[{"citation":{"ieee":"S. Peschtrich, R. Schoch, D. Kuckling, and J. Paradies, “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes,” <i>European Journal of Organic Chemistry</i>, vol. 27, no. 8, 2024, doi: <a href=\"https://doi.org/10.1002/ejoc.202301207\">10.1002/ejoc.202301207</a>.","apa":"Peschtrich, S., Schoch, R., Kuckling, D., &#38; Paradies, J. (2024). A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. <i>European Journal of Organic Chemistry</i>, <i>27</i>(8). <a href=\"https://doi.org/10.1002/ejoc.202301207\">https://doi.org/10.1002/ejoc.202301207</a>","short":"S. Peschtrich, R. Schoch, D. Kuckling, J. Paradies, European Journal of Organic Chemistry 27 (2024).","chicago":"Peschtrich, Sebastian, Roland Schoch, Dirk Kuckling, and Jan Paradies. “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.” <i>European Journal of Organic Chemistry</i> 27, no. 8 (2024). <a href=\"https://doi.org/10.1002/ejoc.202301207\">https://doi.org/10.1002/ejoc.202301207</a>.","mla":"Peschtrich, Sebastian, et al. “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.” <i>European Journal of Organic Chemistry</i>, vol. 27, no. 8, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/ejoc.202301207\">10.1002/ejoc.202301207</a>.","bibtex":"@article{Peschtrich_Schoch_Kuckling_Paradies_2024, title={A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes}, volume={27}, DOI={<a href=\"https://doi.org/10.1002/ejoc.202301207\">10.1002/ejoc.202301207</a>}, number={8}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Peschtrich, Sebastian and Schoch, Roland and Kuckling, Dirk and Paradies, Jan}, year={2024} }","ama":"Peschtrich S, Schoch R, Kuckling D, Paradies J. A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. <i>European Journal of Organic Chemistry</i>. 2024;27(8). doi:<a href=\"https://doi.org/10.1002/ejoc.202301207\">10.1002/ejoc.202301207</a>"},"user_id":"53339","volume":27,"publisher":"Wiley","_id":"52541","status":"public","type":"journal_article","keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"department":[{"_id":"2"},{"_id":"389"}],"date_created":"2024-03-13T17:15:14Z","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>We conducted an investigation into the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene derivative and potassium thioacetate as a substitute for hydrogen sulfide. This investigation utilized kinetic and computational methods. We synthesized two palladium complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene (DPPF) and bis(diisopropylphosphino)ferrocene (D<jats:italic>i</jats:italic>PPF), as well as their tentative intermediates in the catalytic cycle. Reaction rates were measured and then compared to computational predictions.</jats:p>","lang":"eng"}],"issue":"8","publication":"European Journal of Organic Chemistry","doi":"10.1002/ejoc.202301207","language":[{"iso":"eng"}],"date_updated":"2024-03-13T17:17:37Z","publication_status":"published","intvolume":"        27","title":"A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes","year":"2024","author":[{"full_name":"Peschtrich, Sebastian","first_name":"Sebastian","last_name":"Peschtrich"},{"full_name":"Schoch, Roland","first_name":"Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch","id":"48467"},{"last_name":"Kuckling","first_name":"Dirk","full_name":"Kuckling, Dirk","id":"287"},{"id":"53339","first_name":"Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X","full_name":"Paradies, Jan"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]}},{"publication_status":"published","date_updated":"2022-07-28T09:57:57Z","author":[{"last_name":"Schmiegel","first_name":"Carsten J.","full_name":"Schmiegel, Carsten J."},{"full_name":"Baier, Rene","last_name":"Baier","first_name":"Rene"},{"last_name":"Kuckling","first_name":"Dirk","full_name":"Kuckling, Dirk","id":"287"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"year":"2021","title":"Direct Asymmetric Aldol Reaction in Continuous Flow Using Gel‐Bound Organocatalysts","status":"public","user_id":"94","doi":"10.1002/ejoc.202100268","publisher":"Wiley-VCH","_id":"23699","language":[{"iso":"eng"}],"page":"2578-2586","citation":{"ama":"Schmiegel CJ, Baier R, Kuckling D. Direct Asymmetric Aldol Reaction in Continuous Flow Using Gel‐Bound Organocatalysts. <i>European Journal of Organic Chemistry</i>. Published online 2021:2578-2586. doi:<a href=\"https://doi.org/10.1002/ejoc.202100268\">10.1002/ejoc.202100268</a>","bibtex":"@article{Schmiegel_Baier_Kuckling_2021, title={Direct Asymmetric Aldol Reaction in Continuous Flow Using Gel‐Bound Organocatalysts}, DOI={<a href=\"https://doi.org/10.1002/ejoc.202100268\">10.1002/ejoc.202100268</a>}, journal={European Journal of Organic Chemistry}, publisher={Wiley-VCH}, author={Schmiegel, Carsten J. and Baier, Rene