@article{42517, author = {{Tapio, Kosti and Kielar, Charlotte and Parikka, Johannes M. and Keller, Adrian and Järvinen, Heini and Fahmy, Karim and Toppari, J. Jussi}}, issn = {{0897-4756}}, journal = {{Chemistry of Materials}}, keywords = {{Materials Chemistry, General Chemical Engineering, General Chemistry}}, pages = {{1961–1971}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Large-Scale Formation of DNA Origami Lattices on Silicon}}}, doi = {{10.1021/acs.chemmater.2c03190}}, volume = {{35}}, year = {{2023}}, } @article{42518, author = {{Pothineni, Bhanu Kiran and Keller, Adrian}}, issn = {{2699-9307}}, journal = {{Advanced NanoBiomed Research}}, keywords = {{General Medicine}}, publisher = {{Wiley}}, title = {{{Nanoparticle‐Based Formulations of Glycopeptide Antibiotics: A Means for Overcoming Vancomycin Resistance in Bacterial Pathogens?}}}, doi = {{10.1002/anbr.202200134}}, volume = {{3}}, year = {{2023}}, } @article{44503, author = {{Hanke, Marcel and Tomm, Emilia and Grundmeier, Guido and Keller, Adrian}}, issn = {{1439-4227}}, journal = {{ChemBioChem}}, keywords = {{Organic Chemistry, Molecular Biology, Molecular Medicine, Biochemistry}}, publisher = {{Wiley}}, title = {{{Effect of Ionic Strength on the Thermal Stability of DNA Origami Nanostructures}}}, doi = {{10.1002/cbic.202300338}}, year = {{2023}}, } @article{44504, author = {{Linko, Veikko and Keller, Adrian}}, issn = {{1613-6810}}, journal = {{Small}}, keywords = {{Biomaterials, Biotechnology, General Materials Science, General Chemistry}}, publisher = {{Wiley}}, title = {{{Stability of DNA Origami Nanostructures in Physiological Media: The Role of Molecular Interactions}}}, doi = {{10.1002/smll.202301935}}, year = {{2023}}, } @article{44523, author = {{Paradies, Jan}}, issn = {{0001-4842}}, journal = {{Accounts of Chemical Research}}, keywords = {{General Medicine, General Chemistry}}, number = {{7}}, pages = {{821--834}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed Hydrogenations, Dehydrogenations, and Cycloisomerizations}}}, doi = {{10.1021/acs.accounts.2c00832}}, volume = {{56}}, year = {{2023}}, } @book{44524, editor = {{Meier-Gräwe, Uta and Praetorius, Ina and Tecklenburg, Feline}}, isbn = {{9783847425922}}, pages = {{307}}, publisher = {{Verlag Barbara Budrich}}, title = {{{Wirtschaft neu ausrichten. Care-Initiativen in Deutschland, Österreich und der Schweiz.}}}, year = {{2023}}, } @article{44545, abstract = {{IntroductionExergames are increasingly used in rehabilitation settings for older adults to train physical and cognitive abilities. To meet the potential that exergames hold, they need to be adapted to the individual abilities of the player and their training objectives. Therefore, it is important to know whether and how game characteristics affect their playing. The aim of this study is to investigate the effect of two different kinds of exergame (step game and balance game) played at two difficulty levels on brain activity and physical activity.MethodsTwenty-eight older independently living adults played two different exergames at two difficulty levels each. In addition, the same movements as during gaming (leaning sideways with feet in place and stepping sideways) were performed as reference movements. Brain activity was recorded using a 64-channel EEG system to assess brain activity, while physical activity was recorded using an accelerometer at the lower back and a heart rate sensor. Source-space analysis was applied to analyze the power spectral density in theta (4 Hz–7 Hz) and alpha-2 (10 Hz–12 Hz) frequency bands. Vector magnitude was applied to the acceleration data.ResultsFriedman ANOVA revealed significantly higher theta power for the exergaming conditions compared to the reference movement for both games. Alpha-2 power showed a more diverse pattern which might be attributed to task-specific conditions. Acceleration decreased significantly from the reference movement to the easy condition to the hard condition for both games.DiscussionThe results indicate that exergaming increases frontal theta activity irrespective of type of game or difficulty level, while physical activity decreases with increasing difficulty level. Heart rate was found to be an inappropriate measure in this population older adults. These findings contribute to understanding of how game characteristics affect physical and cognitive activity and consequently need to be taken into account when choosing appropriate games and game settings for exergame interventions.