---
_id: '60862'
author:
- first_name: Matthias J.
  full_name: Grotevent, Matthias J.
  last_name: Grotevent
- first_name: Linda
  full_name: Kothe, Linda
  last_name: Kothe
- first_name: Yongli
  full_name: Lu, Yongli
  last_name: Lu
- first_name: Chantalle J.
  full_name: Krajewska, Chantalle J.
  last_name: Krajewska
- first_name: Meng-Chen
  full_name: Shih, Meng-Chen
  last_name: Shih
- first_name: Shaun
  full_name: Tan, Shaun
  last_name: Tan
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Moungi G.
  full_name: Bawendi, Moungi G.
  last_name: Bawendi
citation:
  ama: Grotevent MJ, Kothe L, Lu Y, et al. Nontoxic and Rapid Chemical Bath Deposition
    for SnO<sub>2</sub> Electron Transporting Layers in Perovskite Solar Cells. <i>Chemistry
    of Materials</i>. 2025;37(15):5866–5873. doi:<a href="https://doi.org/10.1021/acs.chemmater.5c01081">10.1021/acs.chemmater.5c01081</a>
  apa: Grotevent, M. J., Kothe, L., Lu, Y., Krajewska, C. J., Shih, M.-C., Tan, S.,
    Tiemann, M., &#38; Bawendi, M. G. (2025). Nontoxic and Rapid Chemical Bath Deposition
    for SnO<sub>2</sub> Electron Transporting Layers in Perovskite Solar Cells. <i>Chemistry
    of Materials</i>, <i>37</i>(15), 5866–5873. <a href="https://doi.org/10.1021/acs.chemmater.5c01081">https://doi.org/10.1021/acs.chemmater.5c01081</a>
  bibtex: '@article{Grotevent_Kothe_Lu_Krajewska_Shih_Tan_Tiemann_Bawendi_2025, title={Nontoxic
    and Rapid Chemical Bath Deposition for SnO<sub>2</sub> Electron Transporting Layers
    in Perovskite Solar Cells}, volume={37}, DOI={<a href="https://doi.org/10.1021/acs.chemmater.5c01081">10.1021/acs.chemmater.5c01081</a>},
    number={15}, journal={Chemistry of Materials}, publisher={American Chemical Society
    (ACS)}, author={Grotevent, Matthias J. and Kothe, Linda and Lu, Yongli and Krajewska,
    Chantalle J. and Shih, Meng-Chen and Tan, Shaun and Tiemann, Michael and Bawendi,
    Moungi G.}, year={2025}, pages={5866–5873} }'
  chicago: 'Grotevent, Matthias J., Linda Kothe, Yongli Lu, Chantalle J. Krajewska,
    Meng-Chen Shih, Shaun Tan, Michael Tiemann, and Moungi G. Bawendi. “Nontoxic and
    Rapid Chemical Bath Deposition for SnO<sub>2</sub> Electron Transporting Layers
    in Perovskite Solar Cells.” <i>Chemistry of Materials</i> 37, no. 15 (2025): 5866–5873.
    <a href="https://doi.org/10.1021/acs.chemmater.5c01081">https://doi.org/10.1021/acs.chemmater.5c01081</a>.'
  ieee: 'M. J. Grotevent <i>et al.</i>, “Nontoxic and Rapid Chemical Bath Deposition
    for SnO<sub>2</sub> Electron Transporting Layers in Perovskite Solar Cells,” <i>Chemistry
    of Materials</i>, vol. 37, no. 15, pp. 5866–5873, 2025, doi: <a href="https://doi.org/10.1021/acs.chemmater.5c01081">10.1021/acs.chemmater.5c01081</a>.'
  mla: Grotevent, Matthias J., et al. “Nontoxic and Rapid Chemical Bath Deposition
    for SnO<sub>2</sub> Electron Transporting Layers in Perovskite Solar Cells.” <i>Chemistry
    of Materials</i>, vol. 37, no. 15, American Chemical Society (ACS), 2025, pp.
    5866–5873, doi:<a href="https://doi.org/10.1021/acs.chemmater.5c01081">10.1021/acs.chemmater.5c01081</a>.
  short: M.J. Grotevent, L. Kothe, Y. Lu, C.J. Krajewska, M.-C. Shih, S. Tan, M. Tiemann,
    M.G. Bawendi, Chemistry of Materials 37 (2025) 5866–5873.
date_created: 2025-08-04T11:40:31Z
date_updated: 2025-08-12T13:37:42Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1021/acs.chemmater.5c01081
intvolume: '        37'
issue: '15'
language:
- iso: eng
page: 5866–5873
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Nontoxic and Rapid Chemical Bath Deposition for SnO<sub>2</sub> Electron Transporting
  Layers in Perovskite Solar Cells
type: journal_article
user_id: '23547'
volume: 37
year: '2025'
...
---
_id: '42517'
author:
- first_name: Kosti
  full_name: Tapio, Kosti
  last_name: Tapio
- first_name: Charlotte
  full_name: Kielar, Charlotte
  last_name: Kielar
- first_name: Johannes M.
  full_name: Parikka, Johannes M.
  last_name: Parikka
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
- first_name: Heini
  full_name: Järvinen, Heini
  last_name: Järvinen
- first_name: Karim
  full_name: Fahmy, Karim
  last_name: Fahmy
- first_name: J. Jussi
  full_name: Toppari, J. Jussi
  last_name: Toppari
citation:
  ama: Tapio K, Kielar C, Parikka JM, et al. Large-Scale Formation of DNA Origami
    Lattices on Silicon. <i>Chemistry of Materials</i>. 2023;35:1961–1971. doi:<a
    href="https://doi.org/10.1021/acs.chemmater.2c03190">10.1021/acs.chemmater.2c03190</a>
  apa: Tapio, K., Kielar, C., Parikka, J. M., Keller, A., Järvinen, H., Fahmy, K.,
    &#38; Toppari, J. J. (2023). Large-Scale Formation of DNA Origami Lattices on
    Silicon. <i>Chemistry of Materials</i>, <i>35</i>, 1961–1971. <a href="https://doi.org/10.1021/acs.chemmater.2c03190">https://doi.org/10.1021/acs.chemmater.2c03190</a>
  bibtex: '@article{Tapio_Kielar_Parikka_Keller_Järvinen_Fahmy_Toppari_2023, title={Large-Scale
    Formation of DNA Origami Lattices on Silicon}, volume={35}, DOI={<a href="https://doi.org/10.1021/acs.chemmater.2c03190">10.1021/acs.chemmater.2c03190</a>},
    journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)},
    author={Tapio, Kosti and Kielar, Charlotte and Parikka, Johannes M. and Keller,
    Adrian and Järvinen, Heini and Fahmy, Karim and Toppari, J. Jussi}, year={2023},
    pages={1961–1971} }'
  chicago: 'Tapio, Kosti, Charlotte Kielar, Johannes M. Parikka, Adrian Keller, Heini
    Järvinen, Karim Fahmy, and J. Jussi Toppari. “Large-Scale Formation of DNA Origami
    Lattices on Silicon.” <i>Chemistry of Materials</i> 35 (2023): 1961–1971. <a href="https://doi.org/10.1021/acs.chemmater.2c03190">https://doi.org/10.1021/acs.chemmater.2c03190</a>.'
  ieee: 'K. Tapio <i>et al.</i>, “Large-Scale Formation of DNA Origami Lattices on
    Silicon,” <i>Chemistry of Materials</i>, vol. 35, pp. 1961–1971, 2023, doi: <a
    href="https://doi.org/10.1021/acs.chemmater.2c03190">10.1021/acs.chemmater.2c03190</a>.'
  mla: Tapio, Kosti, et al. “Large-Scale Formation of DNA Origami Lattices on Silicon.”
    <i>Chemistry of Materials</i>, vol. 35, American Chemical Society (ACS), 2023,
    pp. 1961–1971, doi:<a href="https://doi.org/10.1021/acs.chemmater.2c03190">10.1021/acs.chemmater.2c03190</a>.
  short: K. Tapio, C. Kielar, J.M. Parikka, A. Keller, H. Järvinen, K. Fahmy, J.J.
    Toppari, Chemistry of Materials 35 (2023) 1961–1971.
date_created: 2023-02-27T07:42:33Z
date_updated: 2023-05-05T10:50:56Z
department:
- _id: '302'
doi: 10.1021/acs.chemmater.2c03190
intvolume: '        35'
keyword:
- Materials Chemistry
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 1961–1971
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Large-Scale Formation of DNA Origami Lattices on Silicon
type: journal_article
user_id: '48864'
volume: 35
year: '2023'
...
---
_id: '40993'
abstract:
- lang: eng
  text: Understanding high-temperature unconventional superconductivity has become
    a long-lasting problem in which the cuprates stand as central reference materials.
    Given this impasse, the recent discovery of superconductivity in analogous nickelate
    thin films represents a fundamental breakthrough calling for the identification
    of additional materials in this class. In particular, thermodynamically more robust
    systems are required to “upgrade” nickelate superconductors from thin films to
    bulk samples. Here, we contribute in this direction by reporting the synthesis
    of the new single-layer T′ Pr2NiO3F compound, assessing this synthesis in relation
    to the only previous T′ nickelate La2NiO3F, and analyzing the electronic properties
    across the R2NiO3F series (R = La–Lu) via first-principles calculations. We find
    that these mixed anion systems have a comparatively high degree of stability and
    their synthesis enables a fine-tuning of their composition as inferred from their
    characterization. Furthermore, we find that these unprecedented square-planar
    nickelates hold great promise as prospective superconductors due to their exceptional
    electronic structure.
author:
- first_name: Kerstin
  full_name: Wissel, Kerstin
  last_name: Wissel
- first_name: Fabio
  full_name: Bernardini, Fabio
  last_name: Bernardini
- first_name: Heesu
  full_name: Oh, Heesu
  last_name: Oh
- first_name: Sami
  full_name: Vasala, Sami
  last_name: Vasala
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Björn
  full_name: Blaschkowski, Björn
  last_name: Blaschkowski
- first_name: Pieter
  full_name: Glatzel, Pieter
  last_name: Glatzel
- first_name: Matthias
  full_name: Bauer, Matthias
  id: '47241'
  last_name: Bauer
  orcid: 0000-0002-9294-6076
- first_name: Oliver
  full_name: Clemens, Oliver
  last_name: Clemens
- first_name: Andrés
  full_name: Cano, Andrés
  last_name: Cano
citation:
  ama: 'Wissel K, Bernardini F, Oh H, et al. Single-Layer T′ Nickelates: Synthesis
    of the La and Pr Members and Electronic Properties across the Rare-Earth Series.
