---
_id: '57625'
author:
- first_name: Frank
full_name: Giesselmann, Frank
last_name: Giesselmann
- first_name: Heinz-Siegfried
full_name: Kitzerow, Heinz-Siegfried
id: '254'
last_name: Kitzerow
- first_name: Rudolf
full_name: Zentel, Rudolf
last_name: Zentel
citation:
ama: Giesselmann F, Kitzerow H-S, Zentel R. Fifty years of liquid crystal research
in the mirror of the German Liquid Crystal Conference. Liquid Crystals Today.
2024;33(1):2-9. doi:10.1080/1358314x.2024.2415787
apa: Giesselmann, F., Kitzerow, H.-S., & Zentel, R. (2024). Fifty years of liquid
crystal research in the mirror of the German Liquid Crystal Conference. Liquid
Crystals Today, 33(1), 2–9. https://doi.org/10.1080/1358314x.2024.2415787
bibtex: '@article{Giesselmann_Kitzerow_Zentel_2024, title={Fifty years of liquid
crystal research in the mirror of the German Liquid Crystal Conference}, volume={33},
DOI={10.1080/1358314x.2024.2415787},
number={1}, journal={Liquid Crystals Today}, publisher={Informa UK Limited}, author={Giesselmann,
Frank and Kitzerow, Heinz-Siegfried and Zentel, Rudolf}, year={2024}, pages={2–9}
}'
chicago: 'Giesselmann, Frank, Heinz-Siegfried Kitzerow, and Rudolf Zentel. “Fifty
Years of Liquid Crystal Research in the Mirror of the German Liquid Crystal Conference.”
Liquid Crystals Today 33, no. 1 (2024): 2–9. https://doi.org/10.1080/1358314x.2024.2415787.'
ieee: 'F. Giesselmann, H.-S. Kitzerow, and R. Zentel, “Fifty years of liquid crystal
research in the mirror of the German Liquid Crystal Conference,” Liquid Crystals
Today, vol. 33, no. 1, pp. 2–9, 2024, doi: 10.1080/1358314x.2024.2415787.'
mla: Giesselmann, Frank, et al. “Fifty Years of Liquid Crystal Research in the Mirror
of the German Liquid Crystal Conference.” Liquid Crystals Today, vol. 33,
no. 1, Informa UK Limited, 2024, pp. 2–9, doi:10.1080/1358314x.2024.2415787.
short: F. Giesselmann, H.-S. Kitzerow, R. Zentel, Liquid Crystals Today 33 (2024)
2–9.
date_created: 2024-12-08T15:09:20Z
date_updated: 2024-12-08T15:11:24Z
department:
- _id: '313'
- _id: '230'
- _id: '2'
doi: 10.1080/1358314x.2024.2415787
intvolume: ' 33'
issue: '1'
language:
- iso: eng
page: 2-9
publication: Liquid Crystals Today
publication_identifier:
issn:
- 1358-314X
- 1464-5181
publication_status: published
publisher: Informa UK Limited
status: public
title: Fifty years of liquid crystal research in the mirror of the German Liquid Crystal
Conference
type: journal_article
user_id: '254'
volume: 33
year: '2024'
...
---
_id: '56947'
abstract:
- lang: eng
text: Pore engineering is commonly used to alter the properties of metal–organic
frameworks. This is achieved by incorporating different linker molecules (L) into
the structure, generating isoreticular frameworks. CPO-27, also named MOF-74,
is a prototypical material for this approach, offering the potential to modify
the size of its one-dimensional pore channels and the hydrophobicity of pore walls
using various linker ligands during synthesis. Thermal activation of these materials
yields accessible open metal sites (i.e., under-coordinated metal centers) at
the pore walls, thus acting as strong primary binding sites for guest molecules,
including water. We study the effect of the pore size and linker hydrophobicity
within a series of Ni2+-based isoreticular frameworks (i.e., Ni2L, L = dhtp, dhip,
dondc, bpp, bpm, tpp), analyzing their water sorption behavior and the water interactions
in the confined pore space. For this purpose, we apply water vapor sorption analysis
and Fourier transform infrared spectroscopy. In addition, defect degrees of all
compounds are determined by thermogravimetric analysis and solution 1H nuclear
magnetic resonance spectroscopy. We find that larger defect degrees affect the
preferential sorption sites in Ni2dhtp, while no such indication is found for
the other materials in our study. Instead, strong evidence is found for the formation
of water bridges/chains between coordinating water molecules, as previously observed
for hydrophobic porous carbons and mesoporous silica. This suggests similar sorption
energies for additional water molecules in materials with larger pore sizes after
saturation of the primary binding sites, resulting in more bulk-like water arrangements.
Consequently, the sorption mechanism is driven by classical pore condensation
through H-bonding anchor sites instead of sorption at discrete sites.
article_type: original
author:
- first_name: Marvin
full_name: Kloß, Marvin
last_name: Kloß
- first_name: Lara
full_name: Schäfers, Lara
last_name: Schäfers
- first_name: Zhenyu
full_name: Zhao, Zhenyu
last_name: Zhao
- first_name: Christian
full_name: Weinberger, Christian
id: '11848'
last_name: Weinberger
- first_name: Hans
full_name: Egold, Hans
id: '101'
last_name: Egold
- first_name: Michael
full_name: Tiemann, Michael
id: '23547'
last_name: Tiemann
orcid: 0000-0003-1711-2722
citation:
ama: 'Kloß M, Schäfers L, Zhao Z, Weinberger C, Egold H, Tiemann M. Water Sorption
on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites to Water-Bridge-Mediated
Pore Condensation. Nanomaterials. 2024;14(22):1791. doi:10.3390/nano14221791'
apa: 'Kloß, M., Schäfers, L., Zhao, Z., Weinberger, C., Egold, H., & Tiemann,
M. (2024). Water Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption
Sites to Water-Bridge-Mediated Pore Condensation. Nanomaterials, 14(22),
1791. https://doi.org/10.3390/nano14221791'
bibtex: '@article{Kloß_Schäfers_Zhao_Weinberger_Egold_Tiemann_2024, title={Water
Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites to Water-Bridge-Mediated
Pore Condensation}, volume={14}, DOI={10.3390/nano14221791},
number={22}, journal={Nanomaterials}, publisher={MDPI AG}, author={Kloß, Marvin
and Schäfers, Lara and Zhao, Zhenyu and Weinberger, Christian and Egold, Hans
and Tiemann, Michael}, year={2024}, pages={1791} }'
chicago: 'Kloß, Marvin, Lara Schäfers, Zhenyu Zhao, Christian Weinberger, Hans Egold,
and Michael Tiemann. “Water Sorption on Isoreticular CPO-27-Type MOFs: From Discrete
Sorption Sites to Water-Bridge-Mediated Pore Condensation.” Nanomaterials
14, no. 22 (2024): 1791. https://doi.org/10.3390/nano14221791.'
ieee: 'M. Kloß, L. Schäfers, Z. Zhao, C. Weinberger, H. Egold, and M. Tiemann, “Water
Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites to Water-Bridge-Mediated
Pore Condensation,” Nanomaterials, vol. 14, no. 22, p. 1791, 2024, doi:
10.3390/nano14221791.'
mla: 'Kloß, Marvin, et al. “Water Sorption on Isoreticular CPO-27-Type MOFs: From
Discrete Sorption Sites to Water-Bridge-Mediated Pore Condensation.” Nanomaterials,
vol. 14, no. 22, MDPI AG, 2024, p. 1791, doi:10.3390/nano14221791.'
short: M. Kloß, L. Schäfers, Z. Zhao, C. Weinberger, H. Egold, M. Tiemann, Nanomaterials
14 (2024) 1791.
date_created: 2024-11-08T06:18:11Z
date_updated: 2025-01-10T14:27:39Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.3390/nano14221791
intvolume: ' 14'
issue: '22'
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
page: '1791'
publication: Nanomaterials
publication_identifier:
issn:
- 2079-4991
publication_status: published
publisher: MDPI AG
quality_controlled: '1'
status: public
title: 'Water Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites
to Water-Bridge-Mediated Pore Condensation'
type: journal_article
user_id: '23547'
volume: 14
year: '2024'
...
---
_id: '56080'
abstract:
- lang: eng
text: CPO‐27 is a metal‐organic framework (MOF) with coordinatively unsaturated
metal centers (open metal sites). It is therefore an ideal host material for small
guest molecules, including water. This opens up numerous possible applications,
such as proton conduction, humidity sensing, water harvesting, or adsorption‐driven
heat pumps. For all of these applications, profound knowledge of the adsorption
and desorption of water in the micropores is mandatory. The hydration and water
structure in CPO‐27‐M (M = Zn or Cu) is investigated using water vapor sorption,
Fourier transform infrared (FTIR) spectroscopy, density functional theory (DFT)
calculations, and molecular dynamics simulation. In the pores of CPO‐27‐Zn, water
binds as a ligand to the Zn center. Additional water molecules are stepwise incorporated
at defined positions, forming a network of H‐bonds with the framework and with
each other. In CPO‐27‐Cu, hydration proceeds by an entirely different mechanism.
