[{"publication_identifier":{"issn":["0039-7881","1437-210X"]},"author":[{"orcid":"0000-0001-9025-3244","first_name":"Thomas","last_name":"Werner","full_name":"Werner, Thomas","id":"89271"},{"full_name":"Grandane, Aiga","last_name":"Grandane","first_name":"Aiga"},{"last_name":"Pudnika","first_name":"Linda","full_name":"Pudnika, Linda"},{"full_name":"Domraceva, Ilona","first_name":"Ilona","last_name":"Domraceva"},{"full_name":"Zalubovskis, Raivis","last_name":"Zalubovskis","first_name":"Raivis"}],"title":"Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones","year":"2021","intvolume":" 53","date_updated":"2025-11-10T08:47:47Z","publication_status":"published","language":[{"iso":"eng"}],"doi":"10.1055/a-1509-6078","issue":"19","publication":"Synthesis","abstract":[{"text":"AbstractThe facile synthesis of highly functionalized building blocks with potential biological activity is of great interest to medicinal chemistry. The benzoxepinone core structures commonly exhibit biological activity. Thus, a short and efficient synthetic route towards benzoxepine containing scaffold, which enables late stage modification was developed. Namely, base-free catalytic Wittig reactions enabled the synthesis of bromobenzoxepinones from readily available starting materials. Subsequent, Suzuki–Miyaura and Stille reactions proved to be suitable methods to access a variety of benzoxepinone diaryl derivatives by late stage modification in only three steps. This three-step reaction sequence is suitable for high throughput applications and gives facile access to highly complex molecular structures, which are suitable for further functionalization. The antiproliferative properties of selected arylbenzoxepinones were tested in vitro on monolayer tumor cell line A549. Notably, in this initial screening, these compounds were found to be active in the micromolar range.","lang":"eng"}],"date_created":"2023-01-22T20:27:34Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["T2","T4","CSSD"],"type":"journal_article","status":"public","_id":"37946","publisher":"Georg Thieme Verlag KG","page":"3545-3554","volume":53,"user_id":"89271","citation":{"ieee":"T. Werner, A. Grandane, L. Pudnika, I. Domraceva, and R. Zalubovskis, “Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones,” Synthesis, vol. 53, no. 19, pp. 3545–3554, 2021, doi: 10.1055/a-1509-6078.","apa":"Werner, T., Grandane, A., Pudnika, L., Domraceva, I., & Zalubovskis, R. (2021). Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones. Synthesis, 53(19), 3545–3554. https://doi.org/10.1055/a-1509-6078","chicago":"Werner, Thomas, Aiga Grandane, Linda Pudnika, Ilona Domraceva, and Raivis Zalubovskis. “Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones.” Synthesis 53, no. 19 (2021): 3545–54. https://doi.org/10.1055/a-1509-6078.","short":"T. Werner, A. Grandane, L. Pudnika, I. Domraceva, R. Zalubovskis, Synthesis 53 (2021) 3545–3554.","mla":"Werner, Thomas, et al. “Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones.” Synthesis, vol. 53, no. 19, Georg Thieme Verlag KG, 2021, pp. 3545–54, doi:10.1055/a-1509-6078.","bibtex":"@article{Werner_Grandane_Pudnika_Domraceva_Zalubovskis_2021, title={Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones}, volume={53}, DOI={10.1055/a-1509-6078}, number={19}, journal={Synthesis}, publisher={Georg Thieme Verlag KG}, author={Werner, Thomas and Grandane, Aiga and Pudnika, Linda and Domraceva, Ilona and Zalubovskis, Raivis}, year={2021}, pages={3545–3554} }","ama":"Werner T, Grandane A, Pudnika L, Domraceva I, Zalubovskis R. Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones. Synthesis. 2021;53(19):3545-3554. doi:10.1055/a-1509-6078"}},{"intvolume":" 12","date_updated":"2025-11-10T08:49:01Z","publication_status":"published","author":[{"full_name":"Liu, Xin","first_name":"Xin","last_name":"Liu"},{"orcid":"https://orcid.org/0000-0001-9025-3244","last_name":"Werner","first_name":"Thomas","full_name":"Werner, Thomas","id":"89271"}],"publication_identifier":{"issn":["2041-6520","2041-6539"]},"year":"2021","title":"Indirect reduction of CO2 and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes","doi":"10.1039/d1sc02663a","language":[{"iso":"eng"}],"abstract":[{"text":"A Mn–PNP complex proved to be a suitable catalyst for the transfer hydrogenation of amides, carbamates, urea derivatives and even polyurethanes.
","lang":"eng"}],"publication":"Chemical Science","issue":"31","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["T1","T3","CSSD"],"date_created":"2023-01-22T20:24:03Z","status":"public","volume":12,"user_id":"89271","publisher":"Royal Society of Chemistry (RSC)","_id":"37944","page":"10590-10597","citation":{"ieee":"X. Liu and T. Werner, “Indirect reduction of CO2 and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes,” Chemical Science, vol. 12, no. 31, pp. 10590–10597, 2021, doi: 10.1039/d1sc02663a.","apa":"Liu, X., & Werner, T. (2021). Indirect reduction of CO2 and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes. Chemical Science, 12(31), 10590–10597. https://doi.org/10.1039/d1sc02663a","chicago":"Liu, Xin, and Thomas Werner. “Indirect Reduction of CO2 and Recycling of Polymers by Manganese-Catalyzed Transfer Hydrogenation of Amides, Carbamates, Urea Derivatives, and Polyurethanes.” Chemical Science 12, no. 31 (2021): 10590–97. https://doi.org/10.1039/d1sc02663a.","short":"X. Liu, T. Werner, Chemical Science 12 (2021) 10590–10597.","mla":"Liu, Xin, and Thomas Werner. “Indirect Reduction of CO2 and Recycling of Polymers by Manganese-Catalyzed Transfer Hydrogenation of Amides, Carbamates, Urea Derivatives, and Polyurethanes.” Chemical Science, vol. 12, no. 31, Royal Society of Chemistry (RSC), 2021, pp. 10590–97, doi:10.1039/d1sc02663a.","bibtex":"@article{Liu_Werner_2021, title={Indirect reduction of CO2 and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes}, volume={12}, DOI={10.1039/d1sc02663a}, number={31}, journal={Chemical Science}, publisher={Royal Society of Chemistry (RSC)}, author={Liu, Xin and Werner, Thomas}, year={2021}, pages={10590–10597} }","ama":"Liu X, Werner T. Indirect reduction of CO2 and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes. Chemical Science. 2021;12(31):10590-10597. doi:10.1039/d1sc02663a"}},{"citation":{"mla":"Tönjes, Jan, et al. “Poly(Methylhydrosiloxane) as a Reductant in the Catalytic Base-Free Wittig Reaction.” Green Chemistry, vol. 23, no. 13, Royal Society of Chemistry (RSC), 2021, pp. 4852–57, doi:10.1039/d1gc00953b.","apa":"Tönjes, J., Longwitz, L., & Werner, T. (2021). Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction. Green Chemistry, 23(13), 4852–4857. https://doi.org/10.1039/d1gc00953b","ieee":"J. Tönjes, L. Longwitz, and T. Werner, “Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction,” Green Chemistry, vol. 23, no. 13, pp. 4852–4857, 2021, doi: 10.1039/d1gc00953b.","short":"J. Tönjes, L. Longwitz, T. Werner, Green Chemistry 23 (2021) 4852–4857.","ama":"Tönjes J, Longwitz L, Werner T. Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction. Green Chemistry. 2021;23(13):4852-4857. doi:10.1039/d1gc00953b","chicago":"Tönjes, Jan, Lars Longwitz, and Thomas Werner. “Poly(Methylhydrosiloxane) as a Reductant in the Catalytic Base-Free Wittig Reaction.” Green Chemistry 23, no. 13 (2021): 4852–57. https://doi.org/10.1039/d1gc00953b.","bibtex":"@article{Tönjes_Longwitz_Werner_2021, title={Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction}, volume={23}, DOI={10.1039/d1gc00953b}, number={13}, journal={Green Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Tönjes, Jan and Longwitz, Lars and Werner, Thomas}, year={2021}, pages={4852–4857} }"},"user_id":"89271","volume":23,"page":"4852-4857","publisher":"Royal Society of Chemistry (RSC)","_id":"37945","status":"public","type":"journal_article","keyword":["T2","CSSD"],"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"date_created":"2023-01-22T20:25:13Z","abstract":[{"text":"PMHS proved to be a suitable terminal reductant for P(iii)/P(v) redox cycling with a methyl-substituted phosphetane as catalyst and BuOAc as solvent. The formation of water by silanol condensation was identified as main pathway of siloxane formation.
