--- _id: '42517' author: - first_name: Kosti full_name: Tapio, Kosti last_name: Tapio - first_name: Charlotte full_name: Kielar, Charlotte last_name: Kielar - first_name: Johannes M. full_name: Parikka, Johannes M. last_name: Parikka - first_name: Adrian full_name: Keller, Adrian id: '48864' last_name: Keller orcid: 0000-0001-7139-3110 - first_name: Heini full_name: Järvinen, Heini last_name: Järvinen - first_name: Karim full_name: Fahmy, Karim last_name: Fahmy - first_name: J. Jussi full_name: Toppari, J. Jussi last_name: Toppari citation: ama: Tapio K, Kielar C, Parikka JM, et al. Large-Scale Formation of DNA Origami Lattices on Silicon. Chemistry of Materials. 2023;35:1961–1971. doi:10.1021/acs.chemmater.2c03190 apa: Tapio, K., Kielar, C., Parikka, J. M., Keller, A., Järvinen, H., Fahmy, K., & Toppari, J. J. (2023). Large-Scale Formation of DNA Origami Lattices on Silicon. Chemistry of Materials, 35, 1961–1971. https://doi.org/10.1021/acs.chemmater.2c03190 bibtex: '@article{Tapio_Kielar_Parikka_Keller_Järvinen_Fahmy_Toppari_2023, title={Large-Scale Formation of DNA Origami Lattices on Silicon}, volume={35}, DOI={10.1021/acs.chemmater.2c03190}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Tapio, Kosti and Kielar, Charlotte and Parikka, Johannes M. and Keller, Adrian and Järvinen, Heini and Fahmy, Karim and Toppari, J. Jussi}, year={2023}, pages={1961–1971} }' chicago: 'Tapio, Kosti, Charlotte Kielar, Johannes M. Parikka, Adrian Keller, Heini Järvinen, Karim Fahmy, and J. Jussi Toppari. “Large-Scale Formation of DNA Origami Lattices on Silicon.” Chemistry of Materials 35 (2023): 1961–1971. https://doi.org/10.1021/acs.chemmater.2c03190.' ieee: 'K. Tapio et al., “Large-Scale Formation of DNA Origami Lattices on Silicon,” Chemistry of Materials, vol. 35, pp. 1961–1971, 2023, doi: 10.1021/acs.chemmater.2c03190.' mla: Tapio, Kosti, et al. “Large-Scale Formation of DNA Origami Lattices on Silicon.” Chemistry of Materials, vol. 35, American Chemical Society (ACS), 2023, pp. 1961–1971, doi:10.1021/acs.chemmater.2c03190. short: K. Tapio, C. Kielar, J.M. Parikka, A. Keller, H. Järvinen, K. Fahmy, J.J. Toppari, Chemistry of Materials 35 (2023) 1961–1971. date_created: 2023-02-27T07:42:33Z date_updated: 2023-05-05T10:50:56Z department: - _id: '302' doi: 10.1021/acs.chemmater.2c03190 intvolume: ' 35' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 1961–1971 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: Large-Scale Formation of DNA Origami Lattices on Silicon type: journal_article user_id: '48864' volume: 35 year: '2023' ... --- _id: '40993' abstract: - lang: eng text: Understanding high-temperature unconventional superconductivity has become a long-lasting problem in which the cuprates stand as central reference materials. Given this impasse, the recent discovery of superconductivity in analogous nickelate thin films represents a fundamental breakthrough calling for the identification of additional materials in this class. In particular, thermodynamically more robust systems are required to “upgrade” nickelate superconductors from thin films to bulk samples. Here, we contribute in this direction by reporting the synthesis of the new single-layer T′ Pr2NiO3F compound, assessing this synthesis in relation to the only previous T′ nickelate La2NiO3F, and analyzing the electronic properties across the R2NiO3F series (R = La–Lu) via first-principles calculations. We find that these mixed anion systems have a comparatively high degree of stability and their synthesis enables a fine-tuning of their composition as inferred from their characterization. Furthermore, we find that these unprecedented square-planar nickelates hold great promise as prospective superconductors due to their exceptional electronic structure. author: - first_name: Kerstin full_name: Wissel, Kerstin last_name: Wissel - first_name: Fabio full_name: Bernardini, Fabio last_name: Bernardini - first_name: Heesu full_name: Oh, Heesu last_name: Oh - first_name: Sami full_name: Vasala, Sami last_name: Vasala - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Björn full_name: Blaschkowski, Björn last_name: Blaschkowski - first_name: Pieter full_name: Glatzel, Pieter last_name: Glatzel - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Oliver full_name: Clemens, Oliver last_name: Clemens - first_name: Andrés full_name: Cano, Andrés last_name: Cano citation: ama: 'Wissel K, Bernardini F, Oh H, et al. Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic Properties across the Rare-Earth Series. Chemistry of Materials. 2022;34(16):7201-7209. doi:10.1021/acs.chemmater.2c00726' apa: 'Wissel, K., Bernardini, F., Oh, H., Vasala, S., Schoch, R., Blaschkowski, B., Glatzel, P., Bauer, M., Clemens, O., & Cano, A. (2022). Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic Properties across the Rare-Earth Series. Chemistry of Materials, 34(16), 7201–7209. https://doi.org/10.1021/acs.chemmater.2c00726' bibtex: '@article{Wissel_Bernardini_Oh_Vasala_Schoch_Blaschkowski_Glatzel_Bauer_Clemens_Cano_2022, title={Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic Properties across the Rare-Earth Series}, volume={34}, DOI={10.1021/acs.chemmater.2c00726}, number={16}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Wissel, Kerstin and Bernardini, Fabio and Oh, Heesu and Vasala, Sami and Schoch, Roland and Blaschkowski, Björn and Glatzel, Pieter and Bauer, Matthias and Clemens, Oliver and Cano, Andrés}, year={2022}, pages={7201–7209} }' chicago: 'Wissel, Kerstin, Fabio Bernardini, Heesu Oh, Sami Vasala, Roland Schoch, Björn Blaschkowski, Pieter Glatzel, Matthias Bauer, Oliver Clemens, and Andrés Cano. “Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic Properties across the Rare-Earth Series.” Chemistry of Materials 34, no. 16 (2022): 7201–9. https://doi.org/10.1021/acs.chemmater.2c00726.' ieee: 'K. Wissel et al., “Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic Properties across the Rare-Earth Series,” Chemistry of Materials, vol. 34, no. 16, pp. 7201–7209, 2022, doi: 10.1021/acs.chemmater.2c00726.' mla: 'Wissel, Kerstin, et al. “Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic Properties across the Rare-Earth Series.” Chemistry of Materials, vol. 34, no. 16, American Chemical Society (ACS), 2022, pp. 7201–09, doi:10.1021/acs.chemmater.2c00726.' short: K. Wissel, F. Bernardini, H. Oh, S. Vasala, R. Schoch, B. Blaschkowski, P. Glatzel, M. Bauer, O. Clemens, A. Cano, Chemistry of Materials 34 (2022) 7201–7209. date_created: 2023-01-30T16:44:52Z date_updated: 2023-01-31T08:01:26Z department: - _id: '35' - _id: '306' doi: 10.1021/acs.chemmater.2c00726 intvolume: ' 34' issue: '16' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 7201-7209 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: 'Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic Properties across the Rare-Earth Series' type: journal_article user_id: '48467' volume: 34 year: '2022' ... --- _id: '25183' author: - first_name: Natalie R. full_name: Geise, Natalie R. last_name: Geise - first_name: Robert M. full_name: Kasse, Robert M. last_name: Kasse - first_name: Johanna full_name: Nelson Weker, Johanna last_name: Nelson Weker - first_name: Hans-Georg full_name: Steinrück, Hans-Georg id: '84268' last_name: Steinrück orcid: 0000-0001-6373-0877 - first_name: Michael F. full_name: Toney, Michael F. last_name: Toney citation: ama: Geise NR, Kasse RM, Nelson Weker J, Steinrück H-G, Toney MF. Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando X-ray Diffraction. Chemistry of Materials. 2021;33:7537-7545. doi:10.1021/acs.chemmater.1c02585 apa: Geise, N. R., Kasse, R. M., Nelson Weker, J., Steinrück, H.-G., & Toney, M. F. (2021). Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando X-ray Diffraction. Chemistry of Materials, 33, 7537–7545. https://doi.org/10.1021/acs.chemmater.1c02585 bibtex: '@article{Geise_Kasse_Nelson Weker_Steinrück_Toney_2021, title={Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando X-ray Diffraction}, volume={33}, DOI={10.1021/acs.chemmater.1c02585}, journal={Chemistry of Materials}, author={Geise, Natalie R. and Kasse, Robert M. and Nelson Weker, Johanna and Steinrück, Hans-Georg and Toney, Michael F.}, year={2021}, pages={7537–7545} }' chicago: 'Geise, Natalie R., Robert M. Kasse, Johanna Nelson Weker, Hans-Georg Steinrück, and Michael F. Toney. “Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando X-Ray Diffraction.” Chemistry of Materials 33 (2021): 7537–45. https://doi.org/10.1021/acs.chemmater.1c02585.' ieee: 'N. R. Geise, R. M. Kasse, J. Nelson Weker, H.-G. Steinrück, and M. F. Toney, “Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando X-ray Diffraction,” Chemistry of Materials, vol. 33, pp. 7537–7545, 2021, doi: 10.1021/acs.chemmater.1c02585.' mla: Geise, Natalie R., et al. “Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando X-Ray Diffraction.” Chemistry of Materials, vol. 33, 2021, pp. 7537–45, doi:10.1021/acs.chemmater.1c02585. short: N.R. Geise, R.M. Kasse, J. Nelson Weker, H.-G. Steinrück, M.F. Toney, Chemistry of Materials 33 (2021) 7537–7545. date_created: 2021-09-30T14:32:12Z date_updated: 2022-01-06T06:56:54Z department: - _id: '633' doi: 10.1021/acs.chemmater.1c02585 intvolume: ' 33' language: - iso: eng page: 7537-7545 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published status: public title: Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando X-ray Diffraction type: journal_article user_id: '84268' volume: 33 year: '2021' ... --- _id: '25184' author: - first_name: Chuntian full_name: Cao, Chuntian last_name: Cao - first_name: Travis P. full_name: Pollard, Travis P. last_name: Pollard - first_name: Oleg full_name: Borodin, Oleg last_name: Borodin - first_name: Julian E. full_name: Mars, Julian E. last_name: Mars - first_name: Yuchi full_name: Tsao, Yuchi last_name: Tsao - first_name: Maria R. full_name: Lukatskaya, Maria R. last_name: Lukatskaya - first_name: Robert M. full_name: Kasse, Robert M. last_name: Kasse - first_name: Marshall A. full_name: Schroeder, Marshall A. last_name: Schroeder - first_name: Kang full_name: Xu, Kang last_name: Xu - first_name: Michael F. full_name: Toney, Michael F. last_name: Toney - first_name: Hans-Georg full_name: Steinrück, Hans-Georg id: '84268' last_name: Steinrück orcid: 0000-0001-6373-0877 citation: ama: Cao C, Pollard TP, Borodin O, et al. Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase. Chemistry of Materials. 2021;33:7315-7336. doi:10.1021/acs.chemmater.1c01744 apa: Cao, C., Pollard, T. P., Borodin, O., Mars, J. E., Tsao, Y., Lukatskaya, M. R., Kasse, R. M., Schroeder, M. A., Xu, K., Toney, M. F., & Steinrück, H.-G. (2021). Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase. Chemistry of Materials, 33, 7315–7336. https://doi.org/10.1021/acs.chemmater.1c01744 bibtex: '@article{Cao_Pollard_Borodin_Mars_Tsao_Lukatskaya_Kasse_Schroeder_Xu_Toney_et al._2021, title={Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase}, volume={33}, DOI={10.1021/acs.chemmater.1c01744}, journal={Chemistry of Materials}, author={Cao, Chuntian and Pollard, Travis P. and Borodin, Oleg and Mars, Julian E. and Tsao, Yuchi and Lukatskaya, Maria R. and Kasse, Robert M. and Schroeder, Marshall A. and Xu, Kang and Toney, Michael F. and et al.}, year={2021}, pages={7315–7336} }' chicago: 'Cao, Chuntian, Travis P. Pollard, Oleg Borodin, Julian E. Mars, Yuchi Tsao, Maria R. Lukatskaya, Robert M. Kasse, et al. “Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase.” Chemistry of Materials 33 (2021): 7315–36. https://doi.org/10.1021/acs.chemmater.1c01744.' ieee: 'C. Cao et al., “Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase,” Chemistry of Materials, vol. 33, pp. 7315–7336, 2021, doi: 10.1021/acs.chemmater.1c01744.' mla: Cao, Chuntian, et al. “Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase.” Chemistry of Materials, vol. 33, 2021, pp. 7315–36, doi:10.1021/acs.chemmater.1c01744. short: C. Cao, T.P. Pollard, O. Borodin, J.E. Mars, Y. Tsao, M.R. Lukatskaya, R.M. Kasse, M.A. Schroeder, K. Xu, M.F. Toney, H.