---
_id: '64887'
abstract:
- lang: eng
  text: "<jats:title>Abstract</jats:title>\r\n                  <jats:p>Lachgas gelangt
    etwa aus Düngemitteln, Abgasen oder Narkosemitteln in die Atmosphäre und verursacht
    rund sechs Prozent der globalen Erwärmung. Effiziente Methoden, Lachgas abzubauen,
    gibt es bisher nicht. Wie ein neuer metallfreier Katalysator helfen könnte.</jats:p>"
author:
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Paradies J. Nichts zu lachen – oder doch? <i>Nachrichten aus der Chemie</i>.
    2026;74(1):61-63. doi:<a href="https://doi.org/10.1002/nadc.20264154740">10.1002/nadc.20264154740</a>
  apa: Paradies, J. (2026). Nichts zu lachen – oder doch? <i>Nachrichten Aus Der Chemie</i>,
    <i>74</i>(1), 61–63. <a href="https://doi.org/10.1002/nadc.20264154740">https://doi.org/10.1002/nadc.20264154740</a>
  bibtex: '@article{Paradies_2026, title={Nichts zu lachen – oder doch?}, volume={74},
    DOI={<a href="https://doi.org/10.1002/nadc.20264154740">10.1002/nadc.20264154740</a>},
    number={1}, journal={Nachrichten aus der Chemie}, publisher={Wiley}, author={Paradies,
    Jan}, year={2026}, pages={61–63} }'
  chicago: 'Paradies, Jan. “Nichts Zu Lachen – Oder Doch?” <i>Nachrichten Aus Der
    Chemie</i> 74, no. 1 (2026): 61–63. <a href="https://doi.org/10.1002/nadc.20264154740">https://doi.org/10.1002/nadc.20264154740</a>.'
  ieee: 'J. Paradies, “Nichts zu lachen – oder doch?,” <i>Nachrichten aus der Chemie</i>,
    vol. 74, no. 1, pp. 61–63, 2026, doi: <a href="https://doi.org/10.1002/nadc.20264154740">10.1002/nadc.20264154740</a>.'
  mla: Paradies, Jan. “Nichts Zu Lachen – Oder Doch?” <i>Nachrichten Aus Der Chemie</i>,
    vol. 74, no. 1, Wiley, 2026, pp. 61–63, doi:<a href="https://doi.org/10.1002/nadc.20264154740">10.1002/nadc.20264154740</a>.
  short: J. Paradies, Nachrichten Aus Der Chemie 74 (2026) 61–63.
date_created: 2026-03-11T10:14:54Z
date_updated: 2026-03-11T10:15:07Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/nadc.20264154740
intvolume: '        74'
issue: '1'
language:
- iso: eng
page: 61-63
publication: Nachrichten aus der Chemie
publication_identifier:
  issn:
  - 1439-9598
  - 1868-0054
publication_status: published
publisher: Wiley
status: public
title: Nichts zu lachen – oder doch?
type: journal_article
user_id: '53339'
volume: 74
year: '2026'
...
---
_id: '64886'
abstract:
- lang: eng
  text: "<jats:p>\r\n                    In the young field of enantioselective catalysis
    by frustrated Lewis pairs, the search for new chiral backbones for Lewis acids
    is desirable for future developments of the field. By taking advantage of the
    toluenesulfinyl group, a very useful traceless chiral auxiliary, it was possible
    to decorate stereopure axially chiral biphenyl tolyl sulfoxides and access unique
    chiral quaterphenyl tolyl sulfoxides by directed\r\n                    <jats:italic>ortho</jats:italic>\r\n
    \                   ‐metalation and electrophile trapping as well as a dynamic
    kinetic asymmetric arylative cross‐coupling. The resulting chiral backbone is
    amenable to accessing chiral boron‐based Lewis acids by conversion of the sulfinyl
    group to boron‐based ones.\r\n                  </jats:p>"
article_number: e70158
author:
- first_name: Jordan
  full_name: Berreur, Jordan
  last_name: Berreur
- first_name: Julien
  full_name: Bortoluzzi, Julien
  last_name: Bortoluzzi
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Frédéric R.
  full_name: Leroux, Frédéric R.
  last_name: Leroux
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
- first_name: Armen
  full_name: Panossian, Armen
  last_name: Panossian
citation:
  ama: Berreur J, Bortoluzzi J, Köring L, Leroux FR, Paradies J, Panossian A. Double
    Functionalization of Atropisomeric Biphenyl Sulfoxides by                    <i>Ortho</i> 
                      ‐Metalation and DYKAT Toward Chiral Quaterphenyl‐Based Borane
    Lewis Acids. <i>European Journal of Inorganic Chemistry</i>. Published online
    2026. doi:<a href="https://doi.org/10.1002/ejic.70158">10.1002/ejic.70158</a>
  apa: Berreur, J., Bortoluzzi, J., Köring, L., Leroux, F. R., Paradies, J., &#38;
    Panossian, A. (2026). Double Functionalization of Atropisomeric Biphenyl Sulfoxides
    by                    <i>Ortho</i>                    ‐Metalation and DYKAT Toward
    Chiral Quaterphenyl‐Based Borane Lewis Acids. <i>European Journal of Inorganic
    Chemistry</i>, Article e70158. <a href="https://doi.org/10.1002/ejic.70158">https://doi.org/10.1002/ejic.70158</a>
  bibtex: '@article{Berreur_Bortoluzzi_Köring_Leroux_Paradies_Panossian_2026, title={Double
    Functionalization of Atropisomeric Biphenyl Sulfoxides by                    <i>Ortho</i> 
                      ‐Metalation and DYKAT Toward Chiral Quaterphenyl‐Based Borane
    Lewis Acids}, DOI={<a href="https://doi.org/10.1002/ejic.70158">10.1002/ejic.70158</a>},
    number={e70158}, journal={European Journal of Inorganic Chemistry}, publisher={Wiley},
    author={Berreur, Jordan and Bortoluzzi, Julien and Köring, Laura and Leroux, Frédéric
    R. and Paradies, Jan and Panossian, Armen}, year={2026} }'
  chicago: Berreur, Jordan, Julien Bortoluzzi, Laura Köring, Frédéric R. Leroux, Jan
    Paradies, and Armen Panossian. “Double Functionalization of Atropisomeric Biphenyl
    Sulfoxides by                    <i>Ortho</i>                    ‐Metalation and
    DYKAT Toward Chiral Quaterphenyl‐Based Borane Lewis Acids.” <i>European Journal
    of Inorganic Chemistry</i>, 2026. <a href="https://doi.org/10.1002/ejic.70158">https://doi.org/10.1002/ejic.70158</a>.
  ieee: 'J. Berreur, J. Bortoluzzi, L. Köring, F. R. Leroux, J. Paradies, and A. Panossian,
    “Double Functionalization of Atropisomeric Biphenyl Sulfoxides by             
          <i>Ortho</i>                    ‐Metalation and DYKAT Toward Chiral Quaterphenyl‐Based
    Borane Lewis Acids,” <i>European Journal of Inorganic Chemistry</i>, Art. no.
    e70158, 2026, doi: <a href="https://doi.org/10.1002/ejic.70158">10.1002/ejic.70158</a>.'
  mla: Berreur, Jordan, et al. “Double Functionalization of Atropisomeric Biphenyl
    Sulfoxides by                    <i>Ortho</i>                    ‐Metalation and
    DYKAT Toward Chiral Quaterphenyl‐Based Borane Lewis Acids.” <i>European Journal
    of Inorganic Chemistry</i>, e70158, Wiley, 2026, doi:<a href="https://doi.org/10.1002/ejic.70158">10.1002/ejic.70158</a>.
  short: J. Berreur, J. Bortoluzzi, L. Köring, F.R. Leroux, J. Paradies, A. Panossian,
    European Journal of Inorganic Chemistry (2026).
date_created: 2026-03-11T10:10:08Z
date_updated: 2026-03-11T10:36:31Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/ejic.70158
language:
- iso: eng
publication: European Journal of Inorganic Chemistry
publication_identifier:
  issn:
  - 1434-1948
  - 1099-0682
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Double Functionalization of Atropisomeric Biphenyl Sulfoxides by                    <i>Ortho</i>                    ‐Metalation
  and DYKAT Toward Chiral Quaterphenyl‐Based Borane Lewis Acids
type: journal_article
user_id: '53339'
year: '2026'
...
---
_id: '61335'
abstract:
- lang: eng
  text: <jats:p>Amidines are a ubiquitous class of bioactive compounds found in a
    wide variety of natural products; thus, efficient strategies for their preparation
    are in great demand. Herein, a novel protocol is reported for the synthesis of
    amidines based on P<jats:sup>III</jats:sup>/P<jats:sup>V</jats:sup>O redox catalysis.