    <i>Chemistry of Materials</i>. 2022;34(16):7201-7209. doi:<a href="https://doi.org/10.1021/acs.chemmater.2c00726">10.1021/acs.chemmater.2c00726</a>'
  apa: 'Wissel, K., Bernardini, F., Oh, H., Vasala, S., Schoch, R., Blaschkowski,
    B., Glatzel, P., Bauer, M., Clemens, O., &#38; Cano, A. (2022). Single-Layer T′
    Nickelates: Synthesis of the La and Pr Members and Electronic Properties across
    the Rare-Earth Series. <i>Chemistry of Materials</i>, <i>34</i>(16), 7201–7209.
    <a href="https://doi.org/10.1021/acs.chemmater.2c00726">https://doi.org/10.1021/acs.chemmater.2c00726</a>'
  bibtex: '@article{Wissel_Bernardini_Oh_Vasala_Schoch_Blaschkowski_Glatzel_Bauer_Clemens_Cano_2022,
    title={Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic
    Properties across the Rare-Earth Series}, volume={34}, DOI={<a href="https://doi.org/10.1021/acs.chemmater.2c00726">10.1021/acs.chemmater.2c00726</a>},
    number={16}, journal={Chemistry of Materials}, publisher={American Chemical Society
    (ACS)}, author={Wissel, Kerstin and Bernardini, Fabio and Oh, Heesu and Vasala,
    Sami and Schoch, Roland and Blaschkowski, Björn and Glatzel, Pieter and Bauer,
    Matthias and Clemens, Oliver and Cano, Andrés}, year={2022}, pages={7201–7209}
    }'
  chicago: 'Wissel, Kerstin, Fabio Bernardini, Heesu Oh, Sami Vasala, Roland Schoch,
    Björn Blaschkowski, Pieter Glatzel, Matthias Bauer, Oliver Clemens, and Andrés
    Cano. “Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic
    Properties across the Rare-Earth Series.” <i>Chemistry of Materials</i> 34, no.
    16 (2022): 7201–9. <a href="https://doi.org/10.1021/acs.chemmater.2c00726">https://doi.org/10.1021/acs.chemmater.2c00726</a>.'
  ieee: 'K. Wissel <i>et al.</i>, “Single-Layer T′ Nickelates: Synthesis of the La
    and Pr Members and Electronic Properties across the Rare-Earth Series,” <i>Chemistry
    of Materials</i>, vol. 34, no. 16, pp. 7201–7209, 2022, doi: <a href="https://doi.org/10.1021/acs.chemmater.2c00726">10.1021/acs.chemmater.2c00726</a>.'
  mla: 'Wissel, Kerstin, et al. “Single-Layer T′ Nickelates: Synthesis of the La and
    Pr Members and Electronic Properties across the Rare-Earth Series.” <i>Chemistry
    of Materials</i>, vol. 34, no. 16, American Chemical Society (ACS), 2022, pp.
    7201–09, doi:<a href="https://doi.org/10.1021/acs.chemmater.2c00726">10.1021/acs.chemmater.2c00726</a>.'
  short: K. Wissel, F. Bernardini, H. Oh, S. Vasala, R. Schoch, B. Blaschkowski, P.
    Glatzel, M. Bauer, O. Clemens, A. Cano, Chemistry of Materials 34 (2022) 7201–7209.
date_created: 2023-01-30T16:44:52Z
date_updated: 2023-01-31T08:01:26Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.chemmater.2c00726
intvolume: '        34'
issue: '16'
keyword:
- Materials Chemistry
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 7201-7209
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic
  Properties across the Rare-Earth Series'
type: journal_article
user_id: '48467'
volume: 34
year: '2022'
...
---
_id: '25183'
author:
- first_name: Natalie R.
  full_name: Geise, Natalie R.
  last_name: Geise
- first_name: Robert M.
  full_name: Kasse, Robert M.
  last_name: Kasse
- first_name: Johanna
  full_name: Nelson Weker, Johanna
  last_name: Nelson Weker
- first_name: Hans-Georg
  full_name: Steinrück, Hans-Georg
  id: '84268'
  last_name: Steinrück
  orcid: 0000-0001-6373-0877
- first_name: Michael F.
  full_name: Toney, Michael F.
  last_name: Toney
citation:
  ama: Geise NR, Kasse RM, Nelson Weker J, Steinrück H-G, Toney MF. Quantification
    of Efficiency in Lithium Metal Negative Electrodes via Operando X-ray Diffraction.
    <i>Chemistry of Materials</i>. 2021;33:7537-7545. doi:<a href="https://doi.org/10.1021/acs.chemmater.1c02585">10.1021/acs.chemmater.1c02585</a>
  apa: Geise, N. R., Kasse, R. M., Nelson Weker, J., Steinrück, H.-G., &#38; Toney,
    M. F. (2021). Quantification of Efficiency in Lithium Metal Negative Electrodes
    via Operando X-ray Diffraction. <i>Chemistry of Materials</i>, <i>33</i>, 7537–7545.
    <a href="https://doi.org/10.1021/acs.chemmater.1c02585">https://doi.org/10.1021/acs.chemmater.1c02585</a>
  bibtex: '@article{Geise_Kasse_Nelson Weker_Steinrück_Toney_2021, title={Quantification
    of Efficiency in Lithium Metal Negative Electrodes via Operando X-ray Diffraction},
    volume={33}, DOI={<a href="https://doi.org/10.1021/acs.chemmater.1c02585">10.1021/acs.chemmater.1c02585</a>},
    journal={Chemistry of Materials}, author={Geise, Natalie R. and Kasse, Robert
    M. and Nelson Weker, Johanna and Steinrück, Hans-Georg and Toney, Michael F.},
    year={2021}, pages={7537–7545} }'
  chicago: 'Geise, Natalie R., Robert M. Kasse, Johanna Nelson Weker, Hans-Georg Steinrück,
    and Michael F. Toney. “Quantification of Efficiency in Lithium Metal Negative
    Electrodes via Operando X-Ray Diffraction.” <i>Chemistry of Materials</i> 33 (2021):
    7537–45. <a href="https://doi.org/10.1021/acs.chemmater.1c02585">https://doi.org/10.1021/acs.chemmater.1c02585</a>.'
  ieee: 'N. R. Geise, R. M. Kasse, J. Nelson Weker, H.-G. Steinrück, and M. F. Toney,
    “Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando
    X-ray Diffraction,” <i>Chemistry of Materials</i>, vol. 33, pp. 7537–7545, 2021,
    doi: <a href="https://doi.org/10.1021/acs.chemmater.1c02585">10.1021/acs.chemmater.1c02585</a>.'
  mla: Geise, Natalie R., et al. “Quantification of Efficiency in Lithium Metal Negative
    Electrodes via Operando X-Ray Diffraction.” <i>Chemistry of Materials</i>, vol.
    33, 2021, pp. 7537–45, doi:<a href="https://doi.org/10.1021/acs.chemmater.1c02585">10.1021/acs.chemmater.1c02585</a>.
  short: N.R. Geise, R.M. Kasse, J. Nelson Weker, H.-G. Steinrück, M.F. Toney, Chemistry
    of Materials 33 (2021) 7537–7545.
date_created: 2021-09-30T14:32:12Z
date_updated: 2022-01-06T06:56:54Z
department:
- _id: '633'
doi: 10.1021/acs.chemmater.1c02585
intvolume: '        33'
language:
- iso: eng
page: 7537-7545
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
status: public
title: Quantification of Efficiency in Lithium Metal Negative Electrodes via Operando
  X-ray Diffraction
type: journal_article
user_id: '84268'
volume: 33
year: '2021'
...
---
_id: '25184'
author:
- first_name: Chuntian
  full_name: Cao, Chuntian
  last_name: Cao
- first_name: Travis P.
  full_name: Pollard, Travis P.
  last_name: Pollard
- first_name: Oleg
  full_name: Borodin, Oleg
  last_name: Borodin
- first_name: Julian E.
  full_name: Mars, Julian E.
  last_name: Mars
- first_name: Yuchi
  full_name: Tsao, Yuchi
  last_name: Tsao
- first_name: Maria R.
  full_name: Lukatskaya, Maria R.
  last_name: Lukatskaya
- first_name: Robert M.
  full_name: Kasse, Robert M.
  last_name: Kasse
- first_name: Marshall A.
  full_name: Schroeder, Marshall A.
  last_name: Schroeder
- first_name: Kang
  full_name: Xu, Kang
  last_name: Xu
- first_name: Michael F.
  full_name: Toney, Michael F.
  last_name: Toney
- first_name: Hans-Georg
  full_name: Steinrück, Hans-Georg
  id: '84268'
  last_name: Steinrück
  orcid: 0000-0001-6373-0877
citation:
  ama: Cao C, Pollard TP, Borodin O, et al. Toward Unraveling the Origin of Lithium
    Fluoride in the Solid Electrolyte Interphase. <i>Chemistry of Materials</i>. 2021;33:7315-7336.
    doi:<a href="https://doi.org/10.1021/acs.chemmater.1c01744">10.1021/acs.chemmater.1c01744</a>
  apa: Cao, C., Pollard, T. P., Borodin, O., Mars, J. E., Tsao, Y., Lukatskaya, M.
    R., Kasse, R. M., Schroeder, M. A., Xu, K., Toney, M. F., &#38; Steinrück, H.-G.
