---
_id: '51121'
abstract:
- lang: eng
  text: <jats:p>DNA origami nanostructures are a powerful tool in biomedicine and
    can be used to combat drug‐resistant bacterial infections. However, the effect
    of unmodified DNA origami nanostructures on bacteria is yet to be elucidated.
    With the aim to obtain a better understanding of this phenomenon, the effect of
    three DNA origami shapes, i.e., DNA origami triangles, six‐helix bundles (6HBs),
    and 24‐helix bundles (24HBs), on the growth of Gram‐negative Escherichia coli
    and Gram‐positive Bacillus subtilis is investigated. These results reveal that
    while triangles and 24HBs can be used as a source of nutrients by E. coli and
    thereby promote population growth, their effect is much smaller than that of genomic
    single‐ and double‐stranded DNA. However, no effect on E. coli population growth
    is observed for the 6HBs. On the other hand, B. subtilis does not show any significant
    changes in population growth when cultured with the different DNA origami shapes
    or genomic DNA. The detailed effect of DNA origami nanostructures on bacterial
    growth thus depends on the competence signals and uptake mechanism of each bacterial
    species, as well as the DNA origami shape. This should be considered in the development
    of antimicrobial DNA origami nanostructures.</jats:p>
author:
- first_name: Jaime Andres
  full_name: Garcia-Diosa, Jaime Andres
  last_name: Garcia-Diosa
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
citation:
  ama: Garcia-Diosa JA, Grundmeier G, Keller A. Effect of DNA Origami Nanostructures
    on Bacterial Growth. <i>ChemBioChem</i>. Published online 2024. doi:<a href="https://doi.org/10.1002/cbic.202400091">10.1002/cbic.202400091</a>
  apa: Garcia-Diosa, J. A., Grundmeier, G., &#38; Keller, A. (2024). Effect of DNA
    Origami Nanostructures on Bacterial Growth. <i>ChemBioChem</i>. <a href="https://doi.org/10.1002/cbic.202400091">https://doi.org/10.1002/cbic.202400091</a>
  bibtex: '@article{Garcia-Diosa_Grundmeier_Keller_2024, title={Effect of DNA Origami
    Nanostructures on Bacterial Growth}, DOI={<a href="https://doi.org/10.1002/cbic.202400091">10.1002/cbic.202400091</a>},
    journal={ChemBioChem}, publisher={Wiley}, author={Garcia-Diosa, Jaime Andres and
    Grundmeier, Guido and Keller, Adrian}, year={2024} }'
  chicago: Garcia-Diosa, Jaime Andres, Guido Grundmeier, and Adrian Keller. “Effect
    of DNA Origami Nanostructures on Bacterial Growth.” <i>ChemBioChem</i>, 2024.
    <a href="https://doi.org/10.1002/cbic.202400091">https://doi.org/10.1002/cbic.202400091</a>.
  ieee: 'J. A. Garcia-Diosa, G. Grundmeier, and A. Keller, “Effect of DNA Origami
    Nanostructures on Bacterial Growth,” <i>ChemBioChem</i>, 2024, doi: <a href="https://doi.org/10.1002/cbic.202400091">10.1002/cbic.202400091</a>.'
  mla: Garcia-Diosa, Jaime Andres, et al. “Effect of DNA Origami Nanostructures on
    Bacterial Growth.” <i>ChemBioChem</i>, Wiley, 2024, doi:<a href="https://doi.org/10.1002/cbic.202400091">10.1002/cbic.202400091</a>.
  short: J.A. Garcia-Diosa, G. Grundmeier, A. Keller, ChemBioChem (2024).
date_created: 2024-02-03T12:41:16Z
date_updated: 2024-02-03T12:42:48Z
department:
- _id: '302'
doi: 10.1002/cbic.202400091
keyword:
- Organic Chemistry
- Molecular Biology
- Molecular Medicine
- Biochemistry
language:
- iso: eng
publication: ChemBioChem
publication_identifier:
  issn:
  - 1439-4227
  - 1439-7633
publication_status: published
publisher: Wiley
status: public
title: Effect of DNA Origami Nanostructures on Bacterial Growth
type: journal_article
user_id: '48864'
year: '2024'
...
---
_id: '52541'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>We conducted an investigation into
    the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene
    derivative and potassium thioacetate as a substitute for hydrogen sulfide. This
    investigation utilized kinetic and computational methods. We synthesized two palladium
    complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene
    (DPPF) and bis(diisopropylphosphino)ferrocene (D<jats:italic>i</jats:italic>PPF),
    as well as their tentative intermediates in the catalytic cycle. Reaction rates
    were measured and then compared to computational predictions.</jats:p>
author:
- first_name: Sebastian
  full_name: Peschtrich, Sebastian
  last_name: Peschtrich
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Dirk
  full_name: Kuckling, Dirk
  id: '287'
  last_name: Kuckling
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Peschtrich S, Schoch R, Kuckling D, Paradies J. A Comparative Kinetic and Computational
    Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and
    2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. <i>European Journal
    of Organic Chemistry</i>. 2024;27(8). doi:<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>
  apa: Peschtrich, S., Schoch, R., Kuckling, D., &#38; Paradies, J. (2024). A Comparative
    Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of
    Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.
    <i>European Journal of Organic Chemistry</i>, <i>27</i>(8). <a href="https://doi.org/10.1002/ejoc.202301207">https://doi.org/10.1002/ejoc.202301207</a>
  bibtex: '@article{Peschtrich_Schoch_Kuckling_Paradies_2024, title={A Comparative
    Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of
    Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes},
    volume={27}, DOI={<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>},
    number={8}, journal={European Journal of Organic Chemistry}, publisher={Wiley},
    author={Peschtrich, Sebastian and Schoch, Roland and Kuckling, Dirk and Paradies,
    Jan}, year={2024} }'
  chicago: Peschtrich, Sebastian, Roland Schoch, Dirk Kuckling, and Jan Paradies.
    “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross
    Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine
    Complexes.” <i>European Journal of Organic Chemistry</i> 27, no. 8 (2024). <a
    href="https://doi.org/10.1002/ejoc.202301207">https://doi.org/10.1002/ejoc.202301207</a>.
  ieee: 'S. Peschtrich, R. Schoch, D. Kuckling, and J. Paradies, “A Comparative Kinetic
    and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium
    Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes,” <i>European
    Journal of Organic Chemistry</i>, vol. 27, no. 8, 2024, doi: <a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>.'
  mla: Peschtrich, Sebastian, et al. “A Comparative Kinetic and Computational Investigation
    of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene
    Using Palladium/Bisphosphine Complexes.” <i>European Journal of Organic Chemistry</i>,
    vol. 27, no. 8, Wiley, 2024, doi:<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>.
  short: S. Peschtrich, R. Schoch, D. Kuckling, J. Paradies, European Journal of Organic
    Chemistry 27 (2024).
date_created: 2024-03-13T17:15:14Z
date_updated: 2024-03-13T17:17:37Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/ejoc.202301207
intvolume: '        27'
issue: '8'
keyword:
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
publication: European Journal of Organic Chemistry
publication_identifier:
  issn:
  - 1434-193X
  - 1099-0690
publication_status: published
publisher: Wiley
status: public
title: A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur
  Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine
  Complexes
type: journal_article
user_id: '53339'
volume: 27
year: '2024'
...
---
_id: '52572'
abstract:
- lang: eng
  text: <jats:p>A series of substituted ferrocenyl boron derivatives was synthesized.
    The oxidation of the ferrocenyl unit resulted in a significant increase of the
    boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized
    by NMR‐spectroscopy, crystal structure analysis and by computational methods.
    The new Lewis acids were then applied in the Meinwald rearrangement of epoxides,
    predominantly furnishing aldehydes as the kinetic products.</jats:p>
author:
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Bernhard
  full_name: Birenheide, Bernhard
  last_name: Birenheide
- first_name: Felix
  full_name: Krämer, Felix
  last_name: Krämer
- first_name: Jonas O.
  full_name: Wenzel, Jonas O.
  last_name: Wenzel
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Martin
  full_name: Brehm, Martin
  id: '100167'
  last_name: Brehm
- first_name: Frank
  full_name: Breher, Frank
  last_name: Breher
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Köring L, Birenheide B, Krämer F, et al. Synthesis of Ferrocenyl Boranes and
    their Application as Lewis Acids in Epoxide Rearrangements. <i>European Journal
    of Inorganic Chemistry</i>. Published online 2024. doi:<a href="https://doi.org/10.1002/ejic.202400057">10.1002/ejic.202400057</a>
  apa: Köring, L., Birenheide, B., Krämer, F., Wenzel, J. O., Schoch, R., Brehm, M.,
    Breher, F., &#38; Paradies, J. (2024). Synthesis of Ferrocenyl Boranes and their
    Application as Lewis Acids in Epoxide Rearrangements. <i>European Journal of Inorganic
    Chemistry</i>. <a href="https://doi.org/10.1002/ejic.202400057">https://doi.org/10.1002/ejic.202400057</a>
  bibtex: '@article{Köring_Birenheide_Krämer_Wenzel_Schoch_Brehm_Breher_Paradies_2024,
    title={Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in
    Epoxide Rearrangements}, DOI={<a href="https://doi.org/10.1002/ejic.202400057">10.1002/ejic.202400057</a>},
    journal={European Journal of Inorganic Chemistry}, publisher={Wiley}, author={Köring,
    Laura and Birenheide, Bernhard and Krämer, Felix and Wenzel, Jonas O. and Schoch,
    Roland and Brehm, Martin and Breher, Frank and Paradies, Jan}, year={2024} }'
  chicago: Köring, Laura, Bernhard Birenheide, Felix Krämer, Jonas O. Wenzel, Roland
    Schoch, Martin Brehm, Frank Breher, and Jan Paradies. “Synthesis of Ferrocenyl
    Boranes and Their Application as Lewis Acids in Epoxide Rearrangements.” <i>European
    Journal of Inorganic Chemistry</i>, 2024. <a href="https://doi.org/10.1002/ejic.202400057">https://doi.org/10.1002/ejic.202400057</a>.
  ieee: 'L. Köring <i>et al.</i>, “Synthesis of Ferrocenyl Boranes and their Application
    as Lewis Acids in Epoxide Rearrangements,” <i>European Journal of Inorganic Chemistry</i>,
    2024, doi: <a href="https://doi.org/10.1002/ejic.202400057">10.1002/ejic.202400057</a>.'
  mla: Köring, Laura, et al. “Synthesis of Ferrocenyl Boranes and Their Application
    as Lewis Acids in Epoxide Rearrangements.” <i>European Journal of Inorganic Chemistry</i>,
    Wiley, 2024, doi:<a href="https://doi.org/10.1002/ejic.202400057">10.1002/ejic.202400057</a>.
  short: L. Köring, B. Birenheide, F. Krämer, J.O. Wenzel, R. Schoch, M. Brehm, F.
