---
_id: '52344'
abstract:
- lang: eng
text: Macrocyclization reactions are still challenging due to competing oligomerization,
which requires the use of small substrate concentrations. Here, the cationic tungsten
imido and tungsten oxo alkylidene N-heterocyclic carbene complexes [[W(N-2,6-Cl2-C6H3)(CHCMe2Ph(OC6F5)(pivalonitrile)(IMes)+
B(ArF)4−] (W1) and [W(O)(CHCMe2Ph(OCMe(CF3)2)(IMes)(CH3CN)+ B(ArF)4−] (W2) (IMes=1,3-dimesitylimidazol-2-ylidene;
B(ArF)4−=tetrakis(3,5-bis(trifluoromethyl)phenyl borate) have been immobilized
inside the pores of ordered mesoporous silica (OMS) with pore diameters of 3.3
and 6.8 nm, respectively, using a pore-selective immobilization protocol. X-ray
absorption spectroscopy of W1@OMS showed that even though the catalyst structure
is contracted due to confinement by the mesopores, both the oxidation state and
structure of the catalyst stayed intact upon immobilization. Catalytic testing
with four differently sized α,ω-dienes revealed a dramatically increased macrocyclization
(MC) and Z-selectivity of the supported catalysts compared to the homogenous progenitors,
allowing high substrate concentrations of 25 mM. With the supported complexes,
a maximum increase in MC-selectivity from 27 to 81 % and in Z-selectivity from
17 to 34 % was achieved. In general, smaller mesopores exhibited a stronger confinement
effect. A comparison of the two supported tungsten-based catalysts showed that
W1@OMS possesses a higher MC-selectivity, while W2@OMS exhibits a higher Z-selectivity
which can be rationalized by the structures of the catalysts.
article_type: original
author:
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Johanna R.
full_name: Bruckner, Johanna R.
last_name: Bruckner
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Patrick
full_name: Probst, Patrick
last_name: Probst
- first_name: Boshra
full_name: Atwi, Boshra
last_name: Atwi
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: Ziegler F, Bruckner JR, Nowakowski M, et al. Macrocyclization of Dienes under
Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic
Carbene Complexes. ChemCatChem. 2023;15(21). doi:10.1002/cctc.202300871
apa: Ziegler, F., Bruckner, J. R., Nowakowski, M., Bauer, M., Probst, P., Atwi,
B., & Buchmeiser, M. R. (2023). Macrocyclization of Dienes under Confinement
with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes.
ChemCatChem, 15(21). https://doi.org/10.1002/cctc.202300871
bibtex: '@article{Ziegler_Bruckner_Nowakowski_Bauer_Probst_Atwi_Buchmeiser_2023,
title={Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo
Alkylidene N‐Heterocyclic Carbene Complexes}, volume={15}, DOI={10.1002/cctc.202300871},
number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Ziegler, Felix
and Bruckner, Johanna R. and Nowakowski, Michal and Bauer, Matthias and Probst,
Patrick and Atwi, Boshra and Buchmeiser, Michael R.}, year={2023} }'
chicago: Ziegler, Felix, Johanna R. Bruckner, Michal Nowakowski, Matthias Bauer,
Patrick Probst, Boshra Atwi, and Michael R. Buchmeiser. “Macrocyclization of Dienes
under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic
Carbene Complexes.” ChemCatChem 15, no. 21 (2023). https://doi.org/10.1002/cctc.202300871.
ieee: 'F. Ziegler et al., “Macrocyclization of Dienes under Confinement with
Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes,”
ChemCatChem, vol. 15, no. 21, 2023, doi: 10.1002/cctc.202300871.'
mla: Ziegler, Felix, et al. “Macrocyclization of Dienes under Confinement with Cationic
Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes.” ChemCatChem,
vol. 15, no. 21, Wiley, 2023, doi:10.1002/cctc.202300871.
short: F. Ziegler, J.R. Bruckner, M. Nowakowski, M. Bauer, P. Probst, B. Atwi, M.R.
