@article{33681, author = {{da Silva, Marcos A.R. and Silva, Ingrid F. and Xue, Qi and Lo, Benedict T.W. and Tarakina, Nadezda V. and Nunes, Barbara N. and Adler, Peter and Sahoo, Sudhir K. and Bahnemann, Detlef W. and López-Salas, Nieves and Savateev, Aleksandr and Ribeiro, Caue and Kühne, Thomas and Antonietti, Markus and Teixeira, Ivo F.}}, issn = {{0926-3373}}, journal = {{Applied Catalysis B: Environmental}}, keywords = {{Process Chemistry and Technology, General Environmental Science, Catalysis}}, publisher = {{Elsevier BV}}, title = {{{Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst}}}, doi = {{10.1016/j.apcatb.2021.120965}}, volume = {{304}}, year = {{2021}}, } @article{33675, abstract = {{The influence of different polymer side chains on the vapor phase infiltration with TMA is investigated and supported by DFT-calculations.}}, author = {{Mai, Lukas and Maniar, Dina and Zysk, Frederik and Schöbel, Judith and Kühne, Thomas and Loos, Katja and Devi, Anjana}}, issn = {{1477-9226}}, journal = {{Dalton Transactions}}, keywords = {{Inorganic Chemistry}}, number = {{4}}, pages = {{1384--1394}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Influence of different ester side groups in polymers on the vapor phase infiltration with trimethyl aluminum}}}, doi = {{10.1039/d1dt03753f}}, volume = {{51}}, year = {{2021}}, } @article{23728, abstract = {{We demonstrate the integration of amorphous tungsten silicide superconducting nanowire single-photon detectors on titanium in-diffused lithium niobate waveguides. We show proof-of-principle detection of evanescently coupled photons of 1550 nm wavelength using bidirectional waveguide coupling for two orthogonal polarization directions. We investigate the internal detection efficiency as well as detector absorption using coupling-independent characterization measurements. Furthermore, we describe strategies to improve the yield and efficiency of these devices.}}, author = {{Höpker, Jan Philipp and Verma, Varun B and Protte, Maximilian and Ricken, Raimund and Quiring, Viktor and Eigner, Christof and Ebers, Lena and Hammer, Manfred and Förstner, Jens and Silberhorn, Christine and Mirin, Richard P and Woo Nam, Sae and Bartley, Tim}}, issn = {{2515-7647}}, journal = {{Journal of Physics: Photonics}}, pages = {{034022}}, title = {{{Integrated superconducting nanowire single-photon detectors on titanium in-diffused lithium niobate waveguides}}}, doi = {{10.1088/2515-7647/ac105b}}, volume = {{3}}, year = {{2021}}, } @article{34087, author = {{Knust, Steffen and Ruhm, Lukas and Kuhlmann, Andreas and Meinderink, Dennis and Bürger, Julius and Lindner, Jörg and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido}}, issn = {{0377-0486}}, journal = {{Journal of Raman Spectroscopy}}, keywords = {{Spectroscopy, General Materials Science}}, number = {{7}}, pages = {{1237--1245}}, publisher = {{Wiley}}, title = {{{In situ backside Raman spectroscopy of zinc oxide nanorods in an atmospheric‐pressure dielectric barrier discharge plasma}}}, doi = {{10.1002/jrs.6123}}, volume = {{52}}, year = {{2021}}, } @article{35303, abstract = {{Abstract Purpose Studies about effects of lunch dietary Glycemic Index (GI) on cognition of schoolchildren are scarce. Our previous CogniDo GI study found no changes of cognition in the early postprandial phase after consumption of two rice types with medium vs. high dietary GI for lunch (i.e., 45 min after starting lunch). This study investigated whether the dietary GI of lunch has an impact on cognition of schoolchildren in the late postprandial phase, 90 min after lunch. Methods A randomized, 2 × 2 crossover intervention study was conducted at a comprehensive school with 5th and 6th grade students. Participants (n = 212) were randomly assigned to either sequence 1 or 2. In the first period, participants of sequence 1 received a dish with high GI rice (GI: 79), those of sequence 2 with medium GI rice (GI: 64)—in the second period, 1 week later, vice versa. Computer-based cognitive testing was performed 90 min after lunch examining tonic