---
_id: '41011'
abstract:
- lang: eng
text: The controlled assembly of well-defined planar nanoclusters from molecular
precursors is synthetically challenging and often plagued by the predominant formation
of 3D-structures and nanoparticles. Herein, we report planar iron hydride nanoclusters
from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide).
The structures and properties of isolated Fe4, Fe6, and Fe7 nanoplatelets and
calculated intermediates enable an unprecedented insight into the underlying building
principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles.
article_type: original
author:
- first_name: Uttam
full_name: Chakraborty, Uttam
last_name: Chakraborty
- first_name: Patrick
full_name: Bügel, Patrick
last_name: Bügel
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Florian
full_name: Weigend, Florian
last_name: Weigend
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Axel
full_name: Jacobi von Wangelin, Axel
last_name: Jacobi von Wangelin
citation:
ama: 'Chakraborty U, Bügel P, Fritsch L, Weigend F, Bauer M, Jacobi von Wangelin
A. Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights
into Structures and Building Principles. ChemistryOpen. 2021;10(2):265-271.
doi:10.1002/open.202000307'
apa: 'Chakraborty, U., Bügel, P., Fritsch, L., Weigend, F., Bauer, M., & Jacobi
von Wangelin, A. (2021). Planar Iron Hydride Nanoclusters: Combined Spectroscopic
and Theoretical Insights into Structures and Building Principles. ChemistryOpen,
10(2), 265–271. https://doi.org/10.1002/open.202000307'
bibtex: '@article{Chakraborty_Bügel_Fritsch_Weigend_Bauer_Jacobi von Wangelin_2021,
title={Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical
Insights into Structures and Building Principles}, volume={10}, DOI={10.1002/open.202000307},
number={2}, journal={ChemistryOpen}, publisher={Wiley}, author={Chakraborty, Uttam
and Bügel, Patrick and Fritsch, Lorena and Weigend, Florian and Bauer, Matthias
and Jacobi von Wangelin, Axel}, year={2021}, pages={265–271} }'
chicago: 'Chakraborty, Uttam, Patrick Bügel, Lorena Fritsch, Florian Weigend, Matthias
Bauer, and Axel Jacobi von Wangelin. “Planar Iron Hydride Nanoclusters: Combined
Spectroscopic and Theoretical Insights into Structures and Building Principles.”
ChemistryOpen 10, no. 2 (2021): 265–71. https://doi.org/10.1002/open.202000307.'
ieee: 'U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, and A. Jacobi
von Wangelin, “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical
Insights into Structures and Building Principles,” ChemistryOpen, vol.
10, no. 2, pp. 265–271, 2021, doi: 10.1002/open.202000307.'
mla: 'Chakraborty, Uttam, et al. “Planar Iron Hydride Nanoclusters: Combined Spectroscopic
and Theoretical Insights into Structures and Building Principles.” ChemistryOpen,
vol. 10, no. 2, Wiley, 2021, pp. 265–71, doi:10.1002/open.202000307.'
short: U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, A. Jacobi von
Wangelin, ChemistryOpen 10 (2021) 265–271.
date_created: 2023-01-30T17:00:36Z
date_updated: 2023-01-31T08:07:01Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/open.202000307
intvolume: ' 10'
issue: '2'
keyword:
- General Chemistry
language:
- iso: eng
page: 265-271
publication: ChemistryOpen
publication_identifier:
issn:
- 2191-1363
- 2191-1363
publication_status: published
publisher: Wiley
status: public
title: 'Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights
into Structures and Building Principles'
type: journal_article
user_id: '48467'
volume: 10
year: '2021'
...
---
_id: '41007'
abstract:
- lang: eng
text: Two closely related FeII complexes with 2,6-bis(1-ethyl-1H-1,2,3-triazol-4yl)pyridine
and 2,6-bis(1,2,3-triazol-5-ylidene)pyridine ligands are presented to gain new
insights into the photophysics of bis(tridentate) iron(II) complexes. The [Fe(N^N^N)2]2+
pseudoisomer sensitizes singlet oxygen through a MC state with nanosecond lifetime
after MLCT excitation, while the bis(tridentate) [Fe(C^N^C)2]2+ pseudoisomer possesses
a similar 3MLCT lifetime as the tris(bidentate) [Fe(C^C)2(N^N)]2+ complexes with
four mesoionic carbenes.
article_type: original
author:
- first_name: Philipp
full_name: Dierks, Philipp
last_name: Dierks
- first_name: Ayla
full_name: Kruse, Ayla
last_name: Kruse
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Mohammed J.
full_name: Al-Marri, Mohammed J.
last_name: Al-Marri
- first_name: Jens
full_name: Kalmbach, Jens
last_name: Kalmbach
- first_name: Marc
full_name: Baltrun, Marc
last_name: Baltrun
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
- first_name: Michael
full_name: Seitz, Michael
last_name: Seitz
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Dierks P, Kruse A, Bokareva OS, et al. Distinct photodynamics of κ-N and κ-C
pseudoisomeric iron(ii) complexes. Chemical Communications. 2021;57(54):6640-6643.
doi:10.1039/d1cc01716k
apa: Dierks, P., Kruse, A., Bokareva, O. S., Al-Marri, M. J., Kalmbach, J., Baltrun,
M., Neuba, A., Schoch, R., Hohloch, S., Heinze, K., Seitz, M., Kühn, O., Lochbrunner,
S., & Bauer, M. (2021). Distinct photodynamics of κ-N and κ-C pseudoisomeric
iron(ii) complexes. Chemical Communications, 57(54), 6640–6643.
https://doi.org/10.1039/d1cc01716k
bibtex: '@article{Dierks_Kruse_Bokareva_Al-Marri_Kalmbach_Baltrun_Neuba_Schoch_Hohloch_Heinze_et
al._2021, title={Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii)
complexes}, volume={57}, DOI={10.1039/d1cc01716k},
number={54}, journal={Chemical Communications}, publisher={Royal Society of Chemistry
(RSC)}, author={Dierks, Philipp and Kruse, Ayla and Bokareva, Olga S. and Al-Marri,
Mohammed J. and Kalmbach, Jens and Baltrun, Marc and Neuba, Adam and Schoch, Roland
and Hohloch, Stephan and Heinze, Katja and et al.}, year={2021}, pages={6640–6643}
}'
chicago: 'Dierks, Philipp, Ayla Kruse, Olga S. Bokareva, Mohammed J. Al-Marri, Jens
Kalmbach, Marc Baltrun, Adam Neuba, et al. “Distinct Photodynamics of κ-N and
κ-C Pseudoisomeric Iron(Ii) Complexes.” Chemical Communications 57, no.
54 (2021): 6640–43. https://doi.org/10.1039/d1cc01716k.'
ieee: 'P. Dierks et al., “Distinct photodynamics of κ-N and κ-C pseudoisomeric
iron(ii) complexes,” Chemical Communications, vol. 57, no. 54, pp. 6640–6643,
2021, doi: 10.1039/d1cc01716k.'
mla: Dierks, Philipp, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric
Iron(Ii) Complexes.” Chemical Communications, vol. 57, no. 54, Royal Society
of Chemistry (RSC), 2021, pp. 6640–43, doi:10.1039/d1cc01716k.
short: P. Dierks, A. Kruse, O.S. Bokareva, M.J. Al-Marri, J. Kalmbach, M. Baltrun,
A. Neuba, R. Schoch, S. Hohloch, K. Heinze, M. Seitz, O. Kühn, S. Lochbrunner,
M. Bauer, Chemical Communications 57 (2021) 6640–6643.
date_created: 2023-01-30T16:59:55Z
date_updated: 2024-10-11T08:42:44Z
department:
- _id: '35'
- _id: '306'
doi: 10.1039/d1cc01716k
intvolume: ' 57'
issue: '54'
keyword:
- Materials Chemistry
- Metals and Alloys
- Surfaces
- Coatings and Films
- General Chemistry
- Ceramics and Composite
- Metallkomplexe
- Optical and Magnetic Materials
- Catalysis
language:
- iso: eng
page: 6640-6643
publication: Chemical Communications
publication_identifier:
issn:
- 1359-7345
- 1364-548X
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes
type: journal_article
user_id: '48467'
volume: 57
year: '2021'
...
---
_id: '18534'
author:
- first_name: Yannik
full_name: Vukadinovic, Yannik
last_name: Vukadinovic
- first_name: Lukas
full_name: Burkhardt, Lukas
last_name: Burkhardt
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Anabel
full_name: Miletic, Anabel
last_name: Miletic
- first_name: Lorena
full_name: Fritsch, Lorena
last_name: Fritsch
- first_name: Björn
full_name: Altenburger, Björn
last_name: Altenburger
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
citation:
ama: 'Vukadinovic Y, Burkhardt L, Päpcke A, et al. When Donors Turn into Acceptors:
Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate
Bis-imidazole-2-ylidene Pyridine Ligands. Inorganic Chemistry. 2020:8762-8774.
doi:10.1021/acs.inorgchem.0c00393'
apa: 'Vukadinovic, Y., Burkhardt, L., Päpcke, A., Miletic, A., Fritsch, L., Altenburger,
B., … Bauer, M. (2020). When Donors Turn into Acceptors: Ground and Excited State
Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene
Pyridine Ligands. Inorganic Chemistry, 8762–8774. https://doi.org/10.1021/acs.inorgchem.0c00393'
bibtex: '@article{Vukadinovic_Burkhardt_Päpcke_Miletic_Fritsch_Altenburger_Schoch_Neuba_Lochbrunner_Bauer_2020,
title={When Donors Turn into Acceptors: Ground and Excited State Properties of
FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine
Ligands}, DOI={10.1021/acs.inorgchem.0c00393},
journal={Inorganic Chemistry}, author={Vukadinovic, Yannik and Burkhardt, Lukas
and Päpcke, Ayla and Miletic, Anabel and Fritsch, Lorena and Altenburger, Björn
and Schoch, Roland and Neuba, Adam and Lochbrunner, Stefan and Bauer, Matthias},
year={2020}, pages={8762–8774} }'
chicago: 'Vukadinovic, Yannik, Lukas Burkhardt, Ayla Päpcke, Anabel Miletic, Lorena
Fritsch, Björn Altenburger, Roland Schoch, Adam Neuba, Stefan Lochbrunner, and
Matthias Bauer. “When Donors Turn into Acceptors: Ground and Excited State Properties
of FeII Complexes with Amine-Substituted Tridentate Bis-Imidazole-2-Ylidene Pyridine
Ligands.” Inorganic Chemistry, 2020, 8762–74. https://doi.org/10.1021/acs.inorgchem.0c00393.'
