---
_id: '41009'
abstract:
- lang: eng
text: Platinum hydride species catalyze a number of interesting organic reactions.
However, their reactions typically involve the use of high loadings of noble metal
and are difficult to recycle, making them somewhat unsustainable. We have synthesized
surface-immobilized Pt–H species via oxidative addition of surface OH groups to
Pt(PtBu3)2 (1), a rarely used immobilization technique in surface organometallic
chemistry. The hydride species thus made were characterized by infrared, magic-angle
spinning nuclear magnetic resonance, and X-ray absorption spectroscopies and catalyzed
both olefin isomerization and cycloisomerization of a 1,6 enyne (5) with a high
selectivity and low Pt loading.
article_type: original
author:
- first_name: Sarah
full_name: Maier, Sarah
last_name: Maier
- first_name: Steve P.
full_name: Cronin, Steve P.
last_name: Cronin
- first_name: Manh-Anh
full_name: Vu Dinh, Manh-Anh
last_name: Vu Dinh
- first_name: Zheng
full_name: Li, Zheng
last_name: Li
- first_name: Michael
full_name: Dyballa, Michael
last_name: Dyballa
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Deven P.
full_name: Estes, Deven P.
last_name: Estes
citation:
ama: Maier S, Cronin SP, Vu Dinh M-A, et al. Immobilized Platinum Hydride Species
as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics.
2021;40(11):1751-1757. doi:10.1021/acs.organomet.1c00216
apa: Maier, S., Cronin, S. P., Vu Dinh, M.-A., Li, Z., Dyballa, M., Nowakowski,
M., Bauer, M., & Estes, D. P. (2021). Immobilized Platinum Hydride Species
as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics,
40(11), 1751–1757. https://doi.org/10.1021/acs.organomet.1c00216
bibtex: '@article{Maier_Cronin_Vu Dinh_Li_Dyballa_Nowakowski_Bauer_Estes_2021, title={Immobilized
Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations},
volume={40}, DOI={10.1021/acs.organomet.1c00216},
number={11}, journal={Organometallics}, publisher={American Chemical Society (ACS)},
author={Maier, Sarah and Cronin, Steve P. and Vu Dinh, Manh-Anh and Li, Zheng
and Dyballa, Michael and Nowakowski, Michał and Bauer, Matthias and Estes, Deven
P.}, year={2021}, pages={1751–1757} }'
chicago: 'Maier, Sarah, Steve P. Cronin, Manh-Anh Vu Dinh, Zheng Li, Michael Dyballa,
Michał Nowakowski, Matthias Bauer, and Deven P. Estes. “Immobilized Platinum Hydride
Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.”
Organometallics 40, no. 11 (2021): 1751–57. https://doi.org/10.1021/acs.organomet.1c00216.'
ieee: 'S. Maier et al., “Immobilized Platinum Hydride Species as Catalysts
for Olefin Isomerizations and Enyne Cycloisomerizations,” Organometallics,
vol. 40, no. 11, pp. 1751–1757, 2021, doi: 10.1021/acs.organomet.1c00216.'
mla: Maier, Sarah, et al. “Immobilized Platinum Hydride Species as Catalysts for
Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics,
vol. 40, no. 11, American Chemical Society (ACS), 2021, pp. 1751–57, doi:10.1021/acs.organomet.1c00216.
short: S. Maier, S.P. Cronin, M.-A. Vu Dinh, Z. Li, M. Dyballa, M. Nowakowski, M.
Bauer, D.P. Estes, Organometallics 40 (2021) 1751–1757.
date_created: 2023-01-30T17:00:10Z
date_updated: 2024-05-07T11:43:17Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.organomet.1c00216
intvolume: ' 40'
issue: '11'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 1751-1757
publication: Organometallics
publication_identifier:
issn:
- 0276-7333
- 1520-6041
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations
and Enyne Cycloisomerizations
type: journal_article
user_id: '48467'
volume: 40
year: '2021'
...