Here, water does not coordinate to the metal center, but only forms H‐bonds with
the framework; pore filling occurs mostly in a single step, with the open metal
site remaining unoccupied. Water in the pores forms clusters with extensive intra‐cluster
H‐bonding.
author:
- first_name: Marvin
full_name: Kloß, Marvin
last_name: Kloß
- first_name: Michael
full_name: Beerbaum, Michael
last_name: Beerbaum
- first_name: Dominik
full_name: Baier, Dominik
last_name: Baier
- first_name: Christian
full_name: Weinberger, Christian
id: '11848'
last_name: Weinberger
- first_name: Frederik
full_name: Zysk, Frederik
id: '14757'
last_name: Zysk
- first_name: Hossam
full_name: Elgabarty, Hossam
id: '60250'
last_name: Elgabarty
orcid: 0000-0002-4945-1481
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Michael
full_name: Tiemann, Michael
id: '23547'
last_name: Tiemann
orcid: 0000-0003-1711-2722
citation:
ama: 'Kloß M, Beerbaum M, Baier D, et al. Understanding Hydration in CPO‐27 Metal‐Organic
Frameworks: Strong Impact of the Chemical Nature of the Metal (Cu, Zn). Advanced
Materials Interfaces. 2024;11(35):2400476. doi:10.1002/admi.202400476'
apa: 'Kloß, M., Beerbaum, M., Baier, D., Weinberger, C., Zysk, F., Elgabarty, H.,
Kühne, T. D., & Tiemann, M. (2024). Understanding Hydration in CPO‐27 Metal‐Organic
Frameworks: Strong Impact of the Chemical Nature of the Metal (Cu, Zn). Advanced
Materials Interfaces, 11(35), 2400476. https://doi.org/10.1002/admi.202400476'
bibtex: '@article{Kloß_Beerbaum_Baier_Weinberger_Zysk_Elgabarty_Kühne_Tiemann_2024,
title={Understanding Hydration in CPO‐27 Metal‐Organic Frameworks: Strong Impact
of the Chemical Nature of the Metal (Cu, Zn)}, volume={11}, DOI={10.1002/admi.202400476},
number={35}, journal={Advanced Materials Interfaces}, publisher={Wiley}, author={Kloß,
Marvin and Beerbaum, Michael and Baier, Dominik and Weinberger, Christian and
Zysk, Frederik and Elgabarty, Hossam and Kühne, Thomas D. and Tiemann, Michael},
year={2024}, pages={2400476} }'
chicago: 'Kloß, Marvin, Michael Beerbaum, Dominik Baier, Christian Weinberger, Frederik
Zysk, Hossam Elgabarty, Thomas D. Kühne, and Michael Tiemann. “Understanding Hydration
in CPO‐27 Metal‐Organic Frameworks: Strong Impact of the Chemical Nature of the
Metal (Cu, Zn).” Advanced Materials Interfaces 11, no. 35 (2024): 2400476.
https://doi.org/10.1002/admi.202400476.'
ieee: 'M. Kloß et al., “Understanding Hydration in CPO‐27 Metal‐Organic Frameworks:
Strong Impact of the Chemical Nature of the Metal (Cu, Zn),” Advanced Materials
Interfaces, vol. 11, no. 35, p. 2400476, 2024, doi: 10.1002/admi.202400476.'
mla: 'Kloß, Marvin, et al. “Understanding Hydration in CPO‐27 Metal‐Organic Frameworks:
Strong Impact of the Chemical Nature of the Metal (Cu, Zn).” Advanced Materials
Interfaces, vol. 11, no. 35, Wiley, 2024, p. 2400476, doi:10.1002/admi.202400476.'
short: M. Kloß, M. Beerbaum, D. Baier, C. Weinberger, F. Zysk, H. Elgabarty, T.D.
Kühne, M. Tiemann, Advanced Materials Interfaces 11 (2024) 2400476.
date_created: 2024-09-06T07:07:17Z
date_updated: 2025-01-10T14:23:51Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1002/admi.202400476
intvolume: ' 11'
issue: '35'
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
page: '2400476'
publication: Advanced Materials Interfaces
publication_identifier:
issn:
- 2196-7350
- 2196-7350
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: 'Understanding Hydration in CPO‐27 Metal‐Organic Frameworks: Strong Impact
of the Chemical Nature of the Metal (Cu, Zn)'
type: journal_article
user_id: '23547'
volume: 11
year: '2024'
...
---
_id: '58612'
author:
- first_name: Maximina
full_name: Luis-Sunga, Maximina
last_name: Luis-Sunga
- first_name: Alejandro
full_name: González-Orive, Alejandro
last_name: González-Orive
- first_name: Juan Carlos
full_name: Calderón, Juan Carlos
last_name: Calderón
- first_name: Ilaria
full_name: Gamba, Ilaria
last_name: Gamba
- first_name: Airán
full_name: Ródenas, Airán
last_name: Ródenas
- first_name: Maria Teresa
full_name: de los Arcos de Pedro, Maria Teresa
id: '54556'
last_name: de los Arcos de Pedro
orcid: '0000-0002-8684-273X '
- first_name: Alberto
full_name: Hernández-Creus, Alberto
last_name: Hernández-Creus
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
- first_name: Elena
full_name: Pastor, Elena
last_name: Pastor
- first_name: Gonzalo
full_name: García, Gonzalo
last_name: García
citation:
ama: Luis-Sunga M, González-Orive A, Calderón JC, et al. Nickel-Induced Reduced
Graphene Oxide Nanoribbon Formation on Highly Ordered Pyrolytic Graphite for Electronic
and Magnetic Applications. ACS Applied Nano Materials. Published online
2024. doi:10.1021/acsanm.3c05949
apa: Luis-Sunga, M., González-Orive, A., Calderón, J. C., Gamba, I., Ródenas, A.,
de los Arcos de Pedro, M. T., Hernández-Creus, A., Grundmeier, G., Pastor, E.,
& García, G. (2024). Nickel-Induced Reduced Graphene Oxide Nanoribbon Formation
on Highly Ordered Pyrolytic Graphite for Electronic and Magnetic Applications.
ACS Applied Nano Materials. https://doi.org/10.1021/acsanm.3c05949
bibtex: '@article{Luis-Sunga_González-Orive_Calderón_Gamba_Ródenas_de los Arcos
de Pedro_Hernández-Creus_Grundmeier_Pastor_García_2024, title={Nickel-Induced
Reduced Graphene Oxide Nanoribbon Formation on Highly Ordered Pyrolytic Graphite
for Electronic and Magnetic Applications}, DOI={10.1021/acsanm.3c05949},
journal={ACS Applied Nano Materials}, author={Luis-Sunga, Maximina and González-Orive,
Alejandro and Calderón, Juan Carlos and Gamba, Ilaria and Ródenas, Airán and de
los Arcos de Pedro, Maria Teresa and Hernández-Creus, Alberto and Grundmeier,
Guido and Pastor, Elena and García, Gonzalo}, year={2024} }'
chicago: Luis-Sunga, Maximina, Alejandro González-Orive, Juan Carlos Calderón, Ilaria
Gamba, Airán Ródenas, Maria Teresa de los Arcos de Pedro, Alberto Hernández-Creus,
Guido Grundmeier, Elena Pastor, and Gonzalo García. “Nickel-Induced Reduced Graphene
Oxide Nanoribbon Formation on Highly Ordered Pyrolytic Graphite for Electronic
and Magnetic Applications.” ACS Applied Nano Materials, 2024. https://doi.org/10.1021/acsanm.3c05949.
ieee: 'M. Luis-Sunga et al., “Nickel-Induced Reduced Graphene Oxide Nanoribbon
Formation on Highly Ordered Pyrolytic Graphite for Electronic and Magnetic Applications,”
ACS Applied Nano Materials, 2024, doi: 10.1021/acsanm.3c05949.'
mla: Luis-Sunga, Maximina, et al. “Nickel-Induced Reduced Graphene Oxide Nanoribbon
Formation on Highly Ordered Pyrolytic Graphite for Electronic and Magnetic Applications.”
ACS Applied Nano Materials, 2024, doi:10.1021/acsanm.3c05949.
short: M. Luis-Sunga, A. González-Orive, J.C. Calderón, I. Gamba, A. Ródenas, M.T.
de los Arcos de Pedro, A. Hernández-Creus, G. Grundmeier, E. Pastor, G. García,
ACS Applied Nano Materials (2024).
date_created: 2025-02-12T14:49:11Z
date_updated: 2025-02-12T14:56:48Z
department:
- _id: '302'
doi: 10.1021/acsanm.3c05949
language:
- iso: eng
publication: ACS Applied Nano Materials
publication_identifier:
issn:
- 2574-0970
status: public
title: Nickel-Induced Reduced Graphene Oxide Nanoribbon Formation on Highly Ordered
Pyrolytic Graphite for Electronic and Magnetic Applications
type: journal_article
user_id: '54556'
year: '2024'
...
---
_id: '58611'
abstract:
- lang: eng
text: AFM-IR investigation of thin PECVD SiOx films on a polypropylene substrate
in the surface-sensitive mode
author:
- first_name: Hendrik
full_name: Müller, Hendrik
last_name: Müller
- first_name: Hartmut
full_name: Stadler, Hartmut
last_name: Stadler
- first_name: Maria Teresa
full_name: de los Arcos de Pedro, Maria Teresa
id: '54556'
last_name: de los Arcos de Pedro
orcid: '0000-0002-8684-273X '
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
citation:
ama: Müller H, Stadler H, de los Arcos de Pedro MT, Keller A, Grundmeier G. AFM-IR
investigation of thin PECVD SiO x films on a polypropylene substrate in the surface-sensitive
mode. Beilstein Journal of Nanotechnology. 2024;15(1):603–611. doi:10.3762/bjnano.15.51
apa: Müller, H., Stadler, H., de los Arcos de Pedro, M. T., Keller, A., & Grundmeier,
G. (2024). AFM-IR investigation of thin PECVD SiO x films on a polypropylene substrate
in the surface-sensitive mode. Beilstein Journal of Nanotechnology, 15(1),
603–611. https://doi.org/10.3762/bjnano.15.51
bibtex: '@article{Müller_Stadler_de los Arcos de Pedro_Keller_Grundmeier_2024, title={AFM-IR
investigation of thin PECVD SiO x films on a polypropylene substrate in the surface-sensitive
mode}, volume={15}, DOI={10.3762/bjnano.15.51},
number={1}, journal={Beilstein Journal of Nanotechnology}, author={Müller, Hendrik
and Stadler, Hartmut and de los Arcos de Pedro, Maria Teresa and Keller, Adrian
and Grundmeier, Guido}, year={2024}, pages={603–611} }'
chicago: 'Müller, Hendrik, Hartmut Stadler, Maria Teresa de los Arcos de Pedro,
Adrian Keller, and Guido Grundmeier. “AFM-IR Investigation of Thin PECVD SiO x
Films on a Polypropylene Substrate in the Surface-Sensitive Mode.” Beilstein
Journal of Nanotechnology 15, no. 1 (2024): 603–611. https://doi.org/10.3762/bjnano.15.51.'
ieee: 'H. Müller, H. Stadler, M. T. de los Arcos de Pedro, A. Keller, and G. Grundmeier,
“AFM-IR investigation of thin PECVD SiO x films on a polypropylene substrate in
the surface-sensitive mode,” Beilstein Journal of Nanotechnology, vol.