ieee: 'Y. Vukadinovic et al., “When Donors Turn into Acceptors: Ground and
Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene
Pyridine Ligands,” Inorganic Chemistry, pp. 8762–8774, 2020.'
mla: 'Vukadinovic, Yannik, et al. “When Donors Turn into Acceptors: Ground and Excited
State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-Imidazole-2-Ylidene
Pyridine Ligands.” Inorganic Chemistry, 2020, pp. 8762–74, doi:10.1021/acs.inorgchem.0c00393.'
short: Y. Vukadinovic, L. Burkhardt, A. Päpcke, A. Miletic, L. Fritsch, B. Altenburger,
R. Schoch, A. Neuba, S. Lochbrunner, M. Bauer, Inorganic Chemistry (2020) 8762–8774.
date_created: 2020-08-28T09:08:09Z
date_updated: 2022-01-06T06:53:36Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.0c00393
language:
- iso: eng
page: 8762-8774
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: 'When Donors Turn into Acceptors: Ground and Excited State Properties of FeII
Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands'
type: journal_article
user_id: '54038'
year: '2020'
...
---
_id: '41022'
author:
- first_name: Manuel
full_name: Kirchhof, Manuel
last_name: Kirchhof
- first_name: Katrin
full_name: Gugeler, Katrin
last_name: Gugeler
- first_name: Felix Richard
full_name: Fischer, Felix Richard
last_name: Fischer
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Alina
full_name: Bauer, Alina
last_name: Bauer
- first_name: Sonia
full_name: Alvarez-Barcia, Sonia
last_name: Alvarez-Barcia
- first_name: Karina
full_name: Abitaev, Karina
last_name: Abitaev
- first_name: Marc
full_name: Schnierle, Marc
last_name: Schnierle
- first_name: Yaseen
full_name: Qawasmi, Yaseen
last_name: Qawasmi
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Angelika
full_name: Baro, Angelika
last_name: Baro
- first_name: Deven P.
full_name: Estes, Deven P.
last_name: Estes
- first_name: Thomas
full_name: Sottmann, Thomas
last_name: Sottmann
- first_name: Mark R.
full_name: Ringenberg, Mark R.
last_name: Ringenberg
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Sabine
full_name: Laschat, Sabine
last_name: Laschat
citation:
ama: Kirchhof M, Gugeler K, Fischer FR, et al. Experimental and Theoretical Study
on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes
in Catalytic Asymmetric 1,2- and 1,4-Additions. Organometallics. 2020;39(17):3131-3145.
doi:10.1021/acs.organomet.0c00310
apa: Kirchhof, M., Gugeler, K., Fischer, F. R., Nowakowski, M., Bauer, A., Alvarez-Barcia,
S., Abitaev, K., Schnierle, M., Qawasmi, Y., Frey, W., Baro, A., Estes, D. P.,
Sottmann, T., Ringenberg, M. R., Plietker, B., Bauer, M., Kästner, J., & Laschat,
S. (2020). Experimental and Theoretical Study on the Role of Monomeric vs Dimeric
Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and
1,4-Additions. Organometallics, 39(17), 3131–3145. https://doi.org/10.1021/acs.organomet.0c00310
bibtex: '@article{Kirchhof_Gugeler_Fischer_Nowakowski_Bauer_Alvarez-Barcia_Abitaev_Schnierle_Qawasmi_Frey_et
al._2020, title={Experimental and Theoretical Study on the Role of Monomeric vs
Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric
1,2- and 1,4-Additions}, volume={39}, DOI={10.1021/acs.organomet.0c00310},
number={17}, journal={Organometallics}, publisher={American Chemical Society (ACS)},
author={Kirchhof, Manuel and Gugeler, Katrin and Fischer, Felix Richard and Nowakowski,
Michał and Bauer, Alina and Alvarez-Barcia, Sonia and Abitaev, Karina and Schnierle,
Marc and Qawasmi, Yaseen and Frey, Wolfgang and et al.}, year={2020}, pages={3131–3145}
}'
chicago: 'Kirchhof, Manuel, Katrin Gugeler, Felix Richard Fischer, Michał Nowakowski,
Alina Bauer, Sonia Alvarez-Barcia, Karina Abitaev, et al. “Experimental and Theoretical
Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene
Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions.” Organometallics
39, no. 17 (2020): 3131–45. https://doi.org/10.1021/acs.organomet.0c00310.'
ieee: 'M. Kirchhof et al., “Experimental and Theoretical Study on the Role
of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic
Asymmetric 1,2- and 1,4-Additions,” Organometallics, vol. 39, no. 17, pp.
3131–3145, 2020, doi: 10.1021/acs.organomet.0c00310.'
mla: Kirchhof, Manuel, et al. “Experimental and Theoretical Study on the Role of
Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic
Asymmetric 1,2- and 1,4-Additions.” Organometallics, vol. 39, no. 17, American
Chemical Society (ACS), 2020, pp. 3131–45, doi:10.1021/acs.organomet.0c00310.
short: M. Kirchhof, K. Gugeler, F.R. Fischer, M. Nowakowski, A. Bauer, S. Alvarez-Barcia,
K. Abitaev, M. Schnierle, Y. Qawasmi, W. Frey, A. Baro, D.P. Estes, T. Sottmann,
M.R. Ringenberg, B. Plietker, M. Bauer, J. Kästner, S. Laschat, Organometallics
39 (2020) 3131–3145.
date_created: 2023-01-30T17:37:18Z
date_updated: 2024-05-07T11:41:01Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.organomet.0c00310
intvolume: ' 39'
issue: '17'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 3131-3145
publication: Organometallics
publication_identifier:
issn:
- 0276-7333
- 1520-6041
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium
Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions
type: journal_article
user_id: '48467'
volume: 39
year: '2020'
...
---
_id: '41015'
author:
- first_name: Mathis
full_name: Benedikter, Mathis
last_name: Benedikter
- first_name: Janis
full_name: Musso, Janis
last_name: Musso
- first_name: Manoj K.
full_name: Kesharwani, Manoj K.
last_name: Kesharwani
- first_name: K. Leonard
full_name: Sterz, K. Leonard
last_name: Sterz
- first_name: Iris
full_name: Elser, Iris
last_name: Elser
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Felix
full_name: Fischer, Felix
last_name: Fischer
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Mario
full_name: Winkler, Mario
last_name: Winkler
- first_name: Joris
full_name: van Slageren, Joris
last_name: van Slageren
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: 'Benedikter M, Musso J, Kesharwani MK, et al. Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis.
2020;10(24):14810-14823. doi:10.1021/acscatal.0c03978'
apa: 'Benedikter, M., Musso, J., Kesharwani, M. K., Sterz, K. L., Elser, I., Ziegler,
F., Fischer, F., Plietker, B., Frey, W., Kästner, J., Winkler, M., van Slageren,
J., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2020). Charge Distribution
in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes:
A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis,
10(24), 14810–14823. https://doi.org/10.1021/acscatal.0c03978'
bibtex: '@article{Benedikter_Musso_Kesharwani_Sterz_Elser_Ziegler_Fischer_Plietker_Frey_Kästner_et
al._2020, title={Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach},
volume={10}, DOI={10.1021/acscatal.0c03978},
number={24}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz,
K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker,
Bernd and Frey, Wolfgang and Kästner, Johannes and et al.}, year={2020}, pages={14810–14823}
}'
chicago: 'Benedikter, Mathis, Janis Musso, Manoj K. Kesharwani, K. Leonard Sterz,
Iris Elser, Felix Ziegler, Felix Fischer, et al. “Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis
10, no. 24 (2020): 14810–23. https://doi.org/10.1021/acscatal.0c03978.'
ieee: 'M. Benedikter et al., “Charge Distribution in Cationic Molybdenum
Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS,
XES, DFT, Mössbauer, and Catalysis Approach,” ACS Catalysis, vol. 10, no.
24, pp. 14810–14823, 2020, doi: 10.1021/acscatal.0c03978.'
mla: 'Benedikter, Mathis, et al. “Charge Distribution in Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES,
DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis, vol. 10, no. 24,
American Chemical Society (ACS), 2020, pp. 14810–23, doi:10.1021/acscatal.0c03978.'
short: M. Benedikter, J. Musso, M.K. Kesharwani, K.L. Sterz, I. Elser, F. Ziegler,
F. Fischer, B. Plietker, W. Frey, J. Kästner, M. Winkler, J. van Slageren, M.
Nowakowski, M. Bauer, M.R. Buchmeiser, ACS Catalysis 10 (2020) 14810–14823.
date_created: 2023-01-30T17:12:11Z
date_updated: 2024-05-07T11:42:56Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acscatal.0c03978
intvolume: ' 10'
issue: '24'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 14810-14823
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach'
type: journal_article
user_id: '48467'
volume: 10
year: '2020'
...