    Breher, J. Paradies, European Journal of Inorganic Chemistry (2024).
date_created: 2024-03-14T07:09:09Z
date_updated: 2024-03-14T07:10:37Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/ejic.202400057
keyword:
- Inorganic Chemistry
language:
- iso: eng
publication: European Journal of Inorganic Chemistry
publication_identifier:
  issn:
  - 1434-1948
  - 1099-0682
publication_status: published
publisher: Wiley
status: public
title: Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide
  Rearrangements
type: journal_article
user_id: '53339'
year: '2024'
...
---
_id: '52372'
abstract:
- lang: eng
  text: Due to the hydrolytic instability of LiPF6 in carbonate-based solvents, HF
    is a typical impurity in Li-ion battery electrolytes. HF significantly influences
    the performance of Li-ion batteries, for example by impacting the formation of
    the solid electrolyte interphase at the anode and by affecting transition metal
    dissolution at the cathode. Additionally, HF complicates studying fundamental
    interfacial electrochemistry of Li-ion battery electrolytes, such as direct anion
    reduction, because it is electrocatalytically relatively unstable, resulting in
    LiF passivation layers. Methods to selectively remove ppm levels of HF from LiPF6-containing
    carbonate-based electrolytes are limited. We introduce and benchmark a simple
    yet efficient electrochemical in situ method to selectively remove ppm amounts
    of HF from LiPF6-containing carbonate-based electrolytes. The basic idea is the
    application of a suitable potential to a high surface-area metallic electrode
    upon which only HF reacts (electrocatalytically) while all other electrolyte components
    are unaffected under the respective conditions.
article_type: original
author:
- first_name: Xiaokun
  full_name: Ge, Xiaokun
  last_name: Ge
- first_name: Marten
  full_name: Huck, Marten
  last_name: Huck
- first_name: Andreas
  full_name: Kuhlmann, Andreas
  last_name: Kuhlmann
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Xiaodan
  full_name: Xu, Xiaodan
  last_name: Xu
- first_name: Zhenyu
  full_name: Zhao, Zhenyu
  last_name: Zhao
- first_name: Hans-Georg
  full_name: Steinrueck, Hans-Georg
  last_name: Steinrueck
citation:
  ama: Ge X, Huck M, Kuhlmann A, et al. Electrochemical Removal of HF from Carbonate-based
    LiPF6-containing Li-ion Battery Electrolytes. <i>Journal of The Electrochemical
    Society</i>. 2024;171:030552. doi:<a href="https://doi.org/10.1149/1945-7111/ad30d3">10.1149/1945-7111/ad30d3</a>
  apa: Ge, X., Huck, M., Kuhlmann, A., Tiemann, M., Weinberger, C., Xu, X., Zhao,
    Z., &#38; Steinrueck, H.-G. (2024). Electrochemical Removal of HF from Carbonate-based
    LiPF6-containing Li-ion Battery Electrolytes. <i>Journal of The Electrochemical
    Society</i>, <i>171</i>, 030552. <a href="https://doi.org/10.1149/1945-7111/ad30d3">https://doi.org/10.1149/1945-7111/ad30d3</a>
  bibtex: '@article{Ge_Huck_Kuhlmann_Tiemann_Weinberger_Xu_Zhao_Steinrueck_2024, title={Electrochemical
    Removal of HF from Carbonate-based LiPF6-containing Li-ion Battery Electrolytes},
    volume={171}, DOI={<a href="https://doi.org/10.1149/1945-7111/ad30d3">10.1149/1945-7111/ad30d3</a>},
    journal={Journal of The Electrochemical Society}, publisher={The Electrochemical
    Society}, author={Ge, Xiaokun and Huck, Marten and Kuhlmann, Andreas and Tiemann,
    Michael and Weinberger, Christian and Xu, Xiaodan and Zhao, Zhenyu and Steinrueck,
    Hans-Georg}, year={2024}, pages={030552} }'
  chicago: 'Ge, Xiaokun, Marten Huck, Andreas Kuhlmann, Michael Tiemann, Christian
    Weinberger, Xiaodan Xu, Zhenyu Zhao, and Hans-Georg Steinrueck. “Electrochemical
    Removal of HF from Carbonate-Based LiPF6-Containing Li-Ion Battery Electrolytes.”
    <i>Journal of The Electrochemical Society</i> 171 (2024): 030552. <a href="https://doi.org/10.1149/1945-7111/ad30d3">https://doi.org/10.1149/1945-7111/ad30d3</a>.'
  ieee: 'X. Ge <i>et al.</i>, “Electrochemical Removal of HF from Carbonate-based
    LiPF6-containing Li-ion Battery Electrolytes,” <i>Journal of The Electrochemical
    Society</i>, vol. 171, p. 030552, 2024, doi: <a href="https://doi.org/10.1149/1945-7111/ad30d3">10.1149/1945-7111/ad30d3</a>.'
  mla: Ge, Xiaokun, et al. “Electrochemical Removal of HF from Carbonate-Based LiPF6-Containing
    Li-Ion Battery Electrolytes.” <i>Journal of The Electrochemical Society</i>, vol.
    171, The Electrochemical Society, 2024, p. 030552, doi:<a href="https://doi.org/10.1149/1945-7111/ad30d3">10.1149/1945-7111/ad30d3</a>.
  short: X. Ge, M. Huck, A. Kuhlmann, M. Tiemann, C. Weinberger, X. Xu, Z. Zhao, H.-G.
    Steinrueck, Journal of The Electrochemical Society 171 (2024) 030552.
date_created: 2024-03-08T06:27:10Z
date_updated: 2024-03-25T17:01:09Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1149/1945-7111/ad30d3
intvolume: '       171'
keyword:
- Materials Chemistry
- Electrochemistry
- Surfaces
- Coatings and Films
- Condensed Matter Physics
- Renewable Energy
- Sustainability and the Environment
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://dx.doi.org/10.1149/1945-7111/ad30d3
oa: '1'
page: '030552'
publication: Journal of The Electrochemical Society
publication_identifier:
  issn:
  - 0013-4651
  - 1945-7111
publication_status: published
publisher: The Electrochemical Society
quality_controlled: '1'
status: public
title: Electrochemical Removal of HF from Carbonate-based LiPF6-containing Li-ion
  Battery Electrolytes
type: journal_article
user_id: '23547'
volume: 171
year: '2024'
...
---
_id: '53163'
abstract:
- lang: eng
  text: <jats:p>An SPR-based dually crosslinked gel sensor for adiponitrile bearing
    pillar[5]arene responsive sites with a low limit of detection was developed.</jats:p>
article_type: original
author:
- first_name: Maksim
  full_name: Rodin, Maksim
  last_name: Rodin
- first_name: David
  full_name: Helle, David
  last_name: Helle
- first_name: Dirk
  full_name: Kuckling, Dirk
  id: '287'
  last_name: Kuckling
citation:
  ama: Rodin M, Helle D, Kuckling D. Pillar[5]arene-based dually crosslinked supramolecular
    gel as a sensor for the detection of adiponitrile. <i>Polymer Chemistry</i>. 2024;15(7):661-679.
    doi:<a href="https://doi.org/10.1039/d3py01354e">10.1039/d3py01354e</a>
  apa: Rodin, M., Helle, D., &#38; Kuckling, D. (2024). Pillar[5]arene-based dually
    crosslinked supramolecular gel as a sensor for the detection of adiponitrile.
    <i>Polymer Chemistry</i>, <i>15</i>(7), 661–679. <a href="https://doi.org/10.1039/d3py01354e">https://doi.org/10.1039/d3py01354e</a>
  bibtex: '@article{Rodin_Helle_Kuckling_2024, title={Pillar[5]arene-based dually
    crosslinked supramolecular gel as a sensor for the detection of adiponitrile},
    volume={15}, DOI={<a href="https://doi.org/10.1039/d3py01354e">10.1039/d3py01354e</a>},
    number={7}, journal={Polymer Chemistry}, publisher={Royal Society of Chemistry
    (RSC)}, author={Rodin, Maksim and Helle, David and Kuckling, Dirk}, year={2024},
    pages={661–679} }'
  chicago: 'Rodin, Maksim, David Helle, and Dirk Kuckling. “Pillar[5]Arene-Based Dually
    Crosslinked Supramolecular Gel as a Sensor for the Detection of Adiponitrile.”
    <i>Polymer Chemistry</i> 15, no. 7 (2024): 661–79. <a href="https://doi.org/10.1039/d3py01354e">https://doi.org/10.1039/d3py01354e</a>.'
  ieee: 'M. Rodin, D. Helle, and D. Kuckling, “Pillar[5]arene-based dually crosslinked
    supramolecular gel as a sensor for the detection of adiponitrile,” <i>Polymer
    Chemistry</i>, vol. 15, no. 7, pp. 661–679, 2024, doi: <a href="https://doi.org/10.1039/d3py01354e">10.1039/d3py01354e</a>.'
  mla: Rodin, Maksim, et al. “Pillar[5]Arene-Based Dually Crosslinked Supramolecular
    Gel as a Sensor for the Detection of Adiponitrile.” <i>Polymer Chemistry</i>,
    vol. 15, no. 7, Royal Society of Chemistry (RSC), 2024, pp. 661–79, doi:<a href="https://doi.org/10.1039/d3py01354e">10.1039/d3py01354e</a>.
  short: M. Rodin, D. Helle, D. Kuckling, Polymer Chemistry 15 (2024) 661–679.
date_created: 2024-04-03T10:57:17Z
date_updated: 2024-04-03T11:03:03Z
department:
- _id: '163'
doi: 10.1039/d3py01354e
intvolume: '        15'
issue: '7'
keyword:
- Organic Chemistry
- Polymers and Plastics
- Biochemistry
- Bioengineering
language:
- iso: eng
page: 661-679
publication: Polymer Chemistry
publication_identifier:
  issn:
  - 1759-9954
  - 1759-9962
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Pillar[5]arene-based dually crosslinked supramolecular gel as a sensor for
  the detection of adiponitrile
type: journal_article
user_id: '94'
volume: 15
year: '2024'
...
---
_id: '53474'
abstract:
- lang: eng
  text: We present a novel approach to characterize and quantify microheterogeneity
    and microphase separation in computer simulations of complex liquid mixtures.
