---
_id: '56265'
abstract:
- lang: eng
  text: The metal-organic framework CPO-27 exhibits free coordination sites (open
    metal sites) and can be prepared with a wide range of metals that influence its
    properties. It is therefore an intriguing structure to study sorption phenomena.
    We analyze the water resistance and sorption behavior of these frameworks, with
    particular attention to the sorption mechanism in detail and the structure of
    the confined water molecules. For this purpose, we use manometric water vapor
    sorption analysis and FTIR spectroscopy. The respective metal center orchestrates
    both the adsorption behavior and the arrangement of the water molecules in the
    micropores of the framework. The extent to which water molecules form hydrogen
    bonds (with each other and with framework oxygen atoms) plays a crucial role in
    the stability of the framework towards water. Water adsorption is governed by
    the coordination of water molecules to the open metal sites (except for CPO-27-Cu)
    and subsequent H-bonding. A stepwise adsorption of water is observed, with significant
    differences depending on the choice of metal.
author:
- first_name: Marvin
  full_name: Kloß, Marvin
  last_name: Kloß
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: 'Kloß M, Weinberger C, Tiemann M. Water in the Micropores of CPO-27 Metal-Organic
    Frameworks: A Comprehensive Study. <i>Microporous and Mesoporous Materials</i>.
    2025;381:113352. doi:<a href="https://doi.org/10.1016/j.micromeso.2024.113352">10.1016/j.micromeso.2024.113352</a>'
  apa: 'Kloß, M., Weinberger, C., &#38; Tiemann, M. (2025). Water in the Micropores
    of CPO-27 Metal-Organic Frameworks: A Comprehensive Study. <i>Microporous and
    Mesoporous Materials</i>, <i>381</i>, 113352. <a href="https://doi.org/10.1016/j.micromeso.2024.113352">https://doi.org/10.1016/j.micromeso.2024.113352</a>'
  bibtex: '@article{Kloß_Weinberger_Tiemann_2025, title={Water in the Micropores of
    CPO-27 Metal-Organic Frameworks: A Comprehensive Study}, volume={381}, DOI={<a
    href="https://doi.org/10.1016/j.micromeso.2024.113352">10.1016/j.micromeso.2024.113352</a>},
    journal={Microporous and Mesoporous Materials}, publisher={Elsevier BV}, author={Kloß,
    Marvin and Weinberger, Christian and Tiemann, Michael}, year={2025}, pages={113352}
    }'
  chicago: 'Kloß, Marvin, Christian Weinberger, and Michael Tiemann. “Water in the
    Micropores of CPO-27 Metal-Organic Frameworks: A Comprehensive Study.” <i>Microporous
    and Mesoporous Materials</i> 381 (2025): 113352. <a href="https://doi.org/10.1016/j.micromeso.2024.113352">https://doi.org/10.1016/j.micromeso.2024.113352</a>.'
  ieee: 'M. Kloß, C. Weinberger, and M. Tiemann, “Water in the Micropores of CPO-27
    Metal-Organic Frameworks: A Comprehensive Study,” <i>Microporous and Mesoporous
    Materials</i>, vol. 381, p. 113352, 2025, doi: <a href="https://doi.org/10.1016/j.micromeso.2024.113352">10.1016/j.micromeso.2024.113352</a>.'
  mla: 'Kloß, Marvin, et al. “Water in the Micropores of CPO-27 Metal-Organic Frameworks:
    A Comprehensive Study.” <i>Microporous and Mesoporous Materials</i>, vol. 381,
    Elsevier BV, 2025, p. 113352, doi:<a href="https://doi.org/10.1016/j.micromeso.2024.113352">10.1016/j.micromeso.2024.113352</a>.'
  short: M. Kloß, C. Weinberger, M. Tiemann, Microporous and Mesoporous Materials
    381 (2025) 113352.
date_created: 2024-09-27T08:40:43Z
date_updated: 2024-11-11T07:48:04Z
doi: 10.1016/j.micromeso.2024.113352
intvolume: '       381'
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
page: '113352'
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
publisher: Elsevier BV
status: public
title: 'Water in the Micropores of CPO-27 Metal-Organic Frameworks: A Comprehensive
  Study'
type: journal_article
user_id: '23547'
volume: 381
year: '2025'
...
---
_id: '25894'
abstract:
- lang: eng
  text: Powder X-ray diffraction (XRD) patterns of ordered mesoporous CMK-8 and CMK-9
    carbon materials are simulated by geometric modeling. The materials are amorphous
    at the atomic length scale but exhibit highly symmetric gyroidal structures at
    the nanometer scale, corresponding to regular, continuous nanopore systems with
    cubic symmetry. Their structures lead to characteristic low-angle XRD signatures.
    We introduce a model based on geometrical considerations to simulate CMK-8 and
    CMK-9 structures with variable volume fraction of carbon (vs. pore volume, i.e.,
    variable 'pore wall thickness'). In addition, we also simulate carbon materials
    with variable amounts of guest species (e.g., sulfur) residing in their pores.
    The corresponding XRD patterns are calculated. The carbon volume fraction turns
    out to have a significant impact on the relative diffraction peak intensities,
    especially in case of CMK-9 carbon that features a bimodal porosity. Likewise,
    the presence of guest species in the pores may also strongly affect the relative
    peak intensities. Our study suggests that careful evaluation of experimental low-angle
    XRD patterns of (real) CMK-8 or CMK-9 materials offers an opportunity to obtain
    detailed information about the nanostructural properties in addition to the mere
    identification of the pore systems geometry.
article_number: '110330'
article_type: original
author:
- first_name: Bertram
  full_name: Schwind, Bertram
  last_name: Schwind
- first_name: Jan-Henrik
  full_name: Smått, Jan-Henrik
  last_name: Smått
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
citation:
  ama: Schwind B, Smått J-H, Tiemann M, Weinberger C. Modeling of gyroidal mesoporous
    CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns. <i>Microporous
    and Mesoporous Materials</i>. Published online 2021. doi:<a href="https://doi.org/10.1016/j.micromeso.2020.110330">10.1016/j.micromeso.2020.110330</a>
  apa: Schwind, B., Smått, J.-H., Tiemann, M., &#38; Weinberger, C. (2021). Modeling
    of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction
    patterns. <i>Microporous and Mesoporous Materials</i>, Article 110330. <a href="https://doi.org/10.1016/j.micromeso.2020.110330">https://doi.org/10.1016/j.micromeso.2020.110330</a>
  bibtex: '@article{Schwind_Smått_Tiemann_Weinberger_2021, title={Modeling of gyroidal
    mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns},
    DOI={<a href="https://doi.org/10.1016/j.micromeso.2020.110330">10.1016/j.micromeso.2020.110330</a>},
    number={110330}, journal={Microporous and Mesoporous Materials}, author={Schwind,
    Bertram and Smått, Jan-Henrik and Tiemann, Michael and Weinberger, Christian},
    year={2021} }'
  chicago: Schwind, Bertram, Jan-Henrik Smått, Michael Tiemann, and Christian Weinberger.
    “Modeling of Gyroidal Mesoporous CMK-8 and CMK-9 Carbon Nanostructures and Their
    X-Ray Diffraction Patterns.” <i>Microporous and Mesoporous Materials</i>, 2021.