    This two‐step, one‐pot approach involves the activation of amides via P<jats:sup>III</jats:sup>/P<jats:sup>V</jats:sup>O
    catalyzed in situ formation of imidoyl chloride intermediates which are directly
    converted upon reaction with amines into the corresponding amidines. Instead of
    traditionally used toxic and corrosive chloride sources, hexachloroacetone (HCA)
    is successfully employed as a halide source. The reaction proceeds with low catalyst
    loading (2 mol%) in BuOAc as the solvent. Under the optimized conditions, 20 amidines
    are prepared in yields up to 99%. A feasible mechanism is proposed based on experimental
    results. The synthetic potential of this method is evaluated in the preparation
    of the tyrosine kinase inhibitor (TKI) Erlotinib.</jats:p>
article_number: '202500394'
author:
- first_name: Viktorija
  full_name: Medvaric, Viktorija
  id: '92677'
  last_name: Medvaric
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
- first_name: Thomas
  full_name: Werner, Thomas
  id: '89271'
  last_name: Werner
  orcid: 0000-0001-9025-3244
citation:
  ama: Medvaric V, Paradies J, Werner T. Synthesis of Amidines Via P(III)/P(V)=O Redox
    Catalyzed In Situ Formation of Imidoyl Chlorides From Amides. <i>Advanced Synthesis
    and Catalysis</i>. Published online 2025. doi:<a href="https://doi.org/10.1002/adsc.70059">10.1002/adsc.70059</a>
  apa: Medvaric, V., Paradies, J., &#38; Werner, T. (2025). Synthesis of Amidines
    Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From
    Amides. <i>Advanced Synthesis and Catalysis</i>, Article 202500394. <a href="https://doi.org/10.1002/adsc.70059">https://doi.org/10.1002/adsc.70059</a>
  bibtex: '@article{Medvaric_Paradies_Werner_2025, title={Synthesis of Amidines Via
    P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides},
    DOI={<a href="https://doi.org/10.1002/adsc.70059">10.1002/adsc.70059</a>}, number={202500394},
    journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Medvaric,
    Viktorija and Paradies, Jan and Werner, Thomas}, year={2025} }'
  chicago: Medvaric, Viktorija, Jan Paradies, and Thomas Werner. “Synthesis of Amidines
    Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From
    Amides.” <i>Advanced Synthesis and Catalysis</i>, 2025. <a href="https://doi.org/10.1002/adsc.70059">https://doi.org/10.1002/adsc.70059</a>.
  ieee: 'V. Medvaric, J. Paradies, and T. Werner, “Synthesis of Amidines Via P(III)/P(V)=O
    Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides,” <i>Advanced
    Synthesis and Catalysis</i>, Art. no. 202500394, 2025, doi: <a href="https://doi.org/10.1002/adsc.70059">10.1002/adsc.70059</a>.'
  mla: Medvaric, Viktorija, et al. “Synthesis of Amidines Via P(III)/P(V)=O Redox
    Catalyzed In Situ Formation of Imidoyl Chlorides From Amides.” <i>Advanced Synthesis
    and Catalysis</i>, 202500394, Wiley, 2025, doi:<a href="https://doi.org/10.1002/adsc.70059">10.1002/adsc.70059</a>.
  short: V. Medvaric, J. Paradies, T. Werner, Advanced Synthesis and Catalysis (2025).
date_created: 2025-09-17T15:16:49Z
date_updated: 2025-11-10T08:44:04Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/adsc.70059
keyword:
- T2
- T
- CSSD
language:
- iso: eng
publication: Advanced Synthesis and Catalysis
publication_identifier:
  issn:
  - 1615-4150
  - 1615-4169
publication_status: published
publisher: Wiley
status: public
title: Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of
  Imidoyl Chlorides From Amides
type: journal_article
user_id: '89271'
year: '2025'
...
---
_id: '61336'
article_number: jacs.5c06190
author:
- first_name: Rundong
  full_name: Zhou, Rundong
  last_name: Zhou
- first_name: Viktorija
  full_name: Medvaric, Viktorija
  id: '92677'
  last_name: Medvaric
- first_name: Thomas
  full_name: Werner, Thomas
  id: '89271'
  last_name: Werner
  orcid: https://orcid.org/0000-0001-9025-3244
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: 'Zhou R, Medvaric V, Werner T, Paradies J. Metal-Free Reduction of Nitrous
    Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights and Catalytic
    Performance. <i>Journal of the American Chemical Society</i>. Published online
    2025. doi:<a href="https://doi.org/10.1021/jacs.5c06190">10.1021/jacs.5c06190</a>'
  apa: 'Zhou, R., Medvaric, V., Werner, T., &#38; Paradies, J. (2025). Metal-Free
    Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic
    Insights and Catalytic Performance. <i>Journal of the American Chemical Society</i>,
    Article jacs. 5c06190. <a href="https://doi.org/10.1021/jacs.5c06190">https://doi.org/10.1021/jacs.5c06190</a>'
  bibtex: '@article{Zhou_Medvaric_Werner_Paradies_2025, title={Metal-Free Reduction
    of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights
    and Catalytic Performance}, DOI={<a href="https://doi.org/10.1021/jacs.5c06190">10.1021/jacs.5c06190</a>},
    number={jacs. 5c06190}, journal={Journal of the American Chemical Society}, publisher={American
    Chemical Society (ACS)}, author={Zhou, Rundong and Medvaric, Viktorija and Werner,
    Thomas and Paradies, Jan}, year={2025} }'
  chicago: 'Zhou, Rundong, Viktorija Medvaric, Thomas Werner, and Jan Paradies. “Metal-Free
    Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic
    Insights and Catalytic Performance.” <i>Journal of the American Chemical Society</i>,
    2025. <a href="https://doi.org/10.1021/jacs.5c06190">https://doi.org/10.1021/jacs.5c06190</a>.'
  ieee: 'R. Zhou, V. Medvaric, T. Werner, and J. Paradies, “Metal-Free Reduction of
    Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights
    and Catalytic Performance,” <i>Journal of the American Chemical Society</i>, Art.
    no. jacs. 5c06190, 2025, doi: <a href="https://doi.org/10.1021/jacs.5c06190">10.1021/jacs.5c06190</a>.'
  mla: 'Zhou, Rundong, et al. “Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O
    Cycling: Mechanistic Insights and Catalytic Performance.” <i>Journal of the American
    Chemical Society</i>, jacs. 5c06190, American Chemical Society (ACS), 2025, doi:<a
    href="https://doi.org/10.1021/jacs.5c06190">10.1021/jacs.5c06190</a>.'
  short: R. Zhou, V. Medvaric, T. Werner, J. Paradies, Journal of the American Chemical
    Society (2025).
date_created: 2025-09-17T15:18:11Z
date_updated: 2025-11-10T08:43:50Z
department:
- _id: '2'
- _id: '389'
doi: 10.1021/jacs.5c06190
keyword:
- T2
- CSSD
language:
- iso: eng
publication: Journal of the American Chemical Society
publication_identifier:
  issn:
  - 0002-7863
  - 1520-5126
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O
  Cycling: Mechanistic Insights and Catalytic Performance'
type: journal_article
user_id: '89271'
year: '2025'
...
---
_id: '52541'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>We conducted an investigation into
    the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene
    derivative and potassium thioacetate as a substitute for hydrogen sulfide. This
    investigation utilized kinetic and computational methods. We synthesized two palladium
    complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene
    (DPPF) and bis(diisopropylphosphino)ferrocene (D<jats:italic>i</jats:italic>PPF),
    as well as their tentative intermediates in the catalytic cycle. Reaction rates
    were measured and then compared to computational predictions.</jats:p>
author:
- first_name: Sebastian
  full_name: Peschtrich, Sebastian
  last_name: Peschtrich
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Dirk
  full_name: Kuckling, Dirk
  id: '287'
  last_name: Kuckling
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Peschtrich S, Schoch R, Kuckling D, Paradies J. A Comparative Kinetic and Computational
    Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and
    2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. <i>European Journal
    of Organic Chemistry</i>. 2024;27(8). doi:<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>
  apa: Peschtrich, S., Schoch, R., Kuckling, D., &#38; Paradies, J. (2024). A Comparative
    Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of
    Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.
    <i>European Journal of Organic Chemistry</i>, <i>27</i>(8). <a href="https://doi.org/10.1002/ejoc.202301207">https://doi.org/10.1002/ejoc.202301207</a>
  bibtex: '@article{Peschtrich_Schoch_Kuckling_Paradies_2024, title={A Comparative
    Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of
    Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes},
    volume={27}, DOI={<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>},
    number={8}, journal={European Journal of Organic Chemistry}, publisher={Wiley},
    author={Peschtrich, Sebastian and Schoch, Roland and Kuckling, Dirk and Paradies,
    Jan}, year={2024} }'
  chicago: Peschtrich, Sebastian, Roland Schoch, Dirk Kuckling, and Jan Paradies.
    “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross
    Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine
    Complexes.” <i>European Journal of Organic Chemistry</i> 27, no. 8 (2024). <a
    href="https://doi.org/10.1002/ejoc.202301207">https://doi.org/10.1002/ejoc.202301207</a>.
  ieee: 'S. Peschtrich, R. Schoch, D. Kuckling, and J. Paradies, “A Comparative Kinetic
    and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium
    Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes,” <i>European
    Journal of Organic Chemistry</i>, vol. 27, no. 8, 2024, doi: <a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>.'
  mla: Peschtrich, Sebastian, et al. “A Comparative Kinetic and Computational Investigation
    of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene
    Using Palladium/Bisphosphine Complexes.” <i>European Journal of Organic Chemistry</i>,
    vol. 27, no. 8, Wiley, 2024, doi:<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>.
  short: S. Peschtrich, R. Schoch, D. Kuckling, J. Paradies, European Journal of Organic
    Chemistry 27 (2024).
date_created: 2024-03-13T17:15:14Z
date_updated: 2024-03-13T17:17:37Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/ejoc.202301207
intvolume: '        27'
issue: '8'
keyword:
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
publication: European Journal of Organic Chemistry
publication_identifier:
  issn:
  - 1434-193X
  - 1099-0690
publication_status: published
publisher: Wiley
status: public
title: A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur
  Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine
  Complexes
type: journal_article
user_id: '53339'
volume: 27
year: '2024'
...
---
_id: '52572'
abstract:
- lang: eng
  text: <jats:p>A series of substituted ferrocenyl boron derivatives was synthesized.
    The oxidation of the ferrocenyl unit resulted in a significant increase of the
    boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized
    by NMR‐spectroscopy, crystal structure analysis and by computational methods.