}}, author = {{Müller, Helen and Baumeister, Jochen and Bardal, Ellen Marie and Vereijken, Beatrix and Skjæret-Maroni, Nina}}, issn = {{1663-4365}}, journal = {{Frontiers in Aging Neuroscience}}, keywords = {{Cognitive Neuroscience, Aging}}, publisher = {{Frontiers Media SA}}, title = {{{Exergaming in older adults: the effects of game characteristics on brain activity and physical activity}}}, doi = {{10.3389/fnagi.2023.1143859}}, volume = {{15}}, year = {{2023}}, } @article{44044, abstract = {{Dispersion is present in every optical setup and is often an undesired effect, especially in nonlinear-optical experiments where ultrashort laser pulses are needed. Typically, bulky pulse compressors consisting of gratings or prisms are used to address this issue by precompensating the dispersion of the optical components. However, these devices are only able to compensate for a part of the dispersion (second-order dispersion). Here, we present a compact pulse-shaping device that uses plasmonic metasurfaces to apply an arbitrarily designed spectral phase delay allowing for a full dispersion control. Furthermore, with specific phase encodings, this device can be used to temporally reshape the incident laser pulses into more complex pulse forms such as a double pulse. We verify the performance of our device by using an SHG-FROG measurement setup together with a retrieval algorithm to extract the dispersion that our device applies to an incident laser pulse.}}, author = {{Geromel, René and Georgi, Philip and Protte, Maximilian and Lei, Shiwei and Bartley, Tim and Huang, Lingling and Zentgraf, Thomas}}, issn = {{1530-6984}}, journal = {{Nano Letters}}, keywords = {{Mechanical Engineering, Condensed Matter Physics, General Materials Science, General Chemistry, Bioengineering}}, number = {{8}}, pages = {{3196 -- 3201}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Compact Metasurface-Based Optical Pulse-Shaping Device}}}, doi = {{10.1021/acs.nanolett.2c04980}}, volume = {{23}}, year = {{2023}}, } @article{44837, abstract = {{Hydrothermal carbonization (HTC) is an efficient thermochemical method for the conversion of organic feedstock to carbonaceous solids. HTC of different saccharides is known to produce microspheres (MS) with mostly Gaussian size distribution, which are utilized as functional materials in various applications, both as pristine MS and as a precursor for hard carbon MS. Although the average size of the MS can be influenced by adjusting the process parameters, there is no reliable mechanism to affect their size distribution. Our results demonstrate that HTC of trehalose, in contrast to other saccharides, results in a distinctly bimodal sphere diameter distribution consisting of small spheres with diameters of (2.1 ± 0.2) μm and of large spheres with diameters of (10.4 ± 2.6) μm. Remarkably, after pyrolytic post-carbonization at 1000 °C the MS develop a multimodal pore size distribution with abundant macropores > 100 nm, mesopores > 10 nm and micropores < 2 nm, which were examined by small-angle X-ray scattering and visualized by charge-compensated helium ion microscopy. The bimodal size distribution and hierarchical porosity provide an extraordinary set of properties and potential variables for the tailored synthesis of hierarchical porous carbons, making trehalose-derived hard carbon MS a highly promising material for applications in catalysis, filtration, and energy storage devices.}}, author = {{Wortmann, Martin and Keil, Waldemar and Diestelhorst, Elise and Westphal, Michael and Haverkamp, René and Brockhagen, Bennet and Biedinger, Jan and Bondzio, Laila and Weinberger, Christian and Baier, Dominik and Tiemann, Michael and Hütten, Andreas and Hellweg, Thomas and Reiss, Günter and Schmidt, Claudia and Sattler, Klaus and Frese, Natalie}}, issn = {{2046-2069}}, journal = {{RSC Advances}}, keywords = {{General Chemical Engineering, General Chemistry}}, number = {{21}}, pages = {{14181--14189}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Hard carbon microspheres with bimodal size distribution and hierarchical porosity via hydrothermal carbonization of trehalose}}}, doi = {{10.1039/d3ra01301d}}, volume = {{13}}, year = {{2023}}, } @article{45013, author = {{Codescu, M.-A. and Kunze, T. and Weiß, M. and Brehm, Martin and Kornilov, O. and Sebastiani, D. and Nibbering, E. T. J.}}, journal = {{J. Phys. Chem. Lett.}}, pages = {{4775--4785}}, title = {{{Ultrafast Proton Transfer Pathways Mediated by Amphoteric Imidazole}}}, doi = {{10.1021/acs.jpclett.3c00595}}, volume = {{14}}, year = {{2023}}, } @article{45012, author = {{Roos, E. and Sebastiani, D. and Brehm, Martin}}, journal = {{Phys. Chem. Chem. Phys.