Buchmeiser, ChemCatChem 15 (2023).
date_created: 2024-03-07T09:44:33Z
date_updated: 2024-03-07T10:02:51Z
department:
- _id: '306'
doi: 10.1002/cctc.202300871
intvolume: ' 15'
issue: '21'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo
Alkylidene N‐Heterocyclic Carbene Complexes
type: journal_article
user_id: '48467'
volume: 15
year: '2023'
...
---
_id: '40988'
abstract:
- lang: eng
text: Increasing the metal-to-ligand charge transfer (MLCT) excited state lifetime
of polypyridine iron(II) complexes can be achieved by lowering the ligand's π*
orbital energy and by increasing the ligand field splitting. In the homo- and
heteroleptic complexes [Fe(cpmp)2]2+ (12+) and [Fe(cpmp)(ddpd)]2+ (22+) with the
tridentate ligands 6,2’’-carboxypyridyl-2,2’-methylamine-pyridyl-pyridine (cpmp)
and N,N’-dimethyl-N,N’-di-pyridin-2-ylpyridine-2,6-diamine (ddpd) two or one dipyridyl
ketone moieties provide low energy π* acceptor orbitals. A good metal-ligand orbital
overlap to increase the ligand field splitting is achieved by optimizing the octahedricity
through CO and NMe units between the coordinating pyridines which enable the formation
of six-membered chelate rings. The push-pull ligand cpmp provides intra-ligand
and ligand-to-ligand charge transfer (ILCT, LL'CT) excited states in addition
to MLCT excited states. Ground and excited state properties of 12+ and 22+ were
accessed by X-ray diffraction analyses, resonance Raman spectroscopy, (spectro)electrochemistry,
EPR spectroscopy, X-ray emission spectroscopy, static and time-resolved IR and
UV/Vis/NIR absorption spectroscopy as well as quantum chemical calculations.
author:
- first_name: Sebastian
full_name: Weber, Sebastian
last_name: Weber
- first_name: Ronny T.
full_name: Zimmermann, Ronny T.
last_name: Zimmermann
- first_name: Jens
full_name: Bremer, Jens
last_name: Bremer
- first_name: Ken L.
full_name: Abel, Ken L.
last_name: Abel
- first_name: David
full_name: Poppitz, David
last_name: Poppitz
- first_name: Nils
full_name: Prinz, Nils
last_name: Prinz
- first_name: Jan
full_name: Ilsemann, Jan
last_name: Ilsemann
- first_name: Sven
full_name: Wendholt, Sven
last_name: Wendholt
- first_name: Qingxin
full_name: Yang, Qingxin
last_name: Yang
- first_name: Reihaneh
full_name: Pashminehazar, Reihaneh
last_name: Pashminehazar
- first_name: Federico
full_name: Monaco, Federico
last_name: Monaco
- first_name: Peter
full_name: Cloetens, Peter
last_name: Cloetens
- first_name: Xiaohui
full_name: Huang, Xiaohui
last_name: Huang
- first_name: Christian
full_name: Kübel, Christian
last_name: Kübel
- first_name: Evgenii
full_name: Kondratenko, Evgenii
last_name: Kondratenko
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Marcus
full_name: Bäumer, Marcus
last_name: Bäumer
- first_name: Mirijam
full_name: Zobel, Mirijam
last_name: Zobel
- first_name: Roger
full_name: Gläser, Roger
last_name: Gläser
- first_name: Kai
full_name: Sundmacher, Kai
last_name: Sundmacher
- first_name: Thomas L.
full_name: Sheppard, Thomas L.
last_name: Sheppard
citation:
ama: 'Weber S, Zimmermann RT, Bremer J, et al. Digitization in Catalysis Research:
Towards a Holistic Description of a Ni/Al2O3Reference Catalyst
for CO2Methanation. ChemCatChem. 2022;14(8). doi:10.1002/cctc.202101878'
apa: 'Weber, S., Zimmermann, R. T., Bremer, J., Abel, K. L., Poppitz, D., Prinz,
N., Ilsemann, J., Wendholt, S., Yang, Q., Pashminehazar, R., Monaco, F., Cloetens,
P., Huang, X., Kübel, C., Kondratenko, E., Bauer, M., Bäumer, M., Zobel, M., Gläser,
R., … Sheppard, T. L. (2022). Digitization in Catalysis Research: Towards a Holistic
Description of a Ni/Al2O3Reference Catalyst for CO2Methanation.