alertness, visual search and task switching, and working memory. Treatment effects and treatment effects adjusted for estimated lunch glycemic load (GL) were analyzed using a linear mixed model. Results The selected cognitive parameters were not affected by the GI of lunch 90 min after lunch, neither after intention-to-treat nor in the per-protocol analysis. Adjustment for GL also did not change results. Conclusion The present study revealed no notable differences after the consumption of two rice types with medium vs. high dietary GI for lunch in children’s cognitive function in the late postprandial phase, 90 min after lunch. Clinical trial registration German Clinical Trials Register (DRKS00013597); date of registration: 16/04/2018, retrospectively registered. }}, author = {{Drozdowska, Alina and Sinningen, Kathrin and Falkenstein, Michael and Rudolf, Henrik and Libuda, Lars and Buyken, Anette and Lücke, Thomas and Kersting, Mathilde}}, issn = {{1436-6207}}, journal = {{European Journal of Nutrition}}, keywords = {{Nutrition and Dietetics, Medicine (miscellaneous)}}, number = {{3}}, pages = {{1637--1647}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Impact of lunch with carbohydrates differing in glycemic index on children's cognitive functioning in the late postprandial phase: a randomized crossover study}}}, doi = {{10.1007/s00394-021-02766-y}}, volume = {{61}}, year = {{2021}}, } @article{35327, author = {{Wortmann, Martin and Viertel, Klaus and Welle, Alexander and Keil, Waldemar and Frese, Natalie and Hachmann, Wiebke and Krieger, Philipp and Brikmann, Johannes and Schmidt, Claudia and Moritzer, Elmar and Hüsgen, Bruno}}, issn = {{0017-9310}}, journal = {{International Journal of Heat and Mass Transfer}}, keywords = {{Fluid Flow and Transfer Processes, Mechanical Engineering, Condensed Matter Physics}}, publisher = {{Elsevier BV}}, title = {{{Anomalous bulk diffusion of methylene diphenyl diisocyanate in silicone elastomer}}}, doi = {{10.1016/j.ijheatmasstransfer.2021.121536}}, volume = {{177}}, year = {{2021}}, } @article{35526, author = {{Kulgemeyer, Christoph and Kempin, Maren and Weißbach, Anna and Borowski, Andreas and Buschhüter, David and Enkrott, Patrick and Reinhold, Peter and Riese, Josef and Schecker, Horst and Schröder, Jan and Vogelsang, Christoph}}, issn = {{0950-0693}}, journal = {{International Journal of Science Education}}, keywords = {{Education}}, number = {{18}}, pages = {{3035--3057}}, publisher = {{Informa UK Limited}}, title = {{{Exploring the impact of pre-service science teachers’ reflection skills on the development of professional knowledge during a field experience}}}, doi = {{10.1080/09500693.2021.2006820}}, volume = {{43}}, year = {{2021}}, } @article{34054, abstract = {{AbstractColloidal nanosphere monolayers—used as a lithography mask for site-controlled material deposition or removal—offer the possibility of cost-effective patterning of large surface areas. In the present study, an automated analysis of scanning electron microscopy (SEM) images is described, which enables the recognition of the individual nanospheres in densely packed monolayers in order to perform a statistical quantification of the sphere size, mask opening size, and sphere-sphere separation distributions. Search algorithms based on Fourier transformation, cross-correlation, multiple-angle intensity profiling, and sphere edge point detection techniques allow for a sphere detection efficiency of at least 99.8%, even in the case of considerable sphere size variations. While the sphere positions and diameters are determined by fitting circles to the spheres edge points, the openings between sphere triples are detected by intensity thresholding. For the analyzed polystyrene sphere monolayers with sphere sizes between 220 and 600 nm and a diameter spread of around 3% coefficients of variation of 6.8–8.1% for the opening size are found. By correlating the mentioned size distributions, it is shown that, in this case, the dominant contribution to the opening size variation stems from nanometer-scale positional variations of the spheres.