[{"article_number":"127417","language":[{"iso":"eng"}],"_id":"22539","department":[{"_id":"302"}],"user_id":"54556","status":"public","publication":"Surface and Coatings Technology","type":"journal_article","title":"Design of a TiAlON multilayer coating: Oxidation stability and deformation behavior","doi":"10.1016/j.surfcoat.2021.127417","date_updated":"2023-01-24T08:33:14Z","date_created":"2021-07-07T08:38:02Z","author":[{"first_name":"K.","full_name":"Bobzin, K.","last_name":"Bobzin"},{"last_name":"Kalscheuer","full_name":"Kalscheuer, C.","first_name":"C."},{"first_name":"G.","full_name":"Grundmeier, G.","last_name":"Grundmeier"},{"id":"54556","full_name":"de los Arcos de Pedro, Maria Teresa","last_name":"de los Arcos de Pedro","first_name":"Maria Teresa"},{"full_name":"Schwiderek, S.","last_name":"Schwiderek","first_name":"S."},{"last_name":"Carlet","full_name":"Carlet, M.","first_name":"M."}],"year":"2021","citation":{"apa":"Bobzin, K., Kalscheuer, C., Grundmeier, G., de los Arcos de Pedro, M. T., Schwiderek, S., &#38; Carlet, M. (2021). Design of a TiAlON multilayer coating: Oxidation stability and deformation behavior. <i>Surface and Coatings Technology</i>, Article 127417. <a href=\"https://doi.org/10.1016/j.surfcoat.2021.127417\">https://doi.org/10.1016/j.surfcoat.2021.127417</a>","short":"K. Bobzin, C. Kalscheuer, G. Grundmeier, M.T. de los Arcos de Pedro, S. Schwiderek, M. Carlet, Surface and Coatings Technology (2021).","bibtex":"@article{Bobzin_Kalscheuer_Grundmeier_de los Arcos de Pedro_Schwiderek_Carlet_2021, title={Design of a TiAlON multilayer coating: Oxidation stability and deformation behavior}, DOI={<a href=\"https://doi.org/10.1016/j.surfcoat.2021.127417\">10.1016/j.surfcoat.2021.127417</a>}, number={127417}, journal={Surface and Coatings Technology}, author={Bobzin, K. and Kalscheuer, C. and Grundmeier, G. and de los Arcos de Pedro, Maria Teresa and Schwiderek, S. and Carlet, M.}, year={2021} }","mla":"Bobzin, K., et al. “Design of a TiAlON Multilayer Coating: Oxidation Stability and Deformation Behavior.” <i>Surface and Coatings Technology</i>, 127417, 2021, doi:<a href=\"https://doi.org/10.1016/j.surfcoat.2021.127417\">10.1016/j.surfcoat.2021.127417</a>.","ama":"Bobzin K, Kalscheuer C, Grundmeier G, de los Arcos de Pedro MT, Schwiderek S, Carlet M. Design of a TiAlON multilayer coating: Oxidation stability and deformation behavior. <i>Surface and Coatings Technology</i>. Published online 2021. doi:<a href=\"https://doi.org/10.1016/j.surfcoat.2021.127417\">10.1016/j.surfcoat.2021.127417</a>","chicago":"Bobzin, K., C. Kalscheuer, G. Grundmeier, Maria Teresa de los Arcos de Pedro, S. Schwiderek, and M. Carlet. “Design of a TiAlON Multilayer Coating: Oxidation Stability and Deformation Behavior.” <i>Surface and Coatings Technology</i>, 2021. <a href=\"https://doi.org/10.1016/j.surfcoat.2021.127417\">https://doi.org/10.1016/j.surfcoat.2021.127417</a>.","ieee":"K. Bobzin, C. Kalscheuer, G. Grundmeier, M. T. de los Arcos de Pedro, S. Schwiderek, and M. Carlet, “Design of a TiAlON multilayer coating: Oxidation stability and deformation behavior,” <i>Surface and Coatings Technology</i>, Art. no. 127417, 2021, doi: <a href=\"https://doi.org/10.1016/j.surfcoat.2021.127417\">10.1016/j.surfcoat.2021.127417</a>."},"publication_identifier":{"issn":["0257-8972"]},"publication_status":"published"},{"user_id":"54556","department":[{"_id":"302"}],"_id":"22535","language":[{"iso":"eng"}],"type":"journal_article","publication":"Journal of Raman Spectroscopy","status":"public","date_created":"2021-07-07T08:34:37Z","author":[{"first_name":"Steffen","full_name":"Knust, Steffen","last_name":"Knust"},{"full_name":"Ruhm, Lukas","last_name":"Ruhm","first_name":"Lukas"},{"first_name":"Andreas","full_name":"Kuhlmann, Andreas","last_name":"Kuhlmann"},{"last_name":"Meinderink","full_name":"Meinderink, Dennis","first_name":"Dennis"},{"full_name":"Bürger, Julius","last_name":"Bürger","first_name":"Julius"},{"first_name":"Jörg K. N.","last_name":"Lindner","full_name":"Lindner, Jörg K. N."},{"first_name":"Maria Teresa","last_name":"de los Arcos de Pedro","full_name":"de los Arcos de Pedro, Maria Teresa","id":"54556"},{"first_name":"Guido","id":"194","full_name":"Grundmeier, Guido","last_name":"Grundmeier"}],"date_updated":"2023-01-24T08:52:47Z","doi":"10.1002/jrs.6123","title":"In situ backside Raman spectroscopy of zinc oxide nanorods in an atmospheric‐pressure dielectric barrier discharge plasma","publication_status":"published","publication_identifier":{"issn":["0377-0486","1097-4555"]},"citation":{"ieee":"S. Knust <i>et al.</i>, “In situ backside Raman spectroscopy of zinc oxide nanorods in an atmospheric‐pressure dielectric barrier discharge plasma,” <i>Journal of Raman Spectroscopy</i>, pp. 1237–1245, 2021, doi: <a href=\"https://doi.org/10.1002/jrs.6123\">10.1002/jrs.6123</a>.","chicago":"Knust, Steffen, Lukas Ruhm, Andreas Kuhlmann, Dennis Meinderink, Julius Bürger, Jörg K. N. Lindner, Maria Teresa de los Arcos de Pedro, and Guido Grundmeier. “In Situ Backside Raman Spectroscopy of Zinc Oxide Nanorods in an Atmospheric‐pressure Dielectric Barrier Discharge Plasma.” <i>Journal of Raman Spectroscopy</i>, 2021, 1237–45. <a href=\"https://doi.org/10.1002/jrs.6123\">https://doi.org/10.1002/jrs.6123</a>.","ama":"Knust S, Ruhm L, Kuhlmann A, et al. In situ backside Raman spectroscopy of zinc oxide nanorods in an atmospheric‐pressure dielectric barrier discharge plasma. <i>Journal of Raman Spectroscopy</i>. Published online 2021:1237-1245. doi:<a href=\"https://doi.org/10.1002/jrs.6123\">10.1002/jrs.6123</a>","bibtex":"@article{Knust_Ruhm_Kuhlmann_Meinderink_Bürger_Lindner_de los Arcos de Pedro_Grundmeier_2021, title={In situ backside Raman spectroscopy of zinc oxide nanorods in an atmospheric‐pressure dielectric barrier discharge plasma}, DOI={<a href=\"https://doi.org/10.1002/jrs.6123\">10.1002/jrs.6123</a>}, journal={Journal of Raman Spectroscopy}, author={Knust, Steffen and Ruhm, Lukas and Kuhlmann, Andreas and Meinderink, Dennis and Bürger, Julius and Lindner, Jörg K. N. and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido}, year={2021}, pages={1237–1245} }","mla":"Knust, Steffen, et al. “In Situ Backside Raman Spectroscopy of Zinc Oxide Nanorods in an Atmospheric‐pressure Dielectric Barrier Discharge Plasma.” <i>Journal of Raman Spectroscopy</i>, 2021, pp. 1237–45, doi:<a href=\"https://doi.org/10.1002/jrs.6123\">10.1002/jrs.6123</a>.","short":"S. Knust, L. Ruhm, A. Kuhlmann, D. Meinderink, J. Bürger, J.K.N. Lindner, M.T. de los Arcos de Pedro, G. Grundmeier, Journal of Raman Spectroscopy (2021) 1237–1245.","apa":"Knust, S., Ruhm, L., Kuhlmann, A., Meinderink, D., Bürger, J., Lindner, J. K. N., de los Arcos de Pedro, M. T., &#38; Grundmeier, G. (2021). In situ backside Raman spectroscopy of zinc oxide nanorods in an atmospheric‐pressure dielectric barrier discharge plasma. <i>Journal of Raman Spectroscopy</i>, 1237–1245. <a href=\"https://doi.org/10.1002/jrs.6123\">https://doi.org/10.1002/jrs.6123</a>"},"page":"1237-1245","year":"2021"},{"type":"dissertation","status":"public","user_id":"27611","department":[{"_id":"35"},{"_id":"306"}],"_id":"41006","language":[{"iso":"eng"}],"citation":{"ieee":"S. Schlicher, <i>Iron oxide catalysts for CO oxidation : from basic structure-activity-correlation to an advanced preparation strategy for highly active catalysts</i>. 2021.","chicago":"Schlicher, Steffen. <i>Iron Oxide Catalysts for CO Oxidation : From Basic Structure-Activity-Correlation to an Advanced Preparation Strategy for Highly Active Catalysts</i>, 2021. <a href=\"https://doi.org/10.17619/UNIPB/1-1089\">https://doi.org/10.17619/UNIPB/1-1089</a>.","ama":"Schlicher S. <i>Iron Oxide Catalysts for CO Oxidation : From Basic Structure-Activity-Correlation to an Advanced Preparation Strategy for Highly Active Catalysts</i>.; 2021. doi:<a href=\"https://doi.org/10.17619/UNIPB/1-1089\">10.17619/UNIPB/1-1089</a>","bibtex":"@book{Schlicher_2021, title={Iron oxide catalysts for CO oxidation : from basic structure-activity-correlation to an advanced preparation strategy for highly active catalysts}, DOI={<a href=\"https://doi.org/10.17619/UNIPB/1-1089\">10.17619/UNIPB/1-1089</a>}, author={Schlicher, Steffen}, year={2021} }","mla":"Schlicher, Steffen. <i>Iron Oxide Catalysts for CO Oxidation : From Basic Structure-Activity-Correlation to an Advanced Preparation Strategy for Highly Active Catalysts</i>. 2021, doi:<a href=\"https://doi.org/10.17619/UNIPB/1-1089\">10.17619/UNIPB/1-1089</a>.","short":"S. Schlicher, Iron Oxide Catalysts for CO Oxidation : From Basic Structure-Activity-Correlation to an Advanced Preparation Strategy for Highly Active Catalysts, 2021.","apa":"Schlicher, S. (2021). <i>Iron oxide catalysts for CO oxidation : from basic structure-activity-correlation to an advanced preparation strategy for highly active catalysts</i>. <a href=\"https://doi.org/10.17619/UNIPB/1-1089\">https://doi.org/10.17619/UNIPB/1-1089</a>"},"year":"2021","supervisor":[{"last_name":"Bauer","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"}],"author":[{"last_name":"Schlicher","full_name":"Schlicher, Steffen","first_name":"Steffen"}],"date_created":"2023-01-30T16:59:34Z","date_updated":"2023-01-31T08:19:09Z","doi":"10.17619/UNIPB/1-1089","title":"Iron oxide catalysts for CO oxidation : from basic structure-activity-correlation to an advanced preparation strategy for highly active catalysts"},{"title":"Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO<sub>2</sub> Hydrogenation","date_created":"2023-01-30T16:49:18Z","publisher":"American Chemical Society (ACS)","year":"2021","issue":"27","language":[{"iso":"eng"}],"keyword":["Surfaces","Coatings and Films","Physical and Theoretical Chemistry","General Energy","Electronic","Optical and Magnetic Materials"],"abstract":[{"lang":"eng","text":"Homogeneous catalysts immobilized on metal oxides often have different catalytic properties than in homogeneous solution. This can be either activating or deactivating and is often attributed to interactions of catalyst species with the metal oxide surface. However, few studies have ever demonstrated the effect that close associations of active sites with surfaces have on the catalytic activity. In this paper, we immobilize H2Ru(PPh3)2(Ph2P)2N–C3H6–Si(OEt)3 (3) on SiO2, Al2O3, and ZnO and interrogate the relationship to the surface using IR, MAS NMR, 1H–31P HETCOR, and XAS spectroscopies. We found that while there are close contacts between the P atoms of the complex and all three metal oxide surfaces, the Ru–H bond only reacts with oxygen bridges on SiO2 and Al2O3, forming new Ru–O bonds. In contrast, complex 3 stays intact on ZnO. Comparison of the catalytic activities of our immobilized species for CO2 hydrogenation to ethyl formate showed that Lewis acidic metal oxides activate, rather than deactivate, complex 3 in the order Al2O3 > ZnO > SiO2. The Lewis acidic sites on the metal oxide surfaces most likely increase the productivity by increasing the rate of esterification of formate intermediates."