    Our post-processing method is based on local density fluctuations of the different
    constituents in sampling spheres of varying size. It can be easily applied to
    both molecular dynamics (MD) and Monte Carlo (MC) simulations, including periodic
    boundary conditions. Multidimensional correlation of the density distributions
    yields a clear picture of the domain formation due to the subtle balance of different
    interactions. We apply our approach to the example of force field molecular dynamics
    simulations of imidazolium-based ionic liquids with different side chain lengths
    at different temperatures, namely 1-ethyl-3-methylimidazolium chloride, 1-hexyl-3-methylimidazolium
    chloride, and 1-decyl-3-methylimidazolium chloride, which are known to form distinct
    liquid domains. We put the results into the context of existing microheterogeneity
    analyses and demonstrate the advantages and sensitivity of our novel method. Furthermore,
    we show how to estimate the configuration entropy from our analysis, and we investigate
    voids in the system. The analysis has been implemented into our program package
    TRAVIS and is thus available as free software.
article_number: '322'
author:
- first_name: Michael
  full_name: Lass, Michael
  id: '24135'
  last_name: Lass
  orcid: 0000-0002-5708-7632
- first_name: Tobias
  full_name: Kenter, Tobias
  id: '3145'
  last_name: Kenter
- first_name: Christian
  full_name: Plessl, Christian
  id: '16153'
  last_name: Plessl
  orcid: 0000-0001-5728-9982
- first_name: Martin
  full_name: Brehm, Martin
  id: '100167'
  last_name: Brehm
citation:
  ama: Lass M, Kenter T, Plessl C, Brehm M. Characterizing Microheterogeneity in Liquid
    Mixtures via Local Density Fluctuations. <i>Entropy</i>. 2024;26(4). doi:<a href="https://doi.org/10.3390/e26040322">10.3390/e26040322</a>
  apa: Lass, M., Kenter, T., Plessl, C., &#38; Brehm, M. (2024). Characterizing Microheterogeneity
    in Liquid Mixtures via Local Density Fluctuations. <i>Entropy</i>, <i>26</i>(4),
    Article 322. <a href="https://doi.org/10.3390/e26040322">https://doi.org/10.3390/e26040322</a>
  bibtex: '@article{Lass_Kenter_Plessl_Brehm_2024, title={Characterizing Microheterogeneity
    in Liquid Mixtures via Local Density Fluctuations}, volume={26}, DOI={<a href="https://doi.org/10.3390/e26040322">10.3390/e26040322</a>},
    number={4322}, journal={Entropy}, publisher={MDPI AG}, author={Lass, Michael and
    Kenter, Tobias and Plessl, Christian and Brehm, Martin}, year={2024} }'
  chicago: Lass, Michael, Tobias Kenter, Christian Plessl, and Martin Brehm. “Characterizing
    Microheterogeneity in Liquid Mixtures via Local Density Fluctuations.” <i>Entropy</i>
    26, no. 4 (2024). <a href="https://doi.org/10.3390/e26040322">https://doi.org/10.3390/e26040322</a>.
  ieee: 'M. Lass, T. Kenter, C. Plessl, and M. Brehm, “Characterizing Microheterogeneity
    in Liquid Mixtures via Local Density Fluctuations,” <i>Entropy</i>, vol. 26, no.
    4, Art. no. 322, 2024, doi: <a href="https://doi.org/10.3390/e26040322">10.3390/e26040322</a>.'
  mla: Lass, Michael, et al. “Characterizing Microheterogeneity in Liquid Mixtures
    via Local Density Fluctuations.” <i>Entropy</i>, vol. 26, no. 4, 322, MDPI AG,
    2024, doi:<a href="https://doi.org/10.3390/e26040322">10.3390/e26040322</a>.
  short: M. Lass, T. Kenter, C. Plessl, M. Brehm, Entropy 26 (2024).
date_created: 2024-04-12T18:31:39Z
date_updated: 2024-04-12T18:34:32Z
department:
- _id: '27'
- _id: '518'
- _id: '803'
doi: 10.3390/e26040322
intvolume: '        26'
issue: '4'
language:
- iso: eng
project:
- _id: '52'
  name: 'PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing'
publication: Entropy
publication_identifier:
  issn:
  - 1099-4300
publication_status: published
publisher: MDPI AG
status: public
title: Characterizing Microheterogeneity in Liquid Mixtures via Local Density Fluctuations
type: journal_article
user_id: '24135'
volume: 26
year: '2024'
...
---
_id: '53621'
abstract:
- lang: eng
  text: <jats:p>The coupling of structural transitions to heat capacity changes leads
    to destabilization of macromolecules at both, elevated and lowered temperatures.
    DNA origami not only exhibit this property but also provide...</jats:p>
author:
- first_name: Daniel
  full_name: Dornbusch, Daniel
  last_name: Dornbusch
- first_name: Marcel
  full_name: Hanke, Marcel
  last_name: Hanke
- first_name: Emilia
  full_name: Tomm, Emilia
  id: '68157'
  last_name: Tomm
- first_name: Charlotte
  full_name: Kielar, Charlotte
  last_name: Kielar
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
- first_name: Karim
  full_name: Fahmy, Karim
  last_name: Fahmy
citation:
  ama: Dornbusch D, Hanke M, Tomm E, et al. Cold denaturation of DNA origami nanostructures.
    <i>Chemical Communications</i>. Published online 2024. doi:<a href="https://doi.org/10.1039/d3cc05985e">10.1039/d3cc05985e</a>
  apa: Dornbusch, D., Hanke, M., Tomm, E., Kielar, C., Grundmeier, G., Keller, A.,
    &#38; Fahmy, K. (2024). Cold denaturation of DNA origami nanostructures. <i>Chemical
    Communications</i>. <a href="https://doi.org/10.1039/d3cc05985e">https://doi.org/10.1039/d3cc05985e</a>
  bibtex: '@article{Dornbusch_Hanke_Tomm_Kielar_Grundmeier_Keller_Fahmy_2024, title={Cold
    denaturation of DNA origami nanostructures}, DOI={<a href="https://doi.org/10.1039/d3cc05985e">10.1039/d3cc05985e</a>},
    journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)},
    author={Dornbusch, Daniel and Hanke, Marcel and Tomm, Emilia and Kielar, Charlotte
    and Grundmeier, Guido and Keller, Adrian and Fahmy, Karim}, year={2024} }'
  chicago: Dornbusch, Daniel, Marcel Hanke, Emilia Tomm, Charlotte Kielar, Guido Grundmeier,
    Adrian Keller, and Karim Fahmy. “Cold Denaturation of DNA Origami Nanostructures.”
    <i>Chemical Communications</i>, 2024. <a href="https://doi.org/10.1039/d3cc05985e">https://doi.org/10.1039/d3cc05985e</a>.
  ieee: 'D. Dornbusch <i>et al.</i>, “Cold denaturation of DNA origami nanostructures,”
    <i>Chemical Communications</i>, 2024, doi: <a href="https://doi.org/10.1039/d3cc05985e">10.1039/d3cc05985e</a>.'
  mla: Dornbusch, Daniel, et al. “Cold Denaturation of DNA Origami Nanostructures.”
    <i>Chemical Communications</i>, Royal Society of Chemistry (RSC), 2024, doi:<a
    href="https://doi.org/10.1039/d3cc05985e">10.1039/d3cc05985e</a>.
  short: D. Dornbusch, M. Hanke, E. Tomm, C. Kielar, G. Grundmeier, A. Keller, K.
    Fahmy, Chemical Communications (2024).
date_created: 2024-04-23T08:20:05Z
date_updated: 2024-04-23T08:21:05Z
department:
- _id: '302'
doi: 10.1039/d3cc05985e
keyword:
- Materials Chemistry
- Metals and Alloys
- Surfaces
- Coatings and Films
- General Chemistry
- Ceramics and Composites
- Electronic
- Optical and Magnetic Materials
- Catalysis
language:
- iso: eng
publication: Chemical Communications
publication_identifier:
  issn:
  - 1359-7345
  - 1364-548X
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Cold denaturation of DNA origami nanostructures
type: journal_article
user_id: '48864'
year: '2024'
...
---
_id: '54419'
abstract:
- lang: eng
  text: Leaky mode resonances of the setae of Cataglyphis bombycina are found to enhance
    the thermal emission of the animals by near field coupling to the chitinous exoskeleton.
    This is remarkable, as the setae are also an adaption to enhance the reflectivity
    in the visible wavelength range. Both effects are dependent on morphology, dimensions
    and spatial arrangement. These parameters were experimentally characterized and
    simulated by finite difference time domain simulations to elucidate the optical
    impact of the setae in the mid infrared range and the contribution of leaky mode
    resonances. This mode of action and the setae’s optical properties in the visible
    range explain evolutionary strains that led to the actual morphology and size
    of the setae.
article_type: original
author:
- first_name: Bertram
  full_name: Schwind, Bertram
  last_name: Schwind
- first_name: Xia
  full_name: Wu, Xia
  last_name: Wu
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Helge-Otto
  full_name: Fabritius, Helge-Otto
  last_name: Fabritius
citation:
  ama: 'Schwind B, Wu X, Tiemann M, Fabritius H-O. Natural near field coupled leaky-mode
    resonant anti-reflection structures: the setae of Cataglyphis bombycina. <i>Frontiers
    in Physics</i>. 2024;12. doi:<a href="https://doi.org/10.3389/fphy.2024.1393279">10.3389/fphy.2024.1393279</a>'
  apa: 'Schwind, B., Wu, X., Tiemann, M., &#38; Fabritius, H.-O. (2024). Natural near
    field coupled leaky-mode resonant anti-reflection structures: the setae of Cataglyphis
    bombycina. <i>Frontiers in Physics</i>, <i>12</i>. <a href="https://doi.org/10.3389/fphy.2024.1393279">https://doi.org/10.3389/fphy.2024.1393279</a>'
  bibtex: '@article{Schwind_Wu_Tiemann_Fabritius_2024, title={Natural near field coupled
    leaky-mode resonant anti-reflection structures: the setae of Cataglyphis bombycina},
    volume={12}, DOI={<a href="https://doi.org/10.3389/fphy.2024.1393279">10.3389/fphy.2024.1393279</a>},
    journal={Frontiers in Physics}, author={Schwind, Bertram and Wu, Xia and Tiemann,
    Michael and Fabritius, Helge-Otto}, year={2024} }'
  chicago: 'Schwind, Bertram, Xia Wu, Michael Tiemann, and Helge-Otto Fabritius. “Natural
    near Field Coupled Leaky-Mode Resonant Anti-Reflection Structures: The Setae of
    Cataglyphis Bombycina.” <i>Frontiers in Physics</i> 12 (2024). <a href="https://doi.org/10.3389/fphy.2024.1393279">https://doi.org/10.3389/fphy.2024.1393279</a>.'
  ieee: 'B. Schwind, X. Wu, M. Tiemann, and H.-O. Fabritius, “Natural near field coupled
    leaky-mode resonant anti-reflection structures: the setae of Cataglyphis bombycina,”
    <i>Frontiers in Physics</i>, vol. 12, 2024, doi: <a href="https://doi.org/10.3389/fphy.2024.1393279">10.3389/fphy.2024.1393279</a>.'
  mla: 'Schwind, Bertram, et al. “Natural near Field Coupled Leaky-Mode Resonant Anti-Reflection
    Structures: The Setae of Cataglyphis Bombycina.” <i>Frontiers in Physics</i>,
    vol. 12, 2024, doi:<a href="https://doi.org/10.3389/fphy.2024.1393279">10.3389/fphy.2024.1393279</a>.'
  short: B. Schwind, X. Wu, M. Tiemann, H.-O. Fabritius, Frontiers in Physics 12 (2024).
date_created: 2024-05-22T14:19:25Z
date_updated: 2024-05-22T14:27:32Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
- _id: '230'
doi: 10.3389/fphy.2024.1393279
intvolume: '        12'
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
publication: Frontiers in Physics
publication_identifier:
  issn:
  - 2296-424X
quality_controlled: '1'
status: public
title: 'Natural near field coupled leaky-mode resonant anti-reflection structures:
  the setae of Cataglyphis bombycina'
type: journal_article
user_id: '23547'
volume: 12
year: '2024'
...