","lang":"eng"}],"issue":"13","publication":"Green Chemistry","doi":"10.1039/d1gc00953b","language":[{"iso":"eng"}],"publication_status":"published","date_updated":"2025-11-10T08:48:01Z","intvolume":" 23","title":"Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction","year":"2021","author":[{"full_name":"Tönjes, Jan","first_name":"Jan","last_name":"Tönjes"},{"last_name":"Longwitz","first_name":"Lars","full_name":"Longwitz, Lars"},{"id":"89271","last_name":"Werner","orcid":"0000-0001-9025-3244","first_name":"Thomas","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["1463-9262","1463-9270"]}},{"date_created":"2025-11-05T15:26:05Z","department":[{"_id":"35"},{"_id":"2"}],"keyword":["T4","CSSD"],"type":"journal_article","issue":"1","publication":"Organic Process Research & Development","language":[{"iso":"eng"}],"doi":"10.1021/acs.oprd.0c00423","publication_identifier":{"issn":["1083-6160","1520-586X"]},"author":[{"first_name":"Vivian","last_name":"Stefanow","full_name":"Stefanow, Vivian"},{"last_name":"Grandane","first_name":"Aiga","full_name":"Grandane, Aiga"},{"last_name":"Eh","first_name":"Marcus","full_name":"Eh, Marcus"},{"first_name":"Johannes","last_name":"Panten","full_name":"Panten, Johannes"},{"last_name":"Spannenberg","first_name":"Anke","full_name":"Spannenberg, Anke"},{"id":"89271","full_name":"Werner, Thomas","orcid":"0000-0001-9025-3244","first_name":"Thomas","last_name":"Werner"}],"year":"2021","title":"Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant","intvolume":" 25","publication_status":"published","date_updated":"2025-11-10T08:48:33Z","citation":{"apa":"Stefanow, V., Grandane, A., Eh, M., Panten, J., Spannenberg, A., & Werner, T. (2021). Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. Organic Process Research & Development, 25(1), 89–97. https://doi.org/10.1021/acs.oprd.0c00423","ieee":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, and T. Werner, “Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant,” Organic Process Research & Development, vol. 25, no. 1, pp. 89–97, 2021, doi: 10.1021/acs.oprd.0c00423.","chicago":"Stefanow, Vivian, Aiga Grandane, Marcus Eh, Johannes Panten, Anke Spannenberg, and Thomas Werner. “Stereoselective Synthesis of aCis-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” Organic Process Research & Development 25, no. 1 (2021): 89–97. https://doi.org/10.1021/acs.oprd.0c00423.","short":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, T. Werner, Organic Process Research & Development 25 (2021) 89–97.","mla":"Stefanow, Vivian, et al. “Stereoselective Synthesis of aCis-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” Organic Process Research & Development, vol. 25, no. 1, American Chemical Society (ACS), 2021, pp. 89–97, doi:10.1021/acs.oprd.0c00423.","ama":"Stefanow V, Grandane A, Eh M, Panten J, Spannenberg A, Werner T. Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. Organic Process Research & Development. 2021;25(1):89-97. doi:10.1021/acs.oprd.0c00423","bibtex":"@article{Stefanow_Grandane_Eh_Panten_Spannenberg_Werner_2021, title={Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant}, volume={25}, DOI={10.1021/acs.oprd.0c00423}, number={1}, journal={Organic Process Research & Development}, publisher={American Chemical Society (ACS)}, author={Stefanow, Vivian and Grandane, Aiga and Eh, Marcus and Panten, Johannes and Spannenberg, Anke and Werner, Thomas}, year={2021}, pages={89–97} }"},"publisher":"American Chemical Society (ACS)","_id":"62098","page":"89-97","volume":25,"user_id":"89271","status":"public"},{"title":"Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant","year":"2021","publication_identifier":{"issn":["1083-6160","1520-586X"]},"author":[{"first_name":"Vivian","last_name":"Stefanow","full_name":"Stefanow, Vivian"},{"full_name":"Grandane, Aiga","last_name":"Grandane","first_name":"Aiga"},{"first_name":"Marcus","last_name":"Eh","full_name":"Eh, Marcus"},{"full_name":"Panten, Johannes","last_name":"Panten","first_name":"Johannes"},{"full_name":"Spannenberg, Anke","first_name":"Anke","last_name":"Spannenberg"},{"id":"89271","first_name":"Thomas","orcid":"0000-0001-9025-3244","last_name":"Werner","full_name":"Werner, Thomas"}],"date_updated":"2025-11-10T08:49:27Z","publication_status":"published","intvolume":" 25","language":[{"iso":"eng"}],"doi":"10.1021/acs.oprd.0c00423","issue":"1","publication":"Organic Process Research & Development","date_created":"2025-11-05T15:28:23Z","type":"journal_article","keyword":["T4","CSSD"],"department":[{"_id":"35"},{"_id":"2"}],"status":"public","page":"89-97","_id":"62099","publisher":"American Chemical Society (ACS)","user_id":"89271","volume":25,"citation":{"bibtex":"@article{Stefanow_Grandane_Eh_Panten_Spannenberg_Werner_2021, title={Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant}, volume={25}, DOI={10.1021/acs.oprd.0c00423}, number={1}, journal={Organic Process Research & Development}, publisher={American Chemical Society (ACS)}, author={Stefanow, Vivian and Grandane, Aiga and Eh, Marcus and Panten, Johannes and Spannenberg, Anke and Werner, Thomas}, year={2021}, pages={89–97} }","ama":"Stefanow V, Grandane A, Eh M, Panten J, Spannenberg A, Werner T. Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. Organic Process Research & Development. 2021;25(1):89-97. doi:10.1021/acs.oprd.0c00423","mla":"Stefanow, Vivian, et al. “Stereoselective Synthesis of aCis-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” Organic Process Research & Development, vol. 25, no. 1, American Chemical Society (ACS), 2021, pp. 89–97, doi:10.1021/acs.oprd.0c00423.","short":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, T. Werner, Organic Process Research & Development 25 (2021) 89–97.","chicago":"Stefanow, Vivian, Aiga Grandane, Marcus Eh, Johannes Panten, Anke Spannenberg, and Thomas Werner. “Stereoselective Synthesis of aCis-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” Organic Process Research & Development 25, no. 1 (2021): 89–97. https://doi.org/10.1021/acs.oprd.0c00423.","ieee":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, and T. Werner, “Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant,” Organic Process Research & Development, vol. 25, no. 1, pp. 89–97, 2021, doi: 10.1021/acs.oprd.0c00423.","apa":"Stefanow, V., Grandane, A., Eh, M., Panten, J., Spannenberg, A., & Werner, T. (2021). Stereoselective Synthesis of acis-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. Organic Process Research & Development, 25(1), 89–97. https://doi.org/10.1021/acs.oprd.0c00423"}},{"status":"public","_id":"37943","publisher":"Elsevier BV","volume":225,"user_id":"89271","citation":{"apa":"Wirth, M. A., Longwitz, L., Kanwischer, M., Gros, P., Leinweber, P., & Werner, T. (2021). AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate. Ecotoxicology and Environmental Safety, 225, Article 112768. https://doi.org/10.1016/j.ecoenv.2021.112768","ieee":"M. A. Wirth, L. Longwitz, M. Kanwischer, P. Gros, P. Leinweber, and T. Werner, “AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate,” Ecotoxicology and Environmental Safety, vol. 225, Art. no. 112768, 2021, doi: 10.1016/j.ecoenv.2021.112768.","short":"M.A. Wirth, L. Longwitz, M. Kanwischer, P. Gros, P. Leinweber, T. Werner, Ecotoxicology and Environmental Safety 225 (2021).","chicago":"Wirth, Marisa A., Lars Longwitz, Marion Kanwischer, Peter Gros, Peter Leinweber, and Thomas Werner. “AMPA-15N – Synthesis and Application as Standard Compound in Traceable Degradation Studies of Glyphosate.” Ecotoxicology and Environmental Safety 225 (2021). https://doi.org/10.1016/j.ecoenv.2021.112768.","mla":"Wirth, Marisa A., et al. “AMPA-15N – Synthesis and Application as Standard Compound in Traceable Degradation Studies of Glyphosate.” Ecotoxicology and Environmental Safety, vol. 225, 112768, Elsevier BV, 2021, doi:10.1016/j.ecoenv.2021.112768.","ama":"Wirth MA, Longwitz L, Kanwischer M, Gros P, Leinweber P, Werner T. AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate. Ecotoxicology and Environmental Safety. 2021;225. doi:10.1016/j.ecoenv.2021.112768","bibtex":"@article{Wirth_Longwitz_Kanwischer_Gros_Leinweber_Werner_2021, title={AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate}, volume={225}, DOI={10.1016/j.ecoenv.2021.112768}, number={112768}, journal={Ecotoxicology and Environmental Safety}, publisher={Elsevier BV}, author={Wirth, Marisa A. and Longwitz, Lars and Kanwischer, Marion and Gros, Peter and Leinweber, Peter and Werner, Thomas}, year={2021} }"},"publication_identifier":{"issn":["0147-6513"]},"author":[{"full_name":"Wirth, Marisa A.","first_name":"Marisa A.","last_name":"Wirth"},{"full_name":"Longwitz, Lars","first_name":"Lars","last_name":"Longwitz"},{"full_name":"Kanwischer, Marion","last_name":"Kanwischer","first_name":"Marion"},{"first_name":"Peter","last_name":"Gros","full_name":"Gros, Peter"},{"last_name":"Leinweber","first_name":"Peter","full_name":"Leinweber, Peter"},{"last_name":"Werner","first_name":"Thomas","orcid":"https://orcid.org/0000-0001-9025-3244","full_name":"Werner, Thomas","id":"89271"}],"year":"2021","title":"AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate","intvolume":" 225","publication_status":"published","date_updated":"2025-11-10T08:48:20Z","language":[{"iso":"eng"}],"article_number":"112768","doi":"10.1016/j.ecoenv.2021.112768","publication":"Ecotoxicology and Environmental Safety","date_created":"2023-01-22T20:23:06Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["T4","CSSD"]},{"citation":{"short":"X. Liu, T. Werner, Advanced Synthesis and Catalysis 363 (2021) 1096–1104.","chicago":"Liu, Xin, and Thomas Werner. “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides.” Advanced Synthesis and Catalysis 363, no. 4 (2021): 1096–1104. https://doi.org/10.1002/adsc.202001209.","apa":"Liu, X., & Werner, T. (2021). Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides. Advanced Synthesis and Catalysis, 363(4), 1096–1104. https://doi.org/10.1002/adsc.202001209","ieee":"X. Liu and T. Werner, “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides,” Advanced Synthesis and Catalysis, vol. 363, no. 4, pp. 1096–1104, 2021, doi: 10.1002/adsc.202001209.","ama":"Liu X, Werner T. Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides. Advanced Synthesis and Catalysis. 2021;363(4):1096-1104. doi:10.1002/adsc.202001209","bibtex":"@article{Liu_Werner_2021, title={Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides}, volume={363}, DOI={10.1002/adsc.202001209}, number={4}, journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Liu, Xin and Werner, Thomas}, year={2021}, pages={1096–1104} }","mla":"Liu, Xin, and Thomas Werner. “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides.” Advanced Synthesis and Catalysis, vol. 363, no. 4, Wiley, 2021, pp. 1096–104, doi:10.1002/adsc.202001209."},"publisher":"Wiley","_id":"37948","page":"1096-1104","volume":363,"user_id":"89271","status":"public","date_created":"2023-01-22T20:30:29Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["T1","T3","CSSD"],"type":"journal_article","issue":"4","publication":"Advanced Synthesis and Catalysis","extern":"1","language":[{"iso":"eng"}],"doi":"10.1002/adsc.202001209","author":[{"full_name":"Liu, Xin","first_name":"Xin","last_name":"Liu"},{"id":"89271","full_name":"Werner, Thomas","last_name":"Werner","first_name":"Thomas","orcid":"https://orcid.org/0000-0001-9025-3244"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"year":"2021","title":"Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides","intvolume":" 363","date_updated":"2025-11-10T08:48:47Z","publication_status":"published"},{"publication_status":"published","date_updated":"2025-12-03T09:05:27Z","title":"Relationierung von Theorie und Praxis in der Lehrkräftebildung im Fach Physik – eine Übersicht über Forschungen und Formate","year":"2021","publication_identifier":{"isbn":["9783658325671","9783658325688"],"issn":["2524-8677","2524-8685"]},"author":[{"last_name":"Vogelsang","first_name":"Christoph","orcid":"0000-0002-5804-1855","full_name":"Vogelsang, Christoph","id":"4245"},{"full_name":"Rehfeldt, Daniel","last_name":"Rehfeldt","first_name":"Daniel"}],"doi":"10.1007/978-3-658-32568-8_19","language":[{"iso":"ger"}],"abstract":[{"text":"Auch in der Lehrkräftebildung in der Domäne Physik ist es Ziel, im Studium vermittelte, theoretische Kenntnisse mit berufspraktischen Anforderungen von angehenden Lehrkräften in Beziehung zu setzen. Charakteristisch für das Fach ist dabei zum einen eine eher anwendungsorientierte theoretische Position zum Zusammenhang von Theorie und Praxis. Zum anderen zeichnet es sich auch durch eine Art experimentelle Orientierung aus, die die Relationierung beider Aspekte als empirisch zu klärende Herausforderung begreift. In diesem Beitrag wird daher zunächst ein kurzer Überblick über Modelle und empirische Forschungen zum Zusammenhang zwischen theoretischem Wissen und praktischem Lehrkräftehandeln gegeben, die das Verständnis der Relationierung von Theorie und Praxis in der Didaktik der Physik prägen. Anschließend werden typische Lehr-Lern-Formate beschrieben und dabei auch jeweils die Ergebnisse begleitender Wirksamkeitsevaluationen kurz dargestellt.","lang":"eng"}],"publication":"Edition Fachdidaktiken","type":"book_chapter","department":[{"_id":"33"},{"_id":"299"}],"date_created":"2023-01-09T15:22:22Z","status":"public","user_id":"4245","page":"333-348","_id":"35520","publisher":"Springer Fachmedien Wiesbaden","quality_controlled":"1","citation":{"ieee":"C. Vogelsang and D. Rehfeldt, “Relationierung von Theorie und Praxis in der Lehrkräftebildung im Fach Physik – eine Übersicht über Forschungen und Formate,” in Edition Fachdidaktiken, Wiesbaden: Springer Fachmedien Wiesbaden, 2021, pp. 333–348.","apa":"Vogelsang, C., & Rehfeldt, D. (2021). Relationierung von Theorie und Praxis in der Lehrkräftebildung im Fach Physik – eine Übersicht über Forschungen und Formate. In Edition Fachdidaktiken (pp. 333–348). Springer Fachmedien Wiesbaden. https://doi.org/10.1007/978-3-658-32568-8_19","chicago":"Vogelsang, Christoph, and Daniel Rehfeldt. “Relationierung von Theorie und Praxis in der Lehrkräftebildung im Fach Physik – eine Übersicht über Forschungen und Formate.” In Edition Fachdidaktiken, 333–48. Wiesbaden: Springer Fachmedien Wiesbaden, 2021. https://doi.org/10.1007/978-3-658-32568-8_19.","short":"C. Vogelsang, D. Rehfeldt, in: Edition Fachdidaktiken, Springer Fachmedien Wiesbaden, Wiesbaden, 2021, pp. 333–348.","mla":"Vogelsang, Christoph, and Daniel Rehfeldt. “Relationierung von Theorie und Praxis in der Lehrkräftebildung im Fach Physik – eine Übersicht über Forschungen und Formate.” Edition Fachdidaktiken, Springer Fachmedien Wiesbaden, 2021, pp. 333–48, doi:10.1007/978-3-658-32568-8_19.","bibtex":"@inbook{Vogelsang_Rehfeldt_2021, place={Wiesbaden}, title={Relationierung von Theorie und Praxis in der Lehrkräftebildung im Fach Physik – eine Übersicht über Forschungen und Formate}, DOI={10.1007/978-3-658-32568-8_19}, booktitle={Edition Fachdidaktiken}, publisher={Springer Fachmedien Wiesbaden}, author={Vogelsang, Christoph and Rehfeldt, Daniel}, year={2021}, pages={333–348} }","ama":"Vogelsang C, Rehfeldt D. Relationierung von Theorie und Praxis in der Lehrkräftebildung im Fach Physik – eine Übersicht über Forschungen und Formate. In: Edition Fachdidaktiken. Springer Fachmedien Wiesbaden; 2021:333-348. doi:10.1007/978-3-658-32568-8_19"},"place":"Wiesbaden"},{"intvolume":" 43","date_updated":"2025-12-03T09:04:43Z","publication_status":"published","author":[{"id":"84533","full_name":"Kulgemeyer, Christoph","first_name":"Christoph","last_name":"Kulgemeyer"},{"full_name":"Kempin, Maren","last_name":"Kempin","first_name":"Maren"},{"full_name":"Weißbach, Anna","first_name":"Anna","last_name":"Weißbach"},{"full_name":"Borowski, Andreas","first_name":"Andreas","last_name":"Borowski"},{"full_name":"Buschhüter, David","last_name":"Buschhüter","first_name":"David"},{"full_name":"Enkrott, Patrick","last_name":"Enkrott","first_name":"Patrick"},{"first_name":"Peter","last_name":"Reinhold","full_name":"Reinhold, Peter","id":"416"},{"full_name":"Riese, Josef","last_name":"Riese","first_name":"Josef","orcid":"0000-0003-2927-2619","id":"429"},{"first_name":"Horst","last_name":"Schecker","full_name":"Schecker, Horst"},{"full_name":"Schröder, Jan","first_name":"Jan","last_name":"Schröder"},{"orcid":"0000-0002-5804-1855","last_name":"Vogelsang","first_name":"Christoph","full_name":"Vogelsang, Christoph","id":"4245"}],"publication_identifier":{"issn":["0950-0693","1464-5289"]},"year":"2021","title":"Exploring the impact of pre-service science teachers’ reflection skills on the development of professional knowledge during a field experience","doi":"10.1080/09500693.2021.2006820","language":[{"iso":"eng"}],"publication":"International Journal of Science Education","issue":"18","department":[{"_id":"299"},{"_id":"33"}],"keyword":["Education"],"type":"journal_article","date_created":"2023-05-20T10:17:33Z","status":"public","volume":43,"user_id":"4245","publisher":"Informa UK Limited","_id":"45177","page":"3035-3057","quality_controlled":"1","citation":{"apa":"Kulgemeyer, C., Kempin, M., Weißbach, A., Borowski, A., Buschhüter, D., Enkrott, P., Reinhold, P., Riese, J., Schecker, H., Schröder, J., & Vogelsang, C. (2021). Exploring the impact of pre-service science teachers’ reflection skills on the development of professional knowledge during a field experience. International Journal of Science Education, 43(18), 3035–3057. https://doi.org/10.1080/09500693.2021.2006820","mla":"Kulgemeyer, Christoph, et al. “Exploring the Impact of Pre-Service Science Teachers’ Reflection Skills on the Development of Professional Knowledge during a Field Experience.” International Journal of Science Education, vol. 43, no. 18, Informa UK Limited, 2021, pp. 3035–57, doi:10.1080/09500693.2021.2006820.","ieee":"C. Kulgemeyer et al., “Exploring the impact of pre-service science teachers’ reflection skills on the development of professional knowledge during a field experience,” International Journal of Science Education, vol. 43, no. 18, pp. 3035–3057, 2021, doi: 10.1080/09500693.2021.2006820.","chicago":"Kulgemeyer, Christoph, Maren Kempin, Anna Weißbach, Andreas Borowski, David Buschhüter, Patrick Enkrott, Peter Reinhold, et al. “Exploring the Impact of Pre-Service Science Teachers’ Reflection Skills on the Development of Professional Knowledge during a Field Experience.” International Journal of Science Education 43, no. 18 (2021): 3035–57. https://doi.org/10.1080/09500693.2021.2006820.","ama":"Kulgemeyer C, Kempin M, Weißbach A, et al. Exploring the impact of pre-service science teachers’ reflection skills on the development of professional knowledge during a field experience. International Journal of Science Education. 