}],"publication":"The Journal of Physical Chemistry C","doi":"10.1021/acs.jpcc.1c02074","author":[{"last_name":"Nguyen","full_name":"Nguyen, Hoang-Huy","first_name":"Hoang-Huy"},{"full_name":"Li, Zheng","last_name":"Li","first_name":"Zheng"},{"first_name":"Toni","full_name":"Enenkel, Toni","last_name":"Enenkel"},{"first_name":"Joachim","last_name":"Hildebrand","full_name":"Hildebrand, Joachim"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"last_name":"Dyballa","full_name":"Dyballa, Michael","first_name":"Michael"},{"first_name":"Deven P.","last_name":"Estes","full_name":"Estes, Deven P."}],"volume":125,"date_updated":"2023-01-31T08:06:00Z","citation":{"ama":"Nguyen H-H, Li Z, Enenkel T, et al. Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO<sub>2</sub> Hydrogenation. <i>The Journal of Physical Chemistry C</i>. 2021;125(27):14627-14635. doi:<a href=\"https://doi.org/10.1021/acs.jpcc.1c02074\">10.1021/acs.jpcc.1c02074</a>","chicago":"Nguyen, Hoang-Huy, Zheng Li, Toni Enenkel, Joachim Hildebrand, Matthias Bauer, Michael Dyballa, and Deven P. Estes. “Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO<sub>2</sub> Hydrogenation.” <i>The Journal of Physical Chemistry C</i> 125, no. 27 (2021): 14627–35. <a href=\"https://doi.org/10.1021/acs.jpcc.1c02074\">https://doi.org/10.1021/acs.jpcc.1c02074</a>.","ieee":"H.-H. Nguyen <i>et al.</i>, “Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO<sub>2</sub> Hydrogenation,” <i>The Journal of Physical Chemistry C</i>, vol. 125, no. 27, pp. 14627–14635, 2021, doi: <a href=\"https://doi.org/10.1021/acs.jpcc.1c02074\">10.1021/acs.jpcc.1c02074</a>.","apa":"Nguyen, H.-H., Li, Z., Enenkel, T., Hildebrand, J., Bauer, M., Dyballa, M., &#38; Estes, D. P. (2021). Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO<sub>2</sub> Hydrogenation. <i>The Journal of Physical Chemistry C</i>, <i>125</i>(27), 14627–14635. <a href=\"https://doi.org/10.1021/acs.jpcc.1c02074\">https://doi.org/10.1021/acs.jpcc.1c02074</a>","bibtex":"@article{Nguyen_Li_Enenkel_Hildebrand_Bauer_Dyballa_Estes_2021, title={Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO<sub>2</sub> Hydrogenation}, volume={125}, DOI={<a href=\"https://doi.org/10.1021/acs.jpcc.1c02074\">10.1021/acs.jpcc.1c02074</a>}, number={27}, journal={The Journal of Physical Chemistry C}, publisher={American Chemical Society (ACS)}, author={Nguyen, Hoang-Huy and Li, Zheng and Enenkel, Toni and Hildebrand, Joachim and Bauer, Matthias and Dyballa, Michael and Estes, Deven P.}, year={2021}, pages={14627–14635} }","short":"H.-H. Nguyen, Z. Li, T. Enenkel, J. Hildebrand, M. Bauer, M. Dyballa, D.P. Estes, The Journal of Physical Chemistry C 125 (2021) 14627–14635.","mla":"Nguyen, Hoang-Huy, et al. “Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO<sub>2</sub> Hydrogenation.” <i>The Journal of Physical Chemistry C</i>, vol. 125, no. 27, American Chemical Society (ACS), 2021, pp. 14627–35, doi:<a href=\"https://doi.org/10.1021/acs.jpcc.1c02074\">10.1021/acs.jpcc.1c02074</a>."},"intvolume":"       125","page":"14627-14635","publication_status":"published","publication_identifier":{"issn":["1932-7447","1932-7455"]},"article_type":"original","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"41002","status":"public","type":"journal_article"},{"status":"public","abstract":[{"lang":"eng","text":"Covalent organic frameworks (COFs) offer vast structural and chemical diversity enabling a wide and growing range of applications. While COFs are well-established as heterogeneous catalysts, so far, their high and ordered porosity has scarcely been utilized to its full potential when it comes to spatially confined reactions in COF pores to alter the outcome of reactions. Here, we present a highly porous and crystalline, large-pore COF as catalytic support in α,ω-diene ring-closing metathesis reactions, leading to increased macrocyclization selectivity. COF pore-wall modification by immobilization of a Grubbs-Hoveyda-type catalyst via a mild silylation reaction provides a molecularly precise heterogeneous olefin metathesis catalyst. An increased macro(mono)cyclization (MMC) selectivity over oligomerization (O) for the heterogeneous COF-catalyst (MMC:O=1.35) of up to 51 % compared to the homogeneous catalyst (MMC:O=0.90) was observed along with a substrate-size dependency in selectivity, pointing to diffusion limitations induced by the pore confinement."}],"type":"journal_article","publication":"Chemistry – A European Journal","language":[{"iso":"eng"}],"article_type":"original","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"40998","citation":{"apa":"Emmerling, S. T., Ziegler, F., Fischer, F. R., Schoch, R., Bauer, M., Plietker, B., Buchmeiser, M. R., &#38; Lotsch, B. V. (2021). Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. <i>Chemistry – A European Journal</i>, <i>28</i>(8). <a href=\"https://doi.org/10.1002/chem.202104108\">https://doi.org/10.1002/chem.202104108</a>","short":"S.T. Emmerling, F. Ziegler, F.R. Fischer, R. Schoch, M. Bauer, B. Plietker, M.R. Buchmeiser, B.V. Lotsch, Chemistry – A European Journal 28 (2021).","bibtex":"@article{Emmerling_Ziegler_Fischer_Schoch_Bauer_Plietker_Buchmeiser_Lotsch_2021, title={Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity}, volume={28}, DOI={<a href=\"https://doi.org/10.1002/chem.202104108\">10.1002/chem.202104108</a>}, number={8}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Emmerling, Sebastian T. and Ziegler, Felix and Fischer, Felix R. and Schoch, Roland and Bauer, Matthias and Plietker, Bernd and Buchmeiser, Michael R. and Lotsch, Bettina V.}, year={2021} }","mla":"Emmerling, Sebastian T., et al. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” <i>Chemistry – A European Journal</i>, vol. 28, no. 8, Wiley, 2021, doi:<a href=\"https://doi.org/10.1002/chem.202104108\">10.1002/chem.202104108</a>.","ama":"Emmerling ST, Ziegler F, Fischer FR, et al. Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. <i>Chemistry – A European Journal</i>. 2021;28(8). doi:<a href=\"https://doi.org/10.1002/chem.202104108\">10.1002/chem.202104108</a>","chicago":"Emmerling, Sebastian T., Felix Ziegler, Felix R. Fischer, Roland Schoch, Matthias Bauer, Bernd Plietker, Michael R. Buchmeiser, and Bettina V. Lotsch. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” <i>Chemistry – A European Journal</i> 28, no. 8 (2021). <a href=\"https://doi.org/10.1002/chem.202104108\">https://doi.org/10.1002/chem.202104108</a>.","ieee":"S. T. Emmerling <i>et al.</i>, “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity,” <i>Chemistry – A European Journal</i>, vol. 28, no. 8, 2021, doi: <a href=\"https://doi.org/10.1002/chem.202104108\">10.1002/chem.202104108</a>."},"intvolume":"        28","year":"2021","issue":"8","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"doi":"10.1002/chem.202104108","title":"Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity","author":[{"first_name":"Sebastian T.","last_name":"Emmerling","full_name":"Emmerling, Sebastian T."},{"last_name":"Ziegler","full_name":"Ziegler, Felix","first_name":"Felix"},{"first_name":"Felix R.","last_name":"Fischer","full_name":"Fischer, Felix R."},{"first_name":"Roland","full_name":"Schoch, Roland","id":"48467","orcid":"0000-0003-2061-7289","last_name":"Schoch"},{"full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer","first_name":"Matthias"},{"first_name":"Bernd","full_name":"Plietker, Bernd","last_name":"Plietker"},{"first_name":"Michael R.","full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser"},{"first_name":"Bettina V.","full_name":"Lotsch, Bettina V.","last_name":"Lotsch"}],"date_created":"2023-01-30T16:48:22Z","volume":28,"date_updated":"2023-01-31T08:05:07Z","publisher":"Wiley"},{"year":"2021","issue":"61","title":"Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion","date_created":"2023-01-30T16:49:33Z","publisher":"Royal Society of Chemistry (RSC)","abstract":[{"lang":"eng","text":"Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(II) complexes increases the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2 ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(II) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap"}],"publication":"Chemical Communications","language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composites","Electronic","Optical and Magnetic Materials","Catalysis"],"page":"7541-7544","intvolume":"        57","citation":{"chicago":"Reuter, Thomas, Ayla Kruse, Roland Schoch, Stefan Lochbrunner, Matthias Bauer, and Katja Heinze. “Higher MLCT Lifetime of Carbene Iron(&#60;scp&#62;ii&#60;/Scp&#62;) Complexes by Chelate Ring Expansion.” <i>Chemical Communications</i> 57, no. 61 (2021): 7541–44. <a href=\"https://doi.org/10.1039/d1cc02173g\">https://doi.org/10.1039/d1cc02173g</a>.","ieee":"T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, and K. Heinze, “Higher MLCT lifetime of carbene iron(&#60;scp&#62;ii&#60;/scp&#62;) complexes by chelate ring expansion,” <i>Chemical Communications</i>, vol. 57, no. 61, pp. 7541–7544, 2021, doi: <a href=\"https://doi.org/10.1039/d1cc02173g\">10.1039/d1cc02173g</a>.","ama":"Reuter T, Kruse A, Schoch R, Lochbrunner S, Bauer M, Heinze K. Higher MLCT lifetime of carbene iron(&#60;scp&#62;ii&#60;/scp&#62;) complexes by chelate ring expansion. <i>Chemical Communications</i>. 