    The new Lewis acids were then applied in the Meinwald rearrangement of epoxides,
    predominantly furnishing aldehydes as the kinetic products.</jats:p>
author:
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Bernhard
  full_name: Birenheide, Bernhard
  last_name: Birenheide
- first_name: Felix
  full_name: Krämer, Felix
  last_name: Krämer
- first_name: Jonas O.
  full_name: Wenzel, Jonas O.
  last_name: Wenzel
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Martin
  full_name: Brehm, Martin
  id: '100167'
  last_name: Brehm
- first_name: Frank
  full_name: Breher, Frank
  last_name: Breher
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Köring L, Birenheide B, Krämer F, et al. Synthesis of Ferrocenyl Boranes and
    their Application as Lewis Acids in Epoxide Rearrangements. <i>European Journal
    of Inorganic Chemistry</i>. Published online 2024. doi:<a href="https://doi.org/10.1002/ejic.202400057">10.1002/ejic.202400057</a>
  apa: Köring, L., Birenheide, B., Krämer, F., Wenzel, J. O., Schoch, R., Brehm, M.,
    Breher, F., &#38; Paradies, J. (2024). Synthesis of Ferrocenyl Boranes and their
    Application as Lewis Acids in Epoxide Rearrangements. <i>European Journal of Inorganic
    Chemistry</i>. <a href="https://doi.org/10.1002/ejic.202400057">https://doi.org/10.1002/ejic.202400057</a>
  bibtex: '@article{Köring_Birenheide_Krämer_Wenzel_Schoch_Brehm_Breher_Paradies_2024,
    title={Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in
    Epoxide Rearrangements}, DOI={<a href="https://doi.org/10.1002/ejic.202400057">10.1002/ejic.202400057</a>},
    journal={European Journal of Inorganic Chemistry}, publisher={Wiley}, author={Köring,
    Laura and Birenheide, Bernhard and Krämer, Felix and Wenzel, Jonas O. and Schoch,
    Roland and Brehm, Martin and Breher, Frank and Paradies, Jan}, year={2024} }'
  chicago: Köring, Laura, Bernhard Birenheide, Felix Krämer, Jonas O. Wenzel, Roland
    Schoch, Martin Brehm, Frank Breher, and Jan Paradies. “Synthesis of Ferrocenyl
    Boranes and Their Application as Lewis Acids in Epoxide Rearrangements.” <i>European
    Journal of Inorganic Chemistry</i>, 2024. <a href="https://doi.org/10.1002/ejic.202400057">https://doi.org/10.1002/ejic.202400057</a>.
  ieee: 'L. Köring <i>et al.</i>, “Synthesis of Ferrocenyl Boranes and their Application
    as Lewis Acids in Epoxide Rearrangements,” <i>European Journal of Inorganic Chemistry</i>,
    2024, doi: <a href="https://doi.org/10.1002/ejic.202400057">10.1002/ejic.202400057</a>.'
  mla: Köring, Laura, et al. “Synthesis of Ferrocenyl Boranes and Their Application
    as Lewis Acids in Epoxide Rearrangements.” <i>European Journal of Inorganic Chemistry</i>,
    Wiley, 2024, doi:<a href="https://doi.org/10.1002/ejic.202400057">10.1002/ejic.202400057</a>.
  short: L. Köring, B. Birenheide, F. Krämer, J.O. Wenzel, R. Schoch, M. Brehm, F.
    Breher, J. Paradies, European Journal of Inorganic Chemistry (2024).
date_created: 2024-03-14T07:09:09Z
date_updated: 2024-03-14T07:10:37Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/ejic.202400057
keyword:
- Inorganic Chemistry
language:
- iso: eng
publication: European Journal of Inorganic Chemistry
publication_identifier:
  issn:
  - 1434-1948
  - 1099-0682
publication_status: published
publisher: Wiley
status: public
title: Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide
  Rearrangements
type: journal_article
user_id: '53339'
year: '2024'
...
---
_id: '55371'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F
    bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub>
    is reported and applied in reactions with arenes, allylic, vinylic and acetylenic
    silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>
author:
- first_name: Axel
  full_name: Hoppe, Axel
  last_name: Hoppe
- first_name: Arne J.
  full_name: Stepen, Arne J.
  last_name: Stepen
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>.
    2024;366(13):2933-2938. doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>
  apa: Hoppe, A., Stepen, A. J., Köring, L., &#38; Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    <i>366</i>(13), 2933–2938. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>
  bibtex: '@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>},
    number={13}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley},
    author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan},
    year={2024}, pages={2933–2938} }'
  chicago: 'Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>
    366, no. 13 (2024): 2933–38. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>.'
  ieee: 'A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds,” <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    vol. 366, no. 13, pp. 2933–2938, 2024, doi: <a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.'
  mla: Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization
    of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366,
    no. 13, Wiley, 2024, pp. 2933–38, doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.
  short: A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis &#38;amp;
    Catalysis 366 (2024) 2933–2938.
date_created: 2024-07-24T09:16:15Z
date_updated: 2024-07-24T09:18:18Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/adsc.202400511
intvolume: '       366'
issue: '13'
language:
- iso: eng
page: 2933-2938
publication: Advanced Synthesis &amp; Catalysis
publication_identifier:
  issn:
  - 1615-4150
  - 1615-4169
publication_status: published
publisher: Wiley
status: public
title: Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds
type: journal_article
user_id: '53339'
volume: 366
year: '2024'
...
---
_id: '59616'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F
    bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub>
    is reported and applied in reactions with arenes, allylic, vinylic and acetylenic
    silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>
author:
- first_name: Axel
  full_name: Hoppe, Axel
  id: '62844'
  last_name: Hoppe
- first_name: Arne J.
  full_name: Stepen, Arne J.
  last_name: Stepen
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>.
    2024;366(13):2933-2938. doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>
  apa: Hoppe, A., Stepen, A. J., Köring, L., &#38; Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    <i>366</i>(13), 2933–2938. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>
  bibtex: '@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>},
    number={13}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley},
    author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan},
    year={2024}, pages={2933–2938} }'
  chicago: 'Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>
    366, no. 13 (2024): 2933–38. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>.'
  ieee: 'A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds,” <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    vol. 366, no. 13, pp. 2933–2938, 2024, doi: <a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.'
  mla: Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization
    of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366,
    no. 13, Wiley, 2024, pp. 2933–38, doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.
  short: A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis &#38;amp;
    Catalysis 366 (2024) 2933–2938.
date_created: 2025-04-22T05:59:08Z
date_updated: 2025-04-22T06:11:59Z
department:
- _id: '389'
doi: 10.1002/adsc.202400511
intvolume: '       366'
issue: '13'
keyword:
- fluoride
- bond activation
- borane
- Lewis acid
- C-C bond formation
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202400511
oa: '1'
page: 2933-2938
publication: Advanced Synthesis &amp; Catalysis
publication_identifier:
  issn:
  - 1615-4150
  - 1615-4169
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds
type: journal_article
user_id: '62844'
volume: 366
year: '2024'
...
---
_id: '47589'
author:
- first_name: Felix
  full_name: Krämer, Felix
  last_name: Krämer
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
- first_name: Israel
  full_name: Fernández, Israel
  last_name: Fernández
- first_name: Frank
  full_name: Breher, Frank
  last_name: Breher
citation:
  ama: Krämer F, Paradies J, Fernández I, Breher F. A crystalline aluminium–carbon-based
    ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous
    media. <i>Nature Chemistry</i>. Published online 2023. doi:<a href="https://doi.org/10.1038/s41557-023-01340-9">10.1038/s41557-023-01340-9</a>
  apa: Krämer, F., Paradies, J., Fernández, I., &#38; Breher, F. (2023). A crystalline
    aluminium–carbon-based ambiphile capable of activation and catalytic transfer
    of ammonia in non-aqueous media. <i>Nature Chemistry</i>. <a href="https://doi.org/10.1038/s41557-023-01340-9">https://doi.org/10.1038/s41557-023-01340-9</a>
  bibtex: '@article{Krämer_Paradies_Fernández_Breher_2023, title={A crystalline aluminium–carbon-based
    ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous
    media}, DOI={<a href="https://doi.org/10.1038/s41557-023-01340-9">10.1038/s41557-023-01340-9</a>},
    journal={Nature Chemistry}, publisher={Springer Science and Business Media LLC},
    author={Krämer, Felix and Paradies, Jan and Fernández, Israel and Breher, Frank},
    year={2023} }'
  chicago: Krämer, Felix, Jan Paradies, Israel Fernández, and Frank Breher. “A Crystalline
    Aluminium–Carbon-Based Ambiphile Capable of Activation and Catalytic Transfer
    of Ammonia in Non-Aqueous Media.” <i>Nature Chemistry</i>, 2023. <a href="https://doi.org/10.1038/s41557-023-01340-9">https://doi.org/10.1038/s41557-023-01340-9</a>.
  ieee: 'F. Krämer, J. Paradies, I. Fernández, and F. Breher, “A crystalline aluminium–carbon-based
    ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous
    media,” <i>Nature Chemistry</i>, 2023, doi: <a href="https://doi.org/10.1038/s41557-023-01340-9">10.1038/s41557-023-01340-9</a>.'
  mla: Krämer, Felix, et al. “A Crystalline Aluminium–Carbon-Based Ambiphile Capable
    of Activation and Catalytic Transfer of Ammonia in Non-Aqueous Media.” <i>Nature
    Chemistry</i>, Springer Science and Business Media LLC, 2023, doi:<a href="https://doi.org/10.1038/s41557-023-01340-9">10.1038/s41557-023-01340-9</a>.
  short: F. Krämer, J. Paradies, I. Fernández, F. Breher, Nature Chemistry (2023).