    <a href="https://doi.org/10.1016/j.micromeso.2020.110330">https://doi.org/10.1016/j.micromeso.2020.110330</a>.
  ieee: 'B. Schwind, J.-H. Smått, M. Tiemann, and C. Weinberger, “Modeling of gyroidal
    mesoporous CMK-8 and CMK-9 carbon nanostructures and their X-Ray diffraction patterns,”
    <i>Microporous and Mesoporous Materials</i>, Art. no. 110330, 2021, doi: <a href="https://doi.org/10.1016/j.micromeso.2020.110330">10.1016/j.micromeso.2020.110330</a>.'
  mla: Schwind, Bertram, et al. “Modeling of Gyroidal Mesoporous CMK-8 and CMK-9 Carbon
    Nanostructures and Their X-Ray Diffraction Patterns.” <i>Microporous and Mesoporous
    Materials</i>, 110330, 2021, doi:<a href="https://doi.org/10.1016/j.micromeso.2020.110330">10.1016/j.micromeso.2020.110330</a>.
  short: B. Schwind, J.-H. Smått, M. Tiemann, C. Weinberger, Microporous and Mesoporous
    Materials (2021).
date_created: 2021-10-08T10:02:31Z
date_updated: 2023-03-07T10:44:44Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2020.110330
language:
- iso: eng
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: Modeling of gyroidal mesoporous CMK-8 and CMK-9 carbon nanostructures and their
  X-Ray diffraction patterns
type: journal_article
user_id: '23547'
year: '2021'
...
---
_id: '25912'
abstract:
- lang: eng
  text: It is possible to infiltrate a guest species selectively in one pore system
    of bimodal mesoporous CMK-5 carbon by an optimized nanocasting procedure. The
    selective filling has a drastic impact on the low-angle X-ray diffraction pattern
    of this novel class of materials. The structures of CMK-5, CMK-5 composite materials
    (sulfur and SnO2 as guest species), and CMK-3 carbon were simulated to investigate
    the influence of the pore filling with different guest species on the diffraction
    pattern and compared with experimental results. Additionally, the impact of structural
    defects is taken into account. The nature of the guest species strongly influences
    the relative intensity of the diffraction peaks. It turns out that the diffraction
    patterns of sulfur-carbon composite materials are nearly identical as those of
    CMK-3 carbon, which is attributed to a similar electron density of carbon and
    sulfur. Thus, sulfur is an ideal guest species to investigate the selective pore
    filling in CMK-5 carbon.
article_type: original
author:
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Marc
  full_name: Hartmann, Marc
  last_name: Hartmann
- first_name: Sai
  full_name: Ren, Sai
  last_name: Ren
- first_name: Thomas
  full_name: Sandberg, Thomas
  last_name: Sandberg
- first_name: Jan-Henrik
  full_name: Smått, Jan-Henrik
  last_name: Smått
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: 'Weinberger C, Hartmann M, Ren S, Sandberg T, Smått J-H, Tiemann M. Selective
    pore filling of mesoporous CMK-5 carbon studied by XRD: Comparison between theoretical
    simulations and experimental results. <i>Microporous and Mesoporous Materials</i>.
    Published online 2018:24-31. doi:<a href="https://doi.org/10.1016/j.micromeso.2018.02.035">10.1016/j.micromeso.2018.02.035</a>'
  apa: 'Weinberger, C., Hartmann, M., Ren, S., Sandberg, T., Smått, J.-H., &#38; Tiemann,
    M. (2018). Selective pore filling of mesoporous CMK-5 carbon studied by XRD: Comparison
    between theoretical simulations and experimental results. <i>Microporous and Mesoporous
    Materials</i>, 24–31. <a href="https://doi.org/10.1016/j.micromeso.2018.02.035">https://doi.org/10.1016/j.micromeso.2018.02.035</a>'
  bibtex: '@article{Weinberger_Hartmann_Ren_Sandberg_Smått_Tiemann_2018, title={Selective
    pore filling of mesoporous CMK-5 carbon studied by XRD: Comparison between theoretical
    simulations and experimental results}, DOI={<a href="https://doi.org/10.1016/j.micromeso.2018.02.035">10.1016/j.micromeso.2018.02.035</a>},
    journal={Microporous and Mesoporous Materials}, author={Weinberger, Christian
    and Hartmann, Marc and Ren, Sai and Sandberg, Thomas and Smått, Jan-Henrik and
    Tiemann, Michael}, year={2018}, pages={24–31} }'
  chicago: 'Weinberger, Christian, Marc Hartmann, Sai Ren, Thomas Sandberg, Jan-Henrik
    Smått, and Michael Tiemann. “Selective Pore Filling of Mesoporous CMK-5 Carbon
    Studied by XRD: Comparison between Theoretical Simulations and Experimental Results.”
    <i>Microporous and Mesoporous Materials</i>, 2018, 24–31. <a href="https://doi.org/10.1016/j.micromeso.2018.02.035">https://doi.org/10.1016/j.micromeso.2018.02.035</a>.'
  ieee: 'C. Weinberger, M. Hartmann, S. Ren, T. Sandberg, J.-H. Smått, and M. Tiemann,
    “Selective pore filling of mesoporous CMK-5 carbon studied by XRD: Comparison
    between theoretical simulations and experimental results,” <i>Microporous and
    Mesoporous Materials</i>, pp. 24–31, 2018, doi: <a href="https://doi.org/10.1016/j.micromeso.2018.02.035">10.1016/j.micromeso.2018.02.035</a>.'
  mla: 'Weinberger, Christian, et al. “Selective Pore Filling of Mesoporous CMK-5
    Carbon Studied by XRD: Comparison between Theoretical Simulations and Experimental
    Results.” <i>Microporous and Mesoporous Materials</i>, 2018, pp. 24–31, doi:<a
    href="https://doi.org/10.1016/j.micromeso.2018.02.035">10.1016/j.micromeso.2018.02.035</a>.'
  short: C. Weinberger, M. Hartmann, S. Ren, T. Sandberg, J.-H. Smått, M. Tiemann,
    Microporous and Mesoporous Materials (2018) 24–31.
date_created: 2021-10-08T10:51:20Z
date_updated: 2023-03-08T10:21:04Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2018.02.035
language:
- iso: eng
page: 24-31
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: 'Selective pore filling of mesoporous CMK-5 carbon studied by XRD: Comparison
  between theoretical simulations and experimental results'
type: journal_article
user_id: '23547'
year: '2018'
...