2021;57(61):7541-7544. doi:<a href=\"https://doi.org/10.1039/d1cc02173g\">10.1039/d1cc02173g</a>","apa":"Reuter, T., Kruse, A., Schoch, R., Lochbrunner, S., Bauer, M., &#38; Heinze, K. (2021). Higher MLCT lifetime of carbene iron(&#60;scp&#62;ii&#60;/scp&#62;) complexes by chelate ring expansion. <i>Chemical Communications</i>, <i>57</i>(61), 7541–7544. <a href=\"https://doi.org/10.1039/d1cc02173g\">https://doi.org/10.1039/d1cc02173g</a>","bibtex":"@article{Reuter_Kruse_Schoch_Lochbrunner_Bauer_Heinze_2021, title={Higher MLCT lifetime of carbene iron(&#60;scp&#62;ii&#60;/scp&#62;) complexes by chelate ring expansion}, volume={57}, DOI={<a href=\"https://doi.org/10.1039/d1cc02173g\">10.1039/d1cc02173g</a>}, number={61}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Reuter, Thomas and Kruse, Ayla and Schoch, Roland and Lochbrunner, Stefan and Bauer, Matthias and Heinze, Katja}, year={2021}, pages={7541–7544} }","mla":"Reuter, Thomas, et al. “Higher MLCT Lifetime of Carbene Iron(&#60;scp&#62;ii&#60;/Scp&#62;) Complexes by Chelate Ring Expansion.” <i>Chemical Communications</i>, vol. 57, no. 61, Royal Society of Chemistry (RSC), 2021, pp. 7541–44, doi:<a href=\"https://doi.org/10.1039/d1cc02173g\">10.1039/d1cc02173g</a>.","short":"T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, K. Heinze, Chemical Communications 57 (2021) 7541–7544."},"publication_identifier":{"issn":["1359-7345","1364-548X"]},"publication_status":"published","doi":"10.1039/d1cc02173g","volume":57,"author":[{"full_name":"Reuter, Thomas","last_name":"Reuter","first_name":"Thomas"},{"first_name":"Ayla","last_name":"Kruse","full_name":"Kruse, Ayla"},{"full_name":"Schoch, Roland","id":"48467","orcid":"0000-0003-2061-7289","last_name":"Schoch","first_name":"Roland"},{"first_name":"Stefan","full_name":"Lochbrunner, Stefan","last_name":"Lochbrunner"},{"orcid":"0000-0002-9294-6076","last_name":"Bauer","id":"47241","full_name":"Bauer, Matthias","first_name":"Matthias"},{"first_name":"Katja","full_name":"Heinze, Katja","last_name":"Heinze"}],"date_updated":"2023-01-31T08:06:16Z","status":"public","type":"journal_article","article_type":"original","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41003"},{"abstract":[{"lang":"eng","text":"On transition metals such as iron rests lots of hope to replace precious metal catalysts in the field of photochemistry for a more sustainable future. Indeed, significant progress has been made in recent years in terms of lifetime extension and emerging applications in catalysis. For this reason, recent synthetic strategies of new photoactive iron compounds, which have proved to show particularly promising properties, are reviewed here. The lifetime of the excited state serves as a key parameter for comparison with the standard ruthenium complex, [Ru(bpy)3]2+, to discuss the potential and performance of the iron complexes. This approach is complemented by a more holistic examination of the sustainability of such a substitution strategy in order to answer the question: when or at which point can we assume that iron represents a more sustainable alternative for noble metals in photochemical applications?"}],"publication":"Inorganic Chemistry Frontiers","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry"],"year":"2021","issue":"2","title":"Photoactive iron complexes: more sustainable, but still a challenge","date_created":"2023-01-30T16:47:45Z","publisher":"Royal Society of Chemistry (RSC)","status":"public","type":"journal_article","article_type":"review","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"40997","citation":{"ama":"Dierks P, Vukadinovic Y, Bauer M. Photoactive iron complexes: more sustainable, but still a challenge. <i>Inorganic Chemistry Frontiers</i>. 2021;9(2):206-220. doi:<a href=\"https://doi.org/10.1039/d1qi01112j\">10.1039/d1qi01112j</a>","ieee":"P. Dierks, Y. Vukadinovic, and M. Bauer, “Photoactive iron complexes: more sustainable, but still a challenge,” <i>Inorganic Chemistry Frontiers</i>, vol. 9, no. 2, pp. 206–220, 2021, doi: <a href=\"https://doi.org/10.1039/d1qi01112j\">10.1039/d1qi01112j</a>.","chicago":"Dierks, Philipp, Yannik Vukadinovic, and Matthias Bauer. “Photoactive Iron Complexes: More Sustainable, but Still a Challenge.” <i>Inorganic Chemistry Frontiers</i> 9, no. 2 (2021): 206–20. <a href=\"https://doi.org/10.1039/d1qi01112j\">https://doi.org/10.1039/d1qi01112j</a>.","mla":"Dierks, Philipp, et al. “Photoactive Iron Complexes: More Sustainable, but Still a Challenge.” <i>Inorganic Chemistry Frontiers</i>, vol. 9, no. 2, Royal Society of Chemistry (RSC), 2021, pp. 206–20, doi:<a href=\"https://doi.org/10.1039/d1qi01112j\">10.1039/d1qi01112j</a>.","short":"P. Dierks, Y. Vukadinovic, M. Bauer, Inorganic Chemistry Frontiers 9 (2021) 206–220.","bibtex":"@article{Dierks_Vukadinovic_Bauer_2021, title={Photoactive iron complexes: more sustainable, but still a challenge}, volume={9}, DOI={<a href=\"https://doi.org/10.1039/d1qi01112j\">10.1039/d1qi01112j</a>}, number={2}, journal={Inorganic Chemistry Frontiers}, publisher={Royal Society of Chemistry (RSC)}, author={Dierks, Philipp and Vukadinovic, Yannik and Bauer, Matthias}, year={2021}, pages={206–220} }","apa":"Dierks, P., Vukadinovic, Y., &#38; Bauer, M. (2021). Photoactive iron complexes: more sustainable, but still a challenge. <i>Inorganic Chemistry Frontiers</i>, <i>9</i>(2), 206–220. <a href=\"https://doi.org/10.1039/d1qi01112j\">https://doi.org/10.1039/d1qi01112j</a>"},"page":"206-220","intvolume":"         9","publication_status":"published","publication_identifier":{"issn":["2052-1553"]},"doi":"10.1039/d1qi01112j","author":[{"first_name":"Philipp","full_name":"Dierks, Philipp","last_name":"Dierks"},{"first_name":"Yannik","full_name":"Vukadinovic, Yannik","last_name":"Vukadinovic"},{"first_name":"Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer","full_name":"Bauer, Matthias","id":"47241"}],"volume":9,"date_updated":"2023-01-31T08:04:56Z"},{"keyword":["General Chemistry","Catalysis"],"article_type":"original","language":[{"iso":"eng"}],"_id":"41000","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","abstract":[{"lang":"eng","text":"Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies for the construction of functional molecules as they obviate the need for pre-functionalized substrates and minimize waste generation. Great challenges reside in the control of selectivities, the utilization of unbiased hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms. An especially mild borylation of benzylic CH bonds was developed with the ligand-free pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic, and preparative mechanistic studies are indicative of a tandem catalysis mechanism of CH-borylation and dehydrocoupling via molecular CoI catalysts."}],"status":"public","publication":"Angewandte Chemie International Edition","type":"journal_article","title":"Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis","doi":"10.1002/anie.202110821","date_updated":"2023-01-31T08:05:26Z","publisher":"Wiley","volume":61,"date_created":"2023-01-30T16:48:53Z","author":[{"first_name":"Pradip","full_name":"Ghosh, Pradip","last_name":"Ghosh"},{"first_name":"Roland","full_name":"Schoch, Roland","id":"48467","last_name":"Schoch","orcid":"0000-0003-2061-7289"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"last_name":"Jacobi von Wangelin","full_name":"Jacobi von Wangelin, Axel","first_name":"Axel"}],"year":"2021","intvolume":"        61","citation":{"apa":"Ghosh, P., Schoch, R., Bauer, M., &#38; Jacobi von Wangelin, A. (2021). Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. <i>Angewandte Chemie International Edition</i>, <i>61</i>(1). <a href=\"https://doi.org/10.1002/anie.202110821\">https://doi.org/10.1002/anie.202110821</a>","short":"P. Ghosh, R. Schoch, M. Bauer, A. Jacobi von Wangelin, Angewandte Chemie International Edition 61 (2021).","mla":"Ghosh, Pradip, et al. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” <i>Angewandte Chemie International Edition</i>, vol. 61, no. 1, Wiley, 2021, doi:<a href=\"https://doi.org/10.1002/anie.202110821\">10.1002/anie.202110821</a>.","bibtex":"@article{Ghosh_Schoch_Bauer_Jacobi von Wangelin_2021, title={Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis}, volume={61}, DOI={<a href=\"https://doi.org/10.1002/anie.202110821\">10.1002/anie.202110821</a>}, number={1}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021} }","ama":"Ghosh P, Schoch R, Bauer M, Jacobi von Wangelin A. Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. <i>Angewandte Chemie International Edition</i>. 2021;61(1). doi:<a href=\"https://doi.org/10.1002/anie.202110821\">10.1002/anie.202110821</a>","chicago":"Ghosh, Pradip, Roland Schoch, Matthias Bauer, and Axel Jacobi von Wangelin. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” <i>Angewandte Chemie International Edition</i> 61, no. 1 (2021). <a href=\"https://doi.org/10.1002/anie.202110821\">https://doi.org/10.1002/anie.202110821</a>.","ieee":"P. Ghosh, R. Schoch, M. Bauer, and A. Jacobi von Wangelin, “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis,” <i>Angewandte Chemie International Edition</i>, vol. 61, no. 1, 2021, doi: <a href=\"https://doi.org/10.1002/anie.202110821\">10.1002/anie.202110821</a>."},"publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published","issue":"1"},{"language":[{"iso":"eng"}],"keyword":["Materials Chemistry","General Chemical Engineering","General Chemistry"],"abstract":[{"text":"Within this article, it is shown that an electrochemical defluorination and additional fluorination of Ruddlesden–Popper-type La2NiO3F2 is possible within all-solid-state fluoride-ion batteries. Structural changes within the reduced and oxidized phases have been examined by X-ray diffraction studies at different states of charging and discharging. The synthesis of the oxidized phase La2NiO3F2+x proved to be successful by structural analysis using both X-ray powder diffraction and automated electron diffraction tomography techniques. The structural reversibility on re-fluorinating and re-defluorinating is also demonstrated. Moreover, the influence of different sequences of consecutive reduction and oxidation steps on the formed phases has been investigated. The observed structural changes have been compared to changes in phases obtained via other topochemical modification approaches such as hydride-based reduction and oxidative fluorination using F2 gas, highlighting the potential of such electrochemical reactions as alternative synthesis routes. Furthermore, the electrochemical routes represent safe and controllable synthesis approaches for novel phases, which cannot be synthesized via other topochemical methods. Additionally, side reactions, occurring alongside the desired electrochemical reactions, have been addressed and the cycling performance has been studied.","lang":"eng"}],"publication":"Chemistry of Materials","title":"Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries","date_created":"2023-01-30T17:01:00Z","publisher":"American Chemical Society (ACS)","year":"2021","issue":"2","article_type":"original","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"41013","status":"public","type":"journal_article","doi":"10.1021/acs.chemmater.0c01762","author":[{"first_name":"Kerstin","last_name":"Wissel","full_name":"Wissel, Kerstin"},{"last_name":"Schoch","orcid":"0000-0003-2061-7289","id":"48467","full_name":"Schoch, Roland","first_name":"Roland"},{"first_name":"Tobias","last_name":"Vogel","full_name":"Vogel, Tobias"},{"first_name":"Manuel","full_name":"Donzelli, Manuel","last_name":"Donzelli"},{"first_name":"Galina","last_name":"Matveeva","full_name":"Matveeva, Galina"},{"full_name":"Kolb, Ute","last_name":"Kolb","first_name":"Ute"},{"full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer","first_name":"Matthias"},{"full_name":"Slater, Peter R.","last_name":"Slater","first_name":"Peter R."},{"last_name":"Clemens","full_name":"Clemens, Oliver","first_name":"Oliver"}],"volume":33,"date_updated":"2023-01-31T08:07:28Z","citation":{"ama":"Wissel K, Schoch R, Vogel T, et al. Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries. <i>Chemistry of Materials</i>. 2021;33(2):499-512. doi:<a href=\"https://doi.org/10.1021/acs.chemmater.0c01762\">10.1021/acs.chemmater.0c01762</a>","ieee":"K. Wissel <i>et al.</i>, “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries,” <i>Chemistry of Materials</i>, vol. 33, no. 2, pp. 499–512, 2021, doi: <a href=\"https://doi.org/10.1021/acs.chemmater.0c01762\">10.1021/acs.chemmater.0c01762</a>.","chicago":"Wissel, Kerstin, Roland Schoch, Tobias Vogel, Manuel Donzelli, Galina Matveeva, Ute Kolb, Matthias Bauer, Peter R. Slater, and Oliver Clemens. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries.” <i>Chemistry of Materials</i> 33, no. 2 (2021): 499–512. <a href=\"https://doi.org/10.1021/acs.chemmater.0c01762\">https://doi.org/10.1021/acs.chemmater.0c01762</a>.","short":"K. Wissel, R. Schoch, T. Vogel, M. Donzelli, G. Matveeva, U. Kolb, M. Bauer, P.R. Slater, O. Clemens, Chemistry of Materials 33 (2021) 499–512.","mla":"Wissel, Kerstin, et al. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries.” <i>Chemistry of Materials</i>, vol. 33, no. 2, American Chemical Society (ACS), 2021, pp. 499–512, doi:<a href=\"https://doi.org/10.1021/acs.chemmater.0c01762\">10.1021/acs.chemmater.0c01762</a>.","bibtex":"@article{Wissel_Schoch_Vogel_Donzelli_Matveeva_Kolb_Bauer_Slater_Clemens_2021, title={Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries}, volume={33}, DOI={<a href=\"https://doi.org/10.1021/acs.chemmater.0c01762\">10.1021/acs.chemmater.0c01762</a>}, number={2}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Wissel, Kerstin and Schoch, Roland and Vogel, Tobias and Donzelli, Manuel and Matveeva, Galina and Kolb, Ute and Bauer, Matthias and Slater, Peter R. and Clemens, Oliver}, year={2021}, pages={499–512} }","apa":"Wissel, K., Schoch, R., Vogel, T., Donzelli, M., Matveeva, G., Kolb, U., Bauer, M., Slater, P. R., &#38; Clemens, O. (2021). Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries. <i>Chemistry of Materials</i>, <i>33</i>(2), 499–512. <a href=\"https://doi.org/10.1021/acs.chemmater.0c01762\">https://doi.org/10.1021/acs.chemmater.0c01762</a>"},"page":"499-512","intvolume":"        33","publication_status":"published","publication_identifier":{"issn":["0897-4756","1520-5002"]}},{"publication":"Angewandte Chemie International Edition","abstract":[{"text":"We present the η3-coordination of the 2-phosphaethynthiolate anion in the complex (PN)2La(SCP) (2) [PN=N-(2-(diisopropylphosphanyl)-4-methylphenyl)-2,4,6-trimethylanilide)]. Structural comparison with dinuclear thiocyanate-bridged (PN)2La(μ-1,3-SCN)2La(PN)2 (3) and azide-bridged (PN)2La(μ-1,3-N3)2La(PN)2 (4) complexes indicates that the [SCP]− coordination mode is mainly governed by electronic, rather than steric factors. Quantum mechanical investigations reveal large contributions of the antibonding π*-orbital of the [SCP]− ligand to the LUMO of complex 2, rendering it the ideal precursor for the first functionalization of the [SCP]− anion. Complex 2 was therefore reacted with CAACs which induced a selective rearrangement of the [SCP]− ligand to form the first CAAC stabilized group 15–group 16 fulminate-type complexes (PN)2La{SPC(RCAAC)} (5 a,b, R=Ad, Me). A detailed reaction mechanism for the SCP-to-SPC isomerization is proposed based on DFT calculations.","lang":"eng"}],"language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis"],"issue":"17","year":"2021","date_created":"2023-01-30T17:00:21Z","publisher":"Wiley","title":"η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**","type":"journal_article","status":"public","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"41010","article_type":"original","publication_status":"published","publication_identifier":{"issn":["1433-7851","1521-3773"]},"citation":{"apa":"Watt, F. A., Burkhardt, L., Schoch, R., Mitzinger, S., Bauer, M., Weigend, F., Goicoechea, J. M., Tambornino, F., &#38; Hohloch, S. (2021). η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**. <i>Angewandte Chemie International Edition</i>, <i>60</i>(17), 9534–9539. <a href=\"https://doi.org/10.1002/anie.202100559\">https://doi.org/10.1002/anie.202100559</a>","bibtex":"@article{Watt_Burkhardt_Schoch_Mitzinger_Bauer_Weigend_Goicoechea_Tambornino_Hohloch_2021, title={η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**}, volume={60}, DOI={<a href=\"https://doi.org/10.1002/anie.202100559\">10.1002/anie.202100559</a>}, number={17}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Watt, Fabian A. and Burkhardt, Lukas and Schoch, Roland and Mitzinger, Stefan and Bauer, Matthias and Weigend, Florian and Goicoechea, Jose M. and Tambornino, Frank and Hohloch, Stephan}, year={2021}, pages={9534–9539} }","short":"F.A. Watt, L. Burkhardt, R. Schoch, S. Mitzinger, M. Bauer, F. Weigend, J.M. Goicoechea, F. Tambornino, S. Hohloch, Angewandte Chemie International Edition 60 (2021) 9534–9539.","mla":"Watt, Fabian A., et al. “η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” <i>Angewandte Chemie International Edition</i>, vol. 60, no. 17, Wiley, 2021, pp. 9534–39, doi:<a href=\"https://doi.org/10.1002/anie.202100559\">10.1002/anie.202100559</a>.","ama":"Watt FA, Burkhardt L, Schoch R, et al. η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**. <i>Angewandte Chemie International Edition</i>. 2021;60(17):9534-9539. doi:<a href=\"https://doi.org/10.1002/anie.202100559\">10.1002/anie.202100559</a>","ieee":"F. A. Watt <i>et al.</i>, “η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**,” <i>Angewandte Chemie International Edition</i>, vol. 60, no. 17, pp. 9534–9539, 2021, doi: <a href=\"https://doi.org/10.1002/anie.202100559\">10.1002/anie.202100559</a>.","chicago":"Watt, Fabian A., Lukas Burkhardt, Roland Schoch, Stefan Mitzinger, Matthias Bauer, Florian Weigend, Jose M. Goicoechea, Frank Tambornino, and Stephan Hohloch. “η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” <i>Angewandte Chemie International Edition</i> 60, no. 17 (2021): 9534–39. <a href=\"https://doi.org/10.1002/anie.202100559\">https://doi.org/10.1002/anie.202100559</a>."},"page":"9534-9539","intvolume":"        60","author":[{"first_name":"Fabian A.","last_name":"Watt","full_name":"Watt, Fabian A."},{"full_name":"Burkhardt, Lukas","last_name":"Burkhardt","first_name":"Lukas"},{"full_name":"Schoch, Roland","id":"48467","orcid":"0000-0003-2061-7289","last_name":"Schoch","first_name":"Roland"},{"first_name":"Stefan","full_name":"Mitzinger, Stefan","last_name":"Mitzinger"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"first_name":"Florian","full_name":"Weigend, Florian","last_name":"Weigend"},{"full_name":"Goicoechea, Jose M.","last_name":"Goicoechea","first_name":"Jose M."