@article{62090,
  abstract     = {{<jats:p>The selective <jats:italic>N</jats:italic>-formylation and <jats:italic>N</jats:italic>-methylation of amines with carbon dioxide (CO<jats:sub>2</jats:sub>) catalyzed by methyltriphenylphosphonium methylcarbonate and tuned by polymethylhydrosiloxane or trimethoxysilane as reducing agents is reported.</jats:p>}},
  author       = {{Ren, Changyue and Terazzi, Constanza and Werner, Thomas}},
  issn         = {{1463-9262}},
  journal      = {{Green Chemistry}},
  keywords     = {{T1, T2, CSSD}},
  number       = {{1}},
  pages        = {{439--447}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Tuneable reduction of CO<sub>2</sub> – organocatalyzed selective formylation and methylation of amines}}},
  doi          = {{10.1039/d3gc03993e}},
  volume       = {{26}},
  year         = {{2024}},
}

@article{62091,
  author       = {{Ren, Changyue and Spannenberg, Anke and Werner, Thomas}},
  issn         = {{2168-0485}},
  journal      = {{ACS Sustainable Chemistry &amp; Engineering}},
  keywords     = {{T1, T2, CSSD}},
  number       = {{29}},
  pages        = {{10969--10977}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>}}},
  doi          = {{10.1021/acssuschemeng.4c03464}},
  volume       = {{12}},
  year         = {{2024}},
}

@article{62088,
  author       = {{Tönjes, Jan and Medvarić, Viktorija and Werner, Thomas}},
  issn         = {{0022-3263}},
  journal      = {{The Journal of Organic Chemistry}},
  keywords     = {{T2, CSSD}},
  number       = {{15}},
  pages        = {{10729--10735}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis}}},
  doi          = {{10.1021/acs.joc.4c00985}},
  volume       = {{89}},
  year         = {{2024}},
}

@article{62236,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>Due to its excellent biocompatibility, pure iron is a very promising implant material, but often features corrosion rates that are too low. Using additive manufacturing and modified powders the microstructure and, thus, the material properties, e.g., the corrosion properties, can be tailored for specific applications. Within the scope of this study, pure iron powder was modified with different amounts of CeO<jats:sub>2</jats:sub> or Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> nanoparticles and subsequently processed by Electron Beam Powder Bed Fusion (PBF-EB/M). The corrosion-fatigue behavior of CeO<jats:sub>2</jats:sub> and Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> modified iron was investigated using rotation bending tests under the influence of simulated body fluid (m-SBF). While the modification using Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> showed reduced fatigue and corrosion-fatigue strengths, it could be demonstrated that the modification with CeO<jats:sub>2</jats:sub> is characterized by improved fatigue properties. The superior fatigue properties in air are attributed to the positive impact of dispersion strengthening. Additionally, an increased degradation rate compared to pure iron could be observed, eventually promoting an earlier failure of the specimens in the corrosion fatigue tests.</jats:p>}},
  author       = {{Wackenrohr, Steffen and Torrent, Christof Johannes Jaime and Herbst, Sebastian and Nürnberger, Florian and Krooss, Philipp and Frenck, Johanna-Maria and Ebbert, Christoph and Voigt, Markus and Grundmeier, Guido and Niendorf, Thomas and Maier, Hans Jürgen}},
  issn         = {{2397-2106}},
  journal      = {{npj Materials Degradation}},
  number       = {{1}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{Corrosion fatigue behavior of nanoparticle modified iron processed by electron powder bed fusion}}},
  doi          = {{10.1038/s41529-024-00470-w}},
  volume       = {{8}},
  year         = {{2024}},
}