}}, author = {{Riedl, Thomas and Lindner, Jörg}}, issn = {{1431-9276}}, journal = {{Microscopy and Microanalysis}}, keywords = {{Instrumentation}}, number = {{1}}, pages = {{185--195}}, publisher = {{Cambridge University Press (CUP)}}, title = {{{Automated SEM Image Analysis of the Sphere Diameter, Sphere-Sphere Separation, and Opening Size Distributions of Nanosphere Lithography Masks}}}, doi = {{10.1017/s1431927621013866}}, volume = {{28}}, year = {{2021}}, } @article{29189, author = {{Rogge, Tim and Vogelsang, Christoph and Pollmeier, Pascal}}, issn = {{1431-2859}}, journal = {{Seminar}}, pages = {{91--105}}, title = {{{Wie erleben Lehramtsstudierende unterschiedliche Feedbacksituationen im Praxissemester? – Analysen auf Basis einer Interviewstudie zum Einsatz von Unterrichtsvideografien}}}, volume = {{4}}, year = {{2021}}, } @article{33986, abstract = {{ Zusammenfassung. Genetische Varianten beeinflussen die Gewichtsregulation und die Entwicklung von Essstörungen. Zunächst haben familienbasierte, sogenannte formalgenetische Studien den erblichen Anteil an der Gewichtsregulation und an der Ätiologie von Essstörungen beleuchtet. In einer Vielzahl von Studien zeigten sich sowohl für die Varianz des Körpergewichts als auch für die Entstehung von Essstörungen Erblichkeitsschätzer (Heritabilitätsraten) von über 50 %. Mit diesem Wissen begab man sich in den 90er-Jahren des letzten Jahrhunderts auf die Suche nach den zugrundeliegenden Genen (genauer: genetischen Varianten), die das Körpergewicht, das Essverhalten oder beide Phänotypen auf Grundlage geteilter Mechanismen beeinflussen. Zunächst wurden Kandidatengenstudien durchgeführt. Dabei untersuchte man auf Grundlage unterschiedlicher, v. a. aber pathophysiologisch plausibler Überlegungen Gene mit hoher Relevanz für die untersuchten Phänotypen. Dieser Ansatz war für Essstörungen nicht sehr erfolgreich, für die Gewichtsregulation konnte eine Handvoll Gene identifiziert werden. Verbunden mit großen methodischen Fortschritten in der genetischen Forschung und v. a. der Etablierung sogenannter genomweiter Assoziationsstudien (GWAS) Anfang der 2000er-Jahre konnten bislang über 1000 Varianten/Genorte detektiert werden, die das Körpergewicht beeinflussen. Für die Essstörung Anorexia nervosa (AN) sind aktuell acht solcher Genorte beschrieben. Diese Ergebnisse, aber auch aktuelle Ansätze zu phänotypübergreifenden Analysen lassen Einblicke in die komplexe Regulation des Körpergewichtes zu und haben zudem unerwartete Pathomechanismen für AN aufgezeigt. }}, author = {{Hirtz, Raphael and Zheng, Yiran and Rajcsanyi, Luisa S. and Libuda, Lars and Antel, Jochen and Peters, Triinu and Hebebrand, Johannes and Hinney, Anke}}, issn = {{1422-4917}}, journal = {{Zeitschrift für Kinder- und Jugendpsychiatrie und Psychotherapie}}, keywords = {{Psychiatry and Mental health, Clinical Psychology, General Medicine, Pediatrics, Perinatology and Child Health}}, number = {{3}}, pages = {{175--185}}, publisher = {{Hogrefe Publishing Group}}, title = {{{Ebenen der genetischen Analyse komplexer Phänotypen am Beispiel der Anorexia nervosa und der Varianz des Körpergewichts}}}, doi = {{10.1024/1422-4917/a000829}}, volume = {{50}}, year = {{2021}}, } @book{24737, editor = {{Woitkowski, David and Vogelsang, Christoph}}, isbn = {{9783832552688}}, publisher = {{LOGOS}}, title = {{{Zentrale Themen der Ideengeschichte physikdidaktischer Forschung in Deutschland anhand ausgewählter Originalquellen}}}, doi = {{10.30819/5268}}, year = {{2021}}, } @article{23826, abstract = {{Potassium titanyl phosphate (KTP) is a nonlinear optical material with applications in high-power frequency conversion or quasi-phase matching in submicron period domain grids. A prerequisite for these applications is a precise control and understanding of the poling mechanisms to enable the fabrication of high-grade domain grids. In contrast to the widely used material lithium niobate, the domain growth in KTP is less studied, because many standard methods, such as selective etching or polarization microscopy, provides less insight or are not applicable on non-polar surfaces, respectively. In this work, we present results of confocal Raman-spectroscopy of the ferroelectric domain structure in KTP. This analytical method allows for the visualization of domain grids of the non-polar KTP y-face and therefore more insight into the domain-growth and -structure in KTP, which can be used for improved domain fabrication.