@article{47589,
  author       = {{Krämer, Felix and Paradies, Jan and Fernández, Israel and Breher, Frank}},
  issn         = {{1755-4330}},
  journal      = {{Nature Chemistry}},
  keywords     = {{General Chemical Engineering, General Chemistry}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{A crystalline aluminium–carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media}}},
  doi          = {{10.1038/s41557-023-01340-9}},
  year         = {{2023}},
}

@article{46481,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>Although iron is a dream candidate to substitute noble metals in photoactive complexes, realization of emissive and photoactive iron compounds is demanding due to the fast deactivation of their charge-transfer states. Emissive iron compounds are scarce and dual emission has not been observed before. Here we report the Fe<jats:sup>III</jats:sup> complex [Fe(ImP)<jats:sub>2</jats:sub>][PF<jats:sub>6</jats:sub>] (HImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazol-2-ylidene)), showing a Janus-type dual emission from ligand-to-metal charge transfer (LMCT)- and metal-to-ligand charge transfer (MLCT)-dominated states. This behaviour is achieved by a ligand design that combines four <jats:italic>N</jats:italic>-heterocyclic carbenes with two cyclometalating aryl units. The low-lying <jats:italic>π</jats:italic>* levels of the cyclometalating units lead to energetically accessible MLCT states that cannot evolve into LMCT states. With a lifetime of 4.6 ns, the strongly reducing and oxidizing MLCT-dominated state can initiate electron transfer reactions, which could constitute a basis for future applications of iron in photoredox catalysis.</jats:p>}},
  author       = {{Steube, Jakob and Kruse, Ayla and Bokareva, Olga S. and Reuter, Thomas and Demeshko, Serhiy and Schoch, Roland and Argüello Cordero, Miguel A. and Krishna, Athul and Hohloch, Stephan and Meyer, Franc and Heinze, Katja and Kühn, Oliver and Lochbrunner, Stefan and Bauer, Matthias}},
  issn         = {{1755-4330}},
  journal      = {{Nature Chemistry}},
  keywords     = {{General Chemical Engineering, General Chemistry}},
  number       = {{4}},
  pages        = {{468--474}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{Janus-type emission from a cyclometalated iron(iii) complex}}},
  doi          = {{10.1038/s41557-023-01137-w}},
  volume       = {{15}},
  year         = {{2023}},
}

@article{34300,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>The solvation of ions changes the physical, chemical and thermodynamic properties of water, and the microscopic origin of this behaviour is believed to be ion-induced perturbation of water’s hydrogen-bonding network. Here we provide microscopic insights into this process by monitoring the dissipation of energy in salt solutions using time-resolved terahertz–Raman spectroscopy. We resonantly drive the low-frequency rotational dynamics of water molecules using intense terahertz pulses and probe the Raman response of their intermolecular translational motions. We find that the intermolecular rotational-to-translational energy transfer is enhanced by highly charged cations and is drastically reduced by highly charged anions, scaling with the ion surface charge density and ion concentration. Our molecular dynamics simulations reveal that the water–water hydrogen-bond strength between the first and second solvation shells of cations increases, while it decreases around anions. The opposite effects of cations and anions on the intermolecular interactions of water resemble the effects of ions on the stabilization and denaturation of proteins.</jats:p>}},
  author       = {{Balos, Vasileios and Kaliannan, Naveen Kumar and Elgabarty, Hossam and Wolf, Martin and Kühne, Thomas and Sajadi, Mohsen}},
  issn         = {{1755-4330}},
  journal      = {{Nature Chemistry}},
  keywords     = {{General Chemical Engineering, General Chemistry}},
  number       = {{9}},
  pages        = {{1031--1037}},
  publisher    = {{Springer Science and Business Media LLC}},
  title        = {{{Time-resolved terahertz–Raman spectroscopy reveals that cations and anions distinctly modify intermolecular interactions of water}}},
  doi          = {{10.1038/s41557-022-00977-2}},
  volume       = {{14}},
  year         = {{2022}},
}

@article{24975,
  author       = {{Franz, Martin and Chandola, Sandhya and Koy, Maximilian and Zielinski, Robert and Aldahhak, Hazem and Das, Mowpriya and Freitag, Matthias and Gerstmann, Uwe and Liebig, Denise and Hoffmann, Adrian Karl and Rosin, Maximilian and Schmidt, Wolf Gero and Hogan, Conor and Glorius, Frank and Esser, Norbert and Dähne, Mario}},
  issn         = {{1755-4330}},
  journal      = {{Nature Chemistry}},
  pages        = {{828--835}},
  title        = {{{Controlled growth of ordered monolayers of N-heterocyclic carbenes on silicon}}},
  doi          = {{10.1038/s41557-021-00721-2}},
  year         = {{2021}},
}

@article{16322,
  author       = {{Preiß, Sebastian and Förster, Christoph and Otto, Sven and Bauer, Matthias and Müller, Patrick and Hinderberger, Dariush and Hashemi Haeri, Haleh and Carella, Luca and Heinze, Katja}},
  issn         = {{1755-4330}},
  journal      = {{Nature Chemistry}},
  pages        = {{1249--1255}},
  title        = {{{Structure and reactivity of a mononuclear gold(II) complex}}},
  doi          = {{10.1038/nchem.2836}},
  year         = {{2017}},
}