lyotropic chromonic liquid crystal,” <i>Liquid Crystals</i>, vol. 50, no. 7–10, pp. 1243–1251, 2023, doi: <a href=\"https://doi.org/10.1080/02678292.2023.2188494\">10.1080/02678292.2023.2188494</a>."},"keyword":["Condensed Matter Physics","General Materials Science","General Chemistry"],"language":[{"iso":"eng"}],"publication":"Liquid Crystals","publisher":"Informa UK Limited","date_created":"2023-04-08T17:21:30Z","title":"Luminescent DNA-origami nano-rods dispersed in a lyotropic chromonic liquid crystal","issue":"7-10","year":"2023"},{"status":"public","type":"dissertation","file_date_updated":"2024-01-22T14:32:38Z","department":[{"_id":"386"}],"user_id":"44191","_id":"50731","page":"357","citation":{"ama":"Pollmeier P. <i>Umgang mit Evidenzen angehender Lehrkräfte in den Naturwissenschaften - Epistemologie in der Lehrkräfteausbildung</i>. Universität Paderborn; 2023. doi:<a href=\"https://doi.org/10.17619/UNIPB/1-1869\">10.17619/UNIPB/1-1869</a>","chicago":"Pollmeier, Pascal. <i>Umgang mit Evidenzen angehender Lehrkräfte in den Naturwissenschaften - Epistemologie in der Lehrkräfteausbildung</i>. Universität Paderborn, 2023. <a href=\"https://doi.org/10.17619/UNIPB/1-1869\">https://doi.org/10.17619/UNIPB/1-1869</a>.","ieee":"P. Pollmeier, <i>Umgang mit Evidenzen angehender Lehrkräfte in den Naturwissenschaften - Epistemologie in der Lehrkräfteausbildung</i>. Universität Paderborn, 2023.","bibtex":"@book{Pollmeier_2023, title={Umgang mit Evidenzen angehender Lehrkräfte in den Naturwissenschaften - Epistemologie in der Lehrkräfteausbildung}, DOI={<a href=\"https://doi.org/10.17619/UNIPB/1-1869\">10.17619/UNIPB/1-1869</a>}, publisher={Universität Paderborn}, author={Pollmeier, Pascal}, year={2023} }","short":"P. Pollmeier, Umgang mit Evidenzen angehender Lehrkräfte in den Naturwissenschaften - Epistemologie in der Lehrkräfteausbildung, Universität Paderborn, 2023.","mla":"Pollmeier, Pascal. <i>Umgang mit Evidenzen angehender Lehrkräfte in den Naturwissenschaften - Epistemologie in der Lehrkräfteausbildung</i>. Universität Paderborn, 2023, doi:<a href=\"https://doi.org/10.17619/UNIPB/1-1869\">10.17619/UNIPB/1-1869</a>.","apa":"Pollmeier, P. (2023). <i>Umgang mit Evidenzen angehender Lehrkräfte in den Naturwissenschaften - Epistemologie in der Lehrkräfteausbildung</i>. Universität Paderborn. <a href=\"https://doi.org/10.17619/UNIPB/1-1869\">https://doi.org/10.17619/UNIPB/1-1869</a>"},"has_accepted_license":"1","doi":"10.17619/UNIPB/1-1869","author":[{"first_name":"Pascal","last_name":"Pollmeier","full_name":"Pollmeier, Pascal","id":"44191"}],"supervisor":[{"full_name":"Fechner, Sabine","last_name":"Fechner","first_name":"Sabine"}],"date_updated":"2024-01-22T14:36:17Z","file":[{"access_level":"closed","file_id":"50733","file_name":"Dissertation_Pollmeier_Veröffentlichung UB.pdf","file_size":16219829,"creator":"pascalp","date_created":"2024-01-22T14:32:38Z","date_updated":"2024-01-22T14:32:38Z","relation":"main_file","success":1,"content_type":"application/pdf"}],"abstract":[{"text":"Eine Forderung nach evidenzbasierter Praxis (EBP) im Bildungswesen kann sowohl vor dem Hintergrund der Bedeutung wissenschaftlicher Evidenzen innerhalb gesellschaftlicher Diskurse als auch der Evidenzbasierung in anderen Bereichen formuliert werden. Der Umgang mit und die Bewertung von Evidenzen stellen somit vor dem Hintergrund epistemologischer Überzeugungen relevante Aufgaben für den Chemieunterricht dar. Dabei ist unklar, inwiefern (angehende) Lehrkräfte über Kompetenzen in EBP verfügen. Bestehende Studien weisen auf einen Bedarf der fachdidaktischen Analyse und Förderung von Kompetenzen in EBP bei angehenden Lehrkräften hin.Im Rahmen dieser Dissertation wurde die Domänenspezifität der Kompetenzen in EBP sowie deren Förderung in einem fachdidaktischen Kontext untersucht. Dabei wurde ein weiterer Schwerpunkt auf den Umgang mit anomalen Beobachtungen im Sinne widersprüchlicher Evidenzen gelegt. Innerhalb von drei Teilstudien wurden unterschiedliche methodische Zugänge zur Kompetenz in EBP auf Grundlage epistemologischer Überzeugungen gewählt.Die Ergebnisse weisen auf einen Förderbedarf der Kompetenz in EBP für angehende Lehrkräfte aller Unterrichtsfächer hin. Eine entwickelte Intervention für angehende Chemielehrkräfte weist eine Wirksamkeit zur Förderung von Kompetenzen in EBP auf. Im Rahmen einer Modellierungsstudie kann der Einfluss von Fachwissen sowie Indizien für einen Einfluss epistemologischer Überzeugungen auf den Umgang mit anomalen Beobachtungen gezeigt werden.","lang":"eng"},{"text":"The role of evidence based practice (EBP) in educational contexts can be argued from the necessity ofevidence for societal debates, as well as evidence based practice in other research fields, such asmedicine. Therefore, using evidence based on epistemological beliefs is a relevant task for scienceeducation. However, i t is unclear whether pre service teachers hold necessary competences in EBP.Existing research indicates a need for the analysis and promotion of competences in EBP for pre serviceteachers from a scien ce education perspective.This project aims at investigating the domainspecificity and promotion of competences in EBP of preservice teachers. An additional emphasis is put on the reaction to anomalous observations ascontradictory evidence. Within three sub studies, different methodological approaches were used togather insights into the competence in EBP from the base of epistemological beliefs.As results show, there is a need for promotion in competences in EBP for preservice teachers in allsubjects. Therefore, the developed intervention for the promotion of pre service chemistry teacherscompetence in EBP shows to be effective. Moreover, the impact of content knowledge and the role ofepistemological beliefs on the interpretation of anomalous observations could be demonstrated.","lang":"eng"}],"language":[{"iso":"ger"}],"keyword":["Epistemologie","Evidenzen","evidence-based practice"],"ddc":["370"],"year":"2023","title":"Umgang mit Evidenzen angehender Lehrkräfte in den Naturwissenschaften - Epistemologie in der Lehrkräfteausbildung","date_created":"2024-01-22T14:28:52Z","publisher":"Universität Paderborn"},{"department":[{"_id":"321"},{"_id":"302"}],"user_id":"54863","_id":"46023","language":[{"iso":"eng"}],"keyword":["Chemistry (miscellaneous)","Analytical Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Molecular Medicine","Drug Discovery","Pharmaceutical Science"],"article_number":"5109","publication":"Molecules","type":"journal_article","status":"public","abstract":[{"text":"<jats:p>This article presents the potential-dependent adsorption of two proteins, bovine serum albumin (BSA) and lysozyme (LYZ), on Ti6Al4V alloy at pH 7.4 and 37 °C. The adsorption process was studied on an electropolished alloy under cathodic and anodic overpotentials, compared to the open circuit potential (OCP). To analyze the adsorption process, various complementary interface analytical techniques were employed, including PM-IRRAS (polarization-modulation infrared reflection-absorption spectroscopy), AFM (atomic force microscopy), XPS (X-ray photoelectron spectroscopy), and E-QCM (electrochemical quartz crystal microbalance) measurements. The polarization experiments were conducted within a potential range where charging of the electric double layer dominates, and Faradaic currents can be disregarded. The findings highlight the significant influence of the interfacial charge distribution on the adsorption of BSA and LYZ onto the alloy surface. Furthermore, electrochemical analysis of the protein layers formed under applied overpotentials demonstrated improved corrosion protection properties. These studies provide valuable insights into protein adsorption on titanium alloys under physiological conditions, characterized by varying potentials of the passive alloy.