date_created: 2023-10-04T14:40:07Z
date_updated: 2023-10-04T14:41:12Z
department:
- _id: '2'
- _id: '389'
doi: 10.1038/s41557-023-01340-9
keyword:
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
publication: Nature Chemistry
publication_identifier:
  issn:
  - 1755-4330
  - 1755-4349
publication_status: published
publisher: Springer Science and Business Media LLC
status: public
title: A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic
  transfer of ammonia in non-aqueous media
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '52542'
abstract:
- lang: eng
  text: '<jats:title>Abstract</jats:title><jats:p>We report on so‐called “hidden FLPs”
    (FLP: frustrated Lewis pair) consisting of a phosphorus ylide featuring a group
    13 fragment in the <jats:italic>ortho</jats:italic> position of a phenyl ring
    scaffold to form five‐membered ring structures. Although the formation of the
    Lewis acid/base adducts was observed in the solid state, most of the title compounds
    readily react with carbon dioxide to provide stable insertion products. Strikingly,
    0.3–3.0 mol% of the reported aluminum and gallium/carbon‐based ambiphiles catalyze
    the reduction of CO<jats:sub>2</jats:sub> to methanol with satisfactory high selectivity
    and yields using pinacol borane as stoichiometric reduction equivalent. Comprehensive
    computational studies provided valuable mechanistic insights and shed more light
    on activity differences.</jats:p>'
author:
- first_name: Felix
  full_name: Krämer, Felix
  last_name: Krämer
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
- first_name: Israel
  full_name: Fernández, Israel
  last_name: Fernández
- first_name: Frank
  full_name: Breher, Frank
  last_name: Breher
citation:
  ama: 'Krämer F, Paradies J, Fernández I, Breher F. Quo Vadis CO<sub>2</sub> Activation:
    Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based
    Ambiphiles. <i>Chemistry – A European Journal</i>. 2023;30(5). doi:<a href="https://doi.org/10.1002/chem.202303380">10.1002/chem.202303380</a>'
  apa: 'Krämer, F., Paradies, J., Fernández, I., &#38; Breher, F. (2023). Quo Vadis
    CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using
    Aluminum and Gallium/Carbon‐based Ambiphiles. <i>Chemistry – A European Journal</i>,
    <i>30</i>(5). <a href="https://doi.org/10.1002/chem.202303380">https://doi.org/10.1002/chem.202303380</a>'
  bibtex: '@article{Krämer_Paradies_Fernández_Breher_2023, title={Quo Vadis CO<sub>2</sub>
    Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and
    Gallium/Carbon‐based Ambiphiles}, volume={30}, DOI={<a href="https://doi.org/10.1002/chem.202303380">10.1002/chem.202303380</a>},
    number={5}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Krämer,
    Felix and Paradies, Jan and Fernández, Israel and Breher, Frank}, year={2023}
    }'
  chicago: 'Krämer, Felix, Jan Paradies, Israel Fernández, and Frank Breher. “Quo
    Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol
    Using Aluminum and Gallium/Carbon‐based Ambiphiles.” <i>Chemistry – A European
    Journal</i> 30, no. 5 (2023). <a href="https://doi.org/10.1002/chem.202303380">https://doi.org/10.1002/chem.202303380</a>.'
  ieee: 'F. Krämer, J. Paradies, I. Fernández, and F. Breher, “Quo Vadis CO<sub>2</sub>
    Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and
    Gallium/Carbon‐based Ambiphiles,” <i>Chemistry – A European Journal</i>, vol.
    30, no. 5, 2023, doi: <a href="https://doi.org/10.1002/chem.202303380">10.1002/chem.202303380</a>.'
  mla: 'Krämer, Felix, et al. “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction
    of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles.”
    <i>Chemistry – A European Journal</i>, vol. 30, no. 5, Wiley, 2023, doi:<a href="https://doi.org/10.1002/chem.202303380">10.1002/chem.202303380</a>.'
  short: F. Krämer, J. Paradies, I. Fernández, F. Breher, Chemistry – A European Journal
    30 (2023).
date_created: 2024-03-13T17:17:52Z
date_updated: 2024-03-13T17:18:17Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/chem.202303380
intvolume: '        30'
issue: '5'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
  issn:
  - 0947-6539
  - 1521-3765
publication_status: published
publisher: Wiley
status: public
title: 'Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub>
  to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles'
type: journal_article
user_id: '53339'
volume: 30
year: '2023'
...
---
_id: '42878'
author:
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Arne
  full_name: Stepen, Arne
  last_name: Stepen
- first_name: Bernhard
  full_name: Birenheide, Bernhard
  last_name: Birenheide
- first_name: Simon
  full_name: Barth, Simon
  last_name: Barth
- first_name: Maxim
  full_name: Leskov, Maxim
  last_name: Leskov
- first_name: Roland
  full_name: Schoch, Roland
  last_name: Schoch
- first_name: Felix
  full_name: Krämer, Felix
  last_name: Krämer
- first_name: Frank
  full_name: Breher, Frank
  last_name: Breher
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: 'Köring L, Stepen A, Birenheide B, et al. Boron‐Centered Lewis Superacid through
    Redox‐Active Ligands: Application in C−F and S−F Bond Activation. <i>Angewandte
    Chemie International Edition</i>. Published online 2023. doi:<a href="https://doi.org/10.1002/anie.202301632">10.1002/anie.202301632</a>'
  apa: 'Köring, L., Stepen, A., Birenheide, B., Barth, S., Leskov, M., Schoch, R.,
    Krämer, F., Breher, F., &#38; Paradies, J. (2023). Boron‐Centered Lewis Superacid
    through Redox‐Active Ligands: Application in C−F and S−F Bond Activation. <i>Angewandte
    Chemie International Edition</i>. <a href="https://doi.org/10.1002/anie.202301632">https://doi.org/10.1002/anie.202301632</a>'
  bibtex: '@article{Köring_Stepen_Birenheide_Barth_Leskov_Schoch_Krämer_Breher_Paradies_2023,
    title={Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application
    in C−F and S−F Bond Activation}, DOI={<a href="https://doi.org/10.1002/anie.202301632">10.1002/anie.202301632</a>},
    journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Köring,
    Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim
    and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}, year={2023}
    }'
  chicago: 'Köring, Laura, Arne Stepen, Bernhard Birenheide, Simon Barth, Maxim Leskov,
    Roland Schoch, Felix Krämer, Frank Breher, and Jan Paradies. “Boron‐Centered Lewis
    Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation.”
    <i>Angewandte Chemie International Edition</i>, 2023. <a href="https://doi.org/10.1002/anie.202301632">https://doi.org/10.1002/anie.202301632</a>.'
  ieee: 'L. Köring <i>et al.</i>, “Boron‐Centered Lewis Superacid through Redox‐Active
    Ligands: Application in C−F and S−F Bond Activation,” <i>Angewandte Chemie International
    Edition</i>, 2023, doi: <a href="https://doi.org/10.1002/anie.202301632">10.1002/anie.202301632</a>.'
  mla: 'Köring, Laura, et al. “Boron‐Centered Lewis Superacid through Redox‐Active
    Ligands: Application in C−F and S−F Bond Activation.” <i>Angewandte Chemie International
    Edition</i>, Wiley, 2023, doi:<a href="https://doi.org/10.1002/anie.202301632">10.1002/anie.202301632</a>.'
  short: L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer,
    F. Breher, J. Paradies, Angewandte Chemie International Edition (2023).
date_created: 2023-03-08T19:27:25Z
date_updated: 2023-03-08T19:31:59Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/anie.202301632
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
publication: Angewandte Chemie International Edition
publication_identifier:
  issn:
  - 1433-7851
  - 1521-3773
publication_status: published
publisher: Wiley
status: public
title: 'Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in
  C−F and S−F Bond Activation'
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '42879'
author:
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Arne
  full_name: Stepen, Arne
  last_name: Stepen
- first_name: Bernhard
  full_name: Birenheide, Bernhard
  last_name: Birenheide
- first_name: Simon
  full_name: Barth, Simon
  last_name: Barth
- first_name: Maxim
  full_name: Leskov, Maxim
  last_name: Leskov
- first_name: Roland
  full_name: Schoch, Roland
  last_name: Schoch
- first_name: Felix
  full_name: Krämer, Felix
  last_name: Krämer
- first_name: Frank
  full_name: Breher, Frank
  last_name: Breher
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: 'Köring L, Stepen A, Birenheide B, et al. Boron‐Centered Lewis Superacid through
    Redox‐Active Ligands: Application in C−F and S−F Bond Activation. <i>Angewandte
    Chemie</i>. Published online 2023. doi:<a href="https://doi.org/10.1002/ange.202301632">10.1002/ange.202301632</a>'
  apa: 'Köring, L., Stepen, A., Birenheide, B., Barth, S., Leskov, M., Schoch, R.,
    Krämer, F., Breher, F., &#38; Paradies, J. (2023). Boron‐Centered Lewis Superacid
    through Redox‐Active Ligands: Application in C−F and S−F Bond Activation. <i>Angewandte
    Chemie</i>. <a href="https://doi.org/10.1002/ange.202301632">https://doi.org/10.1002/ange.202301632</a>'
  bibtex: '@article{Köring_Stepen_Birenheide_Barth_Leskov_Schoch_Krämer_Breher_Paradies_2023,
    title={Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application
    in C−F and S−F Bond Activation}, DOI={<a href="https://doi.org/10.1002/ange.202301632">10.1002/ange.202301632</a>},
    journal={Angewandte Chemie}, publisher={Wiley}, author={Köring, Laura and Stepen,
    Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim and Schoch, Roland
    and Krämer, Felix and Breher, Frank and Paradies, Jan}, year={2023} }'
  chicago: 'Köring, Laura, Arne Stepen, Bernhard Birenheide, Simon Barth, Maxim Leskov,
    Roland Schoch, Felix Krämer, Frank Breher, and Jan Paradies. “Boron‐Centered Lewis
    Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation.”