---
_id: '41020'
author:
- first_name: Bernhard J.
full_name: Gregori, Bernhard J.
last_name: Gregori
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Anke
full_name: Schoch, Anke
id: '27611'
last_name: Schoch
orcid: 0000-0002-9457-400X
- first_name: Simon
full_name: Pöllath, Simon
last_name: Pöllath
- first_name: Josef
full_name: Zweck, Josef
last_name: Zweck
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Axel
full_name: Jacobi von Wangelin, Axel
last_name: Jacobi von Wangelin
citation:
ama: Gregori BJ, Nowakowski M, Schoch A, et al. Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes. ChemCatChem. 2020;12(21):5359-5363. doi:10.1002/cctc.202000994
apa: Gregori, B. J., Nowakowski, M., Schoch, A., Pöllath, S., Zweck, J., Bauer,
M., & Jacobi von Wangelin, A. (2020). Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes. ChemCatChem, 12(21), 5359–5363. https://doi.org/10.1002/cctc.202000994
bibtex: '@article{Gregori_Nowakowski_Schoch_Pöllath_Zweck_Bauer_Jacobi von Wangelin_2020,
title={Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}, volume={12},
DOI={10.1002/cctc.202000994},
number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Gregori, Bernhard
J. and Nowakowski, Michał and Schoch, Anke and Pöllath, Simon and Zweck, Josef
and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2020}, pages={5359–5363}
}'
chicago: 'Gregori, Bernhard J., Michał Nowakowski, Anke Schoch, Simon Pöllath, Josef
Zweck, Matthias Bauer, and Axel Jacobi von Wangelin. “Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes.” ChemCatChem 12, no. 21 (2020): 5359–63.
https://doi.org/10.1002/cctc.202000994.'
ieee: 'B. J. Gregori et al., “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes,” ChemCatChem, vol. 12, no. 21, pp. 5359–5363, 2020, doi: 10.1002/cctc.202000994.'
mla: Gregori, Bernhard J., et al. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes.” ChemCatChem, vol. 12, no. 21, Wiley, 2020, pp. 5359–63, doi:10.1002/cctc.202000994.
short: B.J. Gregori, M. Nowakowski, A. Schoch, S. Pöllath, J. Zweck, M. Bauer, A.
Jacobi von Wangelin, ChemCatChem 12 (2020) 5359–5363.
date_created: 2023-01-30T17:35:14Z
date_updated: 2024-05-07T11:40:10Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/cctc.202000994
intvolume: ' 12'
issue: '21'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
page: 5359-5363
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes
type: journal_article
user_id: '48467'
volume: 12
year: '2020'
...
---
_id: '16311'
author:
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Yannik
full_name: Vukadinovic, Yannik
last_name: Vukadinovic
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Julian
full_name: Rudolph, Julian
last_name: Rudolph
- first_name: Per-Anders
full_name: Carlsson, Per-Anders
last_name: Carlsson
- first_name: Christoph R.
full_name: Jacob, Christoph R.
last_name: Jacob
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Burkhardt L, Vukadinovic Y, Nowakowski M, et al. Electronic Structure of the
Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy.
Inorganic Chemistry. Published online 2020:3551-3561. doi:10.1021/acs.inorgchem.9b02092
apa: Burkhardt, L., Vukadinovic, Y., Nowakowski, M., Kalinko, A., Rudolph, J., Carlsson,
P.-A., Jacob, C. R., & Bauer, M. (2020). Electronic Structure of the Hieber
Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy.
Inorganic Chemistry, 3551–3561. https://doi.org/10.1021/acs.inorgchem.9b02092
bibtex: '@article{Burkhardt_Vukadinovic_Nowakowski_Kalinko_Rudolph_Carlsson_Jacob_Bauer_2020,
title={Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray
Emission and Absorption Spectroscopy}, DOI={10.1021/acs.inorgchem.9b02092},
journal={Inorganic Chemistry}, author={Burkhardt, Lukas and Vukadinovic, Yannik
and Nowakowski, Michał and Kalinko, Aleksandr and Rudolph, Julian and Carlsson,
Per-Anders and Jacob, Christoph R. and Bauer, Matthias}, year={2020}, pages={3551–3561}
}'
chicago: Burkhardt, Lukas, Yannik Vukadinovic, Michał Nowakowski, Aleksandr Kalinko,
Julian Rudolph, Per-Anders Carlsson, Christoph R. Jacob, and Matthias Bauer. “Electronic
Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-Ray Emission and Absorption
Spectroscopy.” Inorganic Chemistry, 2020, 3551–61. https://doi.org/10.1021/acs.inorgchem.9b02092.
ieee: 'L. Burkhardt et al., “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]−
Revisited by X-ray Emission and Absorption Spectroscopy,” Inorganic Chemistry,
pp. 3551–3561, 2020, doi: 10.1021/acs.inorgchem.9b02092.'
mla: Burkhardt, Lukas, et al. “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]−
Revisited by X-Ray Emission and Absorption Spectroscopy.” Inorganic Chemistry,
2020, pp. 3551–61, doi:10.1021/acs.inorgchem.9b02092.
short: L. Burkhardt, Y. Vukadinovic, M. Nowakowski, A. Kalinko, J. Rudolph, P.-A.
Carlsson, C.R. Jacob, M. Bauer, Inorganic Chemistry (2020) 3551–3561.
date_created: 2020-03-23T10:38:47Z
date_updated: 2024-05-07T11:44:33Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.9b02092
language:
- iso: eng
page: 3551-3561
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray
Emission and Absorption Spectroscopy
type: journal_article
user_id: '48467'
year: '2020'
...
---
_id: '41005'
author:
- first_name: Yannik
full_name: Vukadinovic, Yannik
last_name: Vukadinovic
citation:
ama: Vukadinovic Y. N-Heterocyclic Carbene Based Iron and Ruthenium Photosensitizer
with Amine Donors - A Systematic Study on Spectroscopic Differences.; 2020.
doi:10.17619/UNIPB/1-1060
apa: Vukadinovic, Y. (2020). N-heterocyclic carbene based iron and ruthenium
photosensitizer with amine donors - A systematic study on spectroscopic differences.
https://doi.org/10.17619/UNIPB/1-1060
bibtex: '@book{Vukadinovic_2020, title={N-heterocyclic carbene based iron and ruthenium
photosensitizer with amine donors - A systematic study on spectroscopic differences},
DOI={10.17619/UNIPB/1-1060},
author={Vukadinovic, Yannik}, year={2020} }'
chicago: Vukadinovic, Yannik. N-Heterocyclic Carbene Based Iron and Ruthenium
Photosensitizer with Amine Donors - A Systematic Study on Spectroscopic Differences,
2020. https://doi.org/10.17619/UNIPB/1-1060.
ieee: Y. Vukadinovic, N-heterocyclic carbene based iron and ruthenium photosensitizer
with amine donors - A systematic study on spectroscopic differences. 2020.
mla: Vukadinovic, Yannik. N-Heterocyclic Carbene Based Iron and Ruthenium Photosensitizer
with Amine Donors - A Systematic Study on Spectroscopic Differences. 2020,
doi:10.17619/UNIPB/1-1060.
short: Y. Vukadinovic, N-Heterocyclic Carbene Based Iron and Ruthenium Photosensitizer
with Amine Donors - A Systematic Study on Spectroscopic Differences, 2020.
date_created: 2023-01-30T16:58:21Z
date_updated: 2023-01-31T08:18:58Z
department:
- _id: '35'
- _id: '306'
doi: 10.17619/UNIPB/1-1060
language:
- iso: eng
status: public
supervisor:
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
title: N-heterocyclic carbene based iron and ruthenium photosensitizer with amine
donors - A systematic study on spectroscopic differences
type: dissertation
user_id: '27611'
year: '2020'
...
---
_id: '41018'
author:
- first_name: Philipp
full_name: Dierks, Philipp
last_name: Dierks
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Björn
full_name: Altenburger, Björn
last_name: Altenburger
- first_name: Thomas
full_name: Reuter, Thomas
last_name: Reuter
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Dierks P, Päpcke A, Bokareva OS, et al. Ground- and Excited-State Properties
of Iron(II) Complexes Linked to Organic Chromophores. Inorganic Chemistry.
2020;59(20):14746-14761. doi:10.1021/acs.inorgchem.0c02039
apa: Dierks, P., Päpcke, A., Bokareva, O. S., Altenburger, B., Reuter, T., Heinze,
K., Kühn, O., Lochbrunner, S., & Bauer, M. (2020). Ground- and Excited-State
Properties of Iron(II) Complexes Linked to Organic Chromophores. Inorganic
Chemistry, 59(20), 14746–14761. https://doi.org/10.1021/acs.inorgchem.0c02039
bibtex: '@article{Dierks_Päpcke_Bokareva_Altenburger_Reuter_Heinze_Kühn_Lochbrunner_Bauer_2020,
title={Ground- and Excited-State Properties of Iron(II) Complexes Linked to Organic
Chromophores}, volume={59}, DOI={10.1021/acs.inorgchem.0c02039},
number={20}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Dierks, Philipp and Päpcke, Ayla and Bokareva, Olga S. and Altenburger,
Björn and Reuter, Thomas and Heinze, Katja and Kühn, Oliver and Lochbrunner, Stefan
and Bauer, Matthias}, year={2020}, pages={14746–14761} }'
chicago: 'Dierks, Philipp, Ayla Päpcke, Olga S. Bokareva, Björn Altenburger, Thomas
Reuter, Katja Heinze, Oliver Kühn, Stefan Lochbrunner, and Matthias Bauer. “Ground-
and Excited-State Properties of Iron(II) Complexes Linked to Organic Chromophores.”
Inorganic Chemistry 59, no. 20 (2020): 14746–61. https://doi.org/10.1021/acs.inorgchem.0c02039.'
ieee: 'P. Dierks et al., “Ground- and Excited-State Properties of Iron(II)
Complexes Linked to Organic Chromophores,” Inorganic Chemistry, vol. 59,
no. 20, pp. 14746–14761, 2020, doi: 10.1021/acs.inorgchem.0c02039.'
mla: Dierks, Philipp, et al. “Ground- and Excited-State Properties of Iron(II) Complexes
Linked to Organic Chromophores.” Inorganic Chemistry, vol. 59, no. 20,
American Chemical Society (ACS), 2020, pp. 14746–61, doi:10.1021/acs.inorgchem.0c02039.
short: P. Dierks, A. Päpcke, O.S. Bokareva, B. Altenburger, T. Reuter, K. Heinze,
O. Kühn, S. Lochbrunner, M. Bauer, Inorganic Chemistry 59 (2020) 14746–14761.
date_created: 2023-01-30T17:33:28Z
date_updated: 2023-01-31T08:22:04Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.0c02039
intvolume: ' 59'
issue: '20'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 14746-14761
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Ground- and Excited-State Properties of Iron(II) Complexes Linked to Organic
Chromophores
type: journal_article
user_id: '27611'
volume: 59
year: '2020'
...
