@article{62819, abstract = {{Novel oxalate-bridged heterotrinuclear complexes [A][Mn2Cr(bpy)2(H2O)2Cl2(C2O4)3] (A = (CH3)2(C2H5)NH+ (1) and (CH3)(C2H5)2NH+ (2); bpy = 2,2′-bipyridine) were synthesized using an aqueous solution of [A]3[Cr(C2O4)3] as a building block in reaction with Mn2+ ions and with the addition of the N-donor ligand bipyridine. The isostructural heterometallic complex salts were characterized by single-crystal and powder X-ray diffraction, infrared and impedance spectroscopy, thermal analysis and magnetization measurements. The trinuclear anion [{Mn(bpy)(H2O)Cl(μ-C2O4)}2Cr(C2O4)]− consists of two [Mn(bpy)(H2O)Cl]+ units bridged by the [Cr(C2O4)3]3− anion, which acts as a bidentate ligand towards each of the manganese atoms. The anions are hydrogen bonded to each other via coordinated chloride anions, water molecules and oxygen oxalate atoms, resulting in two-dimensional (2D) hydrogen bonding layers. Compounds exhibit water-assisted proton conductivity behaviour, which was investigated at different temperatures and relative humidities (RH). At 25 °C, an increase in RH from 60% to 93% resulted in an obvious proton conducting switch from 9.1 × 10−11 to 5.6 × 10−5 S cm−1 for 1 and from 7.4 × 10−10 to 1.8 × 10−6 S cm−1 for 2, corresponding to high on/off ratios of about 106 for 1 and 104 for 2. In situ powder X-ray diffraction (PXRD) analysis showed that unit cell parameters of compounds 1 and 2 slightly increase when exposed to humid conditions. This confirmed that incorporation of water molecules into structures with pores and voids causes the proton conductivity switching phenomenon. Magnetic susceptibility measurements indicate a ferromagnetic interaction between Cr3+ and Mn2+ ions bridged by the bis(bidentate) oxalate group. The prepared compounds 1 and 2 were explored as single-source precursors for the formation of spinel oxide by their thermal treatment. With increasing temperature, the spinel composition changed according to the formula Mn1+xCr2–xO4 (0 ≤ x ≤ 1), where x = 0.7 at 500 °C and x = 1 at 900 °C when tet[MnII]oct[MnIIICrIII]O4 is formed. The (micro)structure, morphology, and optical properties of spinel Mn2CrO4 were characterized by PXRD, scanning electron microscopy and UV-Vis diffuse reflectance spectroscopy. The photocatalytic activity of this oxide in degradation of the methylene blue dye under Vis irradiation without and with the support of hydrogen peroxide was further investigated.}}, author = {{Lozančić, Ana and Burazer, Sanja and Wagner, Tobias and Molčanov, Krešimir and Pajić, Damir and Androš Dubraja, Lidija and Tiemann, Michael and Jurić, Marijana}}, issn = {{2050-7526}}, journal = {{Journal of Materials Chemistry C}}, number = {{41}}, pages = {{21179--21195}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Water-assisted proton conductivity and a magnetic study of heterotrinuclear oxalate-bridged compounds: molecular precursors for the Mn2CrO4 spinel}}}, doi = {{10.1039/d5tc02569a}}, volume = {{13}}, year = {{2025}}, } @article{62816, abstract = {{The increasing demand for advanced sensing technologies drives the development of chemical sensors using innovative materials. In gas sensing, optical sensors are often used to detect gases such as CO, NOx, and O2. Oxygen sensors typically incorporate dyes into oxygen-permeable matrices like polymers, silica, or zeolites. Alternatively, semiconductor surface chemistry can enable O2 detection. However, these approaches are often limited by slow response and recovery times and low selectivity, restricting their practical applications. The metal-organic framework MOF-76(Eu) and its yttrium-modified variant, MOF-76(Eu/Y) are reported to exhibit highly reversible and fast optical responses to varying O2 concentrations. Time-resolved emission measurements are performed over short (seconds) and long (hours) timescales using N2 and synthetic air mixtures. Cross-sensitivity to humidity is analyzed. Multichannel scaling photon-counting experiments confirm quenching at the linker level, as the emission lifetime remains nearly constant. Yttrium significantly improves stability and performance at room temperature. Structural and optical changes induced by yttrium are investigated. Additionally, MIL-78(Eu), another Eu-BTC-based MOF with a different coordination environment, is synthesized. Unlike MOF-76(Eu), MIL-78(Eu) exhibits distinct optical properties but lacks a reversible response to O2. These results highlight the potential of MOF-76-based materials for high-performance O2 sensing.