</jats:p>","lang":"eng"}],"volume":28,"date_created":"2023-07-12T07:55:40Z","author":[{"first_name":"Belma","last_name":"Duderija","full_name":"Duderija, Belma"},{"last_name":"González-Orive","full_name":"González-Orive, Alejandro","first_name":"Alejandro"},{"first_name":"Christoph","full_name":"Ebbert, Christoph","last_name":"Ebbert"},{"last_name":"Neßlinger","full_name":"Neßlinger, Vanessa","first_name":"Vanessa"},{"first_name":"Adrian","last_name":"Keller","full_name":"Keller, Adrian"},{"last_name":"Grundmeier","full_name":"Grundmeier, Guido","first_name":"Guido"}],"publisher":"MDPI AG","date_updated":"2024-02-06T12:33:55Z","doi":"10.3390/molecules28135109","title":"Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy","issue":"13","publication_identifier":{"issn":["1420-3049"]},"publication_status":"published","intvolume":"        28","citation":{"short":"B. Duderija, A. González-Orive, C. Ebbert, V. Neßlinger, A. Keller, G. Grundmeier, Molecules 28 (2023).","bibtex":"@article{Duderija_González-Orive_Ebbert_Neßlinger_Keller_Grundmeier_2023, title={Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy}, volume={28}, DOI={<a href=\"https://doi.org/10.3390/molecules28135109\">10.3390/molecules28135109</a>}, number={135109}, journal={Molecules}, publisher={MDPI AG}, author={Duderija, Belma and González-Orive, Alejandro and Ebbert, Christoph and Neßlinger, Vanessa and Keller, Adrian and Grundmeier, Guido}, year={2023} }","mla":"Duderija, Belma, et al. “Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy.” <i>Molecules</i>, vol. 28, no. 13, 5109, MDPI AG, 2023, doi:<a href=\"https://doi.org/10.3390/molecules28135109\">10.3390/molecules28135109</a>.","apa":"Duderija, B., González-Orive, A., Ebbert, C., Neßlinger, V., Keller, A., &#38; Grundmeier, G. (2023). Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy. <i>Molecules</i>, <i>28</i>(13), Article 5109. <a href=\"https://doi.org/10.3390/molecules28135109\">https://doi.org/10.3390/molecules28135109</a>","ieee":"B. Duderija, A. González-Orive, C. Ebbert, V. Neßlinger, A. Keller, and G. Grundmeier, “Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy,” <i>Molecules</i>, vol. 28, no. 13, Art. no. 5109, 2023, doi: <a href=\"https://doi.org/10.3390/molecules28135109\">10.3390/molecules28135109</a>.","chicago":"Duderija, Belma, Alejandro González-Orive, Christoph Ebbert, Vanessa Neßlinger, Adrian Keller, and Guido Grundmeier. “Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy.” <i>Molecules</i> 28, no. 13 (2023). <a href=\"https://doi.org/10.3390/molecules28135109\">https://doi.org/10.3390/molecules28135109</a>.","ama":"Duderija B, González-Orive A, Ebbert C, Neßlinger V, Keller A, Grundmeier G. Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy. <i>Molecules</i>. 2023;28(13). doi:<a href=\"https://doi.org/10.3390/molecules28135109\">10.3390/molecules28135109</a>"},"year":"2023"},{"doi":"10.1016/j.jajp.2023.100181","title":"Electropolymerization of acrylic acid on steel for enhanced joining by plastic deformation","volume":9,"author":[{"last_name":"Duderija","full_name":"Duderija, B.","first_name":"B."},{"first_name":"F.","full_name":"Sahin, F.","last_name":"Sahin"},{"full_name":"Meinderink, D.","last_name":"Meinderink","first_name":"D."},{"full_name":"Calderón-Gómez, J.C.","last_name":"Calderón-Gómez","first_name":"J.C."},{"full_name":"Schmidt, H.C.","last_name":"Schmidt","first_name":"H.C."},{"first_name":"W.","last_name":"Homberg","full_name":"Homberg, W."},{"first_name":"G.","full_name":"Grundmeier, G.","last_name":"Grundmeier"},{"last_name":"González-Orive","full_name":"González-Orive, A.","first_name":"A."}],"date_created":"2024-02-06T12:29:53Z","publisher":"Elsevier BV","date_updated":"2024-02-06T12:32:37Z","intvolume":"         9","citation":{"ieee":"B. Duderija <i>et al.</i>, “Electropolymerization of acrylic acid on steel for enhanced joining by plastic deformation,” <i>Journal of Advanced Joining Processes</i>, vol. 9, Art. no. 100181, 2023, doi: <a href=\"https://doi.org/10.1016/j.jajp.2023.100181\">10.1016/j.jajp.2023.100181</a>.","chicago":"Duderija, B., F. Sahin, D. Meinderink, J.C. Calderón-Gómez, H.C. Schmidt, W. Homberg, G. Grundmeier, and A. González-Orive. “Electropolymerization of Acrylic Acid on Steel for Enhanced Joining by Plastic Deformation.” <i>Journal of Advanced Joining Processes</i> 9 (2023). <a href=\"https://doi.org/10.1016/j.jajp.2023.100181\">https://doi.org/10.1016/j.jajp.2023.100181</a>.","ama":"Duderija B, Sahin F, Meinderink D, et al. Electropolymerization of acrylic acid on steel for enhanced joining by plastic deformation. <i>Journal of Advanced Joining Processes</i>. 2023;9. doi:<a href=\"https://doi.org/10.1016/j.jajp.2023.100181\">10.1016/j.jajp.2023.100181</a>","bibtex":"@article{Duderija_Sahin_Meinderink_Calderón-Gómez_Schmidt_Homberg_Grundmeier_González-Orive_2023, title={Electropolymerization of acrylic acid on steel for enhanced joining by plastic deformation}, volume={9}, DOI={<a href=\"https://doi.org/10.1016/j.jajp.2023.100181\">10.1016/j.jajp.2023.100181</a>}, number={100181}, journal={Journal of Advanced Joining Processes}, publisher={Elsevier BV}, author={Duderija, B. and Sahin, F. and Meinderink, D. and Calderón-Gómez, J.C. and Schmidt, H.C. and Homberg, W. and Grundmeier, G. and González-Orive, A.}, year={2023} }","short":"B. Duderija, F. Sahin, D. Meinderink, J.C. Calderón-Gómez, H.C. Schmidt, W. Homberg, G. Grundmeier, A. González-Orive, Journal of Advanced Joining Processes 9 (2023).","mla":"Duderija, B., et al. “Electropolymerization of Acrylic Acid on Steel for Enhanced Joining by Plastic Deformation.” <i>Journal of Advanced Joining Processes</i>, vol. 9, 100181, Elsevier BV, 2023, doi:<a href=\"https://doi.org/10.1016/j.jajp.2023.100181\">10.1016/j.jajp.2023.100181</a>.","apa":"Duderija, B., Sahin, F., Meinderink, D., Calderón-Gómez, J. C., Schmidt, H. C., Homberg, W., Grundmeier, G., &#38; González-Orive, A. (2023). Electropolymerization of acrylic acid on steel for enhanced joining by plastic deformation. <i>Journal of Advanced Joining Processes</i>, <i>9</i>, Article 100181. <a href=\"https://doi.org/10.1016/j.jajp.2023.100181\">https://doi.org/10.1016/j.jajp.2023.100181</a>"},"year":"2023","publication_identifier":{"issn":["2666-3309"]},"publication_status":"published","language":[{"iso":"eng"}],"keyword":["Mechanical Engineering","Mechanics of Materials","Engineering (miscellaneous)","Chemical Engineering (miscellaneous)"],"article_number":"100181","department":[{"_id":"321"},{"_id":"302"}],"user_id":"54863","_id":"51167","status":"public","publication":"Journal of Advanced Joining Processes","type":"journal_article"},{"publisher":"American Chemical Society (ACS)","date_created":"2024-03-07T09:57:30Z","title":"Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby","issue":"39","year":"2023","keyword":["Inorganic