}}, pages = {{8755--8766}}, title = {{{A Force Field for Bio-Polymers in Ionic Liquids (BILFF) – Part 2: Cellulose in [EMIm][OAc] / Water Mixtures}}}, doi = {{10.1039/D2CP05636D}}, volume = {{25 (12)}}, year = {{2023}}, } @article{45011, author = {{Radicke, J. and Roos, E. and Sebastiani, D. and Brehm, Martin and Kressler, J.}}, journal = {{J. Polym. Sci.}}, pages = {{372--384}}, title = {{{Lactate-Based Ionic Liquids as Chiral Solvents for Cellulose}}}, doi = {{10.1002/pol.20220687}}, volume = {{61 (5)}}, year = {{2023}}, } @article{45134, abstract = {{The aim of the present study was to investigate if the presence of anterior cruciate ligament (ACL) injury risk factors depicted in the laboratory would reflect at-risk patterns in football-specific field data. Twenty-four female footballers (14.9 ± 0.9 year) performed unanticipated cutting maneuvers in a laboratory setting and on the football pitch during football-specific exercises (F-EX) and games (F-GAME). Knee joint moments were collected in the laboratory and grouped using hierarchical agglomerative clustering. The clusters were used to investigate the kinematics collected on field through wearable sensors. Three clusters emerged: Cluster 1 presented the lowest knee moments; Cluster 2 presented high knee extension but low knee abduction and rotation moments; Cluster 3 presented the highest knee abduction, extension, and external rotation moments. In F-EX, greater knee abduction angles were found in Cluster 2 and 3 compared to Cluster 1 (p = 0.007). Cluster 2 showed the lowest knee and hip flexion angles (p < 0.013). Cluster 3 showed the greatest hip external rotation angles (p = 0.006). In F-GAME, Cluster 3 presented the greatest knee external rotation and lowest knee flexion angles (p = 0.003). Clinically relevant differences towards ACL injury identified in the laboratory reflected at-risk patterns only in part when cutting on the field: in the field, low-risk players exhibited similar kinematic patterns as the high-risk players. Therefore, in-lab injury risk screening may lack ecological validity.}}, author = {{Di Paolo, Stefano and Nijmeijer, Eline M. and Bragonzoni, Laura and Gokeler, Alli and Benjaminse, Anne}}, issn = {{1424-8220}}, journal = {{Sensors}}, keywords = {{Electrical and Electronic Engineering, Biochemistry, Instrumentation, Atomic and Molecular Physics, and Optics, Analytical Chemistry}}, number = {{4}}, publisher = {{MDPI AG}}, title = {{{Definition of High-Risk Motion Patterns for Female ACL Injury Based on Football-Specific Field Data: A Wearable Sensors Plus Data Mining Approach}}}, doi = {{10.3390/s23042176}}, volume = {{23}}, year = {{2023}}, } @article{45154, author = {{Gokeler, Alli and Nijmeijer, E. M. and Heuvelmans, P. and Tak, I. and Ramponi, C. and Benjaminse, A.}}, issn = {{0933-7946}}, journal = {{Arthroskopie}}, keywords = {{Orthopedics and Sports Medicine}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Motor learning principles during rehabilitation after anterior cruciate ligament injury Prinzipien motorischen Lernens während der Rehabilitation nach vorderer Kreuzbandverletzung}}}, doi = {{10.1007/s00142-023-00606-1}}, year = {{2023}}, } @article{45159, author = {{Sherman, David A. and Baumeister, Jochen and Stock, Matt S. and Murray, Amanda M. and Bazett-Jones, David M. and Norte, Grant E.}}, issn = {{1388-2457}}, journal = {{Clinical Neurophysiology}}, keywords = {{Physiology (medical), Neurology (clinical), Neurology, Sensory Systems}}, pages = {{88--99}}, publisher = {{Elsevier BV}}, title = {{{Brain activation and single-limb balance following anterior cruciate ligament reconstruction}}}, doi = {{10.1016/j.clinph.2023.02.175}}, volume = {{149}}, year = {{2023}}, } @article{45149, abstract = {{IntroductionExergames are increasingly used in rehabilitation settings for older adults to train physical and cognitive abilities. To meet the potential that exergames hold, they need to be adapted to the individual abilities of the player and their training objectives. Therefore, it is important to know whether and how game characteristics affect their playing. The aim of this study is to investigate the effect of two different kinds of exergame (step game and balance game) played at two difficulty levels on brain activity and physical activity.MethodsTwenty-eight older independently living adults played two different exergames at two difficulty levels each. In addition, the same movements as during gaming (leaning sideways with feet in place and stepping sideways) were performed as reference movements. Brain activity was recorded using a 64-channel EEG system to assess brain