---
_id: '25919'
abstract:
- lang: eng
  text: The sorption properties of mixed-linker CAU-10 type metal organic frameworks
    (MOFs), [Al(OH)(1,3-BDC-X)n(1,3-BDC-SO3H)m] with 1,3-BDC = 1,3-benzenedicarboxyliate,
    X = H, NO2 or OH, 0.76 ≤ n ≤ 0.89 and 0.11 ≤ m ≤ 0.24, can be varied by surface
    modification through variation of the respective linker molecules. It is thus
    possible to design surface-modified CAU-10 type MOFs with variable affinity and
    accessibility of the pores for water vapour. When used as a dielectric in a capacitor,
    the MOF material will change its permittivity depending on the amount of physisorbed
    water; this is the working principle of capacitive humidity sensors. Three different
    mixed-linker compounds with CAU-10 structure are compared regarding their water
    sorption and impedance characteristics. A setup was developed allowing the characterization
    of the MOF samples under exposure to different relative humidity values in air
    by impedance spectroscopy. Interpretation of the results by means of standard
    models shows that the MOFs are qualified for functional layers of capacitive humidity
    sensors. Since the prepared MOFs are more temperature-stable than many commonly
    used polymers they offer the potential to build a new generation of high-temperature
    (up to 350 °C) humidity sensors.
article_type: original
author:
- first_name: Alexander
  full_name: Weiss, Alexander
  last_name: Weiss
- first_name: Nele
  full_name: Reimer, Nele
  last_name: Reimer
- first_name: Norbert
  full_name: Stock, Norbert
  last_name: Stock
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Thorsten
  full_name: Wagner, Thorsten
  last_name: Wagner
citation:
  ama: Weiss A, Reimer N, Stock N, Tiemann M, Wagner T. Screening of mixed-linker
    CAU-10 MOF materials for humidity sensing by impedance spectroscopy. <i>Microporous
    and Mesoporous Materials</i>. Published online 2016:39-43. doi:<a href="https://doi.org/10.1016/j.micromeso.2015.08.020">10.1016/j.micromeso.2015.08.020</a>
  apa: Weiss, A., Reimer, N., Stock, N., Tiemann, M., &#38; Wagner, T. (2016). Screening
    of mixed-linker CAU-10 MOF materials for humidity sensing by impedance spectroscopy.
    <i>Microporous and Mesoporous Materials</i>, 39–43. <a href="https://doi.org/10.1016/j.micromeso.2015.08.020">https://doi.org/10.1016/j.micromeso.2015.08.020</a>
  bibtex: '@article{Weiss_Reimer_Stock_Tiemann_Wagner_2016, title={Screening of mixed-linker
    CAU-10 MOF materials for humidity sensing by impedance spectroscopy}, DOI={<a
    href="https://doi.org/10.1016/j.micromeso.2015.08.020">10.1016/j.micromeso.2015.08.020</a>},
    journal={Microporous and Mesoporous Materials}, author={Weiss, Alexander and Reimer,
    Nele and Stock, Norbert and Tiemann, Michael and Wagner, Thorsten}, year={2016},
    pages={39–43} }'
  chicago: Weiss, Alexander, Nele Reimer, Norbert Stock, Michael Tiemann, and Thorsten
    Wagner. “Screening of Mixed-Linker CAU-10 MOF Materials for Humidity Sensing by
    Impedance Spectroscopy.” <i>Microporous and Mesoporous Materials</i>, 2016, 39–43.
    <a href="https://doi.org/10.1016/j.micromeso.2015.08.020">https://doi.org/10.1016/j.micromeso.2015.08.020</a>.
  ieee: 'A. Weiss, N. Reimer, N. Stock, M. Tiemann, and T. Wagner, “Screening of mixed-linker
    CAU-10 MOF materials for humidity sensing by impedance spectroscopy,” <i>Microporous
    and Mesoporous Materials</i>, pp. 39–43, 2016, doi: <a href="https://doi.org/10.1016/j.micromeso.2015.08.020">10.1016/j.micromeso.2015.08.020</a>.'
  mla: Weiss, Alexander, et al. “Screening of Mixed-Linker CAU-10 MOF Materials for
    Humidity Sensing by Impedance Spectroscopy.” <i>Microporous and Mesoporous Materials</i>,
    2016, pp. 39–43, doi:<a href="https://doi.org/10.1016/j.micromeso.2015.08.020">10.1016/j.micromeso.2015.08.020</a>.
  short: A. Weiss, N. Reimer, N. Stock, M. Tiemann, T. Wagner, Microporous and Mesoporous
    Materials (2016) 39–43.
date_created: 2021-10-08T11:10:33Z
date_updated: 2023-03-08T10:27:01Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2015.08.020
language:
- iso: eng
page: 39-43
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: Screening of mixed-linker CAU-10 MOF materials for humidity sensing by impedance
  spectroscopy
type: journal_article
user_id: '23547'
year: '2016'
...
---
_id: '25918'
abstract:
- lang: eng
  text: Characterization and application of (meso)porous materials often require information
    about the density of the respective samples. For example, the BET surface area
    is, by definition, normalized to the sample mass; hence, any comparison between
    samples of different composition needs to take into account their respective densities.
    Literature data on the densities of porous materials are scarce. Frequently, only
    bulk-phase densities are available which sometimes differ from those of porous
    samples, especially for amorphous systems, such as silica or carbon. The apparent
    density, i.e. the density of the sample excluding the gas-accessible pore volume,
    is typically determined by helium gas pycnometry utilizing specialized pycnometers.
    We demonstrate how to obtain the same data from standard N2 physisorption measurements
    as part of the regular measurement routine. We evaluate the method by reference
    measurements utilizing a non-porous reference sample (glass rod) to confirm the
    validity of the method. Then we present results on apparent density measurements
    of several mesoporous silica materials (MCM-41, MCM-48, SBA-15, KIT-6), mesoporous
    carbon (CMK-3, -5, -8, -9), and a variety of mesoporous metal oxides obtained
    by nanocasting.
article_type: original
author:
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Simon
  full_name: Vetter, Simon
  last_name: Vetter
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Thorsten
  full_name: Wagner, Thorsten
  last_name: Wagner
citation:
  ama: Weinberger C, Vetter S, Tiemann M, Wagner T. Assessment of the density of (meso)porous
    materials from standard volumetric physisorption data. <i>Microporous and Mesoporous
    Materials</i>. Published online 2016:53-57. doi:<a href="https://doi.org/10.1016/j.micromeso.2015.10.027">10.1016/j.micromeso.2015.10.027</a>
  apa: Weinberger, C., Vetter, S., Tiemann, M., &#38; Wagner, T. (2016). Assessment
    of the density of (meso)porous materials from standard volumetric physisorption
    data. <i>Microporous and Mesoporous Materials</i>, 53–57. <a href="https://doi.org/10.1016/j.micromeso.2015.10.027">https://doi.org/10.1016/j.micromeso.2015.10.027</a>
  bibtex: '@article{Weinberger_Vetter_Tiemann_Wagner_2016, title={Assessment of the
    density of (meso)porous materials from standard volumetric physisorption data},
    DOI={<a href="https://doi.org/10.1016/j.micromeso.2015.10.027">10.1016/j.micromeso.2015.10.027</a>},
    journal={Microporous and Mesoporous Materials}, author={Weinberger, Christian
    and Vetter, Simon and Tiemann, Michael and Wagner, Thorsten}, year={2016}, pages={53–57}
    }'
  chicago: Weinberger, Christian, Simon Vetter, Michael Tiemann, and Thorsten Wagner.
    “Assessment of the Density of (Meso)Porous Materials from Standard Volumetric
    Physisorption Data.” <i>Microporous and Mesoporous Materials</i>, 2016, 53–57.