    (2021). Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte
    Interphase. <i>Chemistry of Materials</i>, <i>33</i>, 7315–7336. <a href="https://doi.org/10.1021/acs.chemmater.1c01744">https://doi.org/10.1021/acs.chemmater.1c01744</a>
  bibtex: '@article{Cao_Pollard_Borodin_Mars_Tsao_Lukatskaya_Kasse_Schroeder_Xu_Toney_et
    al._2021, title={Toward Unraveling the Origin of Lithium Fluoride in the Solid
    Electrolyte Interphase}, volume={33}, DOI={<a href="https://doi.org/10.1021/acs.chemmater.1c01744">10.1021/acs.chemmater.1c01744</a>},
    journal={Chemistry of Materials}, author={Cao, Chuntian and Pollard, Travis P.
    and Borodin, Oleg and Mars, Julian E. and Tsao, Yuchi and Lukatskaya, Maria R.
    and Kasse, Robert M. and Schroeder, Marshall A. and Xu, Kang and Toney, Michael
    F. and et al.}, year={2021}, pages={7315–7336} }'
  chicago: 'Cao, Chuntian, Travis P. Pollard, Oleg Borodin, Julian E. Mars, Yuchi
    Tsao, Maria R. Lukatskaya, Robert M. Kasse, et al. “Toward Unraveling the Origin
    of Lithium Fluoride in the Solid Electrolyte Interphase.” <i>Chemistry of Materials</i>
    33 (2021): 7315–36. <a href="https://doi.org/10.1021/acs.chemmater.1c01744">https://doi.org/10.1021/acs.chemmater.1c01744</a>.'
  ieee: 'C. Cao <i>et al.</i>, “Toward Unraveling the Origin of Lithium Fluoride in
    the Solid Electrolyte Interphase,” <i>Chemistry of Materials</i>, vol. 33, pp.
    7315–7336, 2021, doi: <a href="https://doi.org/10.1021/acs.chemmater.1c01744">10.1021/acs.chemmater.1c01744</a>.'
  mla: Cao, Chuntian, et al. “Toward Unraveling the Origin of Lithium Fluoride in
    the Solid Electrolyte Interphase.” <i>Chemistry of Materials</i>, vol. 33, 2021,
    pp. 7315–36, doi:<a href="https://doi.org/10.1021/acs.chemmater.1c01744">10.1021/acs.chemmater.1c01744</a>.
  short: C. Cao, T.P. Pollard, O. Borodin, J.E. Mars, Y. Tsao, M.R. Lukatskaya, R.M.
    Kasse, M.A. Schroeder, K. Xu, M.F. Toney, H.-G. Steinrück, Chemistry of Materials
    33 (2021) 7315–7336.
date_created: 2021-09-30T14:32:44Z
date_updated: 2022-01-06T06:56:54Z
department:
- _id: '633'
doi: 10.1021/acs.chemmater.1c01744
intvolume: '        33'
language:
- iso: eng
page: 7315-7336
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
status: public
title: Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase
type: journal_article
user_id: '84268'
volume: 33
year: '2021'
...
---
_id: '41013'
abstract:
- lang: eng
  text: Within this article, it is shown that an electrochemical defluorination and
    additional fluorination of Ruddlesden–Popper-type La2NiO3F2 is possible within
    all-solid-state fluoride-ion batteries. Structural changes within the reduced
    and oxidized phases have been examined by X-ray diffraction studies at different
    states of charging and discharging. The synthesis of the oxidized phase La2NiO3F2+x
    proved to be successful by structural analysis using both X-ray powder diffraction
    and automated electron diffraction tomography techniques. The structural reversibility
    on re-fluorinating and re-defluorinating is also demonstrated. Moreover, the influence
    of different sequences of consecutive reduction and oxidation steps on the formed
    phases has been investigated. The observed structural changes have been compared
    to changes in phases obtained via other topochemical modification approaches such
    as hydride-based reduction and oxidative fluorination using F2 gas, highlighting
    the potential of such electrochemical reactions as alternative synthesis routes.
    Furthermore, the electrochemical routes represent safe and controllable synthesis
    approaches for novel phases, which cannot be synthesized via other topochemical
    methods. Additionally, side reactions, occurring alongside the desired electrochemical
    reactions, have been addressed and the cycling performance has been studied.
article_type: original
author:
- first_name: Kerstin
  full_name: Wissel, Kerstin
  last_name: Wissel
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Tobias
  full_name: Vogel, Tobias
  last_name: Vogel
- first_name: Manuel
  full_name: Donzelli, Manuel
  last_name: Donzelli
- first_name: Galina
  full_name: Matveeva, Galina
  last_name: Matveeva
- first_name: Ute
  full_name: Kolb, Ute
  last_name: Kolb
- first_name: Matthias
  full_name: Bauer, Matthias
  id: '47241'
  last_name: Bauer
  orcid: 0000-0002-9294-6076
- first_name: Peter R.
  full_name: Slater, Peter R.
  last_name: Slater
- first_name: Oliver
  full_name: Clemens, Oliver
  last_name: Clemens
citation:
  ama: Wissel K, Schoch R, Vogel T, et al. Electrochemical Reduction and Oxidation
    of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion
    Batteries. <i>Chemistry of Materials</i>. 2021;33(2):499-512. doi:<a href="https://doi.org/10.1021/acs.chemmater.0c01762">10.1021/acs.chemmater.0c01762</a>
  apa: Wissel, K., Schoch, R., Vogel, T., Donzelli, M., Matveeva, G., Kolb, U., Bauer,
    M., Slater, P. R., &#38; Clemens, O. (2021). Electrochemical Reduction and Oxidation
    of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion
    Batteries. <i>Chemistry of Materials</i>, <i>33</i>(2), 499–512. <a href="https://doi.org/10.1021/acs.chemmater.0c01762">https://doi.org/10.1021/acs.chemmater.0c01762</a>
  bibtex: '@article{Wissel_Schoch_Vogel_Donzelli_Matveeva_Kolb_Bauer_Slater_Clemens_2021,
    title={Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub>
    within Fluoride-Ion Batteries}, volume={33}, DOI={<a href="https://doi.org/10.1021/acs.chemmater.0c01762">10.1021/acs.chemmater.0c01762</a>},
    number={2}, journal={Chemistry of Materials}, publisher={American Chemical Society
    (ACS)}, author={Wissel, Kerstin and Schoch, Roland and Vogel, Tobias and Donzelli,
    Manuel and Matveeva, Galina and Kolb, Ute and Bauer, Matthias and Slater, Peter
    R. and Clemens, Oliver}, year={2021}, pages={499–512} }'
  chicago: 'Wissel, Kerstin, Roland Schoch, Tobias Vogel, Manuel Donzelli, Galina
    Matveeva, Ute Kolb, Matthias Bauer, Peter R. Slater, and Oliver Clemens. “Electrochemical
    Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub>
    within Fluoride-Ion Batteries.” <i>Chemistry of Materials</i> 33, no. 2 (2021):
    499–512. <a href="https://doi.org/10.1021/acs.chemmater.0c01762">https://doi.org/10.1021/acs.chemmater.0c01762</a>.'
  ieee: 'K. Wissel <i>et al.</i>, “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type
    La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries,” <i>Chemistry
    of Materials</i>, vol. 33, no. 2, pp. 499–512, 2021, doi: <a href="https://doi.org/10.1021/acs.chemmater.0c01762">10.1021/acs.chemmater.0c01762</a>.'
  mla: Wissel, Kerstin, et al. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type
    La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub> within Fluoride-Ion Batteries.” <i>Chemistry
    of Materials</i>, vol. 33, no. 2, American Chemical Society (ACS), 2021, pp. 499–512,
    doi:<a href="https://doi.org/10.1021/acs.chemmater.0c01762">10.1021/acs.chemmater.0c01762</a>.
  short: K. Wissel, R. Schoch, T. Vogel, M. Donzelli, G. Matveeva, U. Kolb, M. Bauer,
    P.R. Slater, O. Clemens, Chemistry of Materials 33 (2021) 499–512.
date_created: 2023-01-30T17:01:00Z
date_updated: 2023-01-31T08:07:28Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.chemmater.0c01762
intvolume: '        33'
issue: '2'
keyword:
- Materials Chemistry
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 499-512
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La<sub>2</sub>NiO<sub>3</sub>F<sub>2</sub>
  within Fluoride-Ion Batteries
type: journal_article
user_id: '48467'
volume: 33
year: '2021'
...
---
_id: '23621'
author:
- first_name: Tzu-Yen
  full_name: Huang, Tzu-Yen
  last_name: Huang
- first_name: Felipe A.
  full_name: Larrain, Felipe A.
  last_name: Larrain
- first_name: Carlos H.
  full_name: Borca, Carlos H.
  last_name: Borca
- first_name: Canek
  full_name: Fuentes-Hernandez, Canek
  last_name: Fuentes-Hernandez
- first_name: Hongping
  full_name: Yan, Hongping
  last_name: Yan
- first_name: Sebastian Alexander
  full_name: Schneider, Sebastian Alexander
  last_name: Schneider
- first_name: Wen-Fang
  full_name: Chou, Wen-Fang
  last_name: Chou
- first_name: Victor A.
  full_name: Rodriguez-Toro, Victor A.
  last_name: Rodriguez-Toro
- first_name: Hans-Georg
  full_name: Steinrück, Hans-Georg
  id: '84268'
  last_name: Steinrück
  orcid: 0000-0001-6373-0877
- first_name: Chuntian
  full_name: Cao, Chuntian
  last_name: Cao
- first_name: C. David
  full_name: Sherrill, C. David
  last_name: Sherrill
- first_name: Bernard
  full_name: Kippelen, Bernard
  last_name: Kippelen
- first_name: Michael F.
  full_name: Toney, Michael F.
  last_name: Toney
citation:
  ama: Huang T-Y, Larrain FA, Borca CH, et al. Morphology of Organic Semiconductors
    Electrically Doped from Solution Using Phosphomolybdic Acid. <i>Chemistry of Materials</i>.