@article{62255,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>Cellular stress and ageing involve an increase in crowding and aggregation of amylogenic proteins. We here investigate if crowding is the intrinsic cause of aggregation and utilise a previously established non-protein aggregation sensor, namely pseudoisocyanine chloride (PIC). PIC shows fibrillization in cells into a highly fluorescent J-aggregated state and is sensitive to crowding. Surprisingly, cell stress conditions stabilise the monomeric rather than the aggregated state of PIC both in the cytoplasm and in stress granules. Regarding the different physiochemical changes of the cytoplasm occurring upon cell stress, involving volume reduction, phase separation and solidification, the intrinsic crowding effect is not the key factor to drive associated self-assembly processes.</jats:p>}},
  author       = {{Pollak, Roland and Koch, Leon and König, Benedikt and Ribeiro, Sara S. and Samanta, Nirnay and Huber, Klaus and Ebbinghaus, Simon}},
  issn         = {{2399-3669}},
  journal      = {{Communications Chemistry}},
  number       = {{1}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{Cell stress and phase separation stabilize the monomeric state of pseudoisocyanine chloride employed as a self-assembly crowding sensor}}},
  doi          = {{10.1038/s42004-024-01315-y}},
  volume       = {{7}},
  year         = {{2024}},
}

@article{62252,
  author       = {{Alfano, Caterina and Fichou, Yann and Huber, Klaus and Weiss, Matthias and Spruijt, Evan and Ebbinghaus, Simon and De Luca, Giuseppe and Morando, Maria Agnese and Vetri, Valeria and Temussi, Piero Andrea and Pastore, Annalisa}},
  issn         = {{0009-2665}},
  journal      = {{Chemical Reviews}},
  number       = {{6}},
  pages        = {{3186--3219}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Molecular Crowding: The History and Development of a Scientific Paradigm}}},
  doi          = {{10.1021/acs.chemrev.3c00615}},
  volume       = {{124}},
  year         = {{2024}},
}

@article{62251,
  author       = {{Müller, Wenke and Sroka, Weronika and Schweins, Ralf and Nöcker, Bernd and Poon, Jia-Fei and Huber, Klaus}},
  issn         = {{0743-7463}},
  journal      = {{Langmuir}},
  number       = {{17}},
  pages        = {{8872--8885}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Impact of Additive Hydrophilicity on Mixed Dye-Nonionic Surfactant Micelles: Micelle Morphology and Dye Localization}}},
  doi          = {{10.1021/acs.langmuir.4c00012}},
  volume       = {{40}},
  year         = {{2024}},
}

@article{62250,
  author       = {{Saha, Sanjib and Büngeler, Anne and Hense, Dominik and Strube, Oliver I. and Huber, Klaus}},
  issn         = {{0743-7463}},
  journal      = {{Langmuir}},
  number       = {{8}},
  pages        = {{4152--4163}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{On the Mechanism of Self-Assembly of Fibrinogen in Thrombin-free Aqueous Solution}}},
  doi          = {{10.1021/acs.langmuir.3c03132}},
  volume       = {{40}},
  year         = {{2024}},
}

@article{62254,
  author       = {{Koch, Leon and Saha, Sanjib and Huber, Klaus}},
  issn         = {{1948-7185}},
  journal      = {{The Journal of Physical Chemistry Letters}},
  number       = {{39}},
  pages        = {{9987--9993}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Impact of Temperature on the Self-Assembly of Fibrinogen in Thrombin-Free Solutions}}},
  doi          = {{10.1021/acs.jpclett.4c02180}},
  volume       = {{15}},
  year         = {{2024}},
}

@article{62253,
  author       = {{Koch, Leon and Pollak, Roland and Ebbinghaus, Simon and Huber, Klaus}},
  issn         = {{0743-7463}},
  journal      = {{Langmuir}},
  number       = {{31}},
  pages        = {{16151--16159}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Early Stages of FUS Droplet Formation via Liquid–Liquid Phase Separation}}},
  doi          = {{10.1021/acs.langmuir.4c01243}},
  volume       = {{40}},
  year         = {{2024}},
}