ChemCatChem, 14(8). https://doi.org/10.1002/cctc.202101878'
bibtex: '@article{Weber_Zimmermann_Bremer_Abel_Poppitz_Prinz_Ilsemann_Wendholt_Yang_Pashminehazar_et
al._2022, title={Digitization in Catalysis Research: Towards a Holistic Description
of a Ni/Al2O3Reference Catalyst for CO2Methanation},
volume={14}, DOI={10.1002/cctc.202101878},
number={8}, journal={ChemCatChem}, publisher={Wiley}, author={Weber, Sebastian
and Zimmermann, Ronny T. and Bremer, Jens and Abel, Ken L. and Poppitz, David
and Prinz, Nils and Ilsemann, Jan and Wendholt, Sven and Yang, Qingxin and Pashminehazar,
Reihaneh and et al.}, year={2022} }'
chicago: 'Weber, Sebastian, Ronny T. Zimmermann, Jens Bremer, Ken L. Abel, David
Poppitz, Nils Prinz, Jan Ilsemann, et al. “Digitization in Catalysis Research:
Towards a Holistic Description of a Ni/Al2O3Reference Catalyst
for CO2Methanation.” ChemCatChem 14, no. 8 (2022). https://doi.org/10.1002/cctc.202101878.'
ieee: 'S. Weber et al., “Digitization in Catalysis Research: Towards a Holistic
Description of a Ni/Al2O3Reference Catalyst for CO2Methanation,”
ChemCatChem, vol. 14, no. 8, 2022, doi: 10.1002/cctc.202101878.'
mla: 'Weber, Sebastian, et al. “Digitization in Catalysis Research: Towards a Holistic
Description of a Ni/Al2O3Reference Catalyst for CO2Methanation.”
ChemCatChem, vol. 14, no. 8, Wiley, 2022, doi:10.1002/cctc.202101878.'
short: S. Weber, R.T. Zimmermann, J. Bremer, K.L. Abel, D. Poppitz, N. Prinz, J.
Ilsemann, S. Wendholt, Q. Yang, R. Pashminehazar, F. Monaco, P. Cloetens, X. Huang,
C. Kübel, E. Kondratenko, M. Bauer, M. Bäumer, M. Zobel, R. Gläser, K. Sundmacher,
T.L. Sheppard, ChemCatChem 14 (2022).
date_created: 2023-01-30T16:25:02Z
date_updated: 2023-01-31T08:00:47Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/cctc.202101878
intvolume: ' 14'
issue: '8'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: 'Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference
Catalyst for CO2Methanation'
type: journal_article
user_id: '48467'
volume: 14
year: '2022'
...
---
_id: '41208'
author:
- first_name: Sebastian
full_name: Weber, Sebastian
last_name: Weber
- first_name: Ronny T.
full_name: Zimmermann, Ronny T.
last_name: Zimmermann
- first_name: Jens
full_name: Bremer, Jens
last_name: Bremer
- first_name: Ken L.
full_name: Abel, Ken L.
last_name: Abel
- first_name: David
full_name: Poppitz, David
last_name: Poppitz
- first_name: Nils
full_name: Prinz, Nils
last_name: Prinz
- first_name: Jan
full_name: Ilsemann, Jan
last_name: Ilsemann
- first_name: Sven
full_name: Strübbe, Sven
id: '76968'
last_name: Strübbe
- first_name: Qingxin
full_name: Yang, Qingxin
last_name: Yang
- first_name: Reihaneh
full_name: Pashminehazar, Reihaneh
last_name: Pashminehazar
- first_name: Federico
full_name: Monaco, Federico
last_name: Monaco
- first_name: Peter
full_name: Cloetens, Peter
last_name: Cloetens
- first_name: Xiaohui
full_name: Huang, Xiaohui
last_name: Huang
- first_name: Christian
full_name: Kübel, Christian
last_name: Kübel
- first_name: Evgenii
full_name: Kondratenko, Evgenii
last_name: Kondratenko
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Marcus
full_name: Bäumer, Marcus
last_name: Bäumer
- first_name: Mirijam
full_name: Zobel, Mirijam
last_name: Zobel
- first_name: Roger
full_name: Gläser, Roger
last_name: Gläser
- first_name: Kai
full_name: Sundmacher, Kai
last_name: Sundmacher
- first_name: Thomas L.