    2019;31:6677-6683. doi:<a href="https://doi.org/10.1021/acs.chemmater.9b01069">10.1021/acs.chemmater.9b01069</a>
  apa: Huang, T.-Y., Larrain, F. A., Borca, C. H., Fuentes-Hernandez, C., Yan, H.,
    Schneider, S. A., Chou, W.-F., Rodriguez-Toro, V. A., Steinrück, H.-G., Cao, C.,
    Sherrill, C. D., Kippelen, B., &#38; Toney, M. F. (2019). Morphology of Organic
    Semiconductors Electrically Doped from Solution Using Phosphomolybdic Acid. <i>Chemistry
    of Materials</i>, <i>31</i>, 6677–6683. <a href="https://doi.org/10.1021/acs.chemmater.9b01069">https://doi.org/10.1021/acs.chemmater.9b01069</a>
  bibtex: '@article{Huang_Larrain_Borca_Fuentes-Hernandez_Yan_Schneider_Chou_Rodriguez-Toro_Steinrück_Cao_et
    al._2019, title={Morphology of Organic Semiconductors Electrically Doped from
    Solution Using Phosphomolybdic Acid}, volume={31}, DOI={<a href="https://doi.org/10.1021/acs.chemmater.9b01069">10.1021/acs.chemmater.9b01069</a>},
    journal={Chemistry of Materials}, author={Huang, Tzu-Yen and Larrain, Felipe A.
    and Borca, Carlos H. and Fuentes-Hernandez, Canek and Yan, Hongping and Schneider,
    Sebastian Alexander and Chou, Wen-Fang and Rodriguez-Toro, Victor A. and Steinrück,
    Hans-Georg and Cao, Chuntian and et al.}, year={2019}, pages={6677–6683} }'
  chicago: 'Huang, Tzu-Yen, Felipe A. Larrain, Carlos H. Borca, Canek Fuentes-Hernandez,
    Hongping Yan, Sebastian Alexander Schneider, Wen-Fang Chou, et al. “Morphology
    of Organic Semiconductors Electrically Doped from Solution Using Phosphomolybdic
    Acid.” <i>Chemistry of Materials</i> 31 (2019): 6677–83. <a href="https://doi.org/10.1021/acs.chemmater.9b01069">https://doi.org/10.1021/acs.chemmater.9b01069</a>.'
  ieee: 'T.-Y. Huang <i>et al.</i>, “Morphology of Organic Semiconductors Electrically
    Doped from Solution Using Phosphomolybdic Acid,” <i>Chemistry of Materials</i>,
    vol. 31, pp. 6677–6683, 2019, doi: <a href="https://doi.org/10.1021/acs.chemmater.9b01069">10.1021/acs.chemmater.9b01069</a>.'
  mla: Huang, Tzu-Yen, et al. “Morphology of Organic Semiconductors Electrically Doped
    from Solution Using Phosphomolybdic Acid.” <i>Chemistry of Materials</i>, vol.
    31, 2019, pp. 6677–83, doi:<a href="https://doi.org/10.1021/acs.chemmater.9b01069">10.1021/acs.chemmater.9b01069</a>.
  short: T.-Y. Huang, F.A. Larrain, C.H. Borca, C. Fuentes-Hernandez, H. Yan, S.A.
    Schneider, W.-F. Chou, V.A. Rodriguez-Toro, H.-G. Steinrück, C. Cao, C.D. Sherrill,
    B. Kippelen, M.F. Toney, Chemistry of Materials 31 (2019) 6677–6683.
date_created: 2021-09-01T09:46:52Z
date_updated: 2022-01-06T06:55:57Z
department:
- _id: '633'
doi: 10.1021/acs.chemmater.9b01069
intvolume: '        31'
language:
- iso: eng
page: 6677-6683
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
status: public
title: Morphology of Organic Semiconductors Electrically Doped from Solution Using
  Phosphomolybdic Acid
type: journal_article
user_id: '84268'
volume: 31
year: '2019'
...
---
_id: '41239'
author:
- first_name: Oliver
  full_name: Clemens, Oliver
  last_name: Clemens
- first_name: Matthias
  full_name: Bauer, Matthias
  id: '47241'
  last_name: Bauer
  orcid: 0000-0002-9294-6076
- first_name: Robert
  full_name: Haberkorn, Robert
  last_name: Haberkorn
- first_name: Michael
  full_name: Springborg, Michael
  last_name: Springborg
- first_name: Horst Philipp
  full_name: Beck, Horst Philipp
  last_name: Beck
citation:
  ama: 'Clemens O, Bauer M, Haberkorn R, Springborg M, Beck HP. Synthesis and Characterization
    of Vanadium-Doped LiMnPO<sub>4</sub>-Compounds: LiMn(PO<sub>4</sub>)<sub><i>x</i></sub>(VO<sub>4</sub>)<sub>1–<i>x</i></sub>
    (0.8 ≤ <i>x</i> ≤ 1.0). <i>Chemistry of Materials</i>. 2012;24(24):4717-4724.
    doi:<a href="https://doi.org/10.1021/cm303005d">10.1021/cm303005d</a>'
  apa: 'Clemens, O., Bauer, M., Haberkorn, R., Springborg, M., &#38; Beck, H. P. (2012).
    Synthesis and Characterization of Vanadium-Doped LiMnPO<sub>4</sub>-Compounds:
    LiMn(PO<sub>4</sub>)<sub><i>x</i></sub>(VO<sub>4</sub>)<sub>1–<i>x</i></sub> (0.8
    ≤ <i>x</i> ≤ 1.0). <i>Chemistry of Materials</i>, <i>24</i>(24), 4717–4724. <a
    href="https://doi.org/10.1021/cm303005d">https://doi.org/10.1021/cm303005d</a>'
  bibtex: '@article{Clemens_Bauer_Haberkorn_Springborg_Beck_2012, title={Synthesis
    and Characterization of Vanadium-Doped LiMnPO<sub>4</sub>-Compounds: LiMn(PO<sub>4</sub>)<sub><i>x</i></sub>(VO<sub>4</sub>)<sub>1–<i>x</i></sub>
    (0.8 ≤ <i>x</i> ≤ 1.0)}, volume={24}, DOI={<a href="https://doi.org/10.1021/cm303005d">10.1021/cm303005d</a>},
    number={24}, journal={Chemistry of Materials}, publisher={American Chemical Society
    (ACS)}, author={Clemens, Oliver and Bauer, Matthias and Haberkorn, Robert and
    Springborg, Michael and Beck, Horst Philipp}, year={2012}, pages={4717–4724} }'
  chicago: 'Clemens, Oliver, Matthias Bauer, Robert Haberkorn, Michael Springborg,
    and Horst Philipp Beck. “Synthesis and Characterization of Vanadium-Doped LiMnPO<sub>4</sub>-Compounds:
    LiMn(PO<sub>4</sub>)<sub><i>x</i></sub>(VO<sub>4</sub>)<sub>1–<i>x</i></sub> (0.8
    ≤ <i>x</i> ≤ 1.0).” <i>Chemistry of Materials</i> 24, no. 24 (2012): 4717–24.
    <a href="https://doi.org/10.1021/cm303005d">https://doi.org/10.1021/cm303005d</a>.'
  ieee: 'O. Clemens, M. Bauer, R. Haberkorn, M. Springborg, and H. P. Beck, “Synthesis
    and Characterization of Vanadium-Doped LiMnPO<sub>4</sub>-Compounds: LiMn(PO<sub>4</sub>)<sub><i>x</i></sub>(VO<sub>4</sub>)<sub>1–<i>x</i></sub>
    (0.8 ≤ <i>x</i> ≤ 1.0),” <i>Chemistry of Materials</i>, vol. 24, no. 24, pp. 4717–4724,
    2012, doi: <a href="https://doi.org/10.1021/cm303005d">10.1021/cm303005d</a>.'
  mla: 'Clemens, Oliver, et al. “Synthesis and Characterization of Vanadium-Doped
    LiMnPO<sub>4</sub>-Compounds: LiMn(PO<sub>4</sub>)<sub><i>x</i></sub>(VO<sub>4</sub>)<sub>1–<i>x</i></sub>
    (0.8 ≤ <i>x</i> ≤ 1.0).” <i>Chemistry of Materials</i>, vol. 24, no. 24, American
    Chemical Society (ACS), 2012, pp. 4717–24, doi:<a href="https://doi.org/10.1021/cm303005d">10.1021/cm303005d</a>.'
  short: O. Clemens, M. Bauer, R. Haberkorn, M. Springborg, H.P. Beck, Chemistry of
    Materials 24 (2012) 4717–4724.
date_created: 2023-01-31T14:54:11Z
date_updated: 2023-01-31T14:54:40Z
department:
- _id: '306'
doi: 10.1021/cm303005d
intvolume: '        24'
issue: '24'
keyword:
- Materials Chemistry
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 4717-4724
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Synthesis and Characterization of Vanadium-Doped LiMnPO<sub>4</sub>-Compounds:
  LiMn(PO<sub>4</sub>)<sub><i>x</i></sub>(VO<sub>4</sub>)<sub>1–<i>x</i></sub> (0.8
  ≤ <i>x</i> ≤ 1.0)'
type: journal_article
user_id: '48467'
volume: 24
year: '2012'
...
---
_id: '22608'
author:
- first_name: Tobias B.
  full_name: Thiede, Tobias B.
  last_name: Thiede
- first_name: Michael
  full_name: Krasnopolski, Michael
  last_name: Krasnopolski
- first_name: Andrian P.
  full_name: Milanov, Andrian P.
  last_name: Milanov
- first_name: Maria Teresa
  full_name: de los Arcos de Pedro, Maria Teresa
  id: '54556'
  last_name: de los Arcos de Pedro
- first_name: Andreas
  full_name: Ney, Andreas
  last_name: Ney
- first_name: Hans-Werner
  full_name: Becker, Hans-Werner
  last_name: Becker
- first_name: Detlef
  full_name: Rogalla, Detlef
  last_name: Rogalla
- first_name: Jörg
  full_name: Winter, Jörg
  last_name: Winter
- first_name: Anjana
  full_name: Devi, Anjana
  last_name: Devi
- first_name: Roland A.
  full_name: Fischer, Roland A.
  last_name: Fischer
citation:
  ama: Thiede TB, Krasnopolski M, Milanov AP, et al. Evaluation of Homoleptic Guanidinate
    and Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride
    Thin Films. <i>Chemistry of Materials</i>. Published online 2011:1430-1440. doi:<a
    href="https://doi.org/10.1021/cm102840v">10.1021/cm102840v</a>
  apa: Thiede, T. B., Krasnopolski, M., Milanov, A. P., de los Arcos de Pedro, M.