---
_id: '41023'
abstract:
- lang: eng
text: AbstractEfficient oxygen evolution reaction
(OER) electrocatalysts are pivotal for sustainable fuel production, where the
Ni-Fe oxyhydroxide (OOH) is among the most active catalysts for alkaline OER.
Electrolyte alkali metal cations have been shown to modify the activity and reaction
intermediates, however, the exact mechanism is at question due to unexplained
deviations from the cation size trend. Our X-ray absorption spectroelectrochemical
results show that bigger cations shift the Ni2+/(3+δ)+ redox
peak and OER activity to lower potentials (however, with typical discrepancies),
following the order CsOH > NaOH ≈ KOH > RbOH > LiOH. Here, we find that
the OER activity follows the variations in electrolyte pH rather than a specific
cation, which accounts for differences both in basicity of the alkali hydroxides
and other contributing anomalies. Our density functional theory-derived reactivity
descriptors confirm that cations impose negligible effect on the Lewis acidity
of Ni, Fe, and O lattice sites, thus strengthening the conclusions of an indirect
pH effect.
article_number: '6181'
author:
- first_name: Mikaela
full_name: Görlin, Mikaela
last_name: Görlin
- first_name: Joakim
full_name: Halldin Stenlid, Joakim
last_name: Halldin Stenlid
- first_name: Sergey
full_name: Koroidov, Sergey
last_name: Koroidov
- first_name: Hsin-Yi
full_name: Wang, Hsin-Yi
last_name: Wang
- first_name: Mia
full_name: Börner, Mia
last_name: Börner
- first_name: Mikhail
full_name: Shipilin, Mikhail
last_name: Shipilin
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Vadim
full_name: Murzin, Vadim
last_name: Murzin
- first_name: Olga V.
full_name: Safonova, Olga V.
last_name: Safonova
- first_name: Maarten
full_name: Nachtegaal, Maarten
last_name: Nachtegaal
- first_name: Abdusalam
full_name: Uheida, Abdusalam
last_name: Uheida
- first_name: Joydeep
full_name: Dutta, Joydeep
last_name: Dutta
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Anders
full_name: Nilsson, Anders
last_name: Nilsson
- first_name: Oscar
full_name: Diaz-Morales, Oscar
last_name: Diaz-Morales
citation:
ama: Görlin M, Halldin Stenlid J, Koroidov S, et al. Key activity descriptors of
nickel-iron oxygen evolution electrocatalysts in the presence of alkali metal
cations. Nature Communications. 2020;11(1). doi:10.1038/s41467-020-19729-2
apa: Görlin, M., Halldin Stenlid, J., Koroidov, S., Wang, H.-Y., Börner, M., Shipilin,
M., Kalinko, A., Murzin, V., Safonova, O. V., Nachtegaal, M., Uheida, A., Dutta,
J., Bauer, M., Nilsson, A., & Diaz-Morales, O. (2020). Key activity descriptors
of nickel-iron oxygen evolution electrocatalysts in the presence of alkali metal
cations. Nature Communications, 11(1), Article 6181. https://doi.org/10.1038/s41467-020-19729-2
bibtex: '@article{Görlin_Halldin Stenlid_Koroidov_Wang_Börner_Shipilin_Kalinko_Murzin_Safonova_Nachtegaal_et
al._2020, title={Key activity descriptors of nickel-iron oxygen evolution electrocatalysts
in the presence of alkali metal cations}, volume={11}, DOI={10.1038/s41467-020-19729-2},
number={16181}, journal={Nature Communications}, publisher={Springer Science and
Business Media LLC}, author={Görlin, Mikaela and Halldin Stenlid, Joakim and Koroidov,
Sergey and Wang, Hsin-Yi and Börner, Mia and Shipilin, Mikhail and Kalinko, Aleksandr
and Murzin, Vadim and Safonova, Olga V. and Nachtegaal, Maarten and et al.}, year={2020}
}'
chicago: Görlin, Mikaela, Joakim Halldin Stenlid, Sergey Koroidov, Hsin-Yi Wang,
Mia Börner, Mikhail Shipilin, Aleksandr Kalinko, et al. “Key Activity Descriptors
of Nickel-Iron Oxygen Evolution Electrocatalysts in the Presence of Alkali Metal
Cations.” Nature Communications 11, no. 1 (2020). https://doi.org/10.1038/s41467-020-19729-2.
ieee: 'M. Görlin et al., “Key activity descriptors of nickel-iron oxygen
evolution electrocatalysts in the presence of alkali metal cations,” Nature
Communications, vol. 11, no. 1, Art. no. 6181, 2020, doi: 10.1038/s41467-020-19729-2.'
mla: Görlin, Mikaela, et al. “Key Activity Descriptors of Nickel-Iron Oxygen Evolution
Electrocatalysts in the Presence of Alkali Metal Cations.” Nature Communications,
vol. 11, no. 1, 6181, Springer Science and Business Media LLC, 2020, doi:10.1038/s41467-020-19729-2.
short: M. Görlin, J. Halldin Stenlid, S. Koroidov, H.-Y. Wang, M. Börner, M. Shipilin,
A. Kalinko, V. Murzin, O.V. Safonova, M. Nachtegaal, A. Uheida, J. Dutta, M. Bauer,
A. Nilsson, O. Diaz-Morales, Nature Communications 11 (2020).
date_created: 2023-01-30T17:38:28Z
date_updated: 2023-01-31T08:23:48Z
department:
- _id: '35'
- _id: '306'
doi: 10.1038/s41467-020-19729-2
intvolume: ' 11'
issue: '1'
keyword:
- General Physics and Astronomy
- General Biochemistry
- Genetics and Molecular Biology
- General Chemistry
- Multidisciplinary
language:
- iso: eng
publication: Nature Communications
publication_identifier:
issn:
- 2041-1723
publication_status: published
publisher: Springer Science and Business Media LLC
status: public
title: Key activity descriptors of nickel-iron oxygen evolution electrocatalysts in
the presence of alkali metal cations
type: journal_article
user_id: '27611'
volume: 11
year: '2020'
...
---
_id: '41024'
article_number: '034101'
author:
- first_name: Jure
full_name: Gujt, Jure
last_name: Gujt
- first_name: Peter
full_name: Zimmer, Peter
last_name: Zimmer
- first_name: Frederik
full_name: Zysk, Frederik
id: '14757'
last_name: Zysk
- first_name: Vicky
full_name: Süß, Vicky
last_name: Süß
- first_name: Claudia
full_name: Felser, Claudia
last_name: Felser
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Thomas
full_name: Kühne, Thomas
id: '49079'
last_name: Kühne
citation:
ama: Gujt J, Zimmer P, Zysk F, et al. Water structure near the surface of Weyl semimetals
as catalysts in photocatalytic proton reduction. Structural Dynamics. 2020;7(3).
doi:10.1063/4.0000008
apa: Gujt, J., Zimmer, P., Zysk, F., Süß, V., Felser, C., Bauer, M., & Kühne,
T. (2020). Water structure near the surface of Weyl semimetals as catalysts in
photocatalytic proton reduction. Structural Dynamics, 7(3), Article
034101. https://doi.org/10.1063/4.0000008
bibtex: '@article{Gujt_Zimmer_Zysk_Süß_Felser_Bauer_Kühne_2020, title={Water structure
near the surface of Weyl semimetals as catalysts in photocatalytic proton reduction},
volume={7}, DOI={10.1063/4.0000008},
number={3034101}, journal={Structural Dynamics}, publisher={AIP Publishing}, author={Gujt,
Jure and Zimmer, Peter and Zysk, Frederik and Süß, Vicky and Felser, Claudia and
Bauer, Matthias and Kühne, Thomas}, year={2020} }'
chicago: Gujt, Jure, Peter Zimmer, Frederik Zysk, Vicky Süß, Claudia Felser, Matthias
Bauer, and Thomas Kühne. “Water Structure near the Surface of Weyl Semimetals
as Catalysts in Photocatalytic Proton Reduction.” Structural Dynamics 7,
no. 3 (2020). https://doi.org/10.1063/4.0000008.
ieee: 'J. Gujt et al., “Water structure near the surface of Weyl semimetals
as catalysts in photocatalytic proton reduction,” Structural Dynamics,
vol. 7, no. 3, Art. no. 034101, 2020, doi: 10.1063/4.0000008.'
mla: Gujt, Jure, et al. “Water Structure near the Surface of Weyl Semimetals as
Catalysts in Photocatalytic Proton Reduction.” Structural Dynamics, vol.
7, no. 3, 034101, AIP Publishing, 2020, doi:10.1063/4.0000008.
short: J. Gujt, P. Zimmer, F. Zysk, V. Süß, C. Felser, M. Bauer, T. Kühne, Structural
Dynamics 7 (2020).
date_created: 2023-01-30T17:40:53Z
date_updated: 2023-01-31T08:23:35Z
department:
- _id: '35'
- _id: '306'
doi: 10.1063/4.0000008
intvolume: ' 7'
issue: '3'
keyword:
- Spectroscopy
- Condensed Matter Physics
- Instrumentation
- Radiation
language:
- iso: eng
publication: Structural Dynamics
publication_identifier:
issn:
- 2329-7778
publication_status: published
publisher: AIP Publishing
status: public
title: Water structure near the surface of Weyl semimetals as catalysts in photocatalytic
proton reduction
type: journal_article
user_id: '27611'
volume: 7
year: '2020'
...
