[{"department":[{"_id":"2"},{"_id":"389"}],"type":"journal_article","keyword":["T2","T","CSSD"],"date_created":"2025-09-17T15:16:49Z","abstract":[{"lang":"eng","text":"<jats:p>Amidines are a ubiquitous class of bioactive compounds found in a wide variety of natural products; thus, efficient strategies for their preparation are in great demand. Herein, a novel protocol is reported for the synthesis of amidines based on P<jats:sup>III</jats:sup>/P<jats:sup>V</jats:sup>O redox catalysis. This two‐step, one‐pot approach involves the activation of amides via P<jats:sup>III</jats:sup>/P<jats:sup>V</jats:sup>O catalyzed in situ formation of imidoyl chloride intermediates which are directly converted upon reaction with amines into the corresponding amidines. Instead of traditionally used toxic and corrosive chloride sources, hexachloroacetone (HCA) is successfully employed as a halide source. The reaction proceeds with low catalyst loading (2 mol%) in BuOAc as the solvent. Under the optimized conditions, 20 amidines are prepared in yields up to 99%. A feasible mechanism is proposed based on experimental results. The synthetic potential of this method is evaluated in the preparation of the tyrosine kinase inhibitor (TKI) Erlotinib.</jats:p>"}],"citation":{"apa":"Medvaric, V., Paradies, J., &#38; Werner, T. (2025). Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides. <i>Advanced Synthesis and Catalysis</i>, Article 202500394. <a href=\"https://doi.org/10.1002/adsc.70059\">https://doi.org/10.1002/adsc.70059</a>","ieee":"V. Medvaric, J. Paradies, and T. Werner, “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides,” <i>Advanced Synthesis and Catalysis</i>, Art. no. 202500394, 2025, doi: <a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>.","chicago":"Medvaric, Viktorija, Jan Paradies, and Thomas Werner. “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides.” <i>Advanced Synthesis and Catalysis</i>, 2025. <a href=\"https://doi.org/10.1002/adsc.70059\">https://doi.org/10.1002/adsc.70059</a>.","short":"V. Medvaric, J. Paradies, T. Werner, Advanced Synthesis and Catalysis (2025).","mla":"Medvaric, Viktorija, et al. “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides.” <i>Advanced Synthesis and Catalysis</i>, 202500394, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>.","ama":"Medvaric V, Paradies J, Werner T. Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides. <i>Advanced Synthesis and Catalysis</i>. Published online 2025. doi:<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>","bibtex":"@article{Medvaric_Paradies_Werner_2025, title={Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides}, DOI={<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>}, number={202500394}, journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Medvaric, Viktorija and Paradies, Jan and Werner, Thomas}, year={2025} }"},"publication":"Advanced Synthesis and Catalysis","user_id":"89271","doi":"10.1002/adsc.70059","_id":"61335","language":[{"iso":"eng"}],"publisher":"Wiley","article_number":"202500394","publication_status":"published","date_updated":"2025-11-10T08:44:04Z","author":[{"id":"92677","first_name":"Viktorija","last_name":"Medvaric","full_name":"Medvaric, Viktorija"},{"id":"53339","orcid":"0000-0002-3698-668X","first_name":"Jan","last_name":"Paradies","full_name":"Paradies, Jan"},{"id":"89271","full_name":"Werner, Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244","first_name":"Thomas"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"title":"Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides","year":"2025","status":"public"},{"status":"public","user_id":"53339","volume":366,"page":"2933-2938","_id":"55371","publisher":"Wiley","citation":{"ieee":"A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds,” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366, no. 13, pp. 2933–2938, 2024, doi: <a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>.","apa":"Hoppe, A., Stepen, A. J., Köring, L., &#38; Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>, <i>366</i>(13), 2933–2938. <a href=\"https://doi.org/10.1002/adsc.202400511\">https://doi.org/10.1002/adsc.202400511</a>","short":"A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis &#38;amp; Catalysis 366 (2024) 2933–2938.","chicago":"Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i> 366, no. 13 (2024): 2933–38. <a href=\"https://doi.org/10.1002/adsc.202400511\">https://doi.org/10.1002/adsc.202400511</a>.","mla":"Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366, no. 13, Wiley, 2024, pp. 2933–38, doi:<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>.","bibtex":"@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>}, number={13}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley}, author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan}, year={2024}, pages={2933–2938} }","ama":"Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>. 