---
_id: '54644'
abstract:
- lang: eng
  text: <jats:p>DNA origami nanostructures (DONs) are able to scavenge reactive oxygen
    species (ROS) and their scavenging efficiency toward ROS radicals was shown to
    be comparable to that of genomic DNA. Herein, we demonstrate that DONs are highly
    efficient singlet oxygen quenchers outperforming double‐stranded (ds) DNA by several
    orders of magnitude. To this end, a ROS mixture rich in singlet oxygen is generated
    by light irradiation of the photosensitizer methylene blue and its cytotoxic effect
    on Escherichia coli cells is quantified in the presence and absence of DONs. DONs
    are found to be vastly superior to dsDNA in protecting the bacteria from ROS‐induced
    damage and even surpass established ROS scavengers. At a concentration of 15 nM,
    DONs are about 50 000 times more efficient ROS scavengers than dsDNA at an equivalent
    concentration. This is attributed to the dominant role of singlet oxygen, which
    has a long diffusion length and reacts specifically with guanine. The dense packing
    of the available guanines into the small volume of the DON increases the overall
    quenching probability compared to a linear dsDNA with the same number of base
    pairs. DONs thus have great potential to alleviate oxidative stress caused by
    singlet oxygen in diverse therapeutic settings.</jats:p>
author:
- first_name: Jaime Andres
  full_name: Garcia-Diosa, Jaime Andres
  last_name: Garcia-Diosa
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
citation:
  ama: Garcia-Diosa JA, Grundmeier G, Keller A. Highly Efficient Quenching of Singlet
    Oxygen by DNA Origami Nanostructures. <i>Chemistry – A European Journal</i>. Published
    online 2024. doi:<a href="https://doi.org/10.1002/chem.202402057">10.1002/chem.202402057</a>
  apa: Garcia-Diosa, J. A., Grundmeier, G., &#38; Keller, A. (2024). Highly Efficient
    Quenching of Singlet Oxygen by DNA Origami Nanostructures. <i>Chemistry – A European
    Journal</i>. <a href="https://doi.org/10.1002/chem.202402057">https://doi.org/10.1002/chem.202402057</a>
  bibtex: '@article{Garcia-Diosa_Grundmeier_Keller_2024, title={Highly Efficient Quenching
    of Singlet Oxygen by DNA Origami Nanostructures}, DOI={<a href="https://doi.org/10.1002/chem.202402057">10.1002/chem.202402057</a>},
    journal={Chemistry – A European Journal}, publisher={Wiley}, author={Garcia-Diosa,
    Jaime Andres and Grundmeier, Guido and Keller, Adrian}, year={2024} }'
  chicago: Garcia-Diosa, Jaime Andres, Guido Grundmeier, and Adrian Keller. “Highly
    Efficient Quenching of Singlet Oxygen by DNA Origami Nanostructures.” <i>Chemistry
    – A European Journal</i>, 2024. <a href="https://doi.org/10.1002/chem.202402057">https://doi.org/10.1002/chem.202402057</a>.
  ieee: 'J. A. Garcia-Diosa, G. Grundmeier, and A. Keller, “Highly Efficient Quenching
    of Singlet Oxygen by DNA Origami Nanostructures,” <i>Chemistry – A European Journal</i>,
    2024, doi: <a href="https://doi.org/10.1002/chem.202402057">10.1002/chem.202402057</a>.'
  mla: Garcia-Diosa, Jaime Andres, et al. “Highly Efficient Quenching of Singlet Oxygen
    by DNA Origami Nanostructures.” <i>Chemistry – A European Journal</i>, Wiley,
    2024, doi:<a href="https://doi.org/10.1002/chem.202402057">10.1002/chem.202402057</a>.
  short: J.A. Garcia-Diosa, G. Grundmeier, A. Keller, Chemistry – A European Journal
    (2024).
date_created: 2024-06-07T07:53:50Z
date_updated: 2024-06-07T07:54:02Z
department:
- _id: '302'
doi: 10.1002/chem.202402057
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
  issn:
  - 0947-6539
  - 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Highly Efficient Quenching of Singlet Oxygen by DNA Origami Nanostructures
type: journal_article
user_id: '48864'
year: '2024'
...
---
_id: '55042'
author:
- first_name: Jonas
  full_name: Ponath, Jonas
  id: '100087'
  last_name: Ponath
- first_name: Claudia
  full_name: Bohrmann-Linde, Claudia
  last_name: Bohrmann-Linde
- first_name: Isabel
  full_name: Rubner, Isabel
  last_name: Rubner
- first_name: Katrin
  full_name: Sommer, Katrin
  last_name: Sommer
- first_name: Sabine
  full_name: Fechner, Sabine
  id: '54823'
  last_name: Fechner
  orcid: 0000-0001-5645-5870
citation:
  ama: 'Ponath J, Bohrmann-Linde C, Rubner I, Sommer K, Fechner S. Digitalisierungsbezogene
    Kompetenzen (angehender) Chemielehrkräfte. In: van Vorst H, ed. <i>Frühe naturwissenschaftliche
    Bildung</i>. Vol 44. ; 2024:878-881.'
  apa: Ponath, J., Bohrmann-Linde, C., Rubner, I., Sommer, K., &#38; Fechner, S. (2024).
    Digitalisierungsbezogene Kompetenzen (angehender) Chemielehrkräfte. In H. van
    Vorst (Ed.), <i>Frühe naturwissenschaftliche Bildung</i> (Vol. 44, pp. 878–881).
  bibtex: '@inproceedings{Ponath_Bohrmann-Linde_Rubner_Sommer_Fechner_2024, place={Essen},
    title={Digitalisierungsbezogene Kompetenzen (angehender) Chemielehrkräfte}, volume={44},
    booktitle={Frühe naturwissenschaftliche Bildung}, author={Ponath, Jonas and Bohrmann-Linde,
    Claudia and Rubner, Isabel and Sommer, Katrin and Fechner, Sabine}, editor={van
    Vorst, Helena}, year={2024}, pages={878–881} }'
  chicago: Ponath, Jonas, Claudia Bohrmann-Linde, Isabel Rubner, Katrin Sommer, and
    Sabine Fechner. “Digitalisierungsbezogene Kompetenzen (angehender) Chemielehrkräfte.”
    In <i>Frühe naturwissenschaftliche Bildung</i>, edited by Helena van Vorst, 44:878–81.
    Essen, 2024.
  ieee: J. Ponath, C. Bohrmann-Linde, I. Rubner, K. Sommer, and S. Fechner, “Digitalisierungsbezogene
    Kompetenzen (angehender) Chemielehrkräfte,” in <i>Frühe naturwissenschaftliche
    Bildung</i>, Hamburg, 2024, vol. 44, pp. 878–881.
  mla: Ponath, Jonas, et al. “Digitalisierungsbezogene Kompetenzen (angehender) Chemielehrkräfte.”
    <i>Frühe naturwissenschaftliche Bildung</i>, edited by Helena van Vorst, vol.
    44, 2024, pp. 878–81.
  short: 'J. Ponath, C. Bohrmann-Linde, I. Rubner, K. Sommer, S. Fechner, in: H. van
    Vorst (Ed.), Frühe naturwissenschaftliche Bildung, Essen, 2024, pp. 878–881.'
conference:
  end_date: 2023-09-14
  location: Hamburg
  name: 50. Jahrestagung der Gesellschaft für Didaktik der Chemie und Physik e.V.
  start_date: 2023-09-11
date_created: 2024-07-05T08:40:02Z
date_updated: 2024-07-05T08:45:48Z
department:
- _id: '386'
editor:
- first_name: Helena
  full_name: van Vorst, Helena
  last_name: van Vorst
has_accepted_license: '1'
intvolume: '        44'
language:
- iso: ger
main_file_link:
- url: https://gdcp-ev.de/wp-content/uploads/securepdfs/2024/06/P098_Ponath.pdf
page: 878-881
place: Essen
publication: Frühe naturwissenschaftliche Bildung
publication_status: published
status: public
title: Digitalisierungsbezogene Kompetenzen (angehender) Chemielehrkräfte
type: conference
user_id: '100087'
volume: 44
year: '2024'
...
---
_id: '54678'
author:
- first_name: Marc
  full_name: Rodemer, Marc
  last_name: Rodemer
- first_name: Lukas
  full_name: Mientus, Lukas
  last_name: Mientus
- first_name: Julia
  full_name: Wiedmann, Julia
  last_name: Wiedmann
- first_name: Anna
  full_name: Nowak, Anna
  last_name: Nowak
- first_name: Pascal
  full_name: Pollmeier, Pascal
  id: '44191'
  last_name: Pollmeier
citation:
  ama: 'Rodemer M, Mientus L, Wiedmann J, Nowak A, Pollmeier P. Professionalisierungsmöglichkeiten
    angehender Lehrkräfte in Praxisphasen. In: van Vorst H, ed. <i>Frühe Naturwissenschaftliche
    Bildung </i>. Vol 44. Tagungsband zur GDCP Jahrestagung. ; 2024.'
  apa: Rodemer, M., Mientus, L., Wiedmann, J., Nowak, A., &#38; Pollmeier, P. (2024).