and Kuckling, Dirk}, year={2021}, pages={2578–2586} }","mla":"Schmiegel, Carsten J., et al. “Direct Asymmetric Aldol Reaction in Continuous Flow Using Gel‐Bound Organocatalysts.” <i>European Journal of Organic Chemistry</i>, Wiley-VCH, 2021, pp. 2578–86, doi:<a href=\"https://doi.org/10.1002/ejoc.202100268\">10.1002/ejoc.202100268</a>.","chicago":"Schmiegel, Carsten J., Rene Baier, and Dirk Kuckling. “Direct Asymmetric Aldol Reaction in Continuous Flow Using Gel‐Bound Organocatalysts.” <i>European Journal of Organic Chemistry</i>, 2021, 2578–86. <a href=\"https://doi.org/10.1002/ejoc.202100268\">https://doi.org/10.1002/ejoc.202100268</a>.","short":"C.J. Schmiegel, R. Baier, D. Kuckling, European Journal of Organic Chemistry (2021) 2578–2586.","apa":"Schmiegel, C. J., Baier, R., &#38; Kuckling, D. (2021). Direct Asymmetric Aldol Reaction in Continuous Flow Using Gel‐Bound Organocatalysts. <i>European Journal of Organic Chemistry</i>, 2578–2586. <a href=\"https://doi.org/10.1002/ejoc.202100268\">https://doi.org/10.1002/ejoc.202100268</a>","ieee":"C. J. Schmiegel, R. Baier, and D. Kuckling, “Direct Asymmetric Aldol Reaction in Continuous Flow Using Gel‐Bound Organocatalysts,” <i>European Journal of Organic Chemistry</i>, pp. 2578–2586, 2021, doi: <a href=\"https://doi.org/10.1002/ejoc.202100268\">10.1002/ejoc.202100268</a>."},"publication":"European Journal of Organic Chemistry","department":[{"_id":"311"}],"type":"journal_article","date_created":"2021-09-02T12:44:25Z"},{"publication":"European Journal of Organic Chemistry","issue":"11","citation":{"ama":"Schmiegel CJ, Berg P, Obst F, Schoch R, Appelhans D, Kuckling D. Continuous Flow Synthesis of Azoxybenzenes by Reductive Dimerization of Nitrosobenzenes with Gel‐Bound Catalysts. <i>European Journal of Organic Chemistry</i>. 2021;(11):1628-1636. doi:<a href=\"https://doi.org/10.1002/ejoc.202100006\">10.1002/ejoc.202100006</a>","bibtex":"@article{Schmiegel_Berg_Obst_Schoch_Appelhans_Kuckling_2021, title={Continuous Flow Synthesis of Azoxybenzenes by Reductive Dimerization of Nitrosobenzenes with Gel‐Bound Catalysts}, DOI={<a href=\"https://doi.org/10.1002/ejoc.202100006\">10.1002/ejoc.202100006</a>}, number={11}, journal={European Journal of Organic Chemistry}, publisher={Wiley-VCH}, author={Schmiegel, Carsten J. and Berg, Patrik and Obst, Franziska and Schoch, Roland and Appelhans, Dietmar and Kuckling, Dirk}, year={2021}, pages={1628–1636} }","mla":"Schmiegel, Carsten J., et al. “Continuous Flow Synthesis of Azoxybenzenes by Reductive Dimerization of Nitrosobenzenes with Gel‐Bound Catalysts.” <i>European Journal of Organic Chemistry</i>, no. 11, Wiley-VCH, 2021, pp. 1628–36, doi:<a href=\"https://doi.org/10.1002/ejoc.202100006\">10.1002/ejoc.202100006</a>.","short":"C.J. Schmiegel, P. Berg, F. Obst, R. Schoch, D. Appelhans, D. Kuckling, European Journal of Organic Chemistry (2021) 1628–1636.","chicago":"Schmiegel, Carsten J., Patrik Berg, Franziska Obst, Roland Schoch, Dietmar Appelhans, and Dirk Kuckling. “Continuous Flow Synthesis of Azoxybenzenes by Reductive Dimerization of Nitrosobenzenes with Gel‐Bound Catalysts.” <i>European Journal of Organic Chemistry</i>, no. 11 (2021): 1628–36. <a href=\"https://doi.org/10.1002/ejoc.202100006\">https://doi.org/10.1002/ejoc.202100006</a>.","apa":"Schmiegel, C. J., Berg, P., Obst, F., Schoch, R., Appelhans, D., &#38; Kuckling, D. (2021). Continuous Flow Synthesis of Azoxybenzenes by Reductive Dimerization of Nitrosobenzenes with Gel‐Bound Catalysts. <i>European Journal of Organic Chemistry</i>, <i>11</i>, 1628–1636. <a href=\"https://doi.org/10.1002/ejoc.202100006\">https://doi.org/10.1002/ejoc.202100006</a>","ieee":"C. J. Schmiegel, P. Berg, F. Obst, R. Schoch, D. Appelhans, and D. Kuckling, “Continuous Flow Synthesis of Azoxybenzenes by Reductive Dimerization of Nitrosobenzenes with Gel‐Bound Catalysts,” <i>European Journal of Organic Chemistry</i>, no. 11, pp. 1628–1636, 2021, doi: <a href=\"https://doi.org/10.1002/ejoc.202100006\">10.1002/ejoc.202100006</a>."},"date_created":"2021-09-02T12:51:17Z","type":"journal_article","department":[{"_id":"311"}],"status":"public","year":"2021","title":"Continuous Flow Synthesis of Azoxybenzenes by Reductive Dimerization of Nitrosobenzenes with Gel‐Bound Catalysts","author":[{"first_name":"Carsten J.","last_name":"Schmiegel","full_name":"Schmiegel, Carsten J."