[{"publication":"Angewandte Chemie International Edition","citation":{"ieee":"J. Li <i>et al.</i>, “When High‐Temperature Cesium Chemistry Meets Self‐Templating: Metal Acetates as Building Blocks of Unusual Highly Porous Carbons,” <i>Angewandte Chemie International Edition</i>, 2023, doi: <a href=\"https://doi.org/10.1002/anie.202217808\">10.1002/anie.202217808</a>.","mla":"Li, Jiaxin, et al. “When High‐Temperature Cesium Chemistry Meets Self‐Templating: Metal Acetates as Building Blocks of Unusual Highly Porous Carbons.” <i>Angewandte Chemie International Edition</i>, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202217808\">10.1002/anie.202217808</a>.","apa":"Li, J., Kossmann, J., Zeng, K., Zhang, K., Wang, B., Weinberger, C., Antonietti, M., Odziomek, M., &#38; López‐Salas, N. (2023). When High‐Temperature Cesium Chemistry Meets Self‐Templating: Metal Acetates as Building Blocks of Unusual Highly Porous Carbons. <i>Angewandte Chemie International Edition</i>. <a href=\"https://doi.org/10.1002/anie.202217808\">https://doi.org/10.1002/anie.202217808</a>","bibtex":"@article{Li_Kossmann_Zeng_Zhang_Wang_Weinberger_Antonietti_Odziomek_López‐Salas_2023, title={When High‐Temperature Cesium Chemistry Meets Self‐Templating: Metal Acetates as Building Blocks of Unusual Highly Porous Carbons}, DOI={<a href=\"https://doi.org/10.1002/anie.202217808\">10.1002/anie.202217808</a>}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Li, Jiaxin and Kossmann, Janina and Zeng, Ke and Zhang, Kun and Wang, Bingjie and Weinberger, Christian and Antonietti, Markus and Odziomek, Mateusz and López‐Salas, Nieves}, year={2023} }","short":"J. Li, J. Kossmann, K. Zeng, K. Zhang, B. Wang, C. Weinberger, M. Antonietti, M. Odziomek, N. López‐Salas, Angewandte Chemie International Edition (2023).","ama":"Li J, Kossmann J, Zeng K, et al. When High‐Temperature Cesium Chemistry Meets Self‐Templating: Metal Acetates as Building Blocks of Unusual Highly Porous Carbons. <i>Angewandte Chemie International Edition</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1002/anie.202217808\">10.1002/anie.202217808</a>","chicago":"Li, Jiaxin, Janina Kossmann, Ke Zeng, Kun Zhang, Bingjie Wang, Christian Weinberger, Markus Antonietti, Mateusz Odziomek, and Nieves López‐Salas. “When High‐Temperature Cesium Chemistry Meets Self‐Templating: Metal Acetates as Building Blocks of Unusual Highly Porous Carbons.” <i>Angewandte Chemie International Edition</i>, 2023. <a href=\"https://doi.org/10.1002/anie.202217808\">https://doi.org/10.1002/anie.202217808</a>."},"abstract":[{"lang":"eng","text":"Self-templating is a facile strategy for synthesizing porous carbons by direct pyrolysis of organic metal salts. However, the method typically suffers from low yields (<4%) and limited specific surface areas (SSA<2000 m2 g−1) originating from low activity of metal cations (e.g., K+ or Na+) in promoting construction and activation of carbon frameworks. Here we use cesium acetate as the only precursor of oxo-carbons with large SSA of the order of 3000 m2 g−1, pore volume approaching 2 cm3 g−1, tunable oxygen contents, and yields of up to 15 %. We unravel the role of Cs+ as an efficient promoter of framework formation, templating and etching agent, while acetates act as carbon/oxygen sources of carbonaceous frameworks. The oxo-carbons show record-high CO2 uptake of 8.71 mmol g−1 and an ultimate specific capacitance of 313 F g−1 in the supercapacitor. This study helps to understand and rationally tailor the materials design by a still rare organic solid-state chemistry."