    Professionalisierungsmöglichkeiten angehender Lehrkräfte in Praxisphasen. In H.
    van Vorst (Ed.), <i>Frühe naturwissenschaftliche Bildung </i> (Vol. 44).
  bibtex: '@inproceedings{Rodemer_Mientus_Wiedmann_Nowak_Pollmeier_2024, place={Essen},
    series={Tagungsband zur GDCP Jahrestagung}, title={Professionalisierungsmöglichkeiten
    angehender Lehrkräfte in Praxisphasen}, volume={44}, booktitle={Frühe naturwissenschaftliche
    Bildung }, author={Rodemer, Marc and Mientus, Lukas and Wiedmann, Julia and Nowak,
    Anna and Pollmeier, Pascal}, editor={van Vorst, Helena}, year={2024}, collection={Tagungsband
    zur GDCP Jahrestagung} }'
  chicago: Rodemer, Marc, Lukas Mientus, Julia Wiedmann, Anna Nowak, and Pascal Pollmeier.
    “Professionalisierungsmöglichkeiten Angehender Lehrkräfte in Praxisphasen.” In
    <i>Frühe Naturwissenschaftliche Bildung </i>, edited by Helena van Vorst, Vol.
    44. Tagungsband Zur GDCP Jahrestagung. Essen, 2024.
  ieee: M. Rodemer, L. Mientus, J. Wiedmann, A. Nowak, and P. Pollmeier, “Professionalisierungsmöglichkeiten
    angehender Lehrkräfte in Praxisphasen,” in <i>Frühe naturwissenschaftliche Bildung
    </i>, Hamburg, 2024, vol. 44.
  mla: Rodemer, Marc, et al. “Professionalisierungsmöglichkeiten Angehender Lehrkräfte
    in Praxisphasen.” <i>Frühe Naturwissenschaftliche Bildung </i>, edited by Helena
    van Vorst, vol. 44, 2024.
  short: 'M. Rodemer, L. Mientus, J. Wiedmann, A. Nowak, P. Pollmeier, in: H. van
    Vorst (Ed.), Frühe Naturwissenschaftliche Bildung , Essen, 2024.'
conference:
  end_date: 2023-09-14
  location: Hamburg
  name: 50. Jahrestagung der Gesellschaft für Didaktik der Chemie und Physik e.V.
  start_date: 2023-09-11
date_created: 2024-06-11T06:57:53Z
date_updated: 2024-07-09T10:33:23Z
department:
- _id: '386'
editor:
- first_name: Helena
  full_name: van Vorst, Helena
  last_name: van Vorst
intvolume: '        44'
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://gdcp-ev.de/wp-content/uploads/securepdfs/2024/06/E01-04_Rodemer.pdf
oa: '1'
place: Essen
publication: 'Frühe naturwissenschaftliche Bildung '
series_title: Tagungsband zur GDCP Jahrestagung
status: public
title: Professionalisierungsmöglichkeiten angehender Lehrkräfte in Praxisphasen
type: conference
user_id: '44191'
volume: 44
year: '2024'
...
---
_id: '55310'
abstract:
- lang: eng
  text: <jats:p>DNA origami nanostructures are promising carries for drug delivery
    applications. However, their limited stability under relevant conditions often
    presents a challenge. Herein, the structural stability of DNA origami nanostructures
    is investigated in a setting compatible with their application in photodynamic
    therapy (PDT). To this end, DNA origami triangles and six‐helix bundles (6HBs)
    are loaded with the clinically tested photosensitizer methylene blue, which upon
    irradiation with red light generates reactive oxygen species (ROS) that attack
    the DNA origami nanostructures. ROS‐induced structural damage is observed to depend
    on the ionic composition of the surrounding medium and becomes more severe at
    low ionic strength. Mg<jats:sup>2+</jats:sup> ions can efficiently protect the
    DNA origami nanostructures from ROS‐induced damage and may even heal some of the
    damage obtained under Mg<jats:sup>2+</jats:sup>‐free conditions when added after
    irradiation. Finally, the employed DNA origami 6HBs are more resistant toward
    ROS‐induced structural damage than the triangles, which is attributed to their
    markedly different mechanical properties. These results thus provide some fundamental
    insights into the stabilizing role of DNA origami superstructure that may guide
    the selection or design of DNA origami nanocarriers with optimized stability for
    their application in PDT.</jats:p>
author:
- first_name: Lukas
  full_name: Rabbe, Lukas
  last_name: Rabbe
- first_name: Jaime Andres
  full_name: Garcia‐Diosa, Jaime Andres
  last_name: Garcia‐Diosa
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
citation:
  ama: Rabbe L, Garcia‐Diosa JA, Grundmeier G, Keller A. Ion‐Dependent Stability of
    DNA Origami Nanostructures in the Presence of Photo‐Generated Reactive Oxygen
    Species. <i>Small Structures</i>. Published online 2024. doi:<a href="https://doi.org/10.1002/sstr.202400094">10.1002/sstr.202400094</a>
  apa: Rabbe, L., Garcia‐Diosa, J. A., Grundmeier, G., &#38; Keller, A. (2024). Ion‐Dependent
    Stability of DNA Origami Nanostructures in the Presence of Photo‐Generated Reactive
    Oxygen Species. <i>Small Structures</i>. <a href="https://doi.org/10.1002/sstr.202400094">https://doi.org/10.1002/sstr.202400094</a>
  bibtex: '@article{Rabbe_Garcia‐Diosa_Grundmeier_Keller_2024, title={Ion‐Dependent
    Stability of DNA Origami Nanostructures in the Presence of Photo‐Generated Reactive
    Oxygen Species}, DOI={<a href="https://doi.org/10.1002/sstr.202400094">10.1002/sstr.202400094</a>},
    journal={Small Structures}, publisher={Wiley}, author={Rabbe, Lukas and Garcia‐Diosa,
    Jaime Andres and Grundmeier, Guido and Keller, Adrian}, year={2024} }'
  chicago: Rabbe, Lukas, Jaime Andres Garcia‐Diosa, Guido Grundmeier, and Adrian Keller.
    “Ion‐Dependent Stability of DNA Origami Nanostructures in the Presence of Photo‐Generated
    Reactive Oxygen Species.” <i>Small Structures</i>, 2024. <a href="https://doi.org/10.1002/sstr.202400094">https://doi.org/10.1002/sstr.202400094</a>.
  ieee: 'L. Rabbe, J. A. Garcia‐Diosa, G. Grundmeier, and A. Keller, “Ion‐Dependent
    Stability of DNA Origami Nanostructures in the Presence of Photo‐Generated Reactive
    Oxygen Species,” <i>Small Structures</i>, 2024, doi: <a href="https://doi.org/10.1002/sstr.202400094">10.1002/sstr.202400094</a>.'
  mla: Rabbe, Lukas, et al. “Ion‐Dependent Stability of DNA Origami Nanostructures
    in the Presence of Photo‐Generated Reactive Oxygen Species.” <i>Small Structures</i>,
    Wiley, 2024, doi:<a href="https://doi.org/10.1002/sstr.202400094">10.1002/sstr.202400094</a>.
  short: L. Rabbe, J.A. Garcia‐Diosa, G. Grundmeier, A. Keller, Small Structures (2024).
date_created: 2024-07-18T09:03:17Z
date_updated: 2024-07-18T09:03:49Z
department:
- _id: '302'
doi: 10.1002/sstr.202400094
language:
- iso: eng
publication: Small Structures
publication_identifier:
  issn:
  - 2688-4062
  - 2688-4062
publication_status: published
publisher: Wiley
status: public
title: Ion‐Dependent Stability of DNA Origami Nanostructures in the Presence of Photo‐Generated
  Reactive Oxygen Species
type: journal_article
user_id: '48864'
year: '2024'
...
---
_id: '55371'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F
    bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub>
    is reported and applied in reactions with arenes, allylic, vinylic and acetylenic
    silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>
author:
- first_name: Axel
  full_name: Hoppe, Axel
  last_name: Hoppe
- first_name: Arne J.
  full_name: Stepen, Arne J.
  last_name: Stepen
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>.
    2024;366(13):2933-2938. doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>
  apa: Hoppe, A., Stepen, A. J., Köring, L., &#38; Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    <i>366</i>(13), 2933–2938. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>
  bibtex: '@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>},
    number={13}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley},
    author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan},
    year={2024}, pages={2933–2938} }'
  chicago: 'Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>
    366, no. 13 (2024): 2933–38. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>.'
  ieee: 'A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds,” <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    vol. 366, no. 13, pp. 2933–2938, 2024, doi: <a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.'
  mla: Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization
    of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366,
    no. 13, Wiley, 2024, pp. 2933–38, doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.
  short: A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis &#38;amp;
    Catalysis 366 (2024) 2933–2938.
date_created: 2024-07-24T09:16:15Z
date_updated: 2024-07-24T09:18:18Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/adsc.202400511
intvolume: '       366'
issue: '13'
language:
- iso: eng
page: 2933-2938
publication: Advanced Synthesis &amp; Catalysis
publication_identifier:
  issn:
  - 1615-4150
  - 1615-4169
publication_status: published
publisher: Wiley
status: public
title: Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds
type: journal_article
user_id: '53339'
volume: 366
year: '2024'
...
---
_id: '55392'
abstract:
- lang: ger
  text: In dieser Arbeit werden Untersuchungen zur sauerstoffabhängigen Photolumineszenz
    von Zink-Zinn-Oxid-Partikeln präsentiert, welche perspektivisch für die optische
    Sauerstoffdetektion eingesetzt werden sollen. Zink-Zinn-Oxid zeigt eine sauerstoffabhängige
    Photolumineszenz im sichtbaren Spektralbereich und wird hier als eine photostabile
    Alternative zu den kommerziell verfügbaren metallorganischen Verbindungen vorgestellt.
    Der Fokus liegt dabei auf dem Einfluss der Temperatur auf die Sauerstoffsensitivität
    der Photolumineszenz. Wir zeigen, dass bereits leichte Temperaturerhöhungen zu
    einer signifikanten Verbesserung der Sauerstoffsensitivität der Photolumineszenz
    führen und gleichzeitig die Signalqualität erhöhen.
author:
- first_name: Linda
  full_name: Kothe, Linda
  last_name: Kothe
- first_name: Stephan
  full_name: Ester, Stephan
  last_name: Ester
- first_name: Michael
  full_name: Poeplau, Michael
  last_name: Poeplau
- first_name: Marc
  full_name: Wengenroth, Marc
  last_name: Wengenroth
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: 'Kothe L, Ester S, Poeplau M, Wengenroth M, Tiemann M. Stabilisierung von O2-sensitiven
    Photolumineszenzsignalen durch Temperaturvariation. In: <i>Proceedings 22. GMA/ITG-Fachtagung
    Sensoren Und Messsysteme 2024</i>. ; 2024:66-71. doi:<a href="https://doi.org/10.5162/sensoren2024/A3.1">10.5162/sensoren2024/A3.1</a>'
  apa: Kothe, L., Ester, S., Poeplau, M., Wengenroth, M., &#38; Tiemann, M. (2024).