15, no. 1, pp. 603–611, 2024, doi: 10.3762/bjnano.15.51.'
mla: Müller, Hendrik, et al. “AFM-IR Investigation of Thin PECVD SiO x Films on
a Polypropylene Substrate in the Surface-Sensitive Mode.” Beilstein Journal
of Nanotechnology, vol. 15, no. 1, 2024, pp. 603–611, doi:10.3762/bjnano.15.51.
short: H. Müller, H. Stadler, M.T. de los Arcos de Pedro, A. Keller, G. Grundmeier,
Beilstein Journal of Nanotechnology 15 (2024) 603–611.
date_created: 2025-02-12T14:48:49Z
date_updated: 2025-02-12T14:56:14Z
department:
- _id: '302'
doi: 10.3762/bjnano.15.51
intvolume: ' 15'
issue: '1'
language:
- iso: eng
page: 603–611
publication: Beilstein Journal of Nanotechnology
publication_identifier:
issn:
- 2190-4286
status: public
title: AFM-IR investigation of thin PECVD SiO x films on a polypropylene substrate
in the surface-sensitive mode
type: journal_article
user_id: '54556'
volume: 15
year: '2024'
...
---
_id: '56075'
abstract:
- lang: eng
text: An isostructural series of FeII, FeIII, and Fe(IV)complexes [Fe(ImP)2]0/+/2+
utilizing the ImP 1,1′-(1,3-phenylene)-bis(3-methyl-1-imidazol-2-ylidene) ligand,
combining N-heterocy-clic carbenes and cyclometalating functions, is presented.
The strong donor motif stabilizes the high-valent Fe(IV) oxidation state yet keeps
the FeII oxidation state accessible from the parent Fe(III)compound. Chemical
oxidation of [Fe(ImP)2]+ yields stable [FeIV(ImP)2]2+. In contrast, [FeII(ImP)2]0,
obtained by reduction,is highly sensitive toward oxygen. Exhaustive ground state
characterization by single-crystal X-ray diffraction, 1H NMR,Mössbauer spectroscopy,
temperature-dependent magnetic measurements, a combination of X-ray absorption
near edge structureand valence-to-core, as well as core-to-core X-ray emission
spectroscopy, complemented by detailed density functional theory (DFT) analysis,
reveals that the three complexes[Fe(ImP)2]0/+/2+ can be unequivocally attributed
to low-spin d6, d5, and d4 complexes. The excited state landscape of the Fe(II)
and Fe(IV) complexes is characterized by short-lived 3MLCT and 3LMCT states, with
lifetimes of 5.1 and 1.4 ps, respectively. In the FeII-compound, an energetically
low-lying MC state leads to fast deactivation of the MLCT state. The distorted
square-pyramidal state, where one carbene is dissociated, can not only relax into
the ground state, but also into a singlet dissociated state. Its formation was
investigated with time-dependent optical spectroscopy, while insights into its
structure were gained by NMR spectroscopy.
author:
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Ayla
full_name: Kruse, Ayla
last_name: Kruse
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Serhiy
full_name: Demeshko, Serhiy
last_name: Demeshko
- first_name: Hossam
full_name: Elgabarty, Hossam
id: '60250'
last_name: Elgabarty
orcid: 0000-0002-4945-1481
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Mohammad
full_name: Alaraby, Mohammad
last_name: Alaraby
- first_name: Hans
full_name: Egold, Hans
id: '101'
last_name: Egold
- first_name: Bastian Johannes
full_name: Bracht, Bastian Johannes
id: '86707'
last_name: Bracht
- first_name: Lennart
full_name: Schmitz, Lennart
id: '53140'
last_name: Schmitz
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Franc
full_name: Meyer, Franc
last_name: Meyer
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Steube J, Fritsch L, Kruse A, et al. Isostructural Series of a Cyclometalated
Iron Complex in Three Oxidation States. Inorganic Chemistry. Published
online 2024. doi:10.1021/acs.inorgchem.4c02576
apa: Steube, J., Fritsch, L., Kruse, A., Bokareva, O. S., Demeshko, S., Elgabarty,
H., Schoch, R., Alaraby, M., Egold, H., Bracht, B. J., Schmitz, L., Hohloch, S.,
Kühne, T. D., Meyer, F., Kühn, O., Lochbrunner, S., & Bauer, M. (2024). Isostructural
Series of a Cyclometalated Iron Complex in Three Oxidation States. Inorganic
Chemistry. https://doi.org/10.1021/acs.inorgchem.4c02576
bibtex: '@article{Steube_Fritsch_Kruse_Bokareva_Demeshko_Elgabarty_Schoch_Alaraby_Egold_Bracht_et
al._2024, title={Isostructural Series of a Cyclometalated Iron Complex in Three
Oxidation States}, DOI={10.1021/acs.inorgchem.4c02576},
journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Steube,
Jakob and Fritsch, Lorena and Kruse, Ayla and Bokareva, Olga S. and Demeshko,
Serhiy and Elgabarty, Hossam and Schoch, Roland and Alaraby, Mohammad and Egold,
Hans and Bracht, Bastian Johannes and et al.}, year={2024} }'
chicago: Steube, Jakob, Lorena Fritsch, Ayla Kruse, Olga S. Bokareva, Serhiy Demeshko,
Hossam Elgabarty, Roland Schoch, et al. “Isostructural Series of a Cyclometalated
Iron Complex in Three Oxidation States.” Inorganic Chemistry, 2024. https://doi.org/10.1021/acs.inorgchem.4c02576.
ieee: 'J. Steube et al., “Isostructural Series of a Cyclometalated Iron Complex
in Three Oxidation States,” Inorganic Chemistry, 2024, doi: 10.1021/acs.inorgchem.4c02576.'
mla: Steube, Jakob, et al. “Isostructural Series of a Cyclometalated Iron Complex
in Three Oxidation States.” Inorganic Chemistry, American Chemical Society
(ACS), 2024, doi:10.1021/acs.inorgchem.4c02576.
short: J. Steube, L. Fritsch, A. Kruse, O.S. Bokareva, S. Demeshko, H. Elgabarty,
R. Schoch, M. Alaraby, H. Egold, B.J. Bracht, L. Schmitz, S. Hohloch, T.D. Kühne,
F. Meyer, O. Kühn, S. Lochbrunner, M. Bauer, Inorganic Chemistry (2024).
date_created: 2024-09-05T11:34:20Z
date_updated: 2025-08-15T12:17:35Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.4c02576
keyword:
- Photo
language:
- iso: eng
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Isostructural Series of a Cyclometalated Iron Complex in Three Oxidation States
type: journal_article
user_id: '48467'
year: '2024'
...
---
_id: '56074'
abstract:
- lang: eng
text: Effective photoinduced charge transfer makes molecular bimetallic assemblies
attractive for applications as active light‐induced proton reduction systems.
Developing competitive base metal dyads is mandatory for a more sustainable future.
However, the electron transfer mechanisms from the photosensitizer to the proton
reduction catalyst in base metal dyads remain so far unexplored. A Fe─Co dyad
that exhibits photocatalytic H2 production activity is studied using femtosecond
X‐ray emission spectroscopy, complemented by ultrafast optical spectroscopy and
theoretical time‐dependent DFT calculations, to understand the electronic and
structural dynamics after photoexcitation and during the subsequent charge transfer
process from the Fe(II) photosensitizer to the cobaloxime catalyst. This novel
approach enables the simultaneous measurement of the transient X‐ray emission
at the iron and cobalt K‐edges in a two‐color experiment. With this methodology,
the excited state dynamics are correlated to the electron transfer processes,
and evidence of the Fe→Co electron transfer as an initial step of proton reduction
activity is unraveled.
author:
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Marina
full_name: Huber‐Gedert, Marina
last_name: Huber‐Gedert
- first_name: Hossam
full_name: Elgabarty, Hossam
id: '60250'
last_name: Elgabarty
orcid: 0000-0002-4945-1481
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Jacek
full_name: Kubicki, Jacek
last_name: Kubicki
- first_name: Ahmet
full_name: Kertmen, Ahmet
last_name: Kertmen
- first_name: Natalia
full_name: Lindner, Natalia
last_name: Lindner
- first_name: Dmitry
full_name: Khakhulin, Dmitry
last_name: Khakhulin
- first_name: Frederico A.
full_name: Lima, Frederico A.
last_name: Lima
- first_name: Tae‐Kyu
full_name: Choi, Tae‐Kyu
last_name: Choi
- first_name: Mykola
full_name: Biednov, Mykola
last_name: Biednov
- first_name: Lennart
full_name: Schmitz, Lennart
id: '53140'
last_name: Schmitz
- first_name: Natalia
full_name: Piergies, Natalia
last_name: Piergies
- first_name: Peter
full_name: Zalden, Peter
last_name: Zalden
- first_name: Katerina
full_name: Kubicek, Katerina
last_name: Kubicek
- first_name: Angel
full_name: Rodriguez‐Fernandez, Angel
last_name: Rodriguez‐Fernandez
- first_name: Mohammad Alaraby
full_name: Salem, Mohammad Alaraby
last_name: Salem
- first_name: Sophie E.
full_name: Canton, Sophie E.
last_name: Canton
- first_name: Christian
full_name: Bressler, Christian
last_name: Bressler
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Wojciech
full_name: Gawelda, Wojciech
last_name: Gawelda
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Nowakowski M, Huber‐Gedert M, Elgabarty H, et al. Ultrafast Two‐Color X‐Ray
Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad. Advanced
Science. Published online 2024. doi:10.1002/advs.202404348
apa: Nowakowski, M., Huber‐Gedert, M., Elgabarty, H., Kalinko, A., Kubicki, J.,
Kertmen, A., Lindner, N., Khakhulin, D., Lima, F. A., Choi, T., Biednov, M., Schmitz,
L., Piergies, N., Zalden, P., Kubicek, K., Rodriguez‐Fernandez, A., Salem, M.
A., Canton, S. E., Bressler, C., … Bauer, M. (2024). Ultrafast Two‐Color X‐Ray
Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad. Advanced
Science. https://doi.org/10.1002/advs.202404348
bibtex: '@article{Nowakowski_Huber‐Gedert_Elgabarty_Kalinko_Kubicki_Kertmen_Lindner_Khakhulin_Lima_Choi_et
al._2024, title={Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited
State Landscape in a Base Metal Dyad}, DOI={10.1002/advs.202404348},
journal={Advanced Science}, publisher={Wiley}, author={Nowakowski, Michał and
Huber‐Gedert, Marina and Elgabarty, Hossam and Kalinko, Aleksandr and Kubicki,
Jacek and Kertmen, Ahmet and Lindner, Natalia and Khakhulin, Dmitry and Lima,
Frederico A. and Choi, Tae‐Kyu and et al.}, year={2024} }'
chicago: Nowakowski, Michał, Marina Huber‐Gedert, Hossam Elgabarty, Aleksandr Kalinko,
Jacek Kubicki, Ahmet Kertmen, Natalia Lindner, et al. “Ultrafast Two‐Color X‐Ray
Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad.” Advanced
Science, 2024. https://doi.org/10.1002/advs.202404348.
ieee: 'M. Nowakowski et al., “Ultrafast Two‐Color X‐Ray Emission Spectroscopy
Reveals Excited State Landscape in a Base Metal Dyad,” Advanced Science,
2024, doi: 10.1002/advs.202404348.'
mla: Nowakowski, Michał, et al. “Ultrafast Two‐Color X‐Ray Emission Spectroscopy
Reveals Excited State Landscape in a Base Metal Dyad.” Advanced Science,
Wiley, 2024, doi:10.1002/advs.202404348.
short: M. Nowakowski, M. Huber‐Gedert, H. Elgabarty, A. Kalinko, J. Kubicki, A.