full_name: Sheppard, Thomas L.
last_name: Sheppard
citation:
ama: 'Weber S, Zimmermann RT, Bremer J, et al. Digitization in Catalysis Research:
Towards a Holistic Description of a Ni/Al2O3Reference Catalyst
for CO2Methanation. ChemCatChem. 2022;14(8). doi:10.1002/cctc.202101878'
apa: 'Weber, S., Zimmermann, R. T., Bremer, J., Abel, K. L., Poppitz, D., Prinz,
N., Ilsemann, J., Strübbe, S., Yang, Q., Pashminehazar, R., Monaco, F., Cloetens,
P., Huang, X., Kübel, C., Kondratenko, E., Bauer, M., Bäumer, M., Zobel, M., Gläser,
R., … Sheppard, T. L. (2022). Digitization in Catalysis Research: Towards a Holistic
Description of a Ni/Al2O3Reference Catalyst for CO2Methanation.
ChemCatChem, 14(8). https://doi.org/10.1002/cctc.202101878'
bibtex: '@article{Weber_Zimmermann_Bremer_Abel_Poppitz_Prinz_Ilsemann_Strübbe_Yang_Pashminehazar_et
al._2022, title={Digitization in Catalysis Research: Towards a Holistic Description
of a Ni/Al2O3Reference Catalyst for CO2Methanation},
volume={14}, DOI={10.1002/cctc.202101878},
number={8}, journal={ChemCatChem}, publisher={Wiley}, author={Weber, Sebastian
and Zimmermann, Ronny T. and Bremer, Jens and Abel, Ken L. and Poppitz, David
and Prinz, Nils and Ilsemann, Jan and Strübbe, Sven and Yang, Qingxin and Pashminehazar,
Reihaneh and et al.}, year={2022} }'
chicago: 'Weber, Sebastian, Ronny T. Zimmermann, Jens Bremer, Ken L. Abel, David
Poppitz, Nils Prinz, Jan Ilsemann, et al. “Digitization in Catalysis Research:
Towards a Holistic Description of a Ni/Al2O3Reference Catalyst
for CO2Methanation.” ChemCatChem 14, no. 8 (2022). https://doi.org/10.1002/cctc.202101878.'
ieee: 'S. Weber et al., “Digitization in Catalysis Research: Towards a Holistic
Description of a Ni/Al2O3Reference Catalyst for CO2Methanation,”
ChemCatChem, vol. 14, no. 8, 2022, doi: 10.1002/cctc.202101878.'
mla: 'Weber, Sebastian, et al. “Digitization in Catalysis Research: Towards a Holistic
Description of a Ni/Al2O3Reference Catalyst for CO2Methanation.”
ChemCatChem, vol. 14, no. 8, Wiley, 2022, doi:10.1002/cctc.202101878.'
short: S. Weber, R.T. Zimmermann, J. Bremer, K.L. Abel, D. Poppitz, N. Prinz, J.
Ilsemann, S. Strübbe, Q. Yang, R. Pashminehazar, F. Monaco, P. Cloetens, X. Huang,
C. Kübel, E. Kondratenko, M. Bauer, M. Bäumer, M. Zobel, R. Gläser, K. Sundmacher,
T.L. Sheppard, ChemCatChem 14 (2022).
date_created: 2023-01-31T14:04:55Z
date_updated: 2023-01-31T14:05:50Z
doi: 10.1002/cctc.202101878
intvolume: ' 14'
issue: '8'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: 'Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference
Catalyst for CO2Methanation'
type: journal_article
user_id: '76968'
volume: 14
year: '2022'
...
