---
_id: '48167'
abstract:
- lang: eng
text: AbstractA new approach for the characterization
of CO2 methanation catalysts prepared by thermal decomposition
of a nickel MOF by hard X‐ray photon‐in/photon‐out spectroscopy in form of high
energy resolution fluorescence detected X‐ray absorption near edge structure spectroscopy
(HERFD‐XANES) and valence‐to‐core X‐ray emission (VtC‐XES) is presented. In contrast
to conventional X‐ray absorption spectroscopy, the increased resolution of both
methods allows a more precise phase determination of the final catalyst, which
is influenced by the conditions during MOF decomposition.
author:
- first_name: Sven
full_name: Strübbe, Sven
id: '76968'
last_name: Strübbe
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Strübbe S, Nowakowski M, Schoch R, Bauer M. High‐Resolution X‐ray Absorption
and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation
Catalysts. ChemPhysChem. Published online 2023. doi:10.1002/cphc.202300113
apa: Strübbe, S., Nowakowski, M., Schoch, R., & Bauer, M. (2023). High‐Resolution
X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2
Methanation Catalysts. ChemPhysChem. https://doi.org/10.1002/cphc.202300113
bibtex: '@article{Strübbe_Nowakowski_Schoch_Bauer_2023, title={High‐Resolution X‐ray
Absorption and Emission Spectroscopy for Detailed Analysis of New CO2
Methanation Catalysts}, DOI={10.1002/cphc.202300113},
journal={ChemPhysChem}, publisher={Wiley}, author={Strübbe, Sven and Nowakowski,
Michał and Schoch, Roland and Bauer, Matthias}, year={2023} }'
chicago: Strübbe, Sven, Michał Nowakowski, Roland Schoch, and Matthias Bauer. “High‐Resolution
X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2
Methanation Catalysts.” ChemPhysChem, 2023. https://doi.org/10.1002/cphc.202300113.
ieee: 'S. Strübbe, M. Nowakowski, R. Schoch, and M. Bauer, “High‐Resolution X‐ray
Absorption and Emission Spectroscopy for Detailed Analysis of New CO2
Methanation Catalysts,” ChemPhysChem, 2023, doi: 10.1002/cphc.202300113.'
mla: Strübbe, Sven, et al. “High‐Resolution X‐ray Absorption and Emission Spectroscopy
for Detailed Analysis of New CO2 Methanation Catalysts.” ChemPhysChem,
Wiley, 2023, doi:10.1002/cphc.202300113.
short: S. Strübbe, M. Nowakowski, R. Schoch, M. Bauer, ChemPhysChem (2023).
date_created: 2023-10-17T08:14:08Z
date_updated: 2023-10-17T08:14:54Z
doi: 10.1002/cphc.202300113
keyword:
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
- 1439-7641
publication_status: published
publisher: Wiley
status: public
title: High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis
of New CO2 Methanation Catalysts
type: journal_article
user_id: '76968'
year: '2023'
...
---
_id: '25900'
abstract:
- lang: eng
text: The proton conduction properties of a phosphonato-sulfonate-based coordination
polymer are studied by impedance spectroscopy using a single crystal specimen.
Two distinct conduction mechanisms are identified. Water-mediated conductance
along the crystal surface occurs by mass transport, as evidenced by a high activation
energy (0.54 eV). In addition, intrinsic conduction by proton ′hopping′ through
the interior of the crystal with a low activation energy (0.31 eV) is observed.
This latter conduction is anisotropic with respect to the crystal structure and
seems to occur through a channel along the c axis of the orthorhombic crystal.
Proton conduction is assumed to be mediated by sulfonate groups and non-coordinating
water molecules that are part of the crystal structure.
article_type: original
author:
- first_name: Ali
full_name: Javed, Ali
last_name: Javed
- first_name: Thorsten
full_name: Wagner, Thorsten
last_name: Wagner
- first_name: Stephan
full_name: Wöhlbrandt, Stephan
last_name: Wöhlbrandt
- first_name: Norbert
full_name: Stock, Norbert
last_name: Stock
- first_name: Michael
full_name: Tiemann, Michael
id: '23547'
last_name: Tiemann
orcid: 0000-0003-1711-2722
citation:
ama: 'Javed A, Wagner T, Wöhlbrandt S, Stock N, Tiemann M. Proton Conduction in
a Single Crystal of a Phosphonato‐Sulfonate‐Based Coordination Polymer: Mechanistic
Insight. ChemPhysChem. Published online 2020:605-609. doi:10.1002/cphc.202000102'
apa: 'Javed, A., Wagner, T., Wöhlbrandt, S., Stock, N., & Tiemann, M. (2020).