}}, author = {{Zhao, Zhenyu and Weinberger, Christian and Steube, Jakob and Bauer, Matthias and Brehm, Martin and Tiemann, Michael}}, issn = {{1616-301X}}, journal = {{Advanced Functional Materials}}, publisher = {{Wiley}}, title = {{{Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76)}}}, doi = {{10.1002/adfm.202511190}}, year = {{2025}}, } @inproceedings{62818, author = {{Radtke, Sabine}}, editor = {{Belalcazar, Catalina}}, keywords = {{Sports Coaching, Diversity, Intersectionality}}, location = {{Athens}}, number = {{S1}}, pages = {{S4}}, publisher = {{Human Kinetics}}, title = {{{Ethical dilemmas in coaching: Diversity and inclusion and the role of the coach}}}, doi = {{https://doi.org/10.1123/iscj.2025-0112}}, volume = {{12}}, year = {{2025}}, } @inproceedings{60637, author = {{Weiser, David and Ditter, Rebecca and Ditter, David and Siepmann, Karin and Grandrath, Rebecca and Fechner, Sabine and Sommer, Katrin and Bohrmann-Linde, Claudia and Rubner, Isabel}}, booktitle = {{International conference New Perspective on Science Education}}, isbn = {{979-12-80225-83-2}}, location = {{Florence}}, number = {{14}}, publisher = {{Libreriauniversitaria.it}}, title = {{{Innovative teaching with actionbound: Digital pathways in chemistry education - a practical example from ComeNet Chemistry in the ComeMINT Project}}}, year = {{2025}}, } @inbook{61474, author = {{Habig, Sebastian and Großmann, Nadine and Schmid, Andrea M. and van Vorst, Helena and Fechner, Sabine and Wilde, Matthias}}, booktitle = {{Interesse revisited}}, isbn = {{9783658485412}}, publisher = {{Springer Fachmedien Wiesbaden}}, title = {{{Empirische Befunde der Interessenforschung der Fächer Biologie, Chemie und Physik im Primar- und Sekundarbereich seit 2012 – Ein systematisches Review}}}, doi = {{10.1007/978-3-658-48542-9_4}}, year = {{2025}}, } @inbook{61475, author = {{Zöchling, Sarah and Pletschacher, Laura and Maurer, Christian and Berger, Roland and Lindmaier, Kerstin and Fechner, Sabine and Wodzinski, Rita}}, booktitle = {{Interesse revisited}}, isbn = {{9783658485412}}, publisher = {{Springer Fachmedien Wiesbaden}}, title = {{{Interessenförderung im Physik- und Chemieunterricht – Eine Bestandsaufnahme}}}, doi = {{10.1007/978-3-658-48542-9_10}}, year = {{2025}}, } @inproceedings{62007, abstract = {{Ensemble methods are widely employed to improve generalization in machine learning. This has also prompted the adoption of ensemble learning for the knowledge graph embedding (KGE) models in performing link prediction. Typical approaches to this end train multiple models as part of the ensemble, and the diverse predictions are then averaged. However, this approach has some significant drawbacks. For instance, the computational overhead of training multiple models increases latency and memory overhead. In contrast, model merging approaches offer a promising alternative that does not require training multiple models. In this work, we introduce model merging, specifically weighted averaging, in KGE models. Herein, a running average of model parameters from a training epoch onward is maintained and used for predictions. To address this, we additionally propose an approach that selectively updates the running average of the ensemble model parameters only when the generalization performance improves on a validation dataset. We evaluate these two different weighted averaging approaches on link prediction tasks, comparing the state-of-the-art benchmark ensemble approach. Additionally, we evaluate the weighted averaging approach considering literal-augmented KGE models and multi-hop query answering tasks as well. The results demonstrate that the proposed weighted averaging approach consistently improves performance across diverse evaluation settings.}}, author = {{Sapkota, Rupesh and Demir, Caglar and Sharma, Arnab and Ngonga Ngomo, Axel-Cyrille}}, booktitle = {{Proceedings of the Thirteenth International Conference on Knowledge Capture(K-CAP 2025)}}, keywords = {{Knowledge Graphs, Embeddings, Ensemble Learning}}, location = {{Dayton, OH, USA}}, publisher = {{ACM}}, title = {{{Parameter Averaging in Link Prediction}}}, doi = {{https://doi.org/10.1145/3731443.3771365}}, year = {{2025}}, } @inbook{48069, author = {{Göddertz, Nina}}, booktitle = {{Soziale Frauenberufe in Ost und West}}, editor = {{Bock, Karin and Braches-Chyrek, Rita and Spanu, Stephanie}}, pages = {{144--162 }}, publisher = {{Wochenschau-Verlag}}, title = {{{Kindermädchen – Von ‚strebsamen Mädchen‘, fliegenden Regenschirmen und neuen Gewändern eines (nicht) ausgestorbenen Berufes}}}, year = {{2025}}, } @inbook{48066, author = {{Göddertz, Nina}}, booktitle = {{Soziale Frauenberufe in Ost und West}}, editor = {{Bock, Karin and Braches-Chyrek , Rita and Spanu, Stephanie }}, pages = {{106--127 }}, publisher = {{Wochenschau-Verlag}}, title = {{{Dienstmädchen – von romantisierten Zuschreibungen und menschenunwürdigen Arbeits- und Lebensbedingungen, damals wie heute.