    T., Ney, A., Becker, H.-W., Rogalla, D., Winter, J., Devi, A., &#38; Fischer,
    R. A. (2011). Evaluation of Homoleptic Guanidinate and Amidinate Complexes of
    Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films. <i>Chemistry
    of Materials</i>, 1430–1440. <a href="https://doi.org/10.1021/cm102840v">https://doi.org/10.1021/cm102840v</a>
  bibtex: '@article{Thiede_Krasnopolski_Milanov_de los Arcos de Pedro_Ney_Becker_Rogalla_Winter_Devi_Fischer_2011,
    title={Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium
    and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films}, DOI={<a href="https://doi.org/10.1021/cm102840v">10.1021/cm102840v</a>},
    journal={Chemistry of Materials}, author={Thiede, Tobias B. and Krasnopolski,
    Michael and Milanov, Andrian P. and de los Arcos de Pedro, Maria Teresa and Ney,
    Andreas and Becker, Hans-Werner and Rogalla, Detlef and Winter, Jörg and Devi,
    Anjana and Fischer, Roland A.}, year={2011}, pages={1430–1440} }'
  chicago: Thiede, Tobias B., Michael Krasnopolski, Andrian P. Milanov, Maria Teresa
    de los Arcos de Pedro, Andreas Ney, Hans-Werner Becker, Detlef Rogalla, Jörg Winter,
    Anjana Devi, and Roland A. Fischer. “Evaluation of Homoleptic Guanidinate and
    Amidinate Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride
    Thin Films.” <i>Chemistry of Materials</i>, 2011, 1430–40. <a href="https://doi.org/10.1021/cm102840v">https://doi.org/10.1021/cm102840v</a>.
  ieee: 'T. B. Thiede <i>et al.</i>, “Evaluation of Homoleptic Guanidinate and Amidinate
    Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films,”
    <i>Chemistry of Materials</i>, pp. 1430–1440, 2011, doi: <a href="https://doi.org/10.1021/cm102840v">10.1021/cm102840v</a>.'
  mla: Thiede, Tobias B., et al. “Evaluation of Homoleptic Guanidinate and Amidinate
    Complexes of Gadolinium and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films.”
    <i>Chemistry of Materials</i>, 2011, pp. 1430–40, doi:<a href="https://doi.org/10.1021/cm102840v">10.1021/cm102840v</a>.
  short: T.B. Thiede, M. Krasnopolski, A.P. Milanov, M.T. de los Arcos de Pedro, A.
    Ney, H.-W. Becker, D. Rogalla, J. Winter, A. Devi, R.A. Fischer, Chemistry of
    Materials (2011) 1430–1440.
date_created: 2021-07-07T11:31:43Z
date_updated: 2023-01-24T08:27:17Z
department:
- _id: '302'
doi: 10.1021/cm102840v
extern: '1'
language:
- iso: eng
page: 1430-1440
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
status: public
title: Evaluation of Homoleptic Guanidinate and Amidinate Complexes of Gadolinium
  and Dysprosium for MOCVD of Rare-Earth Nitride Thin Films
type: journal_article
user_id: '54556'
year: '2011'
...
---
_id: '41990'
author:
- first_name: Janosch
  full_name: Cravillon, Janosch
  last_name: Cravillon
- first_name: Roman
  full_name: Nayuk, Roman
  last_name: Nayuk
- first_name: Sergej
  full_name: Springer, Sergej
  last_name: Springer
- first_name: Armin
  full_name: Feldhoff, Armin
  last_name: Feldhoff
- first_name: Klaus
  full_name: Huber, Klaus
  id: '237'
  last_name: Huber
- first_name: Michael
  full_name: Wiebcke, Michael
  last_name: Wiebcke
citation:
  ama: 'Cravillon J, Nayuk R, Springer S, Feldhoff A, Huber K, Wiebcke M. Controlling
    Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into
    Crystal Growth by Time-Resolved In Situ Static Light Scattering. <i>Chemistry
    of Materials</i>. 2011;23(8):2130-2141. doi:<a href="https://doi.org/10.1021/cm103571y">10.1021/cm103571y</a>'
  apa: 'Cravillon, J., Nayuk, R., Springer, S., Feldhoff, A., Huber, K., &#38; Wiebcke,
    M. (2011). Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation:
    Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering.
    <i>Chemistry of Materials</i>, <i>23</i>(8), 2130–2141. <a href="https://doi.org/10.1021/cm103571y">https://doi.org/10.1021/cm103571y</a>'
  bibtex: '@article{Cravillon_Nayuk_Springer_Feldhoff_Huber_Wiebcke_2011, title={Controlling
    Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into
    Crystal Growth by Time-Resolved In Situ Static Light Scattering}, volume={23},
    DOI={<a href="https://doi.org/10.1021/cm103571y">10.1021/cm103571y</a>}, number={8},
    journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)},
    author={Cravillon, Janosch and Nayuk, Roman and Springer, Sergej and Feldhoff,
    Armin and Huber, Klaus and Wiebcke, Michael}, year={2011}, pages={2130–2141} }'
  chicago: 'Cravillon, Janosch, Roman Nayuk, Sergej Springer, Armin Feldhoff, Klaus
    Huber, and Michael Wiebcke. “Controlling Zeolitic Imidazolate Framework Nano-
    and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ
    Static Light Scattering.” <i>Chemistry of Materials</i> 23, no. 8 (2011): 2130–41.
    <a href="https://doi.org/10.1021/cm103571y">https://doi.org/10.1021/cm103571y</a>.'
  ieee: 'J. Cravillon, R. Nayuk, S. Springer, A. Feldhoff, K. Huber, and M. Wiebcke,
    “Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation:
    Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering,”
    <i>Chemistry of Materials</i>, vol. 23, no. 8, pp. 2130–2141, 2011, doi: <a href="https://doi.org/10.1021/cm103571y">10.1021/cm103571y</a>.'
  mla: 'Cravillon, Janosch, et al. “Controlling Zeolitic Imidazolate Framework Nano-
    and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ
    Static Light Scattering.” <i>Chemistry of Materials</i>, vol. 23, no. 8, American
    Chemical Society (ACS), 2011, pp. 2130–41, doi:<a href="https://doi.org/10.1021/cm103571y">10.1021/cm103571y</a>.'
  short: J. Cravillon, R. Nayuk, S. Springer, A. Feldhoff, K. Huber, M. Wiebcke, Chemistry
    of Materials 23 (2011) 2130–2141.
date_created: 2023-02-10T14:31:09Z
date_updated: 2023-02-10T14:31:32Z
department:
- _id: '314'
doi: 10.1021/cm103571y
intvolume: '        23'
issue: '8'
keyword:
- Materials Chemistry
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 2130-2141
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation:
  Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering'
type: journal_article
user_id: '237'
volume: 23
year: '2011'
...
---
_id: '41997'
author:
- first_name: Janosch
  full_name: Cravillon, Janosch
  last_name: Cravillon
- first_name: Simon
  full_name: Münzer, Simon
  last_name: Münzer
- first_name: Sven-Jare
  full_name: Lohmeier, Sven-Jare
  last_name: Lohmeier
- first_name: Armin
  full_name: Feldhoff, Armin
  last_name: Feldhoff
- first_name: Klaus
  full_name: Huber, Klaus
  id: '237'
  last_name: Huber
- first_name: Michael
  full_name: Wiebcke, Michael
  last_name: Wiebcke
citation:
  ama: Cravillon J, Münzer S, Lohmeier S-J, Feldhoff A, Huber K, Wiebcke M. Rapid
    Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical
    Zeolitic Imidazolate Framework. <i>Chemistry of Materials</i>. 2009;21(8):1410-1412.
    doi:<a href="https://doi.org/10.1021/cm900166h">10.1021/cm900166h</a>
  apa: Cravillon, J., Münzer, S., Lohmeier, S.-J., Feldhoff, A., Huber, K., &#38;
    Wiebcke, M. (2009). Rapid Room-Temperature Synthesis and Characterization of Nanocrystals
    of a Prototypical Zeolitic Imidazolate Framework. <i>Chemistry of Materials</i>,
    <i>21</i>(8), 1410–1412. <a href="https://doi.org/10.1021/cm900166h">https://doi.org/10.1021/cm900166h</a>
  bibtex: '@article{Cravillon_Münzer_Lohmeier_Feldhoff_Huber_Wiebcke_2009, title={Rapid
    Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical
    Zeolitic Imidazolate Framework}, volume={21}, DOI={<a href="https://doi.org/10.1021/cm900166h">10.1021/cm900166h</a>},
    number={8}, journal={Chemistry of Materials}, publisher={American Chemical Society
    (ACS)}, author={Cravillon, Janosch and Münzer, Simon and Lohmeier, Sven-Jare and
    Feldhoff, Armin and Huber, Klaus and Wiebcke, Michael}, year={2009}, pages={1410–1412}
    }'
  chicago: 'Cravillon, Janosch, Simon Münzer, Sven-Jare Lohmeier, Armin Feldhoff,
    Klaus Huber, and Michael Wiebcke. “Rapid Room-Temperature Synthesis and Characterization
    of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework.” <i>Chemistry
    of Materials</i> 21, no. 8 (2009): 1410–12. <a href="https://doi.org/10.1021/cm900166h">https://doi.org/10.1021/cm900166h</a>.'
  ieee: 'J. Cravillon, S. Münzer, S.-J. Lohmeier, A. Feldhoff, K. Huber, and M. Wiebcke,
    “Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical
    Zeolitic Imidazolate Framework,” <i>Chemistry of Materials</i>, vol. 21, no. 8,
    pp. 1410–1412, 2009, doi: <a href="https://doi.org/10.1021/cm900166h">10.1021/cm900166h</a>.'
  mla: Cravillon, Janosch, et al. “Rapid Room-Temperature Synthesis and Characterization
    of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework.” <i>Chemistry
    of Materials</i>, vol. 21, no. 8, American Chemical Society (ACS), 2009, pp. 1410–12,
    doi:<a href="https://doi.org/10.1021/cm900166h">10.1021/cm900166h</a>.
  short: J. Cravillon, S. Münzer, S.-J. Lohmeier, A. Feldhoff, K. Huber, M. Wiebcke,
    Chemistry of Materials 21 (2009) 1410–1412.
date_created: 2023-02-10T14:41:28Z
date_updated: 2023-02-10T14:41:49Z
department:
- _id: '314'
doi: 10.1021/cm900166h
intvolume: '        21'
issue: '8'
keyword:
- Materials Chemistry
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 1410-1412
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a
  Prototypical Zeolitic Imidazolate Framework
type: journal_article
user_id: '237'
volume: 21
year: '2009'
...
