---
_id: '60600'
abstract:
- lang: eng
text: In the search for noble metal free photocatalytic systems, iron is the dream
candidate. To increase excited state lifetimes of iron complexes, the multichromophoric
approach is promising, combining organic chromophores with photoactive iron complexes,
potentially enabling a reservoir effect. We present a series of chromophore-functionalized
complexes based on the parental FeIII complex [Fe(ImP)2][PF6] (HImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazole-2-ylidene)).
The four organic chromophores benzene, naphthalene, anthracene, and pyrene are
attached to the ImP-ligand in para-position to the coordination site to systematically
investigate the influence of the steric demand and electronic properties of the
chromophore on charge transfer lifetimes as well as photodynamics. A thorough
ground state characterization was conducted in addition to investigations of the
excited state dynamics by transient absorption spectroscopy and streak camera
emission measurements. The conclusions drawn are supported by extensive DFT calculations.
The emission coefficients could be significantly improved by the addition of chromophores.
After excitation of the complexes with larger chromophores, coplanarization of
the backbone and complex motif occurs to stabilize the formal charge. This results
in population of a superligand state that exhibits a much faster radiationless
relaxation to the ground state compared to the parent complex, hindering a reservoir
effect.
article_number: acs.inorgchem.5c00526
author:
- first_name: Lennart
full_name: Schmitz, Lennart
id: '53140'
last_name: Schmitz
- first_name: Miguel A.
full_name: Argüello Cordero, Miguel A.
last_name: Argüello Cordero
- first_name: Mohammed J.
full_name: Al-Marri, Mohammed J.
last_name: Al-Marri
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Hans
full_name: Egold, Hans
id: '101'
last_name: Egold
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Bastian Johannes
full_name: Bracht, Bastian Johannes
id: '86707'
last_name: Bracht
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Schmitz L, Argüello Cordero MA, Al-Marri MJ, et al. Chromophore Induced Effects
in Iron(III) Complexes. Inorganic Chemistry. Published online 2025. doi:10.1021/acs.inorgchem.5c00526
apa: Schmitz, L., Argüello Cordero, M. A., Al-Marri, M. J., Schoch, R., Egold, H.,
Neuba, A., Steube, J., Bracht, B. J., Bokareva, O. S., Lochbrunner, S., &
Bauer, M. (2025). Chromophore Induced Effects in Iron(III) Complexes. Inorganic
Chemistry, Article acs. inorgchem.5c00526. https://doi.org/10.1021/acs.inorgchem.5c00526
bibtex: '@article{Schmitz_Argüello Cordero_Al-Marri_Schoch_Egold_Neuba_Steube_Bracht_Bokareva_Lochbrunner_et
al._2025, title={Chromophore Induced Effects in Iron(III) Complexes}, DOI={10.1021/acs.inorgchem.5c00526},
number={acs. inorgchem.5c00526}, journal={Inorganic Chemistry}, publisher={American
Chemical Society (ACS)}, author={Schmitz, Lennart and Argüello Cordero, Miguel
A. and Al-Marri, Mohammed J. and Schoch, Roland and Egold, Hans and Neuba, Adam
and Steube, Jakob and Bracht, Bastian Johannes and Bokareva, Olga S. and Lochbrunner,
Stefan and et al.}, year={2025} }'
chicago: Schmitz, Lennart, Miguel A. Argüello Cordero, Mohammed J. Al-Marri, Roland
Schoch, Hans Egold, Adam Neuba, Jakob Steube, et al. “Chromophore Induced Effects
in Iron(III) Complexes.” Inorganic Chemistry, 2025. https://doi.org/10.1021/acs.inorgchem.5c00526.
ieee: 'L. Schmitz et al., “Chromophore Induced Effects in Iron(III) Complexes,”
Inorganic Chemistry, Art. no. acs. inorgchem.5c00526, 2025, doi: 10.1021/acs.inorgchem.5c00526.'
mla: Schmitz, Lennart, et al. “Chromophore Induced Effects in Iron(III) Complexes.”
Inorganic Chemistry, acs. inorgchem.5c00526, American Chemical Society
(ACS), 2025, doi:10.1021/acs.inorgchem.5c00526.
short: L. Schmitz, M.A. Argüello Cordero, M.J. Al-Marri, R. Schoch, H. Egold, A.
Neuba, J. Steube, B.J. Bracht, O.S. Bokareva, S. Lochbrunner, M. Bauer, Inorganic
Chemistry (2025).
date_created: 2025-07-14T08:49:25Z
date_updated: 2025-08-15T12:18:08Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.5c00526
keyword:
- Photo
language:
- iso: eng
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Chromophore Induced Effects in Iron(III) Complexes
type: journal_article
user_id: '48467'
year: '2025'
...
---
_id: '58180'
abstract:
- lang: eng
text: 'A series of CoIII complexes [Co(RImP)2][PF6], with HMeImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazole-2-ylidene))
and R = Me, Et, iPr, nBu, is presented in this work. The influence of the strong
donor ligand on the ground and excited-state photophysical properties was investigated
in the context of different alkyl substituents at the imidazole nitrogen. X-ray
diffraction revealed no significant alterations of the structures and all differences
in the series emerge from the electronic structures. These were probed via cyclic
voltammetry and UV–vis spectroscopy, detailing the influence of the different
alkyl substituents on the ground-state properties. All complexes are emissive
at 77 K from a 3MC state, which exhibits lifetimes in the range of 1–5 ns at room
temperature, depending on the alkyl substituent. Therefore, it is clearly shown
that even small differences in the electronic structure have a large impact on
the details of the excited state landscape. The observed behavior was rationalized
by a detailed DFT analysis, which shows that the minimum-energy crossing point
to the ground-state is located only slightly above the MC energy: Consequently,
nonradiative decay to the ground state at room temperature is enabled, while at
77 K this path is prohibited, leading to low-temperature 3MC emission.'
author:
- first_name: Athul
full_name: Krishna, Athul
last_name: Krishna
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Miguel A.
full_name: Argüello Cordero, Miguel A.
last_name: Argüello Cordero
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Krishna A, Fritsch L, Steube J, et al. Low Temperature Emissive Cyclometalated
Cobalt(III) Complexes. Inorganic Chemistry. Published online 2025. doi:10.1021/acs.inorgchem.4c04479
apa: Krishna, A., Fritsch, L., Steube, J., Argüello Cordero, M. A., Schoch, R.,
Neuba, A., Lochbrunner, S., & Bauer, M. (2025). Low Temperature Emissive Cyclometalated
Cobalt(III) Complexes. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.4c04479
bibtex: '@article{Krishna_Fritsch_Steube_Argüello Cordero_Schoch_Neuba_Lochbrunner_Bauer_2025,
title={Low Temperature Emissive Cyclometalated Cobalt(III) Complexes}, DOI={10.1021/acs.inorgchem.4c04479},
journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Krishna,
Athul and Fritsch, Lorena and Steube, Jakob and Argüello Cordero, Miguel A. and
Schoch, Roland and Neuba, Adam and Lochbrunner, Stefan and Bauer, Matthias}, year={2025}
}'
chicago: Krishna, Athul, Lorena Fritsch, Jakob Steube, Miguel A. Argüello Cordero,
Roland Schoch, Adam Neuba, Stefan Lochbrunner, and Matthias Bauer. “Low Temperature
Emissive Cyclometalated Cobalt(III) Complexes.” Inorganic Chemistry, 2025.
https://doi.org/10.1021/acs.inorgchem.4c04479.
ieee: 'A. Krishna et al., “Low Temperature Emissive Cyclometalated Cobalt(III)
Complexes,” Inorganic Chemistry, 2025, doi: 10.1021/acs.inorgchem.4c04479.'
mla: Krishna, Athul, et al. “Low Temperature Emissive Cyclometalated Cobalt(III)
Complexes.” Inorganic Chemistry, American Chemical Society (ACS), 2025,
doi:10.1021/acs.inorgchem.4c04479.
short: A. Krishna, L. Fritsch, J. Steube, M.A. Argüello Cordero, R. Schoch, A. Neuba,
S. Lochbrunner, M. Bauer, Inorganic Chemistry (2025).
date_created: 2025-01-15T08:29:21Z
date_updated: 2025-08-15T12:30:18Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.4c04479
keyword:
- Photo
language:
- iso: eng
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Low Temperature Emissive Cyclometalated Cobalt(III) Complexes
type: journal_article
user_id: '48467'
year: '2025'
...
---
_id: '56075'
abstract:
- lang: eng
text: An isostructural series of FeII, FeIII, and Fe(IV)complexes [Fe(ImP)2]0/+/2+
utilizing the ImP 1,1′-(1,3-phenylene)-bis(3-methyl-1-imidazol-2-ylidene) ligand,
combining N-heterocy-clic carbenes and cyclometalating functions, is presented.