---
_id: '41020'
author:
- first_name: Bernhard J.
full_name: Gregori, Bernhard J.
last_name: Gregori
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Anke
full_name: Schoch, Anke
id: '27611'
last_name: Schoch
orcid: 0000-0002-9457-400X
- first_name: Simon
full_name: Pöllath, Simon
last_name: Pöllath
- first_name: Josef
full_name: Zweck, Josef
last_name: Zweck
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Axel
full_name: Jacobi von Wangelin, Axel
last_name: Jacobi von Wangelin
citation:
ama: Gregori BJ, Nowakowski M, Schoch A, et al. Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes. ChemCatChem. 2020;12(21):5359-5363. doi:10.1002/cctc.202000994
apa: Gregori, B. J., Nowakowski, M., Schoch, A., Pöllath, S., Zweck, J., Bauer,
M., & Jacobi von Wangelin, A. (2020). Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes. ChemCatChem, 12(21), 5359–5363. https://doi.org/10.1002/cctc.202000994
bibtex: '@article{Gregori_Nowakowski_Schoch_Pöllath_Zweck_Bauer_Jacobi von Wangelin_2020,
title={Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}, volume={12},
DOI={10.1002/cctc.202000994},
number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Gregori, Bernhard
J. and Nowakowski, Michal and Schoch, Anke and Pöllath, Simon and Zweck, Josef
and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2020}, pages={5359–5363}
}'
chicago: 'Gregori, Bernhard J., Michal Nowakowski, Anke Schoch, Simon Pöllath, Josef
Zweck, Matthias Bauer, and Axel Jacobi von Wangelin. “Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes.” ChemCatChem 12, no. 21 (2020): 5359–63.
https://doi.org/10.1002/cctc.202000994.'
ieee: 'B. J. Gregori et al., “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes,” ChemCatChem, vol. 12, no. 21, pp. 5359–5363, 2020, doi: 10.1002/cctc.202000994.'
mla: Gregori, Bernhard J., et al. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes.” ChemCatChem, vol. 12, no. 21, Wiley, 2020, pp. 5359–63, doi:10.1002/cctc.202000994.
short: B.J. Gregori, M. Nowakowski, A. Schoch, S. Pöllath, J. Zweck, M. Bauer, A.
Jacobi von Wangelin, ChemCatChem 12 (2020) 5359–5363.
date_created: 2023-01-30T17:35:14Z
date_updated: 2023-01-31T08:29:24Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/cctc.202000994
intvolume: ' 12'
issue: '21'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
page: 5359-5363
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes
type: journal_article
user_id: '27611'
volume: 12
year: '2020'
...
---
_id: '41329'
author:
- first_name: Bernhard J.
full_name: Gregori, Bernhard J.
last_name: Gregori
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Anke
full_name: Schoch, Anke
last_name: Schoch
- first_name: Simon
full_name: Pöllath, Simon
last_name: Pöllath
- first_name: Josef
full_name: Zweck, Josef
last_name: Zweck
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Axel
full_name: Jacobi von Wangelin, Axel
last_name: Jacobi von Wangelin
citation:
ama: Gregori BJ, Nowakowski M, Schoch A, et al. Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes. ChemCatChem. 2020;12(21):5359-5363. doi:10.1002/cctc.202000994
apa: Gregori, B. J., Nowakowski, M., Schoch, A., Pöllath, S., Zweck, J., Bauer,
M., & Jacobi von Wangelin, A. (2020). Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes. ChemCatChem, 12(21), 5359–5363. https://doi.org/10.1002/cctc.202000994
bibtex: '@article{Gregori_Nowakowski_Schoch_Pöllath_Zweck_Bauer_Jacobi von Wangelin_2020,
title={Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}, volume={12},
DOI={10.1002/cctc.202000994},
number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Gregori, Bernhard
J. and Nowakowski, Michal and Schoch, Anke and Pöllath, Simon and Zweck, Josef
and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2020}, pages={5359–5363}
}'
chicago: 'Gregori, Bernhard J., Michal Nowakowski, Anke Schoch, Simon Pöllath, Josef
Zweck, Matthias Bauer, and Axel Jacobi von Wangelin. “Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes.” ChemCatChem 12, no. 21 (2020): 5359–63.
https://doi.org/10.1002/cctc.202000994.'
ieee: 'B. J. Gregori et al., “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes,” ChemCatChem, vol. 12, no. 21, pp. 5359–5363, 2020, doi: 10.1002/cctc.202000994.'
mla: Gregori, Bernhard J., et al. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes.” ChemCatChem, vol. 12, no. 21, Wiley, 2020, pp. 5359–63, doi:10.1002/cctc.202000994.
short: B.J. Gregori, M. Nowakowski, A. Schoch, S. Pöllath, J. Zweck, M. Bauer, A.