}],"date_created":"2023-06-12T07:42:09Z","type":"journal_article","keyword":["CO2 Adsorption","Cesium Acetate","Cesium Effect","Porous Carbons","Supercapacitor"],"year":"2023","status":"public","title":"When High‐Temperature Cesium Chemistry Meets Self‐Templating: Metal Acetates as Building Blocks of Unusual Highly Porous Carbons","author":[{"first_name":"Jiaxin","last_name":"Li","full_name":"Li, Jiaxin"},{"last_name":"Kossmann","first_name":"Janina","full_name":"Kossmann, Janina"},{"first_name":"Ke","last_name":"Zeng","full_name":"Zeng, Ke"},{"full_name":"Zhang, Kun","last_name":"Zhang","first_name":"Kun"},{"full_name":"Wang, Bingjie","first_name":"Bingjie","last_name":"Wang"},{"last_name":"Weinberger","first_name":"Christian","full_name":"Weinberger, Christian","id":"11848"},{"full_name":"Antonietti, Markus","last_name":"Antonietti","first_name":"Markus"},{"first_name":"Mateusz","last_name":"Odziomek","full_name":"Odziomek, Mateusz"},{"last_name":"López‐Salas","first_name":"Nieves","full_name":"López‐Salas, Nieves"}],"publication_identifier":{"issn":["0044-8249","1521-3757"]},"date_updated":"2024-03-21T12:01:33Z","publication_status":"published","article_type":"original","language":[{"iso":"eng"}],"_id":"45571","publisher":"Wiley","doi":"10.1002/anie.202217808","user_id":"11848"},{"_id":"42879","publisher":"Wiley","language":[{"iso":"eng"}],"doi":"10.1002/ange.202301632","user_id":"53339","year":"2023","status":"public","title":"Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation","publication_identifier":{"issn":["0044-8249","1521-3757"]},"author":[{"full_name":"Köring, Laura","last_name":"Köring","first_name":"Laura"},{"first_name":"Arne","last_name":"Stepen","full_name":"Stepen, Arne"},{"last_name":"Birenheide","first_name":"Bernhard","full_name":"Birenheide, Bernhard"},{"full_name":"Barth, Simon","first_name":"Simon","last_name":"Barth"},{"last_name":"Leskov","first_name":"Maxim","full_name":"Leskov, Maxim"},{"first_name":"Roland","last_name":"Schoch","full_name":"Schoch, Roland"},{"full_name":"Krämer, Felix","last_name":"Krämer","first_name":"Felix"},{"full_name":"Breher, Frank","last_name":"Breher","first_name":"Frank"},{"id":"53339","full_name":"Paradies, Jan","first_name":"Jan","orcid":"0000-0002-3698-668X","last_name":"Paradies"}],"date_updated":"2023-03-08T19:32:09Z","publication_status":"published","date_created":"2023-03-08T19:31:03Z","keyword":["General Medicine"],"type":"journal_article","department":[{"_id":"2"},{"_id":"389"}],"publication":"Angewandte Chemie","citation":{"short":"L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer, F. Breher, J. Paradies, Angewandte Chemie (2023).","chicago":"Köring, Laura, Arne Stepen, Bernhard Birenheide, Simon Barth, Maxim Leskov, Roland Schoch, Felix Krämer, Frank Breher, and Jan Paradies. “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation.” <i>Angewandte Chemie</i>, 2023. <a href=\"https://doi.org/10.1002/ange.202301632\">https://doi.org/10.1002/ange.202301632</a>.","apa":"Köring, L., Stepen, A., Birenheide, B., Barth, S., Leskov, M., Schoch, R., Krämer, F., Breher, F., &#38; Paradies, J. (2023). Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation. <i>Angewandte Chemie</i>. <a href=\"https://doi.org/10.1002/ange.202301632\">https://doi.org/10.1002/ange.202301632</a>","ieee":"L. Köring <i>et al.</i>, “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation,” <i>Angewandte Chemie</i>, 2023, doi: <a href=\"https://doi.org/10.1002/ange.202301632\">10.1002/ange.202301632</a>.","ama":"Köring L, Stepen A, Birenheide B, et al. Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation. <i>Angewandte Chemie</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1002/ange.202301632\">10.1002/ange.202301632</a>","bibtex":"@article{Köring_Stepen_Birenheide_Barth_Leskov_Schoch_Krämer_Breher_Paradies_2023, title={Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation}, DOI={<a href=\"https://doi.org/10.1002/ange.202301632\">10.1002/ange.202301632</a>}, journal={Angewandte Chemie}, publisher={Wiley}, author={Köring, Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}, year={2023} }","mla":"Köring, Laura, et al. “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation.” <i>Angewandte Chemie</i>, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/ange.202301632\">10.1002/ange.202301632</a>."}},{"status":"public","_id":"62101","publisher":"Wiley","page":"2782-2785","volume":132,"user_id":"89271","citation":{"bibtex":"@article{Longwitz_Werner_2020, title={Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis}, volume={132}, DOI={<a href=\"https://doi.org/10.1002/ange.201912991\">10.1002/ange.201912991</a>}, number={7}, journal={Angewandte Chemie}, publisher={Wiley}, author={Longwitz, Lars and Werner, Thomas}, year={2020}, pages={2782–2785} }","ama":"Longwitz L, Werner T. Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis. <i>Angewandte Chemie</i>. 2020;132(7):2782-2785. doi:<a href=\"https://doi.org/10.1002/ange.201912991\">10.1002/ange.201912991</a>","mla":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie</i>, vol. 132, no. 7, Wiley, 2020, pp. 2782–85, doi:<a href=\"https://doi.org/10.1002/ange.201912991\">10.1002/ange.201912991</a>.","chicago":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie</i> 132, no. 7 (2020): 2782–85. <a href=\"https://doi.org/10.1002/ange.201912991\">https://doi.org/10.1002/ange.201912991</a>.","short":"L. Longwitz, T. Werner, Angewandte Chemie 132 (2020) 2782–2785.","ieee":"L. Longwitz and T. Werner, “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis,” <i>Angewandte Chemie</i>, vol. 132, no. 7, pp. 2782–2785, 2020, doi: <a href=\"https://doi.org/10.1002/ange.201912991\">10.1002/ange.201912991</a>.","apa":"Longwitz, L., &#38; Werner, T. (2020). Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis. <i>Angewandte Chemie</i>, <i>132</i>(7), 2782–2785. <a href=\"https://doi.org/10.1002/ange.201912991\">https://doi.org/10.1002/ange.201912991</a>"},"publication_identifier":{"issn":["0044-8249","1521-3757"]},"author":[{"last_name":"Longwitz","first_name":"Lars","full_name":"Longwitz, Lars"},{"id":"89271","full_name":"Werner, Thomas","first_name":"Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244"}],"year":"2020","title":"Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis","intvolume":"       132","date_updated":"2025-11-10T08:11:23Z","publication_status":"published","language":[{"iso":"eng"}],"doi":"10.1002/ange.201912991","publication":"Angewandte Chemie","issue":"7","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>The carbon–carbon double bond of unsaturated carbonyl compounds was readily reduced by using a phosphetane oxide catalyst in the presence of a simple organosilane as the terminal reductant and water as the hydrogen source. Quantitative hydrogenation was observed when 1.0 mol % of a methyl‐substituted phosphetane oxide was employed as the catalyst. The procedure is highly selective towards activated double bonds, tolerating a variety of functional groups that are usually prone to reduction. In total, 25 alkenes and two alkynes were hydrogenated to the corresponding alkanes in excellent yields of up to 99 %. Notably, less active poly(methylhydrosiloxane) could also be utilized as the terminal reductant. Mechanistic investigations revealed the phosphane as the catalyst resting state and a protonation/deprotonation sequence as the crucial step in the catalytic cycle.