TY - JOUR AB - AbstractWe conducted an investigation into the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene derivative and potassium thioacetate as a substitute for hydrogen sulfide. This investigation utilized kinetic and computational methods. We synthesized two palladium complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene (DPPF) and bis(diisopropylphosphino)ferrocene (DiPPF), as well as their tentative intermediates in the catalytic cycle. Reaction rates were measured and then compared to computational predictions. AU - Peschtrich, Sebastian AU - Schoch, Roland AU - Kuckling, Dirk AU - Paradies, Jan ID - 52541 IS - 8 JF - European Journal of Organic Chemistry KW - Organic Chemistry KW - Physical and Theoretical Chemistry SN - 1434-193X TI - A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes VL - 27 ER - TY - JOUR AB - A series of substituted ferrocenyl boron derivatives was synthesized. The oxidation of the ferrocenyl unit resulted in a significant increase of the boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized by NMR‐spectroscopy, crystal structure analysis and by computational methods. The new Lewis acids were then applied in the Meinwald rearrangement of epoxides, predominantly furnishing aldehydes as the kinetic products. AU - Köring, Laura AU - Birenheide, Bernhard AU - Krämer, Felix AU - Wenzel, Jonas O. AU - Schoch, Roland AU - Brehm, Martin AU - Breher, Frank AU - Paradies, Jan ID - 52572 JF - European Journal of Inorganic Chemistry KW - Inorganic Chemistry SN - 1434-1948 TI - Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements ER - TY - JOUR AU - Köring, Laura AU - Stepen, Arne AU - Birenheide, Bernhard AU - Barth, Simon AU - Leskov, Maxim AU - Schoch, Roland AU - Krämer, Felix AU - Breher, Frank AU - Paradies, Jan ID - 42878 JF - Angewandte Chemie International Edition KW - General Chemistry KW - Catalysis SN - 1433-7851 TI - Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation ER - TY - JOUR AU - Köring, Laura AU - Stepen, Arne AU - Birenheide, Bernhard AU - Barth, Simon AU - Leskov, Maxim AU - Schoch, Roland AU - Krämer, Felix AU - Breher, Frank AU - Paradies, Jan ID - 42879 JF - Angewandte Chemie KW - General Medicine SN - 0044-8249 TI - Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation ER - TY - JOUR AU - Paradies, Jan ID - 44523 IS - 7 JF - Accounts of Chemical Research KW - General Medicine KW - General Chemistry SN - 0001-4842 TI - Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed Hydrogenations, Dehydrogenations, and Cycloisomerizations VL - 56 ER - TY - JOUR AU - Sieland, Benedikt AU - Stahn, Marcel AU - Schoch, Roland AU - Daniliuc, Constantin AU - Spicher, Sebastian AU - Grimme, Stefan AU - Hansen, Andreas AU - Paradies, Jan ID - 46277 JF - Angewandte Chemie International Edition KW - General Chemistry KW - Catalysis SN - 1433-7851 TI - Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs ER - TY - JOUR AU - Krämer, Felix AU - Paradies, Jan AU - Fernández, Israel AU - Breher, Frank ID - 47589 JF - Nature Chemistry KW - General Chemical Engineering KW - General Chemistry SN - 1755-4330 TI - A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media ER - TY - JOUR AB - AbstractWe report on so‐called “hidden FLPs” (FLP: frustrated Lewis pair) consisting of a phosphorus ylide featuring a group 13 fragment in the ortho position of a phenyl ring scaffold to form five‐membered ring structures. Although the formation of the Lewis acid/base adducts was observed in the solid state, most of the title compounds readily react with carbon dioxide to provide stable insertion products. Strikingly, 0.3–3.0 mol% of the reported aluminum and gallium/carbon‐based ambiphiles catalyze the reduction of CO2 to methanol with satisfactory high selectivity and yields using pinacol borane as stoichiometric reduction equivalent. Comprehensive computational studies provided valuable mechanistic insights and shed more light on activity differences. AU - Krämer, Felix AU - Paradies, Jan AU - Fernández, Israel AU - Breher, Frank ID - 52542 IS - 5 JF - Chemistry – A