}}}, year = {{2025}}, } @article{62867, abstract = {{ABSTRACT Effective manipulation of photonic spin–orbit coupling (SOC) in microcavities is of fundamental importance within topological photonics and applications. Anisotropic organic single‐crystalline materials can induce abundant SOC phenomenon due to their flexible tunability of molecular geometries, however, the intrinsic relationship between molecular geometries/orientations in 3D space and photonic SOC is lacking. In this study, we design two kinds of 2D organic polymorphs for the construction of organic microcavities to investigate the structure‐performance relationships. In two polymorphic microcavities, two distinctive photonic SOC phenomena are observed regardless of the in‐plane anisotropy of organic polymorphs. Theoretical analysis indicates that the photonic SOC strength is strongly influenced by the synergies between the crystal anisotropy and the tilted collective molecular transition dipole moment. Our results uncover the correlation mechanism between the structure of molecules and photonic SOC and open an avenue to engineer complex photonic SOC by use of organic microstructures towards the development of diverse integrated photonic devices.}}, author = {{Ji, Ying and Ma, Xuekai and Huang, Han and Deng, Yibo and Wang, Pingyang and Long, Teng and Li, Yuan and Zhao, Ruiyang and Li, Yunfei and An, Cunbin and Schumacher, Stefan and Gu, Chunling and Liao, Bo and Fu, Hongbing and Liao, Qing}}, issn = {{1863-8880}}, journal = {{Laser & Photonics Reviews}}, publisher = {{Wiley}}, title = {{{Molecular Orientation‐Dependent Photonic Spin–Orbit Coupling in Organic Microcavities Filled with 2D Polymorphic Crystals}}}, doi = {{10.1002/lpor.202501874}}, year = {{2025}}, } @article{62862, abstract = {{Exciton polariton condensates are macroscopic coherent states in which topological excitations can be observed. In this work, we observe the excitation of the vortices and realize tuning the topological charge by manipulating the pumping configurations. Using a digital micromirror device, we constructed an annular pumping pattern where the inner and outer rings can be easily tuned. Both the number and the topological charge of the vortices can be changed by slightly tuning the inner ring position against the outer ring. The experimental results can be reproduced in theory by the Gross–Pitaevskii equation. Our work offers to generate and manipulate vortices in exciton polariton condensates using a straightforward optical method.}}, author = {{Ai, Qiang and Ma, Xuekai and Barkhausen, Franziska and Zhai, Xiaokun and Xing, Chunzi and Yang, Xinmiao and Wang, Peilin and Liu, Tianyu and Zhang, Yong and Gu, Yazhou and Li, Peigang and Li, Zhitong and Hatzopoulos, Zacharias and Savvidis, Pavlos G. and Schumacher, Stefan and Gao, Tingge}}, issn = {{0003-6951}}, journal = {{Applied Physics Letters}}, number = {{12}}, publisher = {{AIP Publishing}}, title = {{{Tuning polariton vortices in an asymmetric ring potential}}}, doi = {{10.1063/5.0287076}}, volume = {{127}}, year = {{2025}}, } @article{62865, author = {{Sun, Jinming and Chen, Manna and Schumacher, Stefan and Hu, Wei and Ma, Xuekai}}, issn = {{2469-9950}}, journal = {{Physical Review B}}, number = {{11}}, publisher = {{American Physical Society (APS)}}, title = {{{Higher-order dark solitons and control dynamics in microcavity polariton condensates}}}, doi = {{10.1103/p357-vyq8}}, volume = {{112}}, year = {{2025}}, } @article{62876, abstract = {{ABSTRACT Spin‐coated polylactide (PLA) thin films were exposed to nitrogen plasma for varying time intervals. The progressive etching of the PLA film in direct contact with the nitrogen plasma was monitored in situ using polarization modulated infrared reflection absorption spectroscopy (PM‐IRRAS). No appreciative changes in composition were seen with PM‐IRRAS, indicating that the etching did not significantly affect the bulk composition. Atomic force microscopy characterization of the