Chemistry","Physical and Theoretical Chemistry"],"language":[{"iso":"eng"}],"publication":"Inorganic Chemistry","abstract":[{"lang":"eng","text":"Photoactive chromium(III) complexes saw a conceptual breakthrough with the discovery of the prototypical molecular ruby mer-[Cr(ddpd)2]3+ (ddpd = N,N′-dimethyl-N,N′-dipyridin-2-ylpyridine-2,6-diamine), which shows intense long-lived near-infrared (NIR) phosphorescence from metal-centered spin-flip states. In contrast to the numerous studies on chromium(III) photophysics, only 10 luminescent molybdenum(III) complexes have been reported so far. Here, we present the synthesis and characterization of mer-MoX3(ddpd) (1, X = Cl; 2, X = Br) and cisfac-[Mo(ddpd)2]3+ (cisfac-[3]3+), an isomeric heavy homologue of the prototypical molecular ruby. For cisfac-[3]3+, we found strong zero-field splitting using magnetic susceptibility measurements and electron paramagnetic resonance spectroscopy. Electronic spectra covering the spin-forbidden transitions show that the spin-flip states in mer-1, mer-2, and cisfac-[3]3+ are much lower in energy than those in comparable chromium(III) compounds. While all three complexes show weak spin-flip phosphorescence in NIR-II, the emission of cisfac-[3]3+ peaking at 1550 nm is particularly low in energy. Femtosecond transient absorption spectroscopy reveals a short excited-state lifetime of 1.4 ns, 6 orders of magnitude shorter than that of mer-[Cr(ddpd)2]3+. Using density functional theory and ab initio multireference calculations, we break down the reasons for this disparity and derive principles for the design of future stable photoactive molybdenum(III) complexes."}],"date_updated":"2024-03-07T10:02:58Z","author":[{"first_name":"Winald R.","full_name":"Kitzmann, Winald R.","last_name":"Kitzmann"},{"last_name":"Hunger","full_name":"Hunger, David","first_name":"David"},{"first_name":"Antti-Pekka M.","full_name":"Reponen, Antti-Pekka M.","last_name":"Reponen"},{"full_name":"Förster, Christoph","last_name":"Förster","first_name":"Christoph"},{"id":"48467","full_name":"Schoch, Roland","last_name":"Schoch","orcid":"0000-0003-2061-7289","first_name":"Roland"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"last_name":"Feldmann","full_name":"Feldmann, Sascha","first_name":"Sascha"},{"last_name":"van Slageren","full_name":"van Slageren, Joris","first_name":"Joris"},{"first_name":"Katja","last_name":"Heinze","full_name":"Heinze, Katja"}],"volume":62,"doi":"10.1021/acs.inorgchem.3c02186","publication_status":"published","publication_identifier":{"issn":["0020-1669","1520-510X"]},"citation":{"ama":"Kitzmann WR, Hunger D, Reponen A-PM, et al. Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby. <i>Inorganic Chemistry</i>. 2023;62(39):15797-15808. doi:<a href=\"https://doi.org/10.1021/acs.inorgchem.3c02186\">10.1021/acs.inorgchem.3c02186</a>","chicago":"Kitzmann, Winald R., David Hunger, Antti-Pekka M. Reponen, Christoph Förster, Roland Schoch, Matthias Bauer, Sascha Feldmann, Joris van Slageren, and Katja Heinze. “Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby.” <i>Inorganic Chemistry</i> 62, no. 39 (2023): 15797–808. <a href=\"https://doi.org/10.1021/acs.inorgchem.3c02186\">https://doi.org/10.1021/acs.inorgchem.3c02186</a>.","ieee":"W. R. Kitzmann <i>et al.</i>, “Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby,” <i>Inorganic Chemistry</i>, vol. 62, no. 39, pp. 15797–15808, 2023, doi: <a href=\"https://doi.org/10.1021/acs.inorgchem.3c02186\">10.1021/acs.inorgchem.3c02186</a>.","apa":"Kitzmann, W. R., Hunger, D., Reponen, A.-P. M., Förster, C., Schoch, R., Bauer, M., Feldmann, S., van Slageren, J., &#38; Heinze, K. (2023). Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby. <i>Inorganic Chemistry</i>, <i>62</i>(39), 15797–15808. <a href=\"https://doi.org/10.1021/acs.inorgchem.3c02186\">https://doi.org/10.1021/acs.inorgchem.3c02186</a>","bibtex":"@article{Kitzmann_Hunger_Reponen_Förster_Schoch_Bauer_Feldmann_van Slageren_Heinze_2023, title={Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby}, volume={62}, DOI={<a href=\"https://doi.org/10.1021/acs.inorgchem.3c02186\">10.1021/acs.inorgchem.3c02186</a>}, number={39}, journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Kitzmann, Winald R. and Hunger, David and Reponen, Antti-Pekka M. and Förster, Christoph and Schoch, Roland and Bauer, Matthias and Feldmann, Sascha and van Slageren, Joris and Heinze, Katja}, year={2023}, pages={15797–15808} }","short":"W.R. Kitzmann, D. Hunger, A.-P.M. Reponen, C. Förster, R. Schoch, M. Bauer, S. Feldmann, J. van Slageren, K. Heinze, Inorganic Chemistry 62 (2023) 15797–15808.","mla":"Kitzmann, Winald R., et al. “Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby.” <i>Inorganic Chemistry</i>, vol. 62, no. 39, American Chemical Society (ACS), 2023, pp. 15797–808, doi:<a href=\"https://doi.org/10.1021/acs.inorgchem.3c02186\">10.1021/acs.inorgchem.3c02186</a>."},"intvolume":"        62","page":"15797-15808","_id":"52345","user_id":"48467","department":[{"_id":"306"}],"article_type":"original","type":"journal_article","status":"public"},{"status":"public","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>We report on so‐called “hidden FLPs” (FLP: frustrated Lewis pair) consisting of a phosphorus ylide featuring a group 13 fragment in the <jats:italic>ortho</jats:italic> position of a phenyl ring scaffold to form five‐membered ring structures. Although the formation of the Lewis acid/base adducts was observed in the solid state, most of the title compounds readily react with carbon dioxide to provide stable insertion products. Strikingly, 0.3–3.0 mol% of the reported aluminum and gallium/carbon‐based ambiphiles catalyze the reduction of CO<jats:sub>2</jats:sub> to methanol with satisfactory high selectivity and yields using pinacol borane as stoichiometric reduction equivalent. Comprehensive computational studies provided valuable mechanistic insights and shed more light on activity differences.</jats:p>"}],"type":"journal_article","publication":"Chemistry – A European Journal","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"user_id":"53339","department":[{"_id":"2"},{"_id":"389"}],"_id":"52542","citation":{"apa":"Krämer, F., Paradies, J., Fernández, I., &#38; Breher, F. (2023). Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles. <i>Chemistry – A European Journal</i>, <i>30</i>(5). <a href=\"https://doi.org/10.1002/chem.202303380\">https://doi.org/10.1002/chem.202303380</a>","bibtex":"@article{Krämer_Paradies_Fernández_Breher_2023, title={Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles}, volume={30}, DOI={<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>}, number={5}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Krämer, Felix and Paradies, Jan and Fernández, Israel and Breher, Frank}, year={2023} }","short":"F. Krämer, J. Paradies, I. Fernández, F. Breher, Chemistry – A European Journal 30 (2023).","mla":"Krämer, Felix, et al. “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles.” <i>Chemistry – A European Journal</i>, vol. 30, no. 5, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>.","ama":"Krämer F, Paradies J, Fernández I, Breher F. Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles. <i>Chemistry – A European Journal</i>. 