},{"full_name":"Berg, Patrik","first_name":"Patrik","last_name":"Berg"},{"last_name":"Obst","first_name":"Franziska","full_name":"Obst, Franziska"},{"last_name":"Schoch","first_name":"Roland","full_name":"Schoch, Roland"},{"full_name":"Appelhans, Dietmar","first_name":"Dietmar","last_name":"Appelhans"},{"id":"287","full_name":"Kuckling, Dirk","last_name":"Kuckling","first_name":"Dirk"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"publication_status":"published","date_updated":"2022-07-28T10:01:00Z","page":"1628-1636","publisher":"Wiley-VCH","_id":"23702","language":[{"iso":"eng"}],"user_id":"94","doi":"10.1002/ejoc.202100006"},{"language":[{"iso":"eng"}],"doi":"10.1002/ejoc.202100883","title":"Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?","year":"2021","author":[{"first_name":"Rundong","last_name":"Zhou","full_name":"Zhou, Rundong"},{"full_name":"Paradies, Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X","first_name":"Jan","id":"53339"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"publication_status":"published","date_updated":"2023-01-23T12:51:27Z","intvolume":"      2021","date_created":"2023-01-10T08:57:10Z","type":"journal_article","keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"publication":"European Journal of Organic Chemistry","issue":"46","page":"6334-6339","_id":"35687","publisher":"Wiley","user_id":"53339","volume":2021,"status":"public","citation":{"ieee":"R. Zhou and J. Paradies, “Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?,” <i>European Journal of Organic Chemistry</i>, vol. 2021, no. 46, pp. 6334–6339, 2021, doi: <a href=\"https://doi.org/10.1002/ejoc.202100883\">10.1002/ejoc.202100883</a>.","apa":"Zhou, R., &#38; Paradies, J. (2021). Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration? <i>European Journal of Organic Chemistry</i>, <i>2021</i>(46), 6334–6339. <a href=\"https://doi.org/10.1002/ejoc.202100883\">https://doi.org/10.1002/ejoc.202100883</a>","short":"R. Zhou, J. Paradies, European Journal of Organic Chemistry 2021 (2021) 6334–6339.","chicago":"Zhou, Rundong, and Jan Paradies. “Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?” <i>European Journal of Organic Chemistry</i> 2021, no. 46 (2021): 6334–39. <a href=\"https://doi.org/10.1002/ejoc.202100883\">https://doi.org/10.1002/ejoc.202100883</a>.","mla":"Zhou, Rundong, and Jan Paradies. “Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?” <i>European Journal of Organic Chemistry</i>, vol. 2021, no. 46, Wiley, 2021, pp. 6334–39, doi:<a href=\"https://doi.org/10.1002/ejoc.202100883\">10.1002/ejoc.202100883</a>.","bibtex":"@article{Zhou_Paradies_2021, title={Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?}, volume={2021}, DOI={<a href=\"https://doi.org/10.1002/ejoc.202100883\">10.1002/ejoc.202100883</a>}, number={46}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Zhou, Rundong and Paradies, Jan}, year={2021}, pages={6334–6339} }","ama":"Zhou R, Paradies J. Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration? <i>European Journal of Organic Chemistry</i>. 2021;2021(46):6334-6339. doi:<a href=\"https://doi.org/10.1002/ejoc.202100883\">10.1002/ejoc.202100883</a>"}},{"date_created":"2021-09-07T10:15:38Z","type":"journal_article","department":[{"_id":"311"}],"publication":"European Journal of Organic Chemistry","citation":{"mla":"Berg, Patrik, et al. “Novel Application of Polymer Networks Carrying Tertiary Amines as a Catalyst Inside Microflow Reactors Used for            Knoevenagel            Reactions.” <i>European Journal of Organic Chemistry</i>, Wiley-VCH, 2020, pp. 5765–74, doi:<a href=\"https://doi.org/10.1002/ejoc.202000978\">10.1002/ejoc.202000978</a>.","bibtex":"@article{Berg_Obst_Simon_Richter_Appelhans_Kuckling_2020, title={Novel Application of Polymer Networks Carrying Tertiary Amines as a Catalyst Inside Microflow Reactors Used for            Knoevenagel            Reactions}, DOI={<a href=\"https://doi.org/10.1002/ejoc.202000978\">10.1002/ejoc.202000978</a>}, journal={European Journal of Organic Chemistry}, publisher={Wiley-VCH}, author={Berg, Patrik and Obst, Franziska and Simon, David and Richter, Andreas and Appelhans, Dietmar and Kuckling, Dirk}, year={2020}, pages={5765–5774} }","ama":"Berg P, Obst F, Simon D, Richter A, Appelhans D, Kuckling D. Novel Application of Polymer Networks Carrying Tertiary Amines as a Catalyst Inside Microflow Reactors Used for            Knoevenagel            Reactions. <i>European Journal of Organic Chemistry</i>. Published online 2020:5765-5774. doi:<a href=\"https://doi.org/10.1002/ejoc.202000978\">10.1002/ejoc.202000978</a>","ieee":"P. Berg, F. Obst, D. Simon, A. Richter, D. Appelhans, and D. Kuckling, “Novel Application of Polymer Networks Carrying Tertiary Amines as a Catalyst Inside Microflow Reactors Used for            Knoevenagel            Reactions,” <i>European Journal of Organic Chemistry</i>, pp. 5765–5774, 2020, doi: <a href=\"https://doi.org/10.1002/ejoc.202000978\">10.1002/ejoc.202000978</a>.","apa":"Berg, P., Obst, F., Simon, D., Richter, A., Appelhans, D., &#38; Kuckling, D. (2020). Novel Application of Polymer Networks Carrying Tertiary Amines as a Catalyst Inside Microflow Reactors Used for            