</jats:p>"}],"date_created":"2025-11-05T15:39:06Z","department":[{"_id":"35"},{"_id":"2"}],"type":"journal_article","keyword":["T2","T4"]},{"publisher":"Wiley","_id":"47584","page":"4318-4324","volume":130,"user_id":"101499","status":"public","citation":{"ieee":"A. Reitze, N. Jürgensmeyer, S. Lier, M. Kohnke, J. Riese, and M. Grünewald, “Auf dem Weg zur Smart Factory: modulare, intelligente Konzepte für die Produktion von Spezialchemikalien der Zukunft,” <i>Angewandte Chemie</i>, vol. 130, no. 16, pp. 4318–4324, 2018, doi: <a href=\"https://doi.org/10.1002/ange.201711571\">10.1002/ange.201711571</a>.","apa":"Reitze, A., Jürgensmeyer, N., Lier, S., Kohnke, M., Riese, J., &#38; Grünewald, M. (2018). Auf dem Weg zur Smart Factory: modulare, intelligente Konzepte für die Produktion von Spezialchemikalien der Zukunft. <i>Angewandte Chemie</i>, <i>130</i>(16), 4318–4324. <a href=\"https://doi.org/10.1002/ange.201711571\">https://doi.org/10.1002/ange.201711571</a>","short":"A. Reitze, N. Jürgensmeyer, S. Lier, M. Kohnke, J. Riese, M. Grünewald, Angewandte Chemie 130 (2018) 4318–4324.","chicago":"Reitze, Arnulf, Nikolas Jürgensmeyer, Stefan Lier, Marco Kohnke, Julia Riese, and Marcus Grünewald. “Auf Dem Weg Zur Smart Factory: Modulare, Intelligente Konzepte Für Die Produktion von Spezialchemikalien Der Zukunft.” <i>Angewandte Chemie</i> 130, no. 16 (2018): 4318–24. <a href=\"https://doi.org/10.1002/ange.201711571\">https://doi.org/10.1002/ange.201711571</a>.","mla":"Reitze, Arnulf, et al. “Auf Dem Weg Zur Smart Factory: Modulare, Intelligente Konzepte Für Die Produktion von Spezialchemikalien Der Zukunft.” <i>Angewandte Chemie</i>, vol. 130, no. 16, Wiley, 2018, pp. 4318–24, doi:<a href=\"https://doi.org/10.1002/ange.201711571\">10.1002/ange.201711571</a>.","bibtex":"@article{Reitze_Jürgensmeyer_Lier_Kohnke_Riese_Grünewald_2018, title={Auf dem Weg zur Smart Factory: modulare, intelligente Konzepte für die Produktion von Spezialchemikalien der Zukunft}, volume={130}, DOI={<a href=\"https://doi.org/10.1002/ange.201711571\">10.1002/ange.201711571</a>}, number={16}, journal={Angewandte Chemie}, publisher={Wiley}, author={Reitze, Arnulf and Jürgensmeyer, Nikolas and Lier, Stefan and Kohnke, Marco and Riese, Julia and Grünewald, Marcus}, year={2018}, pages={4318–4324} }","ama":"Reitze A, Jürgensmeyer N, Lier S, Kohnke M, Riese J, Grünewald M. Auf dem Weg zur Smart Factory: modulare, intelligente Konzepte für die Produktion von Spezialchemikalien der Zukunft. <i>Angewandte Chemie</i>. 2018;130(16):4318-4324. doi:<a href=\"https://doi.org/10.1002/ange.201711571\">10.1002/ange.201711571</a>"},"quality_controlled":"1","language":[{"iso":"eng"}],"doi":"10.1002/ange.201711571","author":[{"first_name":"Arnulf","last_name":"Reitze","full_name":"Reitze, Arnulf"},{"first_name":"Nikolas","last_name":"Jürgensmeyer","full_name":"Jürgensmeyer, Nikolas"},{"first_name":"Stefan","last_name":"Lier","full_name":"Lier, Stefan"},{"full_name":"Kohnke, Marco","last_name":"Kohnke","first_name":"Marco"},{"id":"101499","full_name":"Riese, Julia","orcid":"0000-0002-3053-0534","last_name":"Riese","first_name":"Julia"},{"full_name":"Grünewald, Marcus","last_name":"Grünewald","first_name":"Marcus"}],"publication_identifier":{"issn":["0044-8249","1521-3757"]},"year":"2018","title":"Auf dem Weg zur Smart Factory: modulare, intelligente Konzepte für die Produktion von Spezialchemikalien der Zukunft","intvolume":"       130","publication_status":"published","date_updated":"2024-03-08T11:32:36Z","date_created":"2023-10-04T14:19:19Z","keyword":["General