TY - JOUR AB - In the current work, we study the silver ion release potential and the water uptake through a SiOxCyHz-polymer which is grown from the precursor hexamethyldisiloxane (HMDSO) in radiofrequency (RF) plasma. These layers were deposited on top of two dimensional (2D) ensembles of silver nanoparticles (AgNPs) with nominal thickness of 2 nm on a 20 nm RF-sputtered polytetrafluoroethylene (PTFE) thin film. The composition of the plasma-polymerized HMDSO barriers was varied by changing the oxygen flow during the polymerization process and their thickness was varied as well. Morphology and optical properties of the nanocomposites were investigated using transmission electron microscopy (TEM) and UV-Visible spectroscopy (UV-Vis), respectively. The concentration of the silver ions released from the nanocomposites after immersion in water for several time intervals was measured using inductively coupled plasma mass spectrometry (ICP-MS). Contact angle analysis and electrochemical impedance spectroscopy (EIS) measurements were also performed and results show a strong dependence of the coatings properties and their water uptake on the oxygen content in the coating films and their thickness. Plasma polymerization with increasing the oxygen flow leads to the formation of more hydrophilic thin films with a higher Ag ion release potential. Increasing the thickness of the coatings reduced the amount of the released ions and the rate of the release process was slowed down. This indicates that by tailoring the structure and the thickness of the plasma-polymerized coating films, one can tune the silver ion release properties of Ag/polymer nanocomposites. AU - Alissawi, N. AU - Peter, T. AU - Strunskus, T. AU - Ebbert, Christoph AU - Grundmeier, Guido AU - Faupel, F. ID - 20946 IS - 11 JF - JOURNAL OF NANOPARTICLE RESEARCH SN - 1388-0764 TI - Plasma-polymerized HMDSO coatings to adjust the silver ion release properties of Ag/polymer nanocomposites VL - 15 ER - TY - JOUR AB - To improve the understanding of the poor dispersability of fumed silica nanoparticle agglomerates, the stability of highly defined agglomerated model particles was investigated. The high temperature synthesis conditions for fumed silica were simulated by tempering. Along with electron-microscopical analysis of the sintering necks, the interparticle forces were investigated by energy resolved fragmentation analysis based on low pressure impaction. At temperatures above 1,000 °C the fragmentability of the agglomerates rapidly decreased while the energy necessary for fragmentation increased. The development of sintering necks was observed for temperatures exceeding 1,300 °C. Comparison of the experimental data with the fragmentation behaviour of a commercially produced fumed silica indicated solid state contacts (sintering necks) as being most numerous in the agglomerates resulting in limited fragmentability. AU - Seipenbusch, M. AU - Rothenbacher, S. AU - Kirchhoff, M. AU - Schmid, Hans-Joachim AU - Kasper, G. AU - Weber, A. P. ID - 26136 IS - 6 JF - Journal of Nanoparticle Research SN - 1388-0764 TI - Interparticle forces in silica nanoparticle agglomerates VL - 12 ER - TY - JOUR AB - A model for simulation of the three-dimensional morphology of nano-structured aggregates formed by concurrent coagulation and sintering is presented. Diffusion controlled cluster–cluster aggregation is assumed to be the prevailing coagulation mechanism which is implemented using a Monte–Carlo algorithm. Sintering is modeled as a successive overlapping of spherical primary particles, which are allowed to grow as to preserve overall mass. Simulations are characterized by individual ratios τ of characteristic collision to fusion time. A number of resulting aggregate-structures is displayed and reveals structure formation by coagulation and sintering for different values of τ. These aggregates are described qualitatively and quantitatively by their mass fractal dimension Df and radius of gyration. The fractal dimension increases from 1.86 for pure aggregation to ≈ 2.75 for equal characteristic time scales. As sintering turns out to be more and more relevant, increasingly compact aggregates start to form and the radius of gyration decreases significantly. The simulation results clearly reveal a strong dependence of the fractal dimension on the kinetics of the concurrent coagulation and sintering processes. Considering appropriate values of Df in aerosol process simulations may therefore be important in many cases. AU - Schmid, Hans-Joachim AU - Tejwani, Saurabh AU - Artelt, Christian AU - Peukert, Wolfgang ID - 26152 IS - 6 JF - Journal of Nanoparticle Research SN - 1388-0764 TI - Monte Carlo simulation of aggregate morphology for simultaneous coagulation and sintering VL - 6 ER -