Kertmen, N. Lindner, D. Khakhulin, F.A. Lima, T. Choi, M. Biednov, L. Schmitz,
N. Piergies, P. Zalden, K. Kubicek, A. Rodriguez‐Fernandez, M.A. Salem, S.E. Canton,
C. Bressler, T.D. Kühne, W. Gawelda, M. Bauer, Advanced Science (2024).
date_created: 2024-09-05T11:31:30Z
date_updated: 2025-08-15T12:49:56Z
department:
- _id: '306'
doi: 10.1002/advs.202404348
keyword:
- Photo
- Xray
language:
- iso: eng
publication: Advanced Science
publication_identifier:
issn:
- 2198-3844
- 2198-3844
publication_status: published
publisher: Wiley
status: public
title: Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape
in a Base Metal Dyad
type: journal_article
user_id: '48467'
year: '2024'
...
---
_id: '52346'
abstract:
- lang: eng
text: Promising cathode materials for fluoride-ion batteries (FIBs) are 3d transition
metal containing oxides with Ruddlesden-Popper-type structure. So far, multi-elemental
compositions were not investigated, but could alternate electrochemical performance
similar to what has been found for cathode materials for lithium-ion batteries.
Within this study, we investigate RP type La2Ni0.75Co0.25O4.08 as an intercalation-based
active cathode material for all-solid-state FIBs. We determine the structural
changes of La2Ni0.75Co0.25O4.08 during fluoride intercalation / de-intercalation
by ex-situ X-ray diffraction, which showed that F- insertion leads to transformation
of the parent phase to three different phases. Changes in Ni and Co oxidation
states and coordination environment were examined by X-ray absorption spectroscopy
and magnetic measurements in order to understand the complex reaction behaviour
of the phases in detail, showing that the two transition metals behave differently
in the charging and discharging process. Under optimized operating conditions,
a cycle life of 120 cycles at a critical cut-off capacity of 40 mAh g-1 against
Pb/PbF2 was obtained, which is one of the highest observed for intercalation electrode
materials in FIBs so far. The average Coulombic efficiencies ranged from 85% to
90%. Thus, La2Ni0.75Co0.25O4.08 could be a promising candidate for cycling-stable
high-energy cathode materials for all-solid-state FIBs
author:
- first_name: Vanita
full_name: Vanita, Vanita
last_name: Vanita
- first_name: Aamir Iqbal
full_name: Waidha, Aamir Iqbal
last_name: Waidha
- first_name: Sami
full_name: Vasala, Sami
last_name: Vasala
- first_name: Pascal
full_name: Puphal, Pascal
last_name: Puphal
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Pieter
full_name: Glatzel, Pieter
last_name: Glatzel
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Oliver
full_name: Clemens, Oliver
last_name: Clemens
citation:
ama: Vanita V, Waidha AI, Vasala S, et al. Insights into the First Multi-Transition-Metal
Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries.
Journal of Materials Chemistry A. 2024;(12). doi:10.1039/d4ta00704b
apa: Vanita, V., Waidha, A. I., Vasala, S., Puphal, P., Schoch, R., Glatzel, P.,
Bauer, M., & Clemens, O. (2024). Insights into the First Multi-Transition-Metal
Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries.
Journal of Materials Chemistry A, 12. https://doi.org/10.1039/d4ta00704b
bibtex: '@article{Vanita_Waidha_Vasala_Puphal_Schoch_Glatzel_Bauer_Clemens_2024,
title={Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type
Cathode for all-solid-state Fluoride Ion Batteries}, DOI={10.1039/d4ta00704b},
number={12}, journal={Journal of Materials Chemistry A}, publisher={Royal Society
of Chemistry (RSC)}, author={Vanita, Vanita and Waidha, Aamir Iqbal and Vasala,
Sami and Puphal, Pascal and Schoch, Roland and Glatzel, Pieter and Bauer, Matthias
and Clemens, Oliver}, year={2024} }'
chicago: Vanita, Vanita, Aamir Iqbal Waidha, Sami Vasala, Pascal Puphal, Roland
Schoch, Pieter Glatzel, Matthias Bauer, and Oliver Clemens. “Insights into the
First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for All-Solid-State
Fluoride Ion Batteries.” Journal of Materials Chemistry A, no. 12 (2024).
https://doi.org/10.1039/d4ta00704b.
ieee: 'V. Vanita et al., “Insights into the First Multi-Transition-Metal
Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries,”
Journal of Materials Chemistry A, no. 12, 2024, doi: 10.1039/d4ta00704b.'
mla: Vanita, Vanita, et al. “Insights into the First Multi-Transition-Metal Containing
Ruddlesden Popper-Type Cathode for All-Solid-State Fluoride Ion Batteries.” Journal
of Materials Chemistry A, no. 12, Royal Society of Chemistry (RSC), 2024,
doi:10.1039/d4ta00704b.
short: V. Vanita, A.I. Waidha, S. Vasala, P. Puphal, R. Schoch, P. Glatzel, M. Bauer,
O. Clemens, Journal of Materials Chemistry A (2024).
date_created: 2024-03-07T10:01:09Z
date_updated: 2025-08-15T12:50:31Z
department:
- _id: '306'
doi: 10.1039/d4ta00704b
issue: '12'
keyword:
- Xray
language:
- iso: eng
publication: Journal of Materials Chemistry A
publication_identifier:
issn:
- 2050-7488
- 2050-7496
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type
Cathode for all-solid-state Fluoride Ion Batteries
type: journal_article
user_id: '48467'
year: '2024'
...
---
_id: '60216'
abstract:
- lang: eng
text: Hydride donors such as DIBAL or CuH react with ZnO and ZrO2 via hydrogen spillover.
This suggests that hydrogen spillover in catalysts based on these metal oxides
may take place via initial hydride transfer and not via proton–electron transfer.
author:
- first_name: Michael
full_name: Benz, Michael
last_name: Benz
- first_name: Osman
full_name: Bunjaku, Osman
last_name: Bunjaku
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Alexander
full_name: Allgaier, Alexander
last_name: Allgaier
- first_name: Indro
full_name: Biswas, Indro
last_name: Biswas
- first_name: Joris
full_name: van Slageren, Joris
last_name: van Slageren
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Deven P.
full_name: Estes, Deven P.
last_name: Estes
citation:
ama: 'Benz M, Bunjaku O, Nowakowski M, et al. Hydrogen spillover through hydride
transfer: the reaction of ZnO and ZrO2 with strong hydride donors. Catalysis
Science & Technology. 2024;14(20):5854-5863. doi:10.1039/d4cy00504j'
apa: 'Benz, M., Bunjaku, O., Nowakowski, M., Allgaier, A., Biswas, I., van Slageren,
J., Bauer, M., & Estes, D. P. (2024). Hydrogen spillover through hydride transfer:
the reaction of ZnO and ZrO2 with strong hydride donors. Catalysis Science
& Technology, 14(20), 5854–5863. https://doi.org/10.1039/d4cy00504j'
bibtex: '@article{Benz_Bunjaku_Nowakowski_Allgaier_Biswas_van Slageren_Bauer_Estes_2024,
title={Hydrogen spillover through hydride transfer: the reaction of ZnO and ZrO2
with strong hydride donors}, volume={14}, DOI={10.1039/d4cy00504j},
number={20}, journal={Catalysis Science & Technology}, publisher={Royal Society
of Chemistry (RSC)}, author={Benz, Michael and Bunjaku, Osman and Nowakowski,
Michał and Allgaier, Alexander and Biswas, Indro and van Slageren, Joris and Bauer,
Matthias and Estes, Deven P.}, year={2024}, pages={5854–5863} }'
chicago: 'Benz, Michael, Osman Bunjaku, Michał Nowakowski, Alexander Allgaier, Indro
Biswas, Joris van Slageren, Matthias Bauer, and Deven P. Estes. “Hydrogen Spillover
through Hydride Transfer: The Reaction of ZnO and ZrO2 with Strong Hydride Donors.”
Catalysis Science & Technology 14, no. 20 (2024): 5854–63. https://doi.org/10.1039/d4cy00504j.'
ieee: 'M. Benz et al., “Hydrogen spillover through hydride transfer: the
reaction of ZnO and ZrO2 with strong hydride donors,” Catalysis Science &
Technology, vol. 14, no. 20, pp. 5854–5863, 2024, doi: 10.1039/d4cy00504j.'
mla: 'Benz, Michael, et al. “Hydrogen Spillover through Hydride Transfer: The Reaction
of ZnO and ZrO2 with Strong Hydride Donors.” Catalysis Science & Technology,
vol. 14, no. 20, Royal Society of Chemistry (RSC), 2024, pp. 5854–63, doi:10.1039/d4cy00504j.'
short: M. Benz, O. Bunjaku, M. Nowakowski, A. Allgaier, I. Biswas, J. van Slageren,
M. Bauer, D.P. Estes, Catalysis Science & Technology 14 (2024) 5854–5863.
date_created: 2025-06-16T08:55:24Z
date_updated: 2025-08-15T12:42:34Z
department:
- _id: '306'
doi: 10.1039/d4cy00504j
intvolume: ' 14'
issue: '20'
keyword:
- Xray
language:
- iso: eng
page: 5854-5863
publication: Catalysis Science & Technology
publication_identifier:
issn:
- 2044-4753
- 2044-4761
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: 'Hydrogen spillover through hydride transfer: the reaction of ZnO and ZrO2
with strong hydride donors'
type: journal_article
user_id: '48467'
volume: 14
year: '2024'
...
---
_id: '54024'
abstract:
- lang: eng
text: Transition metal complexes, particularly copper hydrides, play an important
role in various catalytic processes and molecular inorganic chemistry. This study
employs synchrotron hard X‐ray spectroscopy to gain insights into the geometric
and electronic properties of copper hydrides as potential catalysts for CO2 hydrogenation.