2023;30(5). doi:<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>","ieee":"F. Krämer, J. Paradies, I. Fernández, and F. Breher, “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles,” <i>Chemistry – A European Journal</i>, vol. 30, no. 5, 2023, doi: <a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>.","chicago":"Krämer, Felix, Jan Paradies, Israel Fernández, and Frank Breher. “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles.” <i>Chemistry – A European Journal</i> 30, no. 5 (2023). <a href=\"https://doi.org/10.1002/chem.202303380\">https://doi.org/10.1002/chem.202303380</a>."},"intvolume":"        30","year":"2023","issue":"5","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"doi":"10.1002/chem.202303380","title":"Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles","date_created":"2024-03-13T17:17:52Z","author":[{"first_name":"Felix","full_name":"Krämer, Felix","last_name":"Krämer"},{"first_name":"Jan","id":"53339","full_name":"Paradies, Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X"},{"first_name":"Israel","full_name":"Fernández, Israel","last_name":"Fernández"},{"full_name":"Breher, Frank","last_name":"Breher","first_name":"Frank"}],"volume":30,"publisher":"Wiley","date_updated":"2024-03-13T17:18:17Z"},{"keyword":["Materials Chemistry","Polymers and Plastics","Organic Chemistry","General Chemical Engineering"],"language":[{"iso":"eng"}],"abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>Coating medical implants with antibacterial polymers may prevent postoperative infections which are a common issue for conventional titanium implants and can even lead to implant failure. Easily applicable diblock copolymers are presented that form polymer brushes via “grafting to” mechanism on titanium and equip the modified material with antibacterial properties. The polymers carry quaternized pyridinium units to combat bacteria and phosphonic acid groups which allow the linear chains to be anchored to metal surfaces in a convenient coating process. The polymers are synthesized via reversible‐addition‐fragmentation‐chain‐transfer (RAFT) polymerization and postmodifications and are characterized using NMR spectroscopy and SEC. Low grafting densities are a major drawback of the “grafting to” approach compared to “grafting from”. Thus, the number of phosphonic acid groups in the anchor block are varied to investigate and optimize the surface binding. Modified titanium surfaces are examined regarding their composition, wetting behavior, streaming potential, and coating stability. Evaluation of the antimicrobial properties revealed reduced bacterial adhesion and biofilm formation for certain polymers, albeit the cell biocompatibility against human gingival fibroblasts is also impaired. The presented findings show the potential of easy‐to‐apply polymer coatings and aid in designing next‐generation implant surface modifications.</jats:p>"}],"publication":"Macromolecular Materials and Engineering","title":"Antimicrobial Brushes on Titanium via “Grafting to” Using Phosphonic Acid/Pyridinium Containing Block Copolymers","publisher":"Wiley","date_created":"2024-04-03T11:08:51Z","year":"2023","issue":"8","article_type":"original","_id":"53170","department":[{"_id":"163"}],"user_id":"94","status":"public","type":"journal_article","doi":"10.1002/mame.202200665","date_updated":"2024-04-03T11:10:05Z","volume":308,"author":[{"first_name":"Rafael","last_name":"Methling","full_name":"Methling, Rafael"},{"full_name":"Dückmann, Oliver","last_name":"Dückmann","first_name":"Oliver"},{"last_name":"Simon","full_name":"Simon, Frank","first_name":"Frank"},{"last_name":"Wolf‐Brandstetter","full_name":"Wolf‐Brandstetter, Cornelia","first_name":"Cornelia"},{"first_name":"Dirk","last_name":"Kuckling","id":"287","full_name":"Kuckling, Dirk"}],"intvolume":"       308","citation":{"apa":"Methling, R., Dückmann, O., Simon, F., Wolf‐Brandstetter, C., &#38; Kuckling, D. (2023). Antimicrobial Brushes on Titanium via “Grafting to” Using Phosphonic Acid/Pyridinium Containing Block Copolymers. <i>Macromolecular Materials and Engineering</i>, <i>308</i>(8). <a href=\"https://doi.org/10.1002/mame.202200665\">https://doi.org/10.1002/mame.202200665</a>","mla":"Methling, Rafael, et al. “Antimicrobial Brushes on Titanium via ‘Grafting to’ Using Phosphonic Acid/Pyridinium Containing Block Copolymers.” <i>Macromolecular Materials and Engineering</i>, vol. 308, no. 8, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/mame.202200665\">10.1002/mame.202200665</a>.","short":"R. Methling, O. Dückmann, F. Simon, C. Wolf‐Brandstetter, D. Kuckling, Macromolecular Materials and Engineering 308 (2023).","bibtex":"@article{Methling_Dückmann_Simon_Wolf‐Brandstetter_Kuckling_2023, title={Antimicrobial Brushes on Titanium via “Grafting to” Using Phosphonic Acid/Pyridinium Containing Block Copolymers}, volume={308}, DOI={<a href=\"https://doi.org/10.1002/mame.202200665\">10.1002/mame.202200665</a>}, number={8}, journal={Macromolecular Materials and Engineering}, publisher={Wiley}, author={Methling, Rafael and Dückmann, Oliver and Simon, Frank and Wolf‐Brandstetter, Cornelia and Kuckling, Dirk}, year={2023} }","ieee":"R. Methling, O. Dückmann, F. Simon, C. Wolf‐Brandstetter, and D. Kuckling, “Antimicrobial Brushes on Titanium via ‘Grafting to’ Using Phosphonic Acid/Pyridinium Containing Block Copolymers,” <i>Macromolecular Materials and Engineering</i>, vol. 308, no. 8, 2023, doi: <a href=\"https://doi.org/10.1002/mame.202200665\">10.1002/mame.202200665</a>.","chicago":"Methling, Rafael, Oliver Dückmann, Frank Simon, Cornelia Wolf‐Brandstetter, and Dirk Kuckling. “Antimicrobial Brushes on Titanium via ‘Grafting to’ Using Phosphonic Acid/Pyridinium Containing Block Copolymers.” <i>Macromolecular Materials and Engineering</i> 308, no. 8 (2023). <a href=\"https://doi.org/10.1002/mame.202200665\">https://doi.org/10.1002/mame.202200665</a>.","ama":"Methling R, Dückmann O, Simon F, Wolf‐Brandstetter C, Kuckling D. Antimicrobial Brushes on Titanium via “Grafting to” Using Phosphonic Acid/Pyridinium Containing Block Copolymers. <i>Macromolecular Materials and Engineering</i>. 2023;308(8). doi:<a href=\"https://doi.org/10.1002/mame.202200665\">10.1002/mame.202200665</a>"},"publication_identifier":{"issn":["1438-7492","1439-2054"]},"publication_status":"published"},{"title":"Polymeric Networks Containing Amine Derivatives as Organocatalysts for Knoevenagel Reaction within Continuously Driven Microfluidic Reactors","publisher":"MDPI AG","date_created":"2024-04-03T11:06:26Z","year":"2023","issue":"3","keyword":["Knoevenagel reaction","organocatalysis","polymeric gel dots","microfluidic reactions","polymeric networks"],"language":[{"iso":"eng"}],"abstract":[{"lang":"eng","text":"<jats:p>The Knoevenagel reaction is a classic reaction in organic chemistry for the formation of C-C bonds. In this study, various catalytic monomers for Knoevenagel reactions were synthesized and polymerized via photolithography to form polymeric gel dots with a composition of 90% catalyst, 9% gelling agent and 1% crosslinker. Furthermore, these gel dots were inserted into a microfluidic reactor (MFR) and the conversion of the reaction using gel dots as catalysts in the MFR for 8 h at room temperature was studied. The gel dots containing primary amines showed a better conversion of about 83–90% with aliphatic aldehyde and 86–100% with aromatic aldehyde, compared to the tertiary amines (52–59% with aliphatic aldehyde and 77–93% with aromatic aldehydes) which resembles the reactivity of the amines. Moreover, the addition of polar solvent (water) in the reaction mixture and the swelling properties of the gel dots by altering the polymer backbone showed a significant enhancement in the conversion of the reaction, due to the increased accessibility of the catalytic sites in the polymeric network. These results suggested the primary-amine-based catalysts facilitate better conversion compared to tertiary amines and the reaction solvent had a significant influence on organocatalysis to improve the efficiency of MFR.