@article{23618, author = {{Steinrück, Hans-Georg and Cao, Chuntian and Veith, Gabriel M. and Toney, Michael F.}}, issn = {{0021-9606}}, journal = {{The Journal of Chemical Physics}}, pages = {{084702}}, title = {{{Toward quantifying capacity losses due to solid electrolyte interphase evolution in silicon thin film batteries}}}, doi = {{10.1063/1.5142643}}, volume = {{152}}, year = {{2020}}, } @article{23619, author = {{Beal, Rachel E. and Hagström, Nanna Zhou and Barrier, Julien and Gold-Parker, Aryeh and Prasanna, Rohit and Bush, Kevin A. and Passarello, Donata and Schelhas, Laura T. and Brüning, Karsten and Tassone, Christopher J. and Steinrück, Hans-Georg and McGehee, Michael D. and Toney, Michael F. and Nogueira, Ana Flávia}}, issn = {{2590-2385}}, journal = {{Matter}}, pages = {{207--219}}, title = {{{Structural Origins of Light-Induced Phase Segregation in Organic-Inorganic Halide Perovskite Photovoltaic Materials}}}, doi = {{10.1016/j.matt.2019.11.001}}, volume = {{2}}, year = {{2019}}, } @article{23620, author = {{Cao, Chuntian and Shyam, Badri and Wang, Jiajun and Toney, Michael F. and Steinrück, Hans-Georg}}, issn = {{0001-4842}}, journal = {{Accounts of Chemical Research}}, pages = {{2673--2683}}, title = {{{Shedding X-ray Light on the Interfacial Electrochemistry of Silicon Anodes for Li-Ion Batteries}}}, doi = {{10.1021/acs.accounts.9b00233}}, volume = {{52}}, year = {{2019}}, } @article{23621, author = {{Huang, Tzu-Yen and Larrain, Felipe A. and Borca, Carlos H. and Fuentes-Hernandez, Canek and Yan, Hongping and Schneider, Sebastian Alexander and Chou, Wen-Fang and Rodriguez-Toro, Victor A. and Steinrück, Hans-Georg and Cao, Chuntian and Sherrill, C. David and Kippelen, Bernard and Toney, Michael F.}}, issn = {{0897-4756}}, journal = {{Chemistry of Materials}}, pages = {{6677--6683}}, title = {{{Morphology of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid}}}, doi = {{10.1021/acs.chemmater.9b01069}}, volume = {{31}}, year = {{2019}}, } @article{23622, author = {{Cao, Chuntian and Abate, Iwnetim Iwnetu and Sivonxay, Eric and Shyam, Badri and Jia, Chunjing and Moritz, Brian and Devereaux, Thomas P. and Persson, Kristin A. and Steinrück, Hans-Georg and Toney, Michael F.}}, issn = {{2542-4351}}, journal = {{Joule}}, pages = {{762--781}}, title = {{{Solid Electrolyte Interphase on Native Oxide-Terminated Silicon Anodes for Li-Ion Batteries}}}, doi = {{10.1016/j.joule.2018.12.013}}, volume = {{3}}, year = {{2019}}, } @article{23623, author = {{Chen, Lin and Chen, Kan-Sheng and Chen, Xinjie and Ramirez, Giovanni and Huang, Zhennan and Geise, Natalie R. and Steinrück, Hans-Georg and Fisher, Brandon L. and Shahbazian-Yassar, Reza and Toney, Michael F. and Hersam, Mark C. and Elam, Jeffrey W.}}, issn = {{1944-8244}}, journal = {{ACS Applied Materials & Interfaces}}, pages = {{26972--26981}}, title = {{{Novel ALD Chemistry Enabled Low-Temperature Synthesis of Lithium Fluoride Coatings for Durable Lithium Anodes}}}, doi = {{10.1021/acsami.8b04573}}, volume = {{20}}, year = {{2018}}, } @article{23624, author = {{Horowitz, Yonatan and Steinrück, Hans-Georg and Han, Hui-Ling and Cao, Chuntian and Abate, Iwnetim Iwnetu and Tsao, Yuchi and Toney, Michael F. and Somorjai, Gabor A.}}, issn = {{1530-6984}}, journal = {{Nano Letters}}, pages = {{2105--2111}}, title = {{{Fluoroethylene Carbonate Induces Ordered Electrolyte Interface on Silicon and Sapphire Surfaces as Revealed by Sum Frequency Generation Vibrational Spectroscopy and X-ray Reflectivity}}}, doi = {{10.1021/acs.nanolett.8b00298}}, volume = {{18}}, year = {{2018}}, } @article{23625, abstract = {{

Combined experimental and theoretical insights into electrolyte–electrode interfaces relevant to lithium ion batteries.