    <i>Angewandte Chemie</i>, 2023. <a href="https://doi.org/10.1002/ange.202301632">https://doi.org/10.1002/ange.202301632</a>.'
  ieee: 'L. Köring <i>et al.</i>, “Boron‐Centered Lewis Superacid through Redox‐Active
    Ligands: Application in C−F and S−F Bond Activation,” <i>Angewandte Chemie</i>,
    2023, doi: <a href="https://doi.org/10.1002/ange.202301632">10.1002/ange.202301632</a>.'
  mla: 'Köring, Laura, et al. “Boron‐Centered Lewis Superacid through Redox‐Active
    Ligands: Application in C−F and S−F Bond Activation.” <i>Angewandte Chemie</i>,
    Wiley, 2023, doi:<a href="https://doi.org/10.1002/ange.202301632">10.1002/ange.202301632</a>.'
  short: L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer,
    F. Breher, J. Paradies, Angewandte Chemie (2023).
date_created: 2023-03-08T19:31:03Z
date_updated: 2023-03-08T19:32:09Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/ange.202301632
keyword:
- General Medicine
language:
- iso: eng
publication: Angewandte Chemie
publication_identifier:
  issn:
  - 0044-8249
  - 1521-3757
publication_status: published
publisher: Wiley
status: public
title: 'Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in
  C−F and S−F Bond Activation'
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '44523'
author:
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Paradies J. Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed
    Hydrogenations, Dehydrogenations, and Cycloisomerizations. <i>Accounts of Chemical
    Research</i>. 2023;56(7):821-834. doi:<a href="https://doi.org/10.1021/acs.accounts.2c00832">10.1021/acs.accounts.2c00832</a>
  apa: Paradies, J. (2023). Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed
    Hydrogenations, Dehydrogenations, and Cycloisomerizations. <i>Accounts of Chemical
    Research</i>, <i>56</i>(7), 821–834. <a href="https://doi.org/10.1021/acs.accounts.2c00832">https://doi.org/10.1021/acs.accounts.2c00832</a>
  bibtex: '@article{Paradies_2023, title={Structure–Reactivity Relationships in Borane-Based
    FLP-Catalyzed Hydrogenations, Dehydrogenations, and Cycloisomerizations}, volume={56},
    DOI={<a href="https://doi.org/10.1021/acs.accounts.2c00832">10.1021/acs.accounts.2c00832</a>},
    number={7}, journal={Accounts of Chemical Research}, publisher={American Chemical
    Society (ACS)}, author={Paradies, Jan}, year={2023}, pages={821–834} }'
  chicago: 'Paradies, Jan. “Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed
    Hydrogenations, Dehydrogenations, and Cycloisomerizations.” <i>Accounts of Chemical
    Research</i> 56, no. 7 (2023): 821–34. <a href="https://doi.org/10.1021/acs.accounts.2c00832">https://doi.org/10.1021/acs.accounts.2c00832</a>.'
  ieee: 'J. Paradies, “Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed
    Hydrogenations, Dehydrogenations, and Cycloisomerizations,” <i>Accounts of Chemical
    Research</i>, vol. 56, no. 7, pp. 821–834, 2023, doi: <a href="https://doi.org/10.1021/acs.accounts.2c00832">10.1021/acs.accounts.2c00832</a>.'
  mla: Paradies, Jan. “Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed
    Hydrogenations, Dehydrogenations, and Cycloisomerizations.” <i>Accounts of Chemical
    Research</i>, vol. 56, no. 7, American Chemical Society (ACS), 2023, pp. 821–34,
    doi:<a href="https://doi.org/10.1021/acs.accounts.2c00832">10.1021/acs.accounts.2c00832</a>.
  short: J. Paradies, Accounts of Chemical Research 56 (2023) 821–834.
date_created: 2023-05-05T13:25:50Z
date_updated: 2023-05-05T13:27:06Z
department:
- _id: '2'
- _id: '389'
doi: 10.1021/acs.accounts.2c00832
intvolume: '        56'
issue: '7'
keyword:
- General Medicine
- General Chemistry
language:
- iso: eng
page: 821-834
publication: Accounts of Chemical Research
publication_identifier:
  issn:
  - 0001-4842
  - 1520-4898
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Structure–Reactivity Relationships in Borane-Based FLP-Catalyzed Hydrogenations,
  Dehydrogenations, and Cycloisomerizations
type: journal_article
user_id: '53339'
volume: 56
year: '2023'
...
---
_id: '46277'
author:
- first_name: Benedikt
  full_name: Sieland, Benedikt
  last_name: Sieland
- first_name: Marcel
  full_name: Stahn, Marcel
  last_name: Stahn
- first_name: Roland
  full_name: Schoch, Roland
  last_name: Schoch
- first_name: Constantin
  full_name: Daniliuc, Constantin
  last_name: Daniliuc
- first_name: Sebastian
  full_name: Spicher, Sebastian
  last_name: Spicher
- first_name: Stefan
  full_name: Grimme, Stefan
  last_name: Grimme
- first_name: Andreas
  full_name: Hansen, Andreas
  last_name: Hansen
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Sieland B, Stahn M, Schoch R, et al. Dispersion Energy‐Stabilized Boron and
    Phosphorus Lewis Pairs. <i>Angewandte Chemie International Edition</i>. Published
    online 2023. doi:<a href="https://doi.org/10.1002/anie.202308752">10.1002/anie.202308752</a>
  apa: Sieland, B., Stahn, M., Schoch, R., Daniliuc, C., Spicher, S., Grimme, S.,
    Hansen, A., &#38; Paradies, J. (2023). Dispersion Energy‐Stabilized Boron and
    Phosphorus Lewis Pairs. <i>Angewandte Chemie International Edition</i>. <a href="https://doi.org/10.1002/anie.202308752">https://doi.org/10.1002/anie.202308752</a>
  bibtex: '@article{Sieland_Stahn_Schoch_Daniliuc_Spicher_Grimme_Hansen_Paradies_2023,
    title={Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs}, DOI={<a
    href="https://doi.org/10.1002/anie.202308752">10.1002/anie.202308752</a>}, journal={Angewandte
    Chemie International Edition}, publisher={Wiley}, author={Sieland, Benedikt and
    Stahn, Marcel and Schoch, Roland and Daniliuc, Constantin and Spicher, Sebastian
    and Grimme, Stefan and Hansen, Andreas and Paradies, Jan}, year={2023} }'
  chicago: Sieland, Benedikt, Marcel Stahn, Roland Schoch, Constantin Daniliuc, Sebastian
    Spicher, Stefan Grimme, Andreas Hansen, and Jan Paradies. “Dispersion Energy‐Stabilized
    Boron and Phosphorus Lewis Pairs.” <i>Angewandte Chemie International Edition</i>,
    2023. <a href="https://doi.org/10.1002/anie.202308752">https://doi.org/10.1002/anie.202308752</a>.
  ieee: 'B. Sieland <i>et al.</i>, “Dispersion Energy‐Stabilized Boron and Phosphorus
    Lewis Pairs,” <i>Angewandte Chemie International Edition</i>, 2023, doi: <a href="https://doi.org/10.1002/anie.202308752">10.1002/anie.202308752</a>.'
  mla: Sieland, Benedikt, et al. “Dispersion Energy‐Stabilized Boron and Phosphorus
    Lewis Pairs.” <i>Angewandte Chemie International Edition</i>, Wiley, 2023, doi:<a
    href="https://doi.org/10.1002/anie.202308752">10.1002/anie.202308752</a>.
  short: B. Sieland, M. Stahn, R. Schoch, C. Daniliuc, S. Spicher, S. Grimme, A. Hansen,
    J. Paradies, Angewandte Chemie International Edition (2023).
date_created: 2023-08-03T09:00:33Z
date_updated: 2023-08-03T09:01:41Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/anie.202308752
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
publication: Angewandte Chemie International Edition
publication_identifier:
  issn:
  - 1433-7851
  - 1521-3773
publication_status: published
publisher: Wiley
status: public
title: Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '64893'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>The synthesis of three novel imidazolyl‐substituted
    sulfur‐containing heteroacenes is reported. These heteroacenes consisting of annelated
    benzo‐ and naphthothiophenes serve as precursors for the generation of open‐shell
    quinoid heteroacenes by oxidation with alkaline ferric cyanide. Spectroscopic
    and computational experiments support the formation of reactive open‐shell quinoids,
    which, however, quickly produce paramagnetic polymeric material.</jats:p>
article_number: e202300003
author:
- first_name: Peng
  full_name: Hou, Peng
  last_name: Hou
- first_name: Sebastian
  full_name: Peschtrich, Sebastian
  last_name: Peschtrich
- first_name: Wolfram
  full_name: Feuerstein, Wolfram
  last_name: Feuerstein
- first_name: Roland
  full_name: Schoch, Roland
  last_name: Schoch
- first_name: Stephan
  full_name: Hohloch, Stephan
  last_name: Hohloch
- first_name: Frank
  full_name: Breher, Frank
  last_name: Breher
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Hou P, Peschtrich S, Feuerstein W, et al. Imidazolyl‐Substituted Benzo‐ and
    Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids.
    <i>ChemistryOpen</i>. 2023;12(11). doi:<a href="https://doi.org/10.1002/open.202300003">10.1002/open.202300003</a>
  apa: Hou, P., Peschtrich, S., Feuerstein, W., Schoch, R., Hohloch, S., Breher, F.,
    &#38; Paradies, J. (2023). Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes
    as Precursors for the Synthesis of Transient Open‐Shell Quinoids. <i>ChemistryOpen</i>,
    <i>12</i>(11), Article e202300003. <a href="https://doi.org/10.1002/open.202300003">https://doi.org/10.1002/open.202300003</a>
  bibtex: '@article{Hou_Peschtrich_Feuerstein_Schoch_Hohloch_Breher_Paradies_2023,
    title={Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for
    the Synthesis of Transient Open‐Shell Quinoids}, volume={12}, DOI={<a href="https://doi.org/10.1002/open.202300003">10.1002/open.202300003</a>},
    number={11e202300003}, journal={ChemistryOpen}, publisher={Wiley}, author={Hou,
    Peng and Peschtrich, Sebastian and Feuerstein, Wolfram and Schoch, Roland and
    Hohloch, Stephan and Breher, Frank and Paradies, Jan}, year={2023} }'
  chicago: Hou, Peng, Sebastian Peschtrich, Wolfram Feuerstein, Roland Schoch, Stephan
    Hohloch, Frank Breher, and Jan Paradies. “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes
    as Precursors for the Synthesis of Transient Open‐Shell Quinoids.” <i>ChemistryOpen</i>
    12, no. 11 (2023). <a href="https://doi.org/10.1002/open.202300003">https://doi.org/10.1002/open.202300003</a>.
  ieee: 'P. Hou <i>et al.</i>, “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes
    as Precursors for the Synthesis of Transient Open‐Shell Quinoids,” <i>ChemistryOpen</i>,
    vol. 12, no. 11, Art. no. e202300003, 2023, doi: <a href="https://doi.org/10.1002/open.202300003">10.1002/open.202300003</a>.'
  mla: Hou, Peng, et al. “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as
    Precursors for the Synthesis of Transient Open‐Shell Quinoids.” <i>ChemistryOpen</i>,
    vol. 12, no. 11, e202300003, Wiley, 2023, doi:<a href="https://doi.org/10.1002/open.202300003">10.1002/open.202300003</a>.
  short: P. Hou, S. Peschtrich, W. Feuerstein, R. Schoch, S. Hohloch, F. Breher, J.