2021;43(18):3035-3057. doi:10.1080/09500693.2021.2006820","short":"C. Kulgemeyer, M. Kempin, A. Weißbach, A. Borowski, D. Buschhüter, P. Enkrott, P. Reinhold, J. Riese, H. Schecker, J. Schröder, C. Vogelsang, International Journal of Science Education 43 (2021) 3035–3057.","bibtex":"@article{Kulgemeyer_Kempin_Weißbach_Borowski_Buschhüter_Enkrott_Reinhold_Riese_Schecker_Schröder_et al._2021, title={Exploring the impact of pre-service science teachers’ reflection skills on the development of professional knowledge during a field experience}, volume={43}, DOI={10.1080/09500693.2021.2006820}, number={18}, journal={International Journal of Science Education}, publisher={Informa UK Limited}, author={Kulgemeyer, Christoph and Kempin, Maren and Weißbach, Anna and Borowski, Andreas and Buschhüter, David and Enkrott, Patrick and Reinhold, Peter and Riese, Josef and Schecker, Horst and Schröder, Jan and et al.}, year={2021}, pages={3035–3057} }"}},{"date_created":"2023-06-02T15:08:39Z","type":"conference","department":[{"_id":"299"},{"_id":"33"}],"publication":"Naturwissenschaftlicher Unterricht und Lehrerbildung im Umbruch? Gesellschaft für Didaktik der Chemie und Physik. Online Jahrestagung 2020","citation":{"apa":"Schröder, J., Vogelsang, C., & Riese, J. (2021). Entwicklung der Fähigkeit zur Unterrichtsplanung im Fach Physik. Naturwissenschaftlicher Unterricht und Lehrerbildung im Umbruch? Gesellschaft für Didaktik der Chemie und Physik. Online Jahrestagung 2020, 41, 266–269.","mla":"Schröder, Jan, et al. “Entwicklung der Fähigkeit zur Unterrichtsplanung im Fach Physik.” Naturwissenschaftlicher Unterricht und Lehrerbildung im Umbruch? Gesellschaft für Didaktik der Chemie und Physik. Online Jahrestagung 2020, vol. 41, 2021, pp. 266–69.","ieee":"J. Schröder, C. Vogelsang, and J. Riese, “Entwicklung der Fähigkeit zur Unterrichtsplanung im Fach Physik,” in Naturwissenschaftlicher Unterricht und Lehrerbildung im Umbruch? Gesellschaft für Didaktik der Chemie und Physik. Online Jahrestagung 2020, 2021, vol. 41, pp. 266–269.","chicago":"Schröder, Jan, Christoph Vogelsang, and Josef Riese. “Entwicklung der Fähigkeit zur Unterrichtsplanung im Fach Physik.” In Naturwissenschaftlicher Unterricht und Lehrerbildung im Umbruch? Gesellschaft für Didaktik der Chemie und Physik. Online Jahrestagung 2020, 41:266–69, 2021.","short":"J. Schröder, C. Vogelsang, J. Riese, in: Naturwissenschaftlicher Unterricht und Lehrerbildung im Umbruch? Gesellschaft für Didaktik der Chemie und Physik. Online Jahrestagung 2020, 2021, pp. 266–269.","ama":"Schröder J, Vogelsang C, Riese J. Entwicklung der Fähigkeit zur Unterrichtsplanung im Fach Physik. In: Naturwissenschaftlicher Unterricht und Lehrerbildung im Umbruch? Gesellschaft für Didaktik der Chemie und Physik. Online Jahrestagung 2020. Vol 41. ; 2021:266-269.","bibtex":"@inproceedings{Schröder_Vogelsang_Riese_2021, title={Entwicklung der Fähigkeit zur Unterrichtsplanung im Fach Physik}, volume={41}, booktitle={Naturwissenschaftlicher Unterricht und Lehrerbildung im Umbruch? Gesellschaft für Didaktik der Chemie und Physik. Online Jahrestagung 2020}, author={Schröder, Jan and Vogelsang, Christoph and Riese, Josef}, year={2021}, pages={266–269} }"},"page":"266-269","language":[{"iso":"ger"}],"_id":"45450","user_id":"4245","volume":41,"status":"public","year":"2021","title":"Entwicklung der Fähigkeit zur Unterrichtsplanung im Fach Physik","author":[{"last_name":"Schröder","first_name":"Jan","full_name":"Schröder, Jan"},{"id":"4245","full_name":"Vogelsang, Christoph","last_name":"Vogelsang","first_name":"Christoph","orcid":"0000-0002-5804-1855"},{"id":"429","orcid":"0000-0003-2927-2619","first_name":"Josef","last_name":"Riese","full_name":"Riese, Josef"}],"date_updated":"2025-12-03T09:04:33Z","intvolume":" 41"},{"extern":"1","abstract":[{"text":"The aim to produce highly active, selective, and long-lived electrocatalysts by design drives major research efforts toward gaining fundamental understanding of the relationship between material properties and their catalytic performance. Surface characterization tools enable to assess atomic scale information on the complexity of electrocatalyst materials. Advancing electrochemical methodologies to adequately characterize such systems was less of a research focus point. In this Review, we shed light on the ability to gain fundamental insights into electrocatalysis from a complementary perspective and establish corresponding design strategies. These may rely on adopting the perceptions and models of other subareas of electrochemistry, such as corrosion, battery research, or electrodeposition. Concepts on how to account for and improve mass transport, manage gas bubble release, or exploit magnetic fields are highlighted in this respect. Particular attention is paid to deriving design strategies for nanoelectrocatalysts, which is often impeded, as structural and physical material properties are buried in electrochemical data of whole electrodes or even devices. Thus, a second major approach focuses on overcoming this difference in the considered level of complexity by methods of single-entity electrochemistry. The gained understanding of intrinsic catalyst performance may allow to rationally advance design concepts with increased complexity, such as three-dimensional electrode architectures. Many materials undergo structural changes upon formation of the working catalyst. Accordingly, developing “precatalysts” with low hindrance of the electrochemical transformation to the active catalyst is suggested as a final design strategy.","lang":"eng"}],"issue":"9","publication":"ACS Catalysis","type":"journal_article","keyword":["electrocatalysis"],"department":[{"_id":"985"}],"date_created":"2025-12-03T15:31:28Z","publication_status":"published","date_updated":"2025-12-03T16:32:18Z","article_type":"review","intvolume":" 11","title":"Design Strategies for Electrocatalysts from an Electrochemist’s Perspective","year":"2021","publication_identifier":{"issn":["2155-5435","2155-5435"]},"author":[{"full_name":"Linnemann, Julia","last_name":"Linnemann","orcid":"0000-0001-6883-5424","first_name":"Julia","id":"116779"},{"full_name":"Kanokkanchana, Kannasoot","first_name":"Kannasoot","last_name":"Kanokkanchana"},{"full_name":"Tschulik, Kristina","first_name":"Kristina","last_name":"Tschulik"}],"doi":"10.1021/acscatal.0c04118","main_file_link":[{"open_access":"1","url":"https://pubs.acs.org/doi/full/10.1021/acscatal.0c04118"}],"language":[{"iso":"eng"}],"quality_controlled":"1","citation":{"mla":"Linnemann, Julia, et al. “Design Strategies for Electrocatalysts from an Electrochemist’s Perspective.” ACS Catalysis, vol. 11, no. 9, American Chemical Society (ACS), 2021, pp. 5318–46, doi:10.1021/acscatal.0c04118.","apa":"Linnemann, J., Kanokkanchana, K., & Tschulik, K. (2021). Design Strategies for Electrocatalysts from an Electrochemist’s Perspective. ACS Catalysis, 11(9), 5318–5346. https://doi.org/10.1021/acscatal.0c04118","ieee":"J. Linnemann, K. Kanokkanchana, and K. Tschulik, “Design Strategies for Electrocatalysts from an Electrochemist’s Perspective,” ACS Catalysis, vol. 11, no. 9, pp. 5318–5346, 2021, doi: 10.1021/acscatal.0c04118.","ama":"Linnemann J, Kanokkanchana K, Tschulik K. Design Strategies for Electrocatalysts from an Electrochemist’s Perspective. ACS Catalysis. 2021;11(9):5318-5346. doi:10.1021/acscatal.0c04118","short":"J. Linnemann, K. Kanokkanchana, K. Tschulik, ACS Catalysis 11 (2021) 5318–5346.","chicago":"Linnemann, Julia, Kannasoot Kanokkanchana, and Kristina Tschulik. “Design Strategies for Electrocatalysts from an Electrochemist’s Perspective.” ACS Catalysis 11, no. 9 (2021): 5318–46. https://doi.org/10.1021/acscatal.0c04118.","bibtex":"@article{Linnemann_Kanokkanchana_Tschulik_2021, title={Design Strategies for Electrocatalysts from an Electrochemist’s Perspective}, volume={11}, DOI={10.1021/acscatal.0c04118}, number={9}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Linnemann, Julia and Kanokkanchana, Kannasoot and Tschulik, Kristina}, year={2021}, pages={5318–5346} }"},"oa":"1","status":"public","user_id":"116779","volume":11,"page":"5318-5346","publisher":"American Chemical Society (ACS)","_id":"62803"},{"doi":"10.1002/anie.202112679","language":[{"iso":"eng"}],"article_number":"e202112679","main_file_link":[{"open_access":"1"}],"article_type":"original","intvolume":" 61","publication_status":"published","date_updated":"2025-12-03T16:31:54Z","publication_identifier":{"issn":["1433-7851","1521-3773"]},"author":[{"full_name":"Azimzadeh Sani, Mahnaz","last_name":"Azimzadeh Sani","first_name":"Mahnaz"},{"first_name":"Nicholas G.","last_name":"Pavlopoulos","full_name":"Pavlopoulos, Nicholas G."