The potential of high energy resolution X‐ray absorption near‐edge structure (HERFD‐XANES)
and valence‐to‐core X‐ray emission (VtC‐XES) is demonstrated with measurement
on Stryker's reagent (Cu6H6) and [Cu3(μ3‐H)(dpmppe)2](PF6)2 (Cu3H), alongside
a non‐hydride copper compound (Cu‐I). The XANES analysis reveals that coordination
geometries strongly influence the spectra, providing only indirect details about
hydride coordination. The VtC‐XES analysis exhibits a distinct signal around 8975
eV, offering a diagnostic tool to identify hydride ligands. Theoretical calculations
support and extend these findings by comparing hydride‐containing complexes with
their hydride‐free counterparts.
article_type: original
author:
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Pia
full_name: Rehsies, Pia
id: '46959'
last_name: Rehsies
- first_name: Wael
full_name: Barakat, Wael
last_name: Barakat
- first_name: Deven P.
full_name: Estes, Deven P.
last_name: Estes
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Fritsch L, Rehsies P, Barakat W, Estes DP, Bauer M. Detection and Characterization
of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy. Chemistry
– A European Journal. 2024;30(36). doi:10.1002/chem.202400357
apa: Fritsch, L., Rehsies, P., Barakat, W., Estes, D. P., & Bauer, M. (2024).
Detection and Characterization of Hydride Ligands in Copper Complexes by Hard
X‐ray Spectroscopy. Chemistry – A European Journal, 30(36). https://doi.org/10.1002/chem.202400357
bibtex: '@article{Fritsch_Rehsies_Barakat_Estes_Bauer_2024, title={Detection and
Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy},
volume={30}, DOI={10.1002/chem.202400357},
number={36}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Fritsch,
Lorena and Rehsies, Pia and Barakat, Wael and Estes, Deven P. and Bauer, Matthias},
year={2024} }'
chicago: Fritsch, Lorena, Pia Rehsies, Wael Barakat, Deven P. Estes, and Matthias
Bauer. “Detection and Characterization of Hydride Ligands in Copper Complexes
by Hard X‐ray Spectroscopy.” Chemistry – A European Journal 30, no. 36
(2024). https://doi.org/10.1002/chem.202400357.
ieee: 'L. Fritsch, P. Rehsies, W. Barakat, D. P. Estes, and M. Bauer, “Detection
and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy,”
Chemistry – A European Journal, vol. 30, no. 36, 2024, doi: 10.1002/chem.202400357.'
mla: Fritsch, Lorena, et al. “Detection and Characterization of Hydride Ligands
in Copper Complexes by Hard X‐ray Spectroscopy.” Chemistry – A European Journal,
vol. 30, no. 36, Wiley, 2024, doi:10.1002/chem.202400357.
short: L. Fritsch, P. Rehsies, W. Barakat, D.P. Estes, M. Bauer, Chemistry – A European
Journal 30 (2024).
date_created: 2024-05-07T08:41:11Z
date_updated: 2025-08-15T12:51:10Z
department:
- _id: '306'
doi: 10.1002/chem.202400357
intvolume: ' 30'
issue: '36'
keyword:
- Xray
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Detection and Characterization of Hydride Ligands in Copper Complexes by Hard
X‐ray Spectroscopy
type: journal_article
user_id: '48467'
volume: 30
year: '2024'
...
---
_id: '54969'
abstract:
- lang: eng
text: This work presents a new and facile route for the preparation of iron oxide-based
catalysts supported on alumina, which enables the targeted synthesis of catalysts
with an increased amount of isolated tetrahedrally coordinated iron centers compared
to a conventional impregnation procedure, and therefore leads to an increase in
activity for CO oxidation reaction. By a multi-step impregnation–calcination protocol,
the catalysts were synthesized with iron loadings of between 1 and 10 wt%, and
their catalytic activity was then compared with a 10 wt% loaded catalyst prepared
by conventional single impregnation. With a loading of 8 wt%, the presented catalysts
showed an improved catalytic activity regarding light-off and full conversion
temperatures compared to this reference. Through the application of several analytical
methods (PXRD, PDF, DRUVS, SEM, XAFS), the improved catalytic activity can be
correlated with an increased amount of isolated iron centers and a significantly
reduced fraction of agglomerates or particles.
article_number: '416'
article_type: original
author:
- first_name: Steffen
full_name: Schlicher, Steffen
last_name: Schlicher
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Nils
full_name: Prinz, Nils
last_name: Prinz
- first_name: Mirijam
full_name: Zobel, Mirijam
last_name: Zobel
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Schlicher S, Schoch R, Prinz N, Zobel M, Bauer M. New and Facile Preparation
Method for Highly Active Iron Oxide Catalysts for CO Oxidation. Catalysts.
2024;14(7). doi:10.3390/catal14070416
apa: Schlicher, S., Schoch, R., Prinz, N., Zobel, M., & Bauer, M. (2024). New
and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation.
Catalysts, 14(7), Article 416. https://doi.org/10.3390/catal14070416
bibtex: '@article{Schlicher_Schoch_Prinz_Zobel_Bauer_2024, title={New and Facile
Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation}, volume={14},
DOI={10.3390/catal14070416},
number={7416}, journal={Catalysts}, publisher={MDPI AG}, author={Schlicher, Steffen
and Schoch, Roland and Prinz, Nils and Zobel, Mirijam and Bauer, Matthias}, year={2024}
}'
chicago: Schlicher, Steffen, Roland Schoch, Nils Prinz, Mirijam Zobel, and Matthias
Bauer. “New and Facile Preparation Method for Highly Active Iron Oxide Catalysts
for CO Oxidation.” Catalysts 14, no. 7 (2024). https://doi.org/10.3390/catal14070416.
ieee: 'S. Schlicher, R. Schoch, N. Prinz, M. Zobel, and M. Bauer, “New and Facile
Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation,” Catalysts,
vol. 14, no. 7, Art. no. 416, 2024, doi: 10.3390/catal14070416.'
mla: Schlicher, Steffen, et al. “New and Facile Preparation Method for Highly Active
Iron Oxide Catalysts for CO Oxidation.” Catalysts, vol. 14, no. 7, 416,
MDPI AG, 2024, doi:10.3390/catal14070416.
short: S. Schlicher, R. Schoch, N. Prinz, M. Zobel, M. Bauer, Catalysts 14 (2024).
date_created: 2024-07-02T07:10:14Z
date_updated: 2025-08-15T12:50:52Z
department:
- _id: '306'
doi: 10.3390/catal14070416
intvolume: ' 14'
issue: '7'
keyword:
- Catalysis
language:
- iso: eng
publication: Catalysts
publication_identifier:
issn:
- 2073-4344
publication_status: published
publisher: MDPI AG
status: public
title: New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for
CO Oxidation
type: journal_article
user_id: '48467'
volume: 14
year: '2024'
...
---
_id: '35657'
abstract:
- lang: eng
text: The controlled delivery of active pharmaceutical ingredients to the site of
disease represents a major challenge in drug therapy. Particularly when drugs
have to be transported across biological barriers, suitable drug delivery systems
are of importance. In recent years responsive delivery systems have been developed
which enable a controlled drug release depending on internal or external stimuli
such as changes in pH, redox environment or light and temperature. In some studies
delivery systems with reactivity against two different stimuli were established
either to enhance the response by synergies of the stimuli or to broaden the window
of possible trigger events. In the present review numerous exciting developments
of pH-, light- and redox-cleavable polymers suitable for the preparation of smart
delivery systems are described. The review discusses the different stimuli that
can be used for a controlled drug release of polymer-based delivery systems. It
puts a focus on the different polymers described for the preparation of stimuli-sensitive
systems, their preparation techniques as well as their stimuli-responsive degradation.
© 2022 The Authors. Polymer International published by John Wiley & Sons Ltd on
behalf of Society of Industrial Chemistry.
article_type: original
author:
- first_name: Tarik
full_name: Rust, Tarik
last_name: Rust
- first_name: Dimitri
full_name: Jung, Dimitri
last_name: Jung
- first_name: Klaus
full_name: Langer, Klaus
last_name: Langer
- first_name: Dirk
full_name: Kuckling, Dirk
id: '287'
last_name: Kuckling
citation:
ama: Rust T, Jung D, Langer K, Kuckling D. Stimuli‐accelerated polymeric drug delivery
systems. Polymer International. 2023;72(1):5-19. doi:10.1002/pi.6474
apa: Rust, T., Jung, D., Langer, K., & Kuckling, D. (2023). Stimuli‐accelerated
polymeric drug delivery systems. Polymer International, 72(1), 5–19.
https://doi.org/10.1002/pi.6474
bibtex: '@article{Rust_Jung_Langer_Kuckling_2023, title={Stimuli‐accelerated polymeric
drug delivery systems}, volume={72}, DOI={10.1002/pi.6474},
number={1}, journal={Polymer International}, publisher={Wiley}, author={Rust,
Tarik and Jung, Dimitri and Langer, Klaus and Kuckling, Dirk}, year={2023}, pages={5–19}
}'
chicago: 'Rust, Tarik, Dimitri Jung, Klaus Langer, and Dirk Kuckling. “Stimuli‐accelerated
Polymeric Drug Delivery Systems.” Polymer International 72, no. 1 (2023):
5–19. https://doi.org/10.1002/pi.6474.'
ieee: 'T. Rust, D. Jung, K. Langer, and D. Kuckling, “Stimuli‐accelerated polymeric
drug delivery systems,” Polymer International, vol. 72, no. 1, pp. 5–19,
2023, doi: 10.1002/pi.6474.'
mla: Rust, Tarik, et al. “Stimuli‐accelerated Polymeric Drug Delivery Systems.”
Polymer International, vol. 72, no. 1, Wiley, 2023, pp. 5–19, doi:10.1002/pi.6474.
short: T. Rust, D. Jung, K. Langer, D. Kuckling, Polymer International 72 (2023)
5–19.
date_created: 2023-01-10T08:25:22Z
date_updated: 2023-01-10T08:31:31Z
department:
- _id: '163'
doi: 10.1002/pi.6474
intvolume: ' 72'
issue: '1'
keyword:
- drug delivery system
- stimuli
- polymer
- cleavable
language:
- iso: eng
main_file_link:
- url: https://onlinelibrary.wiley.com/doi/10.1002/pi.6474
page: 5-19
publication: Polymer International
publication_identifier:
issn:
- 0959-8103
- 1097-0126
publication_status: published
publisher: Wiley
status: public
title: Stimuli‐accelerated polymeric drug delivery systems
type: journal_article
user_id: '94'
volume: 72
year: '2023'
...