The strong donor motif stabilizes the high-valent Fe(IV) oxidation state yet keeps
the FeII oxidation state accessible from the parent Fe(III)compound. Chemical
oxidation of [Fe(ImP)2]+ yields stable [FeIV(ImP)2]2+. In contrast, [FeII(ImP)2]0,
obtained by reduction,is highly sensitive toward oxygen. Exhaustive ground state
characterization by single-crystal X-ray diffraction, 1H NMR,Mössbauer spectroscopy,
temperature-dependent magnetic measurements, a combination of X-ray absorption
near edge structureand valence-to-core, as well as core-to-core X-ray emission
spectroscopy, complemented by detailed density functional theory (DFT) analysis,
reveals that the three complexes[Fe(ImP)2]0/+/2+ can be unequivocally attributed
to low-spin d6, d5, and d4 complexes. The excited state landscape of the Fe(II)
and Fe(IV) complexes is characterized by short-lived 3MLCT and 3LMCT states, with
lifetimes of 5.1 and 1.4 ps, respectively. In the FeII-compound, an energetically
low-lying MC state leads to fast deactivation of the MLCT state. The distorted
square-pyramidal state, where one carbene is dissociated, can not only relax into
the ground state, but also into a singlet dissociated state. Its formation was
investigated with time-dependent optical spectroscopy, while insights into its
structure were gained by NMR spectroscopy.
author:
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Ayla
full_name: Kruse, Ayla
last_name: Kruse
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Serhiy
full_name: Demeshko, Serhiy
last_name: Demeshko
- first_name: Hossam
full_name: Elgabarty, Hossam
id: '60250'
last_name: Elgabarty
orcid: 0000-0002-4945-1481
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Mohammad
full_name: Alaraby, Mohammad
last_name: Alaraby
- first_name: Hans
full_name: Egold, Hans
id: '101'
last_name: Egold
- first_name: Bastian Johannes
full_name: Bracht, Bastian Johannes
id: '86707'
last_name: Bracht
- first_name: Lennart
full_name: Schmitz, Lennart
id: '53140'
last_name: Schmitz
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Franc
full_name: Meyer, Franc
last_name: Meyer
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Steube J, Fritsch L, Kruse A, et al. Isostructural Series of a Cyclometalated
Iron Complex in Three Oxidation States. Inorganic Chemistry. Published
online 2024. doi:10.1021/acs.inorgchem.4c02576
apa: Steube, J., Fritsch, L., Kruse, A., Bokareva, O. S., Demeshko, S., Elgabarty,
H., Schoch, R., Alaraby, M., Egold, H., Bracht, B. J., Schmitz, L., Hohloch, S.,
Kühne, T. D., Meyer, F., Kühn, O., Lochbrunner, S., & Bauer, M. (2024). Isostructural
Series of a Cyclometalated Iron Complex in Three Oxidation States. Inorganic
Chemistry. https://doi.org/10.1021/acs.inorgchem.4c02576
bibtex: '@article{Steube_Fritsch_Kruse_Bokareva_Demeshko_Elgabarty_Schoch_Alaraby_Egold_Bracht_et
al._2024, title={Isostructural Series of a Cyclometalated Iron Complex in Three
Oxidation States}, DOI={10.1021/acs.inorgchem.4c02576},
journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Steube,
Jakob and Fritsch, Lorena and Kruse, Ayla and Bokareva, Olga S. and Demeshko,
Serhiy and Elgabarty, Hossam and Schoch, Roland and Alaraby, Mohammad and Egold,
Hans and Bracht, Bastian Johannes and et al.}, year={2024} }'
chicago: Steube, Jakob, Lorena Fritsch, Ayla Kruse, Olga S. Bokareva, Serhiy Demeshko,
Hossam Elgabarty, Roland Schoch, et al. “Isostructural Series of a Cyclometalated
Iron Complex in Three Oxidation States.” Inorganic Chemistry, 2024. https://doi.org/10.1021/acs.inorgchem.4c02576.
ieee: 'J. Steube et al., “Isostructural Series of a Cyclometalated Iron Complex
in Three Oxidation States,” Inorganic Chemistry, 2024, doi: 10.1021/acs.inorgchem.4c02576.'
mla: Steube, Jakob, et al. “Isostructural Series of a Cyclometalated Iron Complex
in Three Oxidation States.” Inorganic Chemistry, American Chemical Society
(ACS), 2024, doi:10.1021/acs.inorgchem.4c02576.
short: J. Steube, L. Fritsch, A. Kruse, O.S. Bokareva, S. Demeshko, H. Elgabarty,
R. Schoch, M. Alaraby, H. Egold, B.J. Bracht, L. Schmitz, S. Hohloch, T.D. Kühne,
F. Meyer, O. Kühn, S. Lochbrunner, M. Bauer, Inorganic Chemistry (2024).
date_created: 2024-09-05T11:34:20Z
date_updated: 2025-08-15T12:17:35Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.4c02576
keyword:
- Photo
language:
- iso: eng
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Isostructural Series of a Cyclometalated Iron Complex in Three Oxidation States
type: journal_article
user_id: '48467'
year: '2024'
...
---
_id: '52345'
abstract:
- lang: eng
text: Photoactive chromium(III) complexes saw a conceptual breakthrough with the
discovery of the prototypical molecular ruby mer-[Cr(ddpd)2]3+ (ddpd = N,N′-dimethyl-N,N′-dipyridin-2-ylpyridine-2,6-diamine),
which shows intense long-lived near-infrared (NIR) phosphorescence from metal-centered
spin-flip states. In contrast to the numerous studies on chromium(III) photophysics,
only 10 luminescent molybdenum(III) complexes have been reported so far. Here,
we present the synthesis and characterization of mer-MoX3(ddpd) (1, X = Cl; 2,
X = Br) and cisfac-[Mo(ddpd)2]3+ (cisfac-[3]3+), an isomeric heavy homologue of
the prototypical molecular ruby. For cisfac-[3]3+, we found strong zero-field
splitting using magnetic susceptibility measurements and electron paramagnetic
resonance spectroscopy. Electronic spectra covering the spin-forbidden transitions
show that the spin-flip states in mer-1, mer-2, and cisfac-[3]3+ are much lower
in energy than those in comparable chromium(III) compounds. While all three complexes
show weak spin-flip phosphorescence in NIR-II, the emission of cisfac-[3]3+ peaking
at 1550 nm is particularly low in energy. Femtosecond transient absorption spectroscopy
reveals a short excited-state lifetime of 1.4 ns, 6 orders of magnitude shorter
than that of mer-[Cr(ddpd)2]3+. Using density functional theory and ab initio
multireference calculations, we break down the reasons for this disparity and
derive principles for the design of future stable photoactive molybdenum(III)
complexes.
article_type: original
author:
- first_name: Winald R.
full_name: Kitzmann, Winald R.
last_name: Kitzmann
- first_name: David
full_name: Hunger, David
last_name: Hunger
- first_name: Antti-Pekka M.
full_name: Reponen, Antti-Pekka M.
last_name: Reponen
- first_name: Christoph
full_name: Förster, Christoph
last_name: Förster
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Sascha
full_name: Feldmann, Sascha
last_name: Feldmann
- first_name: Joris
full_name: van Slageren, Joris
last_name: van Slageren
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
citation:
ama: Kitzmann WR, Hunger D, Reponen A-PM, et al. Electronic Structure and Excited-State
Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby.
Inorganic Chemistry. 2023;62(39):15797-15808. doi:10.1021/acs.inorgchem.3c02186
apa: Kitzmann, W. R., Hunger, D., Reponen, A.-P. M., Förster, C., Schoch, R., Bauer,
M., Feldmann, S., van Slageren, J., & Heinze, K. (2023). Electronic Structure
and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to
the Molecular Ruby. Inorganic Chemistry, 62(39), 15797–15808. https://doi.org/10.1021/acs.inorgchem.3c02186
bibtex: '@article{Kitzmann_Hunger_Reponen_Förster_Schoch_Bauer_Feldmann_van Slageren_Heinze_2023,
title={Electronic Structure and Excited-State Dynamics of the NIR-II Emissive
Molybdenum(III) Analogue to the Molecular Ruby}, volume={62}, DOI={10.1021/acs.inorgchem.3c02186},
number={39}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Kitzmann, Winald R. and Hunger, David and Reponen, Antti-Pekka
M. and Förster, Christoph and Schoch, Roland and Bauer, Matthias and Feldmann,
Sascha and van Slageren, Joris and Heinze, Katja}, year={2023}, pages={15797–15808}
}'
chicago: 'Kitzmann, Winald R., David Hunger, Antti-Pekka M. Reponen, Christoph Förster,
Roland Schoch, Matthias Bauer, Sascha Feldmann, Joris van Slageren, and Katja
Heinze. “Electronic Structure and Excited-State Dynamics of the NIR-II Emissive
Molybdenum(III) Analogue to the Molecular Ruby.” Inorganic Chemistry 62,
no. 39 (2023): 15797–808. https://doi.org/10.1021/acs.inorgchem.3c02186.'
ieee: 'W. R. Kitzmann et al., “Electronic Structure and Excited-State Dynamics
of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby,” Inorganic
Chemistry, vol. 62, no. 39, pp. 15797–15808, 2023, doi: 10.1021/acs.inorgchem.3c02186.'
mla: Kitzmann, Winald R., et al. “Electronic Structure and Excited-State Dynamics
of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby.” Inorganic
Chemistry, vol. 62, no. 39, American Chemical Society (ACS), 2023, pp. 15797–808,
doi:10.1021/acs.inorgchem.3c02186.
short: W.R. Kitzmann, D. Hunger, A.-P.M. Reponen, C. Förster, R. Schoch, M. Bauer,
S. Feldmann, J. van Slageren, K. Heinze, Inorganic Chemistry 62 (2023) 15797–15808.
date_created: 2024-03-07T09:57:30Z
date_updated: 2024-03-07T10:02:58Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.3c02186
intvolume: ' 62'
issue: '39'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 15797-15808
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III)
Analogue to the Molecular Ruby
type: journal_article
user_id: '48467'
volume: 62
year: '2023'
...