},{"first_name":"Simone","last_name":"Pezzotti","full_name":"Pezzotti, Simone"},{"full_name":"Serva, Alessandra","first_name":"Alessandra","last_name":"Serva"},{"first_name":"Paolo","last_name":"Cignoni","full_name":"Cignoni, Paolo"},{"id":"116779","orcid":"0000-0001-6883-5424","last_name":"Linnemann","first_name":"Julia","full_name":"Linnemann, Julia"},{"full_name":"Salanne, Mathieu","last_name":"Salanne","first_name":"Mathieu"},{"full_name":"Gaigeot, Marie‐Pierre","last_name":"Gaigeot","first_name":"Marie‐Pierre"},{"full_name":"Tschulik, Kristina","first_name":"Kristina","last_name":"Tschulik"}],"year":"2021","title":"Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer","department":[{"_id":"985"}],"type":"journal_article","keyword":["single-entity electrochemistry","electrical double layer","supercapacitor","nanoparticles"],"date_created":"2025-12-03T15:39:25Z","extern":"1","abstract":[{"text":"The electrical double‐layer plays a key role in important interfacial electrochemical processes from catalysis to energy storage and corrosion. Therefore, understanding its structure is crucial for the progress of sustainable technologies. We extract new physico‐chemical information on the capacitance and structure of the electrical double‐layer of platinum and gold nanoparticles at the molecular level, employing single nanoparticle electrochemistry. The charge storage ability of the solid/liquid interface is larger by one order‐of‐magnitude than predicted by the traditional mean‐field models of the double‐layer such as the Gouy–Chapman–Stern model. Performing molecular dynamics simulations, we investigate the possible relationship between the measured high capacitance and adsorption strength of the water adlayer formed at the metal surface. These insights may launch the active tuning of solid–solvent and solvent–solvent interactions as an innovative design strategy to transform energy technologies towards superior performance and sustainability.","lang":"eng"}],"issue":"5","publication":"Angewandte Chemie International Edition","volume":61,"user_id":"116779","_id":"62806","publisher":"Wiley","status":"public","oa":"1","quality_controlled":"1","citation":{"chicago":"Azimzadeh Sani, Mahnaz, Nicholas G. Pavlopoulos, Simone Pezzotti, Alessandra Serva, Paolo Cignoni, Julia Linnemann, Mathieu Salanne, Marie‐Pierre Gaigeot, and Kristina Tschulik. “Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer.” Angewandte Chemie International Edition 61, no. 5 (2021). https://doi.org/10.1002/anie.202112679.","short":"M. Azimzadeh Sani, N.G. Pavlopoulos, S. Pezzotti, A. Serva, P. Cignoni, J. Linnemann, M. Salanne, M. Gaigeot, K. Tschulik, Angewandte Chemie International Edition 61 (2021).","apa":"Azimzadeh Sani, M., Pavlopoulos, N. G., Pezzotti, S., Serva, A., Cignoni, P., Linnemann, J., Salanne, M., Gaigeot, M., & Tschulik, K. (2021). Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer. Angewandte Chemie International Edition, 61(5), Article e202112679. https://doi.org/10.1002/anie.202112679","ieee":"M. Azimzadeh Sani et al., “Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer,” Angewandte Chemie International Edition, vol. 61, no. 5, Art. no. e202112679, 2021, doi: 10.1002/anie.202112679.","ama":"Azimzadeh Sani M, Pavlopoulos NG, Pezzotti S, et al. Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer. Angewandte Chemie International Edition. 2021;61(5). doi:10.1002/anie.202112679","bibtex":"@article{Azimzadeh Sani_Pavlopoulos_Pezzotti_Serva_Cignoni_Linnemann_Salanne_Gaigeot_Tschulik_2021, title={Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer}, volume={61}, DOI={10.1002/anie.202112679}, number={5e202112679}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Azimzadeh Sani, Mahnaz and Pavlopoulos, Nicholas G. and Pezzotti, Simone and Serva, Alessandra and Cignoni, Paolo and Linnemann, Julia and Salanne, Mathieu and Gaigeot, Marie‐Pierre and Tschulik, Kristina}, year={2021} }","mla":"Azimzadeh Sani, Mahnaz, et al. “Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer.” Angewandte Chemie International Edition, vol. 61, no. 5, e202112679, Wiley, 2021, doi:10.1002/anie.202112679."}},{"status":"public","publisher":"MDPI AG","_id":"62805","user_id":"116779","volume":22,"citation":{"ieee":"Z. Liu, M. Corva, H. M. A. Amin, N. Blanc, J. Linnemann, and K. Tschulik, “Single Co3O4 Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects,” International Journal of Molecular Sciences, vol. 22, no. 23, Art. no. 13137, 2021, doi: 10.3390/ijms222313137.","apa":"Liu, Z., Corva, M., Amin, H. M. A., Blanc, N., Linnemann, J., & Tschulik, K. (2021). Single Co3O4 Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects. International Journal of Molecular Sciences, 22(23), Article 13137. https://doi.org/10.3390/ijms222313137","chicago":"Liu, Zhibin, Manuel Corva, Hatem M. A. Amin, Niclas Blanc, Julia Linnemann, and Kristina Tschulik. “Single Co3O4 Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects.” International Journal of Molecular Sciences 22, no. 23 (2021). https://doi.org/10.3390/ijms222313137.","short":"Z. Liu, M. Corva, H.M.A. Amin, N. Blanc, J. Linnemann, K. Tschulik, International Journal of Molecular Sciences 22 (2021).","mla":"Liu, Zhibin, et al. “Single Co3O4 Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects.” International Journal of Molecular Sciences, vol. 22, no. 23, 13137, MDPI AG, 2021, doi:10.3390/ijms222313137.","bibtex":"@article{Liu_Corva_Amin_Blanc_Linnemann_Tschulik_2021, title={Single Co3O4 Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects}, volume={22}, DOI={10.3390/ijms222313137}, number={2313137}, journal={International Journal of Molecular Sciences}, publisher={MDPI AG}, author={Liu, Zhibin and Corva, Manuel and Amin, Hatem M. A. and Blanc, Niclas and Linnemann, Julia and Tschulik, Kristina}, year={2021} }","ama":"Liu Z, Corva M, Amin HMA, Blanc N, Linnemann J, Tschulik K. Single Co3O4 Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects. International Journal of Molecular Sciences. 2021;22(23). doi:10.3390/ijms222313137"},"quality_controlled":"1","oa":"1","title":"Single Co3O4 Nanocubes Electrocatalyzing the Oxygen Evolution Reaction: Nano-Impact Insights into Intrinsic Activity and Support Effects","year":"2021","publication_identifier":{"issn":["1422-0067"]},"author":[{"first_name":"Zhibin","last_name":"Liu","full_name":"Liu, Zhibin"},{"first_name":"Manuel","last_name":"Corva","full_name":"Corva, Manuel"},{"full_name":"Amin, Hatem M. A.","first_name":"Hatem M. A.","last_name":"Amin"},{"first_name":"Niclas","last_name":"Blanc","full_name":"Blanc, Niclas"},{"full_name":"Linnemann, Julia","first_name":"Julia","last_name":"Linnemann","orcid":"0000-0001-6883-5424","id":"116779"},{"full_name":"Tschulik, Kristina","last_name":"Tschulik","first_name":"Kristina"}],"publication_status":"published","date_updated":"2025-12-03T16:52:35Z","article_type":"original","intvolume":" 22","article_number":"13137","main_file_link":[{"open_access":"1"}],"language":[{"iso":"eng"}],"doi":"10.3390/ijms222313137","issue":"23","publication":"International Journal of Molecular Sciences","extern":"1","abstract":[{"lang":"eng","text":"Single-entity electrochemistry allows for assessing electrocatalytic activities of individual material entities such as nanoparticles (NPs). Thus, it becomes possible to consider intrinsic electrochemical properties of nanocatalysts when researching how activity relates to physical and structural material properties. Conversely, conventional electrochemical techniques provide a normalized sum current referring to a huge ensemble of NPs constituting, along with additives (e.g., binders), a complete catalyst-coated electrode. Accordingly, recording electrocatalytic responses of single NPs avoids interferences of ensemble effects and reduces the complexity of electrocatalytic processes, thus enabling detailed description and modelling. Herein, we present insights into the oxygen evolution catalysis at individual cubic Co3O4 NPs impacting microelectrodes of different support materials. Simulating diffusion at supported nanocubes, measured step current signals can be analyzed, providing edge lengths, corresponding size distributions, and interference-free turnover frequencies. The provided nano-impact investigation of (electro-)catalyst-support effects contradicts assumptions on a low number of highly active sites."