---
_id: '41324'
author:
- first_name: Sarah
full_name: Maier, Sarah
last_name: Maier
- first_name: Steve P.
full_name: Cronin, Steve P.
last_name: Cronin
- first_name: Manh-Anh
full_name: Vu Dinh, Manh-Anh
last_name: Vu Dinh
- first_name: Zheng
full_name: Li, Zheng
last_name: Li
- first_name: Michael
full_name: Dyballa, Michael
last_name: Dyballa
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Deven P.
full_name: Estes, Deven P.
last_name: Estes
citation:
ama: Maier S, Cronin SP, Vu Dinh M-A, et al. Immobilized Platinum Hydride Species
as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics.
2021;40(11):1751-1757. doi:10.1021/acs.organomet.1c00216
apa: Maier, S., Cronin, S. P., Vu Dinh, M.-A., Li, Z., Dyballa, M., Nowakowski,
M., Bauer, M., & Estes, D. P. (2021). Immobilized Platinum Hydride Species
as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics,
40(11), 1751–1757. https://doi.org/10.1021/acs.organomet.1c00216
bibtex: '@article{Maier_Cronin_Vu Dinh_Li_Dyballa_Nowakowski_Bauer_Estes_2021, title={Immobilized
Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations},
volume={40}, DOI={10.1021/acs.organomet.1c00216},
number={11}, journal={Organometallics}, publisher={American Chemical Society (ACS)},
author={Maier, Sarah and Cronin, Steve P. and Vu Dinh, Manh-Anh and Li, Zheng
and Dyballa, Michael and Nowakowski, Michal and Bauer, Matthias and Estes, Deven
P.}, year={2021}, pages={1751–1757} }'
chicago: 'Maier, Sarah, Steve P. Cronin, Manh-Anh Vu Dinh, Zheng Li, Michael Dyballa,
Michal Nowakowski, Matthias Bauer, and Deven P. Estes. “Immobilized Platinum Hydride
Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.”
Organometallics 40, no. 11 (2021): 1751–57. https://doi.org/10.1021/acs.organomet.1c00216.'
ieee: 'S. Maier et al., “Immobilized Platinum Hydride Species as Catalysts
for Olefin Isomerizations and Enyne Cycloisomerizations,” Organometallics,
vol. 40, no. 11, pp. 1751–1757, 2021, doi: 10.1021/acs.organomet.1c00216.'
mla: Maier, Sarah, et al. “Immobilized Platinum Hydride Species as Catalysts for
Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics,
vol. 40, no. 11, American Chemical Society (ACS), 2021, pp. 1751–57, doi:10.1021/acs.organomet.1c00216.
short: S. Maier, S.P. Cronin, M.-A. Vu Dinh, Z. Li, M. Dyballa, M. Nowakowski, M.
Bauer, D.P. Estes, Organometallics 40 (2021) 1751–1757.
date_created: 2023-01-31T22:50:43Z
date_updated: 2023-02-01T08:50:56Z
doi: 10.1021/acs.organomet.1c00216
intvolume: ' 40'
issue: '11'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 1751-1757
publication: Organometallics
publication_identifier:
issn:
- 0276-7333
- 1520-6041
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations
and Enyne Cycloisomerizations
type: journal_article
user_id: '78878'
volume: 40
year: '2021'
...
---
_id: '41022'
author:
- first_name: Manuel
full_name: Kirchhof, Manuel
last_name: Kirchhof
- first_name: Katrin
full_name: Gugeler, Katrin
last_name: Gugeler
- first_name: Felix Richard
full_name: Fischer, Felix Richard
last_name: Fischer
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Alina
full_name: Bauer, Alina
last_name: Bauer
- first_name: Sonia
full_name: Alvarez-Barcia, Sonia
last_name: Alvarez-Barcia
- first_name: Karina
full_name: Abitaev, Karina
last_name: Abitaev
- first_name: Marc
full_name: Schnierle, Marc
last_name: Schnierle
- first_name: Yaseen
full_name: Qawasmi, Yaseen
last_name: Qawasmi
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Angelika
full_name: Baro, Angelika
last_name: Baro
- first_name: Deven P.
full_name: Estes, Deven P.
last_name: Estes
- first_name: Thomas
full_name: Sottmann, Thomas
last_name: Sottmann
- first_name: Mark R.
full_name: Ringenberg, Mark R.