-G. Steinrück, Chemistry of Materials 33 (2021) 7315–7336. date_created: 2021-09-30T14:32:44Z date_updated: 2022-01-06T06:56:54Z department: - _id: '633' doi: 10.1021/acs.chemmater.1c01744 intvolume: ' 33' language: - iso: eng page: 7315-7336 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published status: public title: Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase type: journal_article user_id: '84268' volume: 33 year: '2021' ... --- _id: '41013' abstract: - lang: eng text: Within this article, it is shown that an electrochemical defluorination and additional fluorination of Ruddlesden–Popper-type La2NiO3F2 is possible within all-solid-state fluoride-ion batteries. Structural changes within the reduced and oxidized phases have been examined by X-ray diffraction studies at different states of charging and discharging. The synthesis of the oxidized phase La2NiO3F2+x proved to be successful by structural analysis using both X-ray powder diffraction and automated electron diffraction tomography techniques. The structural reversibility on re-fluorinating and re-defluorinating is also demonstrated. Moreover, the influence of different sequences of consecutive reduction and oxidation steps on the formed phases has been investigated. The observed structural changes have been compared to changes in phases obtained via other topochemical modification approaches such as hydride-based reduction and oxidative fluorination using F2 gas, highlighting the potential of such electrochemical reactions as alternative synthesis routes. Furthermore, the electrochemical routes represent safe and controllable synthesis approaches for novel phases, which cannot be synthesized via other topochemical methods. Additionally, side reactions, occurring alongside the desired electrochemical reactions, have been addressed and the cycling performance has been studied. article_type: original author: - first_name: Kerstin full_name: Wissel, Kerstin last_name: Wissel - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Tobias full_name: Vogel, Tobias last_name: Vogel - first_name: Manuel full_name: Donzelli, Manuel last_name: Donzelli - first_name: Galina full_name: Matveeva, Galina last_name: Matveeva - first_name: Ute full_name: Kolb, Ute last_name: Kolb - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Peter R. full_name: Slater, Peter R. last_name: Slater - first_name: Oliver full_name: Clemens, Oliver last_name: Clemens citation: ama: Wissel K, Schoch R, Vogel T, et al. Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries. Chemistry of Materials. 2021;33(2):499-512. doi:10.1021/acs.chemmater.0c01762 apa: Wissel, K., Schoch, R., Vogel, T., Donzelli, M., Matveeva, G., Kolb, U., Bauer, M., Slater, P. R., & Clemens, O. (2021). Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries. Chemistry of Materials, 33(2), 499–512. https://doi.org/10.1021/acs.chemmater.0c01762 bibtex: '@article{Wissel_Schoch_Vogel_Donzelli_Matveeva_Kolb_Bauer_Slater_Clemens_2021, title={Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries}, volume={33}, DOI={10.1021/acs.chemmater.0c01762}, number={2}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Wissel, Kerstin and Schoch, Roland and Vogel, Tobias and Donzelli, Manuel and Matveeva, Galina and Kolb, Ute and Bauer, Matthias and Slater, Peter R. and Clemens, Oliver}, year={2021}, pages={499–512} }' chicago: 'Wissel, Kerstin, Roland Schoch, Tobias Vogel, Manuel Donzelli, Galina Matveeva, Ute Kolb, Matthias Bauer, Peter R. Slater, and Oliver Clemens. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries.” Chemistry of Materials 33, no. 2 (2021): 499–512. https://doi.org/10.1021/acs.chemmater.0c01762.' ieee: 'K. Wissel et al., “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries,” Chemistry of Materials, vol. 33, no. 2, pp. 499–512, 2021, doi: 10.1021/acs.chemmater.0c01762.' mla: Wissel, Kerstin, et al. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries.” Chemistry of Materials, vol. 33, no. 2, American Chemical Society (ACS), 2021, pp. 499–512, doi:10.1021/acs.chemmater.0c01762. short: K. Wissel, R. Schoch, T. Vogel, M. Donzelli, G. Matveeva, U. Kolb, M. Bauer, P.R. Slater, O. Clemens, Chemistry of Materials 33 (2021) 499–512. date_created: 2023-01-30T17:01:00Z date_updated: 2023-01-31T08:07:28Z department: - _id: '35' - _id: '306' doi: 10.1021/acs.chemmater.0c01762 intvolume: ' 33' issue: '2' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 499-512 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries type: journal_article user_id: '48467' volume: 33 year: '2021' ... --- _id: '23621' author: - first_name: Tzu-Yen full_name: Huang, Tzu-Yen last_name: Huang - first_name: Felipe A. full_name: Larrain, Felipe A. last_name: Larrain - first_name: Carlos H. full_name: Borca, Carlos H. last_name: Borca - first_name: Canek full_name: Fuentes-Hernandez, Canek last_name: Fuentes-Hernandez - first_name: Hongping full_name: Yan, Hongping last_name: Yan - first_name: Sebastian Alexander full_name: Schneider, Sebastian Alexander last_name: Schneider - first_name: Wen-Fang full_name: Chou, Wen-Fang last_name: Chou - first_name: Victor A. full_name: Rodriguez-Toro, Victor A. last_name: Rodriguez-Toro - first_name: Hans-Georg full_name: Steinrück, Hans-Georg id: '84268' last_name: Steinrück orcid: 0000-0001-6373-0877 - first_name: Chuntian full_name: Cao, Chuntian last_name: Cao - first_name: C. David full_name: Sherrill, C. David last_name: Sherrill - first_name: Bernard full_name: Kippelen, Bernard last_name: Kippelen - first_name: Michael F. full_name: Toney, Michael F. last_name: Toney citation: ama: Huang T-Y, Larrain FA, Borca CH, et al. Morphology of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid. Chemistry of Materials. 2019;31:6677-6683. doi:10.1021/acs.chemmater.9b01069 apa: Huang, T.-Y., Larrain, F. A., Borca, C. H., Fuentes-Hernandez, C., Yan, H., Schneider, S. A., Chou, W.-F., Rodriguez-Toro, V. A., Steinrück, H.-G., Cao, C., Sherrill, C. D., Kippelen, B., & Toney, M. F. (2019). Morphology of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid. Chemistry of Materials, 31, 6677–6683. https://doi.org/10.1021/acs.chemmater.9b01069 bibtex: '@article{Huang_Larrain_Borca_Fuentes-Hernandez_Yan_Schneider_Chou_Rodriguez-Toro_Steinrück_Cao_et al._2019, title={Morphology of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid}, volume={31}, DOI={10.1021/acs.chemmater.9b01069}, journal={Chemistry of Materials}, author={Huang, Tzu-Yen and Larrain, Felipe A. and Borca, Carlos H. and Fuentes-Hernandez, Canek and Yan, Hongping and Schneider, Sebastian Alexander and Chou, Wen-Fang and Rodriguez-Toro, Victor A. and Steinrück, Hans-Georg and Cao, Chuntian and et al.}, year={2019}, pages={6677–6683} }' chicago: 'Huang, Tzu-Yen, Felipe A. Larrain, Carlos H. Borca, Canek Fuentes-Hernandez, Hongping Yan, Sebastian Alexander Schneider, Wen-Fang Chou, et al. “Morphology of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid.” Chemistry of Materials 31 (2019): 6677–83. https://doi.org/10.1021/acs.chemmater.9b01069.' ieee: 'T.-Y. Huang et al., “Morphology of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid,” Chemistry of Materials, vol. 31, pp. 6677–6683, 2019, doi: 10.1021/acs.chemmater.9b01069.' mla: Huang, Tzu-Yen, et al. “Morphology of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid.” Chemistry of Materials, vol. 31, 2019, pp. 6677–83, doi:10.1021/acs.chemmater.9b01069. short: T.