---
_id: '62854'
abstract:
- lang: eng
text: Highly selective rare-earth separation has become increasingly important due
to the indispensable role of these elements in various cutting-edge technologies
including clean energy. However, the similar physicochemical properties of rare-earth
elements (REEs) render their separation very challenging, and the development
of new selective receptors for these elements is potentially of very considerable
economic and environmental importance. Herein, we report the development of a
series of 4-phosphoryl pyrazolone receptors for the selective separation of trivalent
lanthanum, europium, and ytterbium as the representatives of light, middle, and
heavy REEs, respectively. X-ray crystallography studies were employed to obtain
solid-state structures across 11 of the resulting complexes, allowing comparative
structure–function relationships to be probed, including the effect of lanthanide
contraction that occurs along the series from lanthanum to europium to ytterbium
and which potentially provides a basis for REE ion separation. In addition, the
influence of ligand structure and lipophilicity on lanthanide binding and selectivity
was systematically investigated via n-octanol/water distribution and liquid–liquid
extraction (LLE) studies. Corresponding stoichiometry relationships between solid
and solution states were well established using slope analyses. The results provide
new insights into some fundamental lanthanide coordination chemistry from a separation
perspective and establish 4-phosphoryl pyrazolone derivatives as potential practical
extraction reagents for the selective separation of REEs in the future.
author:
- first_name: Jianfeng
full_name: Zhang, Jianfeng
last_name: Zhang
- first_name: Marco
full_name: Wenzel, Marco
last_name: Wenzel
- first_name: Kathleen
full_name: Schnaars, Kathleen
id: '117735'
last_name: Schnaars
- first_name: Felix
full_name: Hennersdorf, Felix
last_name: Hennersdorf
- first_name: Leonard F.
full_name: Lindoy, Leonard F.
last_name: Lindoy
- first_name: Jan J.
full_name: Weigand, Jan J.
last_name: Weigand
citation:
ama: Zhang J, Wenzel M, Schnaars K, Hennersdorf F, Lindoy LF, Weigand JJ. Highly
Tunable 4-Phosphoryl Pyrazolone Receptors for Selective Rare-Earth Separation.
Inorganic Chemistry. 2023;62(7):3212-3228. doi:10.1021/acs.inorgchem.2c04221
apa: Zhang, J., Wenzel, M., Schnaars, K., Hennersdorf, F., Lindoy, L. F., &
Weigand, J. J. (2023). Highly Tunable 4-Phosphoryl Pyrazolone Receptors for Selective
Rare-Earth Separation. Inorganic Chemistry, 62(7), 3212–3228. https://doi.org/10.1021/acs.inorgchem.2c04221
bibtex: '@article{Zhang_Wenzel_Schnaars_Hennersdorf_Lindoy_Weigand_2023, title={Highly
Tunable 4-Phosphoryl Pyrazolone Receptors for Selective Rare-Earth Separation},
volume={62}, DOI={10.1021/acs.inorgchem.2c04221},
number={7}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Zhang, Jianfeng and Wenzel, Marco and Schnaars, Kathleen and Hennersdorf,
Felix and Lindoy, Leonard F. and Weigand, Jan J.}, year={2023}, pages={3212–3228}
}'
chicago: 'Zhang, Jianfeng, Marco Wenzel, Kathleen Schnaars, Felix Hennersdorf, Leonard
F. Lindoy, and Jan J. Weigand. “Highly Tunable 4-Phosphoryl Pyrazolone Receptors
for Selective Rare-Earth Separation.” Inorganic Chemistry 62, no. 7 (2023):
3212–28. https://doi.org/10.1021/acs.inorgchem.2c04221.'
ieee: 'J. Zhang, M. Wenzel, K. Schnaars, F. Hennersdorf, L. F. Lindoy, and J. J.
Weigand, “Highly Tunable 4-Phosphoryl Pyrazolone Receptors for Selective Rare-Earth
Separation,” Inorganic Chemistry, vol. 62, no. 7, pp. 3212–3228, 2023,
doi: 10.1021/acs.inorgchem.2c04221.'
mla: Zhang, Jianfeng, et al. “Highly Tunable 4-Phosphoryl Pyrazolone Receptors for
Selective Rare-Earth Separation.” Inorganic Chemistry, vol. 62, no. 7,
American Chemical Society (ACS), 2023, pp. 3212–28, doi:10.1021/acs.inorgchem.2c04221.
short: J. Zhang, M. Wenzel, K. Schnaars, F. Hennersdorf, L.F. Lindoy, J.J. Weigand,
Inorganic Chemistry 62 (2023) 3212–3228.
date_created: 2025-12-04T12:10:57Z
date_updated: 2025-12-04T12:19:26Z
department:
- _id: '985'
doi: 10.1021/acs.inorgchem.2c04221
extern: '1'
intvolume: ' 62'
issue: '7'
language:
- iso: eng
page: 3212-3228
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Highly Tunable 4-Phosphoryl Pyrazolone Receptors for Selective Rare-Earth Separation
type: journal_article
user_id: '117735'
volume: 62
year: '2023'
...
---
_id: '41012'
abstract:
- lang: eng
text: Here we explore the electronic structure of the diiron complex [(dppf)Fe(CO)3]0/+
[10/+; dppf = 1,1′-bis(diphenylphosphino)ferrocene] in two oxidation states by
an advanced multitechnique experimental approach. A combination of magnetic circular
dichroism, X-ray absorption and emission, high-frequency electron paramagnetic
resonance (EPR), and Mössbauer spectroscopies is used to establish that oxidation
of 10 occurs on the carbonyl iron ion, resulting in a low-spin iron(I) ion. It
is shown that an unequivocal result is obtained by combining several methods.
Compound 1+ displays slow spin dynamics, which is used here to study its geometric
structure by means of pulsed EPR methods. Surprisingly, these data show an association
of the tetrakis[3,5-bis(trifluoromethylphenyl)]borate counterion with 1+.
article_type: original
author:
- first_name: Mario
full_name: Winkler, Mario
last_name: Winkler
- first_name: Marc
full_name: Schnierle, Marc
last_name: Schnierle
- first_name: Felix
full_name: Ehrlich, Felix
last_name: Ehrlich
- first_name: Kim-Isabelle
full_name: Mehnert, Kim-Isabelle
last_name: Mehnert
- first_name: David
full_name: Hunger, David
last_name: Hunger
- first_name: Alena M.
full_name: Sheveleva, Alena M.
last_name: Sheveleva
- first_name: Lukas
full_name: Burkhardt, Lukas
last_name: Burkhardt
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Floriana
full_name: Tuna, Floriana
last_name: Tuna
- first_name: Mark R.
full_name: Ringenberg, Mark R.
last_name: Ringenberg
- first_name: Joris
full_name: van Slageren, Joris
last_name: van Slageren
citation:
ama: 'Winkler M, Schnierle M, Ehrlich F, et al. Electronic Structure of a Diiron
Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) 3]+/0.
Inorganic Chemistry. 2021;60(5):2856-2865. doi:10.1021/acs.inorgchem.0c03259'
apa: 'Winkler, M., Schnierle, M., Ehrlich, F., Mehnert, K.-I., Hunger, D., Sheveleva,
A. M., Burkhardt, L., Bauer, M., Tuna, F., Ringenberg, M. R., & van Slageren,
J. (2021). Electronic Structure of a Diiron Complex: A Multitechnique Experimental
Study of [(dppf)Fe(CO) 3]+/0. Inorganic Chemistry,
60(5), 2856–2865. https://doi.org/10.1021/acs.inorgchem.0c03259'
bibtex: '@article{Winkler_Schnierle_Ehrlich_Mehnert_Hunger_Sheveleva_Burkhardt_Bauer_Tuna_Ringenberg_et
al._2021, title={Electronic Structure of a Diiron Complex: A Multitechnique Experimental
Study of [(dppf)Fe(CO) 3]+/0}, volume={60}, DOI={10.1021/acs.inorgchem.0c03259},
number={5}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Winkler, Mario and Schnierle, Marc and Ehrlich, Felix and Mehnert,
Kim-Isabelle and Hunger, David and Sheveleva, Alena M. and Burkhardt, Lukas and
Bauer, Matthias and Tuna, Floriana and Ringenberg, Mark R. and et al.}, year={2021},
pages={2856–2865} }'
chicago: 'Winkler, Mario, Marc Schnierle, Felix Ehrlich, Kim-Isabelle Mehnert, David
Hunger, Alena M. Sheveleva, Lukas Burkhardt, et al. “Electronic Structure of a
Diiron Complex: A Multitechnique Experimental Study of [(Dppf)Fe(CO) 3]+/0.”
Inorganic Chemistry 60, no. 5 (2021): 2856–65. https://doi.org/10.1021/acs.inorgchem.0c03259.'
ieee: 'M. Winkler et al., “Electronic Structure of a Diiron Complex: A Multitechnique
Experimental Study of [(dppf)Fe(CO) 3]+/0,” Inorganic
Chemistry, vol. 60, no. 5, pp. 2856–2865, 2021, doi: 10.1021/acs.inorgchem.0c03259.'
mla: 'Winkler, Mario, et al. “Electronic Structure of a Diiron Complex: A Multitechnique
Experimental Study of [(Dppf)Fe(CO) 3]+/0.” Inorganic
Chemistry, vol. 60, no. 5, American Chemical Society (ACS), 2021, pp. 2856–65,
doi:10.1021/acs.inorgchem.0c03259.'
short: M. Winkler, M. Schnierle, F. Ehrlich, K.-I. Mehnert, D. Hunger, A.M. Sheveleva,
L. Burkhardt, M. Bauer, F. Tuna, M.R. Ringenberg, J. van Slageren, Inorganic Chemistry
60 (2021) 2856–2865.
date_created: 2023-01-30T17:00:49Z
date_updated: 2023-01-31T08:07:16Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.0c03259
intvolume: ' 60'
issue: '5'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 2856-2865
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study
of [(dppf)Fe(CO) 3]+/0'
type: journal_article
user_id: '48467'
volume: 60
year: '2021'
...
---
_id: '62851'
abstract:
- lang: eng
text: To reduce high-level radiotoxic waste generated by nuclear power plants, highly
selective separation agents for minor actinides are mandatory. The mixed N,O-donor
ligand N,N,N′,N′-tetrakis[(6-carboxypyridin-2-yl)methyl]ethylenediamine (H4TPAEN;
1) has shown good performance as a masking agent in Am3+/Eu3+ separation studies.