    <a href="https://doi.org/10.1016/j.micromeso.2015.10.027">https://doi.org/10.1016/j.micromeso.2015.10.027</a>.
  ieee: 'C. Weinberger, S. Vetter, M. Tiemann, and T. Wagner, “Assessment of the density
    of (meso)porous materials from standard volumetric physisorption data,” <i>Microporous
    and Mesoporous Materials</i>, pp. 53–57, 2016, doi: <a href="https://doi.org/10.1016/j.micromeso.2015.10.027">10.1016/j.micromeso.2015.10.027</a>.'
  mla: Weinberger, Christian, et al. “Assessment of the Density of (Meso)Porous Materials
    from Standard Volumetric Physisorption Data.” <i>Microporous and Mesoporous Materials</i>,
    2016, pp. 53–57, doi:<a href="https://doi.org/10.1016/j.micromeso.2015.10.027">10.1016/j.micromeso.2015.10.027</a>.
  short: C. Weinberger, S. Vetter, M. Tiemann, T. Wagner, Microporous and Mesoporous
    Materials (2016) 53–57.
date_created: 2021-10-08T11:09:42Z
date_updated: 2023-03-08T10:27:33Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2015.10.027
language:
- iso: eng
page: 53-57
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: Assessment of the density of (meso)porous materials from standard volumetric
  physisorption data
type: journal_article
user_id: '23547'
year: '2016'
...
---
_id: '41224'
author:
- first_name: E.
  full_name: Keceli, E.
  last_name: Keceli
- first_name: M.
  full_name: Hemgesberg, M.
  last_name: Hemgesberg
- first_name: R.
  full_name: Grünker, R.
  last_name: Grünker
- first_name: V.
  full_name: Bon, V.
  last_name: Bon
- first_name: C.
  full_name: Wilhelm, C.
  last_name: Wilhelm
- first_name: T.
  full_name: Philippi, T.
  last_name: Philippi
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Y.
  full_name: Sun, Y.
  last_name: Sun
- first_name: Matthias
  full_name: Bauer, Matthias
  id: '47241'
  last_name: Bauer
  orcid: 0000-0002-9294-6076
- first_name: S.
  full_name: Ernst, S.
  last_name: Ernst
- first_name: S.
  full_name: Kaskel, S.
  last_name: Kaskel
- first_name: Werner R.
  full_name: Thiel, Werner R.
  last_name: Thiel
citation:
  ama: Keceli E, Hemgesberg M, Grünker R, et al. A series of amide functionalized
    isoreticular metal organic frameworks. <i>Microporous and Mesoporous Materials</i>.
    2014;194:115-125. doi:<a href="https://doi.org/10.1016/j.micromeso.2014.03.022">10.1016/j.micromeso.2014.03.022</a>
  apa: Keceli, E., Hemgesberg, M., Grünker, R., Bon, V., Wilhelm, C., Philippi, T.,
    Schoch, R., Sun, Y., Bauer, M., Ernst, S., Kaskel, S., &#38; Thiel, W. R. (2014).
    A series of amide functionalized isoreticular metal organic frameworks. <i>Microporous
    and Mesoporous Materials</i>, <i>194</i>, 115–125. <a href="https://doi.org/10.1016/j.micromeso.2014.03.022">https://doi.org/10.1016/j.micromeso.2014.03.022</a>
  bibtex: '@article{Keceli_Hemgesberg_Grünker_Bon_Wilhelm_Philippi_Schoch_Sun_Bauer_Ernst_et
    al._2014, title={A series of amide functionalized isoreticular metal organic frameworks},
    volume={194}, DOI={<a href="https://doi.org/10.1016/j.micromeso.2014.03.022">10.1016/j.micromeso.2014.03.022</a>},
    journal={Microporous and Mesoporous Materials}, publisher={Elsevier BV}, author={Keceli,
    E. and Hemgesberg, M. and Grünker, R. and Bon, V. and Wilhelm, C. and Philippi,
    T. and Schoch, Roland and Sun, Y. and Bauer, Matthias and Ernst, S. and et al.},
    year={2014}, pages={115–125} }'
  chicago: 'Keceli, E., M. Hemgesberg, R. Grünker, V. Bon, C. Wilhelm, T. Philippi,
    Roland Schoch, et al. “A Series of Amide Functionalized Isoreticular Metal Organic
    Frameworks.” <i>Microporous and Mesoporous Materials</i> 194 (2014): 115–25. <a
    href="https://doi.org/10.1016/j.micromeso.2014.03.022">https://doi.org/10.1016/j.micromeso.2014.03.022</a>.'
  ieee: 'E. Keceli <i>et al.</i>, “A series of amide functionalized isoreticular metal
    organic frameworks,” <i>Microporous and Mesoporous Materials</i>, vol. 194, pp.
    115–125, 2014, doi: <a href="https://doi.org/10.1016/j.micromeso.2014.03.022">10.1016/j.micromeso.2014.03.022</a>.'
  mla: Keceli, E., et al. “A Series of Amide Functionalized Isoreticular Metal Organic
    Frameworks.” <i>Microporous and Mesoporous Materials</i>, vol. 194, Elsevier BV,
    2014, pp. 115–25, doi:<a href="https://doi.org/10.1016/j.micromeso.2014.03.022">10.1016/j.micromeso.2014.03.022</a>.
  short: E. Keceli, M. Hemgesberg, R. Grünker, V. Bon, C. Wilhelm, T. Philippi, R.
    Schoch, Y. Sun, M. Bauer, S. Ernst, S. Kaskel, W.R. Thiel, Microporous and Mesoporous
    Materials 194 (2014) 115–125.
date_created: 2023-01-31T14:45:24Z
date_updated: 2023-01-31T14:48:17Z
department:
- _id: '306'
doi: 10.1016/j.micromeso.2014.03.022
intvolume: '       194'
keyword:
- Mechanics of Materials
- Condensed Matter Physics
- General Materials Science
- General Chemistry
language:
- iso: eng
page: 115-125
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
publisher: Elsevier BV
status: public
title: A series of amide functionalized isoreticular metal organic frameworks
type: journal_article
user_id: '48467'
volume: 194
year: '2014'
...
---
_id: '25946'
abstract:
- lang: eng
  text: The synthesis of a periodically ordered, nanostructured composite consisting
    of CoFe2O4 and BaTiO3 is presented. In a first step, mesoporous CoFe2O4 is prepared
    by the structure replication method (nanocasting) using mesoporous KIT-6 silica
    as a structural mold. Subsequently, BaTiO3 is created inside the pores of CoFe2O4
    by the citrate route, resulting in a well-ordered composite material of both phases.
    The two components are known for their distinct ferroic properties, namely ferrimagnetism
    (CoFe2O4) and ferroelectricity (BaTiO3), respectively. Therefore, this proof of
    synthesis concept offers new perspectives in the fabrication of composite materials
    with multiferroic properties.
article_type: original
author:
- first_name: Stefanie
  full_name: Haffer, Stefanie
  last_name: Haffer
- first_name: Christian
  full_name: Lüder, Christian
  last_name: Lüder
- first_name: Till
  full_name: Walther, Till
  last_name: Walther
- first_name: Roberto
  full_name: Köferstein, Roberto
  last_name: Köferstein
- first_name: Stefan G.
  full_name: Ebbinghaus, Stefan G.
  last_name: Ebbinghaus
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: 'Haffer S, Lüder C, Walther T, Köferstein R, Ebbinghaus SG, Tiemann M. A synthesis
    concept for a nanostructured CoFe2O4/BaTiO3 composite: Towards multiferroics.