    Paradies, ChemistryOpen 12 (2023).
date_created: 2026-03-11T10:21:31Z
date_updated: 2026-03-11T10:21:47Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/open.202300003
intvolume: '        12'
issue: '11'
language:
- iso: eng
publication: ChemistryOpen
publication_identifier:
  issn:
  - 2191-1363
  - 2191-1363
publication_status: published
publisher: Wiley
status: public
title: Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the
  Synthesis of Transient Open‐Shell Quinoids
type: journal_article
user_id: '53339'
volume: 12
year: '2023'
...
---
_id: '35703'
author:
- first_name: Peng
  full_name: Hou, Peng
  last_name: Hou
- first_name: Sebastian
  full_name: Peschtrich, Sebastian
  last_name: Peschtrich
- first_name: Nils
  full_name: Huber, Nils
  last_name: Huber
- first_name: Wolfram
  full_name: Feuerstein, Wolfram
  last_name: Feuerstein
- first_name: Angela
  full_name: Bihlmeier, Angela
  last_name: Bihlmeier
- first_name: Ivo
  full_name: Krummenacher, Ivo
  last_name: Krummenacher
- first_name: Roland
  full_name: Schoch, Roland
  last_name: Schoch
- first_name: Wim
  full_name: Klopper, Wim
  last_name: Klopper
- first_name: Frank
  full_name: Breher, Frank
  last_name: Breher
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: 'Hou P, Peschtrich S, Huber N, et al. Cover Feature: Impact of Heterocycle
    Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022).
    <i>Chemistry – A European Journal</i>. 2022;28(23). doi:<a href="https://doi.org/10.1002/chem.202200982">10.1002/chem.202200982</a>'
  apa: 'Hou, P., Peschtrich, S., Huber, N., Feuerstein, W., Bihlmeier, A., Krummenacher,
    I., Schoch, R., Klopper, W., Breher, F., &#38; Paradies, J. (2022). Cover Feature:
    Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives
    (Chem. Eur. J. 23/2022). <i>Chemistry – A European Journal</i>, <i>28</i>(23).
    <a href="https://doi.org/10.1002/chem.202200982">https://doi.org/10.1002/chem.202200982</a>'
  bibtex: '@article{Hou_Peschtrich_Huber_Feuerstein_Bihlmeier_Krummenacher_Schoch_Klopper_Breher_Paradies_2022,
    title={Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid
    Thioacene Derivatives (Chem. Eur. J. 23/2022)}, volume={28}, DOI={<a href="https://doi.org/10.1002/chem.202200982">10.1002/chem.202200982</a>},
    number={23}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Hou,
    Peng and Peschtrich, Sebastian and Huber, Nils and Feuerstein, Wolfram and Bihlmeier,
    Angela and Krummenacher, Ivo and Schoch, Roland and Klopper, Wim and Breher, Frank
    and Paradies, Jan}, year={2022} }'
  chicago: 'Hou, Peng, Sebastian Peschtrich, Nils Huber, Wolfram Feuerstein, Angela
    Bihlmeier, Ivo Krummenacher, Roland Schoch, Wim Klopper, Frank Breher, and Jan
    Paradies. “Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in
    Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022).” <i>Chemistry – A European
    Journal</i> 28, no. 23 (2022). <a href="https://doi.org/10.1002/chem.202200982">https://doi.org/10.1002/chem.202200982</a>.'
  ieee: 'P. Hou <i>et al.</i>, “Cover Feature: Impact of Heterocycle Annulation on
    NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022),” <i>Chemistry
    – A European Journal</i>, vol. 28, no. 23, 2022, doi: <a href="https://doi.org/10.1002/chem.202200982">10.1002/chem.202200982</a>.'
  mla: 'Hou, Peng, et al. “Cover Feature: Impact of Heterocycle Annulation on NIR
    Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022).” <i>Chemistry
    – A European Journal</i>, vol. 28, no. 23, Wiley, 2022, doi:<a href="https://doi.org/10.1002/chem.202200982">10.1002/chem.202200982</a>.'
  short: P. Hou, S. Peschtrich, N. Huber, W. Feuerstein, A. Bihlmeier, I. Krummenacher,
    R. Schoch, W. Klopper, F. Breher, J. Paradies, Chemistry – A European Journal
    28 (2022).
date_created: 2023-01-10T09:10:15Z
date_updated: 2023-01-23T12:47:43Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/chem.202200982
intvolume: '        28'
issue: '23'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
  issn:
  - 0947-6539
  - 1521-3765
publication_status: published
publisher: Wiley
status: public
title: 'Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid
  Thioacene Derivatives (Chem. Eur. J. 23/2022)'
type: journal_article
user_id: '53339'
volume: 28
year: '2022'
...
---
_id: '59619'
abstract:
- lang: eng
  text: "<jats:title>Abstract</jats:title><jats:p>A frustrated Lewis pair‐catalyzed
    hydroboration of aromatic and aliphatic nitriles was developed. The catalyst provides
    the primary amines in high yields of 77–99% with catalyst loading as low as 2 mol%.
    The reaction displays high functional group tolerance towards esters, amides,
    nitro groups and aliphatic halides. The addition of the diborylated amines to
    ethyl 3‐phenylpropiolate proceeds with Z‐selectivity with d.r. of &gt;99:1 in
    77–90% yield over two steps. The reaction mechanism was investigated by control
    and computational experiments.</jats:p><jats:p><jats:boxed-text content-type=\"graphic\"
    position=\"anchor\"><jats:graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\"
    mimetype=\"image/png\" position=\"anchor\" specific-use=\"enlarged-web-image\"
    xlink:href=\"graphic/adsc202200525-toc-0001-m.png\"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text>\r\n</jats:p>"
author:
- first_name: Benedikt
  full_name: Sieland, Benedikt
  last_name: Sieland
- first_name: Axel
  full_name: Hoppe, Axel
  id: '62844'
  last_name: Hoppe
- first_name: Arne J.
  full_name: Stepen, Arne J.
  last_name: Stepen
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: 'Sieland B, Hoppe A, Stepen AJ, Paradies J. Frustrated Lewis Pair‐Catalyzed
    Hydroboration of Nitriles: FLP Versus Borenium Catalysis. <i>Advanced Synthesis
    &#38;amp; Catalysis</i>. 2022;364(18):3143-3148. doi:<a href="https://doi.org/10.1002/adsc.202200525">10.1002/adsc.202200525</a>'
  apa: 'Sieland, B., Hoppe, A., Stepen, A. J., &#38; Paradies, J. (2022). Frustrated
    Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis.
    <i>Advanced Synthesis &#38;amp; Catalysis</i>, <i>364</i>(18), 3143–3148. <a href="https://doi.org/10.1002/adsc.202200525">https://doi.org/10.1002/adsc.202200525</a>'
  bibtex: '@article{Sieland_Hoppe_Stepen_Paradies_2022, title={Frustrated Lewis Pair‐Catalyzed
    Hydroboration of Nitriles: FLP Versus Borenium Catalysis}, volume={364}, DOI={<a
    href="https://doi.org/10.1002/adsc.202200525">10.1002/adsc.202200525</a>}, number={18},
    journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley}, author={Sieland,
    Benedikt and Hoppe, Axel and Stepen, Arne J. and Paradies, Jan}, year={2022},
    pages={3143–3148} }'
  chicago: 'Sieland, Benedikt, Axel Hoppe, Arne J. Stepen, and Jan Paradies. “Frustrated
    Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis.”
    <i>Advanced Synthesis &#38;amp; Catalysis</i> 364, no. 18 (2022): 3143–48. <a
    href="https://doi.org/10.1002/adsc.202200525">https://doi.org/10.1002/adsc.202200525</a>.'
  ieee: 'B. Sieland, A. Hoppe, A. J. Stepen, and J. Paradies, “Frustrated Lewis Pair‐Catalyzed
    Hydroboration of Nitriles: FLP Versus Borenium Catalysis,” <i>Advanced Synthesis
    &#38;amp; Catalysis</i>, vol. 364, no. 18, pp. 3143–3148, 2022, doi: <a href="https://doi.org/10.1002/adsc.202200525">10.1002/adsc.202200525</a>.'
  mla: 'Sieland, Benedikt, et al. “Frustrated Lewis Pair‐Catalyzed Hydroboration of
    Nitriles: FLP Versus Borenium Catalysis.” <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    vol. 364, no. 18, Wiley, 2022, pp. 3143–48, doi:<a href="https://doi.org/10.1002/adsc.202200525">10.1002/adsc.202200525</a>.'
  short: B. Sieland, A. Hoppe, A.J. Stepen, J. Paradies, Advanced Synthesis &#38;amp;
    Catalysis 364 (2022) 3143–3148.
date_created: 2025-04-22T06:01:56Z
date_updated: 2025-04-22T06:12:05Z
department:
- _id: '389'
doi: 10.1002/adsc.202200525
intvolume: '       364'
issue: '18'
keyword:
- hydroboration
- nitrile
- amine
- frustrated Lewis pair
- density functional theory
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202200525
oa: '1'
page: 3143-3148
publication: Advanced Synthesis &amp; Catalysis
publication_identifier:
  issn:
  - 1615-4150
  - 1615-4169
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: 'Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium
  Catalysis'
type: journal_article
user_id: '62844'
volume: 364
year: '2022'
...