2024;366(13):2933-2938. doi:<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>"},"date_updated":"2024-07-24T09:18:18Z","publication_status":"published","intvolume":"       366","title":"Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds","year":"2024","author":[{"last_name":"Hoppe","first_name":"Axel","full_name":"Hoppe, Axel"},{"full_name":"Stepen, Arne J.","first_name":"Arne J.","last_name":"Stepen"},{"full_name":"Köring, Laura","first_name":"Laura","last_name":"Köring"},{"full_name":"Paradies, Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X","first_name":"Jan","id":"53339"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"doi":"10.1002/adsc.202400511","language":[{"iso":"eng"}],"abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub> is reported and applied in reactions with arenes, allylic, vinylic and acetylenic silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>"}],"issue":"13","publication":"Advanced Synthesis &amp; Catalysis","type":"journal_article","department":[{"_id":"2"},{"_id":"389"}],"date_created":"2024-07-24T09:16:15Z"},{"oa":"1","citation":{"bibtex":"@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>}, number={13}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley}, author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan}, year={2024}, pages={2933–2938} }","ama":"Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>. 2024;366(13):2933-2938. doi:<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>","mla":"Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366, no. 13, Wiley, 2024, pp. 2933–38, doi:<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>.","short":"A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis &#38;amp; Catalysis 366 (2024) 2933–2938.","chicago":"Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i> 366, no. 13 (2024): 2933–38. <a href=\"https://doi.org/10.1002/adsc.202400511\">https://doi.org/10.1002/adsc.202400511</a>.","ieee":"A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds,” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366, no. 13, pp. 2933–2938, 2024, doi: <a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>.","apa":"Hoppe, A., Stepen, A. J., Köring, L., &#38; Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>, <i>366</i>(13), 2933–2938. <a href=\"https://doi.org/10.1002/adsc.202400511\">https://doi.org/10.1002/adsc.202400511</a>"},"quality_controlled":"1","page":"2933-2938","publisher":"Wiley","_id":"59616","user_id":"62844","volume":366,"status":"public","date_created":"2025-04-22T05:59:08Z","type":"journal_article","keyword":["fluoride","bond activation","borane","Lewis acid","C-C bond formation"],"department":[{"_id":"389"}],"issue":"13","publication":"Advanced Synthesis &amp; Catalysis","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub> is reported and applied in reactions with arenes, allylic, vinylic and acetylenic silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>"}],"main_file_link":[{"url":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202400511","open_access":"1"}],"language":[{"iso":"eng"}],"doi":"10.1002/adsc.202400511","title":"Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds","year":"2024","publication_identifier":{"issn":["1615-4150","1615-4169"]},"author":[{"last_name":"Hoppe","first_name":"Axel","full_name":"Hoppe, Axel","id":"62844"},{"full_name":"Stepen, Arne J.","first_name":"Arne J.","last_name":"Stepen"},{"full_name":"Köring, Laura","first_name":"Laura","last_name":"Köring"},{"full_name":"Paradies, Jan","orcid":"0000-0002-3698-668X","first_name":"Jan","last_name":"Paradies","id":"53339"}],"date_updated":"2025-04-22T06:11:59Z","publication_status":"published","intvolume":"       366"},{"citation":{"ieee":"B. Sieland, A. Hoppe, A. J. Stepen, and J. Paradies, “Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis,” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 364, no. 18, pp. 3143–3148, 2022, doi: <a href=\"https://doi.org/10.1002/adsc.202200525\">10.1002/adsc.202200525</a>.","apa":"Sieland, B., Hoppe, A., Stepen, A. J., &#38; Paradies, J. (2022). Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis. <i>Advanced Synthesis &#38;amp; Catalysis</i>, <i>364</i>(18), 3143–3148. <a href=\"https://doi.org/10.1002/adsc.202200525\">https://doi.org/10.1002/adsc.202200525</a>","short":"B. Sieland, A. Hoppe, A.J. Stepen, J. Paradies, Advanced Synthesis &#38;amp; Catalysis 364 (2022) 3143–3148.","chicago":"Sieland, Benedikt, Axel Hoppe, Arne J. Stepen, and Jan Paradies. “Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis.” <i>Advanced Synthesis &#38;amp; Catalysis</i> 364, no. 18 (2022): 3143–48. <a href=\"https://doi.org/10.1002/adsc.202200525\">https://doi.org/10.1002/adsc.202200525</a>.","mla":"Sieland, Benedikt, et al. “Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 364, no. 18, Wiley, 2022, pp. 3143–48, doi:<a href=\"https://doi.org/10.1002/adsc.202200525\">10.1002/adsc.202200525</a>.","bibtex":"@article{Sieland_Hoppe_Stepen_Paradies_2022, title={Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis}, volume={364}, DOI={<a href=\"https://doi.org/10.1002/adsc.202200525\">10.1002/adsc.202200525</a>}, number={18}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley}, author={Sieland, Benedikt and Hoppe, Axel and Stepen, Arne J. and Paradies, Jan}, year={2022}, pages={3143–3148} }","ama":"Sieland B, Hoppe A, Stepen AJ, Paradies J. Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis. <i>Advanced Synthesis &#38;amp; Catalysis</i>. 2022;364(18):3143-3148. doi:<a href=\"https://doi.org/10.1002/adsc.202200525\">10.1002/adsc.202200525</a>"},"publisher":"Wiley","_id":"35692","page":"3143-3148","volume":364,"user_id":"53339","status":"public","date_created":"2023-01-10T08:58:42Z","type":"journal_article","keyword":["General Chemistry"],"publication":"Advanced Synthesis &amp; Catalysis","issue":"18","language":[{"iso":"eng"}],"doi":"10.1002/adsc.202200525","publication_identifier":{"issn":["1615-4150","1615-4169"]},"author":[{"last_name":"Sieland","first_name":"Benedikt","full_name":"Sieland, Benedikt"},{"last_name":"Hoppe","first_name":"Axel","full_name":"Hoppe, Axel"},{"full_name":"Stepen, Arne J.","last_name":"Stepen","first_name":"Arne J."},{"full_name":"Paradies, Jan","last_name":"Paradies","first_name":"Jan","orcid":"0000-0002-3698-668X","id":"53339"}],"title":"Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis","year":"2022","intvolume":"       364","date_updated":"2023-01-23T12:52:02Z","publication_status":"published"},{"citation":{"chicago":"Sieland, Benedikt, Axel Hoppe, Arne J. Stepen, and Jan Paradies. “Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis.” <i>Advanced Synthesis &#38;amp; Catalysis</i> 364, no. 18 (2022): 3143–48. <a href=\"https://doi.org/10.1002/adsc.202200525\">https://doi.org/10.1002/adsc.202200525</a>.","short":"B. Sieland, A. Hoppe, A.J. Stepen, J. Paradies, Advanced Synthesis &#38;amp; Catalysis 364 (2022) 3143–3148.","ieee":"B. Sieland, A. Hoppe, A. J. Stepen, and J. Paradies, “Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis,” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 364, no. 18, pp. 3143–3148, 2022, doi: <a href=\"https://doi.org/10.1002/adsc.202200525\">10.1002/adsc.202200525</a>.","apa":"Sieland, B., Hoppe, A., Stepen, A. J., &#38; Paradies, J. (2022). Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis. <i>Advanced Synthesis &#38;amp; Catalysis</i>, <i>364</i>(18), 3143–3148. <a href=\"https://doi.org/10.1002/adsc.202200525\">https://doi.org/10.1002/adsc.202200525</a>","bibtex":"@article{Sieland_Hoppe_Stepen_Paradies_2022, title={Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis}, volume={364}, DOI={<a href=\"https://doi.org/10.1002/adsc.202200525\">10.1002/adsc.202200525</a>}, number={18}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley}, author={Sieland, Benedikt and Hoppe, Axel and Stepen, Arne J. and Paradies, Jan}, year={2022}, pages={3143–3148} }","ama":"Sieland B, Hoppe A, Stepen AJ, Paradies J. Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis. <i>Advanced Synthesis &#38;amp; Catalysis</i>. 2022;364(18):3143-3148. doi:<a href=\"https://doi.org/10.1002/adsc.202200525\">10.1002/adsc.202200525</a>","mla":"Sieland, Benedikt, et al. “Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 364, no. 18, Wiley, 2022, pp. 3143–48, doi:<a href=\"https://doi.org/10.1002/adsc.202200525\">10.1002/adsc.202200525</a>."},"quality_controlled":"1","oa":"1","status":"public","page":"3143-3148","_id":"59619","publisher":"Wiley","user_id":"62844","volume":364,"publication":"Advanced Synthesis &amp; Catalysis","issue":"18","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>A frustrated Lewis pair‐catalyzed hydroboration of aromatic and aliphatic nitriles was developed. The catalyst provides the primary amines in high yields of 77–99% with catalyst loading as low as 2 mol%. The reaction displays high functional group tolerance towards esters, amides, nitro groups and aliphatic halides. The addition of the diborylated amines to ethyl 3‐phenylpropiolate proceeds with Z‐selectivity with d.r. of &gt;99:1 in 77–90% yield over two steps. The reaction mechanism was investigated by control and computational experiments.</jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" mimetype=\"image/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic/adsc202200525-toc-0001-m.png\"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text>\r\n</jats:p>"}],"date_created":"2025-04-22T06:01:56Z","keyword":["hydroboration","nitrile","amine","frustrated Lewis pair","density functional theory"],"type":"journal_article","department":[{"_id":"389"}],"title":"Frustrated Lewis Pair‐Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis","year":"2022","author":[{"full_name":"Sieland, Benedikt","first_name":"Benedikt","last_name":"Sieland"},{"first_name":"Axel","last_name":"Hoppe","full_name":"Hoppe, Axel","id":"62844"},{"full_name":"Stepen, Arne J.","last_name":"Stepen","first_name":"Arne J."},{"id":"53339","last_name":"Paradies","first_name":"Jan","orcid":"0000-0002-3698-668X","full_name":"Paradies, Jan"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"date_updated":"2025-04-22T06:12:05Z","publication_status":"published","intvolume":"       364","main_file_link":[{"url":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202200525","open_access":"1"}],"language":[{"iso":"eng"}],"doi":"10.1002/adsc.202200525"},{"citation":{"mla":"Liu, Xin, and Thomas Werner. “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides.” <i>Advanced Synthesis and Catalysis</i>, vol. 363, no. 4, Wiley, 2021, pp. 1096–104, doi:<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>.","ama":"Liu X, Werner T. Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides. <i>Advanced Synthesis and Catalysis</i>. 2021;363(4):1096-1104. doi:<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>","bibtex":"@article{Liu_Werner_2021, title={Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides}, volume={363}, DOI={<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>}, number={4}, journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Liu, Xin and Werner, Thomas}, year={2021}, pages={1096–1104} }","apa":"Liu, X., &#38; Werner, T. (2021). Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides. <i>Advanced Synthesis and Catalysis</i>, <i>363</i>(4), 1096–1104. <a href=\"https://doi.org/10.1002/adsc.202001209\">https://doi.org/10.1002/adsc.202001209</a>","ieee":"X. Liu and T. Werner, “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides,” <i>Advanced Synthesis and Catalysis</i>, vol. 363, no. 4, pp. 1096–1104, 2021, doi: <a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>.","short":"X. Liu, T. Werner, Advanced Synthesis and Catalysis 363 (2021) 1096–1104.","chicago":"Liu, Xin, and Thomas Werner. “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides.” <i>Advanced Synthesis and Catalysis</i> 363, no. 4 (2021): 1096–1104. <a href=\"https://doi.org/10.1002/adsc.202001209\">https://doi.org/10.1002/adsc.202001209</a>."