---
_id: '41027'
abstract:
- lang: eng
text: AbstractFluoride ion batteries (FIBs) are
a recent alternative all-solid-state battery technology. However, the FIB systems
proposed so far suffer from poor cycling performance. In this work, we report
La2NiO4.13 with a Ruddlesden-Popper
type structure as an intercalation-based active cathode material in all solid-state
FIB with excellent cycling performance. The critical charging conditions to maintain
the conductivity of the cell were determined, which seems to be a major obstacle
towards improving the cycling stability of FIBs. For optimized operating conditions,
a cycle life of about 60 cycles and over 220 cycles for critical cut-off capacities
of 50 mAh/g and 30 mAh/g, respectively, could be achieved, with average Coulombic
efficiencies between 95 – 99%. Cycling of the cell is a result of fluorination/de-fluorination
into and from the La2NiO4+d cathode,
and it is revealed that La2NiO4.13 is
a multivalent electrode material. Our findings suggest that La2NiO4.13
is a promising high energy cathode for FIBs.
article_number: '27'
author:
- first_name: Mohammad Ali
full_name: Nowroozi, Mohammad Ali
last_name: Nowroozi
- first_name: Kerstin
full_name: Wissel, Kerstin
last_name: Wissel
- first_name: Manuel
full_name: Donzelli, Manuel
last_name: Donzelli
- first_name: Niloofar
full_name: Hosseinpourkahvaz, Niloofar
last_name: Hosseinpourkahvaz
- first_name: Sergi
full_name: Plana-Ruiz, Sergi
last_name: Plana-Ruiz
- first_name: Ute
full_name: Kolb, Ute
last_name: Kolb
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
- first_name: Ali Muhammad
full_name: Malik, Ali Muhammad
last_name: Malik
- first_name: Jochen
full_name: Rohrer, Jochen
last_name: Rohrer
- first_name: Sergei
full_name: Ivlev, Sergei
last_name: Ivlev
- first_name: Florian
full_name: Kraus, Florian
last_name: Kraus
- first_name: Oliver
full_name: Clemens, Oliver
last_name: Clemens
citation:
ama: Nowroozi MA, Wissel K, Donzelli M, et al. High cycle life all-solid-state fluoride
ion battery with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub>
high voltage cathode. Communications Materials. 2020;1(1). doi:10.1038/s43246-020-0030-5
apa: Nowroozi, M. A., Wissel, K., Donzelli, M., Hosseinpourkahvaz, N., Plana-Ruiz,
S., Kolb, U., Schoch, R., Bauer, M., Malik, A. M., Rohrer, J., Ivlev, S., Kraus,
F., & Clemens, O. (2020). High cycle life all-solid-state fluoride ion battery
with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub>
high voltage cathode. Communications Materials, 1(1), Article 27.
https://doi.org/10.1038/s43246-020-0030-5
bibtex: '@article{Nowroozi_Wissel_Donzelli_Hosseinpourkahvaz_Plana-Ruiz_Kolb_Schoch_Bauer_Malik_Rohrer_et
al._2020, title={High cycle life all-solid-state fluoride ion battery with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub>
high voltage cathode}, volume={1}, DOI={10.1038/s43246-020-0030-5},
number={127}, journal={Communications Materials}, publisher={Springer Science
and Business Media LLC}, author={Nowroozi, Mohammad Ali and Wissel, Kerstin and
Donzelli, Manuel and Hosseinpourkahvaz, Niloofar and Plana-Ruiz, Sergi and Kolb,
Ute and Schoch, Roland and Bauer, Matthias and Malik, Ali Muhammad and Rohrer,
Jochen and et al.}, year={2020} }'
chicago: Nowroozi, Mohammad Ali, Kerstin Wissel, Manuel Donzelli, Niloofar Hosseinpourkahvaz,
Sergi Plana-Ruiz, Ute Kolb, Roland Schoch, et al. “High Cycle Life All-Solid-State
Fluoride Ion Battery with La<jats:Sub>2</Jats:Sub>NiO<jats:Sub>4+d</Jats:Sub>
High Voltage Cathode.” Communications Materials 1, no. 1 (2020). https://doi.org/10.1038/s43246-020-0030-5.
ieee: 'M. A. Nowroozi et al., “High cycle life all-solid-state fluoride ion
battery with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub>
high voltage cathode,” Communications Materials, vol. 1, no. 1, Art. no.
27, 2020, doi: 10.1038/s43246-020-0030-5.'
mla: Nowroozi, Mohammad Ali, et al. “High Cycle Life All-Solid-State Fluoride Ion
Battery with La<jats:Sub>2</Jats:Sub>NiO<jats:Sub>4+d</Jats:Sub>
High Voltage Cathode.” Communications Materials, vol. 1, no. 1, 27, Springer
Science and Business Media LLC, 2020, doi:10.1038/s43246-020-0030-5.
short: M.A. Nowroozi, K. Wissel, M. Donzelli, N. Hosseinpourkahvaz, S. Plana-Ruiz,
U. Kolb, R. Schoch, M. Bauer, A.M. Malik, J. Rohrer, S. Ivlev, F. Kraus, O. Clemens,
Communications Materials 1 (2020).
date_created: 2023-01-30T17:49:27Z
date_updated: 2023-01-31T07:45:41Z
department:
- _id: '35'
- _id: '306'
doi: 10.1038/s43246-020-0030-5
intvolume: ' 1'
issue: '1'
keyword:
- Mechanics of Materials
- General Materials Science
language:
- iso: eng
publication: Communications Materials
publication_identifier:
issn:
- 2662-4443
publication_status: published
publisher: Springer Science and Business Media LLC
status: public
title: High cycle life all-solid-state fluoride ion battery with La2NiO4+d
high voltage cathode
type: journal_article
user_id: '48467'
volume: 1
year: '2020'
...
---
_id: '41019'
author:
- first_name: J. Patrick
full_name: Zobel, J. Patrick
last_name: Zobel
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Peter
full_name: Zimmer, Peter
last_name: Zimmer
- first_name: Christoph
full_name: Wölper, Christoph
last_name: Wölper
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Leticia
full_name: González, Leticia
last_name: González
citation:
ama: Zobel JP, Bokareva OS, Zimmer P, Wölper C, Bauer M, González L. Intersystem
Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene Photosensitizer.
Inorganic Chemistry. 2020;59(20):14666-14678. doi:10.1021/acs.inorgchem.0c02147
apa: Zobel, J. P., Bokareva, O. S., Zimmer, P., Wölper, C., Bauer, M., & González,
L. (2020). Intersystem Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic
Carbene Photosensitizer. Inorganic Chemistry, 59(20), 14666–14678.
https://doi.org/10.1021/acs.inorgchem.0c02147
bibtex: '@article{Zobel_Bokareva_Zimmer_Wölper_Bauer_González_2020, title={Intersystem
Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene Photosensitizer},
volume={59}, DOI={10.1021/acs.inorgchem.0c02147},
number={20}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Zobel, J. Patrick and Bokareva, Olga S. and Zimmer, Peter and
Wölper, Christoph and Bauer, Matthias and González, Leticia}, year={2020}, pages={14666–14678}
}'
chicago: 'Zobel, J. Patrick, Olga S. Bokareva, Peter Zimmer, Christoph Wölper, Matthias
Bauer, and Leticia González. “Intersystem Crossing and Triplet Dynamics in an
Iron(II) N-Heterocyclic Carbene Photosensitizer.” Inorganic Chemistry 59,
no. 20 (2020): 14666–78. https://doi.org/10.1021/acs.inorgchem.0c02147.'
ieee: 'J. P. Zobel, O. S. Bokareva, P. Zimmer, C. Wölper, M. Bauer, and L. González,
“Intersystem Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene
Photosensitizer,” Inorganic Chemistry, vol. 59, no. 20, pp. 14666–14678,
2020, doi: 10.1021/acs.inorgchem.0c02147.'
mla: Zobel, J. Patrick, et al. “Intersystem Crossing and Triplet Dynamics in an
Iron(II) N-Heterocyclic Carbene Photosensitizer.” Inorganic Chemistry,
vol. 59, no. 20, American Chemical Society (ACS), 2020, pp. 14666–78, doi:10.1021/acs.inorgchem.0c02147.
short: J.P. Zobel, O.S. Bokareva, P. Zimmer, C. Wölper, M. Bauer, L. González, Inorganic
Chemistry 59 (2020) 14666–14678.
date_created: 2023-01-30T17:34:21Z
date_updated: 2023-01-31T08:21:54Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.0c02147
intvolume: ' 59'
issue: '20'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 14666-14678
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Intersystem Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene
Photosensitizer
type: journal_article
user_id: '27611'
volume: 59
year: '2020'
...
---
_id: '41029'
author:
- first_name: Maria A.
full_name: Naumova, Maria A.
last_name: Naumova
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Joanne W. L.
full_name: Wong, Joanne W. L.
last_name: Wong
- first_name: Mohamed
full_name: Abdellah, Mohamed
last_name: Abdellah
- first_name: Huifang
full_name: Geng, Huifang
last_name: Geng
- first_name: Edoardo
full_name: Domenichini, Edoardo
last_name: Domenichini
- first_name: Jie
full_name: Meng, Jie
last_name: Meng
- first_name: Sol Alvarez
full_name: Gutierrez, Sol Alvarez
last_name: Gutierrez
- first_name: Pierre-Adrien
full_name: Mante, Pierre-Adrien
last_name: Mante
- first_name: Weihua
full_name: Lin, Weihua
last_name: Lin
- first_name: Peter
full_name: Zalden, Peter
last_name: Zalden
- first_name: Andreas
full_name: Galler, Andreas
last_name: Galler
- first_name: Frederico
full_name: Lima, Frederico
last_name: Lima
- first_name: Katharina
full_name: Kubicek, Katharina
last_name: Kubicek
- first_name: Mykola
full_name: Biednov, Mykola
last_name: Biednov
- first_name: Alexander
full_name: Britz, Alexander
last_name: Britz
- first_name: Stefano
full_name: Checchia, Stefano
last_name: Checchia
- first_name: Victoria
full_name: Kabanova, Victoria
last_name: Kabanova
- first_name: Michael
full_name: Wulff, Michael
last_name: Wulff
- first_name: Jennifer
full_name: Zimara, Jennifer
last_name: Zimara
- first_name: Dirk
full_name: Schwarzer, Dirk
last_name: Schwarzer
- first_name: Serhiy
full_name: Demeshko, Serhiy
last_name: Demeshko
- first_name: Vadim
full_name: Murzin, Vadim
last_name: Murzin
- first_name: David
full_name: Gosztola, David
last_name: Gosztola
- first_name: Martin
full_name: Jarenmark, Martin
last_name: Jarenmark
- first_name: Jianxin
full_name: Zhang, Jianxin
last_name: Zhang
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Max Latevi
full_name: Lawson Daku, Max Latevi
last_name: Lawson Daku
- first_name: Wojciech
full_name: Gawelda, Wojciech
last_name: Gawelda
- first_name: Dmitry
full_name: Khakhulin, Dmitry
last_name: Khakhulin
- first_name: Christian
full_name: Bressler, Christian
last_name: Bressler
- first_name: Franc
full_name: Meyer, Franc
last_name: Meyer
- first_name: Kaibo
full_name: Zheng, Kaibo
last_name: Zheng
- first_name: Sophie E.