    Stabilisierung von O2-sensitiven Photolumineszenzsignalen durch Temperaturvariation.
    <i>Proceedings 22. GMA/ITG-Fachtagung Sensoren Und Messsysteme 2024</i>, 66–71.
    <a href="https://doi.org/10.5162/sensoren2024/A3.1">https://doi.org/10.5162/sensoren2024/A3.1</a>
  bibtex: '@inproceedings{Kothe_Ester_Poeplau_Wengenroth_Tiemann_2024, title={Stabilisierung
    von O2-sensitiven Photolumineszenzsignalen durch Temperaturvariation}, DOI={<a
    href="https://doi.org/10.5162/sensoren2024/A3.1">10.5162/sensoren2024/A3.1</a>},
    booktitle={Proceedings 22. GMA/ITG-Fachtagung Sensoren und Messsysteme 2024},
    author={Kothe, Linda and Ester, Stephan and Poeplau, Michael and Wengenroth, Marc
    and Tiemann, Michael}, year={2024}, pages={66–71} }'
  chicago: Kothe, Linda, Stephan Ester, Michael Poeplau, Marc Wengenroth, and Michael
    Tiemann. “Stabilisierung von O2-Sensitiven Photolumineszenzsignalen Durch Temperaturvariation.”
    In <i>Proceedings 22. GMA/ITG-Fachtagung Sensoren Und Messsysteme 2024</i>, 66–71,
    2024. <a href="https://doi.org/10.5162/sensoren2024/A3.1">https://doi.org/10.5162/sensoren2024/A3.1</a>.
  ieee: 'L. Kothe, S. Ester, M. Poeplau, M. Wengenroth, and M. Tiemann, “Stabilisierung
    von O2-sensitiven Photolumineszenzsignalen durch Temperaturvariation,” in <i>Proceedings
    22. GMA/ITG-Fachtagung Sensoren und Messsysteme 2024</i>, 2024, pp. 66–71, doi:
    <a href="https://doi.org/10.5162/sensoren2024/A3.1">10.5162/sensoren2024/A3.1</a>.'
  mla: Kothe, Linda, et al. “Stabilisierung von O2-Sensitiven Photolumineszenzsignalen
    Durch Temperaturvariation.” <i>Proceedings 22. GMA/ITG-Fachtagung Sensoren Und
    Messsysteme 2024</i>, 2024, pp. 66–71, doi:<a href="https://doi.org/10.5162/sensoren2024/A3.1">10.5162/sensoren2024/A3.1</a>.
  short: 'L. Kothe, S. Ester, M. Poeplau, M. Wengenroth, M. Tiemann, in: Proceedings
    22. GMA/ITG-Fachtagung Sensoren Und Messsysteme 2024, 2024, pp. 66–71.'
date_created: 2024-07-26T07:20:30Z
date_updated: 2024-07-30T11:52:18Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.5162/sensoren2024/A3.1
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
page: 66 - 71
publication: Proceedings 22. GMA/ITG-Fachtagung Sensoren und Messsysteme 2024
publication_identifier:
  isbn:
  - 978-3-910600-01-0
quality_controlled: '1'
status: public
title: Stabilisierung von O2-sensitiven Photolumineszenzsignalen durch Temperaturvariation
type: conference
user_id: '23547'
year: '2024'
...
---
_id: '59509'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>A strategy for multifunctional biosurfaces
    exploiting multiblock copolymers and the antipolyelectrolyte effect is reported.
    Combining a polyzwitterionic/antifouling and a polycationic/antibacterial block
    with a central anchoring block for attachment to titanium oxide surfaces affords
    surface coatings that exhibit antifouling properties against proteins and allow
    for surface regeneration by clearing adhering proteins by employing a salt washing
    step. The surfaces also kill bacteria by contact killing, which is aided by a
    nonfouling block. The synthesis of block copolymers of 4‐vinyl pyridine (VP),
    dimethyl 4‐vinylbenzyl phosphonate (DMVBP), and 4‐vinylbenzyltrimethyl ammonium
    chloride (TMA) is achieved on the multigram scale via RAFT polymerization with
    good end group retention and narrow dispersities. By polymer analogous reactions,
    poly(4‐vinyl pyridinium propane sulfonate‐<jats:italic>block</jats:italic>‐4‐vinylbenzyl
    phosphonic acid‐<jats:italic>block</jats:italic>‐4‐vinylbenzyl trimethylammonium
    chloride) (P(VSP<jats:sub>64</jats:sub>‐<jats:italic>b</jats:italic>‐PA<jats:sub>14</jats:sub>‐<jats:italic>b</jats:italic>‐TMA<jats:sub>64</jats:sub>))
    is obtained. The antifouling properties against the model protein pepsin and the
    salt‐induced surface regeneration are shown in surface plasmon resonance (SPR)
    experiments, while independently the antibacterial and antifouling properties
    of coated titanium substrates are successfully tested in preliminary microbiological
    assays against <jats:italic>Staphylococcus aureus</jats:italic> (<jats:italic>S.
    aureus</jats:italic>) and <jats:italic>Escherichia coli</jats:italic> (<jats:italic>E.
    coli</jats:italic>). This strategy may contribute to the development of long‐term
    effective antibacterial implant surface coatings to suppress biomedical device‐associated
    infections.</jats:p>
author:
- first_name: Rafael
  full_name: Methling, Rafael
  last_name: Methling
- first_name: Michael
  full_name: Greiter, Michael
  last_name: Greiter
- first_name: Jiwar
  full_name: Al‐Zawity, Jiwar
  last_name: Al‐Zawity
- first_name: Mareike
  full_name: Müller, Mareike
  last_name: Müller
- first_name: Holger
  full_name: Schönherr, Holger
  last_name: Schönherr
- first_name: Dirk
  full_name: Kuckling, Dirk
  id: '287'
  last_name: Kuckling
citation:
  ama: Methling R, Greiter M, Al‐Zawity J, Müller M, Schönherr H, Kuckling D. Salt‐Responsive
    Switchable Block Copolymer Brushes with Antibacterial and Antifouling Properties.
    <i>Macromolecular Bioscience</i>. 2024;25(1). doi:<a href="https://doi.org/10.1002/mabi.202400261">10.1002/mabi.202400261</a>
  apa: Methling, R., Greiter, M., Al‐Zawity, J., Müller, M., Schönherr, H., &#38;
    Kuckling, D. (2024). Salt‐Responsive Switchable Block Copolymer Brushes with Antibacterial
    and Antifouling Properties. <i>Macromolecular Bioscience</i>, <i>25</i>(1). <a
    href="https://doi.org/10.1002/mabi.202400261">https://doi.org/10.1002/mabi.202400261</a>
  bibtex: '@article{Methling_Greiter_Al‐Zawity_Müller_Schönherr_Kuckling_2024, title={Salt‐Responsive
    Switchable Block Copolymer Brushes with Antibacterial and Antifouling Properties},
    volume={25}, DOI={<a href="https://doi.org/10.1002/mabi.202400261">10.1002/mabi.202400261</a>},
    number={1}, journal={Macromolecular Bioscience}, publisher={Wiley}, author={Methling,
    Rafael and Greiter, Michael and Al‐Zawity, Jiwar and Müller, Mareike and Schönherr,
    Holger and Kuckling, Dirk}, year={2024} }'
  chicago: Methling, Rafael, Michael Greiter, Jiwar Al‐Zawity, Mareike Müller, Holger
    Schönherr, and Dirk Kuckling. “Salt‐Responsive Switchable Block Copolymer Brushes
    with Antibacterial and Antifouling Properties.” <i>Macromolecular Bioscience</i>
    25, no. 1 (2024). <a href="https://doi.org/10.1002/mabi.202400261">https://doi.org/10.1002/mabi.202400261</a>.
  ieee: 'R. Methling, M. Greiter, J. Al‐Zawity, M. Müller, H. Schönherr, and D. Kuckling,
    “Salt‐Responsive Switchable Block Copolymer Brushes with Antibacterial and Antifouling
    Properties,” <i>Macromolecular Bioscience</i>, vol. 25, no. 1, 2024, doi: <a href="https://doi.org/10.1002/mabi.202400261">10.1002/mabi.202400261</a>.'
  mla: Methling, Rafael, et al. “Salt‐Responsive Switchable Block Copolymer Brushes
    with Antibacterial and Antifouling Properties.” <i>Macromolecular Bioscience</i>,
    vol. 25, no. 1, Wiley, 2024, doi:<a href="https://doi.org/10.1002/mabi.202400261">10.1002/mabi.202400261</a>.
  short: R. Methling, M. Greiter, J. Al‐Zawity, M. Müller, H. Schönherr, D. Kuckling,
    Macromolecular Bioscience 25 (2024).
date_created: 2025-04-11T07:07:31Z
date_updated: 2025-04-11T07:09:03Z
department:
- _id: '163'
doi: 10.1002/mabi.202400261
intvolume: '        25'
issue: '1'
keyword:
- antibacterial coatings
- antipolyelectrolyte eﬀect
- salt switchable polymers
- zwitterionic brushes
language:
- iso: eng
main_file_link:
- url: https://onlinelibrary.wiley.com/doi/10.1002/mabi.202400261
publication: Macromolecular Bioscience
publication_identifier:
  issn:
  - 1616-5187
  - 1616-5195
publication_status: published
publisher: Wiley
status: public
title: Salt‐Responsive Switchable Block Copolymer Brushes with Antibacterial and Antifouling
  Properties
type: journal_article
user_id: '94'
volume: 25
year: '2024'
...