Jacobi von Wangelin, ChemCatChem 12 (2020) 5359–5363.
date_created: 2023-01-31T22:52:39Z
date_updated: 2023-02-01T08:50:41Z
doi: 10.1002/cctc.202000994
intvolume: ' 12'
issue: '21'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
page: 5359-5363
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes
type: journal_article
user_id: '78878'
volume: 12
year: '2020'
...
---
_id: '21364'
author:
- first_name: Reni
full_name: Grauke, Reni
last_name: Grauke
- first_name: Rahel
full_name: Schepper, Rahel
last_name: Schepper
- first_name: Jabor
full_name: Rabeah, Jabor
last_name: Rabeah
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Ursula
full_name: Bentrup, Ursula
last_name: Bentrup
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
- first_name: Angelika
full_name: Brückner, Angelika
last_name: Brückner
citation:
ama: Grauke R, Schepper R, Rabeah J, et al. Impact of Al Activators on Structure
and Catalytic Performance of Cr Catalysts in Homogeneous Ethylene Oligomerization
– A Multitechnique in situ/operando Study. ChemCatChem.
2019:1025-1035. doi:10.1002/cctc.201901441
apa: Grauke, R., Schepper, R., Rabeah, J., Schoch, R., Bentrup, U., Bauer, M., &
Brückner, A. (2019). Impact of Al Activators on Structure and Catalytic Performance
of Cr Catalysts in Homogeneous Ethylene Oligomerization – A Multitechnique
in situ/operando Study. ChemCatChem, 1025–1035. https://doi.org/10.1002/cctc.201901441
bibtex: '@article{Grauke_Schepper_Rabeah_Schoch_Bentrup_Bauer_Brückner_2019, title={Impact
of Al Activators on Structure and Catalytic Performance of Cr Catalysts in Homogeneous
Ethylene Oligomerization – A Multitechnique in situ/operando
Study}, DOI={10.1002/cctc.201901441},
journal={ChemCatChem}, author={Grauke, Reni and Schepper, Rahel and Rabeah, Jabor
and Schoch, Roland and Bentrup, Ursula and Bauer, Matthias and Brückner, Angelika},
year={2019}, pages={1025–1035} }'
chicago: Grauke, Reni, Rahel Schepper, Jabor Rabeah, Roland Schoch, Ursula Bentrup,
Matthias Bauer, and Angelika Brückner. “Impact of Al Activators on Structure and
Catalytic Performance of Cr Catalysts in Homogeneous Ethylene Oligomerization
– A Multitechnique in Situ/Operando Study.” ChemCatChem,
2019, 1025–35. https://doi.org/10.1002/cctc.201901441.
ieee: R. Grauke et al., “Impact of Al Activators on Structure and Catalytic
Performance of Cr Catalysts in Homogeneous Ethylene Oligomerization – A Multitechnique
in situ/operando Study,” ChemCatChem, pp. 1025–1035,
2019.
mla: Grauke, Reni, et al. “Impact of Al Activators on Structure and Catalytic Performance
of Cr Catalysts in Homogeneous Ethylene Oligomerization – A Multitechnique
in Situ/Operando Study.” ChemCatChem, 2019, pp. 1025–35,
doi:10.1002/cctc.201901441.
short: R. Grauke, R. Schepper, J. Rabeah, R. Schoch, U. Bentrup, M. Bauer, A. Brückner,
ChemCatChem (2019) 1025–1035.
date_created: 2021-03-02T12:37:34Z
date_updated: 2022-01-06T06:54:56Z
department:
- _id: '306'
doi: 10.1002/cctc.201901441
language:
- iso: eng
page: 1025-1035
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
status: public
title: Impact of Al Activators on Structure and Catalytic Performance of Cr Catalysts
in Homogeneous Ethylene Oligomerization – A Multitechnique in situ/operando Study
type: journal_article
user_id: '54037'
year: '2019'
...