full_name: Canton, Sophie E.
last_name: Canton
citation:
ama: Naumova MA, Kalinko A, Wong JWL, et al. Revealing Hot and Long-Lived Metastable
Spin States in the Photoinduced Switching of Solvated Metallogrid Complexes with
Femtosecond Optical and X-ray Spectroscopies. The Journal of Physical Chemistry
Letters. 2020;11(6):2133-2141. doi:10.1021/acs.jpclett.9b03883
apa: Naumova, M. A., Kalinko, A., Wong, J. W. L., Abdellah, M., Geng, H., Domenichini,
E., Meng, J., Gutierrez, S. A., Mante, P.-A., Lin, W., Zalden, P., Galler, A.,
Lima, F., Kubicek, K., Biednov, M., Britz, A., Checchia, S., Kabanova, V., Wulff,
M., … Canton, S. E. (2020). Revealing Hot and Long-Lived Metastable Spin States
in the Photoinduced Switching of Solvated Metallogrid Complexes with Femtosecond
Optical and X-ray Spectroscopies. The Journal of Physical Chemistry Letters,
11(6), 2133–2141. https://doi.org/10.1021/acs.jpclett.9b03883
bibtex: '@article{Naumova_Kalinko_Wong_Abdellah_Geng_Domenichini_Meng_Gutierrez_Mante_Lin_et
al._2020, title={Revealing Hot and Long-Lived Metastable Spin States in the Photoinduced
Switching of Solvated Metallogrid Complexes with Femtosecond Optical and X-ray
Spectroscopies}, volume={11}, DOI={10.1021/acs.jpclett.9b03883},
number={6}, journal={The Journal of Physical Chemistry Letters}, publisher={American
Chemical Society (ACS)}, author={Naumova, Maria A. and Kalinko, Aleksandr and
Wong, Joanne W. L. and Abdellah, Mohamed and Geng, Huifang and Domenichini, Edoardo
and Meng, Jie and Gutierrez, Sol Alvarez and Mante, Pierre-Adrien and Lin, Weihua
and et al.}, year={2020}, pages={2133–2141} }'
chicago: 'Naumova, Maria A., Aleksandr Kalinko, Joanne W. L. Wong, Mohamed Abdellah,
Huifang Geng, Edoardo Domenichini, Jie Meng, et al. “Revealing Hot and Long-Lived
Metastable Spin States in the Photoinduced Switching of Solvated Metallogrid Complexes
with Femtosecond Optical and X-Ray Spectroscopies.” The Journal of Physical
Chemistry Letters 11, no. 6 (2020): 2133–41. https://doi.org/10.1021/acs.jpclett.9b03883.'
ieee: 'M. A. Naumova et al., “Revealing Hot and Long-Lived Metastable Spin
States in the Photoinduced Switching of Solvated Metallogrid Complexes with Femtosecond
Optical and X-ray Spectroscopies,” The Journal of Physical Chemistry Letters,
vol. 11, no. 6, pp. 2133–2141, 2020, doi: 10.1021/acs.jpclett.9b03883.'
mla: Naumova, Maria A., et al. “Revealing Hot and Long-Lived Metastable Spin States
in the Photoinduced Switching of Solvated Metallogrid Complexes with Femtosecond
Optical and X-Ray Spectroscopies.” The Journal of Physical Chemistry Letters,
vol. 11, no. 6, American Chemical Society (ACS), 2020, pp. 2133–41, doi:10.1021/acs.jpclett.9b03883.
short: M.A. Naumova, A. Kalinko, J.W.L. Wong, M. Abdellah, H. Geng, E. Domenichini,
J. Meng, S.A. Gutierrez, P.-A. Mante, W. Lin, P. Zalden, A. Galler, F. Lima, K.
Kubicek, M. Biednov, A. Britz, S. Checchia, V. Kabanova, M. Wulff, J. Zimara,
D. Schwarzer, S. Demeshko, V. Murzin, D. Gosztola, M. Jarenmark, J. Zhang, M.
Bauer, M.L. Lawson Daku, W. Gawelda, D. Khakhulin, C. Bressler, F. Meyer, K. Zheng,
S.E. Canton, The Journal of Physical Chemistry Letters 11 (2020) 2133–2141.
date_created: 2023-01-30T17:53:18Z
date_updated: 2023-01-31T08:25:14Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.jpclett.9b03883
intvolume: ' 11'
issue: '6'
keyword:
- General Materials Science
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 2133-2141
publication: The Journal of Physical Chemistry Letters
publication_identifier:
issn:
- 1948-7185
- 1948-7185
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Revealing Hot and Long-Lived Metastable Spin States in the Photoinduced Switching
of Solvated Metallogrid Complexes with Femtosecond Optical and X-ray Spectroscopies
type: journal_article
user_id: '27611'
volume: 11
year: '2020'
...
---
_id: '41028'
article_number: '214301'
author:
- first_name: Maria A.
full_name: Naumova, Maria A.
last_name: Naumova
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Joanne W. L.
full_name: Wong, Joanne W. L.
last_name: Wong
- first_name: Sol
full_name: Alvarez Gutierrez, Sol
last_name: Alvarez Gutierrez
- first_name: Jie
full_name: Meng, Jie
last_name: Meng
- first_name: Mingli
full_name: Liang, Mingli
last_name: Liang
- first_name: Mohamed
full_name: Abdellah, Mohamed
last_name: Abdellah
- first_name: Huifang
full_name: Geng, Huifang
last_name: Geng
- first_name: Weihua
full_name: Lin, Weihua
last_name: Lin
- first_name: Katharina
full_name: Kubicek, Katharina
last_name: Kubicek
- first_name: Mykola
full_name: Biednov, Mykola
last_name: Biednov
- first_name: Frederico
full_name: Lima, Frederico
last_name: Lima
- first_name: Andreas
full_name: Galler, Andreas
last_name: Galler
- first_name: Peter
full_name: Zalden, Peter
last_name: Zalden
- first_name: Stefano
full_name: Checchia, Stefano
last_name: Checchia
- first_name: Pierre-Adrien
full_name: Mante, Pierre-Adrien
last_name: Mante
- first_name: Jennifer
full_name: Zimara, Jennifer
last_name: Zimara
- first_name: Dirk
full_name: Schwarzer, Dirk
last_name: Schwarzer
- first_name: Serhiy
full_name: Demeshko, Serhiy
last_name: Demeshko
- first_name: Vadim
full_name: Murzin, Vadim
last_name: Murzin
- first_name: David
full_name: Gosztola, David
last_name: Gosztola
- first_name: Martin
full_name: Jarenmark, Martin
last_name: Jarenmark
- first_name: Jianxin
full_name: Zhang, Jianxin
last_name: Zhang
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Max Latevi
full_name: Lawson Daku, Max Latevi
last_name: Lawson Daku
- first_name: Dmitry
full_name: Khakhulin, Dmitry
last_name: Khakhulin
- first_name: Wojciech
full_name: Gawelda, Wojciech
last_name: Gawelda
- first_name: Christian
full_name: Bressler, Christian
last_name: Bressler
- first_name: Franc
full_name: Meyer, Franc
last_name: Meyer
- first_name: Kaibo
full_name: Zheng, Kaibo
last_name: Zheng
- first_name: Sophie E.
full_name: Canton, Sophie E.
last_name: Canton
citation:
ama: Naumova MA, Kalinko A, Wong JWL, et al. Exploring the light-induced dynamics
in solvated metallogrid complexes with femtosecond pulses across the electromagnetic
spectrum. The Journal of Chemical Physics. 2020;152(21). doi:10.1063/1.5138641
apa: Naumova, M. A., Kalinko, A., Wong, J. W. L., Alvarez Gutierrez, S., Meng, J.,
Liang, M., Abdellah, M., Geng, H., Lin, W., Kubicek, K., Biednov, M., Lima, F.,
Galler, A., Zalden, P., Checchia, S., Mante, P.-A., Zimara, J., Schwarzer, D.,
Demeshko, S., … Canton, S. E. (2020). Exploring the light-induced dynamics in
solvated metallogrid complexes with femtosecond pulses across the electromagnetic
spectrum. The Journal of Chemical Physics, 152(21), Article 214301.
https://doi.org/10.1063/1.5138641
bibtex: '@article{Naumova_Kalinko_Wong_Alvarez Gutierrez_Meng_Liang_Abdellah_Geng_Lin_Kubicek_et
al._2020, title={Exploring the light-induced dynamics in solvated metallogrid
complexes with femtosecond pulses across the electromagnetic spectrum}, volume={152},
DOI={10.1063/1.5138641}, number={21214301},
journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Naumova,
Maria A. and Kalinko, Aleksandr and Wong, Joanne W. L. and Alvarez Gutierrez,
Sol and Meng, Jie and Liang, Mingli and Abdellah, Mohamed and Geng, Huifang and
Lin, Weihua and Kubicek, Katharina and et al.}, year={2020} }'
chicago: Naumova, Maria A., Aleksandr Kalinko, Joanne W. L. Wong, Sol Alvarez Gutierrez,
Jie Meng, Mingli Liang, Mohamed Abdellah, et al. “Exploring the Light-Induced
Dynamics in Solvated Metallogrid Complexes with Femtosecond Pulses across the
Electromagnetic Spectrum.” The Journal of Chemical Physics 152, no. 21
(2020). https://doi.org/10.1063/1.5138641.
ieee: 'M. A. Naumova et al., “Exploring the light-induced dynamics in solvated
metallogrid complexes with femtosecond pulses across the electromagnetic spectrum,”
The Journal of Chemical Physics, vol. 152, no. 21, Art. no. 214301, 2020,
doi: 10.1063/1.5138641.'
mla: Naumova, Maria A., et al. “Exploring the Light-Induced Dynamics in Solvated
Metallogrid Complexes with Femtosecond Pulses across the Electromagnetic Spectrum.”