</jats:p>"}],"publication":"Gels","doi":"10.3390/gels9030171","date_updated":"2024-04-03T11:07:31Z","author":[{"first_name":"Naresh","full_name":"Killi, Naresh","last_name":"Killi"},{"first_name":"Julian","full_name":"Bartenbach, Julian","last_name":"Bartenbach"},{"first_name":"Dirk","last_name":"Kuckling","full_name":"Kuckling, Dirk","id":"287"}],"volume":9,"citation":{"ieee":"N. Killi, J. Bartenbach, and D. Kuckling, “Polymeric Networks Containing Amine Derivatives as Organocatalysts for Knoevenagel Reaction within Continuously Driven Microfluidic Reactors,” <i>Gels</i>, vol. 9, no. 3, Art. no. 171, 2023, doi: <a href=\"https://doi.org/10.3390/gels9030171\">10.3390/gels9030171</a>.","chicago":"Killi, Naresh, Julian Bartenbach, and Dirk Kuckling. “Polymeric Networks Containing Amine Derivatives as Organocatalysts for Knoevenagel Reaction within Continuously Driven Microfluidic Reactors.” <i>Gels</i> 9, no. 3 (2023). <a href=\"https://doi.org/10.3390/gels9030171\">https://doi.org/10.3390/gels9030171</a>.","ama":"Killi N, Bartenbach J, Kuckling D. Polymeric Networks Containing Amine Derivatives as Organocatalysts for Knoevenagel Reaction within Continuously Driven Microfluidic Reactors. <i>Gels</i>. 2023;9(3). doi:<a href=\"https://doi.org/10.3390/gels9030171\">10.3390/gels9030171</a>","apa":"Killi, N., Bartenbach, J., &#38; Kuckling, D. (2023). Polymeric Networks Containing Amine Derivatives as Organocatalysts for Knoevenagel Reaction within Continuously Driven Microfluidic Reactors. <i>Gels</i>, <i>9</i>(3), Article 171. <a href=\"https://doi.org/10.3390/gels9030171\">https://doi.org/10.3390/gels9030171</a>","mla":"Killi, Naresh, et al. “Polymeric Networks Containing Amine Derivatives as Organocatalysts for Knoevenagel Reaction within Continuously Driven Microfluidic Reactors.” <i>Gels</i>, vol. 9, no. 3, 171, MDPI AG, 2023, doi:<a href=\"https://doi.org/10.3390/gels9030171\">10.3390/gels9030171</a>.","short":"N. Killi, J. Bartenbach, D. Kuckling, Gels 9 (2023).","bibtex":"@article{Killi_Bartenbach_Kuckling_2023, title={Polymeric Networks Containing Amine Derivatives as Organocatalysts for Knoevenagel Reaction within Continuously Driven Microfluidic Reactors}, volume={9}, DOI={<a href=\"https://doi.org/10.3390/gels9030171\">10.3390/gels9030171</a>}, number={3171}, journal={Gels}, publisher={MDPI AG}, author={Killi, Naresh and Bartenbach, Julian and Kuckling, Dirk}, year={2023} }"},"intvolume":"         9","publication_status":"published","publication_identifier":{"issn":["2310-2861"]},"article_type":"original","article_number":"171","_id":"53166","user_id":"94","department":[{"_id":"163"}],"status":"public","type":"journal_article"},{"page":"198","citation":{"ieee":"S. Strübbe, <i>Investigations of Ni-based methanation catalysts under dynamic conditions via hard X-ray spectroscopy</i>. Universitätsbibliothek Paderborn, 2023.","chicago":"Strübbe, Sven. <i>Investigations of Ni-Based Methanation Catalysts under Dynamic Conditions via Hard X-Ray Spectroscopy</i>. Universitätsbibliothek Paderborn, 2023. <a href=\"https://doi.org/10.17619/UNIPB/1-1752\">https://doi.org/10.17619/UNIPB/1-1752</a>.","ama":"Strübbe S. <i>Investigations of Ni-Based Methanation Catalysts under Dynamic Conditions via Hard X-Ray Spectroscopy</i>. Universitätsbibliothek Paderborn; 2023. doi:<a href=\"https://doi.org/10.17619/UNIPB/1-1752\">10.17619/UNIPB/1-1752</a>","mla":"Strübbe, Sven. <i>Investigations of Ni-Based Methanation Catalysts under Dynamic Conditions via Hard X-Ray Spectroscopy</i>. Universitätsbibliothek Paderborn, 2023, doi:<a href=\"https://doi.org/10.17619/UNIPB/1-1752\">10.17619/UNIPB/1-1752</a>.","bibtex":"@book{Strübbe_2023, title={Investigations of Ni-based methanation catalysts under dynamic conditions via hard X-ray spectroscopy}, DOI={<a href=\"https://doi.org/10.17619/UNIPB/1-1752\">10.17619/UNIPB/1-1752</a>}, publisher={Universitätsbibliothek Paderborn}, author={Strübbe, Sven}, year={2023} }","short":"S. Strübbe, Investigations of Ni-Based Methanation Catalysts under Dynamic Conditions via Hard X-Ray Spectroscopy, Universitätsbibliothek Paderborn, 2023.","apa":"Strübbe, S. (2023). <i>Investigations of Ni-based methanation catalysts under dynamic conditions via hard X-ray spectroscopy</i>. Universitätsbibliothek Paderborn. <a href=\"https://doi.org/10.17619/UNIPB/1-1752\">https://doi.org/10.17619/UNIPB/1-1752</a>"},"year":"2023","publication_status":"published","doi":"10.17619/UNIPB/1-1752","title":"Investigations of Ni-based methanation catalysts under dynamic conditions via hard X-ray spectroscopy","author":[{"full_name":"Strübbe, Sven","last_name":"Strübbe","first_name":"Sven"}],"date_created":"2024-04-11T14:00:57Z","date_updated":"2024-04-11T14:05:40Z","publisher":"Universitätsbibliothek Paderborn","status":"public","abstract":[{"lang":"eng","text":"Im Rahmen dieser Dissertation wurden Katalysatoren, welche auf der thermischen Zersetzung von metallorganischen Gerüstverbindungen basieren, mittels Röntgenabsorptionsspektroskopie (XAS) und Röntgenemissionsspektroskopie (XES) untersucht. Durch diesen synthetischen Ansatz können hochdisperse Ni-basierte Katalysatoren eingebettet in einer Kohlenstoffmatrix gewonnen werden, welche für die Methanisierung von CO2 Einsatz finden. Diese sollen eine hohe Stabilität gegenüber Wasserstoffausfällen aufweisen, welche bedingt durch Wetterfluktuationen in der Gewinnung von grünem Wasserstoff auftreten. Um ein derartiges System gezielt gestalten zu können, ist ein detailliertes Verständnis zugrundeliegender chemischer Mechanismen und damit einhergehend elektronischer Strukturen der Katalysatorsysteme notwendig. Durch die detaillierte Analyse der Katalysator-Vorstufen mittels XAS konnte gezeigt werden, dass auch unter reduktiven Bedingungen in der thermischen Zersetzung Spuren von Ni(II) vorliegen und keine reine Nifcc-Struktur erreicht werden konnte. Eine detaillierte Auswertung der gleichen Präkatalysatoren mittels XES konnte durch eine neuartige Kombination von HERFD-XANES, theoretischer Berechnungen und VtC-XES einen eindeutigen Beweis für das Vorhandensein der gewünschten Kohlenstoffmatrix sowie Spuren von NiO im Präkatalysator liefern, welche sich vorteilhaft auf die spätere Aktivität im finalen Katalysator auswirken. Abschließend konnte mittels einer in-situ Untersuchung der Temperaturbereich, in dem sich die aktive Katalysatorspezies ausbildet, auf 80 bis 200 C eingegrenzt werden. Schließlich konnte ein eindeutiger Zusammenhang zwischen dem Verlust einer stabilisierenden Kohlenstoffschicht und einem Rückgang der Aktivität belegt werden."