@article{63532,
abstract = {{Room-temperature lasing is a key milestone in the development of miniaturized optoelectronic and photonic devices. We present a simple approach to synthesize phase-pure quasi-2D layered tin perovskite nanowires with varying quantum well thicknesses (n = 1 to 4). By incorporating a new organic spacer capable of forming a hydrogen-bonded organic framework, this method promoted anisotropic crystal growth and enhanced lattice rigidity. Furthermore, introducing molecular intercalants enabled controlled crystallization into well-defined nanowires that function as Fabry–Pérot cavities. Cavities made from n = 2 to 4 perovskites support efficient and robust near-infrared, room-temperature optically pumped lasing with the threshold as low as 75.8 μJ/cm2, cavity quality factor over 3000, and negligible degradation over 106 pulses. A cleaved coupled nanolaser was fabricated as a proof-of-concept device for photonic applications.}},
author = {{Kim, Jeong Hui and Simon, Jeffrey and Shao, Wenhao and Nian, Zhichen and Yang, Hanjun and Chen, Peigang and Triplett, Brandon and Li, Zhixu and Wu, Pengfei and Chen, Yuheng and Farheen, Henna and Pagadala, Karthik and Choi, Kyu Ri and Fruhling, Colton B. and Förstner, Jens and Boltasseva, Alexandra and Savoie, Brett M. and Shalaev, Vladimir M. and Dou, Letian}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{tet_topic_opticalantenna}},
pages = {{jacs.5c14431}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Hydrogen-Bonded Organic Framework Enables Phase-Pure Layered Tin Perovskite Nanowires for Room-Temperature Lasing}}},
doi = {{10.1021/jacs.5c14431}},
year = {{2026}},
}
@article{59906,
abstract = {{The cationic molybdenum alkylidyne N-heterocyclic carbene (NHC) complex [Mo(C-p-OMeC6H4)(OCMe(CF3)2)2 (IMes)][B(ArF4] (IMes = 1,3-dimesitylimidazol-2-ylidene) was selectively immobilized inside the pores of ordered mesoporous silica (OMS) with pore diameters of 66, 56, and 28 Å and used in the ring-expansion metathesis polymerization (REMP) of cyclic olefins to yield cyclic polymers. A strong confinement effect was observed for cis-cyclooctene (cCOE), 1,5-cyclooctadiene (COD), (+)-2,3-endo,exo-dicarbomethoxynorborn-5-ene ((+)-DCMNBE), and 2-methyl-2-phenylcycloprop-1-ene (MPCP), allowing for the synthesis of low-molecular-weight cyclic polymers even at a high monomer concentration. The exclusive formation of cyclic polymers was demonstrated by matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) mass spectrometry. Confinement also influences stereoselectivity, resulting in a pronounced increase in Z-selectivity and in an increased cis-syndiospecificity.}},
author = {{Probst, Patrick and Lindemann, Moritz and Bruckner, Johanna R. and Atwi, Boshra and Wang, Dongren and Fischer, Felix Richard and Högler, Marc and Bauer, Matthias and Hansen, Niels and Dyballa, Michael and Buchmeiser, Michael R.}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
number = {{10}},
pages = {{8741--8750}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Ring-Expansion Metathesis Polymerization under Confinement}}},
doi = {{10.1021/jacs.4c18171}},
volume = {{147}},
year = {{2025}},
}
@article{61336,
author = {{Zhou, Rundong and Medvaric, Viktorija and Werner, Thomas and Paradies, Jan}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{T2, CSSD}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Metal-Free Reduction of Nitrous Oxide via PIII/PV═O Cycling: Mechanistic Insights and Catalytic Performance}}},
doi = {{10.1021/jacs.5c06190}},
year = {{2025}},
}
@article{61261,
author = {{Liang, Qian and Ma, Xuekai and Gu, Chunling and Ren, Jiahuan and An, Cunbin and Fu, Hongbing and Schumacher, Stefan and Liao, Qing}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
number = {{7}},
pages = {{4542--4548}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Photochemical Reaction Enabling the Engineering of Photonic Spin–Orbit Coupling in Organic-Crystal Optical Microcavities}}},
doi = {{10.1021/jacs.3c11373}},
volume = {{146}},
year = {{2024}},
}
@article{54866,
author = {{Diederich, Jonathan and Velasquez Rojas, Jennifer and Zare Pour, Mohammad Amin and Ruiz Alvarado, Isaac Azahel and Paszuk, Agnieszka and Sciotto, Rachele and Höhn, Christian and Schwarzburg, Klaus and Ostheimer, David and Eichberger, Rainer and Schmidt, Wolf Gero and Hannappel, Thomas and van de Krol, Roel and Friedrich, Dennis}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
number = {{13}},
pages = {{8949--8960}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Unraveling Electron Dynamics in p-type Indium Phosphide (100): A Time-Resolved Two-Photon Photoemission Study}}},
doi = {{10.1021/jacs.3c12487}},
volume = {{146}},
year = {{2024}},
}
@article{36416,