---
_id: '59508'
abstract:
- lang: eng
  text: Over the last few decades, nanotechnology has established to be a promising
    field in medicine. A remaining dominant challenge in today's pharmacotherapy is
    the limited selectivity of active pharmaceutical ingredients and associated undesirable
    side effects. Controlled drug release can be promoted by smart drug delivery systems,
    which release embedded API primarily depending on specific stimuli. Consequently,
    also the microenvironment of tumor tissue can be used advantageously. Dithiothreitol
    (DTT) based self-immolative polydisulfides were synthesized that preferentially
    respond to pathologically increased glutathione (GSH) concentrations, as found
    in solid tumors. The synthesis with different degrees of polymerisation was investigated
    as well as the synthesis of a copolymer consisting of dithiothreitol and butanedithiol
    (BDT). Toxicity tests were carried out on pure polymers and their degradation
    products. The ability to degrade was examined at pathological and physiological
    glutathione concentrations in order to test the suitability of the polymer as
    a matrix for nanoparticulate carrier systems. In addition, the processability
    of one polymer into nanoparticles was investigated as well as the degradation
    behaviour with glutathione.
article_type: original
author:
- first_name: Katharina
  full_name: Völlmecke, Katharina
  last_name: Völlmecke
- first_name: Maurice
  full_name: Kramer, Maurice
  last_name: Kramer
- first_name: Corinna
  full_name: Horky, Corinna
  last_name: Horky
- first_name: Oliver
  full_name: Dückmann, Oliver
  last_name: Dückmann
- first_name: Dennis
  full_name: Mulac, Dennis
  last_name: Mulac
- first_name: Klaus
  full_name: Langer, Klaus
  last_name: Langer
- first_name: Dirk
  full_name: Kuckling, Dirk
  id: '287'
  last_name: Kuckling
citation:
  ama: Völlmecke K, Kramer M, Horky C, et al. Self-immolative polydisulfides and their
    use as nanoparticles for drug delivery systems. <i>RSC Advances</i>. 2024;14(48):35568-35577.
    doi:<a href="https://doi.org/10.1039/d4ra07228f">10.1039/d4ra07228f</a>
  apa: Völlmecke, K., Kramer, M., Horky, C., Dückmann, O., Mulac, D., Langer, K.,
    &#38; Kuckling, D. (2024). Self-immolative polydisulfides and their use as nanoparticles
    for drug delivery systems. <i>RSC Advances</i>, <i>14</i>(48), 35568–35577. <a
    href="https://doi.org/10.1039/d4ra07228f">https://doi.org/10.1039/d4ra07228f</a>
  bibtex: '@article{Völlmecke_Kramer_Horky_Dückmann_Mulac_Langer_Kuckling_2024, title={Self-immolative
    polydisulfides and their use as nanoparticles for drug delivery systems}, volume={14},
    DOI={<a href="https://doi.org/10.1039/d4ra07228f">10.1039/d4ra07228f</a>}, number={48},
    journal={RSC Advances}, publisher={Royal Society of Chemistry (RSC)}, author={Völlmecke,
    Katharina and Kramer, Maurice and Horky, Corinna and Dückmann, Oliver and Mulac,
    Dennis and Langer, Klaus and Kuckling, Dirk}, year={2024}, pages={35568–35577}
    }'
  chicago: 'Völlmecke, Katharina, Maurice Kramer, Corinna Horky, Oliver Dückmann,
    Dennis Mulac, Klaus Langer, and Dirk Kuckling. “Self-Immolative Polydisulfides
    and Their Use as Nanoparticles for Drug Delivery Systems.” <i>RSC Advances</i>
    14, no. 48 (2024): 35568–77. <a href="https://doi.org/10.1039/d4ra07228f">https://doi.org/10.1039/d4ra07228f</a>.'
  ieee: 'K. Völlmecke <i>et al.</i>, “Self-immolative polydisulfides and their use
    as nanoparticles for drug delivery systems,” <i>RSC Advances</i>, vol. 14, no.
    48, pp. 35568–35577, 2024, doi: <a href="https://doi.org/10.1039/d4ra07228f">10.1039/d4ra07228f</a>.'
  mla: Völlmecke, Katharina, et al. “Self-Immolative Polydisulfides and Their Use
    as Nanoparticles for Drug Delivery Systems.” <i>RSC Advances</i>, vol. 14, no.
    48, Royal Society of Chemistry (RSC), 2024, pp. 35568–77, doi:<a href="https://doi.org/10.1039/d4ra07228f">10.1039/d4ra07228f</a>.
  short: K. Völlmecke, M. Kramer, C. Horky, O. Dückmann, D. Mulac, K. Langer, D. Kuckling,
    RSC Advances 14 (2024) 35568–35577.
date_created: 2025-04-11T07:03:03Z
date_updated: 2025-04-11T07:06:22Z
department:
- _id: '163'
doi: 10.1039/d4ra07228f
intvolume: '        14'
issue: '48'
language:
- iso: eng
main_file_link:
- url: https://pubs.rsc.org/en/content/articlelanding/2024/ra/d4ra07228f
page: 35568-35577
publication: RSC Advances
publication_identifier:
  issn:
  - 2046-2069
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Self-immolative polydisulfides and their use as nanoparticles for drug delivery
  systems
type: journal_article
user_id: '94'
volume: 14
year: '2024'
...
---
_id: '59616'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F
    bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub>
    is reported and applied in reactions with arenes, allylic, vinylic and acetylenic
    silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>
author:
- first_name: Axel
  full_name: Hoppe, Axel
  id: '62844'
  last_name: Hoppe
- first_name: Arne J.
  full_name: Stepen, Arne J.
  last_name: Stepen
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>.
    2024;366(13):2933-2938. doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>
  apa: Hoppe, A., Stepen, A. J., Köring, L., &#38; Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    <i>366</i>(13), 2933–2938. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>
  bibtex: '@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>},
    number={13}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley},
    author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan},
    year={2024}, pages={2933–2938} }'
  chicago: 'Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>
    366, no. 13 (2024): 2933–38. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>.'
  ieee: 'A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds,” <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    vol. 366, no. 13, pp. 2933–2938, 2024, doi: <a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.'
  mla: Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization
    of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366,
    no. 13, Wiley, 2024, pp. 2933–38, doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.
  short: A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis &#38;amp;
    Catalysis 366 (2024) 2933–2938.
date_created: 2025-04-22T05:59:08Z
date_updated: 2025-04-22T06:11:59Z
department:
- _id: '389'
doi: 10.1002/adsc.202400511
intvolume: '       366'
issue: '13'
keyword:
- fluoride
- bond activation
- borane
- Lewis acid
- C-C bond formation
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202400511
oa: '1'
page: 2933-2938
publication: Advanced Synthesis &amp; Catalysis
publication_identifier:
  issn:
  - 1615-4150
  - 1615-4169
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds
type: journal_article
user_id: '62844'
volume: 366
year: '2024'
...
---
_id: '57619'
abstract:
- lang: eng
  text: <jats:p>Ferroelectric liquid crystals exhibiting a chiral smectic C* phase
    are deposited on z cut periodically poled lithium niobate substrates and investigated
    by polarized optical microscopy. While the pure substrates placed between crossed
    polarizers and observed in transmission appear dark, uniformly aligned liquid
    crystal films deposited on these substrates show alternating domains with varying
    brightness. This effect can be attributed to the well-known coupling between the
    direction of the spontaneous polarization and the optical axis in the birefringent
    ferroelectric smectic C* phase. Quantitative measurements of the tilt angle between
    the local optical axis and the smectic layer normal confirm antiparallel orientations
    of spontaneous polarization of the liquid crystal from domain to domain, as expected
    by the periodic poling of the lithium niobate substrate. This effect provides
    a valuable non-destructive method of optical inspection of the quality of periodically
    poled ferroelectric substrates, which plays an important role in achieving quasi-phase-matching
    in non-linear optical applications.</jats:p>
author:
- first_name: Patrick A.
  full_name: Meier, Patrick A.
  last_name: Meier
- first_name: Susanne
  full_name: Keuker-Baumann, Susanne
  last_name: Keuker-Baumann
- first_name: Thorsten
  full_name: Röder, Thorsten
  last_name: Röder
- first_name: Harald
  full_name: Herrmann, Harald
  id: '216'
  last_name: Herrmann
- first_name: Raimund
  full_name: Ricken, Raimund
  last_name: Ricken
- first_name: Christine
  full_name: Silberhorn, Christine
  id: '26263'
  last_name: Silberhorn
- first_name: Heinz-Siegfried
  full_name: Kitzerow, Heinz-Siegfried
  id: '254'
  last_name: Kitzerow
citation:
  ama: Meier PA, Keuker-Baumann S, Röder T, et al. Optical imaging of ferroelectric
    domains in periodically poled lithium niobate using ferroelectric liquid crystals.
    <i>Opto-Electronics Review</i>. Published online 2024:150611-150611. doi:<a href="https://doi.org/10.24425/opelre.2024.150611">10.24425/opelre.2024.150611</a>
  apa: Meier, P. A., Keuker-Baumann, S., Röder, T., Herrmann, H., Ricken, R., Silberhorn,
    C., &#38; Kitzerow, H.-S. (2024). Optical imaging of ferroelectric domains in
    periodically poled lithium niobate using ferroelectric liquid crystals. <i>Opto-Electronics
    Review</i>, 150611–150611. <a href="https://doi.org/10.24425/opelre.2024.150611">https://doi.org/10.24425/opelre.2024.150611</a>
  bibtex: '@article{Meier_Keuker-Baumann_Röder_Herrmann_Ricken_Silberhorn_Kitzerow_2024,
    title={Optical imaging of ferroelectric domains in periodically poled lithium
    niobate using ferroelectric liquid crystals}, DOI={<a href="https://doi.org/10.24425/opelre.2024.150611">10.24425/opelre.2024.150611</a>},
    journal={Opto-Electronics Review}, publisher={Polish Academy of Sciences Chancellery},
    author={Meier, Patrick A. and Keuker-Baumann, Susanne and Röder, Thorsten and
    Herrmann, Harald and Ricken, Raimund and Silberhorn, Christine and Kitzerow, Heinz-Siegfried},
    year={2024}, pages={150611–150611} }'
  chicago: Meier, Patrick A., Susanne Keuker-Baumann, Thorsten Röder, Harald Herrmann,
    Raimund Ricken, Christine Silberhorn, and Heinz-Siegfried Kitzerow. “Optical imaging
    of ferroelectric domains in periodically poled lithium niobate using ferroelectric
    liquid crystals.” <i>Opto-Electronics Review</i>, 2024, 150611–150611. <a href="https://doi.org/10.24425/opelre.2024.150611">https://doi.org/10.24425/opelre.2024.150611</a>.
  ieee: 'P. A. Meier <i>et al.</i>, “Optical imaging of ferroelectric domains in periodically
    poled lithium niobate using ferroelectric liquid crystals,” <i>Opto-Electronics
    Review</i>, pp. 150611–150611, 2024, doi: <a href="https://doi.org/10.24425/opelre.2024.150611">10.24425/opelre.2024.150611</a>.'
  mla: Meier, Patrick A., et al. “Optical imaging of ferroelectric domains in periodically
    poled lithium niobate using ferroelectric liquid crystals.” <i>Opto-Electronics
    Review</i>, Polish Academy of Sciences Chancellery, 2024, pp. 150611–150611, doi:<a
    href="https://doi.org/10.24425/opelre.2024.150611">10.24425/opelre.2024.150611</a>.
  short: P.A. Meier, S. Keuker-Baumann, T. Röder, H. Herrmann, R. Ricken, C. Silberhorn,
    H.-S. Kitzerow, Opto-Electronics Review (2024) 150611–150611.
date_created: 2024-12-08T14:37:43Z
date_updated: 2024-12-08T14:45:39Z
department:
- _id: '313'
- _id: '230'
- _id: '2'
doi: 10.24425/opelre.2024.150611
language:
- iso: pol
page: 150611-150611
publication: Opto-Electronics Review
publication_identifier:
  issn:
  - 1896-3757
publication_status: published
publisher: Polish Academy of Sciences Chancellery
status: public
title: Optical imaging of ferroelectric domains in periodically poled lithium niobate
  using ferroelectric liquid crystals
type: journal_article
user_id: '254'
year: '2024'
...