    <i>Microporous and Mesoporous Materials</i>. Published online 2014:300-304. doi:<a
    href="https://doi.org/10.1016/j.micromeso.2014.05.023">10.1016/j.micromeso.2014.05.023</a>'
  apa: 'Haffer, S., Lüder, C., Walther, T., Köferstein, R., Ebbinghaus, S. G., &#38;
    Tiemann, M. (2014). A synthesis concept for a nanostructured CoFe2O4/BaTiO3 composite:
    Towards multiferroics. <i>Microporous and Mesoporous Materials</i>, 300–304. <a
    href="https://doi.org/10.1016/j.micromeso.2014.05.023">https://doi.org/10.1016/j.micromeso.2014.05.023</a>'
  bibtex: '@article{Haffer_Lüder_Walther_Köferstein_Ebbinghaus_Tiemann_2014, title={A
    synthesis concept for a nanostructured CoFe2O4/BaTiO3 composite: Towards multiferroics},
    DOI={<a href="https://doi.org/10.1016/j.micromeso.2014.05.023">10.1016/j.micromeso.2014.05.023</a>},
    journal={Microporous and Mesoporous Materials}, author={Haffer, Stefanie and Lüder,
    Christian and Walther, Till and Köferstein, Roberto and Ebbinghaus, Stefan G.
    and Tiemann, Michael}, year={2014}, pages={300–304} }'
  chicago: 'Haffer, Stefanie, Christian Lüder, Till Walther, Roberto Köferstein, Stefan
    G. Ebbinghaus, and Michael Tiemann. “A Synthesis Concept for a Nanostructured
    CoFe2O4/BaTiO3 Composite: Towards Multiferroics.” <i>Microporous and Mesoporous
    Materials</i>, 2014, 300–304. <a href="https://doi.org/10.1016/j.micromeso.2014.05.023">https://doi.org/10.1016/j.micromeso.2014.05.023</a>.'
  ieee: 'S. Haffer, C. Lüder, T. Walther, R. Köferstein, S. G. Ebbinghaus, and M.
    Tiemann, “A synthesis concept for a nanostructured CoFe2O4/BaTiO3 composite: Towards
    multiferroics,” <i>Microporous and Mesoporous Materials</i>, pp. 300–304, 2014,
    doi: <a href="https://doi.org/10.1016/j.micromeso.2014.05.023">10.1016/j.micromeso.2014.05.023</a>.'
  mla: 'Haffer, Stefanie, et al. “A Synthesis Concept for a Nanostructured CoFe2O4/BaTiO3
    Composite: Towards Multiferroics.” <i>Microporous and Mesoporous Materials</i>,
    2014, pp. 300–04, doi:<a href="https://doi.org/10.1016/j.micromeso.2014.05.023">10.1016/j.micromeso.2014.05.023</a>.'
  short: S. Haffer, C. Lüder, T. Walther, R. Köferstein, S.G. Ebbinghaus, M. Tiemann,
    Microporous and Mesoporous Materials (2014) 300–304.
date_created: 2021-10-08T15:54:53Z
date_updated: 2023-03-08T10:32:10Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2014.05.023
language:
- iso: eng
page: 300-304
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: 'A synthesis concept for a nanostructured CoFe2O4/BaTiO3 composite: Towards
  multiferroics'
type: journal_article
user_id: '23547'
year: '2014'
...
---
_id: '25948'
abstract:
- lang: eng
  text: Ordered mesoporous silica phases (e.g. KIT-6, SBA-15) are used as structure
    matrices for negative replica structures of mesoporous In2O3. We present a detailed
    study on how the controlled synthesis of mono-, bi- and trimodal pore systems
    in the products is accomplished by systematic variation of the procedure of infiltrating
    a precursor species (In(NO3)3) into the pores of the silica matrix and subsequent
    thermal conversion into In2O3. Melt impregnation and conversion in a closed reactor
    facilitates a one-step casting process for ordered mesoporous indium oxide (In2O3).
    We present a model based on variation of the pore filling.
article_type: original
author:
- first_name: Dominik
  full_name: Klaus, Dominik
  last_name: Klaus
- first_name: Sabrina
  full_name: Amrehn, Sabrina
  last_name: Amrehn
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Thorsten
  full_name: Wagner, Thorsten
  last_name: Wagner
citation:
  ama: 'Klaus D, Amrehn S, Tiemann M, Wagner T. One-step synthesis of multi-modal
    pore systems in mesoporous In2O3: A detailed study. <i>Microporous and Mesoporous
    Materials</i>. Published online 2014:133-139. doi:<a href="https://doi.org/10.1016/j.micromeso.2014.01.007">10.1016/j.micromeso.2014.01.007</a>'
  apa: 'Klaus, D., Amrehn, S., Tiemann, M., &#38; Wagner, T. (2014). One-step synthesis
    of multi-modal pore systems in mesoporous In2O3: A detailed study. <i>Microporous
    and Mesoporous Materials</i>, 133–139. <a href="https://doi.org/10.1016/j.micromeso.2014.01.007">https://doi.org/10.1016/j.micromeso.2014.01.007</a>'
  bibtex: '@article{Klaus_Amrehn_Tiemann_Wagner_2014, title={One-step synthesis of
    multi-modal pore systems in mesoporous In2O3: A detailed study}, DOI={<a href="https://doi.org/10.1016/j.micromeso.2014.01.007">10.1016/j.micromeso.2014.01.007</a>},
    journal={Microporous and Mesoporous Materials}, author={Klaus, Dominik and Amrehn,
    Sabrina and Tiemann, Michael and Wagner, Thorsten}, year={2014}, pages={133–139}
    }'
  chicago: 'Klaus, Dominik, Sabrina Amrehn, Michael Tiemann, and Thorsten Wagner.
    “One-Step Synthesis of Multi-Modal Pore Systems in Mesoporous In2O3: A Detailed
    Study.” <i>Microporous and Mesoporous Materials</i>, 2014, 133–39. <a href="https://doi.org/10.1016/j.micromeso.2014.01.007">https://doi.org/10.1016/j.micromeso.2014.01.007</a>.'
  ieee: 'D. Klaus, S. Amrehn, M. Tiemann, and T. Wagner, “One-step synthesis of multi-modal
    pore systems in mesoporous In2O3: A detailed study,” <i>Microporous and Mesoporous
    Materials</i>, pp. 133–139, 2014, doi: <a href="https://doi.org/10.1016/j.micromeso.2014.01.007">10.1016/j.micromeso.2014.01.007</a>.'
  mla: 'Klaus, Dominik, et al. “One-Step Synthesis of Multi-Modal Pore Systems in
    Mesoporous In2O3: A Detailed Study.” <i>Microporous and Mesoporous Materials</i>,
    2014, pp. 133–39, doi:<a href="https://doi.org/10.1016/j.micromeso.2014.01.007">10.1016/j.micromeso.2014.01.007</a>.'
  short: D. Klaus, S. Amrehn, M. Tiemann, T. Wagner, Microporous and Mesoporous Materials
    (2014) 133–139.
date_created: 2021-10-08T15:56:54Z
date_updated: 2023-03-08T10:31:10Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2014.01.007
language:
- iso: eng
page: 133-139
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: 'One-step synthesis of multi-modal pore systems in mesoporous In2O3: A detailed
  study'
type: journal_article
user_id: '23547'
year: '2014'
...