---
_id: '25978'
abstract:
- lang: eng
  text: In recent years, a lot of research activity has focused on the synthesis of
    new ordered porous materials by utilization of porous matrices as templates. Since
    the matrices are themselves created by templating procedures, the entire process
    can be envisaged as “repeated templating”. This review describes recent conceptual
    developments in the field of structure replication and summarizes the large number
    of publications on new functional materials prepared by this method.
article_type: review
author:
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: Tiemann M. Repeated Templating. <i>Chemistry of Materials</i>. Published online
    2008:961-971. doi:<a href="https://doi.org/10.1021/cm702050s">10.1021/cm702050s</a>
  apa: Tiemann, M. (2008). Repeated Templating. <i>Chemistry of Materials</i>, 961–971.
    <a href="https://doi.org/10.1021/cm702050s">https://doi.org/10.1021/cm702050s</a>
  bibtex: '@article{Tiemann_2008, title={Repeated Templating}, DOI={<a href="https://doi.org/10.1021/cm702050s">10.1021/cm702050s</a>},
    journal={Chemistry of Materials}, author={Tiemann, Michael}, year={2008}, pages={961–971}
    }'
  chicago: Tiemann, Michael. “Repeated Templating.” <i>Chemistry of Materials</i>,
    2008, 961–71. <a href="https://doi.org/10.1021/cm702050s">https://doi.org/10.1021/cm702050s</a>.
  ieee: 'M. Tiemann, “Repeated Templating,” <i>Chemistry of Materials</i>, pp. 961–971,
    2008, doi: <a href="https://doi.org/10.1021/cm702050s">10.1021/cm702050s</a>.'
  mla: Tiemann, Michael. “Repeated Templating.” <i>Chemistry of Materials</i>, 2008,
    pp. 961–71, doi:<a href="https://doi.org/10.1021/cm702050s">10.1021/cm702050s</a>.
  short: M. Tiemann, Chemistry of Materials (2008) 961–971.
date_created: 2021-10-09T06:51:34Z
date_updated: 2023-03-09T08:47:19Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1021/cm702050s
extern: '1'
language:
- iso: eng
page: 961-971
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
quality_controlled: '1'
status: public
title: Repeated Templating
type: journal_article
user_id: '23547'
year: '2008'
...
---
_id: '25991'
abstract:
- lang: eng
  text: Periodically ordered mesoporous magnesium oxide was synthesized in a double
    replication procedure. Mesoporous SBA-15 silica and CMK-3 carbon were successively
    used as hard structure matrixes. The carbon pore system was infiltrated with Mg(NO3)2,
    which was then converted to MgO at 573 K; the carbon matrix was finally removed
    by thermal combustion. The structure of the mesoporous MgO corresponds to that
    of the original SBA-15 silica. The products consist of hexagonally arranged cylindrical
    mesopores and crystalline pore walls. The efficiency of the replication series
    was studied by variation of the infiltration method and comprehensive pore size
    analysis of all involved mesoporous materials. The in situ formation of MgO inside
    the CMK-3 carbon pore system was monitored by thermal analysis. Postsynthetic
    treatment of the products at 823 K in a vacuum prior to removal of the carbon
    matrix was found to improve the crystallinity but to diminish the periodic order
    of the pore system.
article_type: original
author:
- first_name: Jan
  full_name: Roggenbuck, Jan
  last_name: Roggenbuck
- first_name: Günter
  full_name: Koch, Günter
  last_name: Koch
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: Roggenbuck J, Koch G, Tiemann M. Synthesis of Mesoporous Magnesium Oxide by
    CMK-3 Carbon Structure Replication. <i>Chemistry of Materials</i>. Published online
    2006:4151-4156. doi:<a href="https://doi.org/10.1021/cm060740s">10.1021/cm060740s</a>
  apa: Roggenbuck, J., Koch, G., &#38; Tiemann, M. (2006). Synthesis of Mesoporous
    Magnesium Oxide by CMK-3 Carbon Structure Replication. <i>Chemistry of Materials</i>,
    4151–4156. <a href="https://doi.org/10.1021/cm060740s">https://doi.org/10.1021/cm060740s</a>
  bibtex: '@article{Roggenbuck_Koch_Tiemann_2006, title={Synthesis of Mesoporous Magnesium
    Oxide by CMK-3 Carbon Structure Replication}, DOI={<a href="https://doi.org/10.1021/cm060740s">10.1021/cm060740s</a>},
    journal={Chemistry of Materials}, author={Roggenbuck, Jan and Koch, Günter and
    Tiemann, Michael}, year={2006}, pages={4151–4156} }'
  chicago: Roggenbuck, Jan, Günter Koch, and Michael Tiemann. “Synthesis of Mesoporous
    Magnesium Oxide by CMK-3 Carbon Structure Replication.” <i>Chemistry of Materials</i>,
    2006, 4151–56. <a href="https://doi.org/10.1021/cm060740s">https://doi.org/10.1021/cm060740s</a>.
  ieee: 'J. Roggenbuck, G. Koch, and M. Tiemann, “Synthesis of Mesoporous Magnesium
    Oxide by CMK-3 Carbon Structure Replication,” <i>Chemistry of Materials</i>, pp.
    4151–4156, 2006, doi: <a href="https://doi.org/10.1021/cm060740s">10.1021/cm060740s</a>.'
  mla: Roggenbuck, Jan, et al. “Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon
    Structure Replication.” <i>Chemistry of Materials</i>, 2006, pp. 4151–56, doi:<a
    href="https://doi.org/10.1021/cm060740s">10.1021/cm060740s</a>.
  short: J. Roggenbuck, G. Koch, M. Tiemann, Chemistry of Materials (2006) 4151–4156.
date_created: 2021-10-09T09:45:04Z
date_updated: 2023-03-09T08:58:00Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1021/cm060740s
extern: '1'
language:
- iso: eng
page: 4151-4156
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
quality_controlled: '1'
status: public
title: Synthesis of Mesoporous Magnesium Oxide by CMK-3 Carbon Structure Replication
type: journal_article
user_id: '23547'
year: '2006'
...
---
_id: '25996'
abstract:
- lang: eng
  text: In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic
    Hybrid Materials with Crystal-Like Walls...
article_type: original
author:
- first_name: Jürgen
  full_name: Morell, Jürgen
  last_name: Morell
- first_name: Cilaine V.
  full_name: Teixeira, Cilaine V.
  last_name: Teixeira
- first_name: Maximilian
  full_name: Cornelius, Maximilian
  last_name: Cornelius
- first_name: Vivian
  full_name: Rebbin, Vivian
  last_name: Rebbin
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Heinz
  full_name: Amenitsch, Heinz
  last_name: Amenitsch
- first_name: Michael
  full_name: Fröba, Michael
  last_name: Fröba
- first_name: Mika
  full_name: Lindén, Mika
  last_name: Lindén
citation:
  ama: Morell J, Teixeira CV, Cornelius M, et al. In situ Synchrotron SAXS/XRD Study
    on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls.
    <i>Chemistry of Materials</i>. Published online 2004:5564-5566. doi:<a href="https://doi.org/10.1021/cm048453g">10.1021/cm048453g</a>
  apa: Morell, J., Teixeira, C. V., Cornelius, M., Rebbin, V., Tiemann, M., Amenitsch,
    H., Fröba, M., &#38; Lindén, M. (2004). In situ Synchrotron SAXS/XRD Study on
    the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls.
    <i>Chemistry of Materials</i>, 5564–5566. <a href="https://doi.org/10.1021/cm048453g">https://doi.org/10.1021/cm048453g</a>
  bibtex: '@article{Morell_Teixeira_Cornelius_Rebbin_Tiemann_Amenitsch_Fröba_Lindén_2004,
    title={In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic
    Hybrid Materials with Crystal-Like Walls}, DOI={<a href="https://doi.org/10.1021/cm048453g">10.1021/cm048453g</a>},
    journal={Chemistry of Materials}, author={Morell, Jürgen and Teixeira, Cilaine
    V. and Cornelius, Maximilian and Rebbin, Vivian and Tiemann, Michael and Amenitsch,
    Heinz and Fröba, Michael and Lindén, Mika}, year={2004}, pages={5564–5566} }'
  chicago: Morell, Jürgen, Cilaine V. Teixeira, Maximilian Cornelius, Vivian Rebbin,
    Michael Tiemann, Heinz Amenitsch, Michael Fröba, and Mika Lindén. “In Situ Synchrotron
    SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid Materials with Crystal-Like
    Walls.” <i>Chemistry of Materials</i>, 2004, 5564–66. <a href="https://doi.org/10.1021/cm048453g">https://doi.org/10.1021/cm048453g</a>.
  ieee: 'J. Morell <i>et al.</i>, “In situ Synchrotron SAXS/XRD Study on the Formation
    of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls,” <i>Chemistry
    of Materials</i>, pp. 5564–5566, 2004, doi: <a href="https://doi.org/10.1021/cm048453g">10.1021/cm048453g</a>.'
  mla: Morell, Jürgen, et al. “In Situ Synchrotron SAXS/XRD Study on the Formation
    of Ordered Mesoscopic Hybrid Materials with Crystal-Like Walls.” <i>Chemistry
    of Materials</i>, 2004, pp. 5564–66, doi:<a href="https://doi.org/10.1021/cm048453g">10.1021/cm048453g</a>.
  short: J. Morell, C.V. Teixeira, M. Cornelius, V. Rebbin, M. Tiemann, H. Amenitsch,
    M. Fröba, M. Lindén, Chemistry of Materials (2004) 5564–5566.
date_created: 2021-10-09T09:49:26Z
date_updated: 2023-03-09T09:00:44Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1021/cm048453g
extern: '1'
language:
- iso: eng
page: 5564-5566
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
quality_controlled: '1'
status: public
title: In situ Synchrotron SAXS/XRD Study on the Formation of Ordered Mesoscopic Hybrid
  Materials with Crystal-Like Walls
type: journal_article
user_id: '23547'
year: '2004'
...