---
_id: '57618'
abstract:
- lang: eng
  text: <jats:p>The presence of a polymer network and/or the addition of ferroelectric
    nanoparticles to a nematic liquid crystal are found to lower transition temperatures
    and birefringence, which indicates reduced orientational order. In addition, the
    electro-optic switching voltage is considerably increased when a polymer network
    is formed by in situ polymerization in the nematic state. However, the resulting
    polymer network liquid crystal switches at similar voltages as the neat liquid
    crystal when polymerization is performed at an elevated temperature in the isotropic
    state. When nanoparticle dispersions are polymerized at an applied DC voltage,
    the transition temperatures and switching voltages are reduced, yet they are larger
    than those observed for polymer network liquid crystals without nanoparticles
    polymerized in the isotropic phase.</jats:p>
article_number: '961'
author:
- first_name: Gaby
  full_name: Nordendorf, Gaby
  last_name: Nordendorf
- first_name: Gisela
  full_name: Jünnemann-Held, Gisela
  last_name: Jünnemann-Held
- first_name: Alexander
  full_name: Lorenz, Alexander
  last_name: Lorenz
- first_name: Heinz-Siegfried
  full_name: Kitzerow, Heinz-Siegfried
  id: '254'
  last_name: Kitzerow
citation:
  ama: Nordendorf G, Jünnemann-Held G, Lorenz A, Kitzerow H-S. Effects of Composition
    and Polymerization Conditions on the Electro-Optic Performance of Liquid Crystal–Polymer
    Composites Doped with Ferroelectric Nanoparticles. <i>Nanomaterials</i>. 2024;14(11).
    doi:<a href="https://doi.org/10.3390/nano14110961">10.3390/nano14110961</a>
  apa: Nordendorf, G., Jünnemann-Held, G., Lorenz, A., &#38; Kitzerow, H.-S. (2024).
    Effects of Composition and Polymerization Conditions on the Electro-Optic Performance
    of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles. <i>Nanomaterials</i>,
    <i>14</i>(11), Article 961. <a href="https://doi.org/10.3390/nano14110961">https://doi.org/10.3390/nano14110961</a>
  bibtex: '@article{Nordendorf_Jünnemann-Held_Lorenz_Kitzerow_2024, title={Effects
    of Composition and Polymerization Conditions on the Electro-Optic Performance
    of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles},
    volume={14}, DOI={<a href="https://doi.org/10.3390/nano14110961">10.3390/nano14110961</a>},
    number={11961}, journal={Nanomaterials}, publisher={MDPI AG}, author={Nordendorf,
    Gaby and Jünnemann-Held, Gisela and Lorenz, Alexander and Kitzerow, Heinz-Siegfried},
    year={2024} }'
  chicago: Nordendorf, Gaby, Gisela Jünnemann-Held, Alexander Lorenz, and Heinz-Siegfried
    Kitzerow. “Effects of Composition and Polymerization Conditions on the Electro-Optic
    Performance of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles.”
    <i>Nanomaterials</i> 14, no. 11 (2024). <a href="https://doi.org/10.3390/nano14110961">https://doi.org/10.3390/nano14110961</a>.
  ieee: 'G. Nordendorf, G. Jünnemann-Held, A. Lorenz, and H.-S. Kitzerow, “Effects
    of Composition and Polymerization Conditions on the Electro-Optic Performance
    of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles,”
    <i>Nanomaterials</i>, vol. 14, no. 11, Art. no. 961, 2024, doi: <a href="https://doi.org/10.3390/nano14110961">10.3390/nano14110961</a>.'
  mla: Nordendorf, Gaby, et al. “Effects of Composition and Polymerization Conditions
    on the Electro-Optic Performance of Liquid Crystal–Polymer Composites Doped with
    Ferroelectric Nanoparticles.” <i>Nanomaterials</i>, vol. 14, no. 11, 961, MDPI
    AG, 2024, doi:<a href="https://doi.org/10.3390/nano14110961">10.3390/nano14110961</a>.
  short: G. Nordendorf, G. Jünnemann-Held, A. Lorenz, H.-S. Kitzerow, Nanomaterials
    14 (2024).
date_created: 2024-12-08T14:36:04Z
date_updated: 2024-12-08T14:46:05Z
department:
- _id: '313'
- _id: '230'
- _id: '2'
doi: 10.3390/nano14110961
intvolume: '        14'
issue: '11'
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
status: public
title: Effects of Composition and Polymerization Conditions on the Electro-Optic Performance
  of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles
type: journal_article
user_id: '254'
volume: 14
year: '2024'
...
---
_id: '57616'
author:
- first_name: David
  full_name: Becker, David
  last_name: Becker
- first_name: Patrick
  full_name: Meier, Patrick
  last_name: Meier
- first_name: Andreas
  full_name: Kuhlmann, Andreas
  last_name: Kuhlmann
- first_name: Christian
  full_name: Sternemann, Christian
  last_name: Sternemann
- first_name: Harald
  full_name: Bock, Harald
  last_name: Bock
- first_name: Hans-Georg
  full_name: Steinrück, Hans-Georg
  id: '84268'
  last_name: Steinrück
  orcid: 0000-0001-6373-0877
- first_name: Heinz-Siegfried
  full_name: Kitzerow, Heinz-Siegfried
  id: '254'
  last_name: Kitzerow
citation:
  ama: Becker D, Meier P, Kuhlmann A, et al. Influence of the Deposition Rate on the
    Alignment and Performance of Perylene-3,4,9,10-tetracarboxylic Tetraethyl Ester
    in an Organic Light Emitting Diode. <i>ACS Applied Electronic Materials</i>. 2024;6(2):1234-1243.
    doi:<a href="https://doi.org/10.1021/acsaelm.3c01586">10.1021/acsaelm.3c01586</a>
  apa: Becker, D., Meier, P., Kuhlmann, A., Sternemann, C., Bock, H., Steinrück, H.-G.,
    &#38; Kitzerow, H.-S. (2024). Influence of the Deposition Rate on the Alignment
    and Performance of Perylene-3,4,9,10-tetracarboxylic Tetraethyl Ester in an Organic
    Light Emitting Diode. <i>ACS Applied Electronic Materials</i>, <i>6</i>(2), 1234–1243.
    <a href="https://doi.org/10.1021/acsaelm.3c01586">https://doi.org/10.1021/acsaelm.3c01586</a>
  bibtex: '@article{Becker_Meier_Kuhlmann_Sternemann_Bock_Steinrück_Kitzerow_2024,
    title={Influence of the Deposition Rate on the Alignment and Performance of Perylene-3,4,9,10-tetracarboxylic
    Tetraethyl Ester in an Organic Light Emitting Diode}, volume={6}, DOI={<a href="https://doi.org/10.1021/acsaelm.3c01586">10.1021/acsaelm.3c01586</a>},
    number={2}, journal={ACS Applied Electronic Materials}, publisher={American Chemical
    Society (ACS)}, author={Becker, David and Meier, Patrick and Kuhlmann, Andreas
    and Sternemann, Christian and Bock, Harald and Steinrück, Hans-Georg and Kitzerow,
    Heinz-Siegfried}, year={2024}, pages={1234–1243} }'
  chicago: 'Becker, David, Patrick Meier, Andreas Kuhlmann, Christian Sternemann,
    Harald Bock, Hans-Georg Steinrück, and Heinz-Siegfried Kitzerow. “Influence of
    the Deposition Rate on the Alignment and Performance of Perylene-3,4,9,10-Tetracarboxylic
    Tetraethyl Ester in an Organic Light Emitting Diode.” <i>ACS Applied Electronic
    Materials</i> 6, no. 2 (2024): 1234–43. <a href="https://doi.org/10.1021/acsaelm.3c01586">https://doi.org/10.1021/acsaelm.3c01586</a>.'
  ieee: 'D. Becker <i>et al.</i>, “Influence of the Deposition Rate on the Alignment
    and Performance of Perylene-3,4,9,10-tetracarboxylic Tetraethyl Ester in an Organic
    Light Emitting Diode,” <i>ACS Applied Electronic Materials</i>, vol. 6, no. 2,
    pp. 1234–1243, 2024, doi: <a href="https://doi.org/10.1021/acsaelm.3c01586">10.1021/acsaelm.3c01586</a>.'
  mla: Becker, David, et al. “Influence of the Deposition Rate on the Alignment and
    Performance of Perylene-3,4,9,10-Tetracarboxylic Tetraethyl Ester in an Organic
    Light Emitting Diode.” <i>ACS Applied Electronic Materials</i>, vol. 6, no. 2,
    American Chemical Society (ACS), 2024, pp. 1234–43, doi:<a href="https://doi.org/10.1021/acsaelm.3c01586">10.1021/acsaelm.3c01586</a>.
  short: D. Becker, P. Meier, A. Kuhlmann, C. Sternemann, H. Bock, H.-G. Steinrück,
    H.-S. Kitzerow, ACS Applied Electronic Materials 6 (2024) 1234–1243.
date_created: 2024-12-08T14:30:14Z
date_updated: 2024-12-08T14:43:50Z
department:
- _id: '313'
- _id: '230'
- _id: '2'
doi: 10.1021/acsaelm.3c01586
intvolume: '         6'
issue: '2'
language:
- iso: eng
page: 1234-1243
publication: ACS Applied Electronic Materials
publication_identifier:
  issn:
  - 2637-6113
  - 2637-6113
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Influence of the Deposition Rate on the Alignment and Performance of Perylene-3,4,9,10-tetracarboxylic
  Tetraethyl Ester in an Organic Light Emitting Diode
type: journal_article
user_id: '254'
volume: 6
year: '2024'
...