---
_id: '25980'
abstract:
- lang: eng
  text: Mesoporous SBA-15 (space group p6mm), KIT-6 (Ia3d) and KIT-5 (Fm3m) silicas,
    exhibiting different 2-D and 3-D channel- or cage-like pore structure and pore
    dimensions have been used as supports for iron oxide nanoparticles. The iron modification
    of the silica was performed according to a frequently used impregnation technique
    from aqueous iron nitrate solution. The materials were characterized by nitrogen
    physisorption, X-ray diffraction, TEM–EDX, Moessbauer spectroscopy, and temperature-programmed
    reduction (TPR) and tested in the catalytic decomposition of methanol. It is established
    that the location and dispersion of iron oxide nanoparticles are affected by the
    pore topology of the support. The most homogeneously dispersed iron oxide nanoparticles
    are observed using silica host matrix exhibiting a 3-D channel-like structure
    and pore diameters about 7 nm, and the thus-obtained composites exhibit high catalytic
    activity and selectivity in methanol decomposition to CO and hydrogen. For all
    the samples, characterized with a low mesopore volume and small pore diameters/pore
    entrances, the formation of larger iron oxide particles, mainly located on the
    outer surface, is observed. Inhomogeneously dispersed iron oxide particles with
    a large fraction of isolated, strongly interacting with the support, iron species,
    and possessing low catalytic activity and usually high selectivity to methane,
    are found for the silicas with relatively larger pores/pore entrances.
article_type: original
author:
- first_name: Tanya
  full_name: Tsoncheva, Tanya
  last_name: Tsoncheva
- first_name: Jessica
  full_name: Rosenholm, Jessica
  last_name: Rosenholm
- first_name: Mika
  full_name: Linden, Mika
  last_name: Linden
- first_name: Freddy
  full_name: Kleitz, Freddy
  last_name: Kleitz
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Ljubomira
  full_name: Ivanova, Ljubomira
  last_name: Ivanova
- first_name: Momtchil
  full_name: Dimitrov, Momtchil
  last_name: Dimitrov
- first_name: Daniela
  full_name: Paneva, Daniela
  last_name: Paneva
- first_name: Ivan
  full_name: Mitov, Ivan
  last_name: Mitov
- first_name: Christo
  full_name: Minchev, Christo
  last_name: Minchev
citation:
  ama: Tsoncheva T, Rosenholm J, Linden M, et al. Critical evaluation of the state
    of iron oxide nanoparticles on different mesoporous silicas prepared by an impregnation
    method. <i>Microporous and Mesoporous Materials</i>. Published online 2008:327-337.
    doi:<a href="https://doi.org/10.1016/j.micromeso.2007.10.005">10.1016/j.micromeso.2007.10.005</a>
  apa: Tsoncheva, T., Rosenholm, J., Linden, M., Kleitz, F., Tiemann, M., Ivanova,
    L., Dimitrov, M., Paneva, D., Mitov, I., &#38; Minchev, C. (2008). Critical evaluation
    of the state of iron oxide nanoparticles on different mesoporous silicas prepared
    by an impregnation method. <i>Microporous and Mesoporous Materials</i>, 327–337.
    <a href="https://doi.org/10.1016/j.micromeso.2007.10.005">https://doi.org/10.1016/j.micromeso.2007.10.005</a>
  bibtex: '@article{Tsoncheva_Rosenholm_Linden_Kleitz_Tiemann_Ivanova_Dimitrov_Paneva_Mitov_Minchev_2008,
    title={Critical evaluation of the state of iron oxide nanoparticles on different
    mesoporous silicas prepared by an impregnation method}, DOI={<a href="https://doi.org/10.1016/j.micromeso.2007.10.005">10.1016/j.micromeso.2007.10.005</a>},
    journal={Microporous and Mesoporous Materials}, author={Tsoncheva, Tanya and Rosenholm,
    Jessica and Linden, Mika and Kleitz, Freddy and Tiemann, Michael and Ivanova,
    Ljubomira and Dimitrov, Momtchil and Paneva, Daniela and Mitov, Ivan and Minchev,
    Christo}, year={2008}, pages={327–337} }'
  chicago: Tsoncheva, Tanya, Jessica Rosenholm, Mika Linden, Freddy Kleitz, Michael
    Tiemann, Ljubomira Ivanova, Momtchil Dimitrov, Daniela Paneva, Ivan Mitov, and
    Christo Minchev. “Critical Evaluation of the State of Iron Oxide Nanoparticles
    on Different Mesoporous Silicas Prepared by an Impregnation Method.” <i>Microporous
    and Mesoporous Materials</i>, 2008, 327–37. <a href="https://doi.org/10.1016/j.micromeso.2007.10.005">https://doi.org/10.1016/j.micromeso.2007.10.005</a>.
  ieee: 'T. Tsoncheva <i>et al.</i>, “Critical evaluation of the state of iron oxide
    nanoparticles on different mesoporous silicas prepared by an impregnation method,”
    <i>Microporous and Mesoporous Materials</i>, pp. 327–337, 2008, doi: <a href="https://doi.org/10.1016/j.micromeso.2007.10.005">10.1016/j.micromeso.2007.10.005</a>.'
  mla: Tsoncheva, Tanya, et al. “Critical Evaluation of the State of Iron Oxide Nanoparticles
    on Different Mesoporous Silicas Prepared by an Impregnation Method.” <i>Microporous
    and Mesoporous Materials</i>, 2008, pp. 327–37, doi:<a href="https://doi.org/10.1016/j.micromeso.2007.10.005">10.1016/j.micromeso.2007.10.005</a>.
  short: T. Tsoncheva, J. Rosenholm, M. Linden, F. Kleitz, M. Tiemann, L. Ivanova,
    M. Dimitrov, D. Paneva, I. Mitov, C. Minchev, Microporous and Mesoporous Materials
    (2008) 327–337.
date_created: 2021-10-09T06:53:42Z
date_updated: 2023-03-09T08:44:27Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2007.10.005
extern: '1'
language:
- iso: eng
page: 327-337
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: Critical evaluation of the state of iron oxide nanoparticles on different mesoporous
  silicas prepared by an impregnation method
type: journal_article
user_id: '23547'
year: '2008'
...
