@article{45571,
  abstract     = {{Self-templating is a facile strategy for synthesizing porous carbons by direct pyrolysis of organic metal salts. However, the method typically suffers from low yields (<4%) and limited specific surface areas (SSA<2000 m2 g−1) originating from low activity of metal cations (e.g., K+ or Na+) in promoting construction and activation of carbon frameworks. Here we use cesium acetate as the only precursor of oxo-carbons with large SSA of the order of 3000 m2 g−1, pore volume approaching 2 cm3 g−1, tunable oxygen contents, and yields of up to 15 %. We unravel the role of Cs+ as an efficient promoter of framework formation, templating and etching agent, while acetates act as carbon/oxygen sources of carbonaceous frameworks. The oxo-carbons show record-high CO2 uptake of 8.71 mmol g−1 and an ultimate specific capacitance of 313 F g−1 in the supercapacitor. This study helps to understand and rationally tailor the materials design by a still rare organic solid-state chemistry.}},
  author       = {{Li, Jiaxin and Kossmann, Janina and Zeng, Ke and Zhang, Kun and Wang, Bingjie and Weinberger, Christian and Antonietti, Markus and Odziomek, Mateusz and López‐Salas, Nieves}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{CO2 Adsorption, Cesium Acetate, Cesium Effect, Porous Carbons, Supercapacitor}},
  publisher    = {{Wiley}},
  title        = {{{When High‐Temperature Cesium Chemistry Meets Self‐Templating: Metal Acetates as Building Blocks of Unusual Highly Porous Carbons}}},
  doi          = {{10.1002/anie.202217808}},
  year         = {{2023}},
}

@article{42879,
  author       = {{Köring, Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  keywords     = {{General Medicine}},
  publisher    = {{Wiley}},
  title        = {{{Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation}}},
  doi          = {{10.1002/ange.202301632}},
  year         = {{2023}},
}

@article{62101,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>The carbon–carbon double bond of unsaturated carbonyl compounds was readily reduced by using a phosphetane oxide catalyst in the presence of a simple organosilane as the terminal reductant and water as the hydrogen source. Quantitative hydrogenation was observed when 1.0 mol % of a methyl‐substituted phosphetane oxide was employed as the catalyst. The procedure is highly selective towards activated double bonds, tolerating a variety of functional groups that are usually prone to reduction. In total, 25 alkenes and two alkynes were hydrogenated to the corresponding alkanes in excellent yields of up to 99 %. Notably, less active poly(methylhydrosiloxane) could also be utilized as the terminal reductant. Mechanistic investigations revealed the phosphane as the catalyst resting state and a protonation/deprotonation sequence as the crucial step in the catalytic cycle.</jats:p>}},
  author       = {{Longwitz, Lars and Werner, Thomas}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  keywords     = {{T2, T4}},
  number       = {{7}},
  pages        = {{2782--2785}},
  publisher    = {{Wiley}},
  title        = {{{Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis}}},
  doi          = {{10.1002/ange.201912991}},
  volume       = {{132}},
  year         = {{2020}},
}

@article{17079,
  author       = {{Wiebeler, Christian and Rao, Aditya G. and Gärtner, Wolfgang and Schapiro, Igor}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  keywords     = {{pc2-ressources}},
  pages        = {{1952--1957}},
  title        = {{{Die effektive Konjugationslänge ist für die spektrale Verschiebung im rot/grün schaltenden Cyanobakteriochrom Slr1393g3 verantwortlich}}},
  doi          = {{10.1002/ange.201810266}},
  year         = {{2018}},
}

@article{47584,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>Die Digitalisierung und Flexibilisierung von Produktionsprozessen bieten in der Spezialchemie die Chance, auf marktseitige Herausforderungen adäquat zu reagieren. Kürzer werdende Produktlebenszyklen, zunehmende Produktindividualisierung und die daraus resultierende Volatilität der Märkte stellen neue Anforderungen an Anlagenbetreiber. Neuartige Konzepte wie modulare Produktionsanlagen sowie Technologieentwicklungen im Rahmen der Industrie 4.0 können dabei helfen, die Smart Factory in der Spezialchemie umzusetzen. Im Folgenden werden die für diesen Wandel notwendigen Konzepte vorgestellt.</jats:p>}},
  author       = {{Reitze, Arnulf and Jürgensmeyer, Nikolas and Lier, Stefan and Kohnke, Marco and Riese, Julia and Grünewald, Marcus}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  keywords     = {{General Medicine}},
  number       = {{16}},
  pages        = {{4318--4324}},
  publisher    = {{Wiley}},
  title        = {{{Auf dem Weg zur Smart Factory: modulare, intelligente Konzepte für die Produktion von Spezialchemikalien der Zukunft}}},
  doi          = {{10.1002/ange.201711571}},
  volume       = {{130}},
  year         = {{2018}},
}

@article{22242,
  author       = {{Stepen, Arne J. and Bursch, Markus and Grimme, Stefan and Stephan, Douglas W. and Paradies, Jan}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  pages        = {{15473--15476}},
  title        = {{{Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation}}},
  doi          = {{10.1002/ange.201809275}},
  year         = {{2018}},
}

@article{22253,
  author       = {{Tamke, Sergej and Qu, Zheng-Wang and Sitte, Nikolai A. and Flörke, Ulrich and Grimme, Stefan and Paradies, Jan}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  pages        = {{4408--4411}},
  title        = {{{Cycloisomerisierung von 1,5-Eninen über eine 5-endo-dig- Cyclisierungs-Protodeborylierungs-Sequenz mit einem frustrierten Lewis-Paar als Katalysator}}},
  doi          = {{10.1002/ange.201511921}},
  year         = {{2016}},
}

@article{22255,
  author       = {{Maier, Alexander F. G. and Tussing, Sebastian and Schneider, Tobias and Flörke, Ulrich and Qu, Zheng-Wang and Grimme, Stefan and Paradies, Jan}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  pages        = {{12407--12411}},
  title        = {{{Dehydrierende Oxidation von Indolinen und anderen Heterocyclen durch frustrierte Lewis-Paare}}},
  doi          = {{10.1002/ange.201606426}},
  year         = {{2016}},
}

@article{41052,
  author       = {{Sinha, Woormileela and Sommer, Michael G. and Deibel, Naina and Ehret, Fabian and Bauer, Matthias and Sarkar, Biprajit and Kar, Sanjib}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  keywords     = {{General Medicine}},
  number       = {{46}},
  pages        = {{13973--13978}},
  publisher    = {{Wiley}},
  title        = {{{Experimentelle und theoretische Untersuchung der Existenz von Cu<sup>II</sup>, Cu<sup>III</sup>und Cu<sup>IV</sup>in Kupfercorrolen}}},
  doi          = {{10.1002/ange.201507330}},
  volume       = {{127}},
  year         = {{2015}},
}

@article{41989,
  author       = {{Cravillon, Janosch and Schröder, Christian A. and Nayuk, Roman and Gummel, Jeremie and Huber, Klaus and Wiebcke, Michael}},
  issn         = {{0044-8249}},
  journal      = {{Angewandte Chemie}},
  keywords     = {{General Medicine}},
  number       = {{35}},
  pages        = {{8217--8221}},
  publisher    = {{Wiley}},
  title        = {{{Fast Nucleation and Growth of ZIF-8 Nanocrystals Monitored by Time-Resolved In Situ Small-Angle and Wide-Angle X-Ray Scattering}}},
  doi          = {{10.1002/ange.201102071}},
  volume       = {{123}},
  year         = {{2011}},
}