}}, author = {{Brockmeier, Julian and Mackwitz, Peter Walter Martin and Rüsing, Michael and Eigner, Christof and Padberg, Laura and Santandrea, Matteo and Silberhorn, Christine and Zrenner, Artur and Berth, Gerhard}}, issn = {{2073-4352}}, journal = {{Crystals}}, title = {{{Non-Invasive Visualization of Ferroelectric Domain Structures on the Non-Polar y-Surface of KTiOPO4 via Raman Imaging}}}, doi = {{10.3390/cryst11091086}}, year = {{2021}}, } @article{25227, abstract = {{AbstractQuantum well (QW) heterostructures have been extensively used for the realization of a wide range of optical and electronic devices. Exploiting their potential for further improvement and development requires a fundamental understanding of their electronic structure. So far, the most commonly used experimental techniques for this purpose have been all-optical spectroscopy methods that, however, are generally averaging in momentum space. Additional information can be gained by angle-resolved photoelectron spectroscopy (ARPES), which measures the electronic structure with momentum resolution. Here we report on the use of extremely low-energy ARPES (photon energy ~ 7 eV) to increase depth sensitivity and access buried QW states, located at 3 nm and 6 nm below the surface of cubic-GaN/AlN and GaAs/AlGaAs heterostructures, respectively. We find that the QW states in cubic-GaN/AlN can indeed be observed, but not their energy dispersion, because of the high surface roughness. The GaAs/AlGaAs QW states, on the other hand, are buried too deep to be detected by extremely low-energy ARPES. Since the sample surface is much flatter, the ARPES spectra of the GaAs/AlGaAs show distinct features in momentum space, which can be reconducted to the band structure of the topmost surface layer of the QW structure. Our results provide important information about the samples’ properties required to perform extremely low-energy ARPES experiments on electronic states buried in semiconductor heterostructures.}}, author = {{Hajlaoui, Mahdi and Ponzoni, Stefano and Deppe, Michael and Henksmeier, Tobias and As, Donat Josef and Reuter, Dirk and Zentgraf, Thomas and Springholz, Gunther and Schneider, Claus Michael and Cramm, Stefan and Cinchetti, Mirko}}, issn = {{2045-2322}}, journal = {{Scientific Reports}}, title = {{{Extremely low-energy ARPES of quantum well states in cubic-GaN/AlN and GaAs/AlGaAs heterostructures}}}, doi = {{10.1038/s41598-021-98569-6}}, volume = {{11}}, year = {{2021}}, } @inproceedings{40476, author = {{Tenberge, Claudia and Gödiker, Manon}}, editor = {{PATT38 Organizing Committee , PATT 38}}, location = {{Turku}}, pages = {{24--25}}, title = {{{The ‚teachwodd training concept’ a contribution to the implementation of practical technological learning in primary schools. }}}, year = {{2021}}, } @article{48035, abstract = {{BACKGROUND: Previous studies suggest better visual-spatial processing when participants are tested in postures in which dynamic stability is challenged. The question arises if this is also true for the performance in mental body-rotation tasks (MBRT). AIM: Taking the embodied cognition approach into account, the first aim of the present study was to examine the potential influence of different demands on dynamic stability for two postures (parallel stand vs. tandem stand) on solving two versions of the MBRT, inducing either an object-based or an egocentric perspective transformation strategy. The second aim was to investigate if these different demands on dynamic stability are reflected in postural sway parameters. METHOD: Thirty participants (18 females and 12 males) were tested