plasma‐etched films showed that the PLA films are homogeneously etched. Subsequent ex situ XPS analysis of the treated surface revealed the presence of C‐N bonds in the surface‐near region that could be associated with amino and/or amide surface species. PLA films were also alternatively exposed to nitrogen ion beams produced by an electron‐cyclotron‐resonance (ECR) plasma source and were investigated in vacuo by XPS. This treatment revealed the partial substitution of surface oxygen species by nitrogen, resulting in a similar surface modification as in the plasma case. The comparison of XPS data and water contact angle studies suggest that the activated surfaces show a reorientation of macromolecular fragments in the surface‐near region depending on the polarity of the phase with which they are in contact. Under ultra‐high vacuum (UHV) conditions, the surface tends to lower its surface energy, while in contact with the aqueous phase, subsurface polar groups orientate outwards, which enables the formation of hydrogen bonds.}}, author = {{Gołębiowska, Sandra and Voigt, Markus and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido}}, issn = {{0142-2421}}, journal = {{Surface and Interface Analysis}}, number = {{7}}, pages = {{499--509}}, publisher = {{Wiley}}, title = {{{In Situ PM‐IRRAS and XPS Analysis of Nitrogen Plasma Surface Modification of Polylactide Thin Films}}}, doi = {{10.1002/sia.7406}}, volume = {{57}}, year = {{2025}}, } @article{62871, author = {{Wehde, Janis}}, issn = {{2190-6890}}, journal = {{Zeitschrift für Bildungsforschung}}, publisher = {{Springer}}, title = {{{Selbstwirksamkeitserwartungen zur methodischen Gestaltung eines gemeinschaftsorientierten und partizipativ-verfahrensorientierten Unterrichts: Entwicklung von Kurzskalen zur schulischen Demokratiebildung}}}, doi = {{10.1007/s35834-025-00522-4}}, year = {{2025}}, } @article{62875, author = {{Theile-Rasche, Chantal and Wang, Fuzeng and Prüßner, Tim and Huck, Marten and Steinrück, Hans-Georg and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido}}, issn = {{0040-6090}}, journal = {{Thin Solid Films}}, publisher = {{Elsevier BV}}, title = {{{Evaluation of anti-adhesive and corrosion protection properties of TiAlSiN-magnetron-sputtered films for applications in polymer processing}}}, doi = {{10.1016/j.tsf.2025.140676}}, volume = {{820}}, year = {{2025}}, } @article{62874, abstract = {{DNA origami adsorption at single-crystalline TiO2 surfaces is investigated at different Mg2+ concentrations. For TiO2(001), DNA origami adsorption is stronger at 5 mM than at 10 mM Mg2+, whereas the opposite is observed for TiO2(110) and TiO2(111).}}, author = {{Xu, Xiaodan and Gołębiowska, Sandra and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido and Keller, Adrian}}, issn = {{2755-3701}}, journal = {{RSC Applied Interfaces}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{DNA origami adsorption at single-crystalline TiO2 surfaces}}}, doi = {{10.1039/d5lf00109a}}, year = {{2025}}, } @article{62860, abstract = {{ The Quantum Internet, a network of quantum-enabled infrastructure, represents the next frontier in telecommunications, promising capabilities that cannot be attained by classical counterparts. A crucial step in realizing such large-scale quantum networks is the integration of entanglement distribution within existing telecommunication infrastructure. Here, we demonstrate a real-world scalable quantum networking testbed deployed within Deutsche Telekom’s metropolitan fibers in Berlin. Using commercially available quantum devices and standard add-drop multiplexing hardware, we distributed polarization-entangled photon pairs over dynamically selectable looped fiber paths ranging from 10 m to 60 km and showed entanglement distribution over up to approximately 100 km. Quantum signals, transmitted at 1324 nm (O-band), coexist with conventional bidirectional C-band traffic without dedicated fibers or infrastructure changes. Active stabilization of the polarization enables robust long-term performance, achieving entanglement Bell-state fidelity bounds between 85% and 99% and Clauser–Horne–Shimony–Holt parameter S -values between 2.36 and 2.74 during continuous multiday operation. By achieving a high-fidelity entanglement distribution with less than 1.5% downtime, we confirm the feasibility of hybrid quantum-classical networks under real-world conditions at the metropolitan scale. These results establish deployment benchmarks and provide a practical