---
_id: '45826'
author:
- first_name: Valerie A.
full_name: Niemann, Valerie A.
last_name: Niemann
- first_name: Marten
full_name: Huck, Marten
last_name: Huck
- first_name: Hans-Georg
full_name: Steinrück, Hans-Georg
id: '84268'
last_name: Steinrück
orcid: 0000-0001-6373-0877
- first_name: Michael F.
full_name: Toney, Michael F.
last_name: Toney
- first_name: William A.
full_name: Tarpeh, William A.
last_name: Tarpeh
- first_name: Sharon E.
full_name: Bone, Sharon E.
last_name: Bone
citation:
ama: Niemann VA, Huck M, Steinrück H-G, Toney MF, Tarpeh WA, Bone SE. X-ray Absorption
Spectroscopy Reveals Mechanisms of Calcium and Silicon Fouling on Reverse Osmosis
Membranes Used in Wastewater Reclamation. ACS ES&T Water. 2023;3:2627-2637.
doi:10.1021/acsestwater.3c00144
apa: Niemann, V. A., Huck, M., Steinrück, H.-G., Toney, M. F., Tarpeh, W. A., &
Bone, S. E. (2023). X-ray Absorption Spectroscopy Reveals Mechanisms of Calcium
and Silicon Fouling on Reverse Osmosis Membranes Used in Wastewater Reclamation.
ACS ES&T Water, 3, 2627–2637. https://doi.org/10.1021/acsestwater.3c00144
bibtex: '@article{Niemann_Huck_Steinrück_Toney_Tarpeh_Bone_2023, title={X-ray Absorption
Spectroscopy Reveals Mechanisms of Calcium and Silicon Fouling on Reverse Osmosis
Membranes Used in Wastewater Reclamation}, volume={3}, DOI={10.1021/acsestwater.3c00144},
journal={ACS ES&T Water}, publisher={American Chemical Society (ACS)}, author={Niemann,
Valerie A. and Huck, Marten and Steinrück, Hans-Georg and Toney, Michael F. and
Tarpeh, William A. and Bone, Sharon E.}, year={2023}, pages={2627–2637} }'
chicago: 'Niemann, Valerie A., Marten Huck, Hans-Georg Steinrück, Michael F. Toney,
William A. Tarpeh, and Sharon E. Bone. “X-Ray Absorption Spectroscopy Reveals
Mechanisms of Calcium and Silicon Fouling on Reverse Osmosis Membranes Used in
Wastewater Reclamation.” ACS ES&T Water 3 (2023): 2627–37. https://doi.org/10.1021/acsestwater.3c00144.'
ieee: 'V. A. Niemann, M. Huck, H.-G. Steinrück, M. F. Toney, W. A. Tarpeh, and S.
E. Bone, “X-ray Absorption Spectroscopy Reveals Mechanisms of Calcium and Silicon
Fouling on Reverse Osmosis Membranes Used in Wastewater Reclamation,” ACS ES&T
Water, vol. 3, pp. 2627–2637, 2023, doi: 10.1021/acsestwater.3c00144.'
mla: Niemann, Valerie A., et al. “X-Ray Absorption Spectroscopy Reveals Mechanisms
of Calcium and Silicon Fouling on Reverse Osmosis Membranes Used in Wastewater
Reclamation.” ACS ES&T Water, vol. 3, American Chemical Society (ACS),
2023, pp. 2627–37, doi:10.1021/acsestwater.3c00144.
short: V.A. Niemann, M. Huck, H.-G. Steinrück, M.F. Toney, W.A. Tarpeh, S.E. Bone,
ACS ES&T Water 3 (2023) 2627–2637.
date_created: 2023-07-01T15:47:46Z
date_updated: 2023-10-03T09:11:14Z
department:
- _id: '633'
doi: 10.1021/acsestwater.3c00144
intvolume: ' 3'
keyword:
- Water Science and Technology
- Environmental Chemistry
- Chemistry (miscellaneous)
- Chemical Engineering (miscellaneous)
language:
- iso: eng
page: 2627-2637
publication: ACS ES&T Water
publication_identifier:
issn:
- 2690-0637
- 2690-0637
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: X-ray Absorption Spectroscopy Reveals Mechanisms of Calcium and Silicon Fouling
on Reverse Osmosis Membranes Used in Wastewater Reclamation
type: journal_article
user_id: '84268'
volume: 3
year: '2023'
...
---
_id: '47589'
author:
- first_name: Felix
full_name: Krämer, Felix
last_name: Krämer
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
- first_name: Israel
full_name: Fernández, Israel
last_name: Fernández
- first_name: Frank
full_name: Breher, Frank
last_name: Breher
citation:
ama: Krämer F, Paradies J, Fernández I, Breher F. A crystalline aluminium–carbon-based
ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous
media. Nature Chemistry. Published online 2023. doi:10.1038/s41557-023-01340-9
apa: Krämer, F., Paradies, J., Fernández, I., & Breher, F. (2023). A crystalline
aluminium–carbon-based ambiphile capable of activation and catalytic transfer
of ammonia in non-aqueous media. Nature Chemistry. https://doi.org/10.1038/s41557-023-01340-9
bibtex: '@article{Krämer_Paradies_Fernández_Breher_2023, title={A crystalline aluminium–carbon-based
ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous
media}, DOI={10.1038/s41557-023-01340-9},
journal={Nature Chemistry}, publisher={Springer Science and Business Media LLC},
author={Krämer, Felix and Paradies, Jan and Fernández, Israel and Breher, Frank},
year={2023} }'
chicago: Krämer, Felix, Jan Paradies, Israel Fernández, and Frank Breher. “A Crystalline
Aluminium–Carbon-Based Ambiphile Capable of Activation and Catalytic Transfer
of Ammonia in Non-Aqueous Media.” Nature Chemistry, 2023. https://doi.org/10.1038/s41557-023-01340-9.
ieee: 'F. Krämer, J. Paradies, I. Fernández, and F. Breher, “A crystalline aluminium–carbon-based
ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous
media,” Nature Chemistry, 2023, doi: 10.1038/s41557-023-01340-9.'
mla: Krämer, Felix, et al. “A Crystalline Aluminium–Carbon-Based Ambiphile Capable
of Activation and Catalytic Transfer of Ammonia in Non-Aqueous Media.” Nature
Chemistry, Springer Science and Business Media LLC, 2023, doi:10.1038/s41557-023-01340-9.
short: F. Krämer, J. Paradies, I. Fernández, F. Breher, Nature Chemistry (2023).
date_created: 2023-10-04T14:40:07Z
date_updated: 2023-10-04T14:41:12Z
department:
- _id: '2'
- _id: '389'
doi: 10.1038/s41557-023-01340-9
keyword:
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
publication: Nature Chemistry
publication_identifier:
issn:
- 1755-4330
- 1755-4349
publication_status: published
publisher: Springer Science and Business Media LLC
status: public
title: A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic
transfer of ammonia in non-aqueous media
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '48013'
author:
- first_name: Ping
full_name: Liu, Ping
last_name: Liu
- first_name: Nils
full_name: Schumann, Nils
last_name: Schumann
- first_name: Fabian
full_name: Abele, Fabian
last_name: Abele
- first_name: Fazheng
full_name: Ren, Fazheng
last_name: Ren
- first_name: Marcel
full_name: Hanke, Marcel
last_name: Hanke
- first_name: Yang
full_name: Xin, Yang
last_name: Xin
- first_name: Andreas
full_name: Hartmann, Andreas
last_name: Hartmann
- first_name: Michael
full_name: Schlierf, Michael
last_name: Schlierf
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
- first_name: Weilin
full_name: Lin, Weilin
last_name: Lin
- first_name: Yixin
full_name: Zhang, Yixin
last_name: Zhang
citation:
ama: Liu P, Schumann N, Abele F, et al. Thermophoretic Analysis of Biomolecules
across the Nanoscales in Self-Assembled Polymeric Matrices. ACS Applied Nano
Materials. Published online 2023. doi:10.1021/acsanm.3c03623
apa: Liu, P., Schumann, N., Abele, F., Ren, F., Hanke, M., Xin, Y., Hartmann, A.,
Schlierf, M., Keller, A., Lin, W., & Zhang, Y. (2023). Thermophoretic Analysis
of Biomolecules across the Nanoscales in Self-Assembled Polymeric Matrices. ACS
Applied Nano Materials. https://doi.org/10.1021/acsanm.3c03623
bibtex: '@article{Liu_Schumann_Abele_Ren_Hanke_Xin_Hartmann_Schlierf_Keller_Lin_et
al._2023, title={Thermophoretic Analysis of Biomolecules across the Nanoscales
in Self-Assembled Polymeric Matrices}, DOI={10.1021/acsanm.3c03623},
journal={ACS Applied Nano Materials}, publisher={American Chemical Society (ACS)},
author={Liu, Ping and Schumann, Nils and Abele, Fabian and Ren, Fazheng and Hanke,
Marcel and Xin, Yang and Hartmann, Andreas and Schlierf, Michael and Keller, Adrian
and Lin, Weilin and et al.}, year={2023} }'
chicago: Liu, Ping, Nils Schumann, Fabian Abele, Fazheng Ren, Marcel Hanke, Yang
Xin, Andreas Hartmann, et al. “Thermophoretic Analysis of Biomolecules across
the Nanoscales in Self-Assembled Polymeric Matrices.” ACS Applied Nano Materials,
2023. https://doi.org/10.1021/acsanm.3c03623.
ieee: 'P. Liu et al., “Thermophoretic Analysis of Biomolecules across the
Nanoscales in Self-Assembled Polymeric Matrices,” ACS Applied Nano Materials,
2023, doi: 10.1021/acsanm.3c03623.'
mla: Liu, Ping, et al. “Thermophoretic Analysis of Biomolecules across the Nanoscales
in Self-Assembled Polymeric Matrices.” ACS Applied Nano Materials, American
Chemical Society (ACS), 2023, doi:10.1021/acsanm.3c03623.
short: P. Liu, N. Schumann, F. Abele, F. Ren, M. Hanke, Y. Xin, A. Hartmann, M.
Schlierf, A. Keller, W. Lin, Y. Zhang, ACS Applied Nano Materials (2023).
date_created: 2023-10-11T17:03:32Z
date_updated: 2023-10-11T17:04:21Z
department:
- _id: '302'
doi: 10.1021/acsanm.3c03623
keyword:
- General Materials Science
language:
- iso: eng
publication: ACS Applied Nano Materials
publication_identifier:
issn:
- 2574-0970
- 2574-0970
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Thermophoretic Analysis of Biomolecules across the Nanoscales in Self-Assembled
Polymeric Matrices
type: journal_article
user_id: '48864'
year: '2023'
...