}}, author = {{Steinrück, Hans-Georg and Cao, Chuntian and Tsao, Yuchi and Takacs, Christopher J. and Konovalov, Oleg and Vatamanu, Jenel and Borodin, Oleg and Toney, Michael F.}}, issn = {{1754-5692}}, journal = {{Energy & Environmental Science}}, pages = {{594--602}}, title = {{{The nanoscale structure of the electrolyte–metal oxide interface}}}, doi = {{10.1039/c7ee02724a}}, volume = {{11}}, year = {{2018}}, } @article{23626, abstract = {{Interfaces of room temperature ionic liquids (RTILs) are important for both applications and basic science and are therefore intensely studied. However, the evolution of their interface structure with the cation’s alkyl chain length n from Coulomb to van der Waals interaction domination has not yet been studied for even a single broad homologous RTIL series. We present here such a study of the liquid–air interface for n=2to 22, using angstrom-resolution X-ray methods. For n<6, a typical “simple liquid” monotonic surface-normal electron density profile ρe(z) is obtained, like those of water and organic solvents. For n>6, increasingly more pronounced nanoscale self-segregation of the molecules’ charged moieties and apolar chains yields surface layering with alternating regions of headgroups and chains. The layering decays into the bulk over a few, to a few tens, of nanometers. The layering periods and decay lengths, their linear n dependence, and slopes are discussed within two models, one with partial-chain interdigitation and the other with liquid-like chains. No surface-parallel long-range order is found within the surface layer. For n=22, a different surface phase is observed above melting. Our results also impact general liquid-phase issues like supramolecular self-aggregation and bulk–surface structure relations.}}, author = {{Haddad, Julia and Pontoni, Diego and Murphy, Bridget M. and Festersen, Sven and Runge, Benjamin and Magnussen, Olaf M. and Steinrück, Hans-Georg and Reichert, Harald and Ocko, Benjamin M. and Deutsch, Moshe}}, issn = {{0027-8424}}, journal = {{Proceedings of the National Academy of Sciences}}, pages = {{E1100--E1107}}, title = {{{Surface structure evolution in a homologous series of ionic liquids}}}, doi = {{10.1073/pnas.1716418115}}, volume = {{115}}, year = {{2018}}, } @article{23627, author = {{Schmaltz, Thomas and Gothe, Bastian and Krause, Andreas and Leitherer, Susanne and Steinrück, Hans-Georg and Thoss, Michael and Clark, Timothy and Halik, Marcus}}, issn = {{1936-0851}}, journal = {{ACS Nano}}, pages = {{8747--8757}}, title = {{{Effect of Structure and Disorder on the Charge Transport in Defined Self-Assembled Monolayers of Organic Semiconductors}}}, doi = {{10.1021/acsnano.7b02394}}, volume = {{11}}, year = {{2017}}, } @article{23628, author = {{Cao, Chuntian and Steinrück, Hans-Georg and Shyam, Badri and Toney, Michael F.}}, issn = {{2196-7350}}, journal = {{Advanced Materials Interfaces}}, pages = {{1700771}}, title = {{{The Atomic Scale Electrochemical Lithiation and Delithiation Process of Silicon}}}, doi = {{10.1002/admi.201700771}}, volume = {{4}}, year = {{2017}}, } @article{23629, author = {{Kirschner, Johannes and Will, Johannes and Rejek, Tobias J. and Portilla, Luis and Berlinghof, Marvin and Schweizer, Peter and Spiecker, Erdmann and Steinrück, Hans-Georg and Unruh, Tobias and Halik, Marcus}}, issn = {{2196-7350}}, journal = {{Advanced Materials Interfaces}}, pages = {{1700230}}, title = {{{Memory Effect of Self-Assembled PS-b-PEO Block Copolymer Films