---
_id: '26003'
abstract:
- lang: eng
  text: Long-chain n-alkylamine surfactants have been used as structure-directing
    agents in the synthesis of mesoporous aluminophosphates by a highly cooperative
    formation mechanism in an alcoholic system. Small amounts of water in the synthesis
    mixture play a significant role in the hydrolysis of the aluminum precursor (Al[OiPr]3)
    and are important for the quality of the mesostructured products. The materials
    exhibit disordered mesostructures, the stability and structural order of which
    can be improved by a postsynthetic thermal treatment. The products are then stable
    enough for the removal of the surfactant molecules by acidic solvent extraction,
    yielding surface areas up to 690 m2/g.
article_type: original
author:
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Marcus
  full_name: Schulz, Marcus
  last_name: Schulz
- first_name: Christian
  full_name: Jäger, Christian
  last_name: Jäger
- first_name: Michael
  full_name: Fröba, Michael
  last_name: Fröba
citation:
  ama: Tiemann M, Schulz M, Jäger C, Fröba M. Mesoporous Aluminophosphate Molecular
    Sieves Synthesized under Nonaqueous Conditions. <i>Chemistry of Materials</i>.
    Published online 2001:2885-2891. doi:<a href="https://doi.org/10.1021/cm011044p">10.1021/cm011044p</a>
  apa: Tiemann, M., Schulz, M., Jäger, C., &#38; Fröba, M. (2001). Mesoporous Aluminophosphate
    Molecular Sieves Synthesized under Nonaqueous Conditions. <i>Chemistry of Materials</i>,
    2885–2891. <a href="https://doi.org/10.1021/cm011044p">https://doi.org/10.1021/cm011044p</a>
  bibtex: '@article{Tiemann_Schulz_Jäger_Fröba_2001, title={Mesoporous Aluminophosphate
    Molecular Sieves Synthesized under Nonaqueous Conditions}, DOI={<a href="https://doi.org/10.1021/cm011044p">10.1021/cm011044p</a>},
    journal={Chemistry of Materials}, author={Tiemann, Michael and Schulz, Marcus
    and Jäger, Christian and Fröba, Michael}, year={2001}, pages={2885–2891} }'
  chicago: Tiemann, Michael, Marcus Schulz, Christian Jäger, and Michael Fröba. “Mesoporous
    Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions.” <i>Chemistry
    of Materials</i>, 2001, 2885–91. <a href="https://doi.org/10.1021/cm011044p">https://doi.org/10.1021/cm011044p</a>.
  ieee: 'M. Tiemann, M. Schulz, C. Jäger, and M. Fröba, “Mesoporous Aluminophosphate
    Molecular Sieves Synthesized under Nonaqueous Conditions,” <i>Chemistry of Materials</i>,
    pp. 2885–2891, 2001, doi: <a href="https://doi.org/10.1021/cm011044p">10.1021/cm011044p</a>.'
  mla: Tiemann, Michael, et al. “Mesoporous Aluminophosphate Molecular Sieves Synthesized
    under Nonaqueous Conditions.” <i>Chemistry of Materials</i>, 2001, pp. 2885–91,
    doi:<a href="https://doi.org/10.1021/cm011044p">10.1021/cm011044p</a>.
  short: M. Tiemann, M. Schulz, C. Jäger, M. Fröba, Chemistry of Materials (2001)
    2885–2891.
date_created: 2021-10-09T10:05:36Z
date_updated: 2023-03-09T09:10:39Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1021/cm011044p
extern: '1'
language:
- iso: eng
page: 2885-2891
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
quality_controlled: '1'
status: public
title: Mesoporous Aluminophosphate Molecular Sieves Synthesized under Nonaqueous Conditions
type: journal_article
user_id: '23547'
year: '2001'
...
---
_id: '26002'
abstract:
- lang: eng
  text: Over the past few years a growing number of scientists have dedicated their
    attention to the synthesis of mesostructured aluminophosphates following the concept
    of supramolecular structure direction. Their research has produced a large variety
    of synthetic approaches and yielded materials with various structural properties.
    Today a substantial number of publications have accumulated; this short review
    provides a general summary of the literature with the aim to display the opportunities
    for future work.
article_type: original
author:
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Michael
  full_name: Fröba, Michael
  last_name: Fröba
citation:
  ama: Tiemann M, Fröba M. Mesostructured Aluminophosphates Synthesized with Supramolecular
    Structure Directors. <i>Chemistry of Materials</i>. Published online 2001:3211-3217.
    doi:<a href="https://doi.org/10.1021/cm0110371">10.1021/cm0110371</a>
  apa: Tiemann, M., &#38; Fröba, M. (2001). Mesostructured Aluminophosphates Synthesized
    with Supramolecular Structure Directors. <i>Chemistry of Materials</i>, 3211–3217.
    <a href="https://doi.org/10.1021/cm0110371">https://doi.org/10.1021/cm0110371</a>
  bibtex: '@article{Tiemann_Fröba_2001, title={Mesostructured Aluminophosphates Synthesized
    with Supramolecular Structure Directors}, DOI={<a href="https://doi.org/10.1021/cm0110371">10.1021/cm0110371</a>},
    journal={Chemistry of Materials}, author={Tiemann, Michael and Fröba, Michael},
    year={2001}, pages={3211–3217} }'
  chicago: Tiemann, Michael, and Michael Fröba. “Mesostructured Aluminophosphates
    Synthesized with Supramolecular Structure Directors.” <i>Chemistry of Materials</i>,
    2001, 3211–17. <a href="https://doi.org/10.1021/cm0110371">https://doi.org/10.1021/cm0110371</a>.
  ieee: 'M. Tiemann and M. Fröba, “Mesostructured Aluminophosphates Synthesized with
    Supramolecular Structure Directors,” <i>Chemistry of Materials</i>, pp. 3211–3217,
    2001, doi: <a href="https://doi.org/10.1021/cm0110371">10.1021/cm0110371</a>.'
  mla: Tiemann, Michael, and Michael Fröba. “Mesostructured Aluminophosphates Synthesized
    with Supramolecular Structure Directors.” <i>Chemistry of Materials</i>, 2001,
    pp. 3211–17, doi:<a href="https://doi.org/10.1021/cm0110371">10.1021/cm0110371</a>.
  short: M. Tiemann, M. Fröba, Chemistry of Materials (2001) 3211–3217.
date_created: 2021-10-09T10:04:55Z
date_updated: 2023-03-09T09:10:59Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1021/cm0110371
extern: '1'
language:
- iso: eng
page: 3211-3217
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
quality_controlled: '1'
status: public
title: Mesostructured Aluminophosphates Synthesized with Supramolecular Structure
  Directors
type: journal_article
user_id: '23547'
year: '2001'
...
---
_id: '26005'
abstract:
- lang: eng
  text: Mesostructured aluminophosphate/dodecyl phosphate composite materials were
    synthesized under aqueous and alcoholic conditions. The syntheses were monitored
    by temperature- and time-resolved in-situ small-angle X-ray scattering (SAXS).
    In the aqueous synthesis, a lamellar mesostructure is formed within the first
    few minutes of the reaction; this structure maintains a constant d spacing independent
    of the reaction time and temperature. The alcoholic synthesis at low temperature
    yields a mixture of a lamellar and a supposedly inverted hexagonal mesostructure.
