---
_id: '32485'
abstract:
- lang: eng
  text: Using the methods of differential mass-spectrometric thermal analysis (DMSTA),
    thermogravimetric analysis (TGA), microscale combustion calorimetry (MCC), and
    fast pyrolysis (FP), thermal decomposition of high-molecular-weight polymethylmetacrylate
    (PMMA) has been investigated in the temperature range of 315 + 500 degrees C.
    Based on these data, the kinetic parameters (the activation energy, the pre-exponential
    factor) were obtained of a one-step pyrolysis reaction in supposition of a first-order
    reaction using simple mathematical fitting and an iso-conversion method. Validity
    of the obtained kinetic parameters was verified by comparing the experimental
    data on dependence of the decomposition rate on temperature in the broad range
    of the heating rates with the results of simulating the above dependence, using
    these kinetic parameters. These parameters, obtained in the broad temperature
    range, may be further used in numerical simulation of PMMA combustion under fire
    conditions and for assessing the polymer's flammability.
author:
- first_name: Oleg P.
  full_name: Korobeinichev, Oleg P.
  last_name: Korobeinichev
- first_name: Alexey А.
  full_name: Paletsky, Alexey А.
  last_name: Paletsky
- first_name: Maksim B.
  full_name: Gonchikzhapov, Maksim B.
  last_name: Gonchikzhapov
- first_name: Roman K.
  full_name: Glaznev, Roman K.
  last_name: Glaznev
- first_name: Ivan E.
  full_name: Gerasimov, Ivan E.
  last_name: Gerasimov
- first_name: Yuri K.
  full_name: Naganovsky, Yuri K.
  last_name: Naganovsky
- first_name: Irina K.
  full_name: Shundrina, Irina K.
  last_name: Shundrina
- first_name: Alexey Y.
  full_name: Snegirev, Alexey Y.
  last_name: Snegirev
- first_name: R.
  full_name: Vinu, R.
  last_name: Vinu
citation:
  ama: Korobeinichev OP, Paletsky AА, Gonchikzhapov MB, et al. Kinetics of thermal
    decomposition of PMMA at different heating rates and in a wide temperature range.
    <i>Thermochimica Acta</i>. 2018;671:17-25. doi:<a href="https://doi.org/10.1016/j.tca.2018.10.019">10.1016/j.tca.2018.10.019</a>
  apa: Korobeinichev, O. P., Paletsky, A. А., Gonchikzhapov, M. B., Glaznev, R. K.,
    Gerasimov, I. E., Naganovsky, Y. K., Shundrina, I. K., Snegirev, A. Y., &#38;
    Vinu, R. (2018). Kinetics of thermal decomposition of PMMA at different heating
    rates and in a wide temperature range. <i>Thermochimica Acta</i>, <i>671</i>,
    17–25. <a href="https://doi.org/10.1016/j.tca.2018.10.019">https://doi.org/10.1016/j.tca.2018.10.019</a>
  bibtex: '@article{Korobeinichev_Paletsky_Gonchikzhapov_Glaznev_Gerasimov_Naganovsky_Shundrina_Snegirev_Vinu_2018,
    title={Kinetics of thermal decomposition of PMMA at different heating rates and
    in a wide temperature range}, volume={671}, DOI={<a href="https://doi.org/10.1016/j.tca.2018.10.019">10.1016/j.tca.2018.10.019</a>},
    journal={Thermochimica Acta}, publisher={Elsevier BV}, author={Korobeinichev,
    Oleg P. and Paletsky, Alexey А. and Gonchikzhapov, Maksim B. and Glaznev, Roman
    K. and Gerasimov, Ivan E. and Naganovsky, Yuri K. and Shundrina, Irina K. and
    Snegirev, Alexey Y. and Vinu, R.}, year={2018}, pages={17–25} }'
  chicago: 'Korobeinichev, Oleg P., Alexey А. Paletsky, Maksim B. Gonchikzhapov, Roman
    K. Glaznev, Ivan E. Gerasimov, Yuri K. Naganovsky, Irina K. Shundrina, Alexey
    Y. Snegirev, and R. Vinu. “Kinetics of Thermal Decomposition of PMMA at Different
    Heating Rates and in a Wide Temperature Range.” <i>Thermochimica Acta</i> 671
    (2018): 17–25. <a href="https://doi.org/10.1016/j.tca.2018.10.019">https://doi.org/10.1016/j.tca.2018.10.019</a>.'
  ieee: 'O. P. Korobeinichev <i>et al.</i>, “Kinetics of thermal decomposition of
    PMMA at different heating rates and in a wide temperature range,” <i>Thermochimica
    Acta</i>, vol. 671, pp. 17–25, 2018, doi: <a href="https://doi.org/10.1016/j.tca.2018.10.019">10.1016/j.tca.2018.10.019</a>.'
  mla: Korobeinichev, Oleg P., et al. “Kinetics of Thermal Decomposition of PMMA at
    Different Heating Rates and in a Wide Temperature Range.” <i>Thermochimica Acta</i>,
    vol. 671, Elsevier BV, 2018, pp. 17–25, doi:<a href="https://doi.org/10.1016/j.tca.2018.10.019">10.1016/j.tca.2018.10.019</a>.
  short: O.P. Korobeinichev, A.А. Paletsky, M.B. Gonchikzhapov, R.K. Glaznev, I.E.
    Gerasimov, Y.K. Naganovsky, I.K. Shundrina, A.Y. Snegirev, R. Vinu, Thermochimica
    Acta 671 (2018) 17–25.
date_created: 2022-08-02T10:20:56Z
date_updated: 2026-03-09T13:24:21Z
department:
- _id: '728'
doi: 10.1016/j.tca.2018.10.019
intvolume: '       671'
keyword:
- Physical and Theoretical Chemistry
- Condensed Matter Physics
- Instrumentation
language:
- iso: eng
page: 17-25
publication: Thermochimica Acta
publication_identifier:
  issn:
  - 0040-6031
publication_status: published
publisher: Elsevier BV
status: public
title: Kinetics of thermal decomposition of PMMA at different heating rates and in
  a wide temperature range
type: journal_article
user_id: '14972'
volume: 671
year: '2018'
...