Proton Conduction in a Single Crystal of a Phosphonato‐Sulfonate‐Based Coordination
Polymer: Mechanistic Insight. ChemPhysChem, 605–609. https://doi.org/10.1002/cphc.202000102'
bibtex: '@article{Javed_Wagner_Wöhlbrandt_Stock_Tiemann_2020, title={Proton Conduction
in a Single Crystal of a Phosphonato‐Sulfonate‐Based Coordination Polymer: Mechanistic
Insight}, DOI={10.1002/cphc.202000102},
journal={ChemPhysChem}, author={Javed, Ali and Wagner, Thorsten and Wöhlbrandt,
Stephan and Stock, Norbert and Tiemann, Michael}, year={2020}, pages={605–609}
}'
chicago: 'Javed, Ali, Thorsten Wagner, Stephan Wöhlbrandt, Norbert Stock, and Michael
Tiemann. “Proton Conduction in a Single Crystal of a Phosphonato‐Sulfonate‐Based
Coordination Polymer: Mechanistic Insight.” ChemPhysChem, 2020, 605–9.
https://doi.org/10.1002/cphc.202000102.'
ieee: 'A. Javed, T. Wagner, S. Wöhlbrandt, N. Stock, and M. Tiemann, “Proton Conduction
in a Single Crystal of a Phosphonato‐Sulfonate‐Based Coordination Polymer: Mechanistic
Insight,” ChemPhysChem, pp. 605–609, 2020, doi: 10.1002/cphc.202000102.'
mla: 'Javed, Ali, et al. “Proton Conduction in a Single Crystal of a Phosphonato‐Sulfonate‐Based
Coordination Polymer: Mechanistic Insight.” ChemPhysChem, 2020, pp. 605–09,
doi:10.1002/cphc.202000102.'
short: A. Javed, T. Wagner, S. Wöhlbrandt, N. Stock, M. Tiemann, ChemPhysChem (2020)
605–609.
date_created: 2021-10-08T10:35:08Z
date_updated: 2023-03-08T08:25:21Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1002/cphc.202000102
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cphc.202000102
oa: '1'
page: 605-609
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
- 1439-7641
publication_status: published
quality_controlled: '1'
status: public
title: 'Proton Conduction in a Single Crystal of a Phosphonato‐Sulfonate‐Based Coordination
Polymer: Mechanistic Insight'
type: journal_article
user_id: '23547'
year: '2020'
...
---
_id: '41275'
author:
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Helmut
full_name: Bertagnolli, Helmut
last_name: Bertagnolli
citation:
ama: Bauer M, Bertagnolli H. Towards X-Ray Absorption Spectroscopy in Real Time.
ChemPhysChem. 2009;10(13):2197-2200. doi:10.1002/cphc.200900418
apa: Bauer, M., & Bertagnolli, H. (2009). Towards X-Ray Absorption Spectroscopy
in Real Time. ChemPhysChem, 10(13), 2197–2200. https://doi.org/10.1002/cphc.200900418
bibtex: '@article{Bauer_Bertagnolli_2009, title={Towards X-Ray Absorption Spectroscopy
in Real Time}, volume={10}, DOI={10.1002/cphc.200900418},
number={13}, journal={ChemPhysChem}, publisher={Wiley}, author={Bauer, Matthias
and Bertagnolli, Helmut}, year={2009}, pages={2197–2200} }'
chicago: 'Bauer, Matthias, and Helmut Bertagnolli. “Towards X-Ray Absorption Spectroscopy
in Real Time.” ChemPhysChem 10, no. 13 (2009): 2197–2200. https://doi.org/10.1002/cphc.200900418.'
ieee: 'M. Bauer and H. Bertagnolli, “Towards X-Ray Absorption Spectroscopy in Real
Time,” ChemPhysChem, vol. 10, no. 13, pp. 2197–2200, 2009, doi: 10.1002/cphc.200900418.'
mla: Bauer, Matthias, and Helmut Bertagnolli. “Towards X-Ray Absorption Spectroscopy
in Real Time.” ChemPhysChem, vol. 10, no. 13, Wiley, 2009, pp. 2197–200,
doi:10.1002/cphc.200900418.
short: M. Bauer, H. Bertagnolli, ChemPhysChem 10 (2009) 2197–2200.
date_created: 2023-01-31T15:06:53Z
date_updated: 2023-01-31T15:07:00Z
department:
- _id: '306'
doi: 10.1002/cphc.200900418
intvolume: ' 10'
issue: '13'
keyword:
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
page: 2197-2200
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
- 1439-7641
publication_status: published
publisher: Wiley
status: public
title: Towards X-Ray Absorption Spectroscopy in Real Time
type: journal_article
user_id: '48467'
volume: 10
year: '2009'
...
---
_id: '39973'
author:
- first_name: Heinz-Siegfried
full_name: Kitzerow, Heinz-Siegfried
id: '254'
last_name: Kitzerow
citation:
ama: Kitzerow H-S. News about Soft Condensed Matter—A Liquid Crystal Meeting Review.