with Selectively Embedded Functionalized TiO2 Nanoparticles}}}, doi = {{10.1002/admi.201700230}}, volume = {{4}}, year = {{2017}}, } @article{23630, author = {{Liu, Ning and Steinrück, Hans-Georg and Osvet, Andres and Yang, Yuyun and Schmuki, Patrik}}, issn = {{0003-6951}}, journal = {{Applied Physics Letters}}, pages = {{072102}}, title = {{{Noble metal free photocatalytic H2 generation on black TiO2: On the influence of crystal facets vs. crystal damage}}}, doi = {{10.1063/1.4976010}}, volume = {{110}}, year = {{2017}}, } @article{23631, author = {{Fukuto, M. and Ocko, B. M. and Bonthuis, D. J. and Netz, R. R. and Steinrück, Hans-Georg and Pontoni, D. and Kuzmenko, I. and Haddad, J. and Deutsch, M.}}, issn = {{0031-9007}}, journal = {{Physical Review Letters}}, pages = {{256102}}, title = {{{Nanoscale Structure of the Oil-Water Interface}}}, doi = {{10.1103/physrevlett.117.256102}}, volume = {{117}}, year = {{2016}}, } @article{23632, author = {{Cao, Chuntian and Steinrück, Hans-Georg and Shyam, Badri and Stone, Kevin H. and Toney, Michael F.}}, issn = {{1530-6984}}, journal = {{Nano Letters}}, pages = {{7394--7401}}, title = {{{In Situ Study of Silicon Electrode Lithiation with X-ray Reflectivity}}}, doi = {{10.1021/acs.nanolett.6b02926}}, volume = {{16}}, year = {{2016}}, } @article{23633, author = {{Steinrück, Hans-Georg and Will, J. and Magerl, A. and Ocko, B. M.}}, issn = {{0743-7463}}, journal = {{Langmuir}}, pages = {{11774--11780}}, title = {{{Structure of n-Alkyltrichlorosilane Monolayers on Si(100)/SiO2}}}, doi = {{10.1021/acs.langmuir.5b03091}}, volume = {{31}}, year = {{2015}}, } @article{23634, author = {{Haddad, Julia and Steinrück, Hans-Georg and Hlaing, Htay and Kewalramani, Sumit and Pontoni, Diego and Reichert, Harald and Murphy, Bridget M. and Festersen, Sven and Runge, Benjamin and Magnussen, Olaf M. and Magerl, Andreas and Deutsch, Moshe and Ocko, Benjamin M.}}, issn = {{1932-7447}}, journal = {{The Journal of Physical Chemistry C}}, pages = {{17648--17654}}, title = {{{Order and Melting in Self-Assembled Alkanol Monolayers on Amorphous SiO2}}}, doi = {{10.1021/acs.jpcc.5b03554}}, volume = {{119}}, year = {{2015}}, } @article{23635, author = {{Khassanov, Artoem and Steinrück, Hans-Georg and Schmaltz, Thomas and Magerl, Andreas and Halik, Marcus}}, issn = {{0001-4842}}, journal = {{Accounts of Chemical Research}}, pages = {{1901--1908}}, title = {{{Structural Investigations of Self-Assembled Monolayers for Organic Electronics: Results from X-ray Reflectivity}}}, doi = {{10.1021/acs.accounts.5b00022}}, volume = {{48}}, year = {{2015}}, } @article{23636, author = {{Schiener, A. and Magerl, A. and Krach, A. and Seifert, S. and Steinrück, Hans-Georg and Zagorac, J. and Zahn, D. and Weihrich, R.}}, issn = {{2040-3364}}, journal = {{Nanoscale}}, pages = {{11328--11333}}, title = {{{In situ investigation of two-step nucleation and growth of CdS nanoparticles from solution}}}, doi = {{10.1039/c5nr01602a}}, volume = {{7}}, year = {{2015}}, } @article{23637, author = {{Steinrück, Hans-Georg and Schiener, Andreas and Schindler, Torben and Will, Johannes and Magerl, Andreas and Konovalov, Oleg and Li Destri, Giovanni and Seeck, Oliver H. and Mezger, Markus and Haddad, Julia and Deutsch, Moshe and Checco, Antonio and Ocko, Benjamin M.}}, issn = {{1936-0851}}, journal = {{ACS Nano}}, pages = {{12676--12681}}, title = {{{Nanoscale Structure of Si/SiO2/Organics Interfaces}}}, doi = {{10.1021/nn5056223}}, volume = {{8}}, year = {{2014}}, }