Adjustments on the pyridyl backbone to raise the hydrophilicity led to a decrease
in selectivity and a decrease in M3+–Nam interactions. An enhanced basicity of
the pyridyl N-donors was given as a cause. In this work, we examine whether a
decrease in O-donor basicity can promote the M3+–Nam interactions. Therefore,
we replace the deprotonated “charged” carboxylic acid groups of TPAEN4– by neutral
amide groups and introduce N,N,N′,N’-tetrakis[(6-N″,N′′-diethylcarbamoylpyridin-2-yl)methyl]ethylenediamine
(TPAMEN; 2) as a new ligand. TPAMEN was crystallized with Eu(OTf)3 and Eu(NO3)3·6H2O
to form positively charged 1:1 [Eu(TPAMEN)]3+ complexes in the solid state. Alterations
in the M–O/N bond distances are compared to [Eu(TPAEN)]− and investigated by DFT
calculations to expose the differences in charge/energy density distributions
at europium(III) and the donor functionalities of the TPAEN4– and TPAMEN. On the
basis of estimations of the bond orders, atomic charges spin populations, and
density of states in the Eu and potential Am and Cm complexes, the specific contributions
of the donor–metal interaction are analyzed. The prediction of complex formation
energy differences for the [M(TPAEN)]− and [M(TPAMEN)]3+ (M3+ = Eu3+, Am3+) complexes
provide an outlook on the potential performance of TPAMEN in Am3+/Eu3+ separation.
author:
- first_name: Kathleen
full_name: Schnaars, Kathleen
id: '117735'
last_name: Schnaars
- first_name: Masashi
full_name: Kaneko, Masashi
last_name: Kaneko
- first_name: Kiyoshi
full_name: Fujisawa, Kiyoshi
last_name: Fujisawa
citation:
ama: Schnaars K, Kaneko M, Fujisawa K. Effect of Oxygen-Donor Charge on Adjacent
Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands
Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex. Inorganic
Chemistry. 2021;60(4):2477-2491. doi:10.1021/acs.inorgchem.0c03405
apa: Schnaars, K., Kaneko, M., & Fujisawa, K. (2021). Effect of Oxygen-Donor
Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of
Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate
Complex. Inorganic Chemistry, 60(4), 2477–2491. https://doi.org/10.1021/acs.inorgchem.0c03405
bibtex: '@article{Schnaars_Kaneko_Fujisawa_2021, title={Effect of Oxygen-Donor Charge
on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed
N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate
Complex}, volume={60}, DOI={10.1021/acs.inorgchem.0c03405},
number={4}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Schnaars, Kathleen and Kaneko, Masashi and Fujisawa, Kiyoshi},
year={2021}, pages={2477–2491} }'
chicago: 'Schnaars, Kathleen, Masashi Kaneko, and Kiyoshi Fujisawa. “Effect of Oxygen-Donor
Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of
Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate
Complex.” Inorganic Chemistry 60, no. 4 (2021): 2477–91. https://doi.org/10.1021/acs.inorgchem.0c03405.'
ieee: 'K. Schnaars, M. Kaneko, and K. Fujisawa, “Effect of Oxygen-Donor Charge on
Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor
Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex,”
Inorganic Chemistry, vol. 60, no. 4, pp. 2477–2491, 2021, doi: 10.1021/acs.inorgchem.0c03405.'
mla: Schnaars, Kathleen, et al. “Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor
Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated
on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex.” Inorganic Chemistry,
vol. 60, no. 4, American Chemical Society (ACS), 2021, pp. 2477–91, doi:10.1021/acs.inorgchem.0c03405.
short: K. Schnaars, M. Kaneko, K. Fujisawa, Inorganic Chemistry 60 (2021) 2477–2491.
date_created: 2025-12-04T12:06:36Z
date_updated: 2025-12-04T12:19:31Z
department:
- _id: '985'
doi: 10.1021/acs.inorgchem.0c03405
extern: '1'
intvolume: ' 60'
issue: '4'
language:
- iso: eng
page: 2477-2491
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+
Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+
Chelate Complex
type: journal_article
user_id: '117735'
volume: 60
year: '2021'
...
---
_id: '18534'
author:
- first_name: Yannik
full_name: Vukadinovic, Yannik
last_name: Vukadinovic
- first_name: Lukas
full_name: Burkhardt, Lukas
last_name: Burkhardt
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Anabel
full_name: Miletic, Anabel
last_name: Miletic
- first_name: Lorena
full_name: Fritsch, Lorena
last_name: Fritsch
- first_name: Björn
full_name: Altenburger, Björn
last_name: Altenburger
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
citation:
ama: 'Vukadinovic Y, Burkhardt L, Päpcke A, et al. When Donors Turn into Acceptors:
Ground and Excited State Properties of FeII Complexes with Amine-Substituted Tridentate
Bis-imidazole-2-ylidene Pyridine Ligands. Inorganic Chemistry. 2020:8762-8774.
doi:10.1021/acs.inorgchem.0c00393'
apa: 'Vukadinovic, Y., Burkhardt, L., Päpcke, A., Miletic, A., Fritsch, L., Altenburger,
B., … Bauer, M. (2020). When Donors Turn into Acceptors: Ground and Excited State
Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene
Pyridine Ligands. Inorganic Chemistry, 8762–8774. https://doi.org/10.1021/acs.inorgchem.0c00393'
bibtex: '@article{Vukadinovic_Burkhardt_Päpcke_Miletic_Fritsch_Altenburger_Schoch_Neuba_Lochbrunner_Bauer_2020,
title={When Donors Turn into Acceptors: Ground and Excited State Properties of
FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine
Ligands}, DOI={10.1021/acs.inorgchem.0c00393},
journal={Inorganic Chemistry}, author={Vukadinovic, Yannik and Burkhardt, Lukas
and Päpcke, Ayla and Miletic, Anabel and Fritsch, Lorena and Altenburger, Björn
and Schoch, Roland and Neuba, Adam and Lochbrunner, Stefan and Bauer, Matthias},
year={2020}, pages={8762–8774} }'
chicago: 'Vukadinovic, Yannik, Lukas Burkhardt, Ayla Päpcke, Anabel Miletic, Lorena
Fritsch, Björn Altenburger, Roland Schoch, Adam Neuba, Stefan Lochbrunner, and
Matthias Bauer. “When Donors Turn into Acceptors: Ground and Excited State Properties
of FeII Complexes with Amine-Substituted Tridentate Bis-Imidazole-2-Ylidene Pyridine
Ligands.” Inorganic Chemistry, 2020, 8762–74. https://doi.org/10.1021/acs.inorgchem.0c00393.'
ieee: 'Y. Vukadinovic et al., “When Donors Turn into Acceptors: Ground and
Excited State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene
Pyridine Ligands,” Inorganic Chemistry, pp. 8762–8774, 2020.'
mla: 'Vukadinovic, Yannik, et al. “When Donors Turn into Acceptors: Ground and Excited
State Properties of FeII Complexes with Amine-Substituted Tridentate Bis-Imidazole-2-Ylidene
Pyridine Ligands.” Inorganic Chemistry, 2020, pp. 8762–74, doi:10.1021/acs.inorgchem.0c00393.'
short: Y. Vukadinovic, L. Burkhardt, A. Päpcke, A. Miletic, L. Fritsch, B. Altenburger,
R. Schoch, A. Neuba, S. Lochbrunner, M. Bauer, Inorganic Chemistry (2020) 8762–8774.
date_created: 2020-08-28T09:08:09Z
date_updated: 2022-01-06T06:53:36Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.0c00393
language:
- iso: eng
page: 8762-8774
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: 'When Donors Turn into Acceptors: Ground and Excited State Properties of FeII
Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands'
type: journal_article
user_id: '54038'
year: '2020'
...
---
_id: '46546'
author:
- first_name: Yannik
full_name: Vukadinovic, Yannik
last_name: Vukadinovic
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Anabel
full_name: Miletic, Anabel
last_name: Miletic
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Björn
full_name: Altenburger, Björn
last_name: Altenburger
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: 'Vukadinovic Y, Burkhardt L, Päpcke A, et al. When Donors Turn into Acceptors:
Ground and Excited State Properties of FeII Complexes with Amine-Substituted
Tridentate Bis-imidazole-2-ylidene Pyridine Ligands. Inorganic Chemistry.
2020;59(13):8762-8774. doi:10.1021/acs.inorgchem.0c00393'
apa: 'Vukadinovic, Y., Burkhardt, L., Päpcke, A., Miletic, A., Fritsch, L., Altenburger,
B., Schoch, R., Neuba, A., Lochbrunner, S., & Bauer, M. (2020). When Donors
Turn into Acceptors: Ground and Excited State Properties of FeII Complexes
with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands. Inorganic
Chemistry, 59(13), 8762–8774. https://doi.org/10.1021/acs.inorgchem.0c00393'
bibtex: '@article{Vukadinovic_Burkhardt_Päpcke_Miletic_Fritsch_Altenburger_Schoch_Neuba_Lochbrunner_Bauer_2020,
title={When Donors Turn into Acceptors: Ground and Excited State Properties of
FeII Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene
Pyridine Ligands}, volume={59}, DOI={10.1021/acs.inorgchem.0c00393},
number={13}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Vukadinovic, Yannik and Burkhardt, Lukas and Päpcke, Ayla and
Miletic, Anabel and Fritsch, Lorena and Altenburger, Björn and Schoch, Roland
and Neuba, Adam and Lochbrunner, Stefan and Bauer, Matthias}, year={2020}, pages={8762–8774}
}'
chicago: 'Vukadinovic, Yannik, Lukas Burkhardt, Ayla Päpcke, Anabel Miletic, Lorena
Fritsch, Björn Altenburger, Roland Schoch, Adam Neuba, Stefan Lochbrunner, and
Matthias Bauer. “When Donors Turn into Acceptors: Ground and Excited State Properties
of FeII Complexes with Amine-Substituted Tridentate Bis-Imidazole-2-Ylidene
Pyridine Ligands.” Inorganic Chemistry 59, no. 13 (2020): 8762–74. https://doi.org/10.1021/acs.inorgchem.0c00393.'