},{"last_name":"Tambornino","full_name":"Tambornino, Frank","first_name":"Frank"},{"first_name":"Stephan","full_name":"Hohloch, Stephan","last_name":"Hohloch"}],"volume":60,"date_updated":"2023-01-31T08:06:50Z","doi":"10.1002/anie.202100559"},{"article_type":"original","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41012","status":"public","type":"journal_article","doi":"10.1021/acs.inorgchem.0c03259","volume":60,"author":[{"full_name":"Winkler, Mario","last_name":"Winkler","first_name":"Mario"},{"last_name":"Schnierle","full_name":"Schnierle, Marc","first_name":"Marc"},{"full_name":"Ehrlich, Felix","last_name":"Ehrlich","first_name":"Felix"},{"first_name":"Kim-Isabelle","last_name":"Mehnert","full_name":"Mehnert, Kim-Isabelle"},{"first_name":"David","full_name":"Hunger, David","last_name":"Hunger"},{"last_name":"Sheveleva","full_name":"Sheveleva, Alena M.","first_name":"Alena M."},{"full_name":"Burkhardt, Lukas","last_name":"Burkhardt","first_name":"Lukas"},{"id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","first_name":"Matthias"},{"first_name":"Floriana","full_name":"Tuna, Floriana","last_name":"Tuna"},{"first_name":"Mark R.","last_name":"Ringenberg","full_name":"Ringenberg, Mark R."},{"full_name":"van Slageren, Joris","last_name":"van Slageren","first_name":"Joris"}],"date_updated":"2023-01-31T08:07:16Z","page":"2856-2865","intvolume":"        60","citation":{"apa":"Winkler, M., Schnierle, M., Ehrlich, F., Mehnert, K.-I., Hunger, D., Sheveleva, A. M., Burkhardt, L., Bauer, M., Tuna, F., Ringenberg, M. R., &#38; van Slageren, J. (2021). Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>. <i>Inorganic Chemistry</i>, <i>60</i>(5), 2856–2865. <a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">https://doi.org/10.1021/acs.inorgchem.0c03259</a>","mla":"Winkler, Mario, et al. “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(Dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>.” <i>Inorganic Chemistry</i>, vol. 60, no. 5, American Chemical Society (ACS), 2021, pp. 2856–65, doi:<a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">10.1021/acs.inorgchem.0c03259</a>.","short":"M. Winkler, M. Schnierle, F. Ehrlich, K.-I. Mehnert, D. Hunger, A.M. Sheveleva, L. Burkhardt, M. Bauer, F. Tuna, M.R. Ringenberg, J. van Slageren, Inorganic Chemistry 60 (2021) 2856–2865.","bibtex":"@article{Winkler_Schnierle_Ehrlich_Mehnert_Hunger_Sheveleva_Burkhardt_Bauer_Tuna_Ringenberg_et al._2021, title={Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>}, volume={60}, DOI={<a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">10.1021/acs.inorgchem.0c03259</a>}, number={5}, journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Winkler, Mario and Schnierle, Marc and Ehrlich, Felix and Mehnert, Kim-Isabelle and Hunger, David and Sheveleva, Alena M. and Burkhardt, Lukas and Bauer, Matthias and Tuna, Floriana and Ringenberg, Mark R. and et al.}, year={2021}, pages={2856–2865} }","ieee":"M. Winkler <i>et al.</i>, “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>,” <i>Inorganic Chemistry</i>, vol. 60, no. 5, pp. 2856–2865, 2021, doi: <a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">10.1021/acs.inorgchem.0c03259</a>.","chicago":"Winkler, Mario, Marc Schnierle, Felix Ehrlich, Kim-Isabelle Mehnert, David Hunger, Alena M. Sheveleva, Lukas Burkhardt, et al. “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(Dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>.” <i>Inorganic Chemistry</i> 60, no. 5 (2021): 2856–65. <a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">https://doi.org/10.1021/acs.inorgchem.0c03259</a>.","ama":"Winkler M, Schnierle M, Ehrlich F, et al. Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>. <i>Inorganic Chemistry</i>. 2021;60(5):2856-2865. doi:<a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">10.1021/acs.inorgchem.0c03259</a>"},"publication_identifier":{"issn":["0020-1669","1520-510X"]},"publication_status":"published","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Physical and Theoretical Chemistry"],"abstract":[{"lang":"eng","text":"Here we explore the electronic structure of the diiron complex [(dppf)Fe(CO)3]0/+ [10/+; dppf = 1,1′-bis(diphenylphosphino)ferrocene] in two oxidation states by an advanced multitechnique experimental approach. A combination of magnetic circular dichroism, X-ray absorption and emission, high-frequency electron paramagnetic resonance (EPR), and Mössbauer spectroscopies is used to establish that oxidation of 10 occurs on the carbonyl iron ion, resulting in a low-spin iron(I) ion. It is shown that an unequivocal result is obtained by combining several methods. Compound 1+ displays slow spin dynamics, which is used here to study its geometric structure by means of pulsed EPR methods. Surprisingly, these data show an association of the tetrakis[3,5-bis(trifluoromethylphenyl)]borate counterion with 1+."}],"publication":"Inorganic Chemistry","title":"Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>","date_created":"2023-01-30T17:00:49Z","publisher":"American Chemical Society (ACS)","year":"2021","issue":"5"},{"issue":"2","year":"2021","date_created":"2023-01-30T17:00:36Z","publisher":"Wiley","title":"Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles","publication":"ChemistryOpen","abstract":[{"text":"The controlled assembly of well-defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D-structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe4, Fe6, and Fe7 nanoplatelets and calculated intermediates enable an unprecedented insight into the underlying building principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles.","lang":"eng"}],"language":[{"iso":"eng"}],"keyword":["General Chemistry"],"publication_identifier":{"issn":["2191-1363","2191-1363"]},"publication_status":"published","intvolume":"        10","page":"265-271","citation":{"ama":"Chakraborty U, Bügel P, Fritsch L, Weigend F, Bauer M, Jacobi von Wangelin A. Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles. <i>ChemistryOpen</i>. 2021;10(2):265-271. doi:<a href=\"https://doi.org/10.1002/open.202000307\">10.1002/open.202000307</a>","ieee":"U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, and A. Jacobi von Wangelin, “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles,” <i>ChemistryOpen</i>, vol. 10, no. 2, pp. 265–271, 2021, doi: <a href=\"https://doi.org/10.1002/open.202000307\">10.1002/open.202000307</a>.","chicago":"Chakraborty, Uttam, Patrick Bügel, Lorena Fritsch, Florian Weigend, Matthias Bauer, and Axel Jacobi von Wangelin. “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles.” <i>ChemistryOpen</i> 10, no. 2 (2021): 265–71. <a href=\"https://doi.org/10.1002/open.202000307\">https://doi.org/10.1002/open.202000307</a>.","apa":"Chakraborty, U., Bügel, P., Fritsch, L., Weigend, F., Bauer, M., &#38; Jacobi von Wangelin, A. (2021). Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles. <i>ChemistryOpen</i>, <i>10</i>(2), 265–271. <a href=\"https://doi.org/10.1002/open.202000307\">https://doi.org/10.1002/open.202000307</a>","bibtex":"@article{Chakraborty_Bügel_Fritsch_Weigend_Bauer_Jacobi von Wangelin_2021, title={Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles}, volume={10}, DOI={<a href=\"https://doi.org/10.1002/open.202000307\">10.1002/open.202000307</a>}, number={2}, journal={ChemistryOpen}, publisher={Wiley}, author={Chakraborty, Uttam and Bügel, Patrick and Fritsch, Lorena and Weigend, Florian and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021}, pages={265–271} }","short":"U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, A. Jacobi von Wangelin, ChemistryOpen 10 (2021) 265–271.","mla":"Chakraborty, Uttam, et al. “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles.” <i>ChemistryOpen</i>, vol. 10, no. 2, Wiley, 2021, pp. 265–71, doi:<a href=\"https://doi.org/10.1002/open.202000307\">10.1002/open.202000307</a>."},"volume":10,"author":[{"full_name":"Chakraborty, Uttam","last_name":"Chakraborty","first_name":"Uttam"},{"full_name":"Bügel, Patrick","last_name":"Bügel","first_name":"Patrick"},{"first_name":"Lorena","last_name":"Fritsch","id":"44418","full_name":"Fritsch, Lorena"},{"first_name":"Florian","full_name":"Weigend, Florian","last_name":"Weigend"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"first_name":"Axel","last_name":"Jacobi von Wangelin","full_name":"Jacobi von Wangelin, Axel"}],"date_updated":"2023-01-31T08:07:01Z","doi":"10.1002/open.202000307","type":"journal_article","status":"public","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41011","article_type":"original"},{"keyword":["Physical and Theoretical Chemistry","General Physics and Astronomy"],"language":[{"iso":"eng"}],"publication":"Physical Chemistry Chemical Physics","abstract":[{"text":"<jats:p>Thermostable compartmentalized sodium-water sites through intercalated γ-aminopropyl-dimethyl-ethoxy silane in synthetic hectorite.