},{"text":"This work aimed to establish methods based on X-ray absorption (XAS) and emission spectroscopy (XES) to study Ni-based catalysts obtained by the thermal decomposition of metal-organic framework compounds. Through the chosen synthetic approach, highly dispersed Ni-based catalysts embedded in a carbon matrix were obtained, suitable for the methanation of CO2. These catalysts are targeted to be highly stable against hydrogen dropouts that can occur due to weather fluctuations during the production of green hydrogen using water electrolysis. However, a detailed understanding of the underlying chemical mechanisms and the associated electronic structures of the catalyst systems is necessary to design such a system in a targeted manner. Detailed analysis of the catalyst precursor by XAS showed that although a suitable pre-catalyst can be prepared even under mildly reducing conditions, traces of Ni(II) are still present under reducing conditions during thermal decomposition, and a pure Nifcc structure was not achieved. Detailed XES analysis of the same pre-catalysts, using a novel combination of HERFD-XANES, theoretical calculations, and VtC-XES, provided clear evidence for the presence of the desired carbon matrix, as well as traces of NiO in the pre-catalyst, which has a beneficial effect on the subsequent activity in the final catalyst. Finally, by in-situ investigation, the temperature range in which the active catalyst species is formed could be narrowed down to 80 to 200 C. Furthermore, a clear correlation was proven between the loss of a stabilizing carbon layer and decreased activity.","lang":"eng"}],"type":"dissertation","language":[{"iso":"eng"}],"ddc":["540"],"department":[{"_id":"306"}],"user_id":"76968","_id":"53434"},{"doi":"10.1002/cctc.202300871","title":"Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes","volume":15,"author":[{"first_name":"Felix","full_name":"Ziegler, Felix","last_name":"Ziegler"},{"full_name":"Bruckner, Johanna R.","last_name":"Bruckner","first_name":"Johanna R."},{"first_name":"Michał","last_name":"Nowakowski","orcid":"0000-0002-3734-7011","id":"78878","full_name":"Nowakowski, Michał"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"first_name":"Patrick","last_name":"Probst","full_name":"Probst, Patrick"},{"first_name":"Boshra","full_name":"Atwi, Boshra","last_name":"Atwi"},{"last_name":"Buchmeiser","full_name":"Buchmeiser, Michael R.","first_name":"Michael R."}],"date_created":"2024-03-07T09:44:33Z","publisher":"Wiley","date_updated":"2024-05-07T11:41:51Z","intvolume":"        15","citation":{"mla":"Ziegler, Felix, et al. “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes.” <i>ChemCatChem</i>, vol. 15, no. 21, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/cctc.202300871\">10.1002/cctc.202300871</a>.","short":"F. Ziegler, J.R. Bruckner, M. Nowakowski, M. Bauer, P. Probst, B. Atwi, M.R. Buchmeiser, ChemCatChem 15 (2023).","bibtex":"@article{Ziegler_Bruckner_Nowakowski_Bauer_Probst_Atwi_Buchmeiser_2023, title={Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes}, volume={15}, DOI={<a href=\"https://doi.org/10.1002/cctc.202300871\">10.1002/cctc.202300871</a>}, number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Ziegler, Felix and Bruckner, Johanna R. and Nowakowski, Michał and Bauer, Matthias and Probst, Patrick and Atwi, Boshra and Buchmeiser, Michael R.}, year={2023} }","apa":"Ziegler, F., Bruckner, J. R., Nowakowski, M., Bauer, M., Probst, P., Atwi, B., &#38; Buchmeiser, M. R. (2023). Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes. <i>ChemCatChem</i>, <i>15</i>(21). <a href=\"https://doi.org/10.1002/cctc.202300871\">https://doi.org/10.1002/cctc.202300871</a>","ama":"Ziegler F, Bruckner JR, Nowakowski M, et al. Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes. <i>ChemCatChem</i>. 2023;15(21). doi:<a href=\"https://doi.org/10.1002/cctc.202300871\">10.1002/cctc.202300871</a>","ieee":"F. Ziegler <i>et al.</i>, “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes,” <i>ChemCatChem</i>, vol. 15, no. 21, 2023, doi: <a href=\"https://doi.org/10.1002/cctc.202300871\">10.1002/cctc.202300871</a>.","chicago":"Ziegler, Felix, Johanna R. Bruckner, Michał Nowakowski, Matthias Bauer, Patrick Probst, Boshra Atwi, and Michael R. Buchmeiser. “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes.” <i>ChemCatChem</i> 15, no. 21 (2023). <a href=\"https://doi.org/10.1002/cctc.202300871\">https://doi.org/10.1002/cctc.202300871</a>."},"year":"2023","issue":"21","publication_identifier":{"issn":["1867-3880","1867-3899"]},"publication_status":"published","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"article_type":"original","department":[{"_id":"306"}],"user_id":"48467","_id":"52344","status":"public","abstract":[{"lang":"eng","text":"Macrocyclization reactions are still challenging due to competing oligomerization, which requires the use of small substrate concentrations. Here, the cationic tungsten imido and tungsten oxo alkylidene N-heterocyclic carbene complexes [[W(N-2,6-Cl2-C6H3)(CHCMe2Ph(OC6F5)(pivalonitrile)(IMes)+ B(ArF)4−] (W1) and [W(O)(CHCMe2Ph(OCMe(CF3)2)(IMes)(CH3CN)+ B(ArF)4−] (W2) (IMes=1,3-dimesitylimidazol-2-ylidene; B(ArF)4−=tetrakis(3,5-bis(trifluoromethyl)phenyl borate) have been immobilized inside the pores of ordered mesoporous silica (OMS) with pore diameters of 3.3 and 6.8 nm, respectively, using a pore-selective immobilization protocol. X-ray absorption spectroscopy of W1@OMS showed that even though the catalyst structure is contracted due to confinement by the mesopores, both the oxidation state and structure of the catalyst stayed intact upon immobilization. Catalytic testing with four differently sized α,ω-dienes revealed a dramatically increased macrocyclization (MC) and Z-selectivity of the supported catalysts compared to the homogenous progenitors, allowing high substrate concentrations of 25 mM. With the supported complexes, a maximum increase in MC-selectivity from 27 to 81 % and in Z-selectivity from 17 to 34 % was achieved. In general, smaller mesopores exhibited a stronger confinement effect. A comparison of the two supported tungsten-based catalysts showed that W1@OMS possesses a higher MC-selectivity, while W2@OMS exhibits a higher Z-selectivity which can be rationalized by the structures of the catalysts."