ieee: 'Y. Vukadinovic et al., “When Donors Turn into Acceptors: Ground and
Excited State Properties of FeII Complexes with Amine-Substituted Tridentate
Bis-imidazole-2-ylidene Pyridine Ligands,” Inorganic Chemistry, vol. 59,
no. 13, pp. 8762–8774, 2020, doi: 10.1021/acs.inorgchem.0c00393.'
mla: 'Vukadinovic, Yannik, et al. “When Donors Turn into Acceptors: Ground and Excited
State Properties of FeII Complexes with Amine-Substituted Tridentate
Bis-Imidazole-2-Ylidene Pyridine Ligands.” Inorganic Chemistry, vol. 59,
no. 13, American Chemical Society (ACS), 2020, pp. 8762–74, doi:10.1021/acs.inorgchem.0c00393.'
short: Y. Vukadinovic, L. Burkhardt, A. Päpcke, A. Miletic, L. Fritsch, B. Altenburger,
R. Schoch, A. Neuba, S. Lochbrunner, M. Bauer, Inorganic Chemistry 59 (2020) 8762–8774.
date_created: 2023-08-16T14:43:12Z
date_updated: 2024-03-07T09:40:08Z
doi: 10.1021/acs.inorgchem.0c00393
intvolume: ' 59'
issue: '13'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 8762-8774
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'When Donors Turn into Acceptors: Ground and Excited State Properties of FeII
Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands'
type: journal_article
user_id: '48467'
volume: 59
year: '2020'
...
---
_id: '16311'
author:
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Yannik
full_name: Vukadinovic, Yannik
last_name: Vukadinovic
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Julian
full_name: Rudolph, Julian
last_name: Rudolph
- first_name: Per-Anders
full_name: Carlsson, Per-Anders
last_name: Carlsson
- first_name: Christoph R.
full_name: Jacob, Christoph R.
last_name: Jacob
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Burkhardt L, Vukadinovic Y, Nowakowski M, et al. Electronic Structure of the
Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy.
Inorganic Chemistry. Published online 2020:3551-3561. doi:10.1021/acs.inorgchem.9b02092
apa: Burkhardt, L., Vukadinovic, Y., Nowakowski, M., Kalinko, A., Rudolph, J., Carlsson,
P.-A., Jacob, C. R., & Bauer, M. (2020). Electronic Structure of the Hieber
Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption Spectroscopy.
Inorganic Chemistry, 3551–3561. https://doi.org/10.1021/acs.inorgchem.9b02092
bibtex: '@article{Burkhardt_Vukadinovic_Nowakowski_Kalinko_Rudolph_Carlsson_Jacob_Bauer_2020,
title={Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray
Emission and Absorption Spectroscopy}, DOI={10.1021/acs.inorgchem.9b02092},
journal={Inorganic Chemistry}, author={Burkhardt, Lukas and Vukadinovic, Yannik
and Nowakowski, Michał and Kalinko, Aleksandr and Rudolph, Julian and Carlsson,
Per-Anders and Jacob, Christoph R. and Bauer, Matthias}, year={2020}, pages={3551–3561}
}'
chicago: Burkhardt, Lukas, Yannik Vukadinovic, Michał Nowakowski, Aleksandr Kalinko,
Julian Rudolph, Per-Anders Carlsson, Christoph R. Jacob, and Matthias Bauer. “Electronic
Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-Ray Emission and Absorption
Spectroscopy.” Inorganic Chemistry, 2020, 3551–61. https://doi.org/10.1021/acs.inorgchem.9b02092.
ieee: 'L. Burkhardt et al., “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]−
Revisited by X-ray Emission and Absorption Spectroscopy,” Inorganic Chemistry,
pp. 3551–3561, 2020, doi: 10.1021/acs.inorgchem.9b02092.'
mla: Burkhardt, Lukas, et al. “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]−
Revisited by X-Ray Emission and Absorption Spectroscopy.” Inorganic Chemistry,
2020, pp. 3551–61, doi:10.1021/acs.inorgchem.9b02092.
short: L. Burkhardt, Y. Vukadinovic, M. Nowakowski, A. Kalinko, J. Rudolph, P.-A.
Carlsson, C.R. Jacob, M. Bauer, Inorganic Chemistry (2020) 3551–3561.
date_created: 2020-03-23T10:38:47Z
date_updated: 2024-05-07T11:44:33Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.9b02092
language:
- iso: eng
page: 3551-3561
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray
Emission and Absorption Spectroscopy
type: journal_article
user_id: '48467'
year: '2020'
...
---
_id: '41018'
author:
- first_name: Philipp
full_name: Dierks, Philipp
last_name: Dierks
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Björn
full_name: Altenburger, Björn
last_name: Altenburger
- first_name: Thomas
full_name: Reuter, Thomas
last_name: Reuter
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Dierks P, Päpcke A, Bokareva OS, et al. Ground- and Excited-State Properties
of Iron(II) Complexes Linked to Organic Chromophores. Inorganic Chemistry.
2020;59(20):14746-14761. doi:10.1021/acs.inorgchem.0c02039
apa: Dierks, P., Päpcke, A., Bokareva, O. S., Altenburger, B., Reuter, T., Heinze,
K., Kühn, O., Lochbrunner, S., & Bauer, M. (2020). Ground- and Excited-State
Properties of Iron(II) Complexes Linked to Organic Chromophores. Inorganic
Chemistry, 59(20), 14746–14761. https://doi.org/10.1021/acs.inorgchem.0c02039
bibtex: '@article{Dierks_Päpcke_Bokareva_Altenburger_Reuter_Heinze_Kühn_Lochbrunner_Bauer_2020,
title={Ground- and Excited-State Properties of Iron(II) Complexes Linked to Organic
Chromophores}, volume={59}, DOI={10.1021/acs.inorgchem.0c02039},
number={20}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Dierks, Philipp and Päpcke, Ayla and Bokareva, Olga S. and Altenburger,
Björn and Reuter, Thomas and Heinze, Katja and Kühn, Oliver and Lochbrunner, Stefan
and Bauer, Matthias}, year={2020}, pages={14746–14761} }'
chicago: 'Dierks, Philipp, Ayla Päpcke, Olga S. Bokareva, Björn Altenburger, Thomas
Reuter, Katja Heinze, Oliver Kühn, Stefan Lochbrunner, and Matthias Bauer. “Ground-
and Excited-State Properties of Iron(II) Complexes Linked to Organic Chromophores.”
Inorganic Chemistry 59, no. 20 (2020): 14746–61. https://doi.org/10.1021/acs.inorgchem.0c02039.'
ieee: 'P. Dierks et al., “Ground- and Excited-State Properties of Iron(II)
Complexes Linked to Organic Chromophores,” Inorganic Chemistry, vol. 59,
no. 20, pp. 14746–14761, 2020, doi: 10.1021/acs.inorgchem.0c02039.'
mla: Dierks, Philipp, et al. “Ground- and Excited-State Properties of Iron(II) Complexes
Linked to Organic Chromophores.” Inorganic Chemistry, vol. 59, no. 20,
American Chemical Society (ACS), 2020, pp. 14746–61, doi:10.1021/acs.inorgchem.0c02039.
short: P. Dierks, A. Päpcke, O.S. Bokareva, B. Altenburger, T. Reuter, K. Heinze,
O. Kühn, S. Lochbrunner, M. Bauer, Inorganic Chemistry 59 (2020) 14746–14761.
date_created: 2023-01-30T17:33:28Z
date_updated: 2023-01-31T08:22:04Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.0c02039
intvolume: ' 59'
issue: '20'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 14746-14761
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Ground- and Excited-State Properties of Iron(II) Complexes Linked to Organic
Chromophores
type: journal_article
user_id: '27611'
volume: 59
year: '2020'
...
---
_id: '41019'
author:
- first_name: J. Patrick
full_name: Zobel, J. Patrick
last_name: Zobel
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Peter
full_name: Zimmer, Peter
last_name: Zimmer
- first_name: Christoph
full_name: Wölper, Christoph
last_name: Wölper
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Leticia
full_name: González, Leticia
last_name: González
citation:
ama: Zobel JP, Bokareva OS, Zimmer P, Wölper C, Bauer M, González L. Intersystem
Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene Photosensitizer.
Inorganic Chemistry. 2020;59(20):14666-14678. doi:10.1021/acs.inorgchem.0c02147
apa: Zobel, J. P., Bokareva, O. S., Zimmer, P., Wölper, C., Bauer, M., & González,
L. (2020). Intersystem Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic
Carbene Photosensitizer. Inorganic Chemistry, 59(20), 14666–14678.
https://doi.org/10.1021/acs.inorgchem.0c02147
bibtex: '@article{Zobel_Bokareva_Zimmer_Wölper_Bauer_González_2020, title={Intersystem
Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene Photosensitizer},
volume={59}, DOI={10.1021/acs.inorgchem.0c02147},
number={20}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Zobel, J. Patrick and Bokareva, Olga S. and Zimmer, Peter and
Wölper, Christoph and Bauer, Matthias and González, Leticia}, year={2020}, pages={14666–14678}
}'
chicago: 'Zobel, J. Patrick, Olga S. Bokareva, Peter Zimmer, Christoph Wölper, Matthias
Bauer, and Leticia González. “Intersystem Crossing and Triplet Dynamics in an
Iron(II) N-Heterocyclic Carbene Photosensitizer.” Inorganic Chemistry 59,
no. 20 (2020): 14666–78. https://doi.org/10.1021/acs.inorgchem.0c02147.'
ieee: 'J. P. Zobel, O. S. Bokareva, P. Zimmer, C. Wölper, M. Bauer, and L. González,
“Intersystem Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene
Photosensitizer,” Inorganic Chemistry, vol. 59, no. 20, pp. 14666–14678,
2020, doi: 10.1021/acs.inorgchem.0c02147.'
mla: Zobel, J. Patrick, et al. “Intersystem Crossing and Triplet Dynamics in an
Iron(II) N-Heterocyclic Carbene Photosensitizer.” Inorganic Chemistry,
vol. 59, no. 20, American Chemical Society (ACS), 2020, pp. 14666–78, doi:10.1021/acs.inorgchem.0c02147.
short: J.P. Zobel, O.S. Bokareva, P. Zimmer, C. Wölper, M. Bauer, L. González, Inorganic
Chemistry 59 (2020) 14666–14678.
date_created: 2023-01-30T17:34:21Z
date_updated: 2023-01-31T08:21:54Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.0c02147
intvolume: ' 59'
issue: '20'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 14666-14678
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Intersystem Crossing and Triplet Dynamics in an Iron(II) N-Heterocyclic Carbene
Photosensitizer
type: journal_article
user_id: '27611'
volume: 59
year: '2020'
...