    SAXS investigations show that these two phases evolve competitively. The lamellar
    structure is favored by higher temperatures and/or longer synthesis times; above
    ∼70 °C it is formed exclusively. Mixtures of both phases can be isolated as solid
    materials, but thermal analysis shows that the inverted hexagonal product transforms
    into the lamellar phase at ∼35−43 °C. The alcoholic synthesis is a highly cooperative
    reaction; the pure surfactant/alcohol systems are not lyotropic as long as the
    inorganic reactants are absent. In comparison, the surfactant/water system with
    the same surfactant concentrations as employed for the aqueous syntheses is lyotropic
    with a lamellar structure.
article_type: original
author:
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: M.
  full_name: Fröba, M.
  last_name: Fröba
- first_name: G.
  full_name: Rapp, G.
  last_name: Rapp
- first_name: S. S.
  full_name: Funari, S. S.
  last_name: Funari
citation:
  ama: Tiemann M, Fröba M, Rapp G, Funari SS. Nonaqueous Synthesis of Mesostructured
    Aluminophosphate/Surfactant Composites:  Synthesis, Characterization, and In-Situ
    SAXS Studies. <i>Chemistry of Materials</i>. Published online 2000:1342-1348.
    doi:<a href="https://doi.org/10.1021/cm991165d">10.1021/cm991165d</a>
  apa: Tiemann, M., Fröba, M., Rapp, G., &#38; Funari, S. S. (2000). Nonaqueous Synthesis
    of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization,
    and In-Situ SAXS Studies. <i>Chemistry of Materials</i>, 1342–1348. <a href="https://doi.org/10.1021/cm991165d">https://doi.org/10.1021/cm991165d</a>
  bibtex: '@article{Tiemann_Fröba_Rapp_Funari_2000, title={Nonaqueous Synthesis of
    Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization,
    and In-Situ SAXS Studies}, DOI={<a href="https://doi.org/10.1021/cm991165d">10.1021/cm991165d</a>},
    journal={Chemistry of Materials}, author={Tiemann, Michael and Fröba, M. and Rapp,
    G. and Funari, S. S.}, year={2000}, pages={1342–1348} }'
  chicago: Tiemann, Michael, M. Fröba, G. Rapp, and S. S. Funari. “Nonaqueous Synthesis
    of Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization,
    and In-Situ SAXS Studies.” <i>Chemistry of Materials</i>, 2000, 1342–48. <a href="https://doi.org/10.1021/cm991165d">https://doi.org/10.1021/cm991165d</a>.
  ieee: 'M. Tiemann, M. Fröba, G. Rapp, and S. S. Funari, “Nonaqueous Synthesis of
    Mesostructured Aluminophosphate/Surfactant Composites:  Synthesis, Characterization,
    and In-Situ SAXS Studies,” <i>Chemistry of Materials</i>, pp. 1342–1348, 2000,
    doi: <a href="https://doi.org/10.1021/cm991165d">10.1021/cm991165d</a>.'
  mla: Tiemann, Michael, et al. “Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant
    Composites:  Synthesis, Characterization, and In-Situ SAXS Studies.” <i>Chemistry
    of Materials</i>, 2000, pp. 1342–48, doi:<a href="https://doi.org/10.1021/cm991165d">10.1021/cm991165d</a>.
  short: M. Tiemann, M. Fröba, G. Rapp, S.S. Funari, Chemistry of Materials (2000)
    1342–1348.
date_created: 2021-10-09T10:06:55Z
date_updated: 2023-03-09T09:09:05Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1021/cm991165d
extern: '1'
language:
- iso: eng
page: 1342-1348
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
quality_controlled: '1'
status: public
title: Nonaqueous Synthesis of Mesostructured Aluminophosphate/Surfactant Composites: 
  Synthesis, Characterization, and In-Situ SAXS Studies
type: journal_article
user_id: '23547'
year: '2000'
...
---
_id: '26009'
abstract:
- lang: eng
  text: Lamellar mesostructured aluminophosphates were synthesized from aluminum triisopropoxide
    and phosphoric acid; monododecyl phosphate surfactant was used as structure-directing
    template. Depending on the relative Al/P ratio in the samples, variable relative
    amounts of tetrahedrally and octahedrally coordinated Al are found, indicating
    that both aluminophosphate and aluminum oxide species (as thermodynamically favored)
    are being formed in the syntheses. This is investigated quantitatively by Al K-edge
    XANES spectroscopy. The same syntheses were carried out without phosphoric acid,
    resulting in similar lamellar structures. The inorganic lamellae of these products
    consist to a significant extent of aluminophosphate rather than exclusively of
    aluminum oxide, which means that the phosphate headgroups of the surfactant molecules
    become incorporated into the inorganic network. Thus, for the first time, the
    surfactant serves as both template and reactant.
article_type: original
author:
- first_name: Michael
  full_name: Fröba, Michael
  last_name: Fröba
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: Fröba M, Tiemann M. A New Role of the Surfactant in the Synthesis of Mesostructured
    Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates. <i>Chemistry
    of Materials</i>. Published online 1998:3475-3483. doi:<a href="https://doi.org/10.1021/cm980712c">10.1021/cm980712c</a>
  apa: Fröba, M., &#38; Tiemann, M. (1998). A New Role of the Surfactant in the Synthesis
    of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates.
    <i>Chemistry of Materials</i>, 3475–3483. <a href="https://doi.org/10.1021/cm980712c">https://doi.org/10.1021/cm980712c</a>
  bibtex: '@article{Fröba_Tiemann_1998, title={A New Role of the Surfactant in the
    Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant
    for Aluminophosphates}, DOI={<a href="https://doi.org/10.1021/cm980712c">10.1021/cm980712c</a>},
    journal={Chemistry of Materials}, author={Fröba, Michael and Tiemann, Michael},
    year={1998}, pages={3475–3483} }'
  chicago: Fröba, Michael, and Michael Tiemann. “A New Role of the Surfactant in the
    Synthesis of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant
    for Aluminophosphates.” <i>Chemistry of Materials</i>, 1998, 3475–83. <a href="https://doi.org/10.1021/cm980712c">https://doi.org/10.1021/cm980712c</a>.
  ieee: 'M. Fröba and M. Tiemann, “A New Role of the Surfactant in the Synthesis of
    Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates,”
    <i>Chemistry of Materials</i>, pp. 3475–3483, 1998, doi: <a href="https://doi.org/10.1021/cm980712c">10.1021/cm980712c</a>.'
  mla: Fröba, Michael, and Michael Tiemann. “A New Role of the Surfactant in the Synthesis
    of Mesostructured Phases:  Dodecyl Phosphate as Template and Reactant for Aluminophosphates.”
    <i>Chemistry of Materials</i>, 1998, pp. 3475–83, doi:<a href="https://doi.org/10.1021/cm980712c">10.1021/cm980712c</a>.
  short: M. Fröba, M. Tiemann, Chemistry of Materials (1998) 3475–3483.
date_created: 2021-10-09T10:14:44Z
date_updated: 2023-03-09T09:07:28Z
department:
- _id: '35'
- _id: '163'
- _id: '307'
doi: 10.1021/cm980712c
extern: '1'
language:
- iso: eng
page: 3475-3483
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
quality_controlled: '1'
status: public
title: A New Role of the Surfactant in the Synthesis of Mesostructured Phases:  Dodecyl
  Phosphate as Template and Reactant for Aluminophosphates
type: journal_article
user_id: '23547'
year: '1998'
...
---
_id: '40301'
author:
- first_name: Julio
  full_name: Buey, Julio
  last_name: Buey
- first_name: Laura
  full_name: Díez, Laura
  last_name: Díez
- first_name: Pablo
  full_name: Espinet, Pablo
  last_name: Espinet
- first_name: Heinz-Siegfried
  full_name: Kitzerow, Heinz-Siegfried
  id: '254'
  last_name: Kitzerow
- first_name: Jesús A.
  full_name: Miguel, Jesús A.
  last_name: Miguel
citation:
  ama: Buey J, Díez L, Espinet P, Kitzerow H-S, Miguel JA. Platinum Orthometalated
    Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage
    Effect in an Organometallic Liquid Crystal. <i>Chemistry of Materials</i>. 1996;8(9):2375-2381.
    doi:<a href="https://doi.org/10.1021/cm960202n">10.1021/cm960202n</a>
  apa: Buey, J., Díez, L., Espinet, P., Kitzerow, H.-S., &#38; Miguel, J. A. (1996).
    Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues.
    First Optical Storage Effect in an Organometallic Liquid Crystal. <i>Chemistry
    of Materials</i>, <i>8</i>(9), 2375–2381. <a href="https://doi.org/10.1021/cm960202n">https://doi.org/10.1021/cm960202n</a>
  bibtex: '@article{Buey_Díez_Espinet_Kitzerow_Miguel_1996, title={Platinum Orthometalated
    Liquid Crystals Compared with Their Palladium Analogues. First Optical Storage
    Effect in an Organometallic Liquid Crystal}, volume={8}, DOI={<a href="https://doi.org/10.1021/cm960202n">10.1021/cm960202n</a>},
    number={9}, journal={Chemistry of Materials}, publisher={American Chemical Society
    (ACS)}, author={Buey, Julio and Díez, Laura and Espinet, Pablo and Kitzerow, Heinz-Siegfried
    and Miguel, Jesús A.}, year={1996}, pages={2375–2381} }'
  chicago: 'Buey, Julio, Laura Díez, Pablo Espinet, Heinz-Siegfried Kitzerow, and
    Jesús A. Miguel. “Platinum Orthometalated Liquid Crystals Compared with Their
    Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid
    Crystal.” <i>Chemistry of Materials</i> 8, no. 9 (1996): 2375–81. <a href="https://doi.org/10.1021/cm960202n">https://doi.org/10.1021/cm960202n</a>.'
  ieee: 'J. Buey, L. Díez, P. Espinet, H.-S. Kitzerow, and J. A. Miguel, “Platinum
    Orthometalated Liquid Crystals Compared with Their Palladium Analogues. First
    Optical Storage Effect in an Organometallic Liquid Crystal,” <i>Chemistry of Materials</i>,
    vol. 8, no. 9, pp. 2375–2381, 1996, doi: <a href="https://doi.org/10.1021/cm960202n">10.1021/cm960202n</a>.'
  mla: Buey, Julio, et al. “Platinum Orthometalated Liquid Crystals Compared with
    Their Palladium Analogues. First Optical Storage Effect in an Organometallic Liquid
    Crystal.” <i>Chemistry of Materials</i>, vol. 8, no. 9, American Chemical Society
    (ACS), 1996, pp. 2375–81, doi:<a href="https://doi.org/10.1021/cm960202n">10.1021/cm960202n</a>.
  short: J. Buey, L. Díez, P. Espinet, H.-S. Kitzerow, J.A. Miguel, Chemistry of Materials
    8 (1996) 2375–2381.
date_created: 2023-01-26T10:47:34Z
date_updated: 2023-01-26T11:50:45Z
department:
- _id: '313'
doi: 10.1021/cm960202n
extern: '1'
intvolume: '         8'
issue: '9'
keyword:
- Materials Chemistry
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 2375-2381
publication: Chemistry of Materials
publication_identifier:
  issn:
  - 0897-4756
  - 1520-5002
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Platinum Orthometalated Liquid Crystals Compared with Their Palladium Analogues.
  First Optical Storage Effect in an Organometallic Liquid Crystal
type: journal_article
user_id: '254'
volume: 8
year: '1996'
...