Knoevenagel            Reactions. <i>European Journal of Organic Chemistry</i>, 5765–5774. <a href=\"https://doi.org/10.1002/ejoc.202000978\">https://doi.org/10.1002/ejoc.202000978</a>","short":"P. Berg, F. Obst, D. Simon, A. Richter, D. Appelhans, D. Kuckling, European Journal of Organic Chemistry (2020) 5765–5774.","chicago":"Berg, Patrik, Franziska Obst, David Simon, Andreas Richter, Dietmar Appelhans, and Dirk Kuckling. “Novel Application of Polymer Networks Carrying Tertiary Amines as a Catalyst Inside Microflow Reactors Used for            Knoevenagel            Reactions.” <i>European Journal of Organic Chemistry</i>, 2020, 5765–74. <a href=\"https://doi.org/10.1002/ejoc.202000978\">https://doi.org/10.1002/ejoc.202000978</a>."},"page":"5765-5774","publisher":"Wiley-VCH","_id":"23849","language":[{"iso":"eng"}],"doi":"10.1002/ejoc.202000978","user_id":"94","year":"2020","title":"Novel Application of Polymer Networks Carrying Tertiary Amines as a Catalyst Inside Microflow Reactors Used for            Knoevenagel            Reactions","status":"public","publication_identifier":{"issn":["1434-193X","1099-0690"]},"author":[{"last_name":"Berg","first_name":"Patrik","full_name":"Berg, Patrik"},{"first_name":"Franziska","last_name":"Obst","full_name":"Obst, Franziska"},{"full_name":"Simon, David","first_name":"David","last_name":"Simon"},{"full_name":"Richter, Andreas","last_name":"Richter","first_name":"Andreas"},{"full_name":"Appelhans, Dietmar","first_name":"Dietmar","last_name":"Appelhans"},{"first_name":"Dirk","last_name":"Kuckling","full_name":"Kuckling, Dirk","id":"287"}],"date_updated":"2022-07-28T09:48:23Z","publication_status":"published"},{"_id":"38013","publisher":"Wiley","page":"2601-2608","volume":2006,"user_id":"14931","status":"public","citation":{"apa":"Christoffers, J., Kauf, T., Werner, T., &#38; Rössle, M. (2006). Cerium-Catalyzed α-Hydroxylation Reactions of α-Cyclopropyl β-Dicarbonyl Compounds with Molecular Oxygen. <i>European Journal of Organic Chemistry</i>, <i>2006</i>(11), 2601–2608. <a href=\"https://doi.org/10.1002/ejoc.200600061\">https://doi.org/10.1002/ejoc.200600061</a>","ieee":"J. Christoffers, T. Kauf, T. Werner, and M. Rössle, “Cerium-Catalyzed α-Hydroxylation Reactions of α-Cyclopropyl β-Dicarbonyl Compounds with Molecular Oxygen,” <i>European Journal of Organic Chemistry</i>, vol. 2006, no. 11, pp. 2601–2608, 2006, doi: <a href=\"https://doi.org/10.1002/ejoc.200600061\">10.1002/ejoc.200600061</a>.","short":"J. Christoffers, T. Kauf, T. Werner, M. Rössle, European Journal of Organic Chemistry 2006 (2006) 2601–2608.","chicago":"Christoffers, Jens, Thomas Kauf, Thomas Werner, and Michael Rössle. “Cerium-Catalyzed α-Hydroxylation Reactions of α-Cyclopropyl β-Dicarbonyl Compounds with Molecular Oxygen.” <i>European Journal of Organic Chemistry</i> 2006, no. 11 (2006): 2601–8. <a href=\"https://doi.org/10.1002/ejoc.200600061\">https://doi.org/10.1002/ejoc.200600061</a>.","mla":"Christoffers, Jens, et al. “Cerium-Catalyzed α-Hydroxylation Reactions of α-Cyclopropyl β-Dicarbonyl Compounds with Molecular Oxygen.” <i>European Journal of Organic Chemistry</i>, vol. 2006, no. 11, Wiley, 2006, pp. 2601–08, doi:<a href=\"https://doi.org/10.1002/ejoc.200600061\">10.1002/ejoc.200600061</a>.","ama":"Christoffers J, Kauf T, Werner T, Rössle M. Cerium-Catalyzed α-Hydroxylation Reactions of α-Cyclopropyl β-Dicarbonyl Compounds with Molecular Oxygen. <i>European Journal of Organic Chemistry</i>. 2006;2006(11):2601-2608. doi:<a href=\"https://doi.org/10.1002/ejoc.200600061\">10.1002/ejoc.200600061</a>","bibtex":"@article{Christoffers_Kauf_Werner_Rössle_2006, title={Cerium-Catalyzed α-Hydroxylation Reactions of α-Cyclopropyl β-Dicarbonyl Compounds with Molecular Oxygen}, volume={2006}, DOI={<a href=\"https://doi.org/10.1002/ejoc.200600061\">10.1002/ejoc.200600061</a>}, number={11}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Christoffers, Jens and Kauf, Thomas and Werner, Thomas and Rössle, Michael}, year={2006}, pages={2601–2608} }"},"language":[{"iso":"eng"}],"doi":"10.1002/ejoc.200600061","author":[{"full_name":"Christoffers, Jens","last_name":"Christoffers","first_name":"Jens"},{"last_name":"Kauf","first_name":"Thomas","full_name":"Kauf, Thomas"},{"id":"89271","full_name":"Werner, Thomas","first_name":"Thomas","last_name":"Werner"},{"last_name":"Rössle","first_name":"Michael","full_name":"Rössle, Michael"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"title":"Cerium-Catalyzed α-Hydroxylation Reactions of α-Cyclopropyl β-Dicarbonyl Compounds with Molecular Oxygen","year":"2006","intvolume":"      2006","publication_status":"published","date_updated":"2023-01-23T10:12:18Z","date_created":"2023-01-22T21:13:53Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"type":"journal_article","issue":"11","publication":"European