author = {{De, Jianbo and Ma, Xuekai and Yin, Fan and Ren, Jiahuan and Yao, Jiannian and Schumacher, Stefan and Liao, Qing and Fu, Hongbing and Malpuech, Guillaume and Solnyshkov, Dmitry}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society (JACS)}},
keywords = {{Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis}},
number = {{3}},
pages = {{1557--1563}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates}}},
doi = {{10.1021/jacs.2c07557}},
volume = {{145}},
year = {{2023}},
}
@article{21240,
abstract = {{Rechargeable aqueous Zn-ion energy storage devices are promising candidates for next-generation energy storage technologies. However, the lack of highly reversible Zn2+-storage anode materials with low potential windows remains a primary concern. Here, we report a two-dimensional polyarylimide covalent organic framework (PI-COF) anode with high-kinetics Zn2+-storage capability. The well-organized pore channels of PI-COF allow the high accessibility of the build-in redox-active carbonyl groups and efficient ion diffusion with a low energy barrier. The constructed PI-COF anode exhibits a specific capacity (332 C g–1 or 92 mAh g–1 at 0.7 A g–1), a high rate capability (79.8% at 7 A g–1), and a long cycle life (85% over 4000 cycles). In situ Raman investigation and first-principle calculations clarify the two-step Zn2+-storage mechanism, in which imide carbonyl groups reversibly form negatively charged enolates. Dendrite-free full Zn-ion devices are fabricated by coupling PI-COF anodes with MnO2 cathodes, delivering excellent energy densities (23.9 ∼ 66.5 Wh kg–1) and supercapacitor-level power densities (133 ∼ 4782 W kg–1). This study demonstrates the feasibility of covalent organic framework as Zn2+-storage anodes and shows a promising prospect for constructing reliable aqueous energy storage devices.}},
author = {{Yu, Minghao and Chandrasekhar, Naisa and Kormath Madam Raghupathy, Ramya and Ly, Khoa Hoang and Zhang, Haozhe and Dmitrieva, Evgenia and Liang, Chaolun and Lu, Xihong and Kühne, Thomas and Mirhosseini, S. Hossein and Weidinger, Inez M. and Feng, Xinliang}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
number = {{46}},
pages = {{19570--19578}},
publisher = {{American Chemical Society}},
title = {{{A High-Rate Two-Dimensional Polyarylimide Covalent Organic Framework Anode for Aqueous Zn-Ion Energy Storage Devices}}},
doi = {{10.1021/jacs.0c07992}},
volume = {{142}},
year = {{2020}},
}
@article{40584,
author = {{Castillo-Blas, Celia and Lopez Salas, Nieves and Gutiérrez, María C. and Puente-Orench, Inés and Gutiérrez-Puebla, Enrique and Ferrer, M. Luisa and Monge, M. Ángeles and Gándara, Felipe}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis}},
number = {{4}},
pages = {{1766--1774}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides}}},
doi = {{10.1021/jacs.8b12860}},
volume = {{141}},
year = {{2019}},
}
@article{22239,
author = {{Sitte, Nikolai A. and Bursch, Markus and Grimme, Stefan and Paradies, Jan}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
pages = {{159--162}},
title = {{{Frustrated Lewis Pair Catalyzed Hydrogenation of Amides: Halides as Active Lewis Base in the Metal-Free Hydrogen Activation}}},
doi = {{10.1021/jacs.8b12997}},
year = {{2018}},
}
@article{16954,
author = {{Hanske, Jonas and Aleksić, Stevan and Ballaschk, Martin and Jurk, Marcel and Shanina, Elena and Beerbaum, Monika and Schmieder, Peter and Keller, Bettina G. and Rademacher, Christoph}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{pc2-ressources}},
pages = {{12176--12186}},
title = {{{Intradomain Allosteric Network Modulates Calcium Affinity of the C-Type Lectin Receptor Langerin}}},
doi = {{10.1021/jacs.6b05458}},
year = {{2016}},
}
@article{15867,
author = {{Tautz, Raphael and Da Como, Enrico and Wiebeler, Christian and Soavi, Giancarlo and Dumsch, Ines and Fröhlich, Nils and Grancini, Giulia and Allard, Sybille and Scherf, Ullrich and Cerullo, Giulio and Schumacher, Stefan and Feldmann, Jochen}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
pages = {{4282--4290}},
title = {{{Charge Photogeneration in Donor–Acceptor Conjugated Materials: Influence of Excess Excitation Energy and Chain Length}}},
doi = {{10.1021/ja309252a}},
year = {{2013}},
}
@article{41256,
author = {{Eitel, Simon H. and Bauer, Matthias and Schweinfurth, David and Deibel, Naina and Sarkar, Biprajit and Kelm, Harald and Krüger, Hans-Jörg and Frey, Wolfgang and Peters, René}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis}},
number = {{10}},
pages = {{4683--4693}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Paramagnetic Palladacycles with PdIIICenters Are Highly Active Catalysts for Asymmetric Aza-Claisen Rearrangements}}},