}],"date_created":"2025-12-03T15:35:52Z","keyword":["electrocatalysis","oxygen evolution reaction","cobalt spinel","single-entity electrochemistry"],"type":"journal_article","department":[{"_id":"985"}]},{"author":[{"id":"44191","full_name":"Pollmeier, Pascal","last_name":"Pollmeier","first_name":"Pascal"},{"full_name":"Fechner, Sabine","last_name":"Fechner","first_name":"Sabine","orcid":"0000-0001-5645-5870","id":"54823"}],"publication_identifier":{"isbn":["9783830943495"]},"year":"2021","title":"Förderung angehender Lehrkräfte im Umgang mit Evidenzen für den naturwissenschaftlichen Unterricht","publication_status":"published","date_updated":"2025-12-03T18:02:50Z","language":[{"iso":"ger"}],"main_file_link":[{"url":"https://www.waxmann.com/shop/download?tx_p2waxmann_download%5Baction%5D=download&tx_p2waxmann_download%5Bbuchnr%5D=4349&tx_p2waxmann_download%5Bcontroller%5D=Zeitschrift&cHash=4ac498ffa50e3b0ac5dff4f160ffbc85","open_access":"1"}],"doi":"10.31244/9783830993490","publication":"Lehrkräftebildung neu gedacht. Ein Praxishandbuch für die Lehre in den Naturwissenschaften und deren Didaktiken","date_created":"2021-09-03T09:41:21Z","department":[{"_id":"386"},{"_id":"33"}],"type":"book_chapter","status":"public","_id":"23733","publisher":"Waxmann","page":"150-154","editor":[{"full_name":"Kubsch, Marcus","last_name":"Kubsch","first_name":"Marcus"},{"first_name":"Stefan","last_name":"Sorge","full_name":"Sorge, Stefan"},{"last_name":"Arnold","first_name":"Julia","full_name":"Arnold, Julia"},{"last_name":"Graulich","first_name":"Nicole","full_name":"Graulich, Nicole"}],"user_id":"54823","citation":{"mla":"Pollmeier, Pascal, and Sabine Fechner. “Förderung angehender Lehrkräfte im Umgang mit Evidenzen für den naturwissenschaftlichen Unterricht.” Lehrkräftebildung neu gedacht. Ein Praxishandbuch für die Lehre in den Naturwissenschaften und deren Didaktiken, edited by Marcus Kubsch et al., Waxmann, 2021, pp. 150–54, doi:10.31244/9783830993490.","bibtex":"@inbook{Pollmeier_Fechner_2021, title={Förderung angehender Lehrkräfte im Umgang mit Evidenzen für den naturwissenschaftlichen Unterricht}, DOI={10.31244/9783830993490}, booktitle={Lehrkräftebildung neu gedacht. Ein Praxishandbuch für die Lehre in den Naturwissenschaften und deren Didaktiken}, publisher={Waxmann}, author={Pollmeier, Pascal and Fechner, Sabine}, editor={Kubsch, Marcus and Sorge, Stefan and Arnold, Julia and Graulich, Nicole}, year={2021}, pages={150–154} }","ama":"Pollmeier P, Fechner S. Förderung angehender Lehrkräfte im Umgang mit Evidenzen für den naturwissenschaftlichen Unterricht. In: Kubsch M, Sorge S, Arnold J, Graulich N, eds. Lehrkräftebildung neu gedacht. Ein Praxishandbuch für die Lehre in den Naturwissenschaften und deren Didaktiken. Waxmann; 2021:150-154. doi:10.31244/9783830993490","ieee":"P. Pollmeier and S. Fechner, “Förderung angehender Lehrkräfte im Umgang mit Evidenzen für den naturwissenschaftlichen Unterricht,” in Lehrkräftebildung neu gedacht. Ein Praxishandbuch für die Lehre in den Naturwissenschaften und deren Didaktiken, M. Kubsch, S. Sorge, J. Arnold, and N. Graulich, Eds. Waxmann, 2021, pp. 150–154.","apa":"Pollmeier, P., & Fechner, S. (2021). Förderung angehender Lehrkräfte im Umgang mit Evidenzen für den naturwissenschaftlichen Unterricht. In M. Kubsch, S. Sorge, J. Arnold, & N. Graulich (Eds.), Lehrkräftebildung neu gedacht. Ein Praxishandbuch für die Lehre in den Naturwissenschaften und deren Didaktiken (pp. 150–154). Waxmann. https://doi.org/10.31244/9783830993490","short":"P. Pollmeier, S. Fechner, in: M. Kubsch, S. Sorge, J. Arnold, N. Graulich (Eds.), Lehrkräftebildung neu gedacht. Ein Praxishandbuch für die Lehre in den Naturwissenschaften und deren Didaktiken, Waxmann, 2021, pp. 150–154.","chicago":"Pollmeier, Pascal, and Sabine Fechner. “Förderung angehender Lehrkräfte im Umgang mit Evidenzen für den naturwissenschaftlichen Unterricht.” In Lehrkräftebildung neu gedacht. Ein Praxishandbuch für die Lehre in den Naturwissenschaften und deren Didaktiken, edited by Marcus Kubsch, Stefan Sorge, Julia Arnold, and Nicole Graulich, 150–54. Waxmann, 2021. https://doi.org/10.31244/9783830993490."},"oa":"1"},{"citation":{"bibtex":"@inbook{Pollmeier_Fechner_2021, place={Wiesbaden}, title={Zwischen den Stühlen? – Verknüpfung von Erfahrungen des Praxissemesters mit Theorien im Lehramtsstudium Chemie. Sukzessiven Kompetenzaufbau nach dem Praxissemester gestalten}, DOI={10.1007/978-3-658-32568-8_16}, booktitle={Theorie und Praxis in der Lehrerbildung - Verhältnisbestimmungen aus der Perspektive von Fachdidaktiken}, publisher={Springer Fachmedien}, author={Pollmeier, Pascal and Fechner, Sabine}, editor={Caruso, Carina and Harteis, Christian and Gröschner, Alexander}, year={2021} }","chicago":"Pollmeier, Pascal, and Sabine Fechner. “Zwischen den Stühlen? – Verknüpfung von Erfahrungen des Praxissemesters mit Theorien im Lehramtsstudium Chemie. Sukzessiven Kompetenzaufbau nach dem Praxissemester gestalten.” In Theorie und Praxis in der Lehrerbildung - Verhältnisbestimmungen aus der Perspektive von Fachdidaktiken, edited by Carina Caruso, Christian Harteis, and Alexander Gröschner. Wiesbaden: Springer Fachmedien, 2021. https://doi.org/10.1007/978-3-658-32568-8_16.","short":"P. Pollmeier, S. Fechner, in: C. Caruso, C. Harteis, A. Gröschner (Eds.), Theorie und Praxis in der Lehrerbildung - Verhältnisbestimmungen aus der Perspektive von Fachdidaktiken, Springer Fachmedien, Wiesbaden, 2021.","ama":"Pollmeier P, Fechner S. Zwischen den Stühlen? – Verknüpfung von Erfahrungen des Praxissemesters mit Theorien im Lehramtsstudium Chemie. Sukzessiven Kompetenzaufbau nach dem Praxissemester gestalten. In: Caruso C, Harteis C, Gröschner A, eds. Theorie und Praxis in der Lehrerbildung - Verhältnisbestimmungen aus der Perspektive von Fachdidaktiken. Springer Fachmedien; 2021. doi:10.1007/978-3-658-32568-8_16","ieee":"P. Pollmeier and S. Fechner, “Zwischen den Stühlen? – Verknüpfung von Erfahrungen des Praxissemesters mit Theorien im Lehramtsstudium Chemie. Sukzessiven Kompetenzaufbau nach dem Praxissemester gestalten,” in Theorie und Praxis in der Lehrerbildung - Verhältnisbestimmungen aus der Perspektive von Fachdidaktiken, C. Caruso, C. Harteis, and A. Gröschner, Eds. Wiesbaden: Springer Fachmedien, 2021.","apa":"Pollmeier, P., & Fechner, S. (2021). Zwischen den Stühlen? – Verknüpfung von Erfahrungen des Praxissemesters mit Theorien im Lehramtsstudium Chemie. Sukzessiven Kompetenzaufbau nach dem Praxissemester gestalten. In C. Caruso, C. Harteis, & A. Gröschner (Eds.), Theorie und Praxis in der Lehrerbildung - Verhältnisbestimmungen aus der Perspektive von Fachdidaktiken. Springer Fachmedien. https://doi.org/10.1007/978-3-658-32568-8_16","mla":"Pollmeier, Pascal, and Sabine Fechner. “Zwischen den Stühlen? – Verknüpfung von Erfahrungen des Praxissemesters mit Theorien im Lehramtsstudium Chemie. Sukzessiven Kompetenzaufbau nach dem Praxissemester gestalten.” Theorie und Praxis in der Lehrerbildung - Verhältnisbestimmungen aus der Perspektive von Fachdidaktiken, edited by Carina Caruso et al., Springer Fachmedien, 2021, doi:10.1007/978-3-658-32568-8_16."},"publication":"Theorie und Praxis in der Lehrerbildung - Verhältnisbestimmungen aus der Perspektive von Fachdidaktiken","quality_controlled":"1","date_created":"2021-11-02T21:05:48Z","place":"Wiesbaden","department":[{"_id":"386"},{"_id":"33"}],"type":"book_chapter","publication_identifier":{"issn":["2524-8677","2524-8685"]},"author":[{"id":"44191","first_name":"Pascal","last_name":"Pollmeier","full_name":"Pollmeier, Pascal"},{"id":"54823","orcid":"0000-0001-5645-5870","first_name":"Sabine","last_name":"Fechner","full_name":"Fechner, Sabine"}],"title":"Zwischen den Stühlen? – Verknüpfung von Erfahrungen des Praxissemesters mit Theorien im Lehramtsstudium Chemie. Sukzessiven Kompetenzaufbau nach dem Praxissemester gestalten","year":"2021","status":"public","publication_status":"published","date_updated":"2025-12-03T18:13:33Z","language":[{"iso":"ger"}],"_id":"27071","publisher":"Springer Fachmedien","editor":[{"full_name":"Caruso, Carina","last_name":"Caruso","first_name":"Carina"},{"full_name":"Harteis, Christian ","first_name":"Christian ","last_name":"Harteis"},{"full_name":"Gröschner, Alexander","first_name":"Alexander","last_name":"Gröschner"}],"user_id":"54823","doi":"10.1007/978-3-658-32568-8_16"},{"author":[{"id":"24755","first_name":"Anna","last_name":"Bauer","orcid":"0000-0002-1742-3099","full_name":"Bauer, Anna"},{"id":"26883","first_name":"Marc","orcid":"0000-0001-6217-336X","last_name":"Sacher","full_name":"Sacher, Marc"},{"full_name":"Habig, Sebastian","last_name":"Habig","first_name":"Sebastian"},{"first_name":"Sabine","last_name":"Fechner","orcid":"0000-0001-5645-5870","full_name":"Fechner, Sabine","id":"54823"}],"title":"Laborpraktika auf Distanz. Ansätze in den