The Journal of Chemical Physics, vol. 152, no. 21, 214301, AIP Publishing,
2020, doi:10.1063/1.5138641.
short: M.A. Naumova, A. Kalinko, J.W.L. Wong, S. Alvarez Gutierrez, J. Meng, M.
Liang, M. Abdellah, H. Geng, W. Lin, K. Kubicek, M. Biednov, F. Lima, A. Galler,
P. Zalden, S. Checchia, P.-A. Mante, J. Zimara, D. Schwarzer, S. Demeshko, V.
Murzin, D. Gosztola, M. Jarenmark, J. Zhang, M. Bauer, M.L. Lawson Daku, D. Khakhulin,
W. Gawelda, C. Bressler, F. Meyer, K. Zheng, S.E. Canton, The Journal of Chemical
Physics 152 (2020).
date_created: 2023-01-30T17:51:09Z
date_updated: 2023-01-31T08:25:38Z
department:
- _id: '35'
- _id: '306'
doi: 10.1063/1.5138641
intvolume: ' 152'
issue: '21'
keyword:
- Physical and Theoretical Chemistry
- General Physics and Astronomy
language:
- iso: eng
publication: The Journal of Chemical Physics
publication_identifier:
issn:
- 0021-9606
- 1089-7690
publication_status: published
publisher: AIP Publishing
status: public
title: Exploring the light-induced dynamics in solvated metallogrid complexes with
femtosecond pulses across the electromagnetic spectrum
type: journal_article
user_id: '27611'
volume: 152
year: '2020'
...
---
_id: '40994'
abstract:
- lang: eng
text: Photoactive compounds are essential for photocatalytic and luminescent applications,
such as photoredox catalysis or light emitting diodes. However, the substitution
of noble metals, which are almost exclusively used, by base metals remains a major
challenge on the way to a more sustainable world.1 Iron is a dream candidate for
this ambitious aim.2 But compared to noble metal complexes that show long-lived
metal-to-ligand charge-transfer (MLCT) states, realization of emissive and photoactive
iron complexes is demanding, due to the fast deactivation of charge transfer states
into non-emissive inactive states. No MLCT emission has been observed for monometallic
iron complexes before. Consequently, dual emission could also not yet be realized
with iron complexes, as it is a very rare property even of noble metal compounds.
Here we report the FeIII complex [Fe(ImP)2][PF6]
(HImP = 1,1’-(1,3-phenylene)bis(3-methyl-1-imidazol-2-ylidene)), showing Janus-type
dual emission by combining LMCT (ligand-to-metal charge transfer) with MLCT luminescence.
The respective excited states are characterized by a record lifetime of τMLCT
= 4.2 ns, and a moderate τLMCT = 0.2 ns. Only two emissive
FeIII compounds are known so far and they show LMCT luminescence
only.3,4 The unique properties of the presented complex are caused by the specific
ligand design combining four N-heterocyclic carbenes with two cyclometalating
groups, using the σ-donor strength of six carbon atoms and the acceptor capabilities
of the central phenyl rings. Spectroscopically, doublet manifolds could be identified
in the deactivation process, while (TD)DFT analysis revealed the presence of quartets
as well. With three key advancements of realizing the first iron complex showing
dual luminescence, a MLCT luminescence and a world record MLCT lifetime, the results
constitute a basis for future application of iron complexes as white light emitters
and new photocatalytic reactions making use of the Janus-type properties of the
developed complex.
author:
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Olga
full_name: Bokareva, Olga
last_name: Bokareva
- first_name: Thomas
full_name: Reuter, Thomas
last_name: Reuter
- first_name: Serhiy
full_name: Demeshko, Serhiy
last_name: Demeshko
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Franc
full_name: Meyer, Franc
last_name: Meyer
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
citation:
ama: Bauer M, Steube J, Päpcke A, et al. Janus-type dual emission of a Cyclometalated
Iron(III) complex. Published online 2020.
apa: Bauer, M., Steube, J., Päpcke, A., Bokareva, O., Reuter, T., Demeshko, S.,
Schoch, R., Hohloch, S., Meyer, F., Heinze, K., Kühn, O., & Lochbrunner, S.
(2020). Janus-type dual emission of a Cyclometalated Iron(III) complex.
Research Square Platform LLC.
bibtex: '@article{Bauer_Steube_Päpcke_Bokareva_Reuter_Demeshko_Schoch_Hohloch_Meyer_Heinze_et
al._2020, title={Janus-type dual emission of a Cyclometalated Iron(III) complex},
publisher={Research Square Platform LLC}, author={Bauer, Matthias and Steube,
Jakob and Päpcke, Ayla and Bokareva, Olga and Reuter, Thomas and Demeshko, Serhiy
and Schoch, Roland and Hohloch, Stephan and Meyer, Franc and Heinze, Katja and
et al.}, year={2020} }'
chicago: Bauer, Matthias, Jakob Steube, Ayla Päpcke, Olga Bokareva, Thomas Reuter,
Serhiy Demeshko, Roland Schoch, et al. “Janus-Type Dual Emission of a Cyclometalated
Iron(III) Complex.” Research Square Platform LLC, 2020.
ieee: M. Bauer et al., “Janus-type dual emission of a Cyclometalated Iron(III)
complex.” Research Square Platform LLC, 2020.
mla: Bauer, Matthias, et al. Janus-Type Dual Emission of a Cyclometalated Iron(III)
Complex. Research Square Platform LLC, 2020.
short: M. Bauer, J. Steube, A. Päpcke, O. Bokareva, T. Reuter, S. Demeshko, R. Schoch,
S. Hohloch, F. Meyer, K. Heinze, O. Kühn, S. Lochbrunner, (2020).
date_created: 2023-01-30T16:45:05Z
date_updated: 2023-08-09T12:51:46Z
department:
- _id: '35'
- _id: '306'
language:
- iso: eng
publication_status: published
publisher: Research Square Platform LLC
status: public
title: Janus-type dual emission of a Cyclometalated Iron(III) complex
type: preprint
user_id: '48467'
year: '2020'
...
---
_id: '41025'
abstract:
- lang: eng
text: We investigate the structure-activity correlations of methanation catalysts
obtained by thermal decomposition of a Ni-based metal-organic framework, using
pair distribution function, X-ray absorption spectroscopy and X-ray diffraction.
author:
- first_name: Nils
full_name: Prinz, Nils
last_name: Prinz
- first_name: Leif
full_name: Schwensow, Leif
last_name: Schwensow
- first_name: Sven
full_name: Strübbe, Sven
id: '76968'
last_name: Strübbe
- first_name: Andreas
full_name: Jentys, Andreas
last_name: Jentys
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Wolfgang
full_name: Kleist, Wolfgang
last_name: Kleist
- first_name: Mirijam
full_name: Zobel, Mirijam
last_name: Zobel
citation:
ama: Prinz N, Schwensow L, Strübbe S, et al. Hard X-ray-based techniques for structural
investigations of CO2 methanation catalysts prepared by MOF decomposition. Nanoscale.
2020;12(29):15800-15813. doi:10.1039/d0nr01750g
apa: Prinz, N., Schwensow, L., Strübbe, S., Jentys, A., Bauer, M., Kleist, W., &
Zobel, M. (2020). Hard X-ray-based techniques for structural investigations of
CO2 methanation catalysts prepared by MOF decomposition. Nanoscale, 12(29),
15800–15813. https://doi.org/10.1039/d0nr01750g
bibtex: '@article{Prinz_Schwensow_Strübbe_Jentys_Bauer_Kleist_Zobel_2020, title={Hard
X-ray-based techniques for structural investigations of CO2 methanation catalysts
prepared by MOF decomposition}, volume={12}, DOI={10.1039/d0nr01750g},
number={29}, journal={Nanoscale}, publisher={Royal Society of Chemistry (RSC)},
author={Prinz, Nils and Schwensow, Leif and Strübbe, Sven and Jentys, Andreas
and Bauer, Matthias and Kleist, Wolfgang and Zobel, Mirijam}, year={2020}, pages={15800–15813}
}'
chicago: 'Prinz, Nils, Leif Schwensow, Sven Strübbe, Andreas Jentys, Matthias Bauer,
Wolfgang Kleist, and Mirijam Zobel. “Hard X-Ray-Based Techniques for Structural
Investigations of CO2 Methanation Catalysts Prepared by MOF Decomposition.” Nanoscale
12, no. 29 (2020): 15800–813. https://doi.org/10.1039/d0nr01750g.'
ieee: 'N. Prinz et al., “Hard X-ray-based techniques for structural investigations
of CO2 methanation catalysts prepared by MOF decomposition,” Nanoscale,
vol. 12, no. 29, pp. 15800–15813, 2020, doi: 10.1039/d0nr01750g.'
mla: Prinz, Nils, et al. “Hard X-Ray-Based Techniques for Structural Investigations
of CO2 Methanation Catalysts Prepared by MOF Decomposition.” Nanoscale,
vol. 12, no. 29, Royal Society of Chemistry (RSC), 2020, pp. 15800–13, doi:10.1039/d0nr01750g.
short: N. Prinz, L. Schwensow, S. Strübbe, A. Jentys, M. Bauer, W. Kleist, M. Zobel,
Nanoscale 12 (2020) 15800–15813.
date_created: 2023-01-30T17:47:17Z
date_updated: 2025-08-15T12:43:52Z
department:
- _id: '35'
- _id: '306'
doi: 10.1039/d0nr01750g
intvolume: ' 12'
issue: '29'
keyword:
- Xray
- Catalysis
language:
- iso: eng
page: 15800-15813
publication: Nanoscale
publication_identifier:
issn:
- 2040-3364
- 2040-3372
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Hard X-ray-based techniques for structural investigations of CO2 methanation
catalysts prepared by MOF decomposition
type: journal_article
user_id: '48467'
volume: 12
year: '2020'
...