},"status":"public","publisher":"Wiley","_id":"37948","page":"1096-1104","volume":363,"user_id":"89271","issue":"4","publication":"Advanced Synthesis and Catalysis","extern":"1","date_created":"2023-01-22T20:30:29Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["T1","T3","CSSD"],"type":"journal_article","author":[{"last_name":"Liu","first_name":"Xin","full_name":"Liu, Xin"},{"last_name":"Werner","first_name":"Thomas","orcid":"https://orcid.org/0000-0001-9025-3244","full_name":"Werner, Thomas","id":"89271"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"title":"Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides","year":"2021","intvolume":"       363","publication_status":"published","date_updated":"2025-11-10T08:48:47Z","language":[{"iso":"eng"}],"doi":"10.1002/adsc.202001209"},{"issue":"23","publication":"Advanced Synthesis &amp; Catalysis","type":"journal_article","keyword":["General Chemistry"],"department":[{"_id":"2"},{"_id":"389"}],"date_created":"2023-01-10T09:12:45Z","date_updated":"2024-07-24T09:15:18Z","publication_status":"published","intvolume":"       358","title":"Concise Synthesis of Dithiophene Derivatives by a Palladium- Catalyzed Multiple C-S Cross Coupling/Cyclization Sequence","year":"2016","author":[{"full_name":"Oechsle, Peter","first_name":"Peter","last_name":"Oechsle"},{"first_name":"Peng","last_name":"Hou","full_name":"Hou, Peng"},{"full_name":"Flörke, Ulrich","last_name":"Flörke","first_name":"Ulrich"},{"id":"53339","first_name":"Jan","orcid":"0000-0002-3698-668X","last_name":"Paradies","full_name":"Paradies, Jan"}],"publication_identifier":{"issn":["1615-4150"]},"doi":"10.1002/adsc.201600802","language":[{"iso":"eng"}],"citation":{"ieee":"P. 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Phosphonium Salt Organocatalysis. <i>Advanced Synthesis &#38;amp; Catalysis</i>, <i>351</i>(10), 1469–1481. <a href=\"https://doi.org/10.1002/adsc.200900211\">https://doi.org/10.1002/adsc.200900211</a>"}},{"author":[{"full_name":"Christoffers, Jens","first_name":"Jens","last_name":"Christoffers"},{"full_name":"Baro, Angelika","last_name":"Baro","first_name":"Angelika"},{"full_name":"Werner, Thomas","last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244","id":"89271"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"year":"2004","title":"α-Hydroxylation ofβ-Dicarbonyl Compounds","intvolume":"       346","publication_status":"published","date_updated":"2025-11-10T09:46:02Z","language":[{"iso":"eng"}],"doi":"10.1002/adsc.200303140","publication":"Advanced Synthesis and Catalysis","issue":"23","extern":"1","date_created":"2023-01-22T21:15:14Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["General Chemistry"],"status":"public","publisher":"Wiley","_id":"38017","page":"143-151","volume":346,"user_id":"89271","citation":{"short":"J. Christoffers, A. Baro, T. Werner, Advanced Synthesis and Catalysis 346 (2004) 143–151.","chicago":"Christoffers, Jens, Angelika Baro, and Thomas Werner. “α-Hydroxylation Ofβ-Dicarbonyl Compounds.” <i>Advanced Synthesis and Catalysis</i> 346, no. 23 (2004): 143–51. <a href=\"https://doi.org/10.1002/adsc.200303140\">https://doi.org/10.1002/adsc.200303140</a>.","ieee":"J. Christoffers, A. Baro, and T. Werner, “α-Hydroxylation ofβ-Dicarbonyl Compounds,” <i>Advanced Synthesis and Catalysis</i>, vol. 346, no. 23, pp. 143–151, 2004, doi: <a href=\"https://doi.org/10.1002/adsc.200303140\">10.1002/adsc.200303140</a>.","apa":"Christoffers, J., Baro, A., &#38; Werner, T. (2004). α-Hydroxylation ofβ-Dicarbonyl Compounds. <i>Advanced Synthesis and Catalysis</i>, <i>346</i>(23), 143–151. <a href=\"https://doi.org/10.1002/adsc.200303140\">https://doi.org/10.1002/adsc.200303140</a>","bibtex":"@article{Christoffers_Baro_Werner_2004, title={α-Hydroxylation ofβ-Dicarbonyl Compounds}, volume={346}, DOI={<a href=\"https://doi.org/10.1002/adsc.200303140\">10.1002/adsc.200303140</a>}, number={23}, journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Christoffers, Jens and Baro, Angelika and Werner, Thomas}, year={2004}, pages={143–151} }","ama":"Christoffers J, Baro A, Werner T. α-Hydroxylation ofβ-Dicarbonyl Compounds. <i>Advanced Synthesis and Catalysis</i>. 2004;346(23):143-151. doi:<a href=\"https://doi.org/10.1002/adsc.200303140\">10.1002/adsc.200303140</a>","mla":"Christoffers, Jens, et al. “α-Hydroxylation Ofβ-Dicarbonyl Compounds.” <i>Advanced Synthesis and Catalysis</i>, vol. 346, no. 23, Wiley, 2004, pp. 143–51, doi:<a href=\"https://doi.org/10.1002/adsc.200303140\">10.1002/adsc.200303140</a>."}}]
