@article{63981,
  abstract     = {{The thermal behavior of n-octanol and related ether alcohols has been studied by differential scanning calorimetry (DSC). The melting point, heat of fusion, and isobaric heat capacities of n-octanol obtained from the DSC measurements are in good agreement with literature values. The ether alcohols display kinetic barriers for forming a solid phase during cooldown. These barriers are least for 6-methoxyhexanol that forms a solid upon cooling except for the highest measured temperature change rate of 40 K·min–1, followed by 4-propoxybutanol that forms a solid during cooldown only at low cooling rates. 2-Pentoxyethanol and 5-ethoxypentanol form a solid during the heating cycle that then melts again upon further heating. 3-Butoxypropanol does not display any exo- and endothermic features for all measured temperature change rates. Consequently, new data on melting point and heats of fusion are reported for the ether alcohols except for 3-butoxypropanol. New isobaric heat capacities are presented as well for the liquid phase of these ether alcohols. The thermal behavior of n-octanol and related ether alcohols has been studied by differential scanning calorimetry (DSC). The melting point, heat of fusion, and isobaric heat capacities of n-octanol obtained from the DSC measurements are in good agreement with literature values. The ether alcohols display kinetic barriers for forming a solid phase during cooldown. These barriers are least for 6-methoxyhexanol that forms a solid upon cooling except for the highest measured temperature change rate of 40 K·min–1, followed by 4-propoxybutanol that forms a solid during cooldown only at low cooling rates. 2-Pentoxyethanol and 5-ethoxypentanol form a solid during the heating cycle that then melts again upon further heating. 3-Butoxypropanol does not display any exo- and endothermic features for all measured temperature change rates. Consequently, new data on melting point and heats of fusion are reported for the ether alcohols except for 3-butoxypropanol. New isobaric heat capacities are presented as well for the liquid phase of these ether alcohols.}},
  author       = {{Hoffmann, Markus M. and Gutmann, Torsten and Buntkowsky, Gerd}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  number       = {{1}},
  pages        = {{600–606}},
  publisher    = {{American Chemical Society}},
  title        = {{{Thermal Behavior of n-Octanol and Related Ether Alcohols}}},
  doi          = {{10.1021/acs.jced.4c00525}},
  volume       = {{70}},
  year         = {{2025}},
}

@article{52097,
  author       = {{Hami Dindar, Iman and Mirzaei, Mona and Baumhögger, Elmar and Lutters, Nicole and Kenig, Eugeny Y.}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  keywords     = {{General Chemical Engineering, General Chemistry}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Experimental and Theoretical Investigation of CO2 Absorption in Aqueous Solution of Glucosamine: Material Property and Equilibrium Data}}},
  doi          = {{10.1021/acs.jced.3c00554}},
  year         = {{2024}},
}