Naturwissenschaften","year":"2021","intvolume":" 3","date_updated":"2025-12-03T21:39:53Z","publication_status":"published","series_title":"Hochschulbildung: Lehre und Forschung","language":[{"iso":"ger"}],"main_file_link":[{"open_access":"1","url":"https://www.transcript-verlag.de/978-3-8376-5690-9/hochschule-auf-abstand/"}],"doi":"DOI: 10.14361/9783839456903-011","publication":"Hochschule auf Abstand. Ein multiperspektivischer Zugang zur digitalen Lehre","date_created":"2021-09-23T12:12:49Z","department":[{"_id":"576"},{"_id":"299"},{"_id":"386"}],"type":"book_chapter","status":"public","_id":"24935","publisher":" transcript Verlag","page":"155-168","editor":[{"full_name":"Neiske, Iris","last_name":"Neiske","first_name":"Iris"},{"full_name":"Osthushenrich, Judith","first_name":"Judith","last_name":"Osthushenrich"},{"last_name":"Schaper","first_name":"Niclas","full_name":"Schaper, Niclas"},{"full_name":"Trier, Ulrike","first_name":"Ulrike","last_name":"Trier"},{"first_name":"Nerea","last_name":"Vöing","full_name":"Vöing, Nerea"}],"volume":3,"user_id":"54823","citation":{"chicago":"Bauer, Anna, Marc Sacher, Sebastian Habig, and Sabine Fechner. “Laborpraktika auf Distanz. Ansätze in den Naturwissenschaften.” In Hochschule auf Abstand. Ein multiperspektivischer Zugang zur digitalen Lehre, edited by Iris Neiske, Judith Osthushenrich, Niclas Schaper, Ulrike Trier, and Nerea Vöing, 3:155–68. Hochschulbildung: Lehre und Forschung. Bielefeld: transcript Verlag, 2021. https://doi.org/DOI: 10.14361/9783839456903-011.","short":"A. Bauer, M. Sacher, S. Habig, S. Fechner, in: I. Neiske, J. Osthushenrich, N. Schaper, U. Trier, N. Vöing (Eds.), Hochschule auf Abstand. Ein multiperspektivischer Zugang zur digitalen Lehre, transcript Verlag, Bielefeld, 2021, pp. 155–168.","ieee":"A. Bauer, M. Sacher, S. Habig, and S. Fechner, “Laborpraktika auf Distanz. Ansätze in den Naturwissenschaften,” in Hochschule auf Abstand. Ein multiperspektivischer Zugang zur digitalen Lehre, vol. 3, I. Neiske, J. Osthushenrich, N. Schaper, U. Trier, and N. Vöing, Eds. Bielefeld: transcript Verlag, 2021, pp. 155–168.","apa":"Bauer, A., Sacher, M., Habig, S., & Fechner, S. (2021). Laborpraktika auf Distanz. Ansätze in den Naturwissenschaften. In I. Neiske, J. Osthushenrich, N. Schaper, U. Trier, & N. Vöing (Eds.), Hochschule auf Abstand. Ein multiperspektivischer Zugang zur digitalen Lehre (Vol. 3, pp. 155–168). transcript Verlag. https://doi.org/DOI: 10.14361/9783839456903-011","bibtex":"@inbook{Bauer_Sacher_Habig_Fechner_2021, place={Bielefeld}, series={Hochschulbildung: Lehre und Forschung}, title={Laborpraktika auf Distanz. Ansätze in den Naturwissenschaften}, volume={3}, DOI={DOI: 10.14361/9783839456903-011}, booktitle={Hochschule auf Abstand. Ein multiperspektivischer Zugang zur digitalen Lehre}, publisher={ transcript Verlag}, author={Bauer, Anna and Sacher, Marc and Habig, Sebastian and Fechner, Sabine}, editor={Neiske, Iris and Osthushenrich, Judith and Schaper, Niclas and Trier, Ulrike and Vöing, Nerea}, year={2021}, pages={155–168}, collection={Hochschulbildung: Lehre und Forschung} }","ama":"Bauer A, Sacher M, Habig S, Fechner S. Laborpraktika auf Distanz. Ansätze in den Naturwissenschaften. In: Neiske I, Osthushenrich J, Schaper N, Trier U, Vöing N, eds. Hochschule auf Abstand. Ein multiperspektivischer Zugang zur digitalen Lehre. Vol 3. Hochschulbildung: Lehre und Forschung. transcript Verlag; 2021:155-168. doi:DOI: 10.14361/9783839456903-011","mla":"Bauer, Anna, et al. “Laborpraktika auf Distanz. Ansätze in den Naturwissenschaften.” Hochschule auf Abstand. Ein multiperspektivischer Zugang zur digitalen Lehre, edited by Iris Neiske et al., vol. 3, transcript Verlag, 2021, pp. 155–68, doi:DOI: 10.14361/9783839456903-011."},"quality_controlled":"1","place":"Bielefeld","oa":"1"},{"citation":{"chicago":"Schnaars, Kathleen, Masashi Kaneko, and Kiyoshi Fujisawa. “Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex.” Inorganic Chemistry 60, no. 4 (2021): 2477–91. https://doi.org/10.1021/acs.inorgchem.0c03405.","short":"K. Schnaars, M. Kaneko, K. Fujisawa, Inorganic Chemistry 60 (2021) 2477–2491.","apa":"Schnaars, K., Kaneko, M., & Fujisawa, K. (2021). Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex. Inorganic Chemistry, 60(4), 2477–2491. https://doi.org/10.1021/acs.inorgchem.0c03405","ieee":"K. Schnaars, M. Kaneko, and K. Fujisawa, “Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex,” Inorganic Chemistry, vol. 60, no. 4, pp. 2477–2491, 2021, doi: 10.1021/acs.inorgchem.0c03405.","ama":"Schnaars K, Kaneko M, Fujisawa K. Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex. Inorganic Chemistry. 2021;60(4):2477-2491. doi:10.1021/acs.inorgchem.0c03405","bibtex":"@article{Schnaars_Kaneko_Fujisawa_2021, title={Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex}, volume={60}, DOI={10.1021/acs.inorgchem.0c03405}, number={4}, journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Schnaars, Kathleen and Kaneko, Masashi and Fujisawa, Kiyoshi}, year={2021}, pages={2477–2491} }","mla":"Schnaars, Kathleen, et al. “Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex.” Inorganic Chemistry, vol. 60, no. 4, American Chemical Society (ACS), 2021, pp. 2477–91, doi:10.1021/acs.inorgchem.0c03405."},"quality_controlled":"1","status":"public","page":"2477-2491","publisher":"American Chemical Society (ACS)","_id":"62851","user_id":"117735","volume":60,"publication":"Inorganic Chemistry","issue":"4","extern":"1","abstract":[{"lang":"eng","text":"To reduce high-level radiotoxic waste generated by nuclear power plants, highly selective separation agents for minor actinides are mandatory. The mixed N,O-donor ligand N,N,N′,N′-tetrakis[(6-carboxypyridin-2-yl)methyl]ethylenediamine (H4TPAEN; 1) has shown good performance as a masking agent in Am3+/Eu3+ separation studies. Adjustments on the pyridyl backbone to raise the hydrophilicity led to a decrease in selectivity and a decrease in M3+–Nam interactions. An enhanced basicity of the pyridyl N-donors was given as a cause. In this work, we examine whether a decrease in O-donor basicity can promote the M3+–Nam interactions. Therefore, we replace the deprotonated “charged” carboxylic acid groups of TPAEN4– by neutral amide groups and introduce N,N,N′,N’-tetrakis[(6-N″,N′′-diethylcarbamoylpyridin-2-yl)methyl]ethylenediamine (TPAMEN; 2) as a new ligand. TPAMEN was crystallized with Eu(OTf)3 and Eu(NO3)3·6H2O to form positively charged 1:1 [Eu(TPAMEN)]3+ complexes in the solid state. Alterations in the M–O/N bond distances are compared to [Eu(TPAEN)]− and investigated by DFT calculations to expose the differences in charge/energy density distributions at europium(III) and the donor functionalities of the TPAEN4– and TPAMEN. On the basis of estimations of the bond orders, atomic charges spin populations, and density of states in the Eu and potential Am and Cm complexes, the specific contributions of the donor–metal interaction are analyzed. The prediction of complex formation energy differences for the [M(TPAEN)]− and [M(TPAMEN)]3+ (M3+ = Eu3+, Am3+) complexes provide an outlook on the potential performance of TPAMEN in Am3+/Eu3+ separation."}],"date_created":"2025-12-04T12:06:36Z","type":"journal_article","department":[{"_id":"985"}],"year":"2021","title":"Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex","author":[{"id":"117735","full_name":"Schnaars, Kathleen","first_name":"Kathleen","last_name":"Schnaars"},{"full_name":"Kaneko, Masashi","first_name":"Masashi","last_name":"Kaneko"},{"first_name":"Kiyoshi","last_name":"Fujisawa","full_name":"Fujisawa, Kiyoshi"}],"publication_identifier":{"issn":["0020-1669","1520-510X"]},"publication_status":"published","date_updated":"2025-12-04T12:19:31Z","intvolume":" 60","language":[{"iso":"eng"}],"doi":"10.1021/acs.inorgchem.0c03405"},{"publication":"Physical Review Research","issue":"1","date_created":"2021-03-02T10:28:55Z","type":"journal_article","department":[{"_id":"15"},{"_id":"170"},{"_id":"297"},{"_id":"705"},{"_id":"230"},{"_id":"429"},{"_id":"35"}],"year":"2021","title":"Split-ring polariton condensates as macroscopic two-level quantum systems","author":[{"first_name":"Yan","last_name":"Xue","full_name":"Xue, Yan"},{"full_name":"Chestnov, Igor","last_name":"Chestnov","first_name":"Igor"},{"full_name":"Sedov, Evgeny","last_name":"Sedov","first_name":"Evgeny"},{"first_name":"Evgeniy","last_name":"Kiktenko","full_name":"Kiktenko, Evgeniy"},{"last_name":"Fedorov","first_name":"Aleksey K.","full_name":"Fedorov, Aleksey K."