Journal of Organic Chemistry","extern":"1"},{"extern":"1","issue":"23","publication":"European Journal of Organic Chemistry","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"type":"journal_article","date_created":"2023-01-22T21:14:15Z","intvolume":"      2005","date_updated":"2023-01-23T10:11:45Z","publication_status":"published","author":[{"full_name":"Rössle, Michael","last_name":"Rössle","first_name":"Michael"},{"id":"89271","full_name":"Werner, Thomas","first_name":"Thomas","last_name":"Werner"},{"full_name":"Frey, Wolfgang","first_name":"Wolfgang","last_name":"Frey"},{"last_name":"Christoffers","first_name":"Jens","full_name":"Christoffers, Jens"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"year":"2005","title":"Cerium-Catalyzed, Aerobic Oxidative Synthesis of 1,2-Dioxane Derivatives from Styrene and Their Fragmentation into 1,4-Dicarbonyl Compounds","doi":"10.1002/ejoc.200500487","language":[{"iso":"eng"}],"citation":{"mla":"Rössle, Michael, et al. “Cerium-Catalyzed, Aerobic Oxidative Synthesis of 1,2-Dioxane Derivatives from Styrene and Their Fragmentation into 1,4-Dicarbonyl Compounds.” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 23, Wiley, 2005, pp. 5031–38, doi:<a href=\"https://doi.org/10.1002/ejoc.200500487\">10.1002/ejoc.200500487</a>.","bibtex":"@article{Rössle_Werner_Frey_Christoffers_2005, title={Cerium-Catalyzed, Aerobic Oxidative Synthesis of 1,2-Dioxane Derivatives from Styrene and Their Fragmentation into 1,4-Dicarbonyl Compounds}, volume={2005}, DOI={<a href=\"https://doi.org/10.1002/ejoc.200500487\">10.1002/ejoc.200500487</a>}, number={23}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Rössle, Michael and Werner, Thomas and Frey, Wolfgang and Christoffers, Jens}, year={2005}, pages={5031–5038} }","ama":"Rössle M, Werner T, Frey W, Christoffers J. Cerium-Catalyzed, Aerobic Oxidative Synthesis of 1,2-Dioxane Derivatives from Styrene and Their Fragmentation into 1,4-Dicarbonyl Compounds. <i>European Journal of Organic Chemistry</i>. 2005;2005(23):5031-5038. doi:<a href=\"https://doi.org/10.1002/ejoc.200500487\">10.1002/ejoc.200500487</a>","ieee":"M. Rössle, T. Werner, W. Frey, and J. Christoffers, “Cerium-Catalyzed, Aerobic Oxidative Synthesis of 1,2-Dioxane Derivatives from Styrene and Their Fragmentation into 1,4-Dicarbonyl Compounds,” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 23, pp. 5031–5038, 2005, doi: <a href=\"https://doi.org/10.1002/ejoc.200500487\">10.1002/ejoc.200500487</a>.","apa":"Rössle, M., Werner, T., Frey, W., &#38; Christoffers, J. (2005). Cerium-Catalyzed, Aerobic Oxidative Synthesis of 1,2-Dioxane Derivatives from Styrene and Their Fragmentation into 1,4-Dicarbonyl Compounds. <i>European Journal of Organic Chemistry</i>, <i>2005</i>(23), 5031–5038. <a href=\"https://doi.org/10.1002/ejoc.200500487\">https://doi.org/10.1002/ejoc.200500487</a>","chicago":"Rössle, Michael, Thomas Werner, Wolfgang Frey, and Jens Christoffers. “Cerium-Catalyzed, Aerobic Oxidative Synthesis of 1,2-Dioxane Derivatives from Styrene and Their Fragmentation into 1,4-Dicarbonyl Compounds.” <i>European Journal of Organic Chemistry</i> 2005, no. 23 (2005): 5031–38. <a href=\"https://doi.org/10.1002/ejoc.200500487\">https://doi.org/10.1002/ejoc.200500487</a>.","short":"M. Rössle, T. Werner, W. Frey, J. Christoffers, European Journal of Organic Chemistry 2005 (2005) 5031–5038."},"status":"public","volume":2005,"user_id":"14931","_id":"38014","publisher":"Wiley","page":"5031-5038"},{"language":[{"iso":"eng"}],"doi":"10.1002/ejoc.200500340","author":[{"first_name":"Sonja","last_name":"Herres‐Pawlis","full_name":"Herres‐Pawlis, Sonja"},{"full_name":"Neuba, Adam","last_name":"Neuba","first_name":"Adam"},{"first_name":"Oliver","last_name":"Seewald","full_name":"Seewald, Oliver","id":"495"},{"last_name":"Seshadri","first_name":"Tarimala","full_name":"Seshadri, Tarimala"},{"last_name":"Egold","first_name":"Hans","full_name":"Egold, Hans"},{"last_name":"Flörke","first_name":"Ulrich","full_name":"Flörke, Ulrich"},{"full_name":"Henkel, Gerald","first_name":"Gerald","last_name":"Henkel"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"year":"2005","title":"A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry","intvolume":"      2005","publication_status":"published","date_updated":"2025-02-12T09:30:43Z","date_created":"2025-02-12T09:27:00Z","department":[{"_id":"321"},{"_id":"35"},{"_id":"301"}],"type":"journal_article","issue":"22","publication":"European Journal of Organic Chemistry","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>A series of bis‐guanidine ligands designed for use in biomimetic coordination chemistry has been extended to a library matrix combining unprecedented substitutional flexibility