@article{63980,
  abstract     = {{Density, viscosity, and self-diffusion coefficients are reported for octan-1-ol and the related ether-alcohols 2-pentoxy-ethan-1-ol, 3-butoxypropan-1-ol, 4-propoxybutan-1-ol, 5-ethoxypentan-1-ol, and 6-methoxyhexan-1-ol covering temperature ranges from 298.15 to 359.15 K. These new data reveal structure–property relationships affected by the presence and the position of the ether moiety in the molecular structure of the ether-alcohols. Compared to octan-1-ol, the presence of the ether moiety causes an increase in intermolecular hydrogen bonding interactions, resulting in higher densities. The increase in density is less pronounced for those ether-octanols that engage in intramolecular hydrogen bonding. As for the effects of the ether moiety on the dynamics, these are generally faster for the ether-alcohols compared to octan-1-ol, suggesting that hydrogen bonding between ether oxygen and hydroxy hydrogen is weaker compared to hydrogen bonding between two hydroxy groups. The activation energies obtained from an Arrhenius analysis are higher for translational motion than for momentum transfer for all alcohols. There are additional finer details across the ether alcohols for these activation barriers. These differences cancel out for the mathematical product of self-diffusion coefficient and viscosity (Dη). The effect of water impurities on the studied properties was also investigated and found to lead to small increases in densities for all alcohols. Viscosities decrease for octan-1-ol and 2-pentoxyethan-1-ol but increase for the other ether-alcohols that can engage in intramolecular hydrogen bonding. Density, viscosity, and self-diffusion coefficients are reported for octan-1-ol and the related ether-alcohols 2-pentoxy-ethan-1-ol, 3-butoxypropan-1-ol, 4-propoxybutan-1-ol, 5-ethoxypentan-1-ol, and 6-methoxyhexan-1-ol covering temperature ranges from 298.15 to 359.15 K. These new data reveal structure–property relationships affected by the presence and the position of the ether moiety in the molecular structure of the ether-alcohols. Compared to octan-1-ol, the presence of the ether moiety causes an increase in intermolecular hydrogen bonding interactions, resulting in higher densities. The increase in density is less pronounced for those ether-octanols that engage in intramolecular hydrogen bonding. As for the effects of the ether moiety on the dynamics, these are generally faster for the ether-alcohols compared to octan-1-ol, suggesting that hydrogen bonding between ether oxygen and hydroxy hydrogen is weaker compared to hydrogen bonding between two hydroxy groups. The activation energies obtained from an Arrhenius analysis are higher for translational motion than for momentum transfer for all alcohols. There are additional finer details across the ether alcohols for these activation barriers. These differences cancel out for the mathematical product of self-diffusion coefficient and viscosity (Dη). The effect of water impurities on the studied properties was also investigated and found to lead to small increases in densities for all alcohols. Viscosities decrease for octan-1-ol and 2-pentoxyethan-1-ol but increase for the other ether-alcohols that can engage in intramolecular hydrogen bonding.}},
  author       = {{Hoffmann, Markus M. and Gonzalez, Anthony A. and Huynh, Mandy T. and Miller, Kashane K. and Gutmann, Torsten and Buntkowsky, Gerd}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  number       = {{8}},
  pages        = {{2688–2699}},
  publisher    = {{American Chemical Society}},
  title        = {{{Densities, Viscosities, and Self-Diffusion Coefficients of Octan-1-ol and Related Ether-Alcohols}}},
  doi          = {{10.1021/acs.jced.4c00195}},
  volume       = {{69}},
  year         = {{2024}},
}

@article{16848,
  author       = {{Javed, Muhammad Ali and Rüther, Moritz and Baumhögger, Elmar and Vrabec, Jadran}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  title        = {{{Density and Thermodynamic Speed of Sound of Liquid Vinyl Chloride}}},
  doi          = {{10.1021/acs.jced.9b01133}},
  year         = {{2020}},
}

@article{16305,
  author       = {{Linnemann, Matthias and Nikolaychuk, Pavel Anatolyevich and Muñoz-Muñoz, Y. Mauricio and Baumhögger, Elmar and Vrabec, Jadran}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  pages        = {{1180--1188}},
  title        = {{{Henry’s Law Constant of Noble Gases in Water, Methanol, Ethanol, and Isopropanol by Experiment and Molecular Simulation}}},
  doi          = {{10.1021/acs.jced.9b00565}},
  year         = {{2019}},
}

@article{13159,
  author       = {{Javed, Muhammad Ali and Baumhögger, Elmar and Vrabec, Jadran}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  pages        = {{1035--1044}},
  title        = {{{Thermodynamic Speed of Sound Data for Liquid and Supercritical Alcohols}}},
  doi          = {{10.1021/acs.jced.8b00938}},
  year         = {{2019}},
}

@article{13160,
  author       = {{Thol, Monika and Dubberke, Frithjof H. and Baumhögger, Elmar and Span, Roland and Vrabec, Jadran}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  pages        = {{2533--2547}},
  title        = {{{Speed of Sound Measurements and a Fundamental Equation of State for Hydrogen Chloride}}},
  doi          = {{10.1021/acs.jced.7b01031}},
  year         = {{2018}},
}

@article{13163,
  author       = {{Thol, Monika and Dubberke, Frithjof H. and Baumhögger, Elmar and Span, Roland and Vrabec, Jadran}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  pages        = {{2533--2547}},
  title        = {{{Speed of Sound Measurements and a Fundamental Equation of State for Hydrogen Chloride}}},
  doi          = {{10.1021/acs.jced.7b01031}},
  year         = {{2018}},
}

@article{13164,
  author       = {{Dubberke, Frithjof H. and Riepold, Markus and Baumhögger, Elmar and Vrabec, Jadran}},
  issn         = {{0021-9568}},
  journal      = {{Journal of Chemical & Engineering Data}},
  pages        = {{1632--1636}},
  title        = {{{Speed of Sound of Oxygen in Supercritical States up to 500 K and 100 MPa}}},
  doi          = {{10.1021/acs.jced.5b01007}},
  year         = {{2016}},
}