@article{55999,
  abstract     = {{Clean hydrogen is a key aspect of carbon neutrality, necessitating robust methods for monitoring hydrogen concentration in critical infrastructures like pipelines or power plants. While semiconducting metal oxides such as In2O3 can monitor gas concentrations down to the ppm range, they often exhibit cross-sensitivity to other gases like H2O. In this study, we investigated whether cyclic optical illumination of a gas-sensitive In2O3 layer creates identifiable changes in a gas sensor´s electronic resistance that can be linked to H2 and H2O concentrations via machine learning. We exposed nanostructured In2O3 with a large surface area of 95 m2 g-1 to H2 concentrations (0-800 ppm) and relative humidity (0-70%) under cyclic activation utilizing blue light. The sensors were tested for 20 classes of gas combinations. A support vector machine achieved classification rates up to 92.0%, with reliable reproducibility (88.2 ± 2.7%) across five individual sensors using 10-fold cross-validation. Our findings suggest that cyclic optical activation can be used as a tool to classify H2 and H2O concentrations.}},
  author       = {{Baier, Dominik  and Krüger, Alexander  and Wagner, Thorsten  and Tiemann, Michael and Weinberger, Christian}},
  issn         = {{2227-9040}},
  journal      = {{Chemosensors}},
  keywords     = {{resistive gas sensor, chemiresistor, semiconductor, metal oxide, In2O3, mesoporous, hydrogen, humidtiy, machine learning, sustainable}},
  number       = {{9}},
  pages        = {{178}},
  publisher    = {{MDPI}},
  title        = {{{Gas Sensing with Nanoporous In2O3 under Cyclic Optical Activation: Machine Learning-Aided Classification of H2 and H2O}}},
  doi          = {{10.3390/chemosensors12090178}},
  volume       = {{12}},
  year         = {{2024}},
}

@article{56267,
  author       = {{Serino, Laura and Ridder, Werner and Bhattacharjee, Abhinandan and Gil López, Jano and Brecht, Benjamin and Silberhorn, Christine}},
  issn         = {{2837-6714}},
  journal      = {{Optica Quantum}},
  publisher    = {{Optica Publishing Group}},
  title        = {{{Orchestrating time and color: a programmable source of high-dimensional entanglement}}},
  doi          = {{10.1364/opticaq.532334}},
  year         = {{2024}},
}

@inproceedings{54811,
  author       = {{Pollmeier, Pascal and Vogelsang, Christoph and Rogge, Tim}},
  booktitle    = {{Frühe naturwissenschaftliche Bildung}},
  editor       = {{van Vorst, Helena}},
  location     = {{Hamburg}},
  title        = {{{Eigenvideografien als Instrument zur Professionalisierung angehender Lehrkräfte}}},
  volume       = {{44}},
  year         = {{2024}},
}

@inbook{57767,
  author       = {{Pollmeier, Pascal and Stroop, Dietlinde and Fechner, Sabine}},
  booktitle    = {{Lehrkräftebildung in der digitalen Welt - Zukunftsorientierte Forschungs- und Praxisperspektiven}},
  editor       = {{Herzig, Bardo and Eickelmann, Birgit and Schwabl, Franszika and Schulze, Johanna and Niemann, Jan}},
  pages        = {{53--64}},
  publisher    = {{Waxmann}},
  title        = {{{Digitale Messwerterfassung im Chemieunterricht}}},
  year         = {{2024}},
}

@inbook{57769,
  author       = {{Peeters, Hendrik and Graute, André and Hansel, Jan-Luca and Fischer, Matthias and Fechner, Sabine}},
  booktitle    = {{Lehrkräftebildung in der digitalen Welt - Zukunftsorientierte Forschungs- und Praxisperspektiven}},
  editor       = {{Herzig, Bardo and Eickelmann, Birgit and Schwabl, Franziska and Schulze, Johanna and Niemann, Jan}},
  pages        = {{241--252}},
  publisher    = {{Waxmann}},
  title        = {{{VirtuChemLab - Ein VR-Unterstützungsformat zur Vorbereitung auf das reale Chemielabor}}},
  doi          = {{https://www.waxmann.com/shop/download?tx_p2waxmann_download%5Baction%5D=download&tx_p2waxmann_download%5Bbuchnr%5D=4837&tx_p2waxmann_download%5Bcontroller%5D=Zeitschrift&cHash=8a25fe58c1166ed639ec8ef14076a936}},
  volume       = {{1}},
  year         = {{2024}},
}