---
_id: '25979'
abstract:
- lang: eng
  text: Various measures to optimise the impregnation of mesoporous CMK-3 carbon and
    SBA-15 silica matrices with metal nitrates for the synthesis of mesoporous metal
    oxides by structure replication are investigated. The effect of surface modification
    of the matrix pores, the choice of a solvent with suitable polarity, and the concentration
    of the metal nitrate solution are studied in detail. The efficiency of pore loading
    is monitored by nitrogen physisorption measurements. The creation of polar functions
    at the pore surface of CMK-3 carbon is shown to increase the impregnation efficiency
    substantially while maximizing the pore wall polarity of SBA-15 silica by increasing
    the amount of free silanol groups does not have any significant impact. The choice
    of a less polar solvent (THF instead of water) has a positive effect on the wettability
    of CMK-3 carbon in the first impregnation cycle but turns out to be disadvantageous
    in the second cycle; a similar trend is observed for variation of the metal salt
    concentration.
article_type: original
author:
- first_name: Jan
  full_name: Roggenbuck, Jan
  last_name: Roggenbuck
- first_name: Thomas
  full_name: Waitz, Thomas
  last_name: Waitz
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: 'Roggenbuck J, Waitz T, Tiemann M. Synthesis of mesoporous metal oxides by
    structure replication: Strategies of impregnating porous matrices with metal salts.
    <i>Microporous and Mesoporous Materials</i>. Published online 2008:575-582. doi:<a
    href="https://doi.org/10.1016/j.micromeso.2007.12.018">10.1016/j.micromeso.2007.12.018</a>'
  apa: 'Roggenbuck, J., Waitz, T., &#38; Tiemann, M. (2008). Synthesis of mesoporous
    metal oxides by structure replication: Strategies of impregnating porous matrices
    with metal salts. <i>Microporous and Mesoporous Materials</i>, 575–582. <a href="https://doi.org/10.1016/j.micromeso.2007.12.018">https://doi.org/10.1016/j.micromeso.2007.12.018</a>'
  bibtex: '@article{Roggenbuck_Waitz_Tiemann_2008, title={Synthesis of mesoporous
    metal oxides by structure replication: Strategies of impregnating porous matrices
    with metal salts}, DOI={<a href="https://doi.org/10.1016/j.micromeso.2007.12.018">10.1016/j.micromeso.2007.12.018</a>},
    journal={Microporous and Mesoporous Materials}, author={Roggenbuck, Jan and Waitz,
    Thomas and Tiemann, Michael}, year={2008}, pages={575–582} }'
  chicago: 'Roggenbuck, Jan, Thomas Waitz, and Michael Tiemann. “Synthesis of Mesoporous
    Metal Oxides by Structure Replication: Strategies of Impregnating Porous Matrices
    with Metal Salts.” <i>Microporous and Mesoporous Materials</i>, 2008, 575–82.
    <a href="https://doi.org/10.1016/j.micromeso.2007.12.018">https://doi.org/10.1016/j.micromeso.2007.12.018</a>.'
  ieee: 'J. Roggenbuck, T. Waitz, and M. Tiemann, “Synthesis of mesoporous metal oxides
    by structure replication: Strategies of impregnating porous matrices with metal
    salts,” <i>Microporous and Mesoporous Materials</i>, pp. 575–582, 2008, doi: <a
    href="https://doi.org/10.1016/j.micromeso.2007.12.018">10.1016/j.micromeso.2007.12.018</a>.'
  mla: 'Roggenbuck, Jan, et al. “Synthesis of Mesoporous Metal Oxides by Structure
    Replication: Strategies of Impregnating Porous Matrices with Metal Salts.” <i>Microporous
    and Mesoporous Materials</i>, 2008, pp. 575–82, doi:<a href="https://doi.org/10.1016/j.micromeso.2007.12.018">10.1016/j.micromeso.2007.12.018</a>.'
  short: J. Roggenbuck, T. Waitz, M. Tiemann, Microporous and Mesoporous Materials
    (2008) 575–582.
date_created: 2021-10-09T06:52:34Z
date_updated: 2023-03-09T08:46:47Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2007.12.018
extern: '1'
language:
- iso: eng
page: 575-582
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: 'Synthesis of mesoporous metal oxides by structure replication: Strategies
  of impregnating porous matrices with metal salts'
type: journal_article
user_id: '23547'
year: '2008'
...
---
_id: '25982'
abstract:
- lang: eng
  text: 'Iron (III) containing nanoparticles with superparamagnetic behaviour are
    prepared via deposition on various mesoporous supports (MgO, CeO2 and SBA-15).
    XRD, TEM-EDX, N2 physisorption, FTIR, and Moessbauer spectroscopy are used for
    their characterization. The reductive properties and catalytic behaviour in methanol
    decomposition of the materials are also studied. Depending on the chemical nature
    of the support, the predominant formation of: isolated iron species, strongly
    interacting with the support (for SBA-15), mixture of hematite and binary MgFe2O4
    nanoparticles (for MgO) or almost homogeneously dispersed hematite particles (for
    CeO2) are observed. The state of iron species strongly affects their catalytic
    properties. The favorable effect of the support mesoporosity on the catalytic
    activity is most pronounced for the iron modified CeO2.'
article_type: original
author:
- first_name: Tanya
  full_name: Tsoncheva, Tanya
  last_name: Tsoncheva
- first_name: Jan
  full_name: Roggenbuck, Jan
  last_name: Roggenbuck
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Lyubomira
  full_name: Ivanova, Lyubomira
  last_name: Ivanova
- first_name: Daniela
  full_name: Paneva, Daniela
  last_name: Paneva
- first_name: Ivan
  full_name: Mitov, Ivan
  last_name: Mitov
- first_name: Christo
  full_name: Minchev, Christo
  last_name: Minchev
citation:
  ama: 'Tsoncheva T, Roggenbuck J, Tiemann M, et al. Iron oxide nanoparticles supported
    on mesoporous MgO and CeO2: A comparative physicochemical and catalytic study.
    <i>Microporous and Mesoporous Materials</i>. Published online 2008:339-346. doi:<a
    href="https://doi.org/10.1016/j.micromeso.2007.06.021">10.1016/j.micromeso.2007.06.021</a>'
  apa: 'Tsoncheva, T., Roggenbuck, J., Tiemann, M., Ivanova, L., Paneva, D., Mitov,
    I., &#38; Minchev, C. (2008). Iron oxide nanoparticles supported on mesoporous
    MgO and CeO2: A comparative physicochemical and catalytic study. <i>Microporous
    and Mesoporous Materials</i>, 339–346. <a href="https://doi.org/10.1016/j.micromeso.2007.06.021">https://doi.org/10.1016/j.micromeso.2007.06.021</a>'
  bibtex: '@article{Tsoncheva_Roggenbuck_Tiemann_Ivanova_Paneva_Mitov_Minchev_2008,
    title={Iron oxide nanoparticles supported on mesoporous MgO and CeO2: A comparative
    physicochemical and catalytic study}, DOI={<a href="https://doi.org/10.1016/j.micromeso.2007.06.021">10.1016/j.micromeso.2007.06.021</a>},
    journal={Microporous and Mesoporous Materials}, author={Tsoncheva, Tanya and Roggenbuck,
    Jan and Tiemann, Michael and Ivanova, Lyubomira and Paneva, Daniela and Mitov,
    Ivan and Minchev, Christo}, year={2008}, pages={339–346} }'
  chicago: 'Tsoncheva, Tanya, Jan Roggenbuck, Michael Tiemann, Lyubomira Ivanova,
    Daniela Paneva, Ivan Mitov, and Christo Minchev. “Iron Oxide Nanoparticles Supported
    on Mesoporous MgO and CeO2: A Comparative Physicochemical and Catalytic Study.”