in the two MBRTs and in a control condition. All tasks were performed while standing on a balance beam in tandem stand and in a feet parallel position on a force plate. RESULTS: The results for response time and response error revealed effects of rotation angle and task, but no effect of posture. The analyzed Center of Pressure (CoP) data revealed a reduction of body sway during the MBRT for egocentric perspective transformations. CONCLUSION: The results indicate that participants performed better for egocentric than for object-based transformations and that the egocentric transformation leads to more postural stability than the object-based.}}, author = {{Budde, Kirsten and Jöllenbeck, Thomas and Barela, José A. and Figueiredo, Gabriella A. and Weigelt, Matthias}}, issn = {{2446-4902}}, journal = {{Brazilian Journal of Motor Behavior}}, number = {{3}}, pages = {{180--194}}, publisher = {{Brazilian Journal for Motor Behavior}}, title = {{{Mental body rotation with egocentric and object-based transformations in different postures: standing vs. balancing}}}, doi = {{10.20338/bjmb.v15i3.250}}, volume = {{15}}, year = {{2021}}, } @inproceedings{48037, author = {{Budde, Kirsten and Barela, José A and Figueiredo, Gabriella A and Weigelt, Matthias}}, booktitle = {{TeaP 2021 - Abstracts of the 63rd Conference of Experimental Psychologists.}}, editor = {{Huckauf, Anke and Baumann, Martin and Ernst, Marc and Herbert, Cornelia and Kiefer, Markus and Sauter, Marian}}, location = {{Ulm}}, pages = {{50}}, title = {{{Mental body rotation with egocentric and object-based transformations in different postures: sitting vs. standing.}}}, doi = {{10.23668/PSYCHARCHIVES.5178}}, year = {{2021}}, } @article{46545, abstract = {{Context: Only 55% of the athletes return to competitive sports after an anterior cruciate ligament (ACL) injury. Athletes younger than 25 years who return to sports have a second injury rate of 23%. There may be a mismatch between rehabilitation contents and the demands an athlete faces after returning to sports. Current return-to-sports (RTS) tests utilize closed and predictable motor skills; however, demands on the field are different. Neurocognitive functions are essential to manage dynamic sport situations and may fluctuate after peripheral injuries. Most RTS and rehabilitation paradigms appear to lack this aspect, which might be linked to increased risk of second injury. Objective: This systematic and scoping review aims to map existing evidence about neurocognitive and neurophysiological functions in athletes, which could be linked to ACL injury in an integrated fashion and bring an extensive perspective to assessment and rehabilitation approaches. Data Sources: PubMed and Cochrane databases were searched to identify relevant studies published between 2005 and 2020 using the keywords ACL, brain, cortical, neuroplasticity, cognitive, cognition, neurocognition, and athletes. Study Selection: Studies investigating either neurocognitive or neurophysiological functions in athletes and linking these to ACL injury regardless of their design and technique were included. Study Design: Systematic review. Level of Evidence: Level 3. Data Extraction: The demographic, temporal, neurological, and behavioral data revealing possible injury-related aspects were extracted and summarized. Results: A total of 16 studies were included in this review. Deficits in different neurocognitive domains and changes in neurophysiological functions could be a predisposing risk factor for, or a consequence caused by, ACL injuries. Conclusion: Clinicians should view ACL injuries not only as a musculoskeletal but also as a neural lesion with neurocognitive and neurophysiological aspects. Rehabilitation and RTS paradigms should consider these changes for assessment and interventions after injury. }}, author = {{Piskin, Daghan Yuksel and Benjaminse, Anne and Dimitrakis, Panagiotis and Gokeler, Alli}}, issn = {{1941-7381}}, journal = {{Sports Health: A Multidisciplinary Approach}}, keywords = {{Physical Therapy, Sports Therapy and