</jats:p>","lang":"eng"}],"publisher":"Royal Society of Chemistry (RSC)","date_created":"2023-01-06T12:14:54Z","title":"Thermostable water reservoirs in the interlayer space of a sodium hectorite clay through the intercalation of γ-aminopropyl(dimethyl)ethoxysilane in toluene","quality_controlled":"1","issue":"1","year":"2021","_id":"35326","user_id":"32","department":[{"_id":"2"},{"_id":"315"},{"_id":"301"},{"_id":"321"}],"article_type":"original","type":"journal_article","status":"public","date_updated":"2023-02-06T09:59:31Z","author":[{"first_name":"Waldemar","last_name":"Keil","full_name":"Keil, Waldemar"},{"first_name":"Kai","last_name":"Zhao","full_name":"Zhao, Kai"},{"full_name":"Oswald, Arthur","last_name":"Oswald","first_name":"Arthur"},{"full_name":"Bremser, Wolfgang","id":"32","last_name":"Bremser","first_name":"Wolfgang"},{"last_name":"Schmidt","orcid":"0000-0003-3179-9997","full_name":"Schmidt, Claudia","id":"466","first_name":"Claudia"},{"last_name":"Hintze-Bruening","full_name":"Hintze-Bruening, Horst","first_name":"Horst"}],"volume":24,"doi":"10.1039/d1cp03321b","publication_status":"published","publication_identifier":{"issn":["1463-9076","1463-9084"]},"citation":{"apa":"Keil, W., Zhao, K., Oswald, A., Bremser, W., Schmidt, C., &#38; Hintze-Bruening, H. (2021). Thermostable water reservoirs in the interlayer space of a sodium hectorite clay through the intercalation of γ-aminopropyl(dimethyl)ethoxysilane in toluene. <i>Physical Chemistry Chemical Physics</i>, <i>24</i>(1), 477–487. <a href=\"https://doi.org/10.1039/d1cp03321b\">https://doi.org/10.1039/d1cp03321b</a>","bibtex":"@article{Keil_Zhao_Oswald_Bremser_Schmidt_Hintze-Bruening_2021, title={Thermostable water reservoirs in the interlayer space of a sodium hectorite clay through the intercalation of γ-aminopropyl(dimethyl)ethoxysilane in toluene}, volume={24}, DOI={<a href=\"https://doi.org/10.1039/d1cp03321b\">10.1039/d1cp03321b</a>}, number={1}, journal={Physical Chemistry Chemical Physics}, publisher={Royal Society of Chemistry (RSC)}, author={Keil, Waldemar and Zhao, Kai and Oswald, Arthur and Bremser, Wolfgang and Schmidt, Claudia and Hintze-Bruening, Horst}, year={2021}, pages={477–487} }","mla":"Keil, Waldemar, et al. “Thermostable Water Reservoirs in the Interlayer Space of a Sodium Hectorite Clay through the Intercalation of γ-Aminopropyl(Dimethyl)Ethoxysilane in Toluene.” <i>Physical Chemistry Chemical Physics</i>, vol. 24, no. 1, Royal Society of Chemistry (RSC), 2021, pp. 477–87, doi:<a href=\"https://doi.org/10.1039/d1cp03321b\">10.1039/d1cp03321b</a>.","short":"W. Keil, K. Zhao, A. Oswald, W. Bremser, C. Schmidt, H. Hintze-Bruening, Physical Chemistry Chemical Physics 24 (2021) 477–487.","ama":"Keil W, Zhao K, Oswald A, Bremser W, Schmidt C, Hintze-Bruening H. Thermostable water reservoirs in the interlayer space of a sodium hectorite clay through the intercalation of γ-aminopropyl(dimethyl)ethoxysilane in toluene. <i>Physical Chemistry Chemical Physics</i>. 2021;24(1):477-487. doi:<a href=\"https://doi.org/10.1039/d1cp03321b\">10.1039/d1cp03321b</a>","ieee":"W. Keil, K. Zhao, A. Oswald, W. Bremser, C. Schmidt, and H. Hintze-Bruening, “Thermostable water reservoirs in the interlayer space of a sodium hectorite clay through the intercalation of γ-aminopropyl(dimethyl)ethoxysilane in toluene,” <i>Physical Chemistry Chemical Physics</i>, vol. 24, no. 1, pp. 477–487, 2021, doi: <a href=\"https://doi.org/10.1039/d1cp03321b\">10.1039/d1cp03321b</a>.","chicago":"Keil, Waldemar, Kai Zhao, Arthur Oswald, Wolfgang Bremser, Claudia Schmidt, and Horst Hintze-Bruening. “Thermostable Water Reservoirs in the Interlayer Space of a Sodium Hectorite Clay through the Intercalation of γ-Aminopropyl(Dimethyl)Ethoxysilane in Toluene.” <i>Physical Chemistry Chemical Physics</i> 24, no. 1 (2021): 477–87. <a href=\"https://doi.org/10.1039/d1cp03321b\">https://doi.org/10.1039/d1cp03321b</a>."},"intvolume":"        24","page":"477-487"},{"_id":"41817","user_id":"237","department":[{"_id":"314"}],"status":"public","type":"journal_article","doi":"10.1039/d1sm00979f","date_updated":"2023-02-06T12:08:46Z","author":[{"full_name":"Hämisch, Benjamin","last_name":"Hämisch","first_name":"Benjamin"},{"last_name":"Huber","id":"237","full_name":"Huber, Klaus","first_name":"Klaus"}],"volume":17,"citation":{"ieee":"B. Hämisch and K. Huber, “Mechanism and equilibrium thermodynamics of H- and J-aggregate formation from pseudo isocyanine chloride in water,” <i>Soft Matter</i>, vol. 17, no. 35, pp. 8140–8152, 2021, doi: <a href=\"https://doi.org/10.1039/d1sm00979f\">10.1039/d1sm00979f</a>.","chicago":"Hämisch, Benjamin, and Klaus Huber. “Mechanism and Equilibrium Thermodynamics of H- and J-Aggregate Formation from Pseudo Isocyanine Chloride in Water.” <i>Soft Matter</i> 17, no. 35 (2021): 8140–52. <a href=\"https://doi.org/10.1039/d1sm00979f\">https://doi.org/10.1039/d1sm00979f</a>.","ama":"Hämisch B, Huber K. Mechanism and equilibrium thermodynamics of H- and J-aggregate formation from pseudo isocyanine chloride in water. <i>Soft Matter</i>. 2021;17(35):8140-8152. doi:<a href=\"https://doi.org/10.1039/d1sm00979f\">10.1039/d1sm00979f</a>","apa":"Hämisch, B., &#38; Huber, K. (2021). Mechanism and equilibrium thermodynamics of H- and J-aggregate formation from pseudo isocyanine chloride in water. <i>Soft Matter</i>, <i>17</i>(35), 8140–8152. <a href=\"https://doi.org/10.1039/d1sm00979f\">https://doi.org/10.1039/d1sm00979f</a>","mla":"Hämisch, Benjamin, and Klaus Huber. “Mechanism and Equilibrium Thermodynamics of H- and J-Aggregate Formation from Pseudo Isocyanine Chloride in Water.” <i>Soft Matter</i>, vol. 17, no. 35, Royal Society of Chemistry (RSC), 2021, pp. 8140–52, doi:<a href=\"https://doi.org/10.1039/d1sm00979f\">10.1039/d1sm00979f</a>.","short":"B. Hämisch, K. Huber, Soft Matter 17 (2021) 8140–8152.","bibtex":"@article{Hämisch_Huber_2021, title={Mechanism and equilibrium thermodynamics of H- and J-aggregate formation from pseudo isocyanine chloride in water}, volume={17}, DOI={<a href=\"https://doi.org/10.1039/d1sm00979f\">10.1039/d1sm00979f</a>}, number={35}, journal={Soft Matter}, publisher={Royal Society of Chemistry (RSC)}, author={Hämisch, Benjamin and Huber, Klaus}, year={2021}, pages={8140–8152} }"},"intvolume":"        17","page":"8140-8152","publication_status":"published","publication_identifier":{"issn":["1744-683X","1744-6848"]},"keyword":["Condensed Matter Physics","General Chemistry"],"language":[{"iso":"eng"}],"abstract":[{"text":"<jats:p>Pseudo isocyanine chloride monomers equilibrate with H-oligomers and, separated by a threshold, with H-oligomers and fiber-like J-aggregates. The mechanism and thermodynamics of J-aggregate formation is interpreted with the concept of chain growth.</jats:p>","lang":"eng"}],"publication":"Soft Matter","title":"Mechanism and equilibrium thermodynamics of H- and J-aggregate formation from pseudo isocyanine chloride in water","publisher":"Royal Society of Chemistry (RSC)","date_created":"2023-02-06T12:08:04Z","year":"2021","issue":"35"},{"author":[{"last_name":"Hense","full_name":"Hense, Dominik","first_name":"Dominik"},{"first_name":"Anne","last_name":"Büngeler","full_name":"Büngeler, Anne"},{"last_name":"Kollmann","full_name":"Kollmann, Fabian","first_name":"Fabian"},{"first_name":"Marcel","last_name":"Hanke","full_name":"Hanke, Marcel"},{"full_name":"Orive, Alejandro","last_name":"Orive","first_name":"Alejandro"},{"full_name":"Keller, Adrian","last_name":"Keller","first_name":"Adrian"},{"first_name":"Guido","last_name":"Grundmeier","full_name":"Grundmeier, Guido"},{"last_name":"Huber","full_name":"Huber, Klaus","id":"237","first_name":"Klaus"},{"first_name":"Oliver I.","last_name":"Strube","full_name":"Strube, Oliver I."}],"date_created":"2023-02-06T12:09:33Z","volume":22,"publisher":"American Chemical Society (ACS)","date_updated":"2023-02-06T12:10:19Z","doi":"10.1021/acs.biomac.1c00489","title":"Self-Assembled Fibrinogen Hydro- and Aerogels with Fibrin-like 3D Structures","issue":"10","publication_status":"published","publication_identifier":{"issn":["1525-7797","1526-4602"]},"citation":{"bibtex":"@article{Hense_Büngeler_Kollmann_Hanke_Orive_Keller_Grundmeier_Huber_Strube_2021, title={Self-Assembled Fibrinogen Hydro- and Aerogels with Fibrin-like 3D Structures}, volume={22}, DOI={<a href=\"https://doi.org/10.1021/acs.biomac.1c00489\">10.1021/acs.biomac.1c00489</a>}, number={10}, journal={Biomacromolecules}, publisher={American Chemical Society (ACS)}, author={Hense, Dominik and Büngeler, Anne and Kollmann, Fabian and Hanke, Marcel and Orive, Alejandro and Keller, Adrian and Grundmeier, Guido and Huber, Klaus and Strube, Oliver I.}, year={2021}, pages={4084–4094} }","short":"D. Hense, A. Büngeler, F. Kollmann, M. Hanke, A. Orive, A. Keller, G. Grundmeier, K. Huber, O.I. Strube, Biomacromolecules 22 (2021) 4084–4094.","mla":"Hense, Dominik, et al. “Self-Assembled Fibrinogen Hydro- and Aerogels with Fibrin-like 3D Structures.” <i>Biomacromolecules</i>, vol. 22, no. 10, American Chemical Society (ACS), 2021, pp. 4084–94, doi:<a href=\"https://doi.org/10.1021/acs.biomac.1c00489\">10.1021/acs.biomac.1c00489</a>.","apa":"Hense, D., Büngeler, A., Kollmann, F., Hanke, M., Orive, A., Keller, A., Grundmeier, G., Huber, K., &#38; Strube, O. I. (2021). Self-Assembled Fibrinogen Hydro- and Aerogels with Fibrin-like 3D Structures. <i>Biomacromolecules</i>, <i>22</i>(10), 4084–4094. <a href=\"https://doi.org/10.1021/acs.biomac.1c00489\">https://doi.org/10.1021/acs.biomac.1c00489</a>","ama":"Hense D, Büngeler A, Kollmann F, et al. Self-Assembled Fibrinogen Hydro- and Aerogels with Fibrin-like 3D Structures. <i>Biomacromolecules</i>. 2021;22(10):4084-4094. doi:<a href=\"https://doi.org/10.1021/acs.biomac.1c00489\">10.1021/acs.biomac.1c00489</a>","chicago":"Hense, Dominik, Anne Büngeler, Fabian Kollmann, Marcel Hanke, Alejandro Orive, Adrian Keller, Guido Grundmeier, Klaus Huber, and Oliver I. Strube. “Self-Assembled Fibrinogen Hydro- and Aerogels with Fibrin-like 3D Structures.” <i>Biomacromolecules</i> 22, no. 10 (2021): 4084–94. <a href=\"https://doi.org/10.1021/acs.biomac.1c00489\">https://doi.org/10.1021/acs.biomac.1c00489</a>.","ieee":"D. Hense <i>et al.</i>, “Self-Assembled Fibrinogen Hydro- and Aerogels with Fibrin-like 3D Structures,” <i>Biomacromolecules</i>, vol. 22, no. 10, pp. 4084–4094, 2021, doi: <a href=\"https://doi.org/10.1021/acs.biomac.1c00489\">10.1021/acs.biomac.1c00489</a>."