---
_id: '62855'
abstract:
- lang: eng
  text: <jats:p>Two N,N'-bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamine proligands,
    H2L1 (R = OCH3) and H2L2 (R = OC2H5), and five heterodinuclear ZnII/LnIII complexes,
    [Zn(L)(µ-CH3COO)Ln(NO3)2], containing [L1]2– and Gd3+, Tb3+, Er3+, or Yb3+ and
    [L2]2– and Yb3+ have been synthesised and structurally characterised. The complexes
    are isostructural and crystallise in the P21/n monoclinic space group. Zinc(ii)
    is coordinated by the inner N2O2 donor set of the ligand and an oxygen of the
    bridging acetate anion; the lanthanide(iii) ions possess an O9 coordination environment
    involving the interaction with the ligand’s outer O4 donor set, two bidentate
    nitrate ions, and the bridging acetate.</jats:p>
author:
- first_name: Norman
  full_name: Kelly, Norman
  last_name: Kelly
- first_name: Kathleen
  full_name: Schnaars, Kathleen
  id: '117735'
  last_name: Schnaars
- first_name: Kerstin
  full_name: Gloe, Kerstin
  last_name: Gloe
- first_name: Thomas
  full_name: Doert, Thomas
  last_name: Doert
- first_name: Jan J.
  full_name: Weigand, Jan J.
  last_name: Weigand
- first_name: Karsten
  full_name: Gloe, Karsten
  last_name: Gloe
citation:
  ama: 'Kelly N, Schnaars K, Gloe K, Doert T, Weigand JJ, Gloe K. New Heterodinuclear
    Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes of Hexadentate N,N’-Bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamines:
    Synthesis and Structure*. <i>Australian Journal of Chemistry</i>. 2017;70(5):601-607.
    doi:<a href="https://doi.org/10.1071/ch16716">10.1071/ch16716</a>'
  apa: 'Kelly, N., Schnaars, K., Gloe, K., Doert, T., Weigand, J. J., &#38; Gloe,
    K. (2017). New Heterodinuclear Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes of Hexadentate
    N,N’-Bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamines: Synthesis and Structure*.
    <i>Australian Journal of Chemistry</i>, <i>70</i>(5), 601–607. <a href="https://doi.org/10.1071/ch16716">https://doi.org/10.1071/ch16716</a>'
  bibtex: '@article{Kelly_Schnaars_Gloe_Doert_Weigand_Gloe_2017, title={New Heterodinuclear
    Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes of Hexadentate N,N’-Bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamines:
    Synthesis and Structure*}, volume={70}, DOI={<a href="https://doi.org/10.1071/ch16716">10.1071/ch16716</a>},
    number={5}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing},
    author={Kelly, Norman and Schnaars, Kathleen and Gloe, Kerstin and Doert, Thomas
    and Weigand, Jan J. and Gloe, Karsten}, year={2017}, pages={601–607} }'
  chicago: 'Kelly, Norman, Kathleen Schnaars, Kerstin Gloe, Thomas Doert, Jan J. Weigand,
    and Karsten Gloe. “New Heterodinuclear Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes of
    Hexadentate N,N’-Bis(3-Alkoxy-2-Hydroxybenzyl)Cyclohexane-1,2-Diamines: Synthesis
    and Structure*.” <i>Australian Journal of Chemistry</i> 70, no. 5 (2017): 601–7.
    <a href="https://doi.org/10.1071/ch16716">https://doi.org/10.1071/ch16716</a>.'
  ieee: 'N. Kelly, K. Schnaars, K. Gloe, T. Doert, J. J. Weigand, and K. Gloe, “New
    Heterodinuclear Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes of Hexadentate N,N’-Bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamines:
    Synthesis and Structure*,” <i>Australian Journal of Chemistry</i>, vol. 70, no.
    5, pp. 601–607, 2017, doi: <a href="https://doi.org/10.1071/ch16716">10.1071/ch16716</a>.'
  mla: 'Kelly, Norman, et al. “New Heterodinuclear Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes
    of Hexadentate N,N’-Bis(3-Alkoxy-2-Hydroxybenzyl)Cyclohexane-1,2-Diamines: Synthesis
    and Structure*.” <i>Australian Journal of Chemistry</i>, vol. 70, no. 5, CSIRO
    Publishing, 2017, pp. 601–07, doi:<a href="https://doi.org/10.1071/ch16716">10.1071/ch16716</a>.'
  short: N. Kelly, K. Schnaars, K. Gloe, T. Doert, J.J. Weigand, K. Gloe, Australian
    Journal of Chemistry 70 (2017) 601–607.
date_created: 2025-12-04T12:12:54Z
date_updated: 2025-12-04T12:19:28Z
department:
- _id: '985'
doi: 10.1071/ch16716
extern: '1'
intvolume: '        70'
issue: '5'
language:
- iso: eng
page: 601-607
publication: Australian Journal of Chemistry
publication_identifier:
  issn:
  - 0004-9425
  - 1445-0038
publication_status: published
publisher: CSIRO Publishing
quality_controlled: '1'
status: public
title: 'New Heterodinuclear Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes of Hexadentate N,N''-Bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamines:
  Synthesis and Structure*'
type: journal_article
user_id: '117735'
volume: 70
year: '2017'
...