within the guanidyl residues with a wide range of aliphatic and aromatic spacers connecting these functionalities. The underlying protocol can be used with predefined ureas as well as secondary amines to build up these units by reaction with phosgene if the ureas are otherwise unavailable. In the latter case, the resulting urea intermediates do not have to be isolated as the reaction proceeds further with additional phosgene to yield a chloroformamidinium chloride which is transformed into the bis‐guanidine functionality by subsequent reaction with a suitable primary diamine in the presence of triethylamine as an auxiliary base. This concept has been used to synthesise and characterise more then two dozen different bis‐guanidines based on 12 discrete monoguanidine units and seven different spacers. These spacers have been chosen such that the most important phenotypes have been dealt with and which range from rigid to more flexible scaffolds. In addition to spacers with no metal‐binding capabilities, other species containing further donor functions such as <jats:italic>N</jats:italic>‐methyldiphenyleneamine or pyridine‐2,6‐diyl have also been used. The substitution patterns of the guanidine residues can be classified into acyclic and cyclic types. Among the cyclic types, one subset is characterised by five‐ or six‐membered heterocycles containing both the amino nitrogen atoms and another one by individual N‐heterocyclic systems for each amino nitrogen. Structurally characterised examples are 2‐{2‐[2‐(tetramethylguanidi­no)ethoxy]ethoxy}‐1‐(tetramethylguanidino)ethane (TMG<jats:sub>2</jats:sub>doo) in its diprotonated form and 2,2′‐bis[2<jats:italic>N</jats:italic>‐(1,1′,3,3′‐tetramethylguanidine)]diphenyleneamine (TMG<jats:sub>2</jats:sub>PA) as wellas <jats:italic>N</jats:italic><jats:sup>1</jats:sup>,<jats:italic>N</jats:italic><jats:sup>3</jats:sup>‐bis(dimorpholinomethylene)propane‐1,3‐diamine (DMorphG<jats:sub>2</jats:sub>p) as free bases. For the permethylated bis‐guanidine derivatives, the barrier to rotation around the (C=N)<jats:sub>guanidine</jats:sub> bond has been determined by means of temperature‐dependent EXSY <jats:sup>1</jats:sup>H NMR spectroscopy to range between 54 and 79 kJ mol<jats:sup>–1</jats:sup> depending on the type of spacer. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2005)</jats:p>"}],"_id":"58598","publisher":"Wiley","page":"4879-4890","volume":2005,"user_id":"495","status":"public","citation":{"chicago":"Herres‐Pawlis, Sonja, Adam Neuba, Oliver Seewald, Tarimala Seshadri, Hans Egold, Ulrich Flörke, and Gerald Henkel. “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry.” <i>European Journal of Organic Chemistry</i> 2005, no. 22 (2005): 4879–90. <a href=\"https://doi.org/10.1002/ejoc.200500340\">https://doi.org/10.1002/ejoc.200500340</a>.","short":"S. Herres‐Pawlis, A. Neuba, O. Seewald, T. Seshadri, H. Egold, U. Flörke, G. Henkel, European Journal of Organic Chemistry 2005 (2005) 4879–4890.","ieee":"S. Herres‐Pawlis <i>et al.</i>, “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry,” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 22, pp. 4879–4890, 2005, doi: <a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>.","apa":"Herres‐Pawlis, S., Neuba, A., Seewald, O., Seshadri, T., Egold, H., Flörke, U., &#38; Henkel, G. (2005). A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry. <i>European Journal of Organic Chemistry</i>, <i>2005</i>(22), 4879–4890. <a href=\"https://doi.org/10.1002/ejoc.200500340\">https://doi.org/10.1002/ejoc.200500340</a>","bibtex":"@article{Herres‐Pawlis_Neuba_Seewald_Seshadri_Egold_Flörke_Henkel_2005, title={A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry}, volume={2005}, DOI={<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>}, number={22}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Herres‐Pawlis, Sonja and Neuba, Adam and Seewald, Oliver and Seshadri, Tarimala and Egold, Hans and Flörke, Ulrich and Henkel, Gerald}, year={2005}, pages={4879–4890} }","ama":"Herres‐Pawlis S, Neuba A, Seewald O, et al. A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry. <i>European Journal of Organic Chemistry</i>. 2005;2005(22):4879-4890. doi:<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>","mla":"Herres‐Pawlis, Sonja, et al. “A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry.” <i>European Journal of Organic Chemistry</i>, vol. 2005, no. 22, Wiley, 2005, pp. 4879–90, doi:<a href=\"https://doi.org/10.1002/ejoc.200500340\">10.1002/ejoc.200500340</a>."