},{"full_name":"Schumacher, Stefan","orcid":"0000-0003-4042-4951","last_name":"Schumacher","first_name":"Stefan","id":"27271"},{"id":"59416","full_name":"Ma, Xuekai","first_name":"Xuekai","last_name":"Ma"},{"first_name":"Alexey","last_name":"Kavokin","full_name":"Kavokin, Alexey"}],"publication_identifier":{"issn":["2643-1564"]},"publication_status":"published","date_updated":"2025-12-05T13:48:59Z","intvolume":" 3","article_number":"013099","language":[{"iso":"eng"}],"doi":"10.1103/physrevresearch.3.013099","citation":{"mla":"Xue, Yan, et al. “Split-Ring Polariton Condensates as Macroscopic Two-Level Quantum Systems.” Physical Review Research, vol. 3, no. 1, 013099, 2021, doi:10.1103/physrevresearch.3.013099.","bibtex":"@article{Xue_Chestnov_Sedov_Kiktenko_Fedorov_Schumacher_Ma_Kavokin_2021, title={Split-ring polariton condensates as macroscopic two-level quantum systems}, volume={3}, DOI={10.1103/physrevresearch.3.013099}, number={1013099}, journal={Physical Review Research}, author={Xue, Yan and Chestnov, Igor and Sedov, Evgeny and Kiktenko, Evgeniy and Fedorov, Aleksey K. and Schumacher, Stefan and Ma, Xuekai and Kavokin, Alexey}, year={2021} }","ama":"Xue Y, Chestnov I, Sedov E, et al. Split-ring polariton condensates as macroscopic two-level quantum systems. Physical Review Research. 2021;3(1). doi:10.1103/physrevresearch.3.013099","ieee":"Y. Xue et al., “Split-ring polariton condensates as macroscopic two-level quantum systems,” Physical Review Research, vol. 3, no. 1, Art. no. 013099, 2021, doi: 10.1103/physrevresearch.3.013099.","apa":"Xue, Y., Chestnov, I., Sedov, E., Kiktenko, E., Fedorov, A. K., Schumacher, S., Ma, X., & Kavokin, A. (2021). Split-ring polariton condensates as macroscopic two-level quantum systems. Physical Review Research, 3(1), Article 013099. https://doi.org/10.1103/physrevresearch.3.013099","chicago":"Xue, Yan, Igor Chestnov, Evgeny Sedov, Evgeniy Kiktenko, Aleksey K. Fedorov, Stefan Schumacher, Xuekai Ma, and Alexey Kavokin. “Split-Ring Polariton Condensates as Macroscopic Two-Level Quantum Systems.” Physical Review Research 3, no. 1 (2021). https://doi.org/10.1103/physrevresearch.3.013099.","short":"Y. Xue, I. Chestnov, E. Sedov, E. Kiktenko, A.K. Fedorov, S. Schumacher, X. Ma, A. Kavokin, Physical Review Research 3 (2021)."},"project":[{"_id":"52","name":"Computing Resources Provided by the Paderborn Center for Parallel Computing"},{"_id":"53","name":"TRR 142: TRR 142"},{"_id":"54","name":"TRR 142 - A: TRR 142 - Project Area A"},{"_id":"61","name":"TRR 142 - A4: TRR 142 - Subproject A4"},{"name":"PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing","_id":"52"},{"_id":"53","name":"TRR 142: Maßgeschneiderte nichtlineare Photonik: Von grundlegenden Konzepten zu funktionellen Strukturen"}],"status":"public","_id":"21362","user_id":"16199","volume":3},{"project":[{"_id":"52","name":"Computing Resources Provided by the Paderborn Center for Parallel Computing"},{"name":"TRR 142: TRR 142","_id":"53"},{"name":"TRR 142 - A: TRR 142 - Project Area A","_id":"54"},{"name":"TRR 142 - A4: TRR 142 - Subproject A4","_id":"61"},{"name":"PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing","_id":"52"},{"_id":"53","name":"TRR 142: Maßgeschneiderte nichtlineare Photonik: Von grundlegenden Konzepten zu funktionellen Strukturen"}],"citation":{"chicago":"Barkhausen, Franziska, Matthias Pukrop, Stefan Schumacher, and Xuekai Ma. “Structuring Coflowing and Counterflowing Currents of Polariton Condensates in Concentric Ring-Shaped and Elliptical Potentials.” Physical Review B 103, no. 7 (2021). https://doi.org/10.1103/physrevb.103.075305.","short":"F. Barkhausen, M. Pukrop, S. Schumacher, X. Ma, Physical Review B 103 (2021).","ama":"Barkhausen F, Pukrop M, Schumacher S, Ma X. Structuring coflowing and counterflowing currents of polariton condensates in concentric ring-shaped and elliptical potentials. Physical Review B. 2021;103(7). doi:10.1103/physrevb.103.075305","bibtex":"@article{Barkhausen_Pukrop_Schumacher_Ma_2021, title={Structuring coflowing and counterflowing currents of polariton condensates in concentric ring-shaped and elliptical potentials}, volume={103}, DOI={10.1103/physrevb.103.075305}, number={7075305}, journal={Physical Review B}, author={Barkhausen, Franziska and Pukrop, Matthias and Schumacher, Stefan and Ma, Xuekai}, year={2021} }","apa":"Barkhausen, F., Pukrop, M., Schumacher, S., & Ma, X. (2021). Structuring coflowing and counterflowing currents of polariton condensates in concentric ring-shaped and elliptical potentials. Physical Review B, 103(7), Article 075305. https://doi.org/10.1103/physrevb.103.075305","mla":"Barkhausen, Franziska, et al. “Structuring Coflowing and Counterflowing Currents of Polariton Condensates in Concentric Ring-Shaped and Elliptical Potentials.” Physical Review B, vol. 103, no. 7, 075305, 2021, doi:10.1103/physrevb.103.075305.","ieee":"F. Barkhausen, M. Pukrop, S. Schumacher, and X. Ma, “Structuring coflowing and counterflowing currents of polariton condensates in concentric ring-shaped and elliptical potentials,” Physical Review B, vol. 103, no. 7, Art. no. 075305, 2021, doi: 10.1103/physrevb.103.075305."},"status":"public","user_id":"16199","volume":103,"_id":"21359","publication":"Physical Review B","issue":"7","type":"journal_article","department":[{"_id":"15"},{"_id":"170"},{"_id":"297"},{"_id":"705"},{"_id":"230"},{"_id":"429"},{"_id":"35"}],"date_created":"2021-03-02T10:25:09Z","date_updated":"2025-12-05T13:50:08Z","publication_status":"published","intvolume":" 103","title":"Structuring coflowing and counterflowing currents of polariton condensates in concentric ring-shaped and elliptical potentials","year":"2021","author":[{"full_name":"Barkhausen, Franziska","last_name":"Barkhausen","first_name":"Franziska"},{"id":"64535","full_name":"Pukrop, Matthias","first_name":"Matthias","last_name":"Pukrop"},{"id":"27271","full_name":"Schumacher, Stefan","first_name":"Stefan","orcid":"0000-0003-4042-4951","last_name":"Schumacher"},{"id":"59416","full_name":"Ma, Xuekai","last_name":"Ma","first_name":"Xuekai"}],"publication_identifier":{"issn":["2469-9950","2469-9969"]},"doi":"10.1103/physrevb.103.075305","article_number":"075305","language":[{"iso":"eng"}]},{"project":[{"name":"PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing","_id":"52"}],"citation":{"ama":"Jain M, Gerstmann U, Schmidt WG, Aldahhak H. Adatom mediated adsorption of <scp>N‐heterocyclic</scp> carbenes on Cu(111) and Au(111). Journal of Computational Chemistry. 2021;43(6):413-420. doi:10.1002/jcc.26801","bibtex":"@article{Jain_Gerstmann_Schmidt_Aldahhak_2021, title={Adatom mediated adsorption of <scp>N‐heterocyclic</scp> carbenes on Cu(111) and Au(111)}, volume={43}, DOI={10.1002/jcc.26801}, number={6}, journal={Journal of Computational Chemistry}, publisher={Wiley}, author={Jain, Mitisha and Gerstmann, Uwe and Schmidt, Wolf Gero and Aldahhak, Hazem}, year={2021}, pages={413–420} }","mla":"Jain, Mitisha, et al. “Adatom Mediated Adsorption of <scp>N‐heterocyclic</Scp> Carbenes on Cu(111) and Au(111).” Journal of Computational Chemistry, vol. 43, no. 6, Wiley, 2021, pp. 413–20, doi:10.1002/jcc.26801.","short":"M. Jain, U. Gerstmann, W.G. Schmidt, H. Aldahhak, Journal of Computational Chemistry 43 (2021) 413–420.","chicago":"Jain, Mitisha, Uwe Gerstmann, Wolf Gero Schmidt, and Hazem Aldahhak. “Adatom Mediated Adsorption of <scp>N‐heterocyclic</Scp> Carbenes on Cu(111) and Au(111).” Journal of Computational Chemistry 43, no. 6 (2021): 413–20. https://doi.org/10.1002/jcc.26801.","apa":"Jain, M., Gerstmann, U., Schmidt, W. G., & Aldahhak, H. (2021). Adatom mediated adsorption of <scp>N‐heterocyclic</scp> carbenes on Cu(111) and Au(111). Journal of Computational Chemistry, 43(6), 413–420. https://doi.org/10.1002/jcc.26801","ieee":"M. Jain, U. Gerstmann, W. G. Schmidt, and H. Aldahhak, “Adatom mediated adsorption of <scp>N‐heterocyclic</scp> carbenes on Cu(111) and Au(111),” Journal of Computational Chemistry, vol. 43, no. 6, pp. 413–420, 2021, doi: 10.1002/jcc.26801."},"user_id":"16199","volume":43,"page":"413-420","_id":"40250","publisher":"Wiley","status":"public","type":"journal_article","keyword":["Computational Mathematics","General Chemistry"],"department":[{"_id":"15"},{"_id":"170"},{"_id":"295"},{"_id":"230"},{"_id":"35"},{"_id":"790"},{"_id":"27"}],"date_created":"2023-01-26T09:50:26Z","issue":"6","publication":"Journal of Computational Chemistry","doi":"10.1002/jcc.26801","language":[{"iso":"eng"}],"date_updated":"2025-12-05T13:57:51Z","publication_status":"published","intvolume":" 43","title":"Adatom mediated adsorption of N‐heterocyclic carbenes on Cu(111) and Au(111)","year":"2021","author":[{"full_name":"Jain, Mitisha","first_name":"Mitisha","last_name":"Jain"},{"full_name":"Gerstmann, Uwe","first_name":"Uwe","last_name":"Gerstmann","orcid":"0000-0002-4476-223X","id":"171"},{"id":"468","full_name":"Schmidt, Wolf Gero","last_name":"Schmidt","orcid":"0000-0002-2717-5076","first_name":"Wolf Gero"},{"first_name":"Hazem","last_name":"Aldahhak","full_name":"Aldahhak, Hazem"}],"publication_identifier":{"issn":["0192-8651","1096-987X"]}}]