TY - JOUR
AB - AbstractWe conducted an investigation into the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene derivative and potassium thioacetate as a substitute for hydrogen sulfide. This investigation utilized kinetic and computational methods. We synthesized two palladium complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene (DPPF) and bis(diisopropylphosphino)ferrocene (DiPPF), as well as their tentative intermediates in the catalytic cycle. Reaction rates were measured and then compared to computational predictions.
AU - Peschtrich, Sebastian
AU - Schoch, Roland
AU - Kuckling, Dirk
AU - Paradies, Jan
ID - 52541
IS - 8
JF - European Journal of Organic Chemistry
KW - Organic Chemistry
KW - Physical and Theoretical Chemistry
SN - 1434-193X
TI - A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes
VL - 27
ER -
TY - JOUR
AB - A series of substituted ferrocenyl boron derivatives was synthesized. The oxidation of the ferrocenyl unit resulted in a significant increase of the boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized by NMR‐spectroscopy, crystal structure analysis and by computational methods. The new Lewis acids were then applied in the Meinwald rearrangement of epoxides, predominantly furnishing aldehydes as the kinetic products.
AU - Köring, Laura
AU - Birenheide, Bernhard
AU - Krämer, Felix
AU - Wenzel, Jonas O.
AU - Schoch, Roland
AU - Brehm, Martin
AU - Breher, Frank
AU - Paradies, Jan
ID - 52572
JF - European Journal of Inorganic Chemistry
KW - Inorganic Chemistry
SN - 1434-1948
TI - Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements
ER -
TY - JOUR
AU - Köring, Laura
AU - Stepen, Arne
AU - Birenheide, Bernhard
AU - Barth, Simon
AU - Leskov, Maxim
AU - Schoch, Roland
AU - Krämer, Felix
AU - Breher, Frank
AU - Paradies, Jan
ID - 42878
JF - Angewandte Chemie International Edition
KW - General Chemistry
KW - Catalysis
SN - 1433-7851
TI - Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation
ER -
TY - JOUR
AU - Köring, Laura
AU - Stepen, Arne
AU - Birenheide, Bernhard
AU - Barth, Simon
AU - Leskov, Maxim
AU - Schoch, Roland
AU - Krämer, Felix
AU - Breher, Frank
AU - Paradies, Jan
ID - 42879
JF - Angewandte Chemie
KW - General Medicine
SN - 0044-8249
TI - Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation
ER -
TY - JOUR
AU - Paradies, Jan
ID - 44523
IS - 7
JF - Accounts of Chemical Research
KW - General Medicine
KW - General Chemistry
SN - 0001-4842
TI - Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed Hydrogenations, Dehydrogenations, and Cycloisomerizations
VL - 56
ER -
TY - JOUR
AU - Sieland, Benedikt
AU - Stahn, Marcel
AU - Schoch, Roland
AU - Daniliuc, Constantin
AU - Spicher, Sebastian
AU - Grimme, Stefan
AU - Hansen, Andreas
AU - Paradies, Jan
ID - 46277
JF - Angewandte Chemie International Edition
KW - General Chemistry
KW - Catalysis
SN - 1433-7851
TI - Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs
ER -
TY - JOUR
AU - Krämer, Felix
AU - Paradies, Jan
AU - Fernández, Israel
AU - Breher, Frank
ID - 47589
JF - Nature Chemistry
KW - General Chemical Engineering
KW - General Chemistry
SN - 1755-4330
TI - A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media
ER -
TY - JOUR
AB - AbstractWe report on so‐called “hidden FLPs” (FLP: frustrated Lewis pair) consisting of a phosphorus ylide featuring a group 13 fragment in the ortho position of a phenyl ring scaffold to form five‐membered ring structures. Although the formation of the Lewis acid/base adducts was observed in the solid state, most of the title compounds readily react with carbon dioxide to provide stable insertion products. Strikingly, 0.3–3.0 mol% of the reported aluminum and gallium/carbon‐based ambiphiles catalyze the reduction of CO2 to methanol with satisfactory high selectivity and yields using pinacol borane as stoichiometric reduction equivalent. Comprehensive computational studies provided valuable mechanistic insights and shed more light on activity differences.
AU - Krämer, Felix
AU - Paradies, Jan
AU - Fernández, Israel
AU - Breher, Frank
ID - 52542
IS - 5
JF - Chemistry – A European Journal
KW - General Chemistry
KW - Catalysis
KW - Organic Chemistry
SN - 0947-6539
TI - Quo Vadis CO2 Activation: Catalytic Reduction of CO2 to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles
VL - 30
ER -
TY - JOUR
AU - Hou, Peng
AU - Peschtrich, Sebastian
AU - Huber, Nils
AU - Feuerstein, Wolfram
AU - Bihlmeier, Angela
AU - Krummenacher, Ivo
AU - Schoch, Roland
AU - Klopper, Wim
AU - Breher, Frank
AU - Paradies, Jan
ID - 35703
IS - 23
JF - Chemistry – A European Journal
KW - General Chemistry
KW - Catalysis
KW - Organic Chemistry
SN - 0947-6539
TI - Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022)
VL - 28
ER -
TY - JOUR
AU - Andexer, Jennifer N.