ChemPhysChem. 2005;2(10):628-632. doi:10.1002/1439-7641(20011015)2:10<628::aid-cphc628>3.0.co;2-7
apa: Kitzerow, H.-S. (2005). News about Soft Condensed Matter—A Liquid Crystal Meeting
Review. ChemPhysChem, 2(10), 628–632. https://doi.org/10.1002/1439-7641(20011015)2:10<628::aid-cphc628>3.0.co;2-7
bibtex: '@article{Kitzerow_2005, title={News about Soft Condensed Matter—A Liquid
Crystal Meeting Review}, volume={2}, DOI={10.1002/1439-7641(20011015)2:10<628::aid-cphc628>3.0.co;2-7},
number={10}, journal={ChemPhysChem}, publisher={Wiley}, author={Kitzerow, Heinz-Siegfried},
year={2005}, pages={628–632} }'
chicago: 'Kitzerow, Heinz-Siegfried. “News about Soft Condensed Matter—A Liquid
Crystal Meeting Review.” ChemPhysChem 2, no. 10 (2005): 628–32. https://doi.org/10.1002/1439-7641(20011015)2:10<628::aid-cphc628>3.0.co;2-7.'
ieee: 'H.-S. Kitzerow, “News about Soft Condensed Matter—A Liquid Crystal Meeting
Review,” ChemPhysChem, vol. 2, no. 10, pp. 628–632, 2005, doi: 10.1002/1439-7641(20011015)2:10<628::aid-cphc628>3.0.co;2-7.'
mla: Kitzerow, Heinz-Siegfried. “News about Soft Condensed Matter—A Liquid Crystal
Meeting Review.” ChemPhysChem, vol. 2, no. 10, Wiley, 2005, pp. 628–32,
doi:10.1002/1439-7641(20011015)2:10<628::aid-cphc628>3.0.co;2-7.
short: H.-S. Kitzerow, ChemPhysChem 2 (2005) 628–632.
date_created: 2023-01-25T11:32:08Z
date_updated: 2023-01-25T11:38:17Z
department:
- _id: '313'
- _id: '638'
doi: 10.1002/1439-7641(20011015)2:10<628::aid-cphc628>3.0.co;2-7
intvolume: ' 2'
issue: '10'
keyword:
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
page: 628-632
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
- 1439-7641
publication_status: published
publisher: Wiley
status: public
title: News about Soft Condensed Matter—A Liquid Crystal Meeting Review
type: journal_article
user_id: '254'
volume: 2
year: '2005'
...
---
_id: '39993'
author:
- first_name: Nicole
full_name: Mießen, Nicole
last_name: Mießen
- first_name: Jochen
full_name: Strauß, Jochen
last_name: Strauß
- first_name: Andreas
full_name: Hoischen, Andreas
last_name: Hoischen
- first_name: Kathrin
full_name: Kürschner, Kathrin
last_name: Kürschner
- first_name: Heinz-Siegfried
full_name: Kitzerow, Heinz-Siegfried
id: '254'
last_name: Kitzerow
citation:
ama: Mießen N, Strauß J, Hoischen A, Kürschner K, Kitzerow H-S. Durable Micropatterns
Obtained from Dissipative Structures in Liquid Crystals. ChemPhysChem.
2005;2(11):691-694. doi:10.1002/1439-7641(20011119)2:11<691::aid-cphc691>3.0.co;2-s
apa: Mießen, N., Strauß, J., Hoischen, A., Kürschner, K., & Kitzerow, H.-S.
(2005). Durable Micropatterns Obtained from Dissipative Structures in Liquid Crystals.
ChemPhysChem, 2(11), 691–694. https://doi.org/10.1002/1439-7641(20011119)2:11<691::aid-cphc691>3.0.co;2-s
bibtex: '@article{Mießen_Strauß_Hoischen_Kürschner_Kitzerow_2005, title={Durable
Micropatterns Obtained from Dissipative Structures in Liquid Crystals}, volume={2},
DOI={10.1002/1439-7641(20011119)2:11<691::aid-cphc691>3.0.co;2-s},
number={11}, journal={ChemPhysChem}, publisher={Wiley}, author={Mießen, Nicole
and Strauß, Jochen and Hoischen, Andreas and Kürschner, Kathrin and Kitzerow,
Heinz-Siegfried}, year={2005}, pages={691–694} }'
chicago: 'Mießen, Nicole, Jochen Strauß, Andreas Hoischen, Kathrin Kürschner, and
Heinz-Siegfried Kitzerow. “Durable Micropatterns Obtained from Dissipative Structures
in Liquid Crystals.” ChemPhysChem 2, no. 11 (2005): 691–94. https://doi.org/10.1002/1439-7641(20011119)2:11<691::aid-cphc691>3.0.co;2-s.'