last_name: Ringenberg
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Sabine
full_name: Laschat, Sabine
last_name: Laschat
citation:
ama: Kirchhof M, Gugeler K, Fischer FR, et al. Experimental and Theoretical Study
on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes
in Catalytic Asymmetric 1,2- and 1,4-Additions. Organometallics. 2020;39(17):3131-3145.
doi:10.1021/acs.organomet.0c00310
apa: Kirchhof, M., Gugeler, K., Fischer, F. R., Nowakowski, M., Bauer, A., Alvarez-Barcia,
S., Abitaev, K., Schnierle, M., Qawasmi, Y., Frey, W., Baro, A., Estes, D. P.,
Sottmann, T., Ringenberg, M. R., Plietker, B., Bauer, M., Kästner, J., & Laschat,
S. (2020). Experimental and Theoretical Study on the Role of Monomeric vs Dimeric
Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and
1,4-Additions. Organometallics, 39(17), 3131–3145. https://doi.org/10.1021/acs.organomet.0c00310
bibtex: '@article{Kirchhof_Gugeler_Fischer_Nowakowski_Bauer_Alvarez-Barcia_Abitaev_Schnierle_Qawasmi_Frey_et
al._2020, title={Experimental and Theoretical Study on the Role of Monomeric vs
Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric
1,2- and 1,4-Additions}, volume={39}, DOI={10.1021/acs.organomet.0c00310},
number={17}, journal={Organometallics}, publisher={American Chemical Society (ACS)},
author={Kirchhof, Manuel and Gugeler, Katrin and Fischer, Felix Richard and Nowakowski,
Michał and Bauer, Alina and Alvarez-Barcia, Sonia and Abitaev, Karina and Schnierle,
Marc and Qawasmi, Yaseen and Frey, Wolfgang and et al.}, year={2020}, pages={3131–3145}
}'
chicago: 'Kirchhof, Manuel, Katrin Gugeler, Felix Richard Fischer, Michał Nowakowski,
Alina Bauer, Sonia Alvarez-Barcia, Karina Abitaev, et al. “Experimental and Theoretical
Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene
Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions.” Organometallics
39, no. 17 (2020): 3131–45. https://doi.org/10.1021/acs.organomet.0c00310.'
ieee: 'M. Kirchhof et al., “Experimental and Theoretical Study on the Role
of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic
Asymmetric 1,2- and 1,4-Additions,” Organometallics, vol. 39, no. 17, pp.
3131–3145, 2020, doi: 10.1021/acs.organomet.0c00310.'
mla: Kirchhof, Manuel, et al. “Experimental and Theoretical Study on the Role of
Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic
Asymmetric 1,2- and 1,4-Additions.” Organometallics, vol. 39, no. 17, American
Chemical Society (ACS), 2020, pp. 3131–45, doi:10.1021/acs.organomet.0c00310.
short: M. Kirchhof, K. Gugeler, F.R. Fischer, M. Nowakowski, A. Bauer, S. Alvarez-Barcia,
K. Abitaev, M. Schnierle, Y. Qawasmi, W. Frey, A. Baro, D.P. Estes, T. Sottmann,
M.R. Ringenberg, B. Plietker, M. Bauer, J. Kästner, S. Laschat, Organometallics
39 (2020) 3131–3145.
date_created: 2023-01-30T17:37:18Z
date_updated: 2024-05-07T11:41:01Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.organomet.0c00310
intvolume: ' 39'
issue: '17'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 3131-3145
publication: Organometallics
publication_identifier:
issn:
- 0276-7333
- 1520-6041
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium
Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions
type: journal_article
user_id: '48467'
volume: 39
year: '2020'
...