@article{62828,
  author       = {{Ruhm, Lukas and Löseke, Jannik and Vieth, Pascal and Prüßner, Tim and Grundmeier, Guido}},
  issn         = {{0169-4332}},
  journal      = {{Applied Surface Science}},
  publisher    = {{Elsevier BV}},
  title        = {{{Adhesion promotion and corrosion resistance of mixed phosphonic acid monolayers on AA 2024}}},
  doi          = {{10.1016/j.apsusc.2024.160655}},
  volume       = {{670}},
  year         = {{2024}},
}

@article{62873,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>Vapor phase infiltration (VPI) has emerged as a promising tool for fabrication of novel hybrid materials. In the field of polymeric gas separation membranes, a beneficial impact on stability and membrane performance is known for several polymers with differing functional groups. This study for the first time investigates VPI of trimethylaluminum (TMA) into poly(1‐trimethylsilyl‐1‐propyne) (PTMSP), featuring a carbon–carbon double bond as functional group. Saturation of the precursor inside the polymer is already attained after 60 s infiltration time leading to significant densification of the material. Depth profiling proves accumulation of aluminum in the polymer itself, but a significantly increased accumulation is visible in the gradient layer between polymer and SiO<jats:sub>2</jats:sub> substrate. A reaction pathway is proposed and supplemented by density‐functional theory (DFT) calculations. Infrared spectra derived from both experiments and simulation support the presented reaction pathway. In terms of permeance, a favorable impact on selectivity is observed for infiltration times up to 1 s. Longer infiltration times yield greatly reduced permeance values close or even below the detection limit of the measurement device. The present results of this study set a strong basis for the application of VPI on polymers for gas‐barrier and membrane applications in the future.</jats:p>}},
  author       = {{Jenderny, Jonathan and Boysen, Nils and Rubner, Jens and Zysk, Frederik and Preischel, Florian and de los Arcos de Pedro, Maria Teresa and Damerla, Varun Raj and Kostka, Aleksander and Franke, Jonas and Dahlmann, Rainer and Kühne, Thomas D. and Wessling, Matthias and Awakowicz, Peter and Devi, Anjana}},
  issn         = {{2196-7350}},
  journal      = {{Advanced Materials Interfaces}},
  number       = {{28}},
  publisher    = {{Wiley}},
  title        = {{{Tuning the Permeation Properties of Poly(1‐trimethylsilyl‐1‐propyne) by Vapor Phase Infiltration Using Trimethylaluminum}}},
  doi          = {{10.1002/admi.202400171}},
  volume       = {{11}},
  year         = {{2024}},
}

@article{52876,
  author       = {{Arends, Christian and Wolf, Lasse Lennart and Meinecke, Jasmin and Barkhofen, Sonja and Weich, Tobias and Bartley, Tim}},
  issn         = {{2643-1564}},
  journal      = {{Physical Review Research}},
  keywords     = {{General Physics and Astronomy}},
  number       = {{1}},
  publisher    = {{American Physical Society (APS)}},
  title        = {{{Decomposing large unitaries into multimode devices of arbitrary size}}},
  doi          = {{10.1103/physrevresearch.6.l012043}},
  volume       = {{6}},
  year         = {{2024}},
}

@article{55384,
  author       = {{Schröer, Franz and Schemel, Nele and Osnabrügge, Malin and Schneider, Lea and Tenberge, Claudia}},
  issn         = {{1360-1431}},
  journal      = {{Design and Technology Education: An International Journal}},
  number       = {{1}},
  publisher    = {{Liverpool John Moore's University}},
  title        = {{{Learning to Teach and Teaching to Learn about Robotics at primary level - Professionalization for inclusive technology education integrating Theory and Practice}}},
  volume       = {{29}},
  year         = {{2024}},
}

@inbook{58258,
  author       = {{Fechner, Sabine}},
  booktitle    = {{Wissenschaftsdidaktik als kritische Kommunikationsanalyse - Ein Sammelwerk zur Weiterführung eines Gedankens von Ludwig Huber}},
  editor       = {{Scharlau, Ingrid and Jenert, Tobias}},
  pages        = {{29--44}},
  publisher    = {{Budrich}},
  title        = {{{"Das ist einfach so!" - Eine kritische Analyse von Lehrwerken der Chemie in der Studieneingangsphase}}},
  year         = {{2024}},
}