---
_id: '48588'
abstract:
- lang: eng
text: Bacterial colonization and biofilm formation on abiotic surfaces are
initiated by the adhesion of peptides and proteins. Understanding the adhesion
of such peptides and proteins at a molecular level thus represents an important
step toward controlling and suppressing biofilm formation on technological and
medical materials. This study investigates the molecular adhesion of a pilus‐derived
peptide that facilitates biofilm formation of Pseudomonas aeruginosa, a multidrug‐resistant
opportunistic pathogen frequently encountered in healthcare settings. Single‐molecule
force spectroscopy (SMFS) was performed on chemically etched ZnO surfaces to gather
insights about peptide adsorption force and its kinetics. Metal‐free click chemistry
for the fabrication of peptide‐terminated SMFS cantilevers was performed on amine‐terminated
gold cantilevers and verified by X‐ray photoelectron spectroscopy (XPS) and polarization‐modulated
infrared reflection absorption spectroscopy (PM‐IRRAS). Atomic force microscopy
(AFM) and XPS analyses reveal stable topographies and surface chemistries of the
substrates that are not affected by SMFS. Rupture events described by the worm‐like
chain model (WLC) up to 600 pN were detected for the non‐polar ZnO(11‐20) surfaces.
The dissociation barrier energy at zero force ΔG(0), the transition state distance
xb and bound‐unbound dissociation rate at zero force koff(0) for the single crystalline
substrate indicate that coordination and hydrogen bonds dominate the peptide/surface
interaction.
author:
- first_name: Tim
full_name: Prüßner, Tim
last_name: Prüßner
- first_name: Dennis
full_name: Meinderink, Dennis
id: '32378'
last_name: Meinderink
orcid: 0000-0002-2755-6514
- first_name: Siqi
full_name: Zhu, Siqi
last_name: Zhu
- first_name: Alejandro G.
full_name: Orive, Alejandro G.
last_name: Orive
- first_name: Charlotte
full_name: Kielar, Charlotte
last_name: Kielar
- first_name: Marten
full_name: Huck, Marten
last_name: Huck
- first_name: Hans-Georg
full_name: Steinrück, Hans-Georg
id: '84268'
last_name: Steinrück
orcid: 0000-0001-6373-0877
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
citation:
ama: Prüßner T, Meinderink D, Zhu S, et al. Molecular Adhesion of a Pilus‐derived
Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO
Surfaces. Chemistry – A European Journal. Published online 2023. doi:10.1002/chem.202302464
apa: Prüßner, T., Meinderink, D., Zhu, S., Orive, A. G., Kielar, C., Huck, M., Steinrück,
H.-G., Keller, A., & Grundmeier, G. (2023). Molecular Adhesion of a Pilus‐derived
Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO
Surfaces. Chemistry – A European Journal. https://doi.org/10.1002/chem.202302464
bibtex: '@article{Prüßner_Meinderink_Zhu_Orive_Kielar_Huck_Steinrück_Keller_Grundmeier_2023,
title={Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa
Biofilm Formation on non‐polar ZnO Surfaces}, DOI={10.1002/chem.202302464},
journal={Chemistry – A European Journal}, publisher={Wiley}, author={Prüßner,
Tim and Meinderink, Dennis and Zhu, Siqi and Orive, Alejandro G. and Kielar, Charlotte
and Huck, Marten and Steinrück, Hans-Georg and Keller, Adrian and Grundmeier,
Guido}, year={2023} }'
chicago: Prüßner, Tim, Dennis Meinderink, Siqi Zhu, Alejandro G. Orive, Charlotte
Kielar, Marten Huck, Hans-Georg Steinrück, Adrian Keller, and Guido Grundmeier.
“Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas Aeruginosa
Biofilm Formation on Non‐polar ZnO Surfaces.” Chemistry – A European Journal,
2023. https://doi.org/10.1002/chem.202302464.
ieee: 'T. Prüßner et al., “Molecular Adhesion of a Pilus‐derived Peptide
Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces,”
Chemistry – A European Journal, 2023, doi: 10.1002/chem.202302464.'
mla: Prüßner, Tim, et al. “Molecular Adhesion of a Pilus‐derived Peptide Involved
in Pseudomonas Aeruginosa Biofilm Formation on Non‐polar ZnO Surfaces.” Chemistry
– A European Journal, Wiley, 2023, doi:10.1002/chem.202302464.
short: T. Prüßner, D. Meinderink, S. Zhu, A.G. Orive, C. Kielar, M. Huck, H.-G.
Steinrück, A. Keller, G. Grundmeier, Chemistry – A European Journal (2023).
date_created: 2023-11-02T09:23:41Z
date_updated: 2023-11-02T09:26:00Z
department:
- _id: '302'
- _id: '633'
doi: 10.1002/chem.202302464
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa
Biofilm Formation on non‐polar ZnO Surfaces
type: journal_article
user_id: '48864'
year: '2023'
...
---
_id: '48602'
abstract:
- lang: eng
text: This article presents the results of the implementation of the Erasmus Plus
project (KA203 financed by the European Union, contract number 2019-1-NL01-KA203-060339)
Research in Teacher Education (RiTE). The aim of the project was to promote and
facilitate pre-service teachers to create and undertake evidence-based practices
in teaching science, technology, engineering, and mathematics (STEM). In the RiTE
project, pre-service teachers were encouraged to use evidence from educational
and scientific research and to experiment and introduce didactic innovations in
teaching and learning processes. Although it has its justification in the tradition
of thinking about science, evidence-based practice is not yet consciously applied
in school practice. In the article, we present both the theoretical framework
for such practices, and the results of qualitative research – an analysis of interviews
conducted with students, future teachers, and novice teachers involved in the
project. The presented results show changes in the context of an understanding
of evidence and what evidence-based practices are in the teaching process and
the vision of such teaching presented by the respondents.
author:
- first_name: Eliza
full_name: Rybska, Eliza
last_name: Rybska
- first_name: Renata
full_name: Dudziak, Renata
last_name: Dudziak
- first_name: Pascal
full_name: Pollmeier, Pascal
id: '44191'
last_name: Pollmeier
citation:
ama: Rybska E, Dudziak R, Pollmeier P. Evidence-based practices in teaching. Problemy
Wczesnej Edukacji. 2023;56(1):89-108. doi:10.26881/pwe.2023.56.06
apa: Rybska, E., Dudziak, R., & Pollmeier, P. (2023). Evidence-based practices
in teaching. Problemy Wczesnej Edukacji, 56(1), 89–108. https://doi.org/10.26881/pwe.2023.56.06
bibtex: '@article{Rybska_Dudziak_Pollmeier_2023, title={Evidence-based practices
in teaching}, volume={56}, DOI={10.26881/pwe.2023.56.06},
number={1}, journal={Problemy Wczesnej Edukacji}, publisher={Uniwersytet Gdanski},
author={Rybska, Eliza and Dudziak, Renata and Pollmeier, Pascal}, year={2023},
pages={89–108} }'
chicago: 'Rybska, Eliza, Renata Dudziak, and Pascal Pollmeier. “Evidence-Based Practices
in Teaching.” Problemy Wczesnej Edukacji 56, no. 1 (2023): 89–108. https://doi.org/10.26881/pwe.2023.56.06.'
ieee: 'E. Rybska, R. Dudziak, and P. Pollmeier, “Evidence-based practices in teaching,”
Problemy Wczesnej Edukacji, vol. 56, no. 1, pp. 89–108, 2023, doi: 10.26881/pwe.2023.56.06.'
mla: Rybska, Eliza, et al. “Evidence-Based Practices in Teaching.” Problemy Wczesnej
Edukacji, vol. 56, no. 1, Uniwersytet Gdanski, 2023, pp. 89–108, doi:10.26881/pwe.2023.56.06.
short: E. Rybska, R. Dudziak, P. Pollmeier, Problemy Wczesnej Edukacji 56 (2023)
89–108.
date_created: 2023-11-03T10:50:49Z
date_updated: 2023-11-03T10:52:21Z
department:
- _id: '386'
doi: 10.26881/pwe.2023.56.06
intvolume: ' 56'
issue: '1'
language:
- iso: eng
page: 89-108
publication: Problemy Wczesnej Edukacji
publication_identifier:
issn:
- 2451-2230
- 1734-1582
publication_status: published
publisher: Uniwersytet Gdanski
status: public
title: Evidence-based practices in teaching
type: journal_article
user_id: '44191'
volume: 56
year: '2023'
...
---
_id: '49356'
author:
- first_name: Stephanie L.
full_name: Moffitt, Stephanie L.
last_name: Moffitt
- first_name: Chuntian
full_name: Cao, Chuntian
last_name: Cao
- first_name: Maikel F. A. M.
full_name: Van Hest, Maikel F. A. M.
last_name: Van Hest
- first_name: Laura T.
full_name: Schelhas, Laura T.
last_name: Schelhas
- first_name: Hans-Georg
full_name: Steinrück, Hans-Georg
id: '84268'
last_name: Steinrück
orcid: 0000-0001-6373-0877
- first_name: Michael F.
full_name: Toney, Michael F.
last_name: Toney
citation:
ama: Moffitt SL, Cao C, Van Hest MFAM, Schelhas LT, Steinrück H-G, Toney MF. Heterogeneous
Structural Evolution of In–Zn–O Thin Films during Annealing. The Journal of
Physical Chemistry C. 2023;127(47):23099–23108. doi:10.1021/acs.jpcc.3c06410
apa: Moffitt, S. L., Cao, C., Van Hest, M. F. A. M., Schelhas, L. T., Steinrück,
H.-G., & Toney, M. F. (2023). Heterogeneous Structural Evolution of In–Zn–O
Thin Films during Annealing. The Journal of Physical Chemistry C, 127(47),
23099–23108. https://doi.org/10.1021/acs.jpcc.3c06410
bibtex: '@article{Moffitt_Cao_Van Hest_Schelhas_Steinrück_Toney_2023, title={Heterogeneous
Structural Evolution of In–Zn–O Thin Films during Annealing}, volume={127}, DOI={10.1021/acs.jpcc.3c06410},
number={47}, journal={The Journal of Physical Chemistry C}, publisher={American
Chemical Society (ACS)}, author={Moffitt, Stephanie L. and Cao, Chuntian and Van
Hest, Maikel F. A. M. and Schelhas, Laura T. and Steinrück, Hans-Georg and Toney,
Michael F.}, year={2023}, pages={23099–23108} }'
chicago: 'Moffitt, Stephanie L., Chuntian Cao, Maikel F. A. M. Van Hest, Laura T.