---
_id: '64895'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>Elektrochemische Synthese – Naturstoffe
    und deren Synthese – photokatalytische Redoxchemie – Farbstoffe – Nanostrukturen
    – Wirkstoffe – asymmetrische Katalyse und mehr.</jats:p>
author:
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
- first_name: Jennifer
  full_name: Andexer, Jennifer
  last_name: Andexer
- first_name: Uwe
  full_name: Beifuss, Uwe
  last_name: Beifuss
- first_name: Florian
  full_name: Beuerle, Florian
  last_name: Beuerle
- first_name: Malte
  full_name: Brasholz, Malte
  last_name: Brasholz
- first_name: Rolf
  full_name: Breinbauer, Rolf
  last_name: Breinbauer
- first_name: Martin
  full_name: Ernst, Martin
  last_name: Ernst
- first_name: Ruth
  full_name: Ganardi, Ruth
  last_name: Ganardi
- first_name: Tobias A. M.
  full_name: Gulder, Tobias A. M.
  last_name: Gulder
- first_name: Wolfgang
  full_name: Hüttel, Wolfgang
  last_name: Hüttel
- first_name: Stephanie
  full_name: Kath‐Schorr, Stephanie
  last_name: Kath‐Schorr
- first_name: Karsten
  full_name: Körber, Karsten
  last_name: Körber
- first_name: Markus
  full_name: Kordes, Markus
  last_name: Kordes
- first_name: Matthias
  full_name: Lehmann, Matthias
  last_name: Lehmann
- first_name: Thomas
  full_name: Lindel, Thomas
  last_name: Lindel
- first_name: Burkhard
  full_name: Luy, Burkhard
  last_name: Luy
- first_name: Christian
  full_name: Mück‐Lichtenfeld, Christian
  last_name: Mück‐Lichtenfeld
- first_name: Claudia
  full_name: Muhle‐Goll, Claudia
  last_name: Muhle‐Goll
- first_name: Jochen
  full_name: Niemeyer, Jochen
  last_name: Niemeyer
- first_name: Roland
  full_name: Pfau, Roland
  last_name: Pfau
- first_name: Jörg
  full_name: Pietruszka, Jörg
  last_name: Pietruszka
- first_name: Johannes L.
  full_name: Röckl, Johannes L.
  last_name: Röckl
- first_name: Norbert
  full_name: Schaschke, Norbert
  last_name: Schaschke
- first_name: Mathias O.
  full_name: Senge, Mathias O.
  last_name: Senge
- first_name: Bernd F.
  full_name: Straub, Bernd F.
  last_name: Straub
- first_name: Siegfried R.
  full_name: Waldvogel, Siegfried R.
  last_name: Waldvogel
- first_name: Thomas
  full_name: Werner, Thomas
  last_name: Werner
- first_name: Daniel B.
  full_name: Werz, Daniel B.
  last_name: Werz
- first_name: Christian
  full_name: Winter, Christian
  last_name: Winter
citation:
  ama: Paradies J, Andexer J, Beifuss U, et al. Organische Chemie. <i>Nachrichten
    aus der Chemie</i>. 2021;69(3):38-68. doi:<a href="https://doi.org/10.1002/nadc.20214105947">10.1002/nadc.20214105947</a>
  apa: Paradies, J., Andexer, J., Beifuss, U., Beuerle, F., Brasholz, M., Breinbauer,
    R., Ernst, M., Ganardi, R., Gulder, T. A. M., Hüttel, W., Kath‐Schorr, S., Körber,
    K., Kordes, M., Lehmann, M., Lindel, T., Luy, B., Mück‐Lichtenfeld, C., Muhle‐Goll,
    C., Niemeyer, J., … Winter, C. (2021). Organische Chemie. <i>Nachrichten Aus Der
    Chemie</i>, <i>69</i>(3), 38–68. <a href="https://doi.org/10.1002/nadc.20214105947">https://doi.org/10.1002/nadc.20214105947</a>
  bibtex: '@article{Paradies_Andexer_Beifuss_Beuerle_Brasholz_Breinbauer_Ernst_Ganardi_Gulder_Hüttel_et
    al._2021, title={Organische Chemie}, volume={69}, DOI={<a href="https://doi.org/10.1002/nadc.20214105947">10.1002/nadc.20214105947</a>},
    number={3}, journal={Nachrichten aus der Chemie}, publisher={Wiley}, author={Paradies,
    Jan and Andexer, Jennifer and Beifuss, Uwe and Beuerle, Florian and Brasholz,
    Malte and Breinbauer, Rolf and Ernst, Martin and Ganardi, Ruth and Gulder, Tobias
    A. M. and Hüttel, Wolfgang and et al.}, year={2021}, pages={38–68} }'
  chicago: 'Paradies, Jan, Jennifer Andexer, Uwe Beifuss, Florian Beuerle, Malte Brasholz,
    Rolf Breinbauer, Martin Ernst, et al. “Organische Chemie.” <i>Nachrichten Aus
    Der Chemie</i> 69, no. 3 (2021): 38–68. <a href="https://doi.org/10.1002/nadc.20214105947">https://doi.org/10.1002/nadc.20214105947</a>.'
  ieee: 'J. Paradies <i>et al.</i>, “Organische Chemie,” <i>Nachrichten aus der Chemie</i>,
    vol. 69, no. 3, pp. 38–68, 2021, doi: <a href="https://doi.org/10.1002/nadc.20214105947">10.1002/nadc.20214105947</a>.'
  mla: Paradies, Jan, et al. “Organische Chemie.” <i>Nachrichten Aus Der Chemie</i>,
    vol. 69, no. 3, Wiley, 2021, pp. 38–68, doi:<a href="https://doi.org/10.1002/nadc.20214105947">10.1002/nadc.20214105947</a>.
  short: J. Paradies, J. Andexer, U. Beifuss, F. Beuerle, M. Brasholz, R. Breinbauer,
    M. Ernst, R. Ganardi, T.A.M. Gulder, W. Hüttel, S. Kath‐Schorr, K. Körber, M.
    Kordes, M. Lehmann, T. Lindel, B. Luy, C. Mück‐Lichtenfeld, C. Muhle‐Goll, J.
    Niemeyer, R. Pfau, J. Pietruszka, J.L. Röckl, N. Schaschke, M.O. Senge, B.F. Straub,
    S.R. Waldvogel, T. Werner, D.B. Werz, C. Winter, Nachrichten Aus Der Chemie 69
    (2021) 38–68.
date_created: 2026-03-11T10:23:15Z
date_updated: 2026-03-11T10:23:22Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/nadc.20214105947
intvolume: '        69'
issue: '3'
language:
- iso: eng
page: 38-68
publication: Nachrichten aus der Chemie
publication_identifier:
  issn:
  - 1439-9598
  - 1868-0054
publication_status: published
publisher: Wiley
status: public
title: Organische Chemie
type: journal_article
user_id: '53339'
volume: 69
year: '2021'
...
---
_id: '37956'
author:
- first_name: Jennifer N.
  full_name: Andexer, Jennifer N.
  last_name: Andexer
- first_name: Uwe
  full_name: Beifuss, Uwe
  last_name: Beifuss
- first_name: Florian
  full_name: Beuerle, Florian
  last_name: Beuerle
- first_name: Malte
  full_name: Brasholz, Malte
  last_name: Brasholz
- first_name: Rolf
  full_name: Breinbauer, Rolf
  last_name: Breinbauer
- first_name: Martin
  full_name: Ernst, Martin
  last_name: Ernst
- first_name: Julian
  full_name: Greb, Julian
  last_name: Greb
- first_name: Tobias
  full_name: Gulder, Tobias
  last_name: Gulder
- first_name: Wolfgang
  full_name: Hüttel, Wolfgang
  last_name: Hüttel
- first_name: Stephanie
  full_name: Kath‐Schorr, Stephanie
  last_name: Kath‐Schorr
- first_name: Markus
  full_name: Kordes, Markus
  last_name: Kordes
- first_name: Matthias
  full_name: Lehmann, Matthias
  last_name: Lehmann
- first_name: Thomas
  full_name: Lindel, Thomas
  last_name: Lindel
- first_name: Burkhard
  full_name: Luy, Burkhard
  last_name: Luy
- first_name: Christian
  full_name: Mück‐Lichtenfeld, Christian
  last_name: Mück‐Lichtenfeld
- first_name: Claudia
  full_name: Muhle, Claudia
  last_name: Muhle
- first_name: Arun
  full_name: Narine, Arun
  last_name: Narine
- first_name: Jörg
  full_name: Niemeyer, Jörg
  last_name: Niemeyer
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
- first_name: Roland
  full_name: Pfau, Roland
  last_name: Pfau
- first_name: Jörg
  full_name: Pietruszka, Jörg
  last_name: Pietruszka
- first_name: Norbert
  full_name: Schaschke, Norbert
  last_name: Schaschke
- first_name: Mathias
  full_name: Senge, Mathias
  last_name: Senge
- first_name: Bernd F.
  full_name: Straub, Bernd F.
  last_name: Straub
- first_name: Thomas
  full_name: Werner, Thomas
  id: '89271'
  last_name: Werner
  orcid: 0000-0001-9025-3244
- first_name: Daniel B.
  full_name: Werz, Daniel B.