},"page":"4084-4094","intvolume":"        22","year":"2021","user_id":"237","department":[{"_id":"314"}],"_id":"41818","language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Polymers and Plastics","Biomaterials","Bioengineering"],"type":"journal_article","publication":"Biomacromolecules","status":"public"},{"keyword":["Materials Chemistry","Inorganic Chemistry","Polymers and Plastics","Organic Chemistry"],"language":[{"iso":"eng"}],"_id":"41816","user_id":"237","department":[{"_id":"314"}],"status":"public","type":"journal_article","publication":"Macromolecules","title":"Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds","doi":"10.1021/acs.macromol.1c00299","date_updated":"2023-02-06T12:05:32Z","publisher":"American Chemical Society (ACS)","date_created":"2023-02-06T12:02:19Z","author":[{"first_name":"Maximilian","last_name":"Wagner","full_name":"Wagner, Maximilian"},{"first_name":"Anja","full_name":"Krieger, Anja","last_name":"Krieger"},{"first_name":"Martin","full_name":"Minameyer, Martin","last_name":"Minameyer"},{"full_name":"Hämisch, Benjamin","last_name":"Hämisch","first_name":"Benjamin"},{"first_name":"Klaus","last_name":"Huber","full_name":"Huber, Klaus","id":"237"},{"first_name":"Thomas","last_name":"Drewello","full_name":"Drewello, Thomas"},{"last_name":"Gröhn","full_name":"Gröhn, Franziska","first_name":"Franziska"}],"volume":54,"year":"2021","citation":{"ama":"Wagner M, Krieger A, Minameyer M, et al. Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds. <i>Macromolecules</i>. 2021;54(6):2899-2911. doi:<a href=\"https://doi.org/10.1021/acs.macromol.1c00299\">10.1021/acs.macromol.1c00299</a>","chicago":"Wagner, Maximilian, Anja Krieger, Martin Minameyer, Benjamin Hämisch, Klaus Huber, Thomas Drewello, and Franziska Gröhn. “Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds.” <i>Macromolecules</i> 54, no. 6 (2021): 2899–2911. <a href=\"https://doi.org/10.1021/acs.macromol.1c00299\">https://doi.org/10.1021/acs.macromol.1c00299</a>.","ieee":"M. Wagner <i>et al.</i>, “Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds,” <i>Macromolecules</i>, vol. 54, no. 6, pp. 2899–2911, 2021, doi: <a href=\"https://doi.org/10.1021/acs.macromol.1c00299\">10.1021/acs.macromol.1c00299</a>.","apa":"Wagner, M., Krieger, A., Minameyer, M., Hämisch, B., Huber, K., Drewello, T., &#38; Gröhn, F. (2021). Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds. <i>Macromolecules</i>, <i>54</i>(6), 2899–2911. <a href=\"https://doi.org/10.1021/acs.macromol.1c00299\">https://doi.org/10.1021/acs.macromol.1c00299</a>","short":"M. Wagner, A. Krieger, M. Minameyer, B. Hämisch, K. Huber, T. Drewello, F. Gröhn, Macromolecules 54 (2021) 2899–2911.","mla":"Wagner, Maximilian, et al. “Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds.” <i>Macromolecules</i>, vol. 54, no. 6, American Chemical Society (ACS), 2021, pp. 2899–911, doi:<a href=\"https://doi.org/10.1021/acs.macromol.1c00299\">10.1021/acs.macromol.1c00299</a>.","bibtex":"@article{Wagner_Krieger_Minameyer_Hämisch_Huber_Drewello_Gröhn_2021, title={Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds}, volume={54}, DOI={<a href=\"https://doi.org/10.1021/acs.macromol.1c00299\">10.1021/acs.macromol.1c00299</a>}, number={6}, journal={Macromolecules}, publisher={American Chemical Society (ACS)}, author={Wagner, Maximilian and Krieger, Anja and Minameyer, Martin and Hämisch, Benjamin and Huber, Klaus and Drewello, Thomas and Gröhn, Franziska}, year={2021}, pages={2899–2911} }"},"page":"2899-2911","intvolume":"        54","publication_status":"published","publication_identifier":{"issn":["0024-9297","1520-5835"]},"issue":"6"},{"publisher":"Wiley","date_updated":"2023-02-06T12:06:30Z","author":[{"last_name":"Hämisch","full_name":"Hämisch, Benjamin","first_name":"Benjamin"},{"full_name":"Pollak, Roland","last_name":"Pollak","first_name":"Roland"},{"full_name":"Ebbinghaus, Simon","last_name":"Ebbinghaus","first_name":"Simon"},{"id":"237","full_name":"Huber, Klaus","last_name":"Huber","first_name":"Klaus"}],"date_created":"2023-02-06T11:50:05Z","volume":3,"title":"Thermodynamic Analysis of the Self‐Assembly of Pseudo Isocyanine Chloride in the Presence of Crowding Agents","doi":"10.1002/syst.202000051","publication_status":"published","publication_identifier":{"issn":["2570-4206","2570-4206"]},"issue":"3","year":"2021","citation":{"mla":"Hämisch, Benjamin, et al. “Thermodynamic Analysis of the Self‐Assembly of Pseudo Isocyanine Chloride in the Presence of Crowding Agents.” <i>ChemSystemsChem</i>, vol. 3, no. 3, Wiley, 2021, doi:<a href=\"https://doi.org/10.1002/syst.202000051\">10.1002/syst.202000051</a>.","bibtex":"@article{Hämisch_Pollak_Ebbinghaus_Huber_2021, title={Thermodynamic Analysis of the Self‐Assembly of Pseudo Isocyanine Chloride in the Presence of Crowding Agents}, volume={3}, DOI={<a href=\"https://doi.org/10.1002/syst.202000051\">10.1002/syst.202000051</a>}, number={3}, journal={ChemSystemsChem}, publisher={Wiley}, author={Hämisch, Benjamin and Pollak, Roland and Ebbinghaus, Simon and Huber, Klaus}, year={2021} }","short":"B. Hämisch, R. Pollak, S. Ebbinghaus, K. Huber, ChemSystemsChem 3 (2021).","apa":"Hämisch, B., Pollak, R., Ebbinghaus, S., &#38; Huber, K. (2021). Thermodynamic Analysis of the Self‐Assembly of Pseudo Isocyanine Chloride in the Presence of Crowding Agents. <i>ChemSystemsChem</i>, <i>3</i>(3). <a href=\"https://doi.org/10.1002/syst.202000051\">https://doi.org/10.1002/syst.202000051</a>","chicago":"Hämisch, Benjamin, Roland Pollak, Simon Ebbinghaus, and Klaus Huber. “Thermodynamic Analysis of the Self‐Assembly of Pseudo Isocyanine Chloride in the Presence of Crowding Agents.” <i>ChemSystemsChem</i> 3, no. 3 (2021). <a href=\"https://doi.org/10.1002/syst.202000051\">https://doi.org/10.1002/syst.202000051</a>.","ieee":"B. Hämisch, R. Pollak, S. Ebbinghaus, and K. Huber, “Thermodynamic Analysis of the Self‐Assembly of Pseudo Isocyanine Chloride in the Presence of Crowding Agents,” <i>ChemSystemsChem</i>, vol. 3, no. 3, 2021, doi: <a href=\"https://doi.org/10.1002/syst.202000051\">10.1002/syst.202000051</a>.","ama":"Hämisch B, Pollak R, Ebbinghaus S, Huber K. Thermodynamic Analysis of the Self‐Assembly of Pseudo Isocyanine Chloride in the Presence of Crowding Agents. <i>ChemSystemsChem</i>. 2021;3(3). doi:<a href=\"https://doi.org/10.1002/syst.202000051\">10.1002/syst.202000051</a>"},"intvolume":"         3","_id":"41815","user_id":"237","department":[{"_id":"314"}],"keyword":["General Earth and Planetary Sciences","General Environmental Science"],"language":[{"iso":"eng"}],"type":"journal_article","publication":"ChemSystemsChem","status":"public"},{"date_created":"2021-10-08T10:02:31Z","author":[{"first_name":"Bertram","last_name":"Schwind","full_name":"Schwind, Bertram"},{"first_name":"Jan-Henrik","full_name":"Smått, Jan-Henrik","last_name":"Smått"},{"first_name":"Michael","orcid":"0000-0003-1711-2722","last_name":"Tiemann","full_name":"Tiemann, Michael","id":"23547"},{"full_name":"Weinberger, Christian","id":"11848","last_name":"Weinberger","first_name":"Christian"}],"date_updated":"2023-03-07T10:44:44Z","doi":"10.1016/j.micromeso.2020.110330","title":"Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns","publication_status":"published","quality_controlled":"1","publication_identifier":{"issn":["1387-1811"]},"citation":{"ama":"Schwind B, Smått J-H, Tiemann M, Weinberger C. Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns. <i>Microporous and Mesoporous Materials</i>. Published online 2021. doi:<a href=\"https://doi.org/10.1016/j.micromeso.2020.110330\">10.1016/j.micromeso.2020.110330</a>","chicago":"Schwind, Bertram, Jan-Henrik Smått, Michael Tiemann, and Christian Weinberger. “Modeling of Gyroidal Mesoporous CMK-8 and CMK-9 Carbon Nanostructures and Their X-Ray Diffraction Patterns.” <i>Microporous and Mesoporous Materials</i>, 2021. <a href=\"https://doi.org/10.1016/j.micromeso.2020.110330\">https://doi.org/10.1016/j.micromeso.2020.110330</a>.","ieee":"B. Schwind, J.-H. Smått, M. Tiemann, and C. Weinberger, “Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns,” <i>Microporous and Mesoporous Materials</i>, Art. no. 110330, 2021, doi: <a href=\"https://doi.org/10.1016/j.micromeso.2020.110330\">10.1016/j.micromeso.2020.110330</a>.","apa":"Schwind, B., Smått, J.-H., Tiemann, M., &#38; Weinberger, C. (2021). Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns. <i>Microporous and Mesoporous Materials</i>, Article 110330. <a href=\"https://doi.org/10.1016/j.micromeso.2020.110330\">https://doi.org/10.1016/j.micromeso.2020.110330</a>","mla":"Schwind, Bertram, et al. “Modeling of Gyroidal Mesoporous CMK-8 and CMK-9 Carbon Nanostructures and Their X-Ray Diffraction Patterns.” <i>Microporous and Mesoporous Materials</i>, 110330, 2021, doi:<a href=\"https://doi.org/10.1016/j.micromeso.2020.110330\">10.1016/j.micromeso.2020.110330</a>.","bibtex":"@article{Schwind_Smått_Tiemann_Weinberger_2021, title={Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns}, DOI={<a href=\"https://doi.org/10.1016/j.micromeso.2020.110330\">10.1016/j.micromeso.2020.110330</a>}, number={110330}, journal={Microporous and Mesoporous Materials}, author={Schwind, Bertram and Smått, Jan-Henrik and Tiemann, Michael and Weinberger, Christian}, year={2021} }","short":"B. Schwind, J.-H. Smått, M. Tiemann, C. Weinberger, Microporous and Mesoporous Materials (2021)."