@article{41000,
  abstract     = {{Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies for the construction of functional molecules as they obviate the need for pre-functionalized substrates and minimize waste generation. Great challenges reside in the control of selectivities, the utilization of unbiased hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms. An especially mild borylation of benzylic CH bonds was developed with the ligand-free pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic, and preparative mechanistic studies are indicative of a tandem catalysis mechanism of CH-borylation and dehydrocoupling via molecular CoI catalysts.}},
  author       = {{Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin, Axel}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{1}},
  publisher    = {{Wiley}},
  title        = {{{Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis}}},
  doi          = {{10.1002/anie.202110821}},
  volume       = {{61}},
  year         = {{2021}},
}

@article{41010,
  abstract     = {{We present the η3-coordination of the 2-phosphaethynthiolate anion in the complex (PN)2La(SCP) (2) [PN=N-(2-(diisopropylphosphanyl)-4-methylphenyl)-2,4,6-trimethylanilide)]. Structural comparison with dinuclear thiocyanate-bridged (PN)2La(μ-1,3-SCN)2La(PN)2 (3) and azide-bridged (PN)2La(μ-1,3-N3)2La(PN)2 (4) complexes indicates that the [SCP]− coordination mode is mainly governed by electronic, rather than steric factors. Quantum mechanical investigations reveal large contributions of the antibonding π*-orbital of the [SCP]− ligand to the LUMO of complex 2, rendering it the ideal precursor for the first functionalization of the [SCP]− anion. Complex 2 was therefore reacted with CAACs which induced a selective rearrangement of the [SCP]− ligand to form the first CAAC stabilized group 15–group 16 fulminate-type complexes (PN)2La{SPC(RCAAC)} (5 a,b, R=Ad, Me). A detailed reaction mechanism for the SCP-to-SPC isomerization is proposed based on DFT calculations.}},
  author       = {{Watt, Fabian A. and Burkhardt, Lukas and Schoch, Roland and Mitzinger, Stefan and Bauer, Matthias and Weigend, Florian and Goicoechea, Jose M. and Tambornino, Frank and Hohloch, Stephan}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{17}},
  pages        = {{9534--9539}},
  publisher    = {{Wiley}},
  title        = {{{η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**}}},
  doi          = {{10.1002/anie.202100559}},
  volume       = {{60}},
  year         = {{2021}},
}

@article{46000,
  author       = {{Su, Ran and Wang, Zhipeng and Zhu, Lina and Pan, Ying and Zhang, Dawei and Wen, Hui and Luo, Zheng‐Dong and Li, Linglong and Li, Fa‐tang and Wu, Ming and He, Liqiang and Sharma, Pankaj and Seidel, Jan}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{29}},
  pages        = {{16019--16026}},
  publisher    = {{Wiley}},
  title        = {{{Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting}}},
  doi          = {{10.1002/anie.202103112}},
  volume       = {{60}},
  year         = {{2021}},
}

@article{62806,
  abstract     = {{The electrical double‐layer plays a key role in important interfacial electrochemical processes from catalysis to energy storage and corrosion. Therefore, understanding its structure is crucial for the progress of sustainable technologies. We extract new physico‐chemical information on the capacitance and structure of the electrical double‐layer of platinum and gold nanoparticles at the molecular level, employing single nanoparticle electrochemistry. The charge storage ability of the solid/liquid interface is larger by one order‐of‐magnitude than predicted by the traditional mean‐field models of the double‐layer such as the Gouy–Chapman–Stern model. Performing molecular dynamics simulations, we investigate the possible relationship between the measured high capacitance and adsorption strength of the water adlayer formed at the metal surface. These insights may launch the active tuning of solid–solvent and solvent–solvent interactions as an innovative design strategy to transform energy technologies towards superior performance and sustainability.}},
  author       = {{Azimzadeh Sani, Mahnaz and Pavlopoulos, Nicholas G. and Pezzotti, Simone and Serva, Alessandra and Cignoni, Paolo and Linnemann, Julia and Salanne, Mathieu and Gaigeot, Marie‐Pierre and Tschulik, Kristina}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{single-entity electrochemistry, electrical double layer, supercapacitor, nanoparticles}},
  number       = {{5}},
  publisher    = {{Wiley}},
  title        = {{{Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer}}},
  doi          = {{10.1002/anie.202112679}},
  volume       = {{61}},
  year         = {{2021}},
}

@article{23606,
  author       = {{Steinrück, Hans-Georg and Cao, Chuntian and Lukatskaya, Maria R. and Takacs, Christopher J. and Wan, Gang and Mackanic, David G. and Tsao, Yuchi and Zhao, Jingbo and Helms, Brett A. and Xu, Kang and Borodin, Oleg and Wishart, James F. and Toney, Michael F.}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  pages        = {{23180--23187}},
  title        = {{{Interfacial Speciation Determines Interfacial Chemistry: X‐ray‐Induced Lithium Fluoride Formation from Water‐in‐salt Electrolytes on Solid Surfaces}}},
  doi          = {{10.1002/anie.202007745}},
  volume       = {{59}},
  year         = {{2020}},
}

@article{22647,
  author       = {{Kielar, Charlotte and Zhu, Siqi and Grundmeier, Guido and Keller, Adrian}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  pages        = {{14336--14341}},
  title        = {{{Quantitative Assessment of Tip Effects in Single‐Molecule High‐Speed Atomic Force Microscopy Using DNA Origami Substrates}}},
  doi          = {{10.1002/anie.202005884}},
  volume       = {{59}},
  year         = {{2020}},
}