---
_id: '41330'
author:
- first_name: Lukas
full_name: Burkhardt, Lukas
last_name: Burkhardt
- first_name: Yannik
full_name: Vukadinovic, Yannik
last_name: Vukadinovic
- first_name: Michał
full_name: Nowakowski, Michał
last_name: Nowakowski
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Julian
full_name: Rudolph, Julian
last_name: Rudolph
- first_name: Per-Anders
full_name: Carlsson, Per-Anders
last_name: Carlsson
- first_name: Christoph R.
full_name: Jacob, Christoph R.
last_name: Jacob
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
citation:
ama: Burkhardt L, Vukadinovic Y, Nowakowski M, et al. Electronic Structure of the
Hieber Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission
and Absorption Spectroscopy. Inorganic Chemistry. 2020;59(6):3551-3561.
doi:10.1021/acs.inorgchem.9b02092
apa: Burkhardt, L., Vukadinovic, Y., Nowakowski, M., Kalinko, A., Rudolph, J., Carlsson,
P.-A., Jacob, C. R., & Bauer, M. (2020). Electronic Structure of the Hieber
Anion [Fe(CO)3(NO)]− Revisited by X-ray Emission and Absorption
Spectroscopy. Inorganic Chemistry, 59(6), 3551–3561. https://doi.org/10.1021/acs.inorgchem.9b02092
bibtex: '@article{Burkhardt_Vukadinovic_Nowakowski_Kalinko_Rudolph_Carlsson_Jacob_Bauer_2020,
title={Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]−
Revisited by X-ray Emission and Absorption Spectroscopy}, volume={59}, DOI={10.1021/acs.inorgchem.9b02092},
number={6}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Burkhardt, Lukas and Vukadinovic, Yannik and Nowakowski, Michał
and Kalinko, Aleksandr and Rudolph, Julian and Carlsson, Per-Anders and Jacob,
Christoph R. and Bauer, Matthias}, year={2020}, pages={3551–3561} }'
chicago: 'Burkhardt, Lukas, Yannik Vukadinovic, Michał Nowakowski, Aleksandr Kalinko,
Julian Rudolph, Per-Anders Carlsson, Christoph R. Jacob, and Matthias Bauer. “Electronic
Structure of the Hieber Anion [Fe(CO)3(NO)]− Revisited by
X-Ray Emission and Absorption Spectroscopy.” Inorganic Chemistry 59, no.
6 (2020): 3551–61. https://doi.org/10.1021/acs.inorgchem.9b02092.'
ieee: 'L. Burkhardt et al., “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]−
Revisited by X-ray Emission and Absorption Spectroscopy,” Inorganic Chemistry,
vol. 59, no. 6, pp. 3551–3561, 2020, doi: 10.1021/acs.inorgchem.9b02092.'
mla: Burkhardt, Lukas, et al. “Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]−
Revisited by X-Ray Emission and Absorption Spectroscopy.” Inorganic Chemistry,
vol. 59, no. 6, American Chemical Society (ACS), 2020, pp. 3551–61, doi:10.1021/acs.inorgchem.9b02092.
short: L. Burkhardt, Y. Vukadinovic, M. Nowakowski, A. Kalinko, J. Rudolph, P.-A.
Carlsson, C.R. Jacob, M. Bauer, Inorganic Chemistry 59 (2020) 3551–3561.
date_created: 2023-01-31T22:52:57Z
date_updated: 2023-02-01T08:50:38Z
doi: 10.1021/acs.inorgchem.9b02092
intvolume: ' 59'
issue: '6'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 3551-3561
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Electronic Structure of the Hieber Anion [Fe(CO)3(NO)]−
Revisited by X-ray Emission and Absorption Spectroscopy
type: journal_article
user_id: '78878'
volume: 59
year: '2020'
...
---
_id: '16313'
author:
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Carsten
full_name: Mueller, Carsten
last_name: Mueller
- first_name: Oliver A.
full_name: Groß, Oliver A.
last_name: Groß
- first_name: Yu
full_name: Sun, Yu
last_name: Sun
- first_name: Helmut
full_name: Sitzmann, Helmut
last_name: Sitzmann
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
citation:
ama: Burkhardt L, Mueller C, Groß OA, Sun Y, Sitzmann H, Bauer M. The Bonding Situation
in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4] Revisited by Hard X-Ray
Spectroscopy. Inorganic Chemistry. 2018:6609-6618. doi:10.1021/acs.inorgchem.8b03032
apa: Burkhardt, L., Mueller, C., Groß, O. A., Sun, Y., Sitzmann, H., & Bauer,
M. (2018). The Bonding Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4]
Revisited by Hard X-Ray Spectroscopy. Inorganic Chemistry, 6609–6618. https://doi.org/10.1021/acs.inorgchem.8b03032
bibtex: '@article{Burkhardt_Mueller_Groß_Sun_Sitzmann_Bauer_2018, title={The Bonding
Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4] Revisited by
Hard X-Ray Spectroscopy}, DOI={10.1021/acs.inorgchem.8b03032},
journal={Inorganic Chemistry}, author={Burkhardt, Lukas and Mueller, Carsten and
Groß, Oliver A. and Sun, Yu and Sitzmann, Helmut and Bauer, Matthias}, year={2018},
pages={6609–6618} }'
chicago: Burkhardt, Lukas, Carsten Mueller, Oliver A. Groß, Yu Sun, Helmut Sitzmann,
and Matthias Bauer. “The Bonding Situation in the Dinuclear Tetra-Hydrido Complex
[{5CpFe}2(μ-H)4] Revisited by Hard X-Ray Spectroscopy.” Inorganic Chemistry,
2018, 6609–18. https://doi.org/10.1021/acs.inorgchem.8b03032.
ieee: L. Burkhardt, C. Mueller, O. A. Groß, Y. Sun, H. Sitzmann, and M. Bauer, “The
Bonding Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4] Revisited
by Hard X-Ray Spectroscopy,” Inorganic Chemistry, pp. 6609–6618, 2018.
mla: Burkhardt, Lukas, et al. “The Bonding Situation in the Dinuclear Tetra-Hydrido
Complex [{5CpFe}2(μ-H)4] Revisited by Hard X-Ray Spectroscopy.” Inorganic Chemistry,
2018, pp. 6609–18, doi:10.1021/acs.inorgchem.8b03032.
short: L. Burkhardt, C. Mueller, O.A. Groß, Y. Sun, H. Sitzmann, M. Bauer, Inorganic
Chemistry (2018) 6609–6618.
date_created: 2020-03-23T10:39:24Z
date_updated: 2022-01-06T06:52:48Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.8b03032
language:
- iso: eng
page: 6609-6618
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: The Bonding Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4]
Revisited by Hard X-Ray Spectroscopy
type: journal_article
user_id: '54038'
year: '2018'
...
---
_id: '41039'
author:
- first_name: Lukas
full_name: Burkhardt, Lukas
last_name: Burkhardt
- first_name: Carsten
full_name: Mueller, Carsten
last_name: Mueller
- first_name: Oliver A.
full_name: Groß, Oliver A.
last_name: Groß
- first_name: Yu
full_name: Sun, Yu
last_name: Sun
- first_name: Helmut
full_name: Sitzmann, Helmut
last_name: Sitzmann
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Burkhardt L, Mueller C, Groß OA, Sun Y, Sitzmann H, Bauer M. The Bonding Situation
in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4]
Revisited by Hard X-Ray Spectroscopy. Inorganic Chemistry. 2018;58(10):6609-6618.
doi:10.1021/acs.inorgchem.8b03032
apa: Burkhardt, L., Mueller, C., Groß, O. A., Sun, Y., Sitzmann, H., & Bauer,
M. (2018). The Bonding Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4]
Revisited by Hard X-Ray Spectroscopy. Inorganic Chemistry, 58(10),
6609–6618. https://doi.org/10.1021/acs.inorgchem.8b03032
bibtex: '@article{Burkhardt_Mueller_Groß_Sun_Sitzmann_Bauer_2018, title={The Bonding
Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4]
Revisited by Hard X-Ray Spectroscopy}, volume={58}, DOI={10.1021/acs.inorgchem.8b03032},
number={10}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Burkhardt, Lukas and Mueller, Carsten and Groß, Oliver A. and
Sun, Yu and Sitzmann, Helmut and Bauer, Matthias}, year={2018}, pages={6609–6618}
}'
chicago: 'Burkhardt, Lukas, Carsten Mueller, Oliver A. Groß, Yu Sun, Helmut Sitzmann,
and Matthias Bauer. “The Bonding Situation in the Dinuclear Tetra-Hydrido Complex
[{5CpFe}2(μ-H)4] Revisited by Hard X-Ray Spectroscopy.”
Inorganic Chemistry 58, no. 10 (2018): 6609–18. https://doi.org/10.1021/acs.inorgchem.8b03032.'
ieee: 'L. Burkhardt, C. Mueller, O. A. Groß, Y. Sun, H. Sitzmann, and M. Bauer,
“The Bonding Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4]
Revisited by Hard X-Ray Spectroscopy,” Inorganic Chemistry, vol. 58, no.