doi = {{10.1021/ja2098222}},
volume = {{134}},
year = {{2012}},
}
@article{13542,
author = {{Thissen, Peter and Peixoto, Tatiana and Longo, Roberto C. and Peng, Weina and Schmidt, Wolf Gero and Cho, Kyeongjae and Chabal, Yves J.}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
pages = {{8869--8874}},
title = {{{Activation of Surface Hydroxyl Groups by Modification of H-Terminated Si(111) Surfaces}}},
doi = {{10.1021/ja300270w}},
volume = {{134}},
year = {{2012}},
}
@article{1732,
author = {{Yim, Tae-Jin and Zentgraf, Thomas and Min, Bumki and Zhang, Xiang}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
number = {{7}},
pages = {{2154--2156}},
publisher = {{American Chemical Society (ACS)}},
title = {{{All-Liquid Photonic Microcavity Stabilized by Quantum Dots}}},
doi = {{10.1021/ja909483w}},
volume = {{132}},
year = {{2010}},
}
@article{25971,
abstract = {{Precipitation of zinc sulfide particles is a very rapid process, and monitoring of the particle growth is experimentally very demanding. Applying a liquid jet flow cell, we were able to follow zinc sulfide particle formation on time scales down to 10−5 s. The flow cell was designed in such a way that data acquisition on the microsecond time scale was possible under steady-state conditions along a liquid jet (tubular reactor concept), allowing SAXS data accumulation over a time scale of minutes. We were able to monitor the growth of zinc sulfide particles and found experimental evidence for very rapid particle aggregation processes within the liquid jet. Under the experimental conditions the particle growth is controlled by mass transfer: i.e., the diffusion of the hydrogen sulfide into the liquid jet.}},
author = {{Schmidt, Wolfgang and Bussian, Patrick and Lindén, Mika and Amenitsch, Heinz and Agren, Patrik and Tiemann, Michael and Schüth, Ferdi}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
pages = {{6822--6826}},
title = {{{Accessing Ultrashort Reaction Times in Particle Formation with SAXS Experiments: ZnS Precipitation on the Microsecond Time Scale}}},
doi = {{10.1021/ja101519z}},
year = {{2010}},
}
@article{38010,
author = {{Navarro, Ismael and Basset, Jean-François and Hebbe, Séverine and Major, Sarah M. and Werner, Thomas and Howsham, Catherine and Bräckow, Jan and Barrett, Anthony G. M.}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis}},
number = {{31}},
pages = {{10293--10298}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Biomimetic Synthesis of Resorcylate Natural Products Utilizing Late Stage Aromatization: Concise Total Syntheses of the Marine Antifungal Agents 15G256ι and 15G256β}}},
doi = {{10.1021/ja803445u}},
volume = {{130}},
year = {{2008}},
}
@article{42006,
author = {{Hermes, Stephan and Witte, Thomas and Hikov, Todor and Zacher, Denise and Bahnmüller, Stefan and Langstein, Gerhard and Huber, Klaus and Fischer, Roland A.}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis}},
number = {{17}},
pages = {{5324--5325}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Trapping Metal-Organic Framework Nanocrystals: An in-Situ Time-Resolved Light Scattering Study on the Crystal Growth of MOF-5 in Solution}}},
doi = {{10.1021/ja068835i}},
volume = {{129}},
year = {{2007}},
}
@article{42007,
author = {{Huber, Klaus and Witte, Thomas and Hollmann, Jutta and Keuker-Baumann, Susanne}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis}},
number = {{5}},
pages = {{1089--1094}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Controlled Formation of Ag Nanoparticles by Means of Long-Chain Sodium Polyacrylates in Dilute Solution}}},
doi = {{10.1021/ja063368q}},
volume = {{129}},
year = {{2007}},
}
@article{25994,
abstract = {{Periodically ordered mesoporous magnesium oxides were synthesized by utilization of mesoporous CMK-3 carbon as exotemplate. The products exhibit high thermal stability and basic properties, which makes them promising for application in heterogeneous basic catalysis.}},
author = {{Roggenbuck, Jan and Tiemann, Michael}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
pages = {{1096--1097}},
title = {{{Ordered Mesoporous Magnesium Oxide with High Thermal Stability Synthesized by Exotemplating Using CMK-3 Carbon}}},
doi = {{10.1021/ja043605u}},
year = {{2005}},
}
@article{42019,
author = {{Witte, Thomas and Decker, Björn and Mattay, Jochen and Huber, Klaus}},
issn = {{0002-7863}},
journal = {{Journal of the American Chemical Society}},
keywords = {{Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis}},
number = {{30}},
pages = {{9276--9282}},
publisher = {{American Chemical Society (ACS)}},
title = {{{Formation of Branched Calixarene AggregatesA Time-Resolved Static Light Scattering Study}}},
doi = {{10.1021/ja0493291}},
volume = {{126}},
year = {{2004}},
}