}},{"date_created":"2023-01-22T21:16:25Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"type":"journal_article","issue":"24","publication":"European Journal of Organic Chemistry","extern":"1","language":[{"iso":"eng"}],"doi":"10.1002/ejoc.200300439","publication_identifier":{"issn":["1434-193X","1099-0690"]},"author":[{"full_name":"Christoffers, Jens","first_name":"Jens","last_name":"Christoffers"},{"last_name":"Werner","first_name":"Thomas","full_name":"Werner, Thomas","id":"89271"},{"first_name":"Wolfgang","last_name":"Frey","full_name":"Frey, Wolfgang"},{"full_name":"Baro, Angelika","first_name":"Angelika","last_name":"Baro"}],"title":"Cerium-Catalyzed Reaction ofβ-Dicarbonyl Compounds with Styrene and Atmospheric Oxygen","year":"2003","intvolume":"      2003","date_updated":"2023-01-23T10:09:42Z","publication_status":"published","citation":{"mla":"Christoffers, Jens, et al. “Cerium-Catalyzed Reaction Ofβ-Dicarbonyl Compounds with Styrene and Atmospheric Oxygen.” <i>European Journal of Organic Chemistry</i>, vol. 2003, no. 24, Wiley, 2003, pp. 4879–86, doi:<a href=\"https://doi.org/10.1002/ejoc.200300439\">10.1002/ejoc.200300439</a>.","bibtex":"@article{Christoffers_Werner_Frey_Baro_2003, title={Cerium-Catalyzed Reaction ofβ-Dicarbonyl Compounds with Styrene and Atmospheric Oxygen}, volume={2003}, DOI={<a href=\"https://doi.org/10.1002/ejoc.200300439\">10.1002/ejoc.200300439</a>}, number={24}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Christoffers, Jens and Werner, Thomas and Frey, Wolfgang and Baro, Angelika}, year={2003}, pages={4879–4886} }","ama":"Christoffers J, Werner T, Frey W, Baro A. Cerium-Catalyzed Reaction ofβ-Dicarbonyl Compounds with Styrene and Atmospheric Oxygen. <i>European Journal of Organic Chemistry</i>. 2003;2003(24):4879-4886. doi:<a href=\"https://doi.org/10.1002/ejoc.200300439\">10.1002/ejoc.200300439</a>","ieee":"J. Christoffers, T. Werner, W. Frey, and A. Baro, “Cerium-Catalyzed Reaction ofβ-Dicarbonyl Compounds with Styrene and Atmospheric Oxygen,” <i>European Journal of Organic Chemistry</i>, vol. 2003, no. 24, pp. 4879–4886, 2003, doi: <a href=\"https://doi.org/10.1002/ejoc.200300439\">10.1002/ejoc.200300439</a>.","apa":"Christoffers, J., Werner, T., Frey, W., &#38; Baro, A. (2003). Cerium-Catalyzed Reaction ofβ-Dicarbonyl Compounds with Styrene and Atmospheric Oxygen. <i>European Journal of Organic Chemistry</i>, <i>2003</i>(24), 4879–4886. <a href=\"https://doi.org/10.1002/ejoc.200300439\">https://doi.org/10.1002/ejoc.200300439</a>","chicago":"Christoffers, Jens, Thomas Werner, Wolfgang Frey, and Angelika Baro. “Cerium-Catalyzed Reaction Ofβ-Dicarbonyl Compounds with Styrene and Atmospheric Oxygen.” <i>European Journal of Organic Chemistry</i> 2003, no. 24 (2003): 4879–86. <a href=\"https://doi.org/10.1002/ejoc.200300439\">https://doi.org/10.1002/ejoc.200300439</a>.","short":"J. Christoffers, T. Werner, W. Frey, A. Baro, European Journal of Organic Chemistry 2003 (2003) 4879–4886."},"_id":"38019","publisher":"Wiley","page":"4879-4886","volume":2003,"user_id":"14931","status":"public"},{"publisher":"Wiley","_id":"38020","page":"425-431","volume":2003,"user_id":"89271","status":"public","citation":{"mla":"Christoffers, Jens, et al. “Preparation of Acyloins by Cerium-Catalyzed, Direct Hydroxylation of β-Dicarbonyl Compounds with Molecular Oxygen.” <i>European Journal of Organic Chemistry</i>, vol. 2003, no. 3, Wiley, 2003, pp. 425–31, doi:<a href=\"https://doi.org/10.1002/ejoc.200390075\">10.1002/ejoc.200390075</a>.","ama":"Christoffers J, Werner T, Unger S, Frey W. Preparation of Acyloins by Cerium-Catalyzed, Direct Hydroxylation of β-Dicarbonyl Compounds with Molecular Oxygen. <i>European Journal of Organic Chemistry</i>. 2003;2003(3):425-431. doi:<a href=\"https://doi.org/10.1002/ejoc.200390075\">10.1002/ejoc.200390075</a>","bibtex":"@article{Christoffers_Werner_Unger_Frey_2003, title={Preparation of Acyloins by Cerium-Catalyzed, Direct Hydroxylation of β-Dicarbonyl Compounds with Molecular Oxygen}, volume={2003}, DOI={<a href=\"https://doi.org/10.1002/ejoc.200390075\">10.1002/ejoc.200390075</a>}, number={3}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Christoffers, Jens and Werner, Thomas and Unger, Sven and Frey, Wolfgang}, year={2003}, pages={425–431} }","apa":"Christoffers, J., Werner, T., Unger, S., &#38; Frey, W. (2003). Preparation of Acyloins by Cerium-Catalyzed, Direct Hydroxylation of β-Dicarbonyl Compounds with Molecular Oxygen. <i>European Journal of Organic Chemistry</i>, <i>2003</i>(3), 425–431. <a href=\"https://doi.org/10.1002/ejoc.200390075\">https://doi.org/10.1002/ejoc.200390075</a>","ieee":"J. Christoffers, T. Werner, S. Unger, and W. Frey, “Preparation of Acyloins by Cerium-Catalyzed, Direct Hydroxylation of β-Dicarbonyl Compounds with Molecular Oxygen,” <i>European Journal of Organic Chemistry</i>, vol. 2003, no. 3, pp. 425–431, 2003, doi: <a href=\"https://doi.org/10.1002/ejoc.200390075\">10.1002/ejoc.200390075</a>.","chicago":"Christoffers, Jens, Thomas Werner, Sven Unger, and Wolfgang Frey. “Preparation of Acyloins by Cerium-Catalyzed, Direct Hydroxylation of β-Dicarbonyl Compounds with Molecular Oxygen.” <i>European Journal of Organic Chemistry</i> 2003, no. 3 (2003): 425–31. <a href=\"https://doi.org/10.1002/ejoc.200390075\">https://doi.org/10.1002/ejoc.200390075</a>.","short":"J. Christoffers, T. Werner, S. Unger, W. Frey, European Journal of Organic Chemistry 2003 (2003) 425–431."