activity, while physical activity was recorded using an accelerometer at the lower back and a heart rate sensor. Source-space analysis was applied to analyze the power spectral density in theta (4 Hz–7 Hz) and alpha-2 (10 Hz–12 Hz) frequency bands. Vector magnitude was applied to the acceleration data.ResultsFriedman ANOVA revealed significantly higher theta power for the exergaming conditions compared to the reference movement for both games. Alpha-2 power showed a more diverse pattern which might be attributed to task-specific conditions. Acceleration decreased significantly from the reference movement to the easy condition to the hard condition for both games.DiscussionThe results indicate that exergaming increases frontal theta activity irrespective of type of game or difficulty level, while physical activity decreases with increasing difficulty level. Heart rate was found to be an inappropriate measure in this population older adults. These findings contribute to understanding of how game characteristics affect physical and cognitive activity and consequently need to be taken into account when choosing appropriate games and game settings for exergame interventions.}}, author = {{Müller, Helen Martha and Baumeister, Jochen and Bardal, Ellen Marie and Vereijken, Beatrix and Skjæret-Maroni, Nina}}, issn = {{1663-4365}}, journal = {{Frontiers in Aging Neuroscience}}, keywords = {{Cognitive Neuroscience, Aging}}, publisher = {{Frontiers Media SA}}, title = {{{Exergaming in older adults: the effects of game characteristics on brain activity and physical activity}}}, doi = {{10.3389/fnagi.2023.1143859}}, volume = {{15}}, year = {{2023}}, } @article{43092, abstract = {{By using coordinating anions such as acetate, a water-in-salt-like coordination environment of Zn ions is achieved in relatively dilute conditions, leading to prolonged and efficient cycling of zinc metal anodes.}}, author = {{Gomez Vazquez, Dario and Pollard, Travis P. and Mars, Julian and Yoo, Ji Mun and Steinrück, Hans-Georg and Bone, Sharon E. and Safonova, Olga V. and Toney, Michael F. and Borodin, Oleg and Lukatskaya, Maria R.}}, issn = {{1754-5692}}, journal = {{Energy & Environmental Science}}, keywords = {{Pollution, Nuclear Energy and Engineering, Renewable Energy, Sustainability and the Environment, Environmental Chemistry}}, pages = {{1982--1991 (2023).}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Creating water-in-salt-like environment using coordinating anions in non-concentrated aqueous electrolytes for efficient Zn batteries}}}, doi = {{10.1039/d3ee00205e}}, volume = {{16}}, year = {{2023}}, } @article{44271, author = {{Weadock, Nicholas J. and Sterling, Tyler C. and Vigil, Julian A. and Gold-Parker, Aryeh and Smith, Ian C. and Ahammed, Ballal and Krogstad, Matthew J. and Ye, Feng and Voneshen, David and Gehring, Peter M. and Rappe, Andrew M. and Steinrück, Hans-Georg and Ertekin, Elif and Karunadasa, Hemamala I. and Reznik, Dmitry and Toney, Michael F.}}, issn = {{2542-4351}}, journal = {{Joule}}, keywords = {{General Energy}}, pages = {{1051--1066}}, publisher = {{Elsevier BV}}, title = {{{The nature of dynamic local order in CH3NH3PbI3 and CH3NH3PbBr3}}}, doi = {{10.1016/j.joule.2023.03.017}}, volume = {{7}}, year = {{2023}}, } @inbook{45171, author = {{Weiler, David and Burde, Jan-Philipp and Große-Heilmann, Rike Isabel and Lachner, Andreas and Riese, Josef and Schubatzky, Thomas}}, booktitle = {{Lehr-Lern-Labore und Digitalisierung}}, editor = {{Meier, Monique and Greefrath, Gilbert and Hammann, Marcus and Wodzinski, Rita and Ziepprecht, Kathrin}}, isbn = {{9783658401085}}, issn = {{2524-8677}}, pages = {{47--62}}, publisher = {{Springer Fachmedien Wiesbaden}}, title = {{{Förderung von digitalisierungsbezogenen Kompetenzen von angehenden Physiklehrkräften mit dem SQD-Modell im Projekt DiKoLeP}}}, doi = {{10.1007/978-3-658-40109-2_4}}, year = {{2023}}, } @article{45485, author = {{Kruse, Stephan and Serino, Laura and Folge, Patrick Fabian and Echeverria Oviedo, Dana and Bhattacharjee, Abhinandan and Stefszky, Michael and Scheytt, J. Christoph and Brecht, Benjamin and Silberhorn, Christine}}, issn = {{1041-1135}}, journal = {{IEEE Photonics Technology Letters}}, keywords = {{Electrical and Electronic Engineering, Atomic and Molecular Physics, and Optics, Electronic, Optical and Magnetic Materials}}, number = {{14}}, pages = {{769--772}}, publisher = {{Institute of Electrical and Electronics Engineers (IEEE)}}, title = {{{A Pulsed Lidar System With Ultimate Quantum Range Accuracy}}}, doi = {{10.1109/lpt.2023.3277515}}, volume = {{35}}, year = {{2023}}, }