---
_id: '41328'
author:
- first_name: Manuel
full_name: Kirchhof, Manuel
last_name: Kirchhof
- first_name: Katrin
full_name: Gugeler, Katrin
last_name: Gugeler
- first_name: Felix Richard
full_name: Fischer, Felix Richard
last_name: Fischer
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Alina
full_name: Bauer, Alina
last_name: Bauer
- first_name: Sonia
full_name: Alvarez-Barcia, Sonia
last_name: Alvarez-Barcia
- first_name: Karina
full_name: Abitaev, Karina
last_name: Abitaev
- first_name: Marc
full_name: Schnierle, Marc
last_name: Schnierle
- first_name: Yaseen
full_name: Qawasmi, Yaseen
last_name: Qawasmi
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Angelika
full_name: Baro, Angelika
last_name: Baro
- first_name: Deven P.
full_name: Estes, Deven P.
last_name: Estes
- first_name: Thomas
full_name: Sottmann, Thomas
last_name: Sottmann
- first_name: Mark R.
full_name: Ringenberg, Mark R.
last_name: Ringenberg
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Sabine
full_name: Laschat, Sabine
last_name: Laschat
citation:
ama: Kirchhof M, Gugeler K, Fischer FR, et al. Experimental and Theoretical Study
on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes
in Catalytic Asymmetric 1,2- and 1,4-Additions. Organometallics. 2020;39(17):3131-3145.
doi:10.1021/acs.organomet.0c00310
apa: Kirchhof, M., Gugeler, K., Fischer, F. R., Nowakowski, M., Bauer, A., Alvarez-Barcia,
S., Abitaev, K., Schnierle, M., Qawasmi, Y., Frey, W., Baro, A., Estes, D. P.,
Sottmann, T., Ringenberg, M. R., Plietker, B., Bauer, M., Kästner, J., & Laschat,
S. (2020). Experimental and Theoretical Study on the Role of Monomeric vs Dimeric
Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and
1,4-Additions. Organometallics, 39(17), 3131–3145. https://doi.org/10.1021/acs.organomet.0c00310
bibtex: '@article{Kirchhof_Gugeler_Fischer_Nowakowski_Bauer_Alvarez-Barcia_Abitaev_Schnierle_Qawasmi_Frey_et
al._2020, title={Experimental and Theoretical Study on the Role of Monomeric vs
Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric
1,2- and 1,4-Additions}, volume={39}, DOI={10.1021/acs.organomet.0c00310},
number={17}, journal={Organometallics}, publisher={American Chemical Society (ACS)},
author={Kirchhof, Manuel and Gugeler, Katrin and Fischer, Felix Richard and Nowakowski,
Michal and Bauer, Alina and Alvarez-Barcia, Sonia and Abitaev, Karina and Schnierle,
Marc and Qawasmi, Yaseen and Frey, Wolfgang and et al.}, year={2020}, pages={3131–3145}
}'
chicago: 'Kirchhof, Manuel, Katrin Gugeler, Felix Richard Fischer, Michal Nowakowski,
Alina Bauer, Sonia Alvarez-Barcia, Karina Abitaev, et al. “Experimental and Theoretical
Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene
Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions.” Organometallics
39, no. 17 (2020): 3131–45. https://doi.org/10.1021/acs.organomet.0c00310.'
ieee: 'M. Kirchhof et al., “Experimental and Theoretical Study on the Role
of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic
Asymmetric 1,2- and 1,4-Additions,” Organometallics, vol. 39, no. 17, pp.
3131–3145, 2020, doi: 10.1021/acs.organomet.0c00310.'
mla: Kirchhof, Manuel, et al. “Experimental and Theoretical Study on the Role of
Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic
Asymmetric 1,2- and 1,4-Additions.” Organometallics, vol. 39, no. 17, American
Chemical Society (ACS), 2020, pp. 3131–45, doi:10.1021/acs.organomet.0c00310.
short: M. Kirchhof, K. Gugeler, F.R. Fischer, M. Nowakowski, A. Bauer, S. Alvarez-Barcia,
K. Abitaev, M. Schnierle, Y. Qawasmi, W. Frey, A. Baro, D.P. Estes, T. Sottmann,
M.R. Ringenberg, B. Plietker, M. Bauer, J. Kästner, S. Laschat, Organometallics
39 (2020) 3131–3145.
date_created: 2023-01-31T22:52:23Z
date_updated: 2023-02-01T08:50:44Z
doi: 10.1021/acs.organomet.0c00310
intvolume: ' 39'
issue: '17'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 3131-3145
publication: Organometallics
publication_identifier:
issn:
- 0276-7333
- 1520-6041
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium
Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions
type: journal_article
user_id: '78878'
volume: 39
year: '2020'
...