-Y. Huang, F.A. Larrain, C.H. Borca, C. Fuentes-Hernandez, H. Yan, S.A. Schneider, W.-F. Chou, V.A. Rodriguez-Toro, H.-G. Steinrück, C. Cao, C.D. Sherrill, B. Kippelen, M.F. Toney, Chemistry of Materials 31 (2019) 6677–6683. date_created: 2021-09-01T09:46:52Z date_updated: 2022-01-06T06:55:57Z department: - _id: '633' doi: 10.1021/acs.chemmater.9b01069 intvolume: ' 31' language: - iso: eng page: 6677-6683 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published status: public title: Morphology of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid type: journal_article user_id: '84268' volume: 31 year: '2019' ... --- _id: '41239' author: - first_name: Oliver full_name: Clemens, Oliver last_name: Clemens - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Robert full_name: Haberkorn, Robert last_name: Haberkorn - first_name: Michael full_name: Springborg, Michael last_name: Springborg - first_name: Horst Philipp full_name: Beck, Horst Philipp last_name: Beck citation: ama: 'Clemens O, Bauer M, Haberkorn R, Springborg M, Beck HP. Synthesis and Characterization of Vanadium-Doped LiMnPO4-Compounds: LiMn(PO4)x(VO4)1–x (0.8 ≤ x ≤ 1.0). Chemistry of Materials. 2012;24(24):4717-4724. doi:10.1021/cm303005d' apa: 'Clemens, O., Bauer, M., Haberkorn, R., Springborg, M., & Beck, H. P. (2012). Synthesis and Characterization of Vanadium-Doped LiMnPO4-Compounds: LiMn(PO4)x(VO4)1–x (0.8 ≤ x ≤ 1.0). Chemistry of Materials, 24(24), 4717–4724. https://doi.org/10.1021/cm303005d' bibtex: '@article{Clemens_Bauer_Haberkorn_Springborg_Beck_2012, title={Synthesis and Characterization of Vanadium-Doped LiMnPO4-Compounds: LiMn(PO4)x(VO4)1–x (0.8 ≤ x ≤ 1.0)}, volume={24}, DOI={10.1021/cm303005d}, number={24}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Clemens, Oliver and Bauer, Matthias and Haberkorn, Robert and Springborg, Michael and Beck, Horst Philipp}, year={2012}, pages={4717–4724} }' chicago: 'Clemens, Oliver, Matthias Bauer, Robert Haberkorn, Michael Springborg, and Horst Philipp Beck. “Synthesis and Characterization of Vanadium-Doped LiMnPO4-Compounds: LiMn(PO4)x(VO4)1–x (0.8 ≤ x ≤ 1.0).” Chemistry of Materials 24, no. 24 (2012): 4717–24. https://doi.org/10.1021/cm303005d.' ieee: 'O. Clemens, M. Bauer, R. Haberkorn, M. Springborg, and H. P. Beck, “Synthesis and Characterization of Vanadium-Doped LiMnPO4-Compounds: LiMn(PO4)x(VO4)1–x (0.8 ≤ x ≤ 1.0),” Chemistry of Materials, vol. 24, no. 24, pp. 4717–4724, 2012, doi: 10.1021/cm303005d.' mla: 'Clemens, Oliver, et al. “Synthesis and Characterization of Vanadium-Doped LiMnPO4-Compounds: LiMn(PO4)x(VO4)1–x (0.8 ≤ x ≤ 1.0).” Chemistry of Materials, vol. 24, no. 24, American Chemical Society (ACS), 2012, pp. 4717–24, doi:10.1021/cm303005d.' short: O. Clemens, M. Bauer, R. Haberkorn, M. Springborg, H.P. Beck, Chemistry of Materials 24 (2012) 4717–4724. date_created: 2023-01-31T14:54:11Z date_updated: 2023-01-31T14:54:40Z department: - _id: '306' doi: 10.1021/cm303005d intvolume: ' 24' issue: '24' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 4717-4724 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: 'Synthesis and Characterization of Vanadium-Doped LiMnPO4-Compounds: LiMn(PO4)x(VO4)1–x (0.8 ≤ x ≤ 1.0)' type: journal_article user_id: '48467' volume: 24 year: '2012' ... --- _id: '22608' author: - first_name: Tobias B. full_name: Thiede, Tobias B. last_name: Thiede - first_name: Michael full_name: Krasnopolski, Michael last_name: Krasnopolski - first_name: Andrian P. full_name: Milanov, Andrian P. last_name: Milanov - first_name: Maria Teresa full_name: de los Arcos de Pedro, Maria Teresa id: '54556' last_name: de los Arcos de Pedro - first_name: Andreas full_name: Ney, Andreas last_name: Ney - first_name: Hans-Werner full_name: Becker, Hans-Werner last_name: Becker - first_name: Detlef full_name: Rogalla, Detlef last_name: Rogalla - first_name: Jörg full_name: Winter, Jörg last_name: Winter - first_name: Anjana full_name: Devi, Anjana last_name: Devi - first_name: Roland A. full_name: Fischer, Roland A. last_name: Fischer citation: ama: Thiede TB, Krasnopolski M, Milanov AP, et al. Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films. Chemistry of Materials. Published online 2011:1430-1440. doi:10.1021/cm102840v apa: Thiede, T. B., Krasnopolski, M., Milanov, A. P., de los Arcos de Pedro, M. T., Ney, A., Becker, H.-W., Rogalla, D., Winter, J., Devi, A., & Fischer, R. A. (2011). Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films. Chemistry of Materials, 1430–1440. https://doi.org/10.1021/cm102840v bibtex: '@article{Thiede_Krasnopolski_Milanov_de los Arcos de Pedro_Ney_Becker_Rogalla_Winter_Devi_Fischer_2011, title={Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films}, DOI={10.1021/cm102840v}, journal={Chemistry of Materials}, author={Thiede, Tobias B. and Krasnopolski, Michael and Milanov, Andrian P. and de los Arcos de Pedro, Maria Teresa and Ney, Andreas and Becker, Hans-Werner and Rogalla, Detlef and Winter, Jörg and Devi, Anjana and Fischer, Roland A.}, year={2011}, pages={1430–1440} }' chicago: Thiede, Tobias B., Michael Krasnopolski, Andrian P. Milanov, Maria Teresa de los Arcos de Pedro, Andreas Ney, Hans-Werner Becker, Detlef Rogalla, Jörg Winter, Anjana Devi, and Roland A. Fischer. “Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films.” Chemistry of Materials, 2011, 1430–40. https://doi.org/10.1021/cm102840v. ieee: 'T. B. Thiede et al., “Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films,” Chemistry of Materials, pp. 1430–1440, 2011, doi: 10.1021/cm102840v.' mla: Thiede, Tobias B., et al. “Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films.” Chemistry of Materials, 2011, pp. 1430–40, doi:10.1021/cm102840v. short: T.B. Thiede, M. Krasnopolski, A.P. Milanov, M.T. de los Arcos de Pedro, A. Ney, H.-W. Becker, D. Rogalla, J. Winter, A. Devi, R.A. Fischer, Chemistry of Materials (2011) 1430–1440. date_created: 2021-07-07T11:31:43Z date_updated: 2023-01-24T08:27:17Z department: - _id: '302' doi: 10.1021/cm102840v extern: '1' language: - iso: eng page: 1430-1440 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published status: public title: Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films type: journal_article user_id: '54556' year: '2011' ... --- _id: '41990' author: - first_name: Janosch full_name: Cravillon, Janosch last_name: Cravillon - first_name: Roman full_name: Nayuk, Roman last_name: Nayuk - first_name: Sergej full_name: Springer, Sergej last_name: Springer - first_name: Armin full_name: Feldhoff, Armin last_name: Feldhoff - first_name: Klaus full_name: Huber, Klaus id: '237' last_name: Huber - first_name: Michael full_name: Wiebcke, Michael last_name: Wiebcke citation: ama: 'Cravillon J, Nayuk R, Springer S, Feldhoff A, Huber K, Wiebcke M. Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering. Chemistry of Materials. 2011;23(8):2130-2141. doi:10.1021/cm103571y' apa: 'Cravillon, J., Nayuk, R., Springer, S., Feldhoff, A., Huber, K., & Wiebcke, M. (2011). Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering. Chemistry of Materials, 23(8), 2130–2141. https://doi.org/10.1021/cm103571y' bibtex: '@article{Cravillon_Nayuk_Springer_Feldhoff_Huber_Wiebcke_2011, title={Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering}, volume={23}, DOI={10.1021/cm103571y}, number={8}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Cravillon, Janosch and Nayuk, Roman and Springer, Sergej and Feldhoff, Armin and Huber, Klaus and Wiebcke, Michael}, year={2011}, pages={2130–2141} }' chicago: 'Cravillon, Janosch, Roman Nayuk, Sergej Springer, Armin Feldhoff, Klaus Huber, and Michael Wiebcke. “Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering.” Chemistry of Materials 23, no. 8 (2011): 2130–41. https://doi.org/10.1021/cm103571y.' ieee: 'J. Cravillon, R. Nayuk, S. Springer, A. Feldhoff, K. Huber, and M. Wiebcke, “Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering,” Chemistry of Materials, vol. 23, no. 8, pp. 2130–2141, 2011, doi: 10.1021/cm103571y.' mla: 'Cravillon, Janosch, et al. “Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering.” Chemistry of Materials, vol. 23, no. 8, American Chemical Society (ACS), 2011, pp. 2130–41, doi:10.1021/cm103571y.' short: J. Cravillon, R. Nayuk, S. Springer, A. Feldhoff, K. Huber, M. Wiebcke, Chemistry of Materials 23 (2011) 2130–2141. date_created: 2023-02-10T14:31:09Z date_updated: 2023-02-10T14:31:32Z department: - _id: '314' doi: 10.1021/cm103571y intvolume: ' 23' issue: '8' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 2130-2141 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: 'Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering' type: journal_article user_id: '237' volume: 23 year: '2011' ... --- _id: '41997' author: - first_name: Janosch full_name: Cravillon, Janosch last_name: Cravillon - first_name: Simon full_name: Münzer, Simon last_name: Münzer - first_name: Sven-Jare full_name: Lohmeier, Sven-Jare last_name: Lohmeier - first_name: Armin full_name: Feldhoff, Armin last_name: Feldhoff - first_name: Klaus full_name: Huber, Klaus id: '237' last_name: Huber - first_name: Michael full_name: Wiebcke, Michael last_name: Wiebcke citation: ama: Cravillon J, Münzer S, Lohmeier S-J, Feldhoff A, Huber K, Wiebcke M. Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework. Chemistry of Materials. 2009;21(8):1410-1412. doi:10.1021/cm900166h apa: Cravillon, J., Münzer, S., Lohmeier, S.-J., Feldhoff, A., Huber, K., & Wiebcke, M. (2009). Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework. Chemistry of Materials, 21(8), 1410–1412. https://doi.org/10.1021/cm900166h bibtex: '@article{Cravillon_Münzer_Lohmeier_Feldhoff_Huber_Wiebcke_2009, title={Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework}, volume={21}, DOI={10.1021/cm900166h}, number={8}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Cravillon, Janosch and Münzer, Simon and Lohmeier, Sven-Jare and Feldhoff, Armin and Huber, Klaus and Wiebcke, Michael}, year={2009}, pages={1410–1412} }' chicago: 'Cravillon, Janosch, Simon Münzer, Sven-Jare Lohmeier, Armin Feldhoff, Klaus Huber, and Michael Wiebcke. “Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework.” Chemistry of Materials 21, no. 8 (2009): 1410–12. https://doi.org/10.1021/cm900166h.' ieee: 'J. Cravillon, S. Münzer, S.-J. Lohmeier, A. Feldhoff, K. Huber, and M. Wiebcke, “Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework,” Chemistry of Materials, vol. 21, no. 8, pp. 1410–1412, 2009, doi: 10.1021/cm900166h.' mla: Cravillon, Janosch, et al. “Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework.” Chemistry of Materials, vol. 21, no. 8, American Chemical Society (ACS), 2009, pp. 1410–12, doi:10.1021/cm900166h. short: J. Cravillon, S. Münzer, S.-J. Lohmeier, A. Feldhoff, K. Huber, M. Wiebcke, Chemistry of Materials 21 (2009) 1410–1412. date_created: 2023-02-10T14:41:28Z date_updated: 2023-02-10T14:41:49Z department: - _id: '314' doi: 10.1021/cm900166h intvolume: ' 21' issue: '8' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 1410-1412 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework type: journal_article user_id: '237' volume: 21 year: '2009' ... --- _id: '25978' abstract: - lang: eng text: In recent years, a lot of research activity has focused on the synthesis of new ordered porous materials by utilization of porous matrices as templates. Since the matrices are themselves created by templating procedures, the entire process can be envisaged as “repeated templating”. This review describes recent conceptual developments in the field of structure replication and summarizes the large number of publications on new functional materials prepared by this method. article_type: review author: - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 citation: ama: Tiemann M. Repeated Templating. Chemistry of Materials. Published online 2008:961-971. doi:10.1021/cm702050s apa: Tiemann, M. (2008). Repeated Templating. Chemistry of Materials, 961–971. https://doi.org/10.1021/cm702050s bibtex: '@article{Tiemann_2008, title={Repeated Templating}, DOI={10.1021/cm702050s}, journal={Chemistry of Materials}, author={Tiemann, Michael}, year={2008}, pages={961–971} }' chicago: Tiemann, Michael. “Repeated Templating.” Chemistry of Materials, 2008, 961–71. https://doi.org/10.1021/cm702050s. ieee: 'M. Tiemann, “Repeated Templating,” Chemistry of Materials, pp. 961–971, 2008, doi: 10.1021/cm702050s.' mla: Tiemann, Michael. “Repeated Templating.” Chemistry of Materials, 2008, pp. 961–71, doi:10.1021/cm702050s. short: M. Tiemann, Chemistry of Materials (2008) 961–971. date_created: 2021-10-09T06:51:34Z date_updated: 2023-03-09T08:47:19Z department: - _id: '35' - _id: '2' - _id: '307' doi: 10.1021/cm702050s extern: '1' language: - iso: eng page: 961-971 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published quality_controlled: '1' status: public title: Repeated Templating type: journal_article user_id: '23547' year: '2008' ... --- _id: '25991' abstract: - lang: eng text: Periodically ordered mesoporous magnesium oxide was synthesized in a double replication procedure. Mesoporous SBA-15 silica and CMK-3 carbon were successively used as hard structure matrixes. The carbon pore system was infiltrated with Mg(NO3)2, which was then converted to MgO at 573 K; the carbon matrix was finally removed by thermal combustion. The structure of the mesoporous MgO corresponds to that of the original SBA-15 silica. The products consist of hexagonally arranged cylindrical mesopores and crystalline pore walls. The efficiency of the replication series was studied by variation of the infiltration method and comprehensive pore size analysis of all involved mesoporous materials. The in situ formation of MgO inside the CMK-3 carbon pore system was monitored by thermal analysis. Postsynthetic treatment of the products at 823 K in a vacuum prior to removal of the carbon matrix was found to improve the crystallinity but to diminish the periodic order of the pore system. article_type: original author: - first_name: Jan full_name: Roggenbuck, Jan last_name: Roggenbuck - first_name: Günter full_name: Koch, Günter last_name: Koch - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 citation: ama: Roggenbuck J, Koch G, Tiemann M. Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon Structure Replication. Chemistry of Materials. Published online 2006:4151-4156. doi:10.1021/cm060740s apa: Roggenbuck, J., Koch, G., & Tiemann, M. (2006). Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon Structure Replication. Chemistry of Materials, 4151–4156. https://doi.org/10.1021/cm060740s bibtex: '@article{Roggenbuck_Koch_Tiemann_2006, title={Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon Structure Replication}, DOI={10.1021/cm060740s}, journal={Chemistry of Materials}, author={Roggenbuck, Jan and Koch, Günter and Tiemann, Michael}, year={2006}, pages={4151–4156} }' chicago: Roggenbuck, Jan, Günter Koch, and Michael Tiemann. “Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon Structure Replication.” Chemistry of Materials, 2006, 4151–56. https://doi.org/10.1021/cm060740s. ieee: 'J. Roggenbuck, G. Koch, and M. Tiemann, “Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon Structure Replication,” Chemistry of Materials, pp. 4151–4156, 2006, doi: 10.1021/cm060740s.' mla: Roggenbuck, Jan, et al. “Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon Structure Replication.” Chemistry of Materials, 2006, pp. 4151–56, doi:10.1021/cm060740s. short: J. Roggenbuck, G. Koch, M. Tiemann, Chemistry of Materials (2006) 4151–4156. date_created: 2021-10-09T09:45:04Z date_updated: 2023-03-09T08:58:00Z department: - _id: '35' - _id: '2' - _id: '307' doi: 10.1021/cm060740s extern: '1' language: - iso: eng page: 4151-4156 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published quality_controlled: '1' status: public title: Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon Structure Replication type: journal_article user_id: '23547' year: '2006' ... --- _id: '25996' abstract: - lang: eng text: In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls... article_type: original author: - first_name: Jürgen full_name: Morell, Jürgen last_name: Morell - first_name: Cilaine V. full_name: Teixeira, Cilaine V. last_name: Teixeira - first_name: Maximilian full_name: Cornelius, Maximilian last_name: Cornelius - first_name: Vivian full_name: Rebbin, Vivian last_name: Rebbin - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: Heinz full_name: Amenitsch, Heinz last_name: Amenitsch - first_name: Michael full_name: Fröba, Michael last_name: Fröba - first_name: Mika full_name: Lindén, Mika last_name: Lindén citation: ama: Morell J, Teixeira CV, Cornelius M, et al. In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls. Chemistry of Materials. Published online 2004:5564-5566. doi:10.1021/cm048453g apa: Morell, J., Teixeira, C. V., Cornelius, M., Rebbin, V., Tiemann, M., Amenitsch, H., Fröba, M., & Lindén, M. (2004). In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls. Chemistry of Materials, 5564–5566. https://doi.org/10.1021/cm048453g bibtex: '@article{Morell_Teixeira_Cornelius_Rebbin_Tiemann_Amenitsch_Fröba_Lindén_2004, title={In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls}, DOI={10.1021/cm048453g}, journal={Chemistry of Materials}, author={Morell, Jürgen and Teixeira, Cilaine V. and Cornelius, Maximilian and Rebbin, Vivian and Tiemann, Michael and Amenitsch, Heinz and Fröba, Michael and Lindén, Mika}, year={2004}, pages={5564–5566} }' chicago: Morell, Jürgen, Cilaine V. Teixeira, Maximilian Cornelius, Vivian Rebbin, Michael Tiemann, Heinz Amenitsch, Michael Fröba, and Mika Lindén. “In Situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls.” Chemistry of Materials, 2004, 5564–66. https://doi.org/10.1021/cm048453g. ieee: 'J. Morell et al., “In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls,” Chemistry of Materials, pp. 5564–5566, 2004, doi: 10.1021/cm048453g.' mla: Morell, Jürgen, et al. “In Situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls.” Chemistry of Materials, 2004, pp. 5564–66, doi:10.1021/cm048453g. short: J. Morell, C.V. Teixeira, M. Cornelius, V. Rebbin, M. Tiemann, H. Amenitsch, M. Fröba, M. Lindén, Chemistry of Materials (2004) 5564–5566. date_created: 2021-10-09T09:49:26Z date_updated: 2023-03-09T09:00:44Z department: - _id: '35' - _id: '2' - _id: '307' doi: 10.1021/cm048453g extern: '1' language: - iso: eng page: 5564-5566 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published quality_controlled: '1' status: public title: In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls type: journal_article user_id: '23547' year: '2004' ... --- _id: '26003' abstract: - lang: eng text: Long-chain n-alkylamine surfactants have been used as structure-directing agents in the synthesis of mesoporous aluminophosphates by a highly cooperative formation mechanism in an alcoholic system. Small amounts of water in the synthesis mixture play a significant role in the hydrolysis of the aluminum precursor (Al[OiPr]3) and are important for the quality of the mesostructured products. The materials exhibit disordered mesostructures, the stability and structural order of which can be improved by a postsynthetic thermal treatment. The products are then stable enough for the removal of the surfactant molecules by acidic solvent extraction, yielding surface areas up to 690 m2/g. article_type: original author: - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: Marcus full_name: Schulz, Marcus last_name: Schulz - first_name: Christian full_name: Jäger, Christian last_name: Jäger - first_name: Michael full_name: Fröba, Michael last_name: Fröba citation: ama: Tiemann M, Schulz M, Jäger C, Fröba M. Mesoporous Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions. Chemistry of Materials. Published online 2001:2885-2891. doi:10.1021/cm011044p apa: Tiemann, M., Schulz, M., Jäger, C., & Fröba, M. (2001). Mesoporous Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions. Chemistry of Materials, 2885–2891. https://doi.org/10.1021/cm011044p bibtex: '@article{Tiemann_Schulz_Jäger_Fröba_2001, title={Mesoporous Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions}, DOI={10.1021/cm011044p}, journal={Chemistry of Materials}, author={Tiemann, Michael and Schulz, Marcus and Jäger, Christian and Fröba, Michael}, year={2001}, pages={2885–2891} }' chicago: Tiemann, Michael, Marcus Schulz, Christian Jäger, and Michael Fröba. “Mesoporous Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions.” Chemistry of Materials, 2001, 2885–91. https://doi.org/10.1021/cm011044p. ieee: 'M. Tiemann, M. Schulz, C. Jäger, and M. Fröba, “Mesoporous Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions,” Chemistry of Materials, pp. 2885–2891, 2001, doi: 10.1021/cm011044p.' mla: Tiemann, Michael, et al. “Mesoporous Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions.” Chemistry of Materials, 2001, pp. 2885–91, doi:10.1021/cm011044p. short: M. Tiemann, M. Schulz, C. Jäger, M. Fröba, Chemistry of Materials (2001) 2885–2891. date_created: 2021-10-09T10:05:36Z date_updated: 2023-03-09T09:10:39Z department: - _id: '35' - _id: '2' - _id: '307' doi: 10.1021/cm011044p extern: '1' language: - iso: eng page: 2885-2891 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published quality_controlled: '1' status: public title: Mesoporous Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions type: journal_article user_id: '23547' year: '2001' ... --- _id: '26002' abstract: - lang: eng text: Over the past few years a growing number of scientists have dedicated their attention to the synthesis of mesostructured aluminophosphates following the concept of supramolecular structure direction. Their research has produced a large variety of synthetic approaches and yielded materials with various structural properties. Today a substantial number of publications have accumulated; this short review provides a general summary of the literature with the aim to display the opportunities for future work. article_type: original author: - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: Michael full_name: Fröba, Michael last_name: Fröba citation: ama: Tiemann M, Fröba M. Mesostructured Aluminophosphates Synthesized with Supramolecular Structure Directors. Chemistry of Materials. Published online 2001:3211-3217. doi:10.1021/cm0110371 apa: Tiemann, M., & Fröba, M. (2001). Mesostructured Aluminophosphates Synthesized with Supramolecular Structure Directors. Chemistry of Materials, 3211–3217. https://doi.org/10.1021/cm0110371 bibtex: '@article{Tiemann_Fröba_2001, title={Mesostructured Aluminophosphates Synthesized with Supramolecular Structure Directors}, DOI={10.1021/cm0110371}, journal={Chemistry of Materials}, author={Tiemann, Michael and Fröba, Michael}, year={2001}, pages={3211–3217} }' chicago: Tiemann, Michael, and Michael Fröba. “Mesostructured Aluminophosphates Synthesized with Supramolecular Structure Directors.” Chemistry of Materials, 2001, 3211–17. https://doi.org/10.1021/cm0110371. ieee: 'M. Tiemann and M. Fröba, “Mesostructured Aluminophosphates Synthesized with Supramolecular Structure Directors,” Chemistry of Materials, pp. 3211–3217, 2001, doi: 10.1021/cm0110371.' mla: Tiemann, Michael, and Michael Fröba. “Mesostructured Aluminophosphates Synthesized with Supramolecular Structure Directors.” Chemistry of Materials, 2001, pp. 3211–17, doi:10.1021/cm0110371. short: M. Tiemann, M. Fröba, Chemistry of Materials (2001) 3211–3217. date_created: 2021-10-09T10:04:55Z date_updated: 2023-03-09T09:10:59Z department: - _id: '35' - _id: '2' - _id: '307' doi: 10.1021/cm0110371 extern: '1' language: - iso: eng page: 3211-3217 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published quality_controlled: '1' status: public title: Mesostructured Aluminophosphates Synthesized with Supramolecular Structure Directors type: journal_article user_id: '23547' year: '2001' ... --- _id: '26005' abstract: - lang: eng text: Mesostructured aluminophosphate/dodecyl phosphate composite materials were synthesized under aqueous and alcoholic conditions. The syntheses were monitored by temperature- and time-resolved in-situ small-angle X-ray scattering (SAXS). In the aqueous synthesis, a lamellar mesostructure is formed within the first few minutes of the reaction; this structure maintains a constant d spacing independent of the reaction time and temperature. The alcoholic synthesis at low temperature yields a mixture of a lamellar and a supposedly inverted hexagonal mesostructure. SAXS investigations show that these two phases evolve competitively. The lamellar structure is favored by higher temperatures and/or longer synthesis times; above ∼70 °C it is formed exclusively. Mixtures of both phases can be isolated as solid materials, but thermal analysis shows that the inverted hexagonal product transforms into the lamellar phase at ∼35−43 °C. The alcoholic synthesis is a highly cooperative reaction; the pure surfactant/alcohol systems are not lyotropic as long as the inorganic reactants are absent. In comparison, the surfactant/water system with the same surfactant concentrations as employed for the aqueous syntheses is lyotropic with a lamellar structure. article_type: original author: - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 - first_name: M. full_name: Fröba, M. last_name: Fröba - first_name: G. full_name: Rapp, G. last_name: Rapp - first_name: S. S. full_name: Funari, S. S. last_name: Funari citation: ama: Tiemann M, Fröba M, Rapp G, Funari SS. Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization, and In-Situ SAXS Studies. Chemistry of Materials. Published online 2000:1342-1348. doi:10.1021/cm991165d apa: Tiemann, M., Fröba, M., Rapp, G., & Funari, S. S. (2000). Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization, and In-Situ SAXS Studies. Chemistry of Materials, 1342–1348. https://doi.org/10.1021/cm991165d bibtex: '@article{Tiemann_Fröba_Rapp_Funari_2000, title={Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization, and In-Situ SAXS Studies}, DOI={10.1021/cm991165d}, journal={Chemistry of Materials}, author={Tiemann, Michael and Fröba, M. and Rapp, G. and Funari, S. S.}, year={2000}, pages={1342–1348} }' chicago: Tiemann, Michael, M. Fröba, G. Rapp, and S. S. Funari. “Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization, and In-Situ SAXS Studies.” Chemistry of Materials, 2000, 1342–48. https://doi.org/10.1021/cm991165d. ieee: 'M. Tiemann, M. Fröba, G. Rapp, and S. S. Funari, “Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization, and In-Situ SAXS Studies,” Chemistry of Materials, pp. 1342–1348, 2000, doi: 10.1021/cm991165d.' mla: Tiemann, Michael, et al. “Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization, and In-Situ SAXS Studies.” Chemistry of Materials, 2000, pp. 1342–48, doi:10.1021/cm991165d. short: M. Tiemann, M. Fröba, G. Rapp, S.S. Funari, Chemistry of Materials (2000) 1342–1348. date_created: 2021-10-09T10:06:55Z date_updated: 2023-03-09T09:09:05Z department: - _id: '35' - _id: '2' - _id: '307' doi: 10.1021/cm991165d extern: '1' language: - iso: eng page: 1342-1348 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published quality_controlled: '1' status: public title: Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization, and In-Situ SAXS Studies type: journal_article user_id: '23547' year: '2000' ... --- _id: '26009' abstract: - lang: eng text: Lamellar mesostructured aluminophosphates were synthesized from aluminum triisopropoxide and phosphoric acid; monododecyl phosphate surfactant was used as structure-directing template. Depending on the relative Al/P ratio in the samples, variable relative amounts of tetrahedrally and octahedrally coordinated Al are found, indicating that both aluminophosphate and aluminum oxide species (as thermodynamically favored) are being formed in the syntheses. This is investigated quantitatively by Al K-edge XANES spectroscopy. The same syntheses were carried out without phosphoric acid, resulting in similar lamellar structures. The inorganic lamellae of these products consist to a significant extent of aluminophosphate rather than exclusively of aluminum oxide, which means that the phosphate headgroups of the surfactant molecules become incorporated into the inorganic network. Thus, for the first time, the surfactant serves as both template and reactant. article_type: original author: - first_name: Michael full_name: Fröba, Michael last_name: Fröba - first_name: Michael full_name: Tiemann, Michael id: '23547' last_name: Tiemann orcid: 0000-0003-1711-2722 citation: ama: Fröba M, Tiemann M. A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates. Chemistry of Materials. Published online 1998:3475-3483. doi:10.1021/cm980712c apa: Fröba, M., & Tiemann, M. (1998). A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates. Chemistry of Materials, 3475–3483. https://doi.org/10.1021/cm980712c bibtex: '@article{Fröba_Tiemann_1998, title={A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates}, DOI={10.1021/cm980712c}, journal={Chemistry of Materials}, author={Fröba, Michael and Tiemann, Michael}, year={1998}, pages={3475–3483} }' chicago: Fröba, Michael, and Michael Tiemann. “A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates.” Chemistry of Materials, 1998, 3475–83. https://doi.org/10.1021/cm980712c. ieee: 'M. Fröba and M. Tiemann, “A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates,” Chemistry of Materials, pp. 3475–3483, 1998, doi: 10.1021/cm980712c.' mla: Fröba, Michael, and Michael Tiemann. “A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates.” Chemistry of Materials, 1998, pp. 3475–83, doi:10.1021/cm980712c. short: M. Fröba, M. Tiemann, Chemistry of Materials (1998) 3475–3483. date_created: 2021-10-09T10:14:44Z date_updated: 2023-03-09T09:07:28Z department: - _id: '35' - _id: '163' - _id: '307' doi: 10.1021/cm980712c extern: '1' language: - iso: eng page: 3475-3483 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published quality_controlled: '1' status: public title: A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates type: journal_article user_id: '23547' year: '1998' ... --- _id: '40301' author: - first_name: Julio full_name: Buey, Julio last_name: Buey - first_name: Laura full_name: Díez, Laura last_name: Díez - first_name: Pablo full_name: Espinet, Pablo last_name: Espinet - first_name: Heinz-Siegfried full_name: Kitzerow, Heinz-Siegfried id: '254' last_name: Kitzerow - first_name: Jesús A. full_name: Miguel, Jesús A. last_name: Miguel citation: ama: Buey J, Díez L, Espinet P, Kitzerow H-S, Miguel JA. Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid Crystal. Chemistry of Materials. 1996;8(9):2375-2381. doi:10.1021/cm960202n apa: Buey, J., Díez, L., Espinet, P., Kitzerow, H.-S., & Miguel, J. A. (1996). Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid Crystal. Chemistry of Materials, 8(9), 2375–2381. https://doi.org/10.1021/cm960202n bibtex: '@article{Buey_Díez_Espinet_Kitzerow_Miguel_1996, title={Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid Crystal}, volume={8}, DOI={10.1021/cm960202n}, number={9}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Buey, Julio and Díez, Laura and Espinet, Pablo and Kitzerow, Heinz-Siegfried and Miguel, Jesús A.}, year={1996}, pages={2375–2381} }' chicago: 'Buey, Julio, Laura Díez, Pablo Espinet, Heinz-Siegfried Kitzerow, and Jesús A. Miguel. “Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid Crystal.” Chemistry of Materials 8, no. 9 (1996): 2375–81. https://doi.org/10.1021/cm960202n.' ieee: 'J. Buey, L. Díez, P. Espinet, H.-S. Kitzerow, and J. A. Miguel, “Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid Crystal,” Chemistry of Materials, vol. 8, no. 9, pp. 2375–2381, 1996, doi: 10.1021/cm960202n.' mla: Buey, Julio, et al. “Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid Crystal.” Chemistry of Materials, vol. 8, no. 9, American Chemical Society (ACS), 1996, pp. 2375–81, doi:10.1021/cm960202n. short: J. Buey, L. Díez, P. Espinet, H.-S. Kitzerow, J.A. Miguel, Chemistry of Materials 8 (1996) 2375–2381. date_created: 2023-01-26T10:47:34Z date_updated: 2023-01-26T11:50:45Z department: - _id: '313' doi: 10.1021/cm960202n extern: '1' intvolume: ' 8' issue: '9' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 2375-2381 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid Crystal type: journal_article user_id: '254' volume: 8 year: '1996' ...