10, pp. 6609–6618, 2018, doi: 10.1021/acs.inorgchem.8b03032.'
mla: Burkhardt, Lukas, et al. “The Bonding Situation in the Dinuclear Tetra-Hydrido
Complex [{5CpFe}2(μ-H)4] Revisited by Hard X-Ray
Spectroscopy.” Inorganic Chemistry, vol. 58, no. 10, American Chemical
Society (ACS), 2018, pp. 6609–18, doi:10.1021/acs.inorgchem.8b03032.
short: L. Burkhardt, C. Mueller, O.A. Groß, Y. Sun, H. Sitzmann, M. Bauer, Inorganic
Chemistry 58 (2018) 6609–6618.
date_created: 2023-01-30T18:41:50Z
date_updated: 2023-01-31T08:27:46Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.8b03032
intvolume: ' 58'
issue: '10'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 6609-6618
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: The Bonding Situation in the Dinuclear Tetra-Hydrido Complex [{5CpFe}2(μ-H)4]
Revisited by Hard X-Ray Spectroscopy
type: journal_article
user_id: '27611'
volume: 58
year: '2018'
...
---
_id: '16318'
author:
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Michael
full_name: Holzwarth, Michael
last_name: Holzwarth
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
citation:
ama: Burkhardt L, Holzwarth M, Plietker B, Bauer M. Detection and Characterization
of Hydride Ligands in Iron Complexes by High-Resolution Hard X-ray Spectroscopy
and Implications for Catalytic Processes. Inorganic Chemistry. 2017:13300-13310.
doi:10.1021/acs.inorgchem.7b02063
apa: Burkhardt, L., Holzwarth, M., Plietker, B., & Bauer, M. (2017). Detection
and Characterization of Hydride Ligands in Iron Complexes by High-Resolution Hard
X-ray Spectroscopy and Implications for Catalytic Processes. Inorganic Chemistry,
13300–13310. https://doi.org/10.1021/acs.inorgchem.7b02063
bibtex: '@article{Burkhardt_Holzwarth_Plietker_Bauer_2017, title={Detection and
Characterization of Hydride Ligands in Iron Complexes by High-Resolution Hard
X-ray Spectroscopy and Implications for Catalytic Processes}, DOI={10.1021/acs.inorgchem.7b02063},
journal={Inorganic Chemistry}, author={Burkhardt, Lukas and Holzwarth, Michael
and Plietker, Bernd and Bauer, Matthias}, year={2017}, pages={13300–13310} }'
chicago: Burkhardt, Lukas, Michael Holzwarth, Bernd Plietker, and Matthias Bauer.
“Detection and Characterization of Hydride Ligands in Iron Complexes by High-Resolution
Hard X-Ray Spectroscopy and Implications for Catalytic Processes.” Inorganic
Chemistry, 2017, 13300–310. https://doi.org/10.1021/acs.inorgchem.7b02063.
ieee: L. Burkhardt, M. Holzwarth, B. Plietker, and M. Bauer, “Detection and Characterization
of Hydride Ligands in Iron Complexes by High-Resolution Hard X-ray Spectroscopy
and Implications for Catalytic Processes,” Inorganic Chemistry, pp. 13300–13310,
2017.
mla: Burkhardt, Lukas, et al. “Detection and Characterization of Hydride Ligands
in Iron Complexes by High-Resolution Hard X-Ray Spectroscopy and Implications
for Catalytic Processes.” Inorganic Chemistry, 2017, pp. 13300–10, doi:10.1021/acs.inorgchem.7b02063.
short: L. Burkhardt, M. Holzwarth, B. Plietker, M. Bauer, Inorganic Chemistry (2017)
13300–13310.
date_created: 2020-03-23T10:40:28Z
date_updated: 2022-01-06T06:52:48Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.7b02063
language:
- iso: eng
page: 13300-13310
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: Detection and Characterization of Hydride Ligands in Iron Complexes by High-Resolution
Hard X-ray Spectroscopy and Implications for Catalytic Processes
type: journal_article
user_id: '54038'
year: '2017'
...
---
_id: '16317'
author:
- first_name: Peter
full_name: Zimmer, Peter
last_name: Zimmer
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Aleksej
full_name: Friedrich, Aleksej
last_name: Friedrich
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Rahel
full_name: Schepper, Rahel
last_name: Schepper
- first_name: Patrick
full_name: Müller, Patrick
id: '54037'
last_name: Müller
orcid: 0000-0003-1103-4073
- first_name: Ulrich
full_name: Flörke, Ulrich
last_name: Flörke
- first_name: Marina
full_name: Huber, Marina
last_name: Huber
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: 'Zimmer P, Burkhardt L, Friedrich A, et al. The Connection between NHC Ligand
Count and Photophysical Properties in Fe(II) Photosensitizers: An Experimental
Study. Inorganic Chemistry. Published online 2017:360-373. doi:10.1021/acs.inorgchem.7b02624'
apa: 'Zimmer, P., Burkhardt, L., Friedrich, A., Steube, J., Neuba, A., Schepper,
R., Müller, P., Flörke, U., Huber, M., Lochbrunner, S., & Bauer, M. (2017).
The Connection between NHC Ligand Count and Photophysical Properties in Fe(II)
Photosensitizers: An Experimental Study. Inorganic Chemistry, 360–373.
https://doi.org/10.1021/acs.inorgchem.7b02624'
bibtex: '@article{Zimmer_Burkhardt_Friedrich_Steube_Neuba_Schepper_Müller_Flörke_Huber_Lochbrunner_et
al._2017, title={The Connection between NHC Ligand Count and Photophysical Properties
in Fe(II) Photosensitizers: An Experimental Study}, DOI={10.1021/acs.inorgchem.7b02624},
journal={Inorganic Chemistry}, author={Zimmer, Peter and Burkhardt, Lukas and
Friedrich, Aleksej and Steube, Jakob and Neuba, Adam and Schepper, Rahel and Müller,
Patrick and Flörke, Ulrich and Huber, Marina and Lochbrunner, Stefan and et al.},
year={2017}, pages={360–373} }'
chicago: 'Zimmer, Peter, Lukas Burkhardt, Aleksej Friedrich, Jakob Steube, Adam
Neuba, Rahel Schepper, Patrick Müller, et al. “The Connection between NHC Ligand
Count and Photophysical Properties in Fe(II) Photosensitizers: An Experimental
Study.” Inorganic Chemistry, 2017, 360–73. https://doi.org/10.1021/acs.inorgchem.7b02624.'
ieee: 'P. Zimmer et al., “The Connection between NHC Ligand Count and Photophysical
Properties in Fe(II) Photosensitizers: An Experimental Study,” Inorganic Chemistry,
pp. 360–373, 2017, doi: 10.1021/acs.inorgchem.7b02624.'
mla: 'Zimmer, Peter, et al. “The Connection between NHC Ligand Count and Photophysical
Properties in Fe(II) Photosensitizers: An Experimental Study.” Inorganic Chemistry,
2017, pp. 360–73, doi:10.1021/acs.inorgchem.7b02624.'
short: P. Zimmer, L. Burkhardt, A. Friedrich, J. Steube, A. Neuba, R. Schepper,
P. Müller, U. Flörke, M. Huber, S. Lochbrunner, M. Bauer, Inorganic Chemistry
(2017) 360–373.
date_created: 2020-03-23T10:40:15Z
date_updated: 2023-08-09T12:52:44Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.7b02624
language:
- iso: eng
page: 360-373
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: 'The Connection between NHC Ligand Count and Photophysical Properties in Fe(II)
Photosensitizers: An Experimental Study'
type: journal_article
user_id: '48467'
year: '2017'
...
---
_id: '16323'
author:
- first_name: Nora Jenny
full_name: Vollmers, Nora Jenny
last_name: Vollmers
- first_name: Patrick
full_name: Müller, Patrick
id: '54037'
last_name: Müller
orcid: 0000-0003-1103-4073
- first_name: Alexander
full_name: Hoffmann, Alexander
last_name: Hoffmann
- first_name: Sonja
full_name: Herres-Pawlis, Sonja
last_name: Herres-Pawlis
- first_name: Martin
full_name: Rohrmüller, Martin
last_name: Rohrmüller
- first_name: Wolf Gero
full_name: Schmidt, Wolf Gero
last_name: Schmidt
- first_name: Uwe
full_name: Gerstmann, Uwe
last_name: Gerstmann
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
citation:
ama: 'Vollmers NJ, Müller P, Hoffmann A, et al. Experimental and Theoretical High-Energy-Resolution
X-ray Absorption Spectroscopy: Implications for the Investigation of the Entatic
State. Inorganic Chemistry. 2016:11694-11706. doi:10.1021/acs.inorgchem.6b01704'
apa: 'Vollmers, N. J., Müller, P., Hoffmann, A., Herres-Pawlis, S., Rohrmüller,
M., Schmidt, W. G., … Bauer, M. (2016). Experimental and Theoretical High-Energy-Resolution
X-ray Absorption Spectroscopy: Implications for the Investigation of the Entatic
State. Inorganic Chemistry, 11694–11706. https://doi.org/10.1021/acs.inorgchem.6b01704'
bibtex: '@article{Vollmers_Müller_Hoffmann_Herres-Pawlis_Rohrmüller_Schmidt_Gerstmann_Bauer_2016,
title={Experimental and Theoretical High-Energy-Resolution X-ray Absorption Spectroscopy:
Implications for the Investigation of the Entatic State}, DOI={10.1021/acs.inorgchem.6b01704},
journal={Inorganic Chemistry}, author={Vollmers, Nora Jenny and Müller, Patrick
and Hoffmann, Alexander and Herres-Pawlis, Sonja and Rohrmüller, Martin and Schmidt,
Wolf Gero and Gerstmann, Uwe and Bauer, Matthias}, year={2016}, pages={11694–11706}
}'
chicago: 'Vollmers, Nora Jenny, Patrick Müller, Alexander Hoffmann, Sonja Herres-Pawlis,
Martin Rohrmüller, Wolf Gero Schmidt, Uwe Gerstmann, and Matthias Bauer. “Experimental
and Theoretical High-Energy-Resolution X-Ray Absorption Spectroscopy: Implications
for the Investigation of the Entatic State.” Inorganic Chemistry, 2016,
11694–706. https://doi.org/10.1021/acs.inorgchem.6b01704.'
ieee: 'N. J. Vollmers et al., “Experimental and Theoretical High-Energy-Resolution
X-ray Absorption Spectroscopy: Implications for the Investigation of the Entatic
State,” Inorganic Chemistry, pp. 11694–11706, 2016.'
mla: 'Vollmers, Nora Jenny, et al. “Experimental and Theoretical High-Energy-Resolution
X-Ray Absorption Spectroscopy: Implications for the Investigation of the Entatic
State.” Inorganic Chemistry, 2016, pp. 11694–706, doi:10.1021/acs.inorgchem.6b01704.'
short: N.J. Vollmers, P. Müller, A. Hoffmann, S. Herres-Pawlis, M. Rohrmüller, W.G.