Schelhas, Hans-Georg Steinrück, and Michael F. Toney. “Heterogeneous Structural
Evolution of In–Zn–O Thin Films during Annealing.” The Journal of Physical
Chemistry C 127, no. 47 (2023): 23099–23108. https://doi.org/10.1021/acs.jpcc.3c06410.'
ieee: 'S. L. Moffitt, C. Cao, M. F. A. M. Van Hest, L. T. Schelhas, H.-G. Steinrück,
and M. F. Toney, “Heterogeneous Structural Evolution of In–Zn–O Thin Films during
Annealing,” The Journal of Physical Chemistry C, vol. 127, no. 47, pp.
23099–23108, 2023, doi: 10.1021/acs.jpcc.3c06410.'
mla: Moffitt, Stephanie L., et al. “Heterogeneous Structural Evolution of In–Zn–O
Thin Films during Annealing.” The Journal of Physical Chemistry C, vol.
127, no. 47, American Chemical Society (ACS), 2023, pp. 23099–23108, doi:10.1021/acs.jpcc.3c06410.
short: S.L. Moffitt, C. Cao, M.F.A.M. Van Hest, L.T. Schelhas, H.-G. Steinrück,
M.F. Toney, The Journal of Physical Chemistry C 127 (2023) 23099–23108.
date_created: 2023-11-30T10:08:46Z
date_updated: 2023-11-30T10:09:26Z
department:
- _id: '633'
doi: 10.1021/acs.jpcc.3c06410
intvolume: ' 127'
issue: '47'
keyword:
- Surfaces
- Coatings and Films
- Physical and Theoretical Chemistry
- General Energy
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
page: 23099–23108
publication: The Journal of Physical Chemistry C
publication_identifier:
issn:
- 1932-7447
- 1932-7455
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing
type: journal_article
user_id: '84268'
volume: 127
year: '2023'
...
---
_id: '49609'
abstract:
- lang: eng
text: The alignment of liquid crystals on surfaces plays a central role
in optimizing their performances. In this work, a cutting-edge nano-lithography-based
method to control the local orientation of a thermotropic liquid crystal is applied
to easily available commercial standard materials and evaluated. Parallel nanogrooves
on a substrate, created through 3D nanoprinting in a negative-tone photoresin
optimized for two-photon polymerization are used for this purpose. Azimuthal anchoring
energies of the order from 10−6 J/m2
to 10−5 J/m2 are found, depending on
the spacing, width and depth of the grooves. In part, these values are larger
than those reported previously for another photopolymer. Both uniform alignment
and spatial patterns of different alignment directions can be realized. Electro-optic
studies confirm the suitability of the method for electrically addressable photonic
applications and indicate strong polar anchoring.
article_number: '3467'
author:
- first_name: Bingru
full_name: Zhang, Bingru
last_name: Zhang
- first_name: Malte
full_name: Plidschun, Malte
last_name: Plidschun
- first_name: Markus A.
full_name: Schmidt, Markus A.
last_name: Schmidt
- first_name: Heinz-Siegfried
full_name: Kitzerow, Heinz-Siegfried
id: '254'
last_name: Kitzerow
citation:
ama: Zhang B, Plidschun M, Schmidt MA, Kitzerow H-S. Anchoring and electro-optic
switching of liquid crystals on nano-structured surfaces fabricated by two-photon
based nano-printing. Optical Materials Express. 2023;13(12). doi:10.1364/ome.503100
apa: Zhang, B., Plidschun, M., Schmidt, M. A., & Kitzerow, H.-S. (2023). Anchoring
and electro-optic switching of liquid crystals on nano-structured surfaces fabricated
by two-photon based nano-printing. Optical Materials Express, 13(12),
Article 3467. https://doi.org/10.1364/ome.503100
bibtex: '@article{Zhang_Plidschun_Schmidt_Kitzerow_2023, title={Anchoring and electro-optic
switching of liquid crystals on nano-structured surfaces fabricated by two-photon
based nano-printing}, volume={13}, DOI={10.1364/ome.503100},
number={123467}, journal={Optical Materials Express}, publisher={Optica Publishing
Group}, author={Zhang, Bingru and Plidschun, Malte and Schmidt, Markus A. and
Kitzerow, Heinz-Siegfried}, year={2023} }'
chicago: Zhang, Bingru, Malte Plidschun, Markus A. Schmidt, and Heinz-Siegfried
Kitzerow. “Anchoring and Electro-Optic Switching of Liquid Crystals on Nano-Structured
Surfaces Fabricated by Two-Photon Based Nano-Printing.” Optical Materials Express
13, no. 12 (2023). https://doi.org/10.1364/ome.503100.
ieee: 'B. Zhang, M. Plidschun, M. A. Schmidt, and H.-S. Kitzerow, “Anchoring and
electro-optic switching of liquid crystals on nano-structured surfaces fabricated
by two-photon based nano-printing,” Optical Materials Express, vol. 13,
no. 12, Art. no. 3467, 2023, doi: 10.1364/ome.503100.'
mla: Zhang, Bingru, et al. “Anchoring and Electro-Optic Switching of Liquid Crystals
on Nano-Structured Surfaces Fabricated by Two-Photon Based Nano-Printing.” Optical
Materials Express, vol. 13, no. 12, 3467, Optica Publishing Group, 2023, doi:10.1364/ome.503100.
short: B. Zhang, M. Plidschun, M.A. Schmidt, H.-S. Kitzerow, Optical Materials Express
13 (2023).
date_created: 2023-12-13T15:59:37Z
date_updated: 2023-12-13T16:06:29Z
department:
- _id: '313'
- _id: '230'
- _id: '35'
doi: 10.1364/ome.503100
intvolume: ' 13'
issue: '12'
keyword:
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
publication: Optical Materials Express
publication_identifier:
issn:
- 2159-3930
publication_status: published
publisher: Optica Publishing Group
status: public
title: Anchoring and electro-optic switching of liquid crystals on nano-structured
surfaces fabricated by two-photon based nano-printing
type: journal_article
user_id: '254'
volume: 13
year: '2023'
...
---
_id: '43440'
author:
- first_name: Bingru
full_name: Zhang, Bingru
last_name: Zhang
- first_name: Linh
full_name: Nguyen, Linh
last_name: Nguyen
- first_name: Kevin
full_name: Martens, Kevin
last_name: Martens
- first_name: Amelie
full_name: Heuer-Jungemann, Amelie
last_name: Heuer-Jungemann
- first_name: Julian
full_name: Philipp, Julian
last_name: Philipp
- first_name: Susanne
full_name: Kempter, Susanne
last_name: Kempter
- first_name: Joachim O.
full_name: Rädler, Joachim O.
last_name: Rädler
- first_name: Tim
full_name: Liedl, Tim
last_name: Liedl
- first_name: Heinz-Siegfried
full_name: Kitzerow, Heinz-Siegfried
id: '254'
last_name: Kitzerow
citation:
ama: Zhang B, Nguyen L, Martens K, et al. Luminescent DNA-origami nano-rods dispersed
in a lyotropic chromonic liquid crystal. Liquid Crystals. 2023;50(7-10):1243-1251.
doi:10.1080/02678292.2023.2188494
apa: Zhang, B., Nguyen, L., Martens, K., Heuer-Jungemann, A., Philipp, J., Kempter,
S., Rädler, J. O., Liedl, T., & Kitzerow, H.-S. (2023). Luminescent DNA-origami
nano-rods dispersed in a lyotropic chromonic liquid crystal. Liquid Crystals,
50(7–10), 1243–1251. https://doi.org/10.1080/02678292.2023.2188494
bibtex: '@article{Zhang_Nguyen_Martens_Heuer-Jungemann_Philipp_Kempter_Rädler_Liedl_Kitzerow_2023,
title={Luminescent DNA-origami nano-rods dispersed in a lyotropic chromonic liquid
crystal}, volume={50}, DOI={10.1080/02678292.2023.2188494},
number={7–10}, journal={Liquid Crystals}, publisher={Informa UK Limited}, author={Zhang,
Bingru and Nguyen, Linh and Martens, Kevin and Heuer-Jungemann, Amelie and Philipp,
Julian and Kempter, Susanne and Rädler, Joachim O. and Liedl, Tim and Kitzerow,
Heinz-Siegfried}, year={2023}, pages={1243–1251} }'
chicago: 'Zhang, Bingru, Linh Nguyen, Kevin Martens, Amelie Heuer-Jungemann, Julian
Philipp, Susanne Kempter, Joachim O. Rädler, Tim Liedl, and Heinz-Siegfried Kitzerow.
“Luminescent DNA-Origami Nano-Rods Dispersed in a Lyotropic Chromonic Liquid Crystal.”
Liquid Crystals 50, no. 7–10 (2023): 1243–51. https://doi.org/10.1080/02678292.2023.2188494.'
ieee: 'B. Zhang et al., “Luminescent DNA-origami nano-rods dispersed in a
lyotropic chromonic liquid crystal,” Liquid Crystals, vol. 50, no. 7–10,
pp. 1243–1251, 2023, doi: 10.1080/02678292.2023.2188494.'
mla: Zhang, Bingru, et al. “Luminescent DNA-Origami Nano-Rods Dispersed in a Lyotropic
Chromonic Liquid Crystal.” Liquid Crystals, vol. 50, no. 7–10, Informa
UK Limited, 2023, pp. 1243–51, doi:10.1080/02678292.2023.2188494.
short: B. Zhang, L. Nguyen, K. Martens, A. Heuer-Jungemann, J. Philipp, S. Kempter,
J.O. Rädler, T. Liedl, H.-S. Kitzerow, Liquid Crystals 50 (2023) 1243–1251.
date_created: 2023-04-08T17:21:30Z
date_updated: 2023-12-13T15:54:31Z
department:
- _id: '313'
- _id: '230'
doi: 10.1080/02678292.2023.2188494
intvolume: ' 50'
issue: 7-10
keyword:
- Condensed Matter Physics
- General Materials Science
- General Chemistry
language:
- iso: eng
page: 1243-1251
publication: Liquid Crystals
publication_identifier:
issn:
- 0267-8292
- 1366-5855
publication_status: published
publisher: Informa UK Limited
status: public
title: Luminescent DNA-origami nano-rods dispersed in a lyotropic chromonic liquid
crystal
type: journal_article
user_id: '254'
volume: 50
year: '2023'
...