AU - Beifuss, Uwe
AU - Beuerle, Florian
AU - Brasholz, Malte
AU - Breinbauer, Rolf
AU - Ernst, Martin
AU - Greb, Julian
AU - Gulder, Tobias
AU - Hüttel, Wolfgang
AU - Kath‐Schorr, Stephanie
AU - Kordes, Markus
AU - Lehmann, Matthias
AU - Lindel, Thomas
AU - Luy, Burkhard
AU - Mück‐Lichtenfeld, Christian
AU - Muhle, Claudia
AU - Narine, Arun
AU - Niemeyer, Jörg
AU - Paradies, Jan
AU - Pfau, Roland
AU - Pietruszka, Jörg
AU - Schaschke, Norbert
AU - Senge, Mathias
AU - Straub, Bernd F.
AU - Werner, Thomas
AU - Werz, Daniel B.
AU - Winter, Christian
ID - 37956
IS - 3
JF - Nachrichten aus der Chemie
KW - General Chemical Engineering
KW - General Chemistry
SN - 1439-9598
TI - Organische Chemie
VL - 68
ER -
TY - JOUR
AU - Straub, Bernd
AU - Andexer, Jennifer N.
AU - Arenz, Christoph
AU - Beifuss, Uwe
AU - Beuerle, Florian
AU - Brasholz, Malte
AU - Breinbauer, Rolf
AU - Ditrich, Klaus
AU - Ernst, Martin
AU - Gulder, Tobias A. M.
AU - Kordes, Markus
AU - Krueger, Anke
AU - Lehmann, Matthias
AU - Lindel, Thomas
AU - Lüdeke, Steffen
AU - Luy, Burkhard
AU - Meier, Michael A. R.
AU - Mück-Lichtenfeld, Christian
AU - Muhle-Goll, Claudia
AU - Narine, Arun
AU - Paradies, Jan
AU - Pfau, Roland
AU - Pietruszka, Jörg
AU - Schaschke, Norbert
AU - Senge, Mathias O.
AU - Werner, Thomas
AU - Werz, Daniel B.
AU - Winter, Christian
AU - Worgull, Dennis
ID - 37971
IS - 3
JF - Nachrichten aus der Chemie
KW - General Chemical Engineering
KW - General Chemistry
SN - 1439-9598
TI - Trendbericht Organische Chemie 2017
VL - 66
ER -
TY - JOUR
AU - Straub, Bernd F.
AU - Andexer, Jennifer
AU - Arenz, Christoph
AU - Beifuss, Uwe
AU - Beuerle, Florian
AU - Brasholz, Malte
AU - Breinbauer, Rolf
AU - Ditrich, Klaus
AU - Gulder, Tobias A. M.
AU - Hüttel, Wolfgang
AU - Kordes, Markus
AU - Krueger, Anke
AU - Lehmann, Matthias
AU - Lindel, Thomas
AU - Luy, Burkhard
AU - Meier, Michael A. R.
AU - Mück-Lichtenfeld, Christian
AU - Muhle-Goll, Claudia
AU - Müller, Thomas J. J.
AU - Narine, Arun
AU - Paradies, Jan
AU - Pfau, Roland
AU - Pietruszka, Jörg
AU - Schaschke, Norbert
AU - Senge, Mathias O.
AU - Werner, Thomas
AU - Werz, Daniel B.
AU - Winter, Christian A.
AU - Worgull, Dennis
ID - 37979
IS - 3
JF - Nachrichten aus der Chemie
KW - General Chemical Engineering
KW - General Chemistry
SN - 1439-9598
TI - Organische Chemie 2016
VL - 65
ER -
TY - JOUR
AU - Bestgen, Sebastian
AU - Seidl, Carmen
AU - Wiesner, Thomas
AU - Zimmer, Andreas
AU - Falk, Martina
AU - Köberle, Beate
AU - Austeri, Martina
AU - Paradies, Jan
AU - Bräse, Stefan
AU - Schepers, Ute
AU - Roesky, Peter W.
ID - 35705
IS - 26
JF - Chemistry - A European Journal
KW - General Chemistry
KW - Catalysis
KW - Organic Chemistry
SN - 0947-6539
TI - Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017)
VL - 23
ER -
TY - JOUR
AU - Oechsle, Peter
AU - Hou, Peng
AU - Flörke, Ulrich
AU - Paradies, Jan
ID - 35708
IS - 23
JF - Advanced Synthesis & Catalysis
KW - General Chemistry
SN - 1615-4150
TI - Cover Picture: Concise Synthesis of Dithiophene Derivatives by a Palladium- Catalyzed Multiple C-S Cross Coupling/Cyclization Sequence (Adv. Synth. Catal. 23/2016)
VL - 358
ER -
TY - JOUR
AU - Tussing, Sebastian
AU - Kaupmees, Karl
AU - Paradies, Jan
ID - 35710
IS - 22
JF - Chemistry – A European Journal
KW - General Chemistry
KW - Catalysis
KW - Organic Chemistry
SN - 0947-6539
TI - Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016)
VL - 22
ER -