Schmidt, U. Gerstmann, M. Bauer, Inorganic Chemistry (2016) 11694–11706.
date_created: 2020-03-23T10:58:57Z
date_updated: 2022-01-06T06:52:48Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
- _id: '15'
doi: 10.1021/acs.inorgchem.6b01704
language:
- iso: eng
page: 11694-11706
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: 'Experimental and Theoretical High-Energy-Resolution X-ray Absorption Spectroscopy:
Implications for the Investigation of the Entatic State'
type: journal_article
user_id: '54038'
year: '2016'
...
---
_id: '13476'
author:
- first_name: Nora Jenny
full_name: Vollmers, Nora Jenny
last_name: Vollmers
- first_name: Patrick
full_name: Müller, Patrick
last_name: Müller
- first_name: Alexander
full_name: Hoffmann, Alexander
last_name: Hoffmann
- first_name: Sonja
full_name: Herres-Pawlis, Sonja
last_name: Herres-Pawlis
- first_name: Martin
full_name: Rohrmüller, Martin
last_name: Rohrmüller
- first_name: Wolf Gero
full_name: Schmidt, Wolf Gero
id: '468'
last_name: Schmidt
orcid: 0000-0002-2717-5076
- first_name: Uwe
full_name: Gerstmann, Uwe
id: '171'
last_name: Gerstmann
orcid: 0000-0002-4476-223X
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: 'Vollmers NJ, Müller P, Hoffmann A, et al. Experimental and Theoretical High-Energy-Resolution
X-ray Absorption Spectroscopy: Implications for the Investigation of the Entatic
State. Inorganic Chemistry. 2016;55:11694-11706. doi:10.1021/acs.inorgchem.6b01704'
apa: 'Vollmers, N. J., Müller, P., Hoffmann, A., Herres-Pawlis, S., Rohrmüller,
M., Schmidt, W. G., Gerstmann, U., & Bauer, M. (2016). Experimental and Theoretical
High-Energy-Resolution X-ray Absorption Spectroscopy: Implications for the Investigation
of the Entatic State. Inorganic Chemistry, 55, 11694–11706. https://doi.org/10.1021/acs.inorgchem.6b01704'
bibtex: '@article{Vollmers_Müller_Hoffmann_Herres-Pawlis_Rohrmüller_Schmidt_Gerstmann_Bauer_2016,
title={Experimental and Theoretical High-Energy-Resolution X-ray Absorption Spectroscopy:
Implications for the Investigation of the Entatic State}, volume={55}, DOI={10.1021/acs.inorgchem.6b01704},
journal={Inorganic Chemistry}, author={Vollmers, Nora Jenny and Müller, Patrick
and Hoffmann, Alexander and Herres-Pawlis, Sonja and Rohrmüller, Martin and Schmidt,
Wolf Gero and Gerstmann, Uwe and Bauer, Matthias}, year={2016}, pages={11694–11706}
}'
chicago: 'Vollmers, Nora Jenny, Patrick Müller, Alexander Hoffmann, Sonja Herres-Pawlis,
Martin Rohrmüller, Wolf Gero Schmidt, Uwe Gerstmann, and Matthias Bauer. “Experimental
and Theoretical High-Energy-Resolution X-Ray Absorption Spectroscopy: Implications
for the Investigation of the Entatic State.” Inorganic Chemistry 55 (2016):
11694–706. https://doi.org/10.1021/acs.inorgchem.6b01704.'
ieee: 'N. J. Vollmers et al., “Experimental and Theoretical High-Energy-Resolution
X-ray Absorption Spectroscopy: Implications for the Investigation of the Entatic
State,” Inorganic Chemistry, vol. 55, pp. 11694–11706, 2016, doi: 10.1021/acs.inorgchem.6b01704.'
mla: 'Vollmers, Nora Jenny, et al. “Experimental and Theoretical High-Energy-Resolution
X-Ray Absorption Spectroscopy: Implications for the Investigation of the Entatic
State.” Inorganic Chemistry, vol. 55, 2016, pp. 11694–706, doi:10.1021/acs.inorgchem.6b01704.'
short: N.J. Vollmers, P. Müller, A. Hoffmann, S. Herres-Pawlis, M. Rohrmüller, W.G.
Schmidt, U. Gerstmann, M. Bauer, Inorganic Chemistry 55 (2016) 11694–11706.
date_created: 2019-09-30T11:31:03Z
date_updated: 2025-12-05T10:26:19Z
department:
- _id: '15'
- _id: '170'
- _id: '295'
- _id: '35'
- _id: '2'
- _id: '306'
- _id: '230'
- _id: '27'
doi: 10.1021/acs.inorgchem.6b01704
intvolume: ' 55'
language:
- iso: eng
page: 11694-11706
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: 'Experimental and Theoretical High-Energy-Resolution X-ray Absorption Spectroscopy:
Implications for the Investigation of the Entatic State'
type: journal_article
user_id: '16199'
volume: 55
year: '2016'
...
---
_id: '41228'
author:
- first_name: Irene
full_name: Bräunlich, Irene
last_name: Bräunlich
- first_name: Antoni
full_name: Sánchez-Ferrer, Antoni
last_name: Sánchez-Ferrer
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Rahel
full_name: Schepper, Rahel
last_name: Schepper
- first_name: Philippe
full_name: Knüsel, Philippe
last_name: Knüsel
- first_name: Julia
full_name: Dshemuchadse, Julia
last_name: Dshemuchadse
- first_name: Raffaele
full_name: Mezzenga, Raffaele
last_name: Mezzenga
- first_name: Walter
full_name: Caseri, Walter
last_name: Caseri
citation:
ama: Bräunlich I, Sánchez-Ferrer A, Bauer M, et al. Polynuclear Iron(II)–Aminotriazole
Spincrossover Complexes (Polymers) In Solution. Inorganic Chemistry. 2014;53(7):3546-3557.
doi:10.1021/ic403035u
apa: Bräunlich, I., Sánchez-Ferrer, A., Bauer, M., Schepper, R., Knüsel, P., Dshemuchadse,
J., Mezzenga, R., & Caseri, W. (2014). Polynuclear Iron(II)–Aminotriazole
Spincrossover Complexes (Polymers) In Solution. Inorganic Chemistry, 53(7),
3546–3557. https://doi.org/10.1021/ic403035u
bibtex: '@article{Bräunlich_Sánchez-Ferrer_Bauer_Schepper_Knüsel_Dshemuchadse_Mezzenga_Caseri_2014,
title={Polynuclear Iron(II)–Aminotriazole Spincrossover Complexes (Polymers) In
Solution}, volume={53}, DOI={10.1021/ic403035u},
number={7}, journal={Inorganic Chemistry}, publisher={American Chemical Society
(ACS)}, author={Bräunlich, Irene and Sánchez-Ferrer, Antoni and Bauer, Matthias
and Schepper, Rahel and Knüsel, Philippe and Dshemuchadse, Julia and Mezzenga,
Raffaele and Caseri, Walter}, year={2014}, pages={3546–3557} }'
chicago: 'Bräunlich, Irene, Antoni Sánchez-Ferrer, Matthias Bauer, Rahel Schepper,
Philippe Knüsel, Julia Dshemuchadse, Raffaele Mezzenga, and Walter Caseri. “Polynuclear
Iron(II)–Aminotriazole Spincrossover Complexes (Polymers) In Solution.” Inorganic
Chemistry 53, no. 7 (2014): 3546–57. https://doi.org/10.1021/ic403035u.'
ieee: 'I. Bräunlich et al., “Polynuclear Iron(II)–Aminotriazole Spincrossover
Complexes (Polymers) In Solution,” Inorganic Chemistry, vol. 53, no. 7,
pp. 3546–3557, 2014, doi: 10.1021/ic403035u.'
mla: Bräunlich, Irene, et al. “Polynuclear Iron(II)–Aminotriazole Spincrossover
Complexes (Polymers) In Solution.” Inorganic Chemistry, vol. 53, no. 7,
American Chemical Society (ACS), 2014, pp. 3546–57, doi:10.1021/ic403035u.
short: I. Bräunlich, A. Sánchez-Ferrer, M. Bauer, R. Schepper, P. Knüsel, J. Dshemuchadse,
R. Mezzenga, W. Caseri, Inorganic Chemistry 53 (2014) 3546–3557.
date_created: 2023-01-31T14:46:03Z
date_updated: 2023-01-31T14:49:01Z
department:
- _id: '306'
doi: 10.1021/ic403035u
intvolume: ' 53'
issue: '7'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 3546-3557
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Polynuclear Iron(II)–Aminotriazole Spincrossover Complexes (Polymers) In Solution
type: journal_article
user_id: '48467'
volume: 53
year: '2014'
...