    <i>Microporous and Mesoporous Materials</i>, 2008, 339–46. <a href="https://doi.org/10.1016/j.micromeso.2007.06.021">https://doi.org/10.1016/j.micromeso.2007.06.021</a>.'
  ieee: 'T. Tsoncheva <i>et al.</i>, “Iron oxide nanoparticles supported on mesoporous
    MgO and CeO2: A comparative physicochemical and catalytic study,” <i>Microporous
    and Mesoporous Materials</i>, pp. 339–346, 2008, doi: <a href="https://doi.org/10.1016/j.micromeso.2007.06.021">10.1016/j.micromeso.2007.06.021</a>.'
  mla: 'Tsoncheva, Tanya, et al. “Iron Oxide Nanoparticles Supported on Mesoporous
    MgO and CeO2: A Comparative Physicochemical and Catalytic Study.” <i>Microporous
    and Mesoporous Materials</i>, 2008, pp. 339–46, doi:<a href="https://doi.org/10.1016/j.micromeso.2007.06.021">10.1016/j.micromeso.2007.06.021</a>.'
  short: T. Tsoncheva, J. Roggenbuck, M. Tiemann, L. Ivanova, D. Paneva, I. Mitov,
    C. Minchev, Microporous and Mesoporous Materials (2008) 339–346.
date_created: 2021-10-09T06:55:50Z
date_updated: 2023-03-09T08:44:52Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1016/j.micromeso.2007.06.021
extern: '1'
language:
- iso: eng
page: 339-346
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: 'Iron oxide nanoparticles supported on mesoporous MgO and CeO2: A comparative
  physicochemical and catalytic study'
type: journal_article
user_id: '23547'
year: '2008'
...
---
_id: '25987'
abstract:
- lang: eng
  text: Mesoporous CeO2 was synthesised by using CMK-3 carbon as a structure matrix.
    Nitrogen physisorption, powder X-ray diffraction, transmission electron microscopy
    (TEM), selected-area electron diffraction (SAED), energy-dispersive X-ray (EDX),
    X-ray absorption near-edge structure (XANES), and thermal (TG/MS) analysis were
    used for their characterisation. Methanol decomposition to hydrogen, CO, and methane
    was used as a catalytic test reaction. The obtained products exhibit uniform pores
    with a diameter of ca. 5 nm in a two-dimensional hexagonal periodic arrangement,
    as well as interparticle porosity, broadly distributed around ca. 35 nm; the specific
    surface area is 148 m2 g−1. The pore walls are polycrystalline. The polycrystalline
    nature and high surface-to-volume ratio of the products is reflected in an increased
    signal intensity in X-ray absorption spectroscopy. The synthesis of CeO2 from
    Ce(NO3)3 within the pores of the carbon matrix and the subsequent thermal combustion
    of the carbon is monitored by thermal analysis. Catalytic tests reveal that the
    activity of the mesoporous products in methanol decomposition are substantially
    higher than for a non-porous sample.
article_type: original
author:
- first_name: Jan
  full_name: Roggenbuck, Jan
  last_name: Roggenbuck
- first_name: Hanno
  full_name: Schäfer, Hanno
  last_name: Schäfer
- first_name: Tanya
  full_name: Tsoncheva, Tanya
  last_name: Tsoncheva
- first_name: Christo
  full_name: Minchev, Christo
  last_name: Minchev
- first_name: Jan
  full_name: Hanss, Jan
  last_name: Hanss
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: 'Roggenbuck J, Schäfer H, Tsoncheva T, Minchev C, Hanss J, Tiemann M. Mesoporous
    CeO2: Synthesis by nanocasting, characterisation and catalytic properties. <i>Microporous
    and Mesoporous Materials</i>. Published online 2007:335-341. doi:<a href="https://doi.org/10.1016/j.micromeso.2006.11.029">10.1016/j.micromeso.2006.11.029</a>'
  apa: 'Roggenbuck, J., Schäfer, H., Tsoncheva, T., Minchev, C., Hanss, J., &#38;
    Tiemann, M. (2007). Mesoporous CeO2: Synthesis by nanocasting, characterisation
    and catalytic properties. <i>Microporous and Mesoporous Materials</i>, 335–341.
    <a href="https://doi.org/10.1016/j.micromeso.2006.11.029">https://doi.org/10.1016/j.micromeso.2006.11.029</a>'
  bibtex: '@article{Roggenbuck_Schäfer_Tsoncheva_Minchev_Hanss_Tiemann_2007, title={Mesoporous
    CeO2: Synthesis by nanocasting, characterisation and catalytic properties}, DOI={<a
    href="https://doi.org/10.1016/j.micromeso.2006.11.029">10.1016/j.micromeso.2006.11.029</a>},
    journal={Microporous and Mesoporous Materials}, author={Roggenbuck, Jan and Schäfer,
    Hanno and Tsoncheva, Tanya and Minchev, Christo and Hanss, Jan and Tiemann, Michael},
    year={2007}, pages={335–341} }'
  chicago: 'Roggenbuck, Jan, Hanno Schäfer, Tanya Tsoncheva, Christo Minchev, Jan
    Hanss, and Michael Tiemann. “Mesoporous CeO2: Synthesis by Nanocasting, Characterisation
    and Catalytic Properties.” <i>Microporous and Mesoporous Materials</i>, 2007,
    335–41. <a href="https://doi.org/10.1016/j.micromeso.2006.11.029">https://doi.org/10.1016/j.micromeso.2006.11.029</a>.'
  ieee: 'J. Roggenbuck, H. Schäfer, T. Tsoncheva, C. Minchev, J. Hanss, and M. Tiemann,
    “Mesoporous CeO2: Synthesis by nanocasting, characterisation and catalytic properties,”
    <i>Microporous and Mesoporous Materials</i>, pp. 335–341, 2007, doi: <a href="https://doi.org/10.1016/j.micromeso.2006.11.029">10.1016/j.micromeso.2006.11.029</a>.'
  mla: 'Roggenbuck, Jan, et al. “Mesoporous CeO2: Synthesis by Nanocasting, Characterisation
    and Catalytic Properties.” <i>Microporous and Mesoporous Materials</i>, 2007,
    pp. 335–41, doi:<a href="https://doi.org/10.1016/j.micromeso.2006.11.029">10.1016/j.micromeso.2006.11.029</a>.'
  short: J. Roggenbuck, H. Schäfer, T. Tsoncheva, C. Minchev, J. Hanss, M. Tiemann,
    Microporous and Mesoporous Materials (2007) 335–341.
date_created: 2021-10-09T09:41:24Z
date_updated: 2023-03-09T08:48:18Z
department:
- _id: '35'
- _id: '163'
- _id: '307'
doi: 10.1016/j.micromeso.2006.11.029
extern: '1'
language:
- iso: eng
page: 335-341
publication: Microporous and Mesoporous Materials
publication_identifier:
  issn:
  - 1387-1811
publication_status: published
quality_controlled: '1'
status: public
title: 'Mesoporous CeO2: Synthesis by nanocasting, characterisation and catalytic
  properties'
type: journal_article
user_id: '23547'
year: '2007'
...