roadmap for telecom operators to integrate quantum capabilities. }}, author = {{Sena, Matheus and Flament, Mael and Andrewski, Shane and Caltzidis, Ioannis and Bigagli, Niccolò and Rieser, Thomas and Bello Portmann, Gabriel and Sekelsky, Rourke and Braun, Ralf-Peter and Craddock, Alexander N. and Schulz, Maximilian and Jöns, Klaus and Ritter, Michaela and Geitz, Marc and Holschke, Oliver and Namazi, Mehdi}}, issn = {{1943-0620}}, journal = {{Journal of Optical Communications and Networking}}, number = {{12}}, publisher = {{Optica Publishing Group}}, title = {{{High-fidelity quantum entanglement distribution in metropolitan fiber networks with co-propagating classical traffic}}}, doi = {{10.1364/jocn.575396}}, volume = {{17}}, year = {{2025}}, } @article{62900, author = {{Hjorth, Therese and Schadow, Alena Marie and Revheim, Ingrid and Spielau, Ulrike and Meyer, Klara and Rieder, Anne and Varela, Paula and Ballance, Simon and Koerner, Antje and Landberg, Rikard and Buyken, Anette and Dierkes, Jutta and Rosendahl-Riise, Hanne}}, issn = {{0002-9165}}, journal = {{The American Journal of Clinical Nutrition}}, number = {{3}}, pages = {{724--732}}, publisher = {{Elsevier BV}}, title = {{{Effectiveness of regular oat β-glucan–enriched bread compared with whole-grain wheat bread on long-term glycemic control in adults at risk of type 2 diabetes: a randomized controlled trial}}}, doi = {{10.1016/j.ajcnut.2025.06.018}}, volume = {{122}}, year = {{2025}}, } @article{62912, abstract = {{We investigate the dynamics of wave packets in a parabolic optical lattice formed by combining an optical lattice with a global parabolic trap. Our study examines the phase space representation of the system's eigenstates by comparing them to the classical phase space of a pendulum, to which the system effectively maps. The analysis reveals that quantum states can exhibit mixed dynamics by straddling the separatrix. A key finding is that the dynamics around the separatrix enables the controlled creation of highly nonclassical states, distinguishing them from the classical oscillatory or rotational dynamics of the pendulum. By considering a finite momentum of the initial wave packet, we demonstrate various dynamical regimes. Furthermore, a slight energy mismatch between nearly degenerate states localized at opposite turning points of the trap potential results in controlled long-range dynamical tunneling. These results can be interpreted as quantum beating between a clockwise rotating and a counterclockwise rotating pendulum.}}, author = {{Ali, Usman and Holthaus, Martin and Meier, Torsten}}, issn = {{2643-1564}}, journal = {{Physical Review Research}}, number = {{1}}, publisher = {{American Physical Society (APS)}}, title = {{{Wave packet dynamics in parabolic optical lattices: From Bloch oscillations to long-range dynamical tunneling}}}, doi = {{10.1103/physrevresearch.7.013141}}, volume = {{7}}, year = {{2025}}, } @article{62911, abstract = {{In this paper, we theoretically study the spectral and temporal properties of pulsed spontaneous parametric down-conversion (SPDC) generated in lossy waveguides. Our theoretical approach is based on the formalism of Gaussian states and the Langevin equation, which is elaborated for weak parametric down-conversion and photon-number-unresolved click detection. Using the example of frequency-degenerate type-II SPDC generated under the pump-idler group-velocity-matching condition, we show how the joint-spectral intensity, mode structure, normalized second-order correlation function, and Hong-Ou-Mandel interference pattern depend on internal losses of the SPDC process. We found that the joint-spectral intensity is almost insensitive to internal losses, while the second-order correlation function shows a strong dependence on them, being different for the signal and idler beams in the presence of internal losses. Based on the sensitivity of the normalized second-order correlation function, we show how its measurement can be used to experimentally determine internal losses.}}, author = {{Kopylov, Denis A. and Stefszky, Michael and Meier, Torsten and Silberhorn, Christine and Sharapova, Polina R.}}, issn = {{2643-1564}}, journal = {{Physical Review Research}}, number = {{3}}, publisher = {{American Physical Society (APS)}}, title = {{{Spectral and temporal properties of type-II parametric down-conversion: The impact of losses during state generation}}}, doi = {{10.1103/zp72-7qwl}}, volume = {{7}}, year = {{2025}}, }