}],"publication":"ChemCatChem","type":"journal_article"},{"keyword":["Atomic and Molecular Physics","and Optics","Statistical and Nonlinear Physics"],"language":[{"iso":"eng"}],"publication":"Journal of the Optical Society of America B","abstract":[{"text":"The Saharan desert ant Cataglyphis bombycina is densely covered with shiny silver setae (hair-like structures). Their appearance was explained by geometric optics and total internal reflection. The setae also increase the emissivity of the ant, as they form an effective medium. This work provides additional data on microstructural details of the setae that are used to simulate the scattering of an individual seta to explain their influence on the optical properties. This is achieved by characterization of their structure using light microscopy and scanning/transmission electron microscopy. How the microstructural features influence scattering is investigated wave-optically within the limits of finite-difference time-domain simulations from the ultraviolet to the mid-infrared spectral range to elucidate the optical effects beyond ray optics and effective medium theory. The results show that Mie scattering plays an important role in protecting the ant from solar radiation and could be relevant for its thermal tolerance.","lang":"eng"}],"publisher":"Optica Publishing Group","date_created":"2023-03-02T17:48:38Z","title":"Broadband Mie scattering effects by structural features of setae from the Saharan silver ant Cataglyphis bombycina","quality_controlled":"1","issue":"3","year":"2023","_id":"42679","department":[{"_id":"35"},{"_id":"2"},{"_id":"307"},{"_id":"230"}],"user_id":"23547","article_type":"original","type":"journal_article","status":"public","date_updated":"2024-05-22T14:29:39Z","volume":40,"author":[{"first_name":"Bertram","full_name":"Schwind, Bertram","last_name":"Schwind"},{"first_name":"Xia","last_name":"Wu","full_name":"Wu, Xia"},{"full_name":"Tiemann, Michael","id":"23547","orcid":"0000-0003-1711-2722","last_name":"Tiemann","first_name":"Michael"},{"first_name":"Helge-Otto","last_name":"Fabritius","full_name":"Fabritius, Helge-Otto"}],"doi":"10.1364/josab.474899","publication_identifier":{"issn":["0740-3224","1520-8540"]},"publication_status":"published","intvolume":"        40","page":"B49 - B58","citation":{"ieee":"B. Schwind, X. Wu, M. Tiemann, and H.-O. Fabritius, “Broadband Mie scattering effects by structural features of setae from the Saharan silver ant Cataglyphis bombycina,” <i>Journal of the Optical Society of America B</i>, vol. 40, no. 3, pp. B49–B58, 2023, doi: <a href=\"https://doi.org/10.1364/josab.474899\">10.1364/josab.474899</a>.","chicago":"Schwind, Bertram, Xia Wu, Michael Tiemann, and Helge-Otto Fabritius. “Broadband Mie Scattering Effects by Structural Features of Setae from the Saharan Silver Ant Cataglyphis Bombycina.” <i>Journal of the Optical Society of America B</i> 40, no. 3 (2023): B49–58. <a href=\"https://doi.org/10.1364/josab.474899\">https://doi.org/10.1364/josab.474899</a>.","ama":"Schwind B, Wu X, Tiemann M, Fabritius H-O. Broadband Mie scattering effects by structural features of setae from the Saharan silver ant Cataglyphis bombycina. <i>Journal of the Optical Society of America B</i>. 2023;40(3):B49-B58. doi:<a href=\"https://doi.org/10.1364/josab.474899\">10.1364/josab.474899</a>","apa":"Schwind, B., Wu, X., Tiemann, M., &#38; Fabritius, H.-O. (2023). Broadband Mie scattering effects by structural features of setae from the Saharan silver ant Cataglyphis bombycina. <i>Journal of the Optical Society of America B</i>, <i>40</i>(3), B49–B58. <a href=\"https://doi.org/10.1364/josab.474899\">https://doi.org/10.1364/josab.474899</a>","bibtex":"@article{Schwind_Wu_Tiemann_Fabritius_2023, title={Broadband Mie scattering effects by structural features of setae from the Saharan silver ant Cataglyphis bombycina}, volume={40}, DOI={<a href=\"https://doi.org/10.1364/josab.474899\">10.1364/josab.474899</a>}, number={3}, journal={Journal of the Optical Society of America B}, publisher={Optica Publishing Group}, author={Schwind, Bertram and Wu, Xia and Tiemann, Michael and Fabritius, Helge-Otto}, year={2023}, pages={B49–B58} }","mla":"Schwind, Bertram, et al. “Broadband Mie Scattering Effects by Structural Features of Setae from the Saharan Silver Ant Cataglyphis Bombycina.” <i>Journal of the Optical Society of America B</i>, vol. 40, no. 3, Optica Publishing Group, 2023, pp. B49–58, doi:<a href=\"https://doi.org/10.1364/josab.474899\">10.1364/josab.474899</a>.","short":"B. Schwind, X. Wu, M. Tiemann, H.-O. Fabritius, Journal of the Optical Society of America B 40 (2023) B49–B58."}},{"date_updated":"2024-09-05T11:44:07Z","author":[{"first_name":"Jakob","full_name":"Steube, Jakob","id":"40342","orcid":"0000-0003-3178-4429","last_name":"Steube"},{"first_name":"Ayla","last_name":"Kruse","full_name":"Kruse, Ayla"},{"first_name":"Olga S.","full_name":"Bokareva, Olga S.","last_name":"Bokareva"},{"first_name":"Thomas","last_name":"Reuter","full_name":"Reuter, Thomas"},{"last_name":"Demeshko","full_name":"Demeshko, Serhiy","first_name":"Serhiy"},{"first_name":"Roland","id":"48467","full_name":"Schoch, Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch"},{"full_name":"Argüello Cordero, Miguel A.","last_name":"Argüello Cordero","first_name":"Miguel A."},{"last_name":"Krishna","full_name":"Krishna, Athul","first_name":"Athul"},{"first_name":"Stephan","last_name":"Hohloch","full_name":"Hohloch, Stephan"},{"first_name":"Franc","last_name":"Meyer","full_name":"Meyer, Franc"},{"full_name":"Heinze, Katja","last_name":"Heinze","first_name":"Katja"},{"last_name":"Kühn","full_name":"Kühn, Oliver","first_name":"Oliver"},{"first_name":"Stefan","full_name":"Lochbrunner, Stefan","last_name":"Lochbrunner"},{"last_name":"Bauer","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"}],"volume":15,"doi":"10.1038/s41557-023-01137-w","publication_status":"published","publication_identifier":{"issn":["1755-4330","1755-4349"]},"citation":{"short":"J. Steube, A. Kruse, O.S. Bokareva, T. Reuter, S. Demeshko, R. Schoch, M.A. Argüello Cordero, A. Krishna, S. Hohloch, F. Meyer, K. Heinze, O. Kühn, S. Lochbrunner, M. Bauer, Nature Chemistry 15 (2023) 468–474.","mla":"Steube, Jakob, et al. “Janus-Type Emission from a Cyclometalated Iron(Iii) Complex.” <i>Nature Chemistry</i>, vol. 15, no. 4, Springer Science and Business Media LLC, 2023, pp. 468–74, doi:<a href=\"https://doi.org/10.1038/s41557-023-01137-w\">10.1038/s41557-023-01137-w</a>.","bibtex":"@article{Steube_Kruse_Bokareva_Reuter_Demeshko_Schoch_Argüello Cordero_Krishna_Hohloch_Meyer_et al._2023, title={Janus-type emission from a cyclometalated iron(iii) complex}, volume={15}, DOI={<a href=\"https://doi.org/10.1038/s41557-023-01137-w\">10.1038/s41557-023-01137-w</a>}, number={4}, journal={Nature Chemistry}, publisher={Springer Science and Business Media LLC}, author={Steube, Jakob and Kruse, Ayla and Bokareva, Olga S. and Reuter, Thomas and Demeshko, Serhiy and Schoch, Roland and Argüello Cordero, Miguel A. and Krishna, Athul and Hohloch, Stephan and Meyer, Franc and et al.}, year={2023}, pages={468–474} }","apa":"Steube, J., Kruse, A., Bokareva, O. S., Reuter, T., Demeshko, S., Schoch, R., Argüello Cordero, M. A., Krishna, A., Hohloch, S., Meyer, F., Heinze, K., Kühn, O., Lochbrunner, S., &#38; Bauer, M. (2023). Janus-type emission from a cyclometalated iron(iii) complex. <i>Nature Chemistry</i>, <i>15</i>(4), 468–474. <a href=\"https://doi.org/10.1038/s41557-023-01137-w\">https://doi.org/10.1038/s41557-023-01137-w</a>","ieee":"J. Steube <i>et al.</i>, “Janus-type emission from a cyclometalated iron(iii) complex,” <i>Nature Chemistry</i>, vol. 15, no. 4, pp. 468–474, 2023, doi: <a href=\"https://doi.org/10.1038/s41557-023-01137-w\">10.1038/s41557-023-01137-w</a>.","chicago":"Steube, Jakob, Ayla Kruse, Olga S. Bokareva, Thomas Reuter, Serhiy Demeshko, Roland Schoch, Miguel A. Argüello Cordero, et al. “Janus-Type Emission from a Cyclometalated Iron(Iii) Complex.” <i>Nature Chemistry</i> 15, no. 4 (2023): 468–74. <a href=\"https://doi.org/10.1038/s41557-023-01137-w\">https://doi.org/10.1038/s41557-023-01137-w</a>.","ama":"Steube J, Kruse A, Bokareva OS, et al. Janus-type emission from a cyclometalated iron(iii) complex. <i>Nature Chemistry</i>. 