Medicine"],"type":"journal_article","publication":"Angewandte Chemie","issue":"16","extern":"1","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>Die Digitalisierung und Flexibilisierung von Produktionsprozessen bieten in der Spezialchemie die Chance, auf marktseitige Herausforderungen adäquat zu reagieren. Kürzer werdende Produktlebenszyklen, zunehmende Produktindividualisierung und die daraus resultierende Volatilität der Märkte stellen neue Anforderungen an Anlagenbetreiber. Neuartige Konzepte wie modulare Produktionsanlagen sowie Technologieentwicklungen im Rahmen der Industrie 4.0 können dabei helfen, die Smart Factory in der Spezialchemie umzusetzen. Im Folgenden werden die für diesen Wandel notwendigen Konzepte vorgestellt.</jats:p>"}]},{"doi":"10.1002/ange.201809275","user_id":"53339","page":"15473-15476","language":[{"iso":"eng"}],"_id":"22242","date_updated":"2023-01-23T12:50:32Z","publication_status":"published","title":"Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation","year":"2018","status":"public","author":[{"first_name":"Arne J.","last_name":"Stepen","full_name":"Stepen, Arne J."},{"full_name":"Bursch, Markus","last_name":"Bursch","first_name":"Markus"},{"first_name":"Stefan","last_name":"Grimme","full_name":"Grimme, Stefan"},{"full_name":"Stephan, Douglas W.","first_name":"Douglas W.","last_name":"Stephan"},{"id":"53339","orcid":"0000-0002-3698-668X","last_name":"Paradies","first_name":"Jan","full_name":"Paradies, Jan"}],"publication_identifier":{"issn":["0044-8249","1521-3757"]},"type":"journal_article","date_created":"2021-05-26T10:42:23Z","publication":"Angewandte Chemie","citation":{"ieee":"A. J. Stepen, M. Bursch, S. Grimme, D. W. Stephan, and J. Paradies, “Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation,” <i>Angewandte Chemie</i>, pp. 15473–15476, 2018, doi: <a href=\"https://doi.org/10.1002/ange.201809275\">10.1002/ange.201809275</a>.","apa":"Stepen, A. J., Bursch, M., Grimme, S., Stephan, D. W., &#38; Paradies, J. (2018). Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation. <i>Angewandte Chemie</i>, 15473–15476. <a href=\"https://doi.org/10.1002/ange.201809275\">https://doi.org/10.1002/ange.201809275</a>","chicago":"Stepen, Arne J., Markus Bursch, Stefan Grimme, Douglas W. Stephan, and Jan Paradies. “Reduktion von Phosphanoxiden Mit Oxalylchlorid Und Wasserstoff, Vermittelt Durch Ein Elektrophiles Phosphoniumkation.” <i>Angewandte Chemie</i>, 2018, 15473–76. <a href=\"https://doi.org/10.1002/ange.201809275\">https://doi.org/10.1002/ange.201809275</a>.","short":"A.J. Stepen, M. Bursch, S. Grimme, D.W. Stephan, J. Paradies, Angewandte Chemie (2018) 15473–15476.","mla":"Stepen, Arne J., et al. “Reduktion von Phosphanoxiden Mit Oxalylchlorid Und Wasserstoff, Vermittelt Durch Ein Elektrophiles Phosphoniumkation.” <i>Angewandte Chemie</i>, 2018, pp. 15473–76, doi:<a href=\"https://doi.org/10.1002/ange.201809275\">10.1002/ange.201809275</a>.","bibtex":"@article{Stepen_Bursch_Grimme_Stephan_Paradies_2018, title={Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation}, DOI={<a href=\"https://doi.org/10.1002/ange.201809275\">10.1002/ange.201809275</a>}, journal={Angewandte Chemie}, author={Stepen, Arne J. and Bursch, Markus and Grimme, Stefan and Stephan, Douglas W. and Paradies, Jan}, year={2018}, pages={15473–15476} }","ama":"Stepen AJ, Bursch M, Grimme S, Stephan DW, Paradies J. Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation. <i>Angewandte Chemie</i>. Published online 2018:15473-15476. doi:<a href=\"https://doi.org/10.1002/ange.201809275\">10.1002/ange.201809275</a>"}}]