European Journal KW - General Chemistry KW - Catalysis KW - Organic Chemistry SN - 0947-6539 TI - Quo Vadis CO2 Activation: Catalytic Reduction of CO2 to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles VL - 30 ER - TY - JOUR AU - Hou, Peng AU - Peschtrich, Sebastian AU - Huber, Nils AU - Feuerstein, Wolfram AU - Bihlmeier, Angela AU - Krummenacher, Ivo AU - Schoch, Roland AU - Klopper, Wim AU - Breher, Frank AU - Paradies, Jan ID - 35703 IS - 23 JF - Chemistry – A European Journal KW - General Chemistry KW - Catalysis KW - Organic Chemistry SN - 0947-6539 TI - Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022) VL - 28 ER - TY - JOUR AU - Andexer, Jennifer N. AU - Beifuss, Uwe AU - Beuerle, Florian AU - Brasholz, Malte AU - Breinbauer, Rolf AU - Ernst, Martin AU - Greb, Julian AU - Gulder, Tobias AU - Hüttel, Wolfgang AU - Kath‐Schorr, Stephanie AU - Kordes, Markus AU - Lehmann, Matthias AU - Lindel, Thomas AU - Luy, Burkhard AU - Mück‐Lichtenfeld, Christian AU - Muhle, Claudia AU - Narine, Arun AU - Niemeyer, Jörg AU - Paradies, Jan AU - Pfau, Roland AU - Pietruszka, Jörg AU - Schaschke, Norbert AU - Senge, Mathias AU - Straub, Bernd F. AU - Werner, Thomas AU - Werz, Daniel B. AU - Winter, Christian ID - 37956 IS - 3 JF - Nachrichten aus der Chemie KW - General Chemical Engineering KW - General Chemistry SN - 1439-9598 TI - Organische Chemie VL - 68 ER - TY - JOUR AU - Straub, Bernd AU - Andexer, Jennifer N. AU - Arenz, Christoph AU - Beifuss, Uwe AU - Beuerle, Florian AU - Brasholz, Malte AU - Breinbauer, Rolf AU - Ditrich, Klaus AU - Ernst, Martin AU - Gulder, Tobias A. M. AU - Kordes, Markus AU - Krueger, Anke AU - Lehmann, Matthias AU - Lindel, Thomas AU - Lüdeke, Steffen AU - Luy, Burkhard AU - Meier, Michael A. R. AU - Mück-Lichtenfeld, Christian AU - Muhle-Goll, Claudia AU - Narine, Arun AU - Paradies, Jan AU - Pfau, Roland AU - Pietruszka, Jörg AU - Schaschke, Norbert AU - Senge, Mathias O. AU - Werner, Thomas AU - Werz, Daniel B. AU - Winter, Christian AU - Worgull, Dennis ID - 37971 IS - 3 JF - Nachrichten aus der Chemie KW - General Chemical Engineering KW - General Chemistry SN - 1439-9598 TI - Trendbericht Organische Chemie 2017 VL - 66 ER - TY - JOUR AU - Straub, Bernd F. AU - Andexer, Jennifer AU - Arenz, Christoph AU - Beifuss, Uwe AU - Beuerle, Florian AU - Brasholz, Malte AU - Breinbauer, Rolf AU - Ditrich, Klaus AU - Gulder, Tobias A. M. AU - Hüttel, Wolfgang AU - Kordes, Markus AU - Krueger, Anke AU - Lehmann, Matthias AU - Lindel, Thomas AU - Luy, Burkhard AU - Meier, Michael A. R. AU - Mück-Lichtenfeld, Christian AU - Muhle-Goll, Claudia AU - Müller, Thomas J. J. AU - Narine, Arun AU - Paradies, Jan AU - Pfau, Roland AU - Pietruszka, Jörg AU - Schaschke, Norbert AU - Senge, Mathias O. AU - Werner, Thomas AU - Werz, Daniel B. AU - Winter, Christian A. AU - Worgull, Dennis ID - 37979 IS - 3 JF - Nachrichten aus der Chemie KW - General Chemical Engineering KW - General Chemistry SN - 1439-9598 TI - Organische Chemie 2016 VL - 65 ER - TY - JOUR AU - Bestgen, Sebastian AU - Seidl, Carmen AU - Wiesner, Thomas AU - Zimmer, Andreas AU - Falk, Martina AU - Köberle, Beate AU - Austeri, Martina AU - Paradies, Jan AU - Bräse, Stefan AU - Schepers, Ute AU - Roesky, Peter W. ID - 35705 IS - 26 JF - Chemistry - A European Journal KW - General Chemistry KW - Catalysis KW - Organic Chemistry SN - 0947-6539 TI - Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017) VL - 23 ER - TY - JOUR AU - Oechsle, Peter AU - Hou, Peng AU - Flörke, Ulrich AU - Paradies, Jan ID - 35708 IS - 23 JF - Advanced Synthesis & Catalysis KW - General Chemistry SN - 1615-4150 TI - Cover Picture: Concise Synthesis of Dithiophene Derivatives by a Palladium- Catalyzed Multiple C-S Cross Coupling/Cyclization Sequence (Adv. Synth. Catal. 23/2016) VL - 358 ER - TY - JOUR AU - Tussing, Sebastian AU - Kaupmees, Karl AU - Paradies, Jan ID - 35710 IS - 22 JF - Chemistry – A European Journal KW - General Chemistry KW - Catalysis KW - Organic Chemistry SN - 0947-6539 TI - Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016) VL - 22 ER -