Rehabilitation, Orthopedics and Sports Medicine}}, number = {{4}}, pages = {{549--555}}, publisher = {{SAGE Publications}}, title = {{{Neurocognitive and Neurophysiological Functions Related to ACL Injury: A Framework for Neurocognitive Approaches in Rehabilitation and Return-to-Sports Tests}}}, doi = {{10.1177/19417381211029265}}, volume = {{14}}, year = {{2021}}, } @techreport{53290, abstract = {{In this report, we consider a semiconductor nanostructure in an optical cavity that is coupled to quantum light. We describe the semiconductor nanostructure with a parabolic band structure in a 1D k-space, while we assume a single-mode quantum field. The 1D
system is chosen for simplicity in both the analytical and the numerical treatment and paves the way for the description of 2D structures in the future. Therefore, instead of using parameters which are realistic for 1D systems, we rather use parameters which qualitatively correspond to 2D GaAs structures.}}, author = {{Rose, H. and Vasil'ev, A.N. and Tikhonova, O.V. and Meier, Torsten and Sharapova, Polina R.}}, publisher = {{LibreCat University}}, title = {{{Excitation of an electronic band structure by a single-photon Fock state}}}, doi = {{10.5281/ZENODO.5774985}}, year = {{2021}}, } @article{41001, abstract = {{For entropic reasons, the synthesis of macrocycles via olefin ring-closing metathesis (RCM) is impeded by competing acyclic diene metathesis (ADMET) oligomerization. With cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes confined in tailored ordered mesoporous silica, RCM can be run with macrocyclization selectivities up to 98% and high substrate concentrations up to 0.1 M. Molecular dynamics simulations show that the high conversions are a direct result of the proximity between the surface-bound catalyst, proven by extended X-ray absorption spectroscopy, and the surface-located substrates. Back-diffusion of the macrocycles decreases with decreasing pore diameter of the silica and is responsible for the high macrocyclization efficiency. Also, Z-selectivity increases with decreasing pore diameter and increasing Tolman electronic parameter of the NHC. Running reactions at different concentrations allows for identifying the optimum substrate concentration for each material and substrate combination.}}, author = {{Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren and Bruckner, Johanna R. and Nowakowski, Michał and Weißer, Kilian and Solodenko, Helena and Schmitz, Guido and Bauer, Matthias and Hansen, Niels and Buchmeiser, Michael R.}}, issn = {{2155-5435}}, journal = {{ACS Catalysis}}, keywords = {{Catalysis, General Chemistry}}, number = {{18}}, pages = {{11570--11578}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes}}}, doi = {{10.1021/acscatal.1c03057}}, volume = {{11}}, year = {{2021}}, } @article{40999, abstract = {{Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl, NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous progenitors, the immobilized catalysts were used in the hydrosilylation of terminal alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and stereoselective catalysts, allowing for the formation of the thermodynamically less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15 immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement, showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes, too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with its homogenous counterpart. These are the first examples of high β(Z)-selectivity in the hydrosilylation of alkynes by confinement generated upon immobilization inside mesoporous silica.}}, author = {{Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michał and Bauer, Matthias and Buchmeiser, Michael R.}}, issn = {{0947-6539}}, journal = {{Chemistry – A European Journal}}, keywords = {{General Chemistry, Catalysis, Organic Chemistry}}, number = {{68}}, pages = {{17220--17229}}, publisher = {{Wiley}}, title = {{{Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}}}, doi = {{10.1002/chem.202103099}}, volume = {{27}}, year = {{2021}}, }