},"year":"2021","user_id":"23547","department":[{"_id":"35"},{"_id":"2"},{"_id":"307"}],"_id":"25894","language":[{"iso":"eng"}],"article_type":"original","article_number":"110330","type":"journal_article","publication":"Microporous and Mesoporous Materials","status":"public","abstract":[{"text":"Powder X-ray diffraction (XRD) patterns of ordered mesoporous CMK-8 and CMK-9 carbon materials are simulated by geometric modeling. The materials are amorphous at the atomic length scale but exhibit highly symmetric gyroidal structures at the nanometer scale, corresponding to regular, continuous nanopore systems with cubic symmetry. Their structures lead to characteristic low-angle XRD signatures. We introduce a model based on geometrical considerations to simulate CMK-8 and CMK-9 structures with variable volume fraction of carbon (vs. pore volume, i.e., variable 'pore wall thickness'). In addition, we also simulate carbon materials with variable amounts of guest species (e.g., sulfur) residing in their pores. The corresponding XRD patterns are calculated. The carbon volume fraction turns out to have a significant impact on the relative diffraction peak intensities, especially in case of CMK-9 carbon that features a bimodal porosity. Likewise, the presence of guest species in the pores may also strongly affect the relative peak intensities. Our study suggests that careful evaluation of experimental low-angle XRD patterns of (real) CMK-8 or CMK-9 materials offers an opportunity to obtain detailed information about the nanostructural properties in addition to the mere identification of the pore systems geometry.","lang":"eng"}]},{"publication_identifier":{"issn":["0924-2031"]},"quality_controlled":"1","publication_status":"published","year":"2021","citation":{"mla":"de los Arcos, Teresa, et al. “Review of Infrared Spectroscopy Techniques for the Determination of Internal Structure in Thin SiO2 Films.” <i>Vibrational Spectroscopy</i>, 103256, 2021, doi:<a href=\"https://doi.org/10.1016/j.vibspec.2021.103256\">10.1016/j.vibspec.2021.103256</a>.","bibtex":"@article{de los Arcos_Müller_Wang_Damerla_Hoppe_Weinberger_Tiemann_Grundmeier_2021, title={Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films}, DOI={<a href=\"https://doi.org/10.1016/j.vibspec.2021.103256\">10.1016/j.vibspec.2021.103256</a>}, number={103256}, journal={Vibrational Spectroscopy}, author={de los Arcos, Teresa and Müller, Hendrik and Wang, Fuzeng and Damerla, Varun Raj and Hoppe, Christian and Weinberger, Christian and Tiemann, Michael and Grundmeier, Guido}, year={2021} }","short":"T. de los Arcos, H. Müller, F. Wang, V.R. Damerla, C. Hoppe, C. Weinberger, M. Tiemann, G. Grundmeier, Vibrational Spectroscopy (2021).","apa":"de los Arcos, T., Müller, H., Wang, F., Damerla, V. R., Hoppe, C., Weinberger, C., Tiemann, M., &#38; Grundmeier, G. (2021). Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films. <i>Vibrational Spectroscopy</i>, Article 103256. <a href=\"https://doi.org/10.1016/j.vibspec.2021.103256\">https://doi.org/10.1016/j.vibspec.2021.103256</a>","ieee":"T. de los Arcos <i>et al.</i>, “Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films,” <i>Vibrational Spectroscopy</i>, Art. no. 103256, 2021, doi: <a href=\"https://doi.org/10.1016/j.vibspec.2021.103256\">10.1016/j.vibspec.2021.103256</a>.","chicago":"Arcos, Teresa de los, Hendrik Müller, Fuzeng Wang, Varun Raj Damerla, Christian Hoppe, Christian Weinberger, Michael Tiemann, and Guido Grundmeier. “Review of Infrared Spectroscopy Techniques for the Determination of Internal Structure in Thin SiO2 Films.” <i>Vibrational Spectroscopy</i>, 2021. <a href=\"https://doi.org/10.1016/j.vibspec.2021.103256\">https://doi.org/10.1016/j.vibspec.2021.103256</a>.","ama":"de los Arcos T, Müller H, Wang F, et al. Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films. <i>Vibrational Spectroscopy</i>. Published online 2021. doi:<a href=\"https://doi.org/10.1016/j.vibspec.2021.103256\">10.1016/j.vibspec.2021.103256</a>"},"date_updated":"2023-03-07T10:44:06Z","author":[{"last_name":"de los Arcos","full_name":"de los Arcos, Teresa","first_name":"Teresa"},{"last_name":"Müller","full_name":"Müller, Hendrik","first_name":"Hendrik"},{"first_name":"Fuzeng","last_name":"Wang","full_name":"Wang, Fuzeng"},{"first_name":"Varun Raj","last_name":"Damerla","full_name":"Damerla, Varun Raj"},{"first_name":"Christian","full_name":"Hoppe, Christian","last_name":"Hoppe"},{"last_name":"Weinberger","id":"11848","full_name":"Weinberger, Christian","first_name":"Christian"},{"full_name":"Tiemann, Michael","id":"23547","orcid":"0000-0003-1711-2722","last_name":"Tiemann","first_name":"Michael"},{"last_name":"Grundmeier","full_name":"Grundmeier, Guido","id":"194","first_name":"Guido"}],"date_created":"2021-10-08T10:09:45Z","title":"Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films","doi":"10.1016/j.vibspec.2021.103256","publication":"Vibrational Spectroscopy","type":"journal_article","abstract":[{"text":"A comparison of infrared spectroscopic analytical approaches was made in order to assess their applicability for internal structure characterization of SiO2 thin films. Markers for porosity and/or disorder based on the analysis of the asymmetric stretching absorption band of SiO2 between 900−1350 cm−1 were discussed. The shape of this band, which shows a well-defined LO–TO splitting, depends not only on the inherent characteristics of the film under analysis but also on the particular geometry of the IR experiment and the specific surface selection rules of the substrate. Three types of SiO2 thin films with clearly defined porosity ranging from dense films to mesoporous films were investigated by transmission (at different incidence angles), direct specular reflection (at different angles), and diffuse reflection. Two different types of substrate, metallic and semiconducting, were used. The combined effect of substrate and specific technique in the final shape of the band, was discussed, and the efficacy for their applicability to the determination of porosity in thin SiO2 films was critically evaluated.","lang":"eng"}],"status":"public","_id":"25897","department":[{"_id":"35"},{"_id":"2"},{"_id":"307"},{"_id":"302"}],"user_id":"23547","article_type":"original","article_number":"103256","language":[{"iso":"eng"}]},{"abstract":[{"lang":"eng","text":"Tailor-made ordered mesoporous materials bear great potential in numerous fields of application where large interfaces are required. However, the inherent surfacechemical properties of conventional materials, such as silica, carbon or organosilica, poses some limitations with respect to their application. Surface manipulation by functionalization with chemically more reactive groups is one way to improve materials for their desired purpose. Another approach is the design of high surface-area composite materials. The surface manipulation, either by functionalization or by introducing guest species, can be performed selectively. This means that when several distinct, i.e. , hierarchical, types of surfaces or pore systems exist in a material, each of them may be chosen for manipulation. Several strategies can be identified to achieve this goal. Molecules or molecule assemblies can be utilized to temporarily protect pores or surfaces (soft protection), while manipulation occurs at the accessible sites. This approach is a recurring motive in this review and can also be applied to rigid template matrices (hard protection). Furthermore, the size of functionalization agents (size protection) and their reactivity/diffusion (kinetic protection) into the pores can also be utilized to achieve selectivity. In addition, challenges in the synthesis and characterization of selectively manipulated ordered mesoporous materials are discussed."}],"status":"public","type":"journal_article","publication":"Advanced Materials Interfaces","article_type":"review","article_number":"2001153","language":[{"iso":"eng"}],"_id":"25893","user_id":"23547","department":[{"_id":"35"},{"_id":"2"},{"_id":"307"}],"year":"2021","citation":{"ama":"Tiemann M, Weinberger C. Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials. <i>Advanced Materials Interfaces</i>. Published online 2021. doi:<a href=\"https://doi.org/10.1002/admi.202001153\">10.1002/admi.202001153</a>","ieee":"M. Tiemann and C. Weinberger, “Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials,” <i>Advanced Materials Interfaces</i>, Art. no. 2001153, 2021, doi: <a href=\"https://doi.org/10.1002/admi.202001153\">10.1002/admi.202001153</a>.","chicago":"Tiemann, Michael, and Christian Weinberger. “Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials.” <i>Advanced Materials Interfaces</i>, 2021. <a href=\"https://doi.org/10.1002/admi.202001153\">https://doi.org/10.1002/admi.202001153</a>.","mla":"Tiemann, Michael, and Christian Weinberger. “Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials.” <i>Advanced Materials Interfaces</i>, 2001153, 2021, doi:<a href=\"https://doi.org/10.1002/admi.202001153\">10.1002/admi.202001153</a>.","bibtex":"@article{Tiemann_Weinberger_2021, title={Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials}, DOI={<a href=\"https://doi.org/10.1002/admi.202001153\">10.1002/admi.202001153</a>}, number={2001153}, journal={Advanced Materials Interfaces}, author={Tiemann, Michael and Weinberger, Christian}, year={2021} }","short":"M. Tiemann, C. Weinberger, Advanced Materials Interfaces (2021).","apa":"Tiemann, M., &#38; Weinberger, C. (2021). Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials. <i>Advanced Materials Interfaces</i>, Article 2001153. <a href=\"https://doi.org/10.1002/admi.202001153\">https://doi.org/10.1002/admi.202001153</a>"},"publication_status":"published","publication_identifier":{"issn":["2196-7350","2196-7350"]},"quality_controlled":"1","title":"Selective Modification of Hierarchical Pores and Surfaces in Nanoporous Materials","main_file_link":[{"url":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202001153","open_access":"1"}],"doi":"10.1002/admi.202001153","date_updated":"2023-03-07T10:45:40Z","oa":"1","date_created":"2021-10-08T10:01:21Z","author":[{"first_name":"Michael","orcid":"0000-0003-1711-2722","last_name":"Tiemann","full_name":"Tiemann, Michael","id":"23547"},{"first_name":"Christian","last_name":"Weinberger","full_name":"Weinberger, Christian","id":"11848"}]}]