},"language":[{"iso":"eng"}],"doi":"10.1002/ejoc.200390075","author":[{"full_name":"Christoffers, Jens","first_name":"Jens","last_name":"Christoffers"},{"id":"89271","full_name":"Werner, Thomas","last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244"},{"last_name":"Unger","first_name":"Sven","full_name":"Unger, Sven"},{"first_name":"Wolfgang","last_name":"Frey","full_name":"Frey, Wolfgang"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"year":"2003","title":"Preparation of Acyloins by Cerium-Catalyzed, Direct Hydroxylation of β-Dicarbonyl Compounds with Molecular Oxygen","intvolume":"      2003","publication_status":"published","date_updated":"2025-11-10T09:46:23Z","date_created":"2023-01-22T21:16:45Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"publication":"European Journal of Organic Chemistry","issue":"3","extern":"1"},{"status":"public","page":"701-705","_id":"38022","publisher":"Wiley","user_id":"89271","volume":2000,"citation":{"ieee":"J. Christoffers, U. Rößler, and T. Werner, “Construction of Quaternary Stereocenters by Nickel-Catalysis of Asymmetric Michael Reactions,” <i>European Journal of Organic Chemistry</i>, vol. 2000, no. 5, pp. 701–705, 2000, doi: <a href=\"https://doi.org/10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5\">10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5</a>.","apa":"Christoffers, J., Rößler, U., &#38; Werner, T. (2000). Construction of Quaternary Stereocenters by Nickel-Catalysis of Asymmetric Michael Reactions. <i>European Journal of Organic Chemistry</i>, <i>2000</i>(5), 701–705. <a href=\"https://doi.org/10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5\">https://doi.org/10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5</a>","chicago":"Christoffers, Jens, Ulrich Rößler, and Thomas Werner. “Construction of Quaternary Stereocenters by Nickel-Catalysis of Asymmetric Michael Reactions.” <i>European Journal of Organic Chemistry</i> 2000, no. 5 (2000): 701–5. <a href=\"https://doi.org/10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5\">https://doi.org/10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5</a>.","short":"J. Christoffers, U. Rößler, T. Werner, European Journal of Organic Chemistry 2000 (2000) 701–705.","mla":"Christoffers, Jens, et al. “Construction of Quaternary Stereocenters by Nickel-Catalysis of Asymmetric Michael Reactions.” <i>European Journal of Organic Chemistry</i>, vol. 2000, no. 5, Wiley, 2000, pp. 701–05, doi:<a href=\"https://doi.org/10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5\">10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5</a>.","bibtex":"@article{Christoffers_Rößler_Werner_2000, title={Construction of Quaternary Stereocenters by Nickel-Catalysis of Asymmetric Michael Reactions}, volume={2000}, DOI={<a href=\"https://doi.org/10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5\">10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5</a>}, number={5}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Christoffers, Jens and Rößler, Ulrich and Werner, Thomas}, year={2000}, pages={701–705} }","ama":"Christoffers J, Rößler U, Werner T. Construction of Quaternary Stereocenters by Nickel-Catalysis of Asymmetric Michael Reactions. <i>European Journal of Organic Chemistry</i>. 2000;2000(5):701-705. doi:<a href=\"https://doi.org/10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5\">10.1002/(sici)1099-0690(200003)2000:5&#60;701::aid-ejoc701&#62;3.0.co;2-5</a>"},"year":"2000","title":"Construction of Quaternary Stereocenters by Nickel-Catalysis of Asymmetric Michael Reactions","author":[{"first_name":"Jens","last_name":"Christoffers","full_name":"Christoffers, Jens"},{"last_name":"Rößler","first_name":"Ulrich","full_name":"Rößler, Ulrich"},{"first_name":"Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244","full_name":"Werner, Thomas","id":"89271"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"publication_status":"published","date_updated":"2025-11-10T09:47:09Z","intvolume":"      2000","language":[{"iso":"eng"}],"doi":"10.1002/(sici)1099-0690(200003)2000:5<701::aid-ejoc701>3.0.co;2-5","issue":"5","publication":"European Journal of Organic Chemistry","extern":"1","date_created":"2023-01-22T21:18:00Z","keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"type":"journal_article","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}]}]