2023;15(4):468-474. doi:<a href=\"https://doi.org/10.1038/s41557-023-01137-w\">10.1038/s41557-023-01137-w</a>"},"page":"468-474","intvolume":"        15","_id":"46481","user_id":"48467","department":[{"_id":"306"}],"type":"journal_article","status":"public","publisher":"Springer Science and Business Media LLC","date_created":"2023-08-11T19:57:32Z","title":"Janus-type emission from a cyclometalated iron(iii) complex","issue":"4","year":"2023","keyword":["General Chemical Engineering","General Chemistry"],"language":[{"iso":"eng"}],"publication":"Nature Chemistry","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>Although iron is a dream candidate to substitute noble metals in photoactive complexes, realization of emissive and photoactive iron compounds is demanding due to the fast deactivation of their charge-transfer states. Emissive iron compounds are scarce and dual emission has not been observed before. Here we report the Fe<jats:sup>III</jats:sup> complex [Fe(ImP)<jats:sub>2</jats:sub>][PF<jats:sub>6</jats:sub>] (HImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazol-2-ylidene)), showing a Janus-type dual emission from ligand-to-metal charge transfer (LMCT)- and metal-to-ligand charge transfer (MLCT)-dominated states. This behaviour is achieved by a ligand design that combines four <jats:italic>N</jats:italic>-heterocyclic carbenes with two cyclometalating aryl units. The low-lying <jats:italic>π</jats:italic>* levels of the cyclometalating units lead to energetically accessible MLCT states that cannot evolve into LMCT states. With a lifetime of 4.6 ns, the strongly reducing and oxidizing MLCT-dominated state can initiate electron transfer reactions, which could constitute a basis for future applications of iron in photoredox catalysis.</jats:p>","lang":"eng"}]},{"title":"Dynamics of DNA Origami Lattices","doi":"10.1021/acs.bioconjchem.2c00359","date_updated":"2023-01-18T08:31:47Z","publisher":"American Chemical Society (ACS)","volume":34,"author":[{"full_name":"Julin, Sofia","last_name":"Julin","first_name":"Sofia"},{"last_name":"Keller","orcid":"0000-0001-7139-3110","full_name":"Keller, Adrian","id":"48864","first_name":"Adrian"},{"last_name":"Linko","full_name":"Linko, Veikko","first_name":"Veikko"}],"date_created":"2022-09-19T07:44:24Z","year":"2023","page":"18-29","intvolume":"        34","citation":{"ieee":"S. Julin, A. Keller, and V. Linko, “Dynamics of DNA Origami Lattices,” <i>Bioconjugate Chemistry</i>, vol. 34, pp. 18–29, 2023, doi: <a href=\"https://doi.org/10.1021/acs.bioconjchem.2c00359\">10.1021/acs.bioconjchem.2c00359</a>.","chicago":"Julin, Sofia, Adrian Keller, and Veikko Linko. “Dynamics of DNA Origami Lattices.” <i>Bioconjugate Chemistry</i> 34 (2023): 18–29. <a href=\"https://doi.org/10.1021/acs.bioconjchem.2c00359\">https://doi.org/10.1021/acs.bioconjchem.2c00359</a>.","ama":"Julin S, Keller A, Linko V. Dynamics of DNA Origami Lattices. <i>Bioconjugate Chemistry</i>. 2023;34:18-29. doi:<a href=\"https://doi.org/10.1021/acs.bioconjchem.2c00359\">10.1021/acs.bioconjchem.2c00359</a>","apa":"Julin, S., Keller, A., &#38; Linko, V. (2023). Dynamics of DNA Origami Lattices. <i>Bioconjugate Chemistry</i>, <i>34</i>, 18–29. <a href=\"https://doi.org/10.1021/acs.bioconjchem.2c00359\">https://doi.org/10.1021/acs.bioconjchem.2c00359</a>","short":"S. Julin, A. Keller, V. Linko, Bioconjugate Chemistry 34 (2023) 18–29.","mla":"Julin, Sofia, et al. “Dynamics of DNA Origami Lattices.” <i>Bioconjugate Chemistry</i>, vol. 34, American Chemical Society (ACS), 2023, pp. 18–29, doi:<a href=\"https://doi.org/10.1021/acs.bioconjchem.2c00359\">10.1021/acs.bioconjchem.2c00359</a>.","bibtex":"@article{Julin_Keller_Linko_2023, title={Dynamics of DNA Origami Lattices}, volume={34}, DOI={<a href=\"https://doi.org/10.1021/acs.bioconjchem.2c00359\">10.1021/acs.bioconjchem.2c00359</a>}, journal={Bioconjugate Chemistry}, publisher={American Chemical Society (ACS)}, author={Julin, Sofia and Keller, Adrian and Linko, Veikko}, year={2023}, pages={18–29} }"},"publication_identifier":{"issn":["1043-1802","1520-4812"]},"publication_status":"published","keyword":["Organic Chemistry","Pharmaceutical Science","Pharmacology","Biomedical Engineering","Bioengineering","Biotechnology"],"language":[{"iso":"eng"}],"_id":"33447","department":[{"_id":"302"}],"user_id":"48864","status":"public","publication":"Bioconjugate Chemistry","type":"journal_article"},{"user_id":"84268","department":[{"_id":"633"}],"_id":"37267","language":[{"iso":"eng"}],"keyword":["General Materials Science","Renewable Energy","Sustainability and the Environment"],"type":"journal_article","publication":"Advanced Energy Materials","status":"public","date_created":"2023-01-18T09:47:47Z","author":[{"first_name":"Aashutosh","last_name":"Mistry","full_name":"Mistry, Aashutosh"},{"last_name":"Srinivasan","full_name":"Srinivasan, Venkat","first_name":"Venkat"},{"last_name":"Steinrück","orcid":"0000-0001-6373-0877","full_name":"Steinrück, Hans-Georg","id":"84268","first_name":"Hans-Georg"}],"volume":13,"publisher":"Wiley","date_updated":"2023-03-23T08:28:44Z","doi":"10.1002/aenm.202203690","title":"Characterizing Ion Transport in Electrolytes via Concentration and Velocity Profiles","publication_status":"published","publication_identifier":{"issn":["1614-6832","1614-6840"]},"citation":{"ama":"Mistry A, Srinivasan V, Steinrück H-G. Characterizing Ion Transport in Electrolytes via Concentration and Velocity Profiles. <i>Advanced Energy Materials</i>. 2023;13:2203690. doi:<a href=\"https://doi.org/10.1002/aenm.202203690\">10.1002/aenm.202203690</a>","chicago":"Mistry, Aashutosh, Venkat Srinivasan, and Hans-Georg Steinrück. “Characterizing Ion Transport in Electrolytes via Concentration and Velocity Profiles.” <i>Advanced Energy Materials</i> 13 (2023): 2203690. <a href=\"https://doi.org/10.1002/aenm.202203690\">https://doi.org/10.1002/aenm.202203690</a>.","ieee":"A. Mistry, V. Srinivasan, and H.-G. Steinrück, “Characterizing Ion Transport in Electrolytes via Concentration and Velocity Profiles,” <i>Advanced Energy Materials</i>, vol. 13, p. 2203690, 2023, doi: <a href=\"https://doi.org/10.1002/aenm.202203690\">10.1002/aenm.202203690</a>.","short":"A. Mistry, V. Srinivasan, H.-G. Steinrück, Advanced Energy Materials 13 (2023) 2203690.","mla":"Mistry, Aashutosh, et al. “Characterizing Ion Transport in Electrolytes via Concentration and Velocity Profiles.” <i>Advanced Energy Materials</i>, vol. 13, Wiley, 2023, p. 2203690, doi:<a href=\"https://doi.org/10.1002/aenm.202203690\">10.1002/aenm.202203690</a>.","bibtex":"@article{Mistry_Srinivasan_Steinrück_2023, title={Characterizing Ion Transport in Electrolytes via Concentration and Velocity Profiles}, volume={13}, DOI={<a href=\"https://doi.org/10.1002/aenm.202203690\">10.1002/aenm.202203690</a>}, journal={Advanced Energy Materials}, publisher={Wiley}, author={Mistry, Aashutosh and Srinivasan, Venkat and Steinrück, Hans-Georg}, year={2023}, pages={2203690} }","apa":"Mistry, A., Srinivasan, V., &#38; Steinrück, H.-G. (2023). Characterizing Ion Transport in Electrolytes via Concentration and Velocity Profiles. <i>Advanced Energy Materials</i>, <i>13</i>, 2203690. <a href=\"https://doi.org/10.1002/aenm.202203690\">https://doi.org/10.1002/aenm.202203690</a>"},"intvolume":"        13","page":"2203690","year":"2023"}]