---
_id: '21364'
author:
- first_name: Reni
full_name: Grauke, Reni
last_name: Grauke
- first_name: Rahel
full_name: Schepper, Rahel
last_name: Schepper
- first_name: Jabor
full_name: Rabeah, Jabor
last_name: Rabeah
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Ursula
full_name: Bentrup, Ursula
last_name: Bentrup
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
- first_name: Angelika
full_name: Brückner, Angelika
last_name: Brückner
citation:
ama: Grauke R, Schepper R, Rabeah J, et al. Impact of Al Activators on Structure
and Catalytic Performance of Cr Catalysts in Homogeneous Ethylene Oligomerization
– A Multitechnique in situ/operando Study. ChemCatChem.
2019:1025-1035. doi:10.1002/cctc.201901441
apa: Grauke, R., Schepper, R., Rabeah, J., Schoch, R., Bentrup, U., Bauer, M., &
Brückner, A. (2019). Impact of Al Activators on Structure and Catalytic Performance
of Cr Catalysts in Homogeneous Ethylene Oligomerization – A Multitechnique
in situ/operando Study. ChemCatChem, 1025–1035. https://doi.org/10.1002/cctc.201901441
bibtex: '@article{Grauke_Schepper_Rabeah_Schoch_Bentrup_Bauer_Brückner_2019, title={Impact
of Al Activators on Structure and Catalytic Performance of Cr Catalysts in Homogeneous
Ethylene Oligomerization – A Multitechnique in situ/operando
Study}, DOI={10.1002/cctc.201901441},
journal={ChemCatChem}, author={Grauke, Reni and Schepper, Rahel and Rabeah, Jabor
and Schoch, Roland and Bentrup, Ursula and Bauer, Matthias and Brückner, Angelika},
year={2019}, pages={1025–1035} }'
chicago: Grauke, Reni, Rahel Schepper, Jabor Rabeah, Roland Schoch, Ursula Bentrup,
Matthias Bauer, and Angelika Brückner. “Impact of Al Activators on Structure and
Catalytic Performance of Cr Catalysts in Homogeneous Ethylene Oligomerization
– A Multitechnique in Situ/Operando Study.” ChemCatChem,
2019, 1025–35. https://doi.org/10.1002/cctc.201901441.
ieee: R. Grauke et al., “Impact of Al Activators on Structure and Catalytic
Performance of Cr Catalysts in Homogeneous Ethylene Oligomerization – A Multitechnique
in situ/operando Study,” ChemCatChem, pp. 1025–1035,
2019.
mla: Grauke, Reni, et al. “Impact of Al Activators on Structure and Catalytic Performance
of Cr Catalysts in Homogeneous Ethylene Oligomerization – A Multitechnique
in Situ/Operando Study.” ChemCatChem, 2019, pp. 1025–35,
doi:10.1002/cctc.201901441.
short: R. Grauke, R. Schepper, J. Rabeah, R. Schoch, U. Bentrup, M. Bauer, A. Brückner,
ChemCatChem (2019) 1025–1035.
date_created: 2021-03-02T12:37:34Z
date_updated: 2022-01-06T06:54:56Z
department:
- _id: '306'
doi: 10.1002/cctc.201901441
language:
- iso: eng
page: 1025-1035
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
status: public
title: Impact of Al Activators on Structure and Catalytic Performance of Cr Catalysts
in Homogeneous Ethylene Oligomerization – A Multitechnique in situ/operando Study
type: journal_article
user_id: '54037'
year: '2019'
...
---
_id: '16314'
author:
- first_name: Sebastian
full_name: Preiß, Sebastian
last_name: Preiß
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Luca
full_name: Großmann, Luca
last_name: Großmann
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
- first_name: Till
full_name: Opatz, Till
last_name: Opatz
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
citation:
ama: Preiß S, Päpcke A, Burkhardt L, et al. Gold(II) Porphyrins in Photoinduced
Electron Transfer Reactions. Chemistry – A European Journal. 2019:5940-5949.
doi:10.1002/chem.201900050
apa: Preiß, S., Päpcke, A., Burkhardt, L., Großmann, L., Lochbrunner, S., Bauer,
M., … Heinze, K. (2019). Gold(II) Porphyrins in Photoinduced Electron Transfer
Reactions. Chemistry – A European Journal, 5940–5949. https://doi.org/10.1002/chem.201900050
bibtex: '@article{Preiß_Päpcke_Burkhardt_Großmann_Lochbrunner_Bauer_Opatz_Heinze_2019,
title={Gold(II) Porphyrins in Photoinduced Electron Transfer Reactions}, DOI={10.1002/chem.201900050}, journal={Chemistry
– A European Journal}, author={Preiß, Sebastian and Päpcke, Ayla and Burkhardt,
Lukas and Großmann, Luca and Lochbrunner, Stefan and Bauer, Matthias and Opatz,
Till and Heinze, Katja}, year={2019}, pages={5940–5949} }'
chicago: Preiß, Sebastian, Ayla Päpcke, Lukas Burkhardt, Luca Großmann, Stefan Lochbrunner,
Matthias Bauer, Till Opatz, and Katja Heinze. “Gold(II) Porphyrins in Photoinduced
Electron Transfer Reactions.” Chemistry – A European Journal, 2019, 5940–49.
https://doi.org/10.1002/chem.201900050.
ieee: S. Preiß et al., “Gold(II) Porphyrins in Photoinduced Electron Transfer
Reactions,” Chemistry – A European Journal, pp. 5940–5949, 2019.
mla: Preiß, Sebastian, et al. “Gold(II) Porphyrins in Photoinduced Electron Transfer
Reactions.” Chemistry – A European Journal, 2019, pp. 5940–49, doi:10.1002/chem.201900050.
short: S. Preiß, A. Päpcke, L. Burkhardt, L. Großmann, S. Lochbrunner, M. Bauer,
T. Opatz, K. Heinze, Chemistry – A European Journal (2019) 5940–5949.
date_created: 2020-03-23T10:39:35Z
date_updated: 2022-01-06T06:52:48Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
doi: 10.1002/chem.201900050
language:
- iso: eng
page: 5940-5949
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
status: public
title: Gold(II) Porphyrins in Photoinduced Electron Transfer Reactions
type: journal_article
user_id: '54038'
year: '2019'
...
---
_id: '16320'
author:
- first_name: Patrick
full_name: Müller, Patrick
id: '54037'
last_name: Müller
orcid: 0000-0003-1103-4073
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Ulrich
full_name: Flörke, Ulrich
last_name: Flörke
- first_name: Gerald
full_name: Henkel, Gerald
last_name: Henkel
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
citation:
ama: Müller P, Neuba A, Flörke U, Henkel G, Kühne TD, Bauer M. Experimental and
Theoretical High Energy Resolution Hard X-ray Absorption and Emission Spectroscopy
on Biomimetic Cu2S2 Complexes. The Journal of Physical Chemistry A. 2019:3575-3581.
doi:10.1021/acs.jpca.9b00463
apa: Müller, P., Neuba, A., Flörke, U., Henkel, G., Kühne, T. D., & Bauer, M.
(2019). Experimental and Theoretical High Energy Resolution Hard X-ray Absorption
and Emission Spectroscopy on Biomimetic Cu2S2 Complexes. The Journal of Physical
Chemistry A, 3575–3581. https://doi.org/10.1021/acs.jpca.9b00463
bibtex: '@article{Müller_Neuba_Flörke_Henkel_Kühne_Bauer_2019, title={Experimental
and Theoretical High Energy Resolution Hard X-ray Absorption and Emission Spectroscopy
on Biomimetic Cu2S2 Complexes}, DOI={10.1021/acs.jpca.9b00463},
journal={The Journal of Physical Chemistry A}, author={Müller, Patrick and Neuba,
Adam and Flörke, Ulrich and Henkel, Gerald and Kühne, Thomas D. and Bauer, Matthias},
year={2019}, pages={3575–3581} }'
chicago: Müller, Patrick, Adam Neuba, Ulrich Flörke, Gerald Henkel, Thomas D. Kühne,
and Matthias Bauer. “Experimental and Theoretical High Energy Resolution Hard
X-Ray Absorption and Emission Spectroscopy on Biomimetic Cu2S2 Complexes.” The
Journal of Physical Chemistry A, 2019, 3575–81. https://doi.org/10.1021/acs.jpca.9b00463.
ieee: P. Müller, A. Neuba, U. Flörke, G. Henkel, T. D. Kühne, and M. Bauer, “Experimental
and Theoretical High Energy Resolution Hard X-ray Absorption and Emission Spectroscopy
on Biomimetic Cu2S2 Complexes,” The Journal of Physical Chemistry A, pp.
3575–3581, 2019.
mla: Müller, Patrick, et al. “Experimental and Theoretical High Energy Resolution
Hard X-Ray Absorption and Emission Spectroscopy on Biomimetic Cu2S2 Complexes.”
The Journal of Physical Chemistry A, 2019, pp. 3575–81, doi:10.1021/acs.jpca.9b00463.
short: P. Müller, A. Neuba, U. Flörke, G. Henkel, T.D. Kühne, M. Bauer, The Journal
of Physical Chemistry A (2019) 3575–3581.
date_created: 2020-03-23T10:58:15Z
date_updated: 2022-01-06T06:52:48Z
department:
- _id: '35'
- _id: '306'
- _id: '304'
doi: 10.1021/acs.jpca.9b00463
language:
- iso: eng
page: 3575-3581
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: The Journal of Physical Chemistry A
publication_identifier:
issn:
- 1089-5639
- 1520-5215
publication_status: published
status: public
title: Experimental and Theoretical High Energy Resolution Hard X-ray Absorption and
Emission Spectroscopy on Biomimetic Cu2S2 Complexes
type: journal_article
user_id: '54038'
year: '2019'
...