  last_name: Werz
- first_name: Christian
  full_name: Winter, Christian
  last_name: Winter
citation:
  ama: Andexer JN, Beifuss U, Beuerle F, et al. Organische Chemie. <i>Nachrichten
    aus der Chemie</i>. 2020;68(3):42-72. doi:<a href="https://doi.org/10.1002/nadc.20204095515">10.1002/nadc.20204095515</a>
  apa: Andexer, J. N., Beifuss, U., Beuerle, F., Brasholz, M., Breinbauer, R., Ernst,
    M., Greb, J., Gulder, T., Hüttel, W., Kath‐Schorr, S., Kordes, M., Lehmann, M.,
    Lindel, T., Luy, B., Mück‐Lichtenfeld, C., Muhle, C., Narine, A., Niemeyer, J.,
    Paradies, J., … Winter, C. (2020). Organische Chemie. <i>Nachrichten Aus Der Chemie</i>,
    <i>68</i>(3), 42–72. <a href="https://doi.org/10.1002/nadc.20204095515">https://doi.org/10.1002/nadc.20204095515</a>
  bibtex: '@article{Andexer_Beifuss_Beuerle_Brasholz_Breinbauer_Ernst_Greb_Gulder_Hüttel_Kath‐Schorr_et
    al._2020, title={Organische Chemie}, volume={68}, DOI={<a href="https://doi.org/10.1002/nadc.20204095515">10.1002/nadc.20204095515</a>},
    number={3}, journal={Nachrichten aus der Chemie}, publisher={Wiley}, author={Andexer,
    Jennifer N. and Beifuss, Uwe and Beuerle, Florian and Brasholz, Malte and Breinbauer,
    Rolf and Ernst, Martin and Greb, Julian and Gulder, Tobias and Hüttel, Wolfgang
    and Kath‐Schorr, Stephanie and et al.}, year={2020}, pages={42–72} }'
  chicago: 'Andexer, Jennifer N., Uwe Beifuss, Florian Beuerle, Malte Brasholz, Rolf
    Breinbauer, Martin Ernst, Julian Greb, et al. “Organische Chemie.” <i>Nachrichten
    Aus Der Chemie</i> 68, no. 3 (2020): 42–72. <a href="https://doi.org/10.1002/nadc.20204095515">https://doi.org/10.1002/nadc.20204095515</a>.'
  ieee: 'J. N. Andexer <i>et al.</i>, “Organische Chemie,” <i>Nachrichten aus der
    Chemie</i>, vol. 68, no. 3, pp. 42–72, 2020, doi: <a href="https://doi.org/10.1002/nadc.20204095515">10.1002/nadc.20204095515</a>.'
  mla: Andexer, Jennifer N., et al. “Organische Chemie.” <i>Nachrichten Aus Der Chemie</i>,
    vol. 68, no. 3, Wiley, 2020, pp. 42–72, doi:<a href="https://doi.org/10.1002/nadc.20204095515">10.1002/nadc.20204095515</a>.
  short: J.N. Andexer, U. Beifuss, F. Beuerle, M. Brasholz, R. Breinbauer, M. Ernst,
    J. Greb, T. Gulder, W. Hüttel, S. Kath‐Schorr, M. Kordes, M. Lehmann, T. Lindel,
    B. Luy, C. Mück‐Lichtenfeld, C. Muhle, A. Narine, J. Niemeyer, J. Paradies, R.
    Pfau, J. Pietruszka, N. Schaschke, M. Senge, B.F. Straub, T. Werner, D.B. Werz,
    C. Winter, Nachrichten Aus Der Chemie 68 (2020) 42–72.
date_created: 2023-01-22T20:40:48Z
date_updated: 2025-11-10T08:13:43Z
department:
- _id: '35'
- _id: '2'
- _id: '657'
- _id: '389'
doi: 10.1002/nadc.20204095515
extern: '1'
intvolume: '        68'
issue: '3'
keyword:
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 42-72
publication: Nachrichten aus der Chemie
publication_identifier:
  issn:
  - 1439-9598
  - 1868-0054
publication_status: published
publisher: Wiley
status: public
title: Organische Chemie
type: journal_article
user_id: '89271'
volume: 68
year: '2020'
...
---
_id: '64896'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>Lichtinduzierte Prozesse effizient
    nutzen – Catenane und neue Kohlenstoffallotrope – komplexe Naturstoffe, einfache
    Wirkstoffe – Enzyme, Proteine und mehr, zusammengestellt von 26 Autoren, koordiniert
    von Jan Paradies.</jats:p>
author:
- first_name: Jennifer N.
  full_name: Andexer, Jennifer N.
  last_name: Andexer
- first_name: Uwe
  full_name: Beifuss, Uwe
  last_name: Beifuss
- first_name: Florian
  full_name: Beuerle, Florian
  last_name: Beuerle
- first_name: Malte
  full_name: Brasholz, Malte
  last_name: Brasholz
- first_name: Rolf
  full_name: Breinbauer, Rolf
  last_name: Breinbauer
- first_name: Martin
  full_name: Ernst, Martin
  last_name: Ernst
- first_name: Julian
  full_name: Greb, Julian
  last_name: Greb
- first_name: Tobias
  full_name: Gulder, Tobias
  last_name: Gulder
- first_name: Wolfgang
  full_name: Hüttel, Wolfgang
  last_name: Hüttel
- first_name: Stephanie
  full_name: Kath‐Schorr, Stephanie
  last_name: Kath‐Schorr
- first_name: Markus
  full_name: Kordes, Markus
  last_name: Kordes
- first_name: Matthias
  full_name: Lehmann, Matthias
  last_name: Lehmann
- first_name: Thomas
  full_name: Lindel, Thomas
  last_name: Lindel
- first_name: Burkhard
  full_name: Luy, Burkhard
  last_name: Luy
- first_name: Christian
  full_name: Mück‐Lichtenfeld, Christian
  last_name: Mück‐Lichtenfeld
- first_name: Claudia
  full_name: Muhle, Claudia
  last_name: Muhle
- first_name: Arun
  full_name: Narine, Arun
  last_name: Narine
- first_name: Jörg
  full_name: Niemeyer, Jörg
  last_name: Niemeyer
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
- first_name: Roland
  full_name: Pfau, Roland
  last_name: Pfau
- first_name: Jörg
  full_name: Pietruszka, Jörg
  last_name: Pietruszka
- first_name: Norbert
  full_name: Schaschke, Norbert
  last_name: Schaschke
- first_name: Mathias
  full_name: Senge, Mathias
  last_name: Senge
- first_name: Bernd F.
  full_name: Straub, Bernd F.
  last_name: Straub
- first_name: Thomas
  full_name: Werner, Thomas
  last_name: Werner
- first_name: Daniel B.
  full_name: Werz, Daniel B.
  last_name: Werz
- first_name: Christian
  full_name: Winter, Christian
  last_name: Winter
citation:
  ama: Andexer JN, Beifuss U, Beuerle F, et al. Organische Chemie. <i>Nachrichten
    aus der Chemie</i>. 2020;68(3):42-72. doi:<a href="https://doi.org/10.1002/nadc.20204095515">10.1002/nadc.20204095515</a>
  apa: Andexer, J. N., Beifuss, U., Beuerle, F., Brasholz, M., Breinbauer, R., Ernst,
    M., Greb, J., Gulder, T., Hüttel, W., Kath‐Schorr, S., Kordes, M., Lehmann, M.,
    Lindel, T., Luy, B., Mück‐Lichtenfeld, C., Muhle, C., Narine, A., Niemeyer, J.,
    Paradies, J., … Winter, C. (2020). Organische Chemie. <i>Nachrichten Aus Der Chemie</i>,
    <i>68</i>(3), 42–72. <a href="https://doi.org/10.1002/nadc.20204095515">https://doi.org/10.1002/nadc.20204095515</a>
  bibtex: '@article{Andexer_Beifuss_Beuerle_Brasholz_Breinbauer_Ernst_Greb_Gulder_Hüttel_Kath‐Schorr_et
    al._2020, title={Organische Chemie}, volume={68}, DOI={<a href="https://doi.org/10.1002/nadc.20204095515">10.1002/nadc.20204095515</a>},
    number={3}, journal={Nachrichten aus der Chemie}, publisher={Wiley}, author={Andexer,
    Jennifer N. and Beifuss, Uwe and Beuerle, Florian and Brasholz, Malte and Breinbauer,
    Rolf and Ernst, Martin and Greb, Julian and Gulder, Tobias and Hüttel, Wolfgang
    and Kath‐Schorr, Stephanie and et al.}, year={2020}, pages={42–72} }'
  chicago: 'Andexer, Jennifer N., Uwe Beifuss, Florian Beuerle, Malte Brasholz, Rolf
    Breinbauer, Martin Ernst, Julian Greb, et al. “Organische Chemie.” <i>Nachrichten
    Aus Der Chemie</i> 68, no. 3 (2020): 42–72. <a href="https://doi.org/10.1002/nadc.20204095515">https://doi.org/10.1002/nadc.20204095515</a>.'
  ieee: 'J. N. Andexer <i>et al.</i>, “Organische Chemie,” <i>Nachrichten aus der
    Chemie</i>, vol. 68, no. 3, pp. 42–72, 2020, doi: <a href="https://doi.org/10.1002/nadc.20204095515">10.1002/nadc.20204095515</a>.'
  mla: Andexer, Jennifer N., et al. “Organische Chemie.” <i>Nachrichten Aus Der Chemie</i>,
    vol. 68, no. 3, Wiley, 2020, pp. 42–72, doi:<a href="https://doi.org/10.1002/nadc.20204095515">10.1002/nadc.20204095515</a>.
  short: J.N. Andexer, U. Beifuss, F. Beuerle, M. Brasholz, R. Breinbauer, M. Ernst,
    J. Greb, T. Gulder, W. Hüttel, S. Kath‐Schorr, M. Kordes, M. Lehmann, T. Lindel,
    B. Luy, C. Mück‐Lichtenfeld, C. Muhle, A. Narine, J. Niemeyer, J. Paradies, R.
    Pfau, J. Pietruszka, N. Schaschke, M. Senge, B.F. Straub, T. Werner, D.B. Werz,
    C. Winter, Nachrichten Aus Der Chemie 68 (2020) 42–72.
date_created: 2026-03-11T10:23:53Z
date_updated: 2026-03-11T10:24:07Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/nadc.20204095515
intvolume: '        68'
issue: '3'
language:
- iso: eng
page: 42-72
publication: Nachrichten aus der Chemie
publication_identifier:
  issn:
  - 1439-9598
  - 1868-0054
publication_status: published
publisher: Wiley
status: public
title: Organische Chemie
type: journal_article
user_id: '53339'
volume: 68
year: '2020'
...