@article{22650,
  author       = {{Keller, Adrian and Linko, Veikko}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  pages        = {{15818--15833}},
  title        = {{{Challenges and Perspectives of DNA Nanostructures in Biomedicine}}},
  doi          = {{10.1002/anie.201916390}},
  volume       = {{59}},
  year         = {{2020}},
}

@article{62102,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>The carbon–carbon double bond of unsaturated carbonyl compounds was readily reduced by using a phosphetane oxide catalyst in the presence of a simple organosilane as the terminal reductant and water as the hydrogen source. Quantitative hydrogenation was observed when 1.0 mol % of a methyl‐substituted phosphetane oxide was employed as the catalyst. The procedure is highly selective towards activated double bonds, tolerating a variety of functional groups that are usually prone to reduction. In total, 25 alkenes and two alkynes were hydrogenated to the corresponding alkanes in excellent yields of up to 99 %. Notably, less active poly(methylhydrosiloxane) could also be utilized as the terminal reductant. Mechanistic investigations revealed the phosphane as the catalyst resting state and a protonation/deprotonation sequence as the crucial step in the catalytic cycle.</jats:p>}},
  author       = {{Longwitz, Lars and Werner, Thomas}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{T2, T4, CSSD}},
  number       = {{7}},
  pages        = {{2760--2763}},
  publisher    = {{Wiley}},
  title        = {{{Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis}}},
  doi          = {{10.1002/anie.201912991}},
  volume       = {{59}},
  year         = {{2020}},
}

@article{47585,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>Digitalization and increasing the flexibility of production concepts offer the possibility to react to market challenges in the field of specialty chemicals. Shorter product lifetimes, increasing product individualization, and the resulting market volatility impose new requirements on plant operators. Novel concepts such as modular production plants and developments in digitalization (Industry 4.0) are able to assist the implementation of smart factories in specialty chemicals. These essential concepts will be presented in this Minireview.</jats:p>}},
  author       = {{Reitze, Arnulf and Jürgensmeyer, Nikolas and Lier, Stefan and Kohnke, Marco and Riese, Julia and Grünewald, Marcus}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{16}},
  pages        = {{4242--4247}},
  publisher    = {{Wiley}},
  title        = {{{Roadmap for a Smart Factory: A Modular, Intelligent Concept for the Production of Specialty Chemicals}}},
  doi          = {{10.1002/anie.201711571}},
  volume       = {{57}},
  year         = {{2018}},
}

@article{22241,
  author       = {{Stepen, Arne J. and Bursch, Markus and Grimme, Stefan and Stephan, Douglas W. and Paradies, Jan}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  pages        = {{15253--15256}},
  title        = {{{Electrophilic Phosphonium Cation‐Mediated Phosphane Oxide Reduction Using Oxalyl Chloride and Hydrogen}}},
  doi          = {{10.1002/anie.201809275}},
  year         = {{2018}},
}

@article{41261,
  author       = {{Hübner, Michael and Koziej, Dorota and Bauer, Matthias and Barsan, Nicolae and Kvashnina, Kristina and Rossell, Marta D. and Weimar, Udo and Grunwaldt, Jan‐Dierk}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{12}},
  pages        = {{2841--2844}},
  publisher    = {{Wiley}},
  title        = {{{The Structure and Behavior of Platinum in SnO            <sub>2</sub>            ‐Based Sensors under Working Conditions}}},
  doi          = {{10.1002/anie.201004499}},
  volume       = {{50}},
  year         = {{2011}},
}

@article{39986,
  author       = {{Hassheider, Thomas and Benning, Stephan A. and Kitzerow, Heinz-Siegfried and Achard, Marie-France and Bock, Harald}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{11}},
  pages        = {{2060--2063}},
  publisher    = {{Wiley}},
  title        = {{{Color-Tuned Electroluminescence from Columnar Liquid Crystalline Alkyl Arenecarboxylates}}},
  doi          = {{10.1002/1521-3773(20010601)40:11<2060::aid-anie2060>3.0.co;2-h}},
  volume       = {{40}},
  year         = {{2005}},
}

@article{39992,
  author       = {{Popova, Elena L. and Rozenberg, Valeria I. and Starikova, Zoya A. and Keuker-Baumann, Susanne and Kitzerow, Heinz-Siegfried and Hopf, Henning}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{18}},
  pages        = {{3411--3414}},
  publisher    = {{Wiley}},
  title        = {{{Thermotropic Liquid Crystals from Planar Chiral Compounds: Optically Active Mesogenic [2.2]Paracyclophane Derivatives}}},
  doi          = {{10.1002/1521-3773(20020916)41:18<3411::aid-anie3411>3.0.co;2-a}},
  volume       = {{41}},
  year         = {{2002}},
}

@article{40326,
  author       = {{Baena, Maria J. and Buey, Julio and Espinet, Pablo and Kitzerow, Heinz-Siegfried and Heppke, Gerd}},
  issn         = {{0570-0833}},
  journal      = {{Angewandte Chemie International Edition in English}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{8}},
  pages        = {{1201--1203}},
  publisher    = {{Wiley}},
  title        = {{{Metallomesogens with a Cholesteric Mesophase}}},
  doi          = {{10.1002/anie.199312011}},
  volume       = {{32}},
  year         = {{1993}},
}