ieee: 'N. Mießen, J. Strauß, A. Hoischen, K. Kürschner, and H.-S. Kitzerow, “Durable
Micropatterns Obtained from Dissipative Structures in Liquid Crystals,” ChemPhysChem,
vol. 2, no. 11, pp. 691–694, 2005, doi: 10.1002/1439-7641(20011119)2:11<691::aid-cphc691>3.0.co;2-s.'
mla: Mießen, Nicole, et al. “Durable Micropatterns Obtained from Dissipative Structures
in Liquid Crystals.” ChemPhysChem, vol. 2, no. 11, Wiley, 2005, pp. 691–94,
doi:10.1002/1439-7641(20011119)2:11<691::aid-cphc691>3.0.co;2-s.
short: N. Mießen, J. Strauß, A. Hoischen, K. Kürschner, H.-S. Kitzerow, ChemPhysChem
2 (2005) 691–694.
date_created: 2023-01-25T13:16:21Z
date_updated: 2023-01-25T16:08:40Z
department:
- _id: '313'
- _id: '638'
doi: 10.1002/1439-7641(20011119)2:11<691::aid-cphc691>3.0.co;2-s
intvolume: ' 2'
issue: '11'
keyword:
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics
- and Optics
language:
- iso: eng
page: 691-694
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
- 1439-7641
publication_status: published
publisher: Wiley
status: public
title: Durable Micropatterns Obtained from Dissipative Structures in Liquid Crystals
type: journal_article
user_id: '254'
volume: 2
year: '2005'
...
---
_id: '25995'
abstract:
- lang: eng
text: The early stages of ZnS nanoparticle growth from supersaturated solution are
investigated in situ by stopped-flow UV absorption spectroscopy with a time resolution
of 1.28 ms. A model for data analysis is suggested which makes it possible to
study both the average particle radius and the concentration. The average radii
lie in the sub-nanometer range. During the first 40 ms, growth is predominantly
governed by ripening.
article_type: original
author:
- first_name: Michael
full_name: Tiemann, Michael
id: '23547'
last_name: Tiemann
orcid: 0000-0003-1711-2722
- first_name: Özlem
full_name: Weiß, Özlem
last_name: Weiß
- first_name: Juha
full_name: Hartikainen, Juha
last_name: Hartikainen
- first_name: Frank
full_name: Marlow, Frank
last_name: Marlow
- first_name: Mika
full_name: Lindén, Mika
last_name: Lindén
citation:
ama: Tiemann M, Weiß Ö, Hartikainen J, Marlow F, Lindén M. Early Stages of ZnS Nanoparticle
Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy. ChemPhysChem.
Published online 2005:2113-2119. doi:10.1002/cphc.200500163
apa: Tiemann, M., Weiß, Ö., Hartikainen, J., Marlow, F., & Lindén, M. (2005).
Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption
Spectroscopy. ChemPhysChem, 2113–2119. https://doi.org/10.1002/cphc.200500163
bibtex: '@article{Tiemann_Weiß_Hartikainen_Marlow_Lindén_2005, title={Early Stages
of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy},
DOI={10.1002/cphc.200500163},
journal={ChemPhysChem}, author={Tiemann, Michael and Weiß, Özlem and Hartikainen,
Juha and Marlow, Frank and Lindén, Mika}, year={2005}, pages={2113–2119} }'
chicago: Tiemann, Michael, Özlem Weiß, Juha Hartikainen, Frank Marlow, and Mika
Lindén. “Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow
UV Absorption Spectroscopy.” ChemPhysChem, 2005, 2113–19. https://doi.org/10.1002/cphc.200500163.
ieee: 'M. Tiemann, Ö. Weiß, J. Hartikainen, F. Marlow, and M. Lindén, “Early Stages
of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV Absorption Spectroscopy,”
ChemPhysChem, pp. 2113–2119, 2005, doi: 10.1002/cphc.200500163.'
mla: Tiemann, Michael, et al. “Early Stages of ZnS Nanoparticle Growth Studied by
In-Situ Stopped-Flow UV Absorption Spectroscopy.” ChemPhysChem, 2005, pp.
2113–19, doi:10.1002/cphc.200500163.
short: M. Tiemann, Ö. Weiß, J. Hartikainen, F. Marlow, M. Lindén, ChemPhysChem (2005)
2113–2119.
date_created: 2021-10-09T09:48:34Z
date_updated: 2023-03-09T08:58:26Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1002/cphc.200500163
extern: '1'
language:
- iso: eng
page: 2113-2119
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
- 1439-7641
publication_status: published
quality_controlled: '1'
status: public
title: Early Stages of ZnS Nanoparticle Growth